Articles | Volume 19, issue 1
https://doi.org/10.5194/acp-19-89-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-89-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Jan 2019
Research article |
| 03 Jan 2019
| 03 Jan 2019
New particle formation in the marine atmosphere during seven cruise campaigns
Yujiao Zhu
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Kai Li
National Marine Environmental Forecasting Center, Beijing 100081,
China
Yanjie Shen
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Laboratory for Marine Ecology and Environmental Science,
Qingdao National Laboratory for Marine Science and Technology, Qingdao
266071, China
Xiaohuan Liu
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Huiwang Gao
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Laboratory for Marine Ecology and Environmental Science,
Qingdao National Laboratory for Marine Science and Technology, Qingdao
266071, China
Xiaohong Yao
CORRESPONDING AUTHOR
Key Lab of Marine Environmental Science and Ecology, Ministry of
Education, Ocean University of China, Qingdao 266100, China
Laboratory for Marine Ecology and Environmental Science,
Qingdao National Laboratory for Marine Science and Technology, Qingdao
266071, China
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Xiadong An, Lifang Sheng, Qian Liu, Chun Li, Yang Gao, and Jianping Li
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ACCMIP simulations were used to study NOy deposition over East Asia in the future. Both dry and wet NOy deposition show significant decreases in the 2100s under RCP4.5 and RCP8.5 due to large anthropogenic emission reduction. The changes in climate only significantly affect the wet deposition primarily linked to changes in precipitation. Over the coastal seas of China, weaker transport of NOy from land due to emission reduction infers a larger impact from shipping and lightning emissions.
Jinhui Shi, Nan Wang, Huiwang Gao, Alex R. Baker, Xiaohong Yao, and Daizhou Zhang
Atmos. Chem. Phys., 19, 847–860, https://doi.org/10.5194/acp-19-847-2019, https://doi.org/10.5194/acp-19-847-2019, 2019
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Water-soluble phosphorus (P) in natural and anthropogenic mineral particles in Asian continent outflow is regarded as one of the key nutrients for the biological cycle in the surface seawater of the North Pacific. Our observations at a Chinese coastal site revealed that P solubility was closely relevant to the particle origins, atmospheric acidic processes and ambient relative humidity. The recent severe air pollution over East Asia has likely enhanced bioavailable P input to the North Pacific.
Ge Zhang, Yang Gao, Wenju Cai, L. Ruby Leung, Shuxiao Wang, Bin Zhao, Minghuai Wang, Huayao Shan, Xiaohong Yao, and Huiwang Gao
Atmos. Chem. Phys., 19, 565–576, https://doi.org/10.5194/acp-19-565-2019, https://doi.org/10.5194/acp-19-565-2019, 2019
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Based on observed data, this study reveals a distinct seesaw feature of abnormally high and low PM2.5 concentrations in December 2015 and January 2016 over North China. The mechanism of the seesaw pattern was found to be linked to a super El Niño and the Arctic Oscillation (AO). During the mature phase of El Niño in December 2015, the weakened East Asian winter monsoon favors strong haze formation; however, the circulation pattern was reversed in the next month due to the phase change of the AO.
Junxi Zhang, Yang Gao, Kun Luo, L. Ruby Leung, Yang Zhang, Kai Wang, and Jianren Fan
Atmos. Chem. Phys., 18, 9861–9877, https://doi.org/10.5194/acp-18-9861-2018, https://doi.org/10.5194/acp-18-9861-2018, 2018
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We used a regional model to investigate the impact of atmosphere with high temperature and low wind speed on ozone concentration. When these compound events (heat waves and stagnant weather) occur simultaneously, a striking ozone enhancement is revealed. This type of compound event is projected to increase more dominantly compared to single events in the future over the US, Europe, and China, implying the importance of reducing emissions in order to alleviate the impact from the compound events.
Pei Hou, Shiliang Wu, Jessica L. McCarty, and Yang Gao
Atmos. Chem. Phys., 18, 8173–8182, https://doi.org/10.5194/acp-18-8173-2018, https://doi.org/10.5194/acp-18-8173-2018, 2018
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Atmospheric aerosols can be affected not only by emissions, but also meteorology, in particular precipitation. Analyses of the historical meteorological data based on multiple datasets show significant changes in precipitation characteristics, including precipitation intensity and frequency, over various regions around the world. We find that the precipitation changes over the past 30 years can easily lead to perturbations in atmospheric aerosols by 10 % or higher at the regional scale.
Li Luo, Shuh-Ji Kao, Hongyan Bao, Huayun Xiao, Hongwei Xiao, Xiaohong Yao, Huiwang Gao, Jiawei Li, and Yangyang Lu
Atmos. Chem. Phys., 18, 6207–6222, https://doi.org/10.5194/acp-18-6207-2018, https://doi.org/10.5194/acp-18-6207-2018, 2018
Zhi-zhen Ni, Kun Luo, Yang Gao, Fei Jiang, Xiang Gao, Jian-ren Fan, and Chang-hong Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-76, https://doi.org/10.5194/acp-2018-76, 2018
Revised manuscript not accepted
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A unique mechanism was found to modulate the high ozone episodes in Hangzhou during G20 summit: Driven by tropical cyclone convergence, prevailing north winds brought in emission sources; with invasion of tropical cycle, subsidence air and stagnant weather was induced, as well as the urban heat island effect, intensifying the ozone enhancement. Different atmospheric processes were further analyzed to elucidate the control factors of ozone formation through integrated process rate method.
Chao Zhang, Huiwang Gao, Xiaohong Yao, Zongbo Shi, Jinhui Shi, Yang Yu, Ling Meng, and Xinyu Guo
Biogeosciences, 15, 749–765, https://doi.org/10.5194/bg-15-749-2018, https://doi.org/10.5194/bg-15-749-2018, 2018
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This study compares the response of phytoplankton growth in the northwest Pacific to those in the Yellow Sea. In general, larger positive responses of phytoplankton induced by combined nutrients (in the subtropical gyre of the northwest Pacific) than those induced by a single nutrient (in the Kuroshio Extension and the Yellow Sea) from the dust are observed. We also emphasize the importance of an increase in bioavailable P stock for phytoplankton growth following dust addition.
Jianhua Qi, Xiaohuan Liu, Xiaohong Yao, Ruifeng Zhang, Xiaojing Chen, Xuehui Lin, Huiwang Gao, and Ruhai Liu
Atmos. Chem. Phys., 18, 571–586, https://doi.org/10.5194/acp-18-571-2018, https://doi.org/10.5194/acp-18-571-2018, 2018
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Inorganic nitrogen has a great impact on marine productivity when deposited to the ocean via atmospheric deposition. Do dust events always increase the atmospheric input of inorganic nitrogen to the ocean? The estimated deposition flux of NNH4++NO3- varied greatly from event to event. A simple assumption of a linear increase in inorganic nitrogen with increasing dust load could lead to a considerable overestimation of the dry deposition flux of nutrients into the oceans.
Chengzhi Xing, Cheng Liu, Shanshan Wang, Ka Lok Chan, Yang Gao, Xin Huang, Wenjing Su, Chengxin Zhang, Yunsheng Dong, Guangqiang Fan, Tianshu Zhang, Zhenyi Chen, Qihou Hu, Hang Su, Zhouqing Xie, and Jianguo Liu
Atmos. Chem. Phys., 17, 14275–14289, https://doi.org/10.5194/acp-17-14275-2017, https://doi.org/10.5194/acp-17-14275-2017, 2017
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Vertical profiles of the aerosol extinction coefficient and NO2 and HCHO concentrations were retrieved from MAX-DOAS measurement, while vertical distribution of O3 was obtained using ozone lidar. The measured O3 vertical distribution indicates that the ozone production not only occurs at surface level but also at higher altitudes (about 1.1 km), which are not directly related to horizontal and vertical transportation but are mainly influenced by the abundance of VOCs in the lower troposphere.
Yujiao Zhu, Caiqing Yan, Renyi Zhang, Zifa Wang, Mei Zheng, Huiwang Gao, Yang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 17, 9469–9484, https://doi.org/10.5194/acp-17-9469-2017, https://doi.org/10.5194/acp-17-9469-2017, 2017
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This study reports the distinct effects of street canyons on new particle formation (NPF) under warm or cold ambient temperature conditions because of on-road vehicle emissions; i.e., stronger condensation sinks are responsible for the reduced NPF in the springtime, but efficient nucleation and partitioning of gaseous species contribute to the enhanced NPF in the wintertime. The oxidization of biogenic organics is suggested to play an important role in growing new particles.
Xiang Gong, Wensheng Jiang, Linhui Wang, Huiwang Gao, Emmanuel Boss, Xiaohong Yao, Shuh-Ji Kao, and Jie Shi
Biogeosciences, 14, 2371–2386, https://doi.org/10.5194/bg-14-2371-2017, https://doi.org/10.5194/bg-14-2371-2017, 2017
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The subsurface chlorophyll maximum layer (SCML) forms near the nitracline. By incorporating a piecewise function for the approximate Gaussian vertical profile of chlorophyll, we derive analytical solutions of a specified nutrient–phytoplankton model. Nitracline depth is deeper than SCML depth, and a thinner SCML corresponds to a steeper nitracline. A higher light attenuation coefficient leads to a shallower but steeper nitracline. Nitracline steepness is independent of surface light intensity.
Xiaohong Yao and Leiming Zhang
Atmos. Chem. Phys., 16, 11465–11475, https://doi.org/10.5194/acp-16-11465-2016, https://doi.org/10.5194/acp-16-11465-2016, 2016
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Atmospheric NH3 plays an important role in forming secondary aerosols and has a direct impact on sensitive ecosystems. This study aims to study its long-term variation and find that the long-term trend can be affected by climate change as well as other anthropogenic factors, depending on sites. A large percentage increase of atmospheric NH3 at remote American sites is surprising and may cause a potential threat to sensitive ecosystems in the future.
Josiane Mélançon, Maurice Levasseur, Martine Lizotte, Michael Scarratt, Jean-Éric Tremblay, Philippe Tortell, Gui-Peng Yang, Guang-Yu Shi, Huiwang Gao, David Semeniuk, Marie Robert, Michael Arychuk, Keith Johnson, Nes Sutherland, Marty Davelaar, Nina Nemcek, Angelica Peña, and Wendy Richardson
Biogeosciences, 13, 1677–1692, https://doi.org/10.5194/bg-13-1677-2016, https://doi.org/10.5194/bg-13-1677-2016, 2016
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Ocean acidification is likely to affect iron-limited phytoplankton fertilization by desert dust. Short incubations of northeast subarctic Pacific waters enriched with dust and set at pH 8.0 and 7.8 were conducted. Acidification led to a significant reduction (by 16–38 %) of the final concentration of chl a reached after enrichment. These results show that dust deposition events in a low-pH iron-limited ocean are likely to stimulate phytoplankton growth to a lesser extent than in today's ocean.
L. Luo, X. H. Yao, H. W. Gao, S. C. Hsu, J. W. Li, and S. J. Kao
Atmos. Chem. Phys., 16, 325–341, https://doi.org/10.5194/acp-16-325-2016, https://doi.org/10.5194/acp-16-325-2016, 2016
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Concentrations and depositions of various nitrogen species of water-soluble fraction in aerosols were observed during spring over the eastern China seas and northwestern Pacific Ocean. Results revealed nitrogen deposition associated with the sea fog weather was 6 times higher than that of spring supply from the Yangtze River to the ECS shelf. The DON emission had occurred most likely during sea spray. Weather conditions modulate the nitrogen exchange at the ocean-atmosphere boundary.
X. Gong, J. Shi, H. W. Gao, and X. H. Yao
Biogeosciences, 12, 905–919, https://doi.org/10.5194/bg-12-905-2015, https://doi.org/10.5194/bg-12-905-2015, 2015
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Analytical solutions indicate that subsurface chlorophyll maximum (SCM) occurs at or below the depth of optimal growth of phytoplankton, and the depth of SCM layer deepens logarithmically with an increase in surface light intensity; thickness and intensity of the SCM layer are mainly affected by nutrient supply, but independent of surface light intensity; intensity of the SCM strengthens as a result of this layer being shrunk by a higher light attenuation coefficient or a large sinking velocity
X. H. Liu, Y. J. Zhu, M. Zheng, H. W. Gao, and X. H. Yao
Atmos. Chem. Phys., 14, 7941–7951, https://doi.org/10.5194/acp-14-7941-2014, https://doi.org/10.5194/acp-14-7941-2014, 2014
X. H. Yao and L. Zhang
Biogeosciences, 10, 7913–7925, https://doi.org/10.5194/bg-10-7913-2013, https://doi.org/10.5194/bg-10-7913-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Characterizing lead-rich particles in Beijing's atmosphere following coal-to-gas conversion: insights from single-particle aerosol mass spectrometry
Climatology of aerosol pH and its controlling factors at the Melpitz continental background site in Central Europe
Technical note: Towards a stronger observational support for haze pollution control by interpreting carbonaceous aerosol results derived from different measurement approaches
Particle flux–gradient relationships in the high Arctic: emission and deposition patterns across three surface types
Advances in characterization of black carbon particles and their associated coatings using the soot-particle aerosol mass spectrometer in Singapore, a complex city environment
Iron isotopes suggest significant aerosol dissolution over the Pacific Ocean
Enrichment of organic nitrogen in fog residuals observed in the Italian Po Valley
Asian dust transport of proteinaceous matter from the Gobi Desert to northern China
Machine-learning-assisted chemical characterization and optical properties of atmospheric brown carbon in Nanjing, China
Technical note: Reconstructing missing surface aerosol elemental carbon data in long-term series with ensemble learning
Enhanced emission of intermediate-volatility/semi-volatile organic matter in gas and particle phases from ship exhausts with low-sulfur fuels
Measurement report: Crustal materials play an increasing role in elevating particle pH – insights from 12-year records in a typical inland city of China
Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations
Measurement report: In-depth characterization of ship emissions during operations in a Mediterranean port
Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations
Measurement report: Per- and polyfluoroalkyl substances (PFAS) in particulate matter (PM10) from activated sludge aeration
African dust transported to Barbados in the wintertime lacks indicators of chemical aging
A 60-year atmospheric nitrate isotope record from a southeastern Greenland ice core with minimal postdepositional alteration
Measurement report: Characterization of aerosol hygroscopicity over Southeast Asia during the NASA CAMP2Ex campaign
Long–term Trends in PM2.5 Chemical Composition and Its Impact on Aerosol Properties: Field Observations from 2007 to 2020 in Pearl River Delta, South China
Atmospheric Organosulfate Formation Regulated by Continental Outflows and Marine Emissions over East Asian Marginal Seas
Individual particle compositions and aerosol mixing states at different altitudes over the ocean in East Asia
Molecular characterization of organic aerosols in urban and forested areas of Paris using high-resolution mass spectrometry
Measurement report: Wintertime aerosol characterization at an urban traffic site in Helsinki, Finland
Source apportionment and ecotoxicity of PM2.5 pollution events in a major Southern Hemisphere megacity: influence of a biofuel-impacted fleet and biomass burning
The impacts of pollution sources and temperature on the light absorption of HULIS were revealed by UHPLC-HRMS/MS at the molecular structure level
Effects of Anthropogenic Pollutants on Biogenic Secondary Organic Aerosol Formation in the Atmosphere of Mt. Hua, China
Marine organic aerosol at Mace Head: effects from phytoplankton and source region variability
Elemental composition, iron mineralogy and solubility of anthropogenic and natural mineral dust aerosols in Namibia: a case study analysis from the AEROCLO-sA campaign
Fossil-Dominated SOA Formation in Coastal China: Size-Divergent Pathways of Aqueous Fenton Reactions versus Gas-phase VOC Autoxidation
Measurement report: Sources and meteorology influencing highly time-resolved PM2.5 trace elements at three urban sites in the extremely polluted Indo-Gangetic Plain in India
Measurement report: Year-long chemical composition, optical properties, and sources of atmospheric aerosols in the northeastern Tibetan Plateau
Formation of highly absorptive secondary brown carbon through nighttime multiphase chemistry of biomass burning emissions
Hydroxymethanesulfonate (HMS) Formation under Urban and Marine Atmosphere: role of aerosol ionic strength
The sources and diurnal variations of submicron aerosols in a coastal-rural environment near Houston, US
Measurement report: Vertically resolved atmospheric properties observed over the Southern Great Plains with the ArcticShark uncrewed aerial system
Measurement report: Simultaneous measurement on atmospheric gas- and aerosol-phase water-soluble organics in Shanghai: Remarkable increase in light absorbing of Asian dust aerosols during long-range transport
Unraveling Arctic submicron organic aerosol sources: a year-long study by H-NMR and AMS in Ny-Ålesund, Svalbard
Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China
Unveiling single-particle composition, size, shape, and mixing state of freshly emitted Icelandic dust via electron microscopy analysis
The Critical Role of Volatile Organic Compounds Emission in Nitrate Formation in Lhasa, Tibetan Plateau: Insights from Oxygen Isotope Anomaly Measurements
The critical role of aqueous-phase processes in aromatic-derived nitrogen-containing organic aerosol formation in cities with different energy consumption patterns
Characterization of atmospheric water-soluble brown carbon in the Athabasca oil sands region, Canada
Sensitivity of aerosol and cloud properties to coupling strength of marine boundary layer clouds over the northwest Atlantic
Measurement Report: Molecular composition, sources, and evolution of atmospheric organic aerosols in a basin city in China
Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer
Observations of high-time-resolution and size-resolved aerosol chemical composition and microphysics in the central Arctic: implications for climate-relevant particle properties
A critical review of the use of iron isotopes in atmospheric aerosol research
Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations
Atmospheric chemistry in East Asia determines the iron solubility of aerosol particles supplied to the North Pacific Ocean
Xiufeng Lian, Yongjiang Xu, Fengxian Liu, Long Peng, Xiaodong Hu, Guigang Tang, Xu Dao, Hui Guo, Liwei Wang, Bo Huang, Chunlei Cheng, Lei Li, Guohua Zhang, Xinhui Bi, Xiaofei Wang, Zhen Zhou, and Mei Li
Atmos. Chem. Phys., 25, 8891–8905, https://doi.org/10.5194/acp-25-8891-2025, https://doi.org/10.5194/acp-25-8891-2025, 2025
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In this study, we analyzed the mixing state and atmospheric chemical processes of Pb-rich single particles in Beijing. We focused on analyzing the differences in Pb-rich particles between the heating period and non-heating period, as well as the formation mechanism of lead nitrate after coal-to-gas conversion. Our results highlighted the improvement of Pb levels in the particulate as a result of coal-to-gas conversion.
Vikram Pratap, Christopher J. Hennigan, Bastian Stieger, Andreas Tilgner, Laurent Poulain, Dominik van Pinxteren, Gerald Spindler, and Hartmut Herrmann
Atmos. Chem. Phys., 25, 8871–8889, https://doi.org/10.5194/acp-25-8871-2025, https://doi.org/10.5194/acp-25-8871-2025, 2025
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In this work, we characterize trends in aerosol pH and its controlling factors during the period 2010–2019 at the Melpitz research station in eastern Germany. We find strong trends in aerosol pH and major inorganic species in response to changing emissions. We conduct a detailed thermodynamic analysis of the aerosol system and discuss implications for controlling particulate matter in the region.
Yuan Cheng, Ying-jie Zhong, Zhi-qing Zhang, Xu-bing Cao, and Jiu-meng Liu
Atmos. Chem. Phys., 25, 8493–8505, https://doi.org/10.5194/acp-25-8493-2025, https://doi.org/10.5194/acp-25-8493-2025, 2025
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As an emerging hotspot of atmospheric sciences, northeastern China is distinct due to the frigid winter and the strong emissions from agricultural fires. Based on field campaigns conducted in Harbin, we successively identified the analytical method that could lead to proper results of organic and elemental carbon. Our results are believed to be a support for future efforts in the exploration of PM2.5 sources in northeastern China, which are essential for further improving the regional air quality.
Theresa Mathes, Heather Guy, John Prytherch, Julia Kojoj, Ian Brooks, Sonja Murto, Paul Zieger, Birgit Wehner, Michael Tjernström, and Andreas Held
Atmos. Chem. Phys., 25, 8455–8474, https://doi.org/10.5194/acp-25-8455-2025, https://doi.org/10.5194/acp-25-8455-2025, 2025
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The Arctic is warming faster than the global average and an investigation of aerosol–cloud–sea ice interactions is crucial for studying its climate system. During the ARTofMELT Expedition 2023, particle and sensible heat fluxes were measured over different surfaces. Wide lead surfaces acted as particle sources, with the strongest sensible heat fluxes, while closed ice surfaces acted as particle sinks. In this study, methods to measure these interactions are improved, enhancing our understanding of Arctic climate processes.
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
Atmos. Chem. Phys., 25, 8185–8211, https://doi.org/10.5194/acp-25-8185-2025, https://doi.org/10.5194/acp-25-8185-2025, 2025
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This work advances our understanding of the emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Capucine Camin, François Lacan, Catherine Pradoux, Marie Labatut, Anne Johansen, and James W. Murray
Atmos. Chem. Phys., 25, 8213–8228, https://doi.org/10.5194/acp-25-8213-2025, https://doi.org/10.5194/acp-25-8213-2025, 2025
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This paper presents the chemical and iron isotopic composition of aerosols (> 1 µm) over the equatorial and tropical Pacific Ocean in previously undocumented areas. Analysis of our data suggests that a significant proportion of aerosol iron (∼ 13 %) is not only dissolved but also removed during atmospheric transport. Such removal had not previously been evidenced to our knowledge. This highlights the unique and strong constraints brought by iron isotopes on atmospheric process studies.
Fredrik Mattsson, Almuth Neuberger, Liine Heikkinen, Yvette Gramlich, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Paul Zieger, Ilona Riipinen, and Claudia Mohr
Atmos. Chem. Phys., 25, 7973–7989, https://doi.org/10.5194/acp-25-7973-2025, https://doi.org/10.5194/acp-25-7973-2025, 2025
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This study investigated aerosol–cloud interactions, focusing on organic nitrogen (ON) formation in the aqueous phase. Measurements were conducted in wintertime in the Po Valley, Italy, using aerosol mass spectrometry. The fog was enriched in more hygroscopic inorganic compounds and ON, containing, e.g., imidazoles. The formation of imidazole by aerosol–fog interactions could be confirmed for the first time in atmospheric observations. Findings highlight the role of fog in nitrogen aerosol formation.
Ren-Guo Zhu, Hua-Yun Xiao, Meiju Yin, Hao Xiao, Zhongkui Zhou, Yuanyuan Pan, Guo Wei, and Cheng Liu
Atmos. Chem. Phys., 25, 7699–7718, https://doi.org/10.5194/acp-25-7699-2025, https://doi.org/10.5194/acp-25-7699-2025, 2025
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The concentrations and δ15N isotopic values of CAAs (combined amino acids) in surface soil and plants from the Gobi Desert, as well as in PM2.5 samples from four cities in Northern China, were measured. CAAs transported by Gobi dust were rich in alanine, glycine and glutamic acid. Glycine and leucine in Gobi Desert sources exhibited δ15N depletion by more than 6 ‰ compared to their values in urban PM2.5. Substantial protein-N deposition can be transported by the Gobi Desert to northern China over brief periods.
Yu Huang, Xingru Li, Dan Dan Huang, Ruoyuan Lei, Binhuang Zhou, Yunjiang Zhang, and Xinlei Ge
Atmos. Chem. Phys., 25, 7619–7645, https://doi.org/10.5194/acp-25-7619-2025, https://doi.org/10.5194/acp-25-7619-2025, 2025
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This work comprises a comprehensive investigation into the chemical and optical properties of brown carbon (BrC) in PM2.5 samples collected in Nanjing, China. In particular, we used a machine learning approach to identify a list of key BrC species, which can be a good reference for future studies. Our findings extend understanding of BrC properties and are valuable to the assessment of BrC's impact on air quality and radiative forcing.
Qingxiao Meng, Yunjiang Zhang, Sheng Zhong, Jie Fang, Lili Tang, Yongcai Rao, Minfeng Zhou, Jian Qiu, Xiaofeng Xu, Jean-Eudes Petit, Olivier Favez, and Xinlei Ge
Atmos. Chem. Phys., 25, 7485–7498, https://doi.org/10.5194/acp-25-7485-2025, https://doi.org/10.5194/acp-25-7485-2025, 2025
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We developed a machine-learning-based method to reconstruct missing elemental carbon (EC) data in four Chinese cities from 2013 to 2023. Using machine learning, we filled data gaps and introduced a new approach to analyze EC trends. Our findings reveal a significant decline in EC due to stricter pollution controls, though this slowed after 2020. This study provides a versatile framework for addressing data gaps and supports strategies to reduce urban air pollution and its climate impacts.
Binyu Xiao, Fan Zhang, Zeyu Liu, Yan Zhang, Rui Li, Can Wu, Xinyi Wan, Yi Wang, Yubao Chen, Yong Han, Min Cui, Libo Zhang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 25, 7053–7069, https://doi.org/10.5194/acp-25-7053-2025, https://doi.org/10.5194/acp-25-7053-2025, 2025
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Intermediate-volatility/semi-volatile organic compounds in gas and particle phases from ship exhausts are enhanced due to the switch of fuels from low sulfur to ultra-low sulfur. The findings indicate that optimization is necessary for the forthcoming global implementation of an ultra-low-sulfur oil policy. Besides, we find that organic diagnostic markers of hopanes in conjunction with the ratio of octadecanoic to tetradecanoic could be considered potential tracers for heavy fuel oil exhausts.
Hongyu Zhang, Shenbo Wang, Zhangsen Dong, Xiao Li, and Ruiqin Zhang
Atmos. Chem. Phys., 25, 6943–6955, https://doi.org/10.5194/acp-25-6943-2025, https://doi.org/10.5194/acp-25-6943-2025, 2025
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Analyzing 12-year Zhengzhou data revealed post-2019 crustal material rebound caused by soil dust resuspension, elevating particle pH. Similar coarse particle increases are observed across cities of the North China Plain. Long-term particle acidity evolution in this region requires an integrated assessment of interactions among acidic precursors, ammonia, and crustal components.
Yanqin Ren, Zhenhai Wu, Fang Bi, Hong Li, Haijie Zhang, Junling Li, Rui Gao, Fangyun Long, Zhengyang Liu, Yuanyuan Ji, and Gehui Wang
Atmos. Chem. Phys., 25, 6975–6990, https://doi.org/10.5194/acp-25-6975-2025, https://doi.org/10.5194/acp-25-6975-2025, 2025
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The daily concentrations of Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs), and nitrated phenols (NPs) in PM2.5 were all increased during the heating season. Biomass burning was identified to be the primary source of these aromatic compounds, particularly for PAHs. Phenol and nitrobenzene are two main primary precursors for 4NP, with phenol showing lower reaction barriers. P-Cresol was identified as the primary precursor for the formation of 4-methyl-5-nitrocatechol.
Lise Le Berre, Brice Temime-Roussel, Grazia Maria Lanzafame, Barbara D'Anna, Nicolas Marchand, Stéphane Sauvage, Marvin Dufresne, Liselotte Tinel, Thierry Leonardis, Joel Ferreira de Brito, Alexandre Armengaud, Grégory Gille, Ludovic Lanzi, Romain Bourjot, and Henri Wortham
Atmos. Chem. Phys., 25, 6575–6605, https://doi.org/10.5194/acp-25-6575-2025, https://doi.org/10.5194/acp-25-6575-2025, 2025
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A summer campaign in a Mediterranean port examined pollution caused by ships. Two stations in the port measured pollution levels and captured over 350 ship plumes to study their chemical composition. Results showed that pollution levels, such as ultra-fine particles, were higher in the port than in the city and offer strong support to improve emission inventories. These findings may also serve as reference to assess the benefits of a sulfur Emission Control Area in the Mediterranean in 2025.
Jiayin Li, Tianyu Zhai, Xiaorui Chen, Haichao Wang, Shuyang Xie, Shiyi Chen, Chunmeng Li, Yuanjun Gong, Huabin Dong, and Keding Lu
Atmos. Chem. Phys., 25, 6395–6406, https://doi.org/10.5194/acp-25-6395-2025, https://doi.org/10.5194/acp-25-6395-2025, 2025
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We directly measured the dinitrogen pentoxide (N2O5) uptake coefficient using an aerosol flow tube, which critically impacts the NOx fate and particulate nitrate formation in a typical highland city, Kunming, in China. We found that the performance of current γ (N2O5) parameterizations showed deviations with the varying aerosol liquid water content (ALWC). Such differences would lead to biased estimation of particulate nitrate production potential. We give suggestions for future research directions.
Jishnu Pandamkulangara Kizhakkethil, Zongbo Shi, Anna Bogush, and Ivan Kourtchev
Atmos. Chem. Phys., 25, 5947–5958, https://doi.org/10.5194/acp-25-5947-2025, https://doi.org/10.5194/acp-25-5947-2025, 2025
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Pollution with per- and polyfluoroalkyl substances (PFAS) has received attention due to their environmental persistence and bioaccumulation, but their sources remain poorly understood. PM10 (particulate matter) collected above a scaled-down activated sludge tank treating domestic sewage in the UK was analysed for a range of short-, medium-, and long-chain PFAS. Eight PFAS were detected in the PM10. Our results suggest that wastewater treatment processes, i.e. activated sludge aeration, could aerosolise PFAS into airborne PM.
Haley M. Royer, Michael T. Sheridan, Hope E. Elliott, Edmund Blades, Nurun Nahar Lata, Zezhen Cheng, Swarup China, Zihua Zhu, Andrew P. Ault, and Cassandra J. Gaston
Atmos. Chem. Phys., 25, 5743–5759, https://doi.org/10.5194/acp-25-5743-2025, https://doi.org/10.5194/acp-25-5743-2025, 2025
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Saharan dust transported across the Atlantic to the Caribbean, South America, and North America is hypothesized to undergo chemical processing by acids that enhances cloud droplet formation and nutrient availability. In this study, chemical analysis performed on African dust deposited over Barbados shows that acid tracers are found mostly on sea salt and smoke particles, rather than dust, indicating that dust particles undergo minimal chemical processing.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
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Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Genevieve Rose Lorenzo, Luke D. Ziemba, Avelino F. Arellano, Mary C. Barth, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Richard Ferrare, Miguel Ricardo A. Hilario, Michael A. Shook, Simone Tilmes, Jian Wang, Qian Xiao, Jun Zhang, and Armin Sorooshian
Atmos. Chem. Phys., 25, 5469–5495, https://doi.org/10.5194/acp-25-5469-2025, https://doi.org/10.5194/acp-25-5469-2025, 2025
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Novel aerosol hygroscopicity analyses of CAMP2Ex (Cloud, Aerosol, and Monsoon Processes Philippines Experiment) field campaign data show low aerosol hygroscopicity values in Southeast Asia. Organic carbon from smoke decreases hygroscopicity to levels more like those in continental than in polluted marine regions. Hygroscopicity changes at cloud level demonstrate how surface particles impact clouds in the region, affecting model representation of aerosol and cloud interactions in similar polluted marine regions with high organic carbon emissions.
Yunfeng He, Xiang Ding, Quanfu He, Yuqing Zhang, Duohong Chen, Tao Zhang, Kong Yang, Junqi Wang, Qian Cheng, Hao Jiang, Zirui Wang, Ping Liu, Xinming Wang, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2025-2204, https://doi.org/10.5194/egusphere-2025-2204, 2025
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The long-term field measurements in the Pearl River Delta revealed a significant decline in PM2.5 main components. As air quality improved, secondary species became more dominant. In addition, the proportion of nitrate had doubled. The changes in chemical composition led to the reductions in aerosol acidity, liquid water content and light extinction coefficient. Our results help to improve understanding of the secondary species formation under decreasing anthropogenic emissions.
Shubin Li, Yujue Wang, Yiwen Zhang, Yizhe Yi, Yuchen Wang, Yuqi Guo, Chao Yu, Yue Jiang, Jinhui Shi, Chao Zhang, Jialei Zhu, Wei Hu, Jianzhen Yu, Xiaohong Yao, Huiwang Gao, and Min Hu
EGUsphere, https://doi.org/10.5194/egusphere-2025-2154, https://doi.org/10.5194/egusphere-2025-2154, 2025
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Organosulfates (OSs) are an unrecognized and potentially important component in marine organic aerosols. In this study, we quantified and characterized the OSs over East Asian marginal seas. The chemical nature and spatiotemporal distribution of OSs were modified by the joint influence of marine emissions and transported terrestrial pollutants. The results highlight the vital roles of OSs in shaping organic aerosol formation and sulfur cycle during summer in marine boundary layer.
Kouji Adachi, Atsushi Yoshida, Tatsuhiro Mori, Nobuhiro Moteki, Sho Ohata, Kazuyuki Kita, Yoshimi Kawai, and Makoto Koike
EGUsphere, https://doi.org/10.5194/egusphere-2025-2230, https://doi.org/10.5194/egusphere-2025-2230, 2025
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This study measured the compositions and mixing states of individual aerosol particles collected at different altitudes over the western North Pacific by simultaneous sampling from an aircraft and a research vessel. The results showed that they were strongly influenced by Siberian Forest biomass burning and mixed with sea spray, and identified various aerosol compositions at different altitudes, sizes, and aerosol sources, highlighting a wide range of individual particle compositions.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 25, 4885–4905, https://doi.org/10.5194/acp-25-4885-2025, https://doi.org/10.5194/acp-25-4885-2025, 2025
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In order to study aerosols in environments influenced by anthropogenic and biogenic emissions, we performed analyses of samples collected during the ACROSS (Atmospheric Chemistry Of the Suburban Forest) campaign in summer 2022 in the greater Paris area. After analysis of the chemical composition by means of total carbon determination and high-resolution mass spectrometry, this work highlights the influence of anthropogenic inputs on the chemical composition of both urban and forested areas.
Kimmo Teinilä, Sanna Saarikoski, Henna Lintusaari, Teemu Lepistö, Petteri Marjanen, Minna Aurela, Heidi Hellén, Toni Tykkä, Markus Lampimäki, Janne Lampilahti, Luis Barreira, Timo Mäkelä, Leena Kangas, Juha Hatakka, Sami Harni, Joel Kuula, Jarkko V. Niemi, Harri Portin, Jaakko Yli-Ojanperä, Ville Niemelä, Milja Jäppi, Katrianne Lehtipalo, Joonas Vanhanen, Liisa Pirjola, Hanna E. Manninen, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 25, 4907–4928, https://doi.org/10.5194/acp-25-4907-2025, https://doi.org/10.5194/acp-25-4907-2025, 2025
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Physical and chemical properties of particulate matter and concentrations of trace gases were measured in a street canyon in Helsinki, Finland, and an urban background site in January–February 2022 to investigate the effect of wintertime conditions on pollutants. State-of-the-art instruments and a mobile laboratory were used, and the measurement data were analysed further with modelling tools like positive matrix factorization and the Pollution Detection Algorithm.
Guilherme Martins Pereira, Leonardo Yoshiaki Kamigauti, Rubens Fabio Pereira, Djacinto Monteiro dos Santos, Thayná da Silva Santos, José Vinicius Martins, Célia Alves, Cátia Gonçalves, Ismael Casotti Rienda, Nora Kováts, Thiago Nogueira, Luciana Rizzo, Paulo Artaxo, Regina Maura de Miranda, Marcia Akemi Yamasoe, Edmilson Dias de Freitas, Pérola de Castro Vasconcellos, and Maria de Fatima Andrade
Atmos. Chem. Phys., 25, 4587–4616, https://doi.org/10.5194/acp-25-4587-2025, https://doi.org/10.5194/acp-25-4587-2025, 2025
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The chemical composition of fine particulate matter was studied in the megacity of São Paulo (Brazil) during a polluted period. Vehicular-related sources remain relevant; however, a high contribution of biomass burning was observed and correlated with sample ecotoxicity. Emerging biomass burning sources, such as forest fires and sugarcane-bagasse-based power plants, highlight the need for additional control measures alongside stricter rules concerning vehicular emissions.
Tao Qiu, Yanting Qiu, Yongyi Yuan, Rui Su, Xiangxinyue Meng, Jialiang Ma, Xiaofan Wang, Yu Gu, Zhijun Wu, Yang Ning, Xiuyi Hua, Dapeng Liang, and Deming Dong
EGUsphere, https://doi.org/10.5194/egusphere-2025-1808, https://doi.org/10.5194/egusphere-2025-1808, 2025
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Our research reveals that some species from biomass burning and coal combustion dominate the light absorption of organic aerosols during winter. Cold weather helps these species accumulate in aerosols by slowing their degradation and altering atmospheric chemical processes. This means colder regions might experience stronger and more persistent climate impacts. Our findings highlight the importance of local temperatures and pollution sources when tackling climate challenges.
Can Wu, Yubao Chen, Yuwei Sun, Huijun Zhang, Si Zhang, Cong Cao, Jianjun Li, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1668, https://doi.org/10.5194/egusphere-2025-1668, 2025
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Biogenic secondary organic aerosol (BSOA), as an important atmospheric component, is prevalent within the boundary layer and can influence air quality and human health. Our observations demonstrate that anthropogenic NOx and the enhanced aerosol water driven by sulfate inhibit BSOA formation in lifting air masses, leading to a moderate reduction in the SOA burden in the upper boundary layer.
Emmanuel Chevassus, Kirsten N. Fossum, Darius Ceburnis, Lu Lei, Chunshui Lin, Wei Xu, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 25, 4107–4129, https://doi.org/10.5194/acp-25-4107-2025, https://doi.org/10.5194/acp-25-4107-2025, 2025
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This study presents the first source apportionment of organic aerosol at Mace Head via high-resolution mass spectrometry. Introducing transfer entropy as a novel method reveals that aged organic aerosol originates from both open-ocean ozonolysis and local peat-burning oxidation. Methanesulfonic acid and organic sea spray both mirror phytoplankton activity, with the former closely tied to coccolithophore blooms and the latter linked to diatoms, chlorophytes, and cyanobacteria.
Paola Formenti, Chiara Giorio, Karine Desboeufs, Alexander Zherebker, Marco Gaetani, Clarissa Baldo, Gautier Landrot, Simona Montebello, Servanne Chevaillier, Sylvain Triquet, Guillaume Siour, Claudia Di Biagio, Francesco Battaglia, Jean-François Doussin, Anais Feron, Andreas Namwoonde, and Stuart John Piketh
EGUsphere, https://doi.org/10.5194/egusphere-2025-446, https://doi.org/10.5194/egusphere-2025-446, 2025
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The elemental composition and solubility of several metals, including iron, at a coastal site in Namibia in August–September 2017, indicate that natural and anthropogenic dust had different solubility depending on mineralogy but mostly to the processing by fluoride ions from marine emissions, pointing out to the complexity of atmospheric/oceanic interactions in this region of the world influenced by the Benguela current and significant aerosol load.
Jia-Yuan Wang, Meng-Xue Tang, Shan Lu, Ke-Jin Tang, Xing Peng, Ling-Yan He, and Xiao-Feng Huang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1034, https://doi.org/10.5194/egusphere-2025-1034, 2025
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Our study explores how secondary organic aerosols (SOA), a major component of air pollution, form in different particle sizes in a coastal city in China. We found that SOA in fine particles is mainly produced through aqueous chemical reactions, especially those involving iron. In contrast, coarse particles form SOA through reactions with ozone and gases from both fossil fuels and natural sources. These findings highlight the need for size-specific air pollution models.
Ashutosh K. Shukla, Sachchida N. Tripathi, Shamitaksha Talukdar, Vishnu Murari, Sreenivas Gaddamidi, Manousos-Ioannis Manousakas, Vipul Lalchandani, Kuldeep Dixit, Vinayak M. Ruge, Peeyush Khare, Mayank Kumar, Vikram Singh, Neeraj Rastogi, Suresh Tiwari, Atul K. Srivastava, Dilip Ganguly, Kaspar Rudolf Daellenbach, and André S. H. Prévôt
Atmos. Chem. Phys., 25, 3765–3784, https://doi.org/10.5194/acp-25-3765-2025, https://doi.org/10.5194/acp-25-3765-2025, 2025
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Our study delves into the elemental composition of aerosols at three sites across the Indo-Gangetic Plain (IGP), revealing distinct patterns during pollution episodes. We found significant increases in chlorine (Cl)-rich and solid fuel combustion (SFC) sources, indicating dynamic emission sources, agricultural burning impacts, and meteorological influences. Surges in Cl-rich particles during cold periods highlight their role in particle growth under high-relative-humidity conditions.
Kemei Li, Yanqing An, Jianzhong Xu, Miao Zhong, Wenhui Zhao, and Xiang Qin
EGUsphere, https://doi.org/10.5194/egusphere-2025-41, https://doi.org/10.5194/egusphere-2025-41, 2025
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This study presents a year-long PM2.5 study at Waliguan Baseline Observatory in the northeast of the Tibet Plateau to investigate the optical properties of water-soluble brown carbon and its source. Our findings highlight that organic matter, sulfate, and nitrate are the dominant contributors to PM2.5 mass concentrations. Notable seasonal variations in the light absorption capacity of water-soluble brown carbon, accompanied by a high degree of photochemical oxidation are also observed.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuwen Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 25, 3737–3752, https://doi.org/10.5194/acp-25-3737-2025, https://doi.org/10.5194/acp-25-3737-2025, 2025
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This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from diluted biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with background aerosol water and water-rich fogs and clouds.
Rongshuang Xu, Yu-Chi Lin, Siyu Bian, Feng Xie, and Yan-Lin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-683, https://doi.org/10.5194/egusphere-2025-683, 2025
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This work reported the hydroxymethanesulfonate (HMS) level in a continental city and, for the first time, in marine atmosphere. The enhancement by aerosol ionic strength (IS) on HMS formation was quantified which first rise with increasing IS, peaking at 4 mol kg–1 before declining. Given the IS range of marine (2–6) and urban aerosol (6–20 mol kg–1) and the clearly negative correlation between humidity and IS, the moderate IS level under humid condition may notably boost ambient HMS formation.
Jing Li, Jiaoshi Zhang, Xianda Gong, Steven Spielman, Chongai Kuang, Ashish Singh, Maria A. Zawadowicz, Lu Xu, and Jian Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-726, https://doi.org/10.5194/egusphere-2025-726, 2025
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Using measurements at a rural coastal site, we quantified aerosols in representative air masses and identified major source of organics in Houston area. Our results show cooking aerosol is likely overestimated by earlier studies. Additionally, diurnal variation of highly oxidized organics is mostly driven by air mass changes instead of photochemistry. This study highlights the impacts of emissions, atmospheric chemistry, and meteorology on aerosol properties in the coastal-rural environment.
Fan Mei, Qi Zhang, Damao Zhang, Jerome D. Fast, Gourihar Kulkarni, Mikhail S. Pekour, Christopher R. Niedek, Susanne Glienke, Israel Silber, Beat Schmid, Jason M. Tomlinson, Hardeep S. Mehta, Xena Mansoura, Zezhen Cheng, Gregory W. Vandergrift, Nurun Nahar Lata, Swarup China, and Zihua Zhu
Atmos. Chem. Phys., 25, 3425–3444, https://doi.org/10.5194/acp-25-3425-2025, https://doi.org/10.5194/acp-25-3425-2025, 2025
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This study highlights the unique capability of the ArcticShark, an uncrewed aerial system, in measuring vertically resolved atmospheric properties. Data from 32 research flights in 2023 reveal seasonal patterns and correlations with conventional measurements. The consistency and complementarity of in situ and remote sensing methods are highlighted. The study demonstrates the ArcticShark’s versatility in bridging data gaps and improving the understanding of vertical atmospheric structures.
Zheng Li, Gehui Wang, Binyu Xiao, Rongjie Li, Can Wu, Shaojun Lv, Feng Wu, Qingyan Fu, and Yusen Duan
EGUsphere, https://doi.org/10.5194/egusphere-2025-654, https://doi.org/10.5194/egusphere-2025-654, 2025
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Gas-to-aerosol partitioning of organics were investigated in Shanghai during 2023 dust storm period. We found the partitioning coefficients (Fp) of WSOCs in DS were comparable to those during a haze episode (HE), and aerosol liquid water content primarily drove Fp variation in HE, while pH was the dominant factor in DS. Moreover, an enhanced light absorption of Asian dust by brown carbon, mainly in coarse mode, formation was revealed.
Marco Paglione, Yufang Hao, Stefano Decesari, Mara Russo, Karam Mansour, Mauro Mazzola, Diego Fellin, Andrea Mazzanti, Emilio Tagliavini, Manousos Ioannis Manousakas, Evangelia Diapouli, Elena Barbaro, Matteo Feltracco, Kaspar Rudolf Daellenbach, and Matteo Rinaldi
EGUsphere, https://doi.org/10.5194/egusphere-2025-760, https://doi.org/10.5194/egusphere-2025-760, 2025
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A year-long set of PM1 samples from Ny-Ålesund, Svalbard, was analyzed by H-NMR and HR-TOF-AMS for the chemical characterization of the organic fraction. Positive Matrix Factorization allowed to identify five organic aerosol sources with specific seasonality. Winter-spring aerosol is dominated by Eurasian pollution, while summer is characterized by biogenic aerosols from marine sources; occasional summertime high OA loadings are associated with wildfire aerosols.
Ting Yang, Yu Xu, Yu-Chen Wang, Yi-Jia Ma, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2967–2978, https://doi.org/10.5194/acp-25-2967-2025, https://doi.org/10.5194/acp-25-2967-2025, 2025
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Previous measurement–model comparisons of atmospheric isoprene levels showed a significant unidentified source of isoprene in some northern Chinese cities during winter. Here, the first combination of large-scale observations and field combustion experiments provides novel insights into biomass burning emissions as a significant source of isoprene-derived organosulfates during winter in northern cities of China.
Agnesh Panta, Konrad Kandler, Kerstin Schepanski, Andres Alastuey, Pavla Dagsson Waldhauserova, Sylvain Dupont, Melanie Eknayan, Cristina González-Flórez, Adolfo González-Romero, Martina Klose, Mara Montag, Xavier Querol, Jesús Yus-Díez, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2025-494, https://doi.org/10.5194/egusphere-2025-494, 2025
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Iceland is among the most active dust source areas in the world. Dust properties are influenced by particle size, mineralogy, shape, and mixing state. This work characterizes freshly emitted individual aerosol particles of Icelandic dust using electron microscopy. Our study provides insights into critical particle-specific information will contribute to better constraining climate models that consider mineralogical variations in their representation of the dust cycle.
Xueqin Zheng, Junwen Liu, Nima Chuduo, Bian Ba, Pengfei Yu, Phu Drolgar, Fang Cao, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-164, https://doi.org/10.5194/egusphere-2025-164, 2025
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In this study, we present the first report on the annual variation of stable oxygen isotope anomalies (∆17O = δ17O - 0.52 × δ18O) in NO3- collected from the urban area of Lhasa , on the Tibetan Plateau, China. Using a Bayesian isotope mixture model, we found that the relative contribution of the NO3+VOC pathway to NO3- formation in spring in Lhasa was several times higher than in urban cities, highlighting the significant influence of VOC transported from outside the Tibetan Plateau.
Yi-Jia Ma, Yu Xu, Ting Yang, Lin Gui, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2763–2780, https://doi.org/10.5194/acp-25-2763-2025, https://doi.org/10.5194/acp-25-2763-2025, 2025
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The abundance, potential precursors, and main formation mechanisms of nitrogen-containing organic compounds (NOCs) in PM2.5 during winter were compared among cities with different energy consumption patterns. The aerosol NOC pollution during winter in China is closely associated with the intensity of precursor emissions and the aqueous-phase processes. Our results highlight the importance of emission reduction strategies in controlling aerosol NOCs pollution during winter in China.
Dane Blanchard, Mark Gordon, Duc Huy Dang, Paul Andrew Makar, and Julian Aherne
Atmos. Chem. Phys., 25, 2423–2442, https://doi.org/10.5194/acp-25-2423-2025, https://doi.org/10.5194/acp-25-2423-2025, 2025
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This study offers the first known evaluation of water-soluble brown carbon aerosols in the Athabasca oil sands region (AOSR), Canada. Fluorescence spectroscopy analysis of aerosol samples from five regional sites (collected during the summer of 2021) identified oil sands operations as a measurable brown carbon source. Industrial aerosol emissions were unlikely to impact regional radiative forcing. These findings show that fluorescence spectroscopy can be used to monitor brown carbon in the AOSR.
Kira Zeider, Kayla McCauley, Sanja Dmitrovic, Leong Wai Siu, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Simon Kirschler, John B. Nowak, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, Paquita Zuidema, and Armin Sorooshian
Atmos. Chem. Phys., 25, 2407–2422, https://doi.org/10.5194/acp-25-2407-2025, https://doi.org/10.5194/acp-25-2407-2025, 2025
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In situ aircraft data collected over the northwest Atlantic Ocean are utilized to compare aerosol conditions and turbulence between near-surface and below-cloud-base altitudes for different regimes of coupling strength between those two levels, along with how cloud microphysical properties vary across those regimes. Stronger coupling yields more homogenous aerosol structure vertically along with higher cloud drop concentrations and sea salt influence in clouds.
Junke Zhang, Xinyi Fu, Chunying Chen, Yunfei Su, Siyu Liu, Luyao Chen, Yubao Chen, Gehui Wang, and Andre S. H. Prevot
EGUsphere, https://doi.org/10.5194/egusphere-2025-92, https://doi.org/10.5194/egusphere-2025-92, 2025
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The 125 organic aerosol (OA) compounds in PM2.5 in winter in Chengdu were measured at the molecular level. OA was dominated by fatty acids, phthalate esters, and anhydrosugars, and were deeply influenced by anthropogenic sources. As pollution worsens: secondary inorganic species and secondary organic carbon (OC) dominated the increase in PM2.5; fatty acids and anhydrosugars dominated the increase in OA; and the contribution of secondary formation and biomass burning to OC increased markedly.
Amie Dobracki, Ernie R. Lewis, Arthur J. Sedlacek III, Tyler Tatro, Maria A. Zawadowicz, and Paquita Zuidema
Atmos. Chem. Phys., 25, 2333–2363, https://doi.org/10.5194/acp-25-2333-2025, https://doi.org/10.5194/acp-25-2333-2025, 2025
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Biomass-burning aerosol is commonly present in the marine boundary layer over the southeast Atlantic Ocean between June and October. Our research indicates that burning conditions, aerosol transport pathways, and prolonged oxidation processes (heterogeneous and aqueous phases) determine the chemical, microphysical, and optical properties of the boundary layer aerosol. Notably, we find that the aerosol optical properties can be estimated from the chemical properties alone.
Benjamin Heutte, Nora Bergner, Hélène Angot, Jakob B. Pernov, Lubna Dada, Jessica A. Mirrielees, Ivo Beck, Andrea Baccarini, Matthew Boyer, Jessie M. Creamean, Kaspar R. Daellenbach, Imad El Haddad, Markus M. Frey, Silvia Henning, Tiia Laurila, Vaios Moschos, Tuukka Petäjä, Kerri A. Pratt, Lauriane L. J. Quéléver, Matthew D. Shupe, Paul Zieger, Tuija Jokinen, and Julia Schmale
Atmos. Chem. Phys., 25, 2207–2241, https://doi.org/10.5194/acp-25-2207-2025, https://doi.org/10.5194/acp-25-2207-2025, 2025
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Limited aerosol measurements in the central Arctic hinder our understanding of aerosol–climate interactions in the region. Our year-long observations of aerosol physicochemical properties during the MOSAiC expedition reveal strong seasonal variations in aerosol chemical composition, where the short-term variability is heavily affected by storms in the Arctic. Local wind-generated particles are shown to be an important source of cloud seeds, especially in autumn.
Yifan Zhang, Rui Li, Zachary B. Bunnell, Yizhu Chen, Guanhong Zhu, Jinlong Ma, Guohua Zhang, Tim M. Conway, and Mingjin Tang
EGUsphere, https://doi.org/10.5194/egusphere-2025-474, https://doi.org/10.5194/egusphere-2025-474, 2025
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The sources of aerosol Fe, especially soluble aerosol Fe, remain to be constrained. The stable isotope ratio of Fe (δ56Fe) has emerged as a potential tracer for discriminating and quantifying sources of aerosol Fe. In this review, we examine the state of the field for using δ56Fe as an aerosol source tracer, and constraints on endmember signatures.
Feng Jiang, Harald Saathoff, Uzoamaka Ezenobi, Junwei Song, Hengheng Zhang, Linyu Gao, and Thomas Leisner
Atmos. Chem. Phys., 25, 1917–1930, https://doi.org/10.5194/acp-25-1917-2025, https://doi.org/10.5194/acp-25-1917-2025, 2025
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The chemical composition of brown carbon in the particle and gas phase was determined by mass spectrometry. BrC in the gas phase was mainly controlled by secondary formation and particle-to-gas partitioning. BrC in the particle phase was mainly from secondary formation. This work helps to get a better understanding of diurnal variations and the sources of brown carbon aerosol at a rural location in central Europe.
Kohei Sakata, Shotaro Takano, Atsushi Matsuki, Yasuo Takeichi, Hiroshi Tanimoto, Aya Sakaguchi, Minako Kurisu, and Yoshio Takahashi
EGUsphere, https://doi.org/10.5194/egusphere-2025-161, https://doi.org/10.5194/egusphere-2025-161, 2025
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Deposition of aerosol iron (Fe) into the ocean stimulates primary production and influences the global carbon cycle, although the factors governing the aerosol Fe solubility remain uncertain. Our observations in Japan revealed that both mineral dust and anthropogenic aerosols are significant sources of dissolved Fe, and that atmospheric chemical weathering enhances their solubility. This finding is expected to play a crucial role in estimating the supply of dissolved iron to the ocean.
Cited articles
Allan, J. D., Williams, P. I., Najera, J., Whitehead, J. D., Flynn, M. J.,
Taylor, J. W., Liu, D., Darbyshire, E., Carpenter, L. J., Chance, R.,
Andrews, S. J., Hackenberg, S. C., and McFiggans, G.: Iodine observed in new
particle formation events in the Arctic atmosphere during ACCACIA, Atmos.
Chem. Phys., 15, 5599–5609, https://doi.org/10.5194/acp-15-5599-2015, 2015.
Arquero, K. D., Gerber, R. B., and Finlayson-Pitts, B. J.: The role of oxalic
acid in new particle formation from methanesulfonic acid, methylamine, and
water, Environ. Sci. Technol., 51, 2124–2130, https://doi.org/10.1021/acs.est.6b05056,
2017.
Ayers, G. P. and Gras, J. L.: Seasonal relationship between cloud
condensation nuclei and aerosol methanesulphonate in marine air, Nature, 353,
834–835, https://doi.org/10.1038/353834a0, 1991.
Buzorius, G., McNaughton, C. S., Clarke, A. D., Covert, D. S., Blomquist,
B., Nielsen, K., and Brechtel, F. J.: Secondary aerosol formation in
continental outflow conditions during ACE-Asia, J. Geophys. Res., 109,
D24203, https://doi.org/10.1029/2004JD004749, 2004.
Bzdek, B. R., Horan, A. J., Pennington, M. R., DePalma, J. W., Zhao, J.,
Jen, C. N., Hanson, D. R., Smith, J. N., McMurry, P. H., and Johnston, M.
V.: Quantitative and time-resolved nanoparticle composition measurements
during new particle formation, Faraday Discuss., 165, 25–43, https://doi.org/10.1039/C3FD00039G, 2013.
Chang, R. Y. W., Sjostedt, S. J., Pierce, J. R., Papakyriakou, T. N.,
Scarratt, M. G., Michaud, S., Levasseur, M., Leaitch, W. R., and Abbatt, J.
P.: Relating atmospheric and oceanic DMS levels to particle nucleation
events in the Canadian Arctic, J. Geophys. Res., 116, D17,
https://doi.org/10.1029/2011JD015926, 2011.
Charlson, R. J., Lovelock, J. E, Andreae, M. O., and Warren, S. G.: Oceanic
phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature, 326,
655–661, https://doi.org/10.1038/326655a0, 1987.
Chen, H. and Finlayson-Pitts, B. J.: New Particle Formation from
Methanesulfonic Acid and Amines/Ammonia as a Function of Temperature,
Environ. Sci. Technol., 51, 243–252, https://doi.org/10.1021/acs.est.6b04173, 2017.
Chen, H., Ezell, M. J., Arquero, K. D., Varner, M. E., Dawson, M. L.,
Gerber, R. B., and Finlayson-Pitts, B. J.: New particle formation and growth
from methanesulfonic acid, trimethylamine and water, Phys. Chem. Chem.
Phys., 17, 13699–13709, https://doi.org/10.1039/c5cp00838g, 2015a.
Chen, H., Varner, M. E., Gerber, R. B., and Finlayson-Pitts, B. J.:
Reactions of methanesulfonic acid with amines and ammonia as a source of new
particles in air, J. Phys. Chem. B, 120, 1526–1536,
https://doi.org/10.1021/acs.jpcb.5b07433, 2015b.
Cho, Y. K., Kim, M. O., and Kim, B. C.: Sea Fog around the Korean Peninsula, J. Appl. Meteorol., 39, 2473–2479,
https://doi.org/10.1175/1520-0450(2000)039<2473:SFATKP>2.0.CO;2, 2000.
Covert, D. S., Kapustin, V. N., Bates, T. S., and Quinn, P. K.: Physical
properties of marine boundary layer aerosol particles of the mid-Pacific in
relation to sources and meteorological transport, J. Geophys. Res., 101, 6919–6930, https://doi.org/10.1029/95JD03068, 1996.
Clarke, A. D., Varner, J. L., Eisele, F., Mauldin, R. L., Tanner, D., and
Litchy, M.: Particle production in the remote marine atmosphere: Cloud
outflow and subsidence during ACE-1, J. Geophys. Res., 103, 16397–16409, https://doi.org/10.1029/97JD02987, 1998.
Dal Maso, M., Kulmala, M., Riipinen, I., Wagner, R., Hussein, T., Aalto, P.
P., and Lehtinen, K. E. J.: Formation and growth of fresh atmospheric
aerosols: Eight years of aerosol size distribution data from SMEAR II,
Hyytiala, Finland, Boreal Environ. Res., 10, 323–336, 2005.
Dusek, U., Frank, G. P., Hildebrandt, L., Curtius, J., Schneider, J.,
Walter, S., Chand, D., Drewnick, F., Hings, S., Jung, D., Borrmann, S., and
Andreae, M. O: Size matters more than chemistry for cloud-nucleating ability
of aerosol particles, Science, 312, 1375–1378, https://doi.org/10.1126/science.1125261,
2006.
Ehn, M., Vuollekoski, H., Petäjä, T., Kerminen, V.-M., Vana, M.,
Aalto, P., Leeuw, de G., Ceburnis, D., Dupuy, R., O'Dowd, C. D., and
Kulmala, M.: Growth rates during coastal and marine new particle formation
in western Ireland, J. Geophys. Res., 115, D18218, https://doi.org/10.1029/2010JD014292,
2010.
Ehn, M., Thornton, J. A., Kleist, E., Sipilä, M., Junninen, H.,
Pullinen, L., Springer, M., Rubach, F., Tillmann, R., Lee, B.,
LopezHilfiker, F., Andres, S., Acir, I.-H., Rissanen, M., Jokinen, T.,
Schobesberger, S., Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurtén,
T., Nielsen, L. B., Jørgensen, S., Kjaergaard, G. H., Canagaratna, M.,
Dal Maso, M., Berndt, T., Petäjä, T., Wahner, A., Kerminen, V.-M.,
Kulmala, M., Worsnop, D. R., Wildt, J., and Mentel, T. F.: A large source of
low-volatility secondary organic aerosol, Nature, 506, 476–4479,
https://doi.org/10.1038/nature13032, 2014.
Gao, H., Chen, J., Wang, B., Tan, S. C., Lee, C. M., Yao, X., Yan, H., and
Shi, J.: A study of air pollution of city clusters, Atmos. Environ., 45,
3069–3077, https://doi.org/10.1016/j.atmosenv.2011.03.018, 2011.
Ge, X., Wexler, A. S., and Clegg, S. L.: Atmospheric amines – part I. A
review, Atmos. Environ., 45, 524–546, https://doi.org/10.1016/j.atmosenv.2010.10.012,
2011.
Guo, T., Li, K., Zhu, Y., Gao, H., and Yao, X.: Concentration and size
distribution of particulate oxalate in marine and coastal
atmospheres–Implication for the increased importance of oxalate in
nanometer atmospheric particles, Atmos. Environ., 142, 19–31,
https://doi.org/10.1016/j.atmosenv.2016.07.026, 2016.
Hegg, D. A., Ferek, R. J., Hobbs, P. V., and Radke, L. F.: Dimethyl sulfide
and cloud condensation nucleus correlations in the northeast Pacific Ocean,
J. Geophys. Res., 96, 13189–13191, https://doi.org/10.1029/91JD01309, 1991.
Hirsikko, A., Bergman, T., Laakso, L., Dal Maso, M., Riipinen, I., Hõrrak,
U., and Kulmala, M.: Identification and classification of the formation of
intermediate ions measured in boreal forest, Atmos. Chem. Phys., 7, 201–210,
https://doi.org/10.5194/acp-7-201-2007, 2007.
Hong, Y., Liu, Y. R., Wen, H., Miao, S. K., Huang, T., Peng, X. Q., Jiang,
S., Feng, Y. J., and Huang, W.: Interaction of oxalic acid with methylamine
and its atmospheric implications, RSC Adv., 8, 7225–7234,
https://doi.org/10.1039/C7RA13670F, 2018.
Hoppel, W. A., Frick, G. M. and Larson, R. E.: Effect of nonprecipitating
clouds on the aerosol size distribution in the marine boundary layer,
Geophys. Res. Lett., 13, 125–128, https://doi.org/10.1029/GL013i002p00125, 1986.
Hoppel, W. A., Frick, G. M., and Fitzgerald, J. W.: Deducing droplet
concentration and supersaturation in marine boundary layer clouds from
surface aerosol measurements, J. Geophys. Res., 101, 26553–26565,
https://doi.org/10.1029/96JD02243, 1996.
Hu, Q., Yu, P., Zhu, Y., Li, K., Gao, H., and Yao, X.: Concentration, size
distribution, and formation of trimethylaminium and dimethylaminium ions in
atmospheric particles over marginal seas of China, J. Atmos. Sci., 72,
3487–3498, https://doi.org/10.1175/JAS-D-14-0393.1, 2015.
Huang, R. J., Seitz, K., Neary, T., O'Dowd, C. D., Platt, U., and Hoffmann,
T.: Observations of high concentrations of I2 and IO in coastal air
supporting iodine-oxide driven coastal new particle formation, Geophys. Res.
Lett., 37, L03803, https://doi.org/10.1029/2009GL041467, 2010.
Hussein, T., Junninen, H., Tunved, P., Kristensson, A., Dal Maso, M.,
Riipinen, I., Aalto, P. P., Hansson, H.-C., Swietlicki, E., and Kulmala, M.:
Time span and spatial scale of regional new particle formation events over
Finland and Southern Sweden, Atmos. Chem. Phys., 9, 4699–4716,
https://doi.org/10.5194/acp-9-4699-2009, 2009.
Jen, C. N., McMurry, P. H., and Hanson, D. R.: Stabilization of sulfuric acid
dimers by ammonia, methylamine, dimethylamine, and trimethylamine, J.
Geophys. Res.-Atmos., 119, 7502–7514, https://doi.org/10.1002/2014JD021592, 2014.
Jeong, C.-H., Evans, G. J., McGuire, M. L., Chang, R. Y.-W., Abbatt, J. P.
D., Zeromskiene, K., Mozurkewich, M., Li, S.-M., and Leaitch, W. R.: Particle
formation and growth at five rural and urban sites, Atmos. Chem. Phys., 10,
7979–7995, https://doi.org/10.5194/acp-10-7979-2010, 2010.
Jung, J., Furutani, H., Uematsu, M., Park, J.: Distributions of atmospheric
non-sea-salt sulfate and methanesulfonic acid over the Pacific Ocean between
48∘ N and 55∘ S during summer, Atmos. Environ., 99,
374–384, https://doi.org/10.1016/j.atmosenv.2014.10.009, 2014.
Kalkavouras, P., Bossioli, E., Bezantakos, S., Bougiatioti, A., Kalivitis,
N., Stavroulas, I., Kouvarakis, G., Protonotariou, A. P., Dandou, A., Biskos,
G., Mihalopoulos, N., Nenes, A., and Tombrou, M.: New particle formation in
the southern Aegean Sea during the Etesians: importance for CCN production
and cloud droplet number, Atmos. Chem. Phys., 17, 175–192,
https://doi.org/10.5194/acp-17-175-2017, 2017.
Kazil, J., Stier, P., Zhang, K., Quaas, J., Kinne, S., O'Donnell, D., Rast,
S., Esch, M., Ferrachat, S., Lohmann, U., and Feichter, J.: Aerosol
nucleation and its role for clouds and Earth's radiative forcing in the
aerosol-climate model ECHAM5-HAM, Atmos. Chem. Phys., 10, 10733–10752,
https://doi.org/10.5194/acp-10-10733-2010, 2010.
Kerminen, V.-M., Paramonov, M., Anttila, T., Riipinen, I., Fountoukis, C.,
Korhonen, H., Asmi, E., Laakso, L., Lihavainen, H., Swietlicki, E.,
Svenningsson, B., Asmi, A., Pandis, S. N., Kulmala, M., and Petäjä, T.:
Cloud condensation nuclei production associated with atmospheric nucleation:
a synthesis based on existing literature and new results, Atmos. Chem. Phys.,
12, 12037–12059, https://doi.org/10.5194/acp-12-12037-2012, 2012.
Kerminen, V. M., Chen, X., Vakkari, V., Petäjä, T., Kulmala, M., and
Bianchi, F.: Atmospheric new particle formation and growth: review of field
observations, Environ. Res. Lett., 13, 103003, https://doi.org/10.1088/1748-9326/aadf3c,
2018.
Khlystov, A., Stanier, C., and Pandis, S. N.: An algorithm for combining
electrical mobility and aerodynamic size distributions data when measuring
ambient aerosol special issue of aerosol science and technology on findings
from the fine particulate matter supersites program, Aerosol Sci. Technol.,
38, 229–238, https://doi.org/10.1080/02786820390229543, 2004.
Kulmala, M. and Kerminen, V. M.: On the formation and growth of atmospheric
nanoparticles, Atmos. Res., 90, 132–150, https://doi.org/10.1016/j.atmosres.2008.01.005,
2008.
Kulmala, M., Vehkamäki, H., Petäjä, T., Dal Maso, M., Lauri, A.,
Kerminen, V. M., Birmili, W., and McMurry, P. H.: Formation and growth rates
of ultrafine atmospheric particles: a review of observations, J. Aerosol
Sci., 35, 143–176, https://doi.org/10.1016/j.jaerosci.2003.10.003, 2004.
Kulmala, M., Petäjä, T., Nieminen, T., Sipilä, M., Manninen, H.
E., Lehtipalo, K., Dao Maso, M., Aalto, P. P., Junninen, H., Paasonen, P.,
Riipinen, I., Lehtinen, K. E. J., Laaksonen, A., and Kerminen, V-M.:
Measurement of the nucleation of atmospheric aerosol particles, Nat. Protoc.,
7, 1651–1667, https://doi.org/10.1038/nprot.2012.091, 2012.
Lana, A., Simó, R., Vallina, S. M., and Dachs, J.: Potential for a biogenic
influence on cloud microphysics over the ocean: a correlation study with
satellite-derived data, Atmos. Chem. Phys., 12, 7977–7993,
https://doi.org/10.5194/acp-12-7977-2012, 2012.
Lee, B. P., Li, Y. J., Flagan, R. C., Lo, C., and Chan, C. K.: Sizing
characterization of the fast mobility particle sizer (FMPS) against SMPS and
HR-ToF-AMS, Aerosol Sci. Technol., 47, 1030–1037,
https://doi.org/10.1080/02786826.2013.810809, 2013.
Liu, X. H., Zhu, Y. J., Zheng, M., Gao, H. W., and Yao, X. H.: Production and
growth of new particles during two cruise campaigns in the marginal seas of
China, Atmos. Chem. Phys., 14, 7941–7951,
https://doi.org/10.5194/acp-14-7941-2014, 2014.
Luo, L., Kao, S.-J., Bao, H., Xiao, H., Xiao, H., Yao, X., Gao, H., Li, J.,
and Lu, Y.: Sources of reactive nitrogen in marine aerosol over the Northwest
Pacific Ocean in spring, Atmos. Chem. Phys., 18, 6207–6222,
https://doi.org/10.5194/acp-18-6207-2018, 2018.
Man, H., Zhu, Y., Ji, F., Yao, X., Lau, N. T., Li, Y. J., Lee, B. P., and
Chan, C. K.: Comparison of daytime and nighttime new particle growth at the
HKUST Supersite in Hong Kong, Environ. Sci. Technol., 49, 7170–7178,
https://doi.org/10.1021/acs.est.5b02143, 2015.
Matsumoto, K., Tanaka, H., Nagao, I., and Ishizaka, Y.: Contribution of
particulate sulfate and organic carbon to cloud condensation nuclei in the
marine atmosphere, Geophys. Res. Lett., 24, 655–658, https://doi.org/10.1029/97GL00541,
1997.
McFiggans, G., Bale, C. S. E., Ball, S. M., Beames, J. M., Bloss, W. J.,
Carpenter, L. J., Dorsey, J., Dunk, R., Flynn, M. J., Furneaux, K. L.,
Gallagher, M. W., Heard, D. E., Hollingsworth, A. M., Hornsby, K., Ingham,
T., Jones, C. E., Jones, R. L., Kramer, L. J., Langridge, J. M., Leblanc, C.,
LeCrane, J.-P., Lee, J. D., Leigh, R. J., Longley, I., Mahajan, A. S., Monks,
P. S., Oetjen, H., Orr-Ewing, A. J., Plane, J. M. C., Potin, P., Shillings,
A. J. L., Thomas, F., von Glasow, R., Wada, R., Whalley, L. K., and
Whitehead, J. D.: Iodine-mediated coastal particle formation: an overview of
the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) Roscoff coastal
study, Atmos. Chem. Phys., 10, 2975–2999,
https://doi.org/10.5194/acp-10-2975-2010, 2010.
Meng, H., Zhu, Y., Evans, G. J., and Yao, X.: An approach to investigate new
particle formation in the vertical direction on the basis of high
time-resolution measurements at ground level and sea level, Atmos. Environ.,
102, 366–375, https://doi.org/10.1016/j.atmosenv.2014.12.016, 2015.
Mukai, H., Yokouchi, Y., and Suzuki, M.: Seasonal variation of
methanesulfonic acid in the atmosphere over the oki islands in the sea of
Japan, Atmos. Environ., 29, 1637–1648, https://doi.org/10.1016/1352-2310(95)00057-6,
1995.
Nieminen, T., Kerminen, V.-M., Petäjä, T., Aalto, P. P., Arshinov, M., Asmi,
E., Baltensperger, U., Beddows, D. C. S., Beukes, J. P., Collins, D., Ding,
A., Harrison, R. M., Henzing, B., Hooda, R., Hu, M., Hõrrak, U., Kivekäs,
N., Komsaare, K., Krejci, R., Kristensson, A., Laakso, L., Laaksonen, A.,
Leaitch, W. R., Lihavainen, H., Mihalopoulos, N., Németh, Z., Nie, W.,
O'Dowd, C., Salma, I., Sellegri, K., Svenningsson, B., Swietlicki, E.,
Tunved, P., Ulevicius, V., Vakkari, V., Vana, M., Wiedensohler, A., Wu, Z.,
Virtanen, A., and Kulmala, M.: Global analysis of continental boundary layer
new particle formation based on long-term measurements, Atmos. Chem. Phys.,
18, 14737–14756, https://doi.org/10.5194/acp-18-14737-2018, 2018.
O'Dowd, C. D. and de Leeuw, G.: Marine aerosol production: A review of the
current knowledge, Philos. T. Roy. Soc. A, 365, 1753–1774,
https://doi.org/10.1098/rsta.2007.2043, 2007.
O'Dowd, C. D., Jimenez, J. L., Bahreini, R., Flagan, R. C., Seinfeld, J. H.,
Hämeri, K., Pirjola, L., Kulmala, M., Jennings, S. G., and Hoffmann, T.:
Marine aerosol formation from biogenic iodine emissions, Nature, 417,
632–636, https://doi.org/10.1038/nature00775, 2002a.
O'Dowd, C. D., Hämeri, K., Mäkelä, J. M., Pirjola, L., Kulmala,
M., Jennings, S. G., Berresheim, H., Hansson, H-C., de Leeuw, G., Kunz, G.
J., Allen, A. G., Hewitt, C. N., Jackson, A., Viisanen, Y., and Hoffmann, T.:
A dedicated study of new particle formation and fate in the coastal
environment (PARFORCE): overview of objectives and achievements, J. Geophys.
Res., 107, D19, https://doi.org/10.1029/2001JD000555, 2002b.
Olenius, T., Halonen, R., Kurtén, T., Henschel, H.,
Kupiainen-Määttä, O., Ortega, I. K., Jen, C. N., Vehkamäki,
H., and Riipinen, I.: New particle formation from sulfuric acid and amines:
Comparison of monomethylamine, dimethylamine, and trimethylamine, J.
Geophys. Res.-Atmos., 122, 7103–7118, https://doi.org/10.1002/2017JD026501, 2017.
Paasonen, P., Nieminen, T., Asmi, E., Manninen, H. E., Petájá, T.,
Plass-Dúlmer, C., Flentje, H., Birmili, W., Wiedensohler, A., Hõrrak, U.,
Metzger, A., Hamed, A., Laaksonen, A., Facchini, M. C., Kerminen, V.-M., and
Kulmala, M.: On the roles of sulphuric acid and low-volatility organic
vapours in the initial steps of atmospheric new particle formation, Atmos.
Chem. Phys., 10, 11223–11242, https://doi.org/10.5194/acp-10-11223-2010,
2010.
Patoulias, D., Fountoukis, C., Riipinen, I., and Pandis, S. N.: The role of
organic condensation on ultrafine particle growth during nucleation events,
Atmos. Chem. Phys., 15, 6337–6350, https://doi.org/10.5194/acp-15-6337-2015,
2015.
Peng, J. F., Hu, M., Wang, Z. B., Huang, X. F., Kumar, P., Wu, Z. J., Guo,
S., Yue, D. L., Shang, D. J., Zheng, Z., and He, L. Y.: Submicron aerosols at
thirteen diversified sites in China: size distribution, new particle
formation and corresponding contribution to cloud condensation nuclei
production, Atmos. Chem. Phys., 14, 10249–10265,
https://doi.org/10.5194/acp-14-10249-2014, 2014.
Petters, M. D. and Kreidenweis, S. M.: A single parameter representation of
hygroscopic growth and cloud condensation nucleus activity, Atmos. Chem.
Phys., 7, 1961–1971, https://doi.org/10.5194/acp-7-1961-2007, 2007.
Pikridas, M., Riipinen, I., Hildebrandt, L., Kostenidou, E., Manninen, H.,
Mihalopoulos, N., Kalivitis, N., Burkhart, J. F., Stohl, A., Kulmala, M.,
and Pandis, S. N.: New particle formation at a remote site in the eastern
Mediterranean, J. Geophys. Res., 117, D12205, https://doi.org/10.1029/2012JD017570,
2012.
Pöschl, U., Rose, D., and Andreae, M. O.: Climatologies of cloud related
aerosols. Part 2: Particle hygroscopicity and cloud condensation nuclei
activity, MIT Press, Cambridge, 58–72,
https://doi.org/10.7551/mitpress/9780262012874.001.0001, 2009.
Quinn, P. K. and Bates, T. S.: The case against climate regulation via
oceanic phytoplankton sulphur emissions, Nature, 480, 51–56,
https://doi.org/10.1038/nature10580, 2011.
Riipinen, I., Yli-Juuti, T., Pierce, J. R., Petäjä, T., Worsnop, D.
R., Kulmala, M., and Donahue, N. M.: The contribution of organics to
atmospheric nanoparticle growth, Nat. Geosci., 5, 453–458,
https://doi.org/10.1038/ngeo1499, 2012.
Roach, W. T.: Back to basics: Fog. Part 3 – the formation and dissipation of
sea fog, Weather, 50, 80–84, 1995.
Rose, D., Nowak, A., Achtert, P., Wiedensohler, A., Hu, M., Shao, M., Zhang,
Y., Andreae, M. O., and Pöschl, U.: Cloud condensation nuclei in polluted air
and biomass burning smoke near the mega-city Guangzhou, China – Part 1:
Size-resolved measurements and implications for the modeling of aerosol
particle hygroscopicity and CCN activity, Atmos. Chem. Phys., 10, 3365–3383,
https://doi.org/10.5194/acp-10-3365-2010, 2010.
Sabaliauskas, K., Jeong, C-H., Yao, X., Jun, Y-S., Jadidian, P., and Evans,
G. J.: Five-Year Roadside Measurements of Ultrafine Particles in a Major
Canadian City, Atmos. Environ., 49, 245–256,
https://doi.org/10.1016/j.atmosenv.2011.11.052, 2012.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from
air pollution to climate change, John Wiley & Sons, New York, 2012.
Sellegri, K., Pey, J., Rose, C., Culot, A., DeWitt, H. L., Mas, S., Schwier,
A. N., Temime-Roussel, B., Charriere, B., Saiz-Lopez, A., Mahajan, A. S.,
Parin, D., Kukui, A., Sempere, R., Anna, B. D., and Marchand, N.: Evidence of
atmospheric nanoparticle formation from emissions of marine microorganisms,
Geophys. Res. Lett., 43, 6596–6603, https://doi.org/10.1002/2016GL069389, 2016.
Shen, X., Sun, J., Kivekäs, N., Kristensson, A., Zhang, X., Zhang, Y.,
Zhang, L., Fan, R., Qi, X., Ma, Q., and Zhou, H.: Spatial distribution and
occurrence probability of regional new particle formation events in eastern
China, Atmos. Chem. Phys., 18, 587–599,
https://doi.org/10.5194/acp-18-587-2018, 2018.
Sipilä, M., Sarnela, N., Jokinen, T., Henschel, H., Junninen, H.,
Kontkanen, J., Richters, S., Kangasluoma, J., Franchin, A., Peräkylä,
O., Rissanen, M., Ehn, M., Vehkamäki, H., Kurten, T., Berndt, T.,
Petäjä, T., Worsnop, D., Ceburnis, D., Kerminen, V.-M., Kulmala, M.,
and O'Dowd, C.: Molecular-scale evidence of aerosol particle formation via
sequential addition of HIO3, Nature, 537, 532–534,
https://doi.org/10.1038/nature19314, 2016.
Sorooshian, A., Padro, L. T., Nenes, A., Feingold, G., McComiskey, A.,
Hersey, S. P., Gates, H., Jonsson, H. H., Miller, S. D., Stephens, G. L.,
Flagan, R. C., and Seinfeld, J. H.: On the link between ocean biota
emissions, aerosol, and maritime clouds: Airborne, ground, and satellite
measurements off the coast of California, Global Biogeochem. Cy., 23, GB4007,
https://doi.org/10.1029/2009GB003464, 2009.
Tao, Y., Ye, X., Jiang, S., Yang, X., Chen, J., Xie, Y., and Wang, R.:
Effects of amines on particle growth observed in new particle formation
events, J. Geophys. Res., 121, 324–335, https://doi.org/10.1002/2015JD024245, 2016.
Teng, X., Hu, Q., Zhang, L., Qi, J., Shi, J., Xie, H., Gao, H. W., and Yao,
X.: Identification of major sources of atmospheric NH3 in an urban
environment in northern China during wintertime, Environ. Sci. Technol., 51,
6839–6848, https://doi.org/10.1021/acs.est.7b00328, 2017.
Ueda, S., Miura, K., Kawata, R., Furutani, H., Uematsu, M., Omori, Y., and
Tanimoto, H.: Number-size distribution of aerosol particles and new particle
formation events in tropical and subtropical Pacific Oceans, Atmos. Environ.,
142, 324–339, https://doi.org/10.1016/j.atmosenv.2016.07.055, 2016.
Vana, M., Ehn, M., Petäjä, T., Vuollekoski, H., Aalto, P., de Leeuw,
G., Ceburnisc, D., O'Dowd, C. D., and Kulmala, M.: Characteristic features of
air ions at Mace Head on the west coast of Ireland, Atmos. Res., 90,
278–286, https://doi.org/10.1016/j.atmosres.2008.04.007, 2008.
Wang, L., Xu, W., Khalizov, A. F., Zheng, J., Qiu, C., and Zhang, R.:
Laboratory investigation on the role of organics in atmospheric nanoparticle
growth, J. Phys. Chem. A, 115, 8940–8947, https://doi.org/10.1021/jp1121855, 2011a.
Wang, Z., Wu, Z., Yue, D., Shang, D., Guo, S., Sun, J., Ding, A., Wang, L.,
Jiang, J., Guo, H., Gao, J., Cheung, H. C., Morawska, L., Keywood, M., and
Hu, M.: New particle formation in China: Current knowledge and further
directions, Sci. Total Environ., 577, 258–266,
https://doi.org/10.1016/j.scitotenv.2016.10.177, 2017.
Wang, Z. B., Hu, M., Yue, D. L., Zheng, J., Zhang, R. Y., Wiedensohler, A.,
Wu, Z. J., Nieminen, T., and Boy, M.: Evaluation on the role of sulfuric acid
in the mechanisms of new particle formation for Beijing case, Atmos. Chem.
Phys., 11, 12663–12671, https://doi.org/10.5194/acp-11-12663-2011, 2011b.
Wang, Z. B., Hu, M., Sun, J. Y., Wu, Z. J., Yue, D. L., Shen, X. J., Zhang,
Y. M., Pei, X. Y., Cheng, Y. F., and Wiedensohler, A.: Characteristics of
regional new particle formation in urban and regional background environments
in the North China Plain, Atmos. Chem. Phys., 13, 12495–12506,
https://doi.org/10.5194/acp-13-12495-2013, 2013.
Wang, Z. B., Hu, M., Pei, X. Y., Zhang, R. Y., Paasonen, P., Zheng, J., Yue,
D. L., Wu, Z. J., Boy, M., and Wiedensohler, A.: Connection of organics to
atmospheric new particle formation and growth at an urban site of Beijing,
Atmos. Environ., 103, 7–17, https://doi.org/10.1016/j.atmosenv.2014.11.069, 2015.
Wen, J., Zhao, Y., and Wexler, A. S.: Marine particle nucleation:
observations at Bodega Bay, California, J. Geophys. Res., 111, D08207,
https://doi.org/10.1029/2005JD006210, 2006.
Wiedensohler, A., Covert, D. S., Swietlicki, E., Aalto, P., Heintzenberg, J.,
and Leck, C.: Occurrence of an ultrafine particle mode less than 20 nm in
diameter in the marine boundary layer during Arctic summer and autumn, Tellus
B, 48, 213–222, https://doi.org/10.1034/j.1600-0889.1996.t01-1-00006.x, 1996.
Yao, X. H., Chio, M. Y., Lau, N. T., Lau, A. P. S., Chan, C. K., and Fang,
M.: Growth and shrinkage of new particles in the atmosphere in Hong Kong,
Aerosol Sci. Tech., 44, 639–650, https://doi.org/10.1080/02786826.2010.482576, 2010.
Yu, F.: A secondary organic aerosol formation model considering successive
oxidation aging and kinetic condensation of organic compounds: global scale
implications, Atmos. Chem. Phys., 11, 1083–1099,
https://doi.org/10.5194/acp-11-1083-2011, 2011.
Yu, F. and Luo, G.: Oceanic dimethyl sulfide emission and new particle
formation around the coast of Antarctica: a modeling study of seasonal
variations and comparison with measurements, Atmosphere, 1, 34–50,
https://doi.org/10.3390/atmos1010034, 2010.
Yu, P., Hu, Q., Li, K., Zhu, Y., Liu, X., Gao, H., and Yao, X.:
Characteristics of dimethylaminium and trimethylaminium in atmospheric
particles ranging from supermicron to nanometer sizes over eutrophic marginal
seas of China and oligotrophic open oceans, Sci. Total Environ., 572,
813–824, https://doi.org/10.1016/j.scitotenv.2016.07.114, 2016.
Yue, D. L., Hu, M., Zhang, R. Y., Wang, Z. B., Zheng, J., Wu, Z. J.,
Wiedensohler, A., He, L. Y., Huang, X. F., and Zhu, T.: The roles of sulfuric
acid in new particle formation and growth in the mega-city of Beijing, Atmos.
Chem. Phys., 10, 4953–4960, https://doi.org/10.5194/acp-10-4953-2010, 2010.
Zhang, R., Khalizov, A., Wang, L., Hu, M., and Xu, W.: Nucleation and growth
of nanoparticles in the atmosphere, Chem. Rev., 112, 1957–2011,
https://doi.org/10.1021/cr2001756, 2012.
Zhang, S. H., Yang, G. P., Zhang, H. H., and Yang, J.: Spatial variation of
biogenic sulfur in the south Yellow Sea and the East China Sea during summer
and its contribution to atmospheric sulfate aerosol, Sci. Total Environ.,
488, 157–167, https://doi.org/10.1016/j.scitotenv.2014.04.074, 2014.
Zhu, Y., Sabaliauskas, K., Liu, X., Meng, H., Gao, H., Jeong, C. H., Evans,
G. J., and Yao, X.: Comparative analysis of new particle formation events in
less and severely polluted urban atmosphere, Atmos. Environ., 98, 655–664,
https://doi.org/10.1016/j.atmosenv.2014.09.043, 2014.
Zhu, Y., Yan, C., Zhang, R., Wang, Z., Zheng, M., Gao, H., Gao, Y., and Yao,
X.: Simultaneous measurements of new particle formation at 1 s time
resolution at a street site and a rooftop site, Atmos. Chem. Phys., 17,
9469–9484, https://doi.org/10.5194/acp-17-9469-2017, 2017.
Zimmerman, N., Jeong, C. H., Wang, J. M., Ramos, M., Wallace, J. S., and
Evans, G. J.: A source-independent empirical correction procedure for the
fast mobility and engine exhaust particle sizers, Atmos. Environ., 100,
178–184, https://doi.org/10.1016/j.atmosenv.2014.10.054, 2015.
Short summary
In this paper, we investigate new particle formation (NPF) events during seven cruises. NPF events were observed on 25 days and were most likely associated with the long-range transport of anthropogenic air pollutants. The relationship between the net generated amount of new particles and their apparent formation rate is established and explained in terms of the roles of different vapor precursors. The survival probability of new particles to CCN size is also discussed.
In this paper, we investigate new particle formation (NPF) events during seven cruises. NPF...
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