Articles | Volume 15, issue 20
https://doi.org/10.5194/acp-15-12079-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-12079-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
30 Oct 2015
Research article |
| 30 Oct 2015
Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records
J. Erbland
Université Grenoble Alpes, LGGE, 38000 Grenoble, France
CNRS, LGGE, 38000 Grenoble, France
J. Savarino
CORRESPONDING AUTHOR
Université Grenoble Alpes, LGGE, 38000 Grenoble, France
CNRS, LGGE, 38000 Grenoble, France
Météo-France – CNRS, CNRM – GAME UMR 3589, CEN, Grenoble, France
J. L. France
Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK
now at: School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
M. M. Frey
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
M. D. King
Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK
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Preprint archived
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We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Matthieu Vernay, Matthieu Lafaysse, Diego Monteiro, Pascal Hagenmuller, Rafife Nheili, Raphaëlle Samacoïts, Deborah Verfaillie, and Samuel Morin
Earth Syst. Sci. Data, 14, 1707–1733, https://doi.org/10.5194/essd-14-1707-2022, https://doi.org/10.5194/essd-14-1707-2022, 2022
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This paper introduces the latest version of the freely available S2M dataset which provides estimates of both meteorological and snow cover variables, as well as various avalanche hazard diagnostics at different elevations, slopes and aspects for the three main French high-elevation mountainous regions. A complete description of the system and the dataset is provided, as well as an overview of the possible uses of this dataset and an objective assessment of its limitations.
Amy Foulds, Grant Allen, Jacob T. Shaw, Prudence Bateson, Patrick A. Barker, Langwen Huang, Joseph R. Pitt, James D. Lee, Shona E. Wilde, Pamela Dominutti, Ruth M. Purvis, David Lowry, James L. France, Rebecca E. Fisher, Alina Fiehn, Magdalena Pühl, Stéphane J. B. Bauguitte, Stephen A. Conley, Mackenzie L. Smith, Tom Lachlan-Cope, Ignacio Pisso, and Stefan Schwietzke
Atmos. Chem. Phys., 22, 4303–4322, https://doi.org/10.5194/acp-22-4303-2022, https://doi.org/10.5194/acp-22-4303-2022, 2022
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We measured CH4 emissions from 21 offshore oil and gas facilities in the Norwegian Sea in 2019. Measurements compared well with operator-reported emissions but were greatly underestimated when compared with a 2016 global fossil fuel inventory. This study demonstrates the need for up-to-date and accurate inventories for use in research and policy and the important benefits of best-practice reporting methods by operators. Airborne measurements are an effective tool to validate such inventories.
Alice E. Ramsden, Anita L. Ganesan, Luke M. Western, Matthew Rigby, Alistair J. Manning, Amy Foulds, James L. France, Patrick Barker, Peter Levy, Daniel Say, Adam Wisher, Tim Arnold, Chris Rennick, Kieran M. Stanley, Dickon Young, and Simon O'Doherty
Atmos. Chem. Phys., 22, 3911–3929, https://doi.org/10.5194/acp-22-3911-2022, https://doi.org/10.5194/acp-22-3911-2022, 2022
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Quantifying methane emissions from different sources is a key focus of current research. We present a method for estimating sectoral methane emissions that uses ethane as a tracer for fossil fuel methane. By incorporating variable ethane : methane emission ratios into this model, we produce emissions estimates with improved uncertainty characterisation. This method will be particularly useful for studying methane emissions in areas with complex distributions of sources.
Lucas Berard-Chenu, Hugues François, Emmanuelle George, and Samuel Morin
The Cryosphere, 16, 863–881, https://doi.org/10.5194/tc-16-863-2022, https://doi.org/10.5194/tc-16-863-2022, 2022
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This study investigates the past snow reliability (1961–2019) of 16 ski resorts in the French Alps using state-of-the-art snowpack modelling. We used snowmaking investment figures to infer the evolution of snowmaking coverage at the individual ski resort level. Snowmaking improved snow reliability for the core of the winter season for the highest-elevation ski resorts. However it did not counterbalance the decreasing trend in snow cover reliability for lower-elevation ski resorts and in spring.
Zacharie Barrou Dumont, Simon Gascoin, Olivier Hagolle, Michaël Ablain, Rémi Jugier, Germain Salgues, Florence Marti, Aurore Dupuis, Marie Dumont, and Samuel Morin
The Cryosphere, 15, 4975–4980, https://doi.org/10.5194/tc-15-4975-2021, https://doi.org/10.5194/tc-15-4975-2021, 2021
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Since 2020, the Copernicus High Resolution Snow & Ice Monitoring Service has distributed snow cover maps at 20 m resolution over Europe in near-real time. These products are derived from the Sentinel-2 Earth observation mission, with a revisit time of 5 d or less (cloud-permitting). Here we show the good accuracy of the snow detection over a wide range of regions in Europe, except in dense forest regions where the snow cover is hidden by the trees.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Erwan Le Roux, Guillaume Evin, Nicolas Eckert, Juliette Blanchet, and Samuel Morin
The Cryosphere, 15, 4335–4356, https://doi.org/10.5194/tc-15-4335-2021, https://doi.org/10.5194/tc-15-4335-2021, 2021
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Extreme snowfall can cause major natural hazards (avalanches, winter storms) that can generate casualties and economic damage. In the French Alps, we show that between 1959 and 2019 extreme snowfall mainly decreased below 2000 m of elevation and increased above 2000 m. At 2500 m, we find a contrasting pattern: extreme snowfall decreased in the north, while it increased in the south. This pattern might be related to increasing trends in extreme snowfall observed near the Mediterranean Sea.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
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We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Pirmin Philipp Ebner, Franziska Koch, Valentina Premier, Carlo Marin, Florian Hanzer, Carlo Maria Carmagnola, Hugues François, Daniel Günther, Fabiano Monti, Olivier Hargoaa, Ulrich Strasser, Samuel Morin, and Michael Lehning
The Cryosphere, 15, 3949–3973, https://doi.org/10.5194/tc-15-3949-2021, https://doi.org/10.5194/tc-15-3949-2021, 2021
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A service to enable real-time optimization of grooming and snow-making at ski resorts was developed and evaluated using both GNSS-measured snow depth and spaceborne snow maps derived from Copernicus Sentinel-2. The correlation to the ground observation data was high. Potential sources for the overestimation of the snow depth by the simulations are mainly the impact of snow redistribution by skiers, compensation of uneven terrain, or spontaneous local adaptions of the snow management.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Xinyi Lu, Stephen J. Harris, Rebecca E. Fisher, James L. France, Euan G. Nisbet, David Lowry, Thomas Röckmann, Carina van der Veen, Malika Menoud, Stefan Schwietzke, and Bryce F. J. Kelly
Atmos. Chem. Phys., 21, 10527–10555, https://doi.org/10.5194/acp-21-10527-2021, https://doi.org/10.5194/acp-21-10527-2021, 2021
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Many coal seam gas (CSG) facilities in the Surat Basin, Australia, are adjacent to other sources of methane, including agricultural, urban, and natural seeps. This makes it challenging to estimate the amount of methane being emitted into the atmosphere from CSG facilities. This research demonstrates that measurements of the carbon and hydrogen stable isotopic composition of methane can distinguish between and apportion methane emissions from CSG facilities, cattle, and many other sources.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
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We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Michael Matiu, Alice Crespi, Giacomo Bertoldi, Carlo Maria Carmagnola, Christoph Marty, Samuel Morin, Wolfgang Schöner, Daniele Cat Berro, Gabriele Chiogna, Ludovica De Gregorio, Sven Kotlarski, Bruno Majone, Gernot Resch, Silvia Terzago, Mauro Valt, Walter Beozzo, Paola Cianfarra, Isabelle Gouttevin, Giorgia Marcolini, Claudia Notarnicola, Marcello Petitta, Simon C. Scherrer, Ulrich Strasser, Michael Winkler, Marc Zebisch, Andrea Cicogna, Roberto Cremonini, Andrea Debernardi, Mattia Faletto, Mauro Gaddo, Lorenzo Giovannini, Luca Mercalli, Jean-Michel Soubeyroux, Andrea Sušnik, Alberto Trenti, Stefano Urbani, and Viktor Weilguni
The Cryosphere, 15, 1343–1382, https://doi.org/10.5194/tc-15-1343-2021, https://doi.org/10.5194/tc-15-1343-2021, 2021
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The first Alpine-wide assessment of station snow depth has been enabled by a collaborative effort of the research community which involves more than 30 partners, 6 countries, and more than 2000 stations. It shows how snow in the European Alps matches the climatic zones and gives a robust estimate of observed changes: stronger decreases in the snow season at low elevations and in spring at all elevations, however, with considerable regional differences.
Shona E. Wilde, Pamela A. Dominutti, Grant Allen, Stephen J. Andrews, Prudence Bateson, Stephane J.-B. Bauguitte, Ralph R. Burton, Ioana Colfescu, James France, James R. Hopkins, Langwen Huang, Anna E. Jones, Tom Lachlan-Cope, James D. Lee, Alastair C. Lewis, Stephen D. Mobbs, Alexandra Weiss, Stuart Young, and Ruth M. Purvis
Atmos. Chem. Phys., 21, 3741–3762, https://doi.org/10.5194/acp-21-3741-2021, https://doi.org/10.5194/acp-21-3741-2021, 2021
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We use airborne measurements to evaluate the speciation of volatile organic compound (VOC) emissions from offshore oil and gas (O&G) installations in the North Sea. The composition of emissions varied across regions associated with either gas, condensate or oil extraction, demonstrating that VOC emissions are not uniform across the whole O&G sector. We compare our results to VOC source profiles in the UK emissions inventory, showing these emissions are not currently fully characterized.
Max Thomas, James France, Odile Crabeck, Benjamin Hall, Verena Hof, Dirk Notz, Tokoloho Rampai, Leif Riemenschneider, Oliver John Tooth, Mathilde Tranter, and Jan Kaiser
Atmos. Meas. Tech., 14, 1833–1849, https://doi.org/10.5194/amt-14-1833-2021, https://doi.org/10.5194/amt-14-1833-2021, 2021
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We describe the Roland von Glasow Air-Sea-Ice Chamber, a laboratory facility for studying ocean–sea-ice–atmosphere interactions. We characterise the technical capabilities of our facility to help future users plan and perform experiments. We also characterise the sea ice grown in the facility, showing that the extinction of photosynthetically active radiation, the bulk salinity, and the growth rate of our artificial sea ice are within the range of natural values.
James L. France, Prudence Bateson, Pamela Dominutti, Grant Allen, Stephen Andrews, Stephane Bauguitte, Max Coleman, Tom Lachlan-Cope, Rebecca E. Fisher, Langwen Huang, Anna E. Jones, James Lee, David Lowry, Joseph Pitt, Ruth Purvis, John Pyle, Jacob Shaw, Nicola Warwick, Alexandra Weiss, Shona Wilde, Jonathan Witherstone, and Stuart Young
Atmos. Meas. Tech., 14, 71–88, https://doi.org/10.5194/amt-14-71-2021, https://doi.org/10.5194/amt-14-71-2021, 2021
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Measuring emission rates of methane from installations is tricky, and it is even more so when those installations are located offshore. Here, we show the aircraft set-up and demonstrate an effective methodology for surveying emissions from UK and Dutch offshore oil and gas installations. We present example data collected from two campaigns to demonstrate the challenges and solutions encountered during these surveys.
Martin Ménégoz, Evgenia Valla, Nicolas C. Jourdain, Juliette Blanchet, Julien Beaumet, Bruno Wilhelm, Hubert Gallée, Xavier Fettweis, Samuel Morin, and Sandrine Anquetin
Hydrol. Earth Syst. Sci., 24, 5355–5377, https://doi.org/10.5194/hess-24-5355-2020, https://doi.org/10.5194/hess-24-5355-2020, 2020
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The study investigates precipitation changes in the Alps, using observations and a 7 km resolution climate simulation over 1900–2010. An increase in mean precipitation is found in winter over the Alps, whereas a drying occurred in summer in the surrounding plains. A general increase in the daily annual maximum of precipitation is evidenced (20 to 40 % per century), suggesting an increase in extreme events that is significant only when considering long time series, typically 50 to 80 years.
Erwan Le Roux, Guillaume Evin, Nicolas Eckert, Juliette Blanchet, and Samuel Morin
Nat. Hazards Earth Syst. Sci., 20, 2961–2977, https://doi.org/10.5194/nhess-20-2961-2020, https://doi.org/10.5194/nhess-20-2961-2020, 2020
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To minimize the risk of structure collapse due to extreme snow loads, structure standards rely on 50-year return levels of ground snow load (GSL), i.e. levels exceeded once every 50 years on average, that do not account for climate change. We study GSL data in the French Alps massifs from 1959 and 2019 and find that these 50-year return levels are decreasing with time between 900 and 4800 m of altitude, but they still exceed return levels of structure standards for half of the massifs at 1800 m.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
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In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
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The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
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We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Pierre Spandre, Hugues François, Deborah Verfaillie, Marc Pons, Matthieu Vernay, Matthieu Lafaysse, Emmanuelle George, and Samuel Morin
The Cryosphere, 13, 1325–1347, https://doi.org/10.5194/tc-13-1325-2019, https://doi.org/10.5194/tc-13-1325-2019, 2019
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This study investigates the snow reliability of 175 ski resorts in the Pyrenees (France, Spain and Andorra) and the French Alps under past and future conditions (1950–2100) using state-of-the-art climate projections and snowpack modelling accounting for snow management, i.e. grooming and snowmaking. The snow reliability of ski resorts shows strong elevation and regional differences, and our study quantifies changes in snow reliability induced by snowmaking under various climate scenarios.
Biagio Di Mauro, Roberto Garzonio, Micol Rossini, Gianluca Filippa, Paolo Pogliotti, Marta Galvagno, Umberto Morra di Cella, Mirco Migliavacca, Giovanni Baccolo, Massimiliano Clemenza, Barbara Delmonte, Valter Maggi, Marie Dumont, François Tuzet, Matthieu Lafaysse, Samuel Morin, Edoardo Cremonese, and Roberto Colombo
The Cryosphere, 13, 1147–1165, https://doi.org/10.5194/tc-13-1147-2019, https://doi.org/10.5194/tc-13-1147-2019, 2019
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The snow albedo reduction due to dust from arid regions alters the melting dynamics of the snowpack, resulting in earlier snowmelt. We estimate up to 38 days of anticipated snow disappearance for a season that was characterized by a strong dust deposition event. This process has a series of further impacts. For example, earlier snowmelts may alter the hydrological cycle in the Alps, induce higher sensitivity to late summer drought, and finally impact vegetation and animal phenology.
Yves Lejeune, Marie Dumont, Jean-Michel Panel, Matthieu Lafaysse, Philippe Lapalus, Erwan Le Gac, Bernard Lesaffre, and Samuel Morin
Earth Syst. Sci. Data, 11, 71–88, https://doi.org/10.5194/essd-11-71-2019, https://doi.org/10.5194/essd-11-71-2019, 2019
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This paper introduces and provides access to a daily (1960–2017) and an hourly (1993–2017) dataset of snow and meteorological data measured at the Col de Porte site, 1325 m a.s.l, Charteuse, France. The daily dataset can be used to quantify the effect of climate change at this site, with a reduction of the mean snow depth of 39 cm from 1960–1990 to 1990–2017. The daily and hourly datasets are useful and appropriate for driving and evaluating a snowpack model over such a long period.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
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Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
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Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Frank Techel, Christoph Mitterer, Elisabetta Ceaglio, Cécile Coléou, Samuel Morin, Francesca Rastelli, and Ross S. Purves
Nat. Hazards Earth Syst. Sci., 18, 2697–2716, https://doi.org/10.5194/nhess-18-2697-2018, https://doi.org/10.5194/nhess-18-2697-2018, 2018
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In 1993, the European Avalanche Warning Services agreed upon a common danger scale to describe the regional avalanche hazard: the European Avalanche Danger Scale. Using published avalanche forecasts, we explored whether forecasters use the scale consistently. We noted differences in the use of the danger levels, some of which could be linked to the size of the regions a regional danger level is issued for. We recommend further harmonizing the avalanche forecast products in the Alps.
Alexandra Touzeau, Amaëlle Landais, Samuel Morin, Laurent Arnaud, and Ghislain Picard
Geosci. Model Dev., 11, 2393–2418, https://doi.org/10.5194/gmd-11-2393-2018, https://doi.org/10.5194/gmd-11-2393-2018, 2018
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We introduced a new module of water vapor diffusion into the snowpack model Crocus. Vapor transport locally modifies the density of snow layers, possibly influencing compaction. It also affects the original isotopic signature of snow layers. We also introduced water isotopes (𝛿18O) in the model. Over 10 years, the modeled attenuation of isotopic variations due to vapor diffusion is 7–18 % lower than the observations. Thus, other processes are required to explain the total attenuation.
Marion Réveillet, Delphine Six, Christian Vincent, Antoine Rabatel, Marie Dumont, Matthieu Lafaysse, Samuel Morin, Vincent Vionnet, and Maxime Litt
The Cryosphere, 12, 1367–1386, https://doi.org/10.5194/tc-12-1367-2018, https://doi.org/10.5194/tc-12-1367-2018, 2018
Deborah Verfaillie, Matthieu Lafaysse, Michel Déqué, Nicolas Eckert, Yves Lejeune, and Samuel Morin
The Cryosphere, 12, 1249–1271, https://doi.org/10.5194/tc-12-1249-2018, https://doi.org/10.5194/tc-12-1249-2018, 2018
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This article addresses local changes of seasonal snow and its meteorological drivers, at 1500 m altitude in the Chartreuse mountain range in the Northern French Alps, for the period 1960–2100. We use an ensemble of adjusted RCM outputs consistent with IPCC AR5 GCM outputs (RCPs 2.6, 4.5 and 8.5) and the snowpack model Crocus. Beyond scenario-based approach, global temperature levels on the order of 1.5 °C and 2 °C above preindustrial levels correspond to 25 and 32% reduction of mean snow depth.
James D. Lee, Stephen D. Mobbs, Axel Wellpott, Grant Allen, Stephane J.-B. Bauguitte, Ralph R. Burton, Richard Camilli, Hugh Coe, Rebecca E. Fisher, James L. France, Martin Gallagher, James R. Hopkins, Mathias Lanoiselle, Alastair C. Lewis, David Lowry, Euan G. Nisbet, Ruth M. Purvis, Sebastian O'Shea, John A. Pyle, and Thomas B. Ryerson
Atmos. Meas. Tech., 11, 1725–1739, https://doi.org/10.5194/amt-11-1725-2018, https://doi.org/10.5194/amt-11-1725-2018, 2018
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This work describes measurements, made from an aircraft platform, of the emission of methane and other organic gases from an uncontrolled leak from an oil platform in the North Sea (Total Elgin). The measurements made helped the platform operators to devise a strategy for repairing the leak and serve as a methodology for assessing future similar incidents.
Martin Beniston, Daniel Farinotti, Markus Stoffel, Liss M. Andreassen, Erika Coppola, Nicolas Eckert, Adriano Fantini, Florie Giacona, Christian Hauck, Matthias Huss, Hendrik Huwald, Michael Lehning, Juan-Ignacio López-Moreno, Jan Magnusson, Christoph Marty, Enrique Morán-Tejéda, Samuel Morin, Mohamed Naaim, Antonello Provenzale, Antoine Rabatel, Delphine Six, Johann Stötter, Ulrich Strasser, Silvia Terzago, and Christian Vincent
The Cryosphere, 12, 759–794, https://doi.org/10.5194/tc-12-759-2018, https://doi.org/10.5194/tc-12-759-2018, 2018
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This paper makes a rather exhaustive overview of current knowledge of past, current, and future aspects of cryospheric issues in continental Europe and makes a number of reflections of areas of uncertainty requiring more attention in both scientific and policy terms. The review paper is completed by a bibliography containing 350 recent references that will certainly be of value to scholars engaged in the fields of glacier, snow, and permafrost research.
Hoi Ga Chan, Markus M. Frey, and Martin D. King
Atmos. Chem. Phys., 18, 1507–1534, https://doi.org/10.5194/acp-18-1507-2018, https://doi.org/10.5194/acp-18-1507-2018, 2018
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Emissions of reactive nitrogen from snowpacks influence remote air quality. Two physical air–snow models for nitrate were developed. One assumes that below a threshold temperature the air–snow grain interface is pure ice and above it a disordered interface emerges. The other assumes an air–ice interface below melting and that any liquid present is concentrated in micropockets. Only the latter matches observations at two Antarctic lcoations covering a wide range of environmental conditions.
Deborah Verfaillie, Michel Déqué, Samuel Morin, and Matthieu Lafaysse
Geosci. Model Dev., 10, 4257–4283, https://doi.org/10.5194/gmd-10-4257-2017, https://doi.org/10.5194/gmd-10-4257-2017, 2017
Francois Tuzet, Marie Dumont, Matthieu Lafaysse, Ghislain Picard, Laurent Arnaud, Didier Voisin, Yves Lejeune, Luc Charrois, Pierre Nabat, and Samuel Morin
The Cryosphere, 11, 2633–2653, https://doi.org/10.5194/tc-11-2633-2017, https://doi.org/10.5194/tc-11-2633-2017, 2017
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Light-absorbing impurities deposited on snow, such as soot or dust, strongly modify its evolution. We implemented impurity deposition and evolution in a detailed snowpack model, thereby expanding the reach of such models into addressing the subtle interplays between snow physics and impurities' optical properties. Model results were evaluated based on innovative field observations at an Alpine site. This allows future investigations in the fields of climate, hydrology and avalanche prediction.
Jesús Revuelto, Grégoire Lecourt, Matthieu Lafaysse, Isabella Zin, Luc Charrois, Vincent Vionnet, Marie Dumont, Antoine Rabatel, Delphine Six, Thomas Condom, Samuel Morin, Alessandra Viani, and Pascal Sirguey
The Cryosphere Discuss., https://doi.org/10.5194/tc-2017-184, https://doi.org/10.5194/tc-2017-184, 2017
Revised manuscript not accepted
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We evaluated distributed and semi-distributed modeling approaches to simulating the spatial and temporal evolution of snow and ice over an extended mountain catchment, using the Crocus snowpack model. The distributed approach simulated the snowpack dynamics on a 250-m grid, enabling inclusion of terrain shadowing effects. The semi-distributed approach simulated the snowpack dynamics for discrete topographic classes characterized by elevation range, aspect, and slope.
Christopher J. L. D'Amboise, Karsten Müller, Laurent Oxarango, Samuel Morin, and Thomas V. Schuler
Geosci. Model Dev., 10, 3547–3566, https://doi.org/10.5194/gmd-10-3547-2017, https://doi.org/10.5194/gmd-10-3547-2017, 2017
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We present a new water percolation routine added to the Crocus model. The new routine is physically based, describing motion of water through a layered snowpack considering capillary-driven and gravity flow. We tested the routine on two data sets. Wet-snow layers were able to reach higher saturations than the empirical routine. Meaningful applicability is limited until new and better parameterizations of water retention are developed, and feedbacks are adjusted to handle higher saturations.
Mathieu Barrere, Florent Domine, Bertrand Decharme, Samuel Morin, Vincent Vionnet, and Matthieu Lafaysse
Geosci. Model Dev., 10, 3461–3479, https://doi.org/10.5194/gmd-10-3461-2017, https://doi.org/10.5194/gmd-10-3461-2017, 2017
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Global warming projections still suffer from a limited representation of the permafrost–carbon feedback. This study assesses the capacity of snow-soil coupled models to simulate the permafrost thermal regime at Bylot Island, a high Arctic site. Significant flaws are found in the description of Arctic snow properties, resulting in erroneous heat transfers between the soil and the snow in simulations. Improved snow schemes are needed to accurately predict the future of permafrost.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Matthieu Lafaysse, Bertrand Cluzet, Marie Dumont, Yves Lejeune, Vincent Vionnet, and Samuel Morin
The Cryosphere, 11, 1173–1198, https://doi.org/10.5194/tc-11-1173-2017, https://doi.org/10.5194/tc-11-1173-2017, 2017
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Physically based multilayer snowpack models suffer from various modelling errors. To represent these errors, we built the new multiphysical ensemble system ESCROC by implementing new representations of different physical processes in a coupled multilayer ground/snowpack model. This system is a promising tool to integrate snow modelling errors in ensemble forecasting and ensemble assimilation systems in support of avalanche hazard forecasting and other snowpack modelling applications.
Marie Dumont, Laurent Arnaud, Ghislain Picard, Quentin Libois, Yves Lejeune, Pierre Nabat, Didier Voisin, and Samuel Morin
The Cryosphere, 11, 1091–1110, https://doi.org/10.5194/tc-11-1091-2017, https://doi.org/10.5194/tc-11-1091-2017, 2017
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Snow spectral albedo in the visible/near-infrared range has been continuously measured during a winter season at Col de Porte alpine site (French Alps; 45.30° N, 5.77°E; 1325 m a.s.l.). This study highlights that the variations of spectral albedo can be successfully explained by variations of the following snow surface variables: snow-specific surface area, effective light-absorbing impurities content, presence of liquid water and slope.
Pierre Spandre, Hugues François, Emmanuel Thibert, Samuel Morin, and Emmanuelle George-Marcelpoil
The Cryosphere, 11, 891–909, https://doi.org/10.5194/tc-11-891-2017, https://doi.org/10.5194/tc-11-891-2017, 2017
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The production of machine-made snow is generalized in ski resorts and represents the most common adaptation method to mitigate effects of climate variability and its projected changes. However, the actual snow mass that can be recovered from a given water mass used for snowmaking remains poorly known. All results were consistent with 60 % (±10 %) of the water mass found as snow within the edge of the ski slope, with most of the lost fraction of water being due to site-dependent characteristics.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
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We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Florent Domine, Mathieu Barrere, and Samuel Morin
Biogeosciences, 13, 6471–6486, https://doi.org/10.5194/bg-13-6471-2016, https://doi.org/10.5194/bg-13-6471-2016, 2016
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Warming-induced shrub growth in the Arctic traps snow and modifies snow properties, hence the permafrost thermal regime. In the Canadian high Arctic, we measured snow physical properties in the presence and absence of willow shrubs (Salix richardsonii). Shrubs dramatically reduce snow density and thermal conductivity, seriously limiting soil winter cooling. Simulations taking into account only winter changes show that shrub growth leads to a ground winter warming of up to 13 °C.
Nicola J. Warwick, Michelle L. Cain, Rebecca Fisher, James L. France, David Lowry, Sylvia E. Michel, Euan G. Nisbet, Bruce H. Vaughn, James W. C. White, and John A. Pyle
Atmos. Chem. Phys., 16, 14891–14908, https://doi.org/10.5194/acp-16-14891-2016, https://doi.org/10.5194/acp-16-14891-2016, 2016
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Methane is an important greenhouse gas. Methane emissions from Arctic wetlands are poorly quantified and may increase in a warming climate. Using a global atmospheric model and atmospheric observations of methane and its isotopologues, we find that isotopologue data are useful in constraining Arctic wetland emissions. Our results suggest that the seasonal cycle of these emissions may be incorrectly simulated in land process models, with implications for our understanding of future emissions.
Maria Zatko, Joseph Erbland, Joel Savarino, Lei Geng, Lauren Easley, Andrew Schauer, Timothy Bates, Patricia K. Quinn, Bonnie Light, David Morison, Hans D. Osthoff, Seth Lyman, William Neff, Bin Yuan, and Becky Alexander
Atmos. Chem. Phys., 16, 13837–13851, https://doi.org/10.5194/acp-16-13837-2016, https://doi.org/10.5194/acp-16-13837-2016, 2016
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This manuscript presents chemical and optical observations collected in the air and snow during UBWOS2014 in eastern Utah. These observations are used to calculate fluxes of reactive nitrogen associated with snow nitrate photolysis. Snow-sourced reactive nitrogen fluxes are compared to reactive nitrogen emission inventories to find that snow-sourced reactive nitrogen is a minor contributor to the reactive nitrogen budget, and thus wintertime ground-level ozone formation, in the Uintah Basin.
Giulia Zazzeri, Dave Lowry, Rebecca E. Fisher, James L. France, Mathias Lanoisellé, Bryce F. J. Kelly, Jaroslaw M. Necki, Charlotte P. Iverach, Elisa Ginty, Miroslaw Zimnoch, Alina Jasek, and Euan G. Nisbet
Atmos. Chem. Phys., 16, 13669–13680, https://doi.org/10.5194/acp-16-13669-2016, https://doi.org/10.5194/acp-16-13669-2016, 2016
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Methane emissions estimates from the coal sector are highly uncertain. Precise δ13C isotopic signatures of methane sources can be used in atmospheric models for a methane budget assessment. Emissions from both underground and opencast coal mines in the UK, Australia and Poland were sampled and isotopically characterised using high-precision measurements of δ13C values. Representative isotopic signatures were provided, taking into account specific ranks of coal and mine type.
Josué Bock, Joël Savarino, and Ghislain Picard
Atmos. Chem. Phys., 16, 12531–12550, https://doi.org/10.5194/acp-16-12531-2016, https://doi.org/10.5194/acp-16-12531-2016, 2016
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We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
Deborah Verfaillie, Michel Déqué, Samuel Morin, and Matthieu Lafaysse
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2016-168, https://doi.org/10.5194/gmd-2016-168, 2016
Revised manuscript not accepted
Ghislain Picard, Laurent Arnaud, Jean-Michel Panel, and Samuel Morin
The Cryosphere, 10, 1495–1511, https://doi.org/10.5194/tc-10-1495-2016, https://doi.org/10.5194/tc-10-1495-2016, 2016
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A cost-effective automatic laser scan has been built to measure snow depth spatio-temporal variations. Deployed in the Alps and in Dome C (Antarctica), two devices acquired daily scans covering a surface area of 100–150 m2. The precision and long-term stability of the measurements are about 1 cm and the accuracy is better than 5 cm. These high performances are particularly suited at Dome C, where it was possible to reveal that most of the accumulation in the year 2015 stems from a single event.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Luc Charrois, Emmanuel Cosme, Marie Dumont, Matthieu Lafaysse, Samuel Morin, Quentin Libois, and Ghislain Picard
The Cryosphere, 10, 1021–1038, https://doi.org/10.5194/tc-10-1021-2016, https://doi.org/10.5194/tc-10-1021-2016, 2016
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This study investigates the assimilation of optical reflectances, snowdepth data and both combined into a multilayer snowpack model. Data assimilation is performed with an ensemble-based method, the Sequential Importance Resampling Particle filter. Experiments assimilating only synthetic data are conducted at one point in the French Alps, the Col du Lautaret, over five hydrological years. Results of the assimilation experiments show improvements of the snowpack bulk variables estimates.
Bertrand Decharme, Eric Brun, Aaron Boone, Christine Delire, Patrick Le Moigne, and Samuel Morin
The Cryosphere, 10, 853–877, https://doi.org/10.5194/tc-10-853-2016, https://doi.org/10.5194/tc-10-853-2016, 2016
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We analyze how snowpack processes and soil properties impact the soil temperature profiles over northern Eurasian regions using a land surface model. A correct representation of snow compaction is critical in winter while snow albedo is dominant in spring. In summer, soil temperature is more affected by soil organic carbon content, which strongly influences the maximum thaw depth in permafrost regions. This work was done to improve the representation of boreal region processes in climate models.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
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The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
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We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
Q. Libois, G. Picard, L. Arnaud, M. Dumont, M. Lafaysse, S. Morin, and E. Lefebvre
The Cryosphere, 9, 2383–2398, https://doi.org/10.5194/tc-9-2383-2015, https://doi.org/10.5194/tc-9-2383-2015, 2015
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The albedo and surface energy budget of the Antarctic Plateau are largely determined by snow specific surface area. The latter experiences substantial daily-to-seasonal variations in response to meteorological conditions. In particular, it decreases by a factor three in summer, causing a drop in albedo. These variations are monitored from in situ and remote sensing observations at Dome C. For the first time, they are also simulated with a snowpack evolution model adapted to Antarctic conditions.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
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In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert
Atmos. Chem. Phys., 15, 7859–7875, https://doi.org/10.5194/acp-15-7859-2015, https://doi.org/10.5194/acp-15-7859-2015, 2015
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Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
H. G. Chan, M. D. King, and M. M. Frey
Atmos. Chem. Phys., 15, 7913–7927, https://doi.org/10.5194/acp-15-7913-2015, https://doi.org/10.5194/acp-15-7913-2015, 2015
F. Domine, M. Barrere, D. Sarrazin, S. Morin, and L. Arnaud
The Cryosphere, 9, 1265–1276, https://doi.org/10.5194/tc-9-1265-2015, https://doi.org/10.5194/tc-9-1265-2015, 2015
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The thermal conductivity of Arctic snow strongly impacts ground temperature, nutrient recycling and vegetation growth. We have monitored the thermal conductivity of snow in low-Arctic shrub tundra for two consecutive winters using heated needle probes. We observe very different thermal conductivity evolutions in both winters studied, with more extensive melting in the second winter. Results illustrate the effect of vegetation on snow properties and the need to include it in snow physics models.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
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During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
H. Gallée, S. Preunkert, S. Argentini, M. M. Frey, C. Genthon, B. Jourdain, I. Pietroni, G. Casasanta, H. Barral, E. Vignon, C. Amory, and M. Legrand
Atmos. Chem. Phys., 15, 6225–6236, https://doi.org/10.5194/acp-15-6225-2015, https://doi.org/10.5194/acp-15-6225-2015, 2015
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Regional climate model MAR was run for the region of Dome C located on the East Antarctic plateau, during summer 2011–2012, with a high vertical resolution in the lower troposphere. MAR is generally in very good agreement with the observations and provides sufficiently reliable information about surface turbulent fluxes and vertical profiles of vertical diffusion coefficients when discussing the representativeness of chemical measurements made nearby the ground surface at Dome C.
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
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Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
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Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
X. V. Phan, L. Ferro-Famil, M. Gay, Y. Durand, M. Dumont, S. Morin, S. Allain, G. D'Urso, and A. Girard
The Cryosphere, 8, 1975–1987, https://doi.org/10.5194/tc-8-1975-2014, https://doi.org/10.5194/tc-8-1975-2014, 2014
M. Legrand, S. Preunkert, M. Frey, Th. Bartels-Rausch, A. Kukui, M. D. King, J. Savarino, M. Kerbrat, and B. Jourdain
Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, https://doi.org/10.5194/acp-14-9963-2014, 2014
H. Castebrunet, N. Eckert, G. Giraud, Y. Durand, and S. Morin
The Cryosphere, 8, 1673–1697, https://doi.org/10.5194/tc-8-1673-2014, https://doi.org/10.5194/tc-8-1673-2014, 2014
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
M. Dietzel, A. Leis, R. Abdalla, J. Savarino, S. Morin, M. E. Böttcher, and S. Köhler
Biogeosciences, 11, 3149–3161, https://doi.org/10.5194/bg-11-3149-2014, https://doi.org/10.5194/bg-11-3149-2014, 2014
C. M. Carmagnola, S. Morin, M. Lafaysse, F. Domine, B. Lesaffre, Y. Lejeune, G. Picard, and L. Arnaud
The Cryosphere, 8, 417–437, https://doi.org/10.5194/tc-8-417-2014, https://doi.org/10.5194/tc-8-417-2014, 2014
S. Masclin, M. M. Frey, W. F. Rogge, and R. C. Bales
Atmos. Chem. Phys., 13, 8857–8877, https://doi.org/10.5194/acp-13-8857-2013, https://doi.org/10.5194/acp-13-8857-2013, 2013
J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, https://doi.org/10.5194/acp-13-6403-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
Related subject area
Subject: Isotopes | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Strong sensitivity of the isotopic composition of methane to the plausible range of tropospheric chlorine
Using ship-borne observations of methane isotopic ratio in the Arctic Ocean to understand methane sources in the Arctic
Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations
Rethinking Craig and Gordon's approach to modeling isotopic compositions of marine boundary layer vapor
Photochemical box modelling of volcanic SO2 oxidation: isotopic constraints
Uncertainties of fluxes and 13C ∕ 12C ratios of atmospheric reactive-gas emissions
Using δ13C-CH4 and δD-CH4 to constrain Arctic methane emissions
Interannual variability of isotopic composition in water vapor over western Africa and its relationship to ENSO
Continental-scale enrichment of atmospheric 14CO2 from the nuclear power industry: potential impact on the estimation of fossil fuel-derived CO2
Global modelling of H2 mixing ratios and isotopic compositions with the TM5 model
Simulation of the diurnal variations of the oxygen isotope anomaly (Δ17O) of reactive atmospheric species
The impact of anthropogenic emissions on atmospheric sulfate production pathways, oxidants, and ice core Δ17O(SO42–)
Quantifying atmospheric nitrate formation pathways based on a global model of the oxygen isotopic composition (Δ17O) of atmospheric nitrate
Sarah A. Strode, James S. Wang, Michael Manyin, Bryan Duncan, Ryan Hossaini, Christoph A. Keller, Sylvia E. Michel, and James W. C. White
Atmos. Chem. Phys., 20, 8405–8419, https://doi.org/10.5194/acp-20-8405-2020, https://doi.org/10.5194/acp-20-8405-2020, 2020
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The 13C : 12C isotopic ratio in methane (CH4) provides information about CH4 sources, but loss of CH4 by reaction with OH and chlorine (Cl) also affects this ratio. Tropospheric Cl provides a small and uncertain sink for CH4 but has a large effect on its isotopic ratio. We use the GEOS model with several different Cl fields to test the sensitivity of methane's isotopic composition to tropospheric Cl. Cl affects the global mean, hemispheric gradient, and seasonal cycle of the isotopic ratio.
Antoine Berchet, Isabelle Pison, Patrick M. Crill, Brett Thornton, Philippe Bousquet, Thibaud Thonat, Thomas Hocking, Joël Thanwerdas, Jean-Daniel Paris, and Marielle Saunois
Atmos. Chem. Phys., 20, 3987–3998, https://doi.org/10.5194/acp-20-3987-2020, https://doi.org/10.5194/acp-20-3987-2020, 2020
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Methane isotopes in the atmosphere can help us differentiate between emission processes. A large variety of natural and anthropogenic emission types are active in the Arctic and are unsatisfactorily understood and documented up to now. A ship-based campaign was carried out in summer 2014, providing a unique dataset of isotopic measurements in the Arctic Ocean. Using a chemistry-transport model, we link these measurements to circumpolar emissions and retrieve information about their signature.
Becky Alexander, Tomás Sherwen, Christopher D. Holmes, Jenny A. Fisher, Qianjie Chen, Mat J. Evans, and Prasad Kasibhatla
Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, https://doi.org/10.5194/acp-20-3859-2020, 2020
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Nitrogen oxides are important for the formation of tropospheric oxidants and are removed from the atmosphere mainly through the formation of nitrate. We compare observations of the oxygen isotopes of nitrate with a global model to test our understanding of the chemistry nitrate formation. We use the model to quantify nitrate formation pathways in the atmosphere and identify key uncertainties and their relevance for the oxidation capacity of the atmosphere.
Xiahong Feng, Eric S. Posmentier, Leslie J. Sonder, and Naixin Fan
Atmos. Chem. Phys., 19, 4005–4024, https://doi.org/10.5194/acp-19-4005-2019, https://doi.org/10.5194/acp-19-4005-2019, 2019
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We present a 1-D model to simulate H2O isotopologues of vapor and their vertical fluxes in the first kilometer above the sea surface. The model includes two processes not in earlier Craig–Gordon isotope evaporation models: height-dependent diffusion/mixing and ascending/converging air. Calculated isotopic ratios compare well with data from seven cruises. The model explains how sea surface meteorology can affect atmospheric vapor, precipitation isotope ratios, and paleoisotope records.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
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Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Sergey Gromov, Carl A. M. Brenninkmeijer, and Patrick Jöckel
Atmos. Chem. Phys., 17, 8525–8552, https://doi.org/10.5194/acp-17-8525-2017, https://doi.org/10.5194/acp-17-8525-2017, 2017
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We revisit the proxies/uncertainties for the 13C/12C ratios of emissions of reactive C into the atmosphere. Our main findings are (i) a factor of 2 less uncertain estimate of tropospheric CO surface sources δ13C, (ii) a confirmed disagreement between the bottom-up and top-down 13CO-inclusive emission estimates, and (iii) a novel estimate of the δ13C signatures of a range of NMHCs/VOCs to be used in modelling studies. Results are based on the EMAC model emission set-up evaluated for 2000.
Nicola J. Warwick, Michelle L. Cain, Rebecca Fisher, James L. France, David Lowry, Sylvia E. Michel, Euan G. Nisbet, Bruce H. Vaughn, James W. C. White, and John A. Pyle
Atmos. Chem. Phys., 16, 14891–14908, https://doi.org/10.5194/acp-16-14891-2016, https://doi.org/10.5194/acp-16-14891-2016, 2016
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Methane is an important greenhouse gas. Methane emissions from Arctic wetlands are poorly quantified and may increase in a warming climate. Using a global atmospheric model and atmospheric observations of methane and its isotopologues, we find that isotopologue data are useful in constraining Arctic wetland emissions. Our results suggest that the seasonal cycle of these emissions may be incorrectly simulated in land process models, with implications for our understanding of future emissions.
A. Okazaki, Y. Satoh, G. Tremoy, F. Vimeux, R. Scheepmaker, and K. Yoshimura
Atmos. Chem. Phys., 15, 3193–3204, https://doi.org/10.5194/acp-15-3193-2015, https://doi.org/10.5194/acp-15-3193-2015, 2015
H. D. Graven and N. Gruber
Atmos. Chem. Phys., 11, 12339–12349, https://doi.org/10.5194/acp-11-12339-2011, https://doi.org/10.5194/acp-11-12339-2011, 2011
G. Pieterse, M. C. Krol, A. M. Batenburg, L. P. Steele, P. B. Krummel, R. L. Langenfelds, and T. Röckmann
Atmos. Chem. Phys., 11, 7001–7026, https://doi.org/10.5194/acp-11-7001-2011, https://doi.org/10.5194/acp-11-7001-2011, 2011
S. Morin, R. Sander, and J. Savarino
Atmos. Chem. Phys., 11, 3653–3671, https://doi.org/10.5194/acp-11-3653-2011, https://doi.org/10.5194/acp-11-3653-2011, 2011
E. D. Sofen, B. Alexander, and S. A. Kunasek
Atmos. Chem. Phys., 11, 3565–3578, https://doi.org/10.5194/acp-11-3565-2011, https://doi.org/10.5194/acp-11-3565-2011, 2011
B. Alexander, M. G. Hastings, D. J. Allman, J. Dachs, J. A. Thornton, and S. A. Kunasek
Atmos. Chem. Phys., 9, 5043–5056, https://doi.org/10.5194/acp-9-5043-2009, https://doi.org/10.5194/acp-9-5043-2009, 2009
Cited articles
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Short summary
In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
In this paper, we describe the development of a numerical model which aims at representing...
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