Articles | Volume 13, issue 12
https://doi.org/10.5194/acp-13-5857-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-5857-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
17 Jun 2013
Research article | Highlight paper |
| 17 Jun 2013
Formation of aqueous-phase α-hydroxyhydroperoxides (α-HHP): potential atmospheric impacts
Department of Chemistry, University of Toronto, Toronto, ON, Canada
A. K. Y. Lee
Department of Chemistry, University of Toronto, Toronto, ON, Canada
R. Soong
Environmental NMR Centre, University of Toronto, Toronto, ON, Canada
A. J. Simpson
Environmental NMR Centre, University of Toronto, Toronto, ON, Canada
J. P. D. Abbatt
Department of Chemistry, University of Toronto, Toronto, ON, Canada
Related authors
Brigitte Rooney, Ran Zhao, Yuan Wang, Kelvin H. Bates, Ajay Pillarisetti, Sumit Sharma, Seema Kundu, Tami C. Bond, Nicholas L. Lam, Bora Ozaltun, Li Xu, Varun Goel, Lauren T. Fleming, Robert Weltman, Simone Meinardi, Donald R. Blake, Sergey A. Nizkorodov, Rufus D. Edwards, Ankit Yadav, Narendra K. Arora, Kirk R. Smith, and John H. Seinfeld
Atmos. Chem. Phys., 19, 7719–7742, https://doi.org/10.5194/acp-19-7719-2019, https://doi.org/10.5194/acp-19-7719-2019, 2019
Short summary
Short summary
Approximately 3 billion people worldwide cook with solid fuels, such as wood, charcoal, and agricultural residues, that are often combusted in inefficient cookstoves. Here, we simulate the distribution of the two major health-damaging outdoor pollution species (PM2.5 and O3) using state-of-the-science emissions databases and atmospheric chemical transport models to estimate the impact of household combustion on ambient air quality in India.
Yuanlong Huang, Matthew M. Coggon, Ran Zhao, Hanna Lignell, Michael U. Bauer, Richard C. Flagan, and John H. Seinfeld
Atmos. Meas. Tech., 10, 839–867, https://doi.org/10.5194/amt-10-839-2017, https://doi.org/10.5194/amt-10-839-2017, 2017
Short summary
Short summary
We report on the development of a new laminar flow tube reactor for the study of gas-phase atmospheric chemistry and secondary organic aerosol formation. The present paper is devoted to the design and fluid dynamical characterization of the reactor. The results of gas and particle residence time distribution experiments in the reactor, together with an evaluation of the effect of non-isothermal conditions, are reported.
R. Zhao, A. K. Y. Lee, L. Huang, X. Li, F. Yang, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 6087–6100, https://doi.org/10.5194/acp-15-6087-2015, https://doi.org/10.5194/acp-15-6087-2015, 2015
Short summary
Short summary
Aqueous-phase photochemical decay of light absorbing organic compounds, or atmospheric brown carbon (BrC), is investigated in this study. The absorptive change of laboratory surrogates of BrC, as well as biofuel combustion samples, were monitored during photolysis and OH oxidation experiments. The major finding is the rapid change in the absorptivity of BrC during such photochemical processing. This change should be taken into account to evaluate the importance of BrC in the atmosphere.
R. Zhao, E. L. Mungall, A. K. Y. Lee, D. Aljawhary, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 9695–9706, https://doi.org/10.5194/acp-14-9695-2014, https://doi.org/10.5194/acp-14-9695-2014, 2014
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-3240, https://doi.org/10.5194/egusphere-2024-3240, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
This work advances our understanding of emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Michael F. Link, Megan S. Claflin, Christina E. Cecelski, Ayomide A. Akande, Delaney Kilgour, Paul A. Heine, Matthew Coggon, Chelsea E. Stockwell, Andrew Jensen, Jie Yu, Han N. Huynh, Jenna C. Ditto, Carsten Warneke, William Dresser, Keighan Gemmell, Spiro Jorga, Rileigh L. Robertson, Joost de Gouw, Timothy Bertram, Jonathan P. D. Abbatt, Nadine Borduas-Dedekind, and Dustin Poppendieck
EGUsphere, https://doi.org/10.5194/egusphere-2024-3132, https://doi.org/10.5194/egusphere-2024-3132, 2024
Short summary
Short summary
Proton-transfer-reaction mass spectrometry (PTR-MS) is widely used for the measurement of volatile organic compounds (VOCs) both indoors and outdoors. An analytical challenge for PTR-MS measurements is the formation of unintended measurement interferences, product ion distributions (PIDs), that may appear in the data as VOCs of interest. We developed a method for quantifying PID formation and use interlaboratory comparison data to put quantitative constraints on PID formation.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
Short summary
Short summary
The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
Short summary
Short summary
A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Jonathan P. D. Abbatt and A. R. Ravishankara
Atmos. Chem. Phys., 23, 9765–9785, https://doi.org/10.5194/acp-23-9765-2023, https://doi.org/10.5194/acp-23-9765-2023, 2023
Short summary
Short summary
With important climate and air quality impacts, atmospheric multiphase chemistry involves gas interactions with aerosol particles and cloud droplets. We summarize the status of the field and discuss potential directions for future growth. We highlight the importance of a molecular-level understanding of the chemistry, along with atmospheric field studies and modeling, and emphasize the necessity for atmospheric multiphase chemists to interact widely with scientists from neighboring disciplines.
Rachel Y.-W. Chang, Jonathan P. D. Abbatt, Matthew C. Boyer, Jai Prakash Chaubey, and Douglas B. Collins
Atmos. Chem. Phys., 22, 8059–8071, https://doi.org/10.5194/acp-22-8059-2022, https://doi.org/10.5194/acp-22-8059-2022, 2022
Short summary
Short summary
During summer 2016, the ability of newly formed particles to turn into droplets was measured in the Canadian Arctic. Our observations suggest that these small particles were growing by the condensation of organic vapours likely coming from the surrounding open waters. These particles grew large enough that they could form cloud droplets and therefore affect the earth’s radiation budget. These results are relevant as the Arctic summer rapidly warms with climate change.
Zoé Brasseur, Dimitri Castarède, Erik S. Thomson, Michael P. Adams, Saskia Drossaart van Dusseldorp, Paavo Heikkilä, Kimmo Korhonen, Janne Lampilahti, Mikhail Paramonov, Julia Schneider, Franziska Vogel, Yusheng Wu, Jonathan P. D. Abbatt, Nina S. Atanasova, Dennis H. Bamford, Barbara Bertozzi, Matthew Boyer, David Brus, Martin I. Daily, Romy Fösig, Ellen Gute, Alexander D. Harrison, Paula Hietala, Kristina Höhler, Zamin A. Kanji, Jorma Keskinen, Larissa Lacher, Markus Lampimäki, Janne Levula, Antti Manninen, Jens Nadolny, Maija Peltola, Grace C. E. Porter, Pyry Poutanen, Ulrike Proske, Tobias Schorr, Nsikanabasi Silas Umo, János Stenszky, Annele Virtanen, Dmitri Moisseev, Markku Kulmala, Benjamin J. Murray, Tuukka Petäjä, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 22, 5117–5145, https://doi.org/10.5194/acp-22-5117-2022, https://doi.org/10.5194/acp-22-5117-2022, 2022
Short summary
Short summary
The present measurement report introduces the ice nucleation campaign organized in Hyytiälä, Finland, in 2018 (HyICE-2018). We provide an overview of the campaign settings, and we describe the measurement infrastructure and operating procedures used. In addition, we use results from ice nucleation instrument inter-comparison to show that the suite of these instruments deployed during the campaign reports consistent results.
Shunyao Wang, Tengyu Liu, Jinmyung Jang, Jonathan P. D. Abbatt, and Arthur W. H. Chan
Atmos. Chem. Phys., 21, 6647–6661, https://doi.org/10.5194/acp-21-6647-2021, https://doi.org/10.5194/acp-21-6647-2021, 2021
Short summary
Short summary
Discrepancies between atmospheric modeling and field observations, especially in highly polluted cities, have highlighted the lack of understanding of sulfate formation mechanisms and kinetics. Here, we directly quantify the reactive uptake coefficient of SO2 onto organic peroxides and study the important governing factors. The SO2 uptake rate was observed to depend on RH, peroxide amount and reactivity, pH, and ionic strength, which provides a framework to better predict sulfate formation.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Hannes Schulz, Daniel Kunkel, Heiko Bozem, Peter Hoor, Thomas Klimach, Frank Helleis, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 21, 6509–6539, https://doi.org/10.5194/acp-21-6509-2021, https://doi.org/10.5194/acp-21-6509-2021, 2021
Short summary
Short summary
We present in situ observations of vertically resolved particle chemical composition in the summertime Arctic lower troposphere. Our analysis demonstrates the strong vertical contrast between particle properties within the boundary layer and aloft. Emissions from vegetation fires and anthropogenic sources in northern Canada, Europe, and East Asia influenced particle composition in the free troposphere. Organics detected in Arctic aerosol particles can partly be identified as dicarboxylic acids.
Mutian Ma, Laura-Hélèna Rivellini, YuXi Cui, Megan D. Willis, Rio Wilkie, Jonathan P. D. Abbatt, Manjula R. Canagaratna, Junfeng Wang, Xinlei Ge, and Alex K. Y. Lee
Atmos. Meas. Tech., 14, 2799–2812, https://doi.org/10.5194/amt-14-2799-2021, https://doi.org/10.5194/amt-14-2799-2021, 2021
Short summary
Short summary
Chemical characterization of organic coatings is important to advance our understanding of the physio-chemical properties and atmospheric processing of black carbon (BC) particles. This work develops two approaches to improve the elemental analysis of oxygenated organic coatings using a soot-particle aerosol mass spectrometer. Analyzing ambient data with the new approaches indicated that secondary organics that coated on BC were likely less oxygenated compared to those externally mixed with BC.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
Short summary
Short summary
We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
W. Richard Leaitch, John K. Kodros, Megan D. Willis, Sarah Hanna, Hannes Schulz, Elisabeth Andrews, Heiko Bozem, Julia Burkart, Peter Hoor, Felicia Kolonjari, John A. Ogren, Sangeeta Sharma, Meng Si, Knut von Salzen, Allan K. Bertram, Andreas Herber, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 20, 10545–10563, https://doi.org/10.5194/acp-20-10545-2020, https://doi.org/10.5194/acp-20-10545-2020, 2020
Short summary
Short summary
Black carbon is a factor in the warming of the Arctic atmosphere due to its ability to absorb light, but the uncertainty is high and few observations have been made in the high Arctic above 80° N. We combine airborne and ground-based observations in the springtime Arctic, at and above 80° N, with simulations from a global model to show that light absorption by black carbon may be much larger than modelled. However, the uncertainty remains high.
Mikhail Paramonov, Saskia Drossaart van Dusseldorp, Ellen Gute, Jonathan P. D. Abbatt, Paavo Heikkilä, Jorma Keskinen, Xuemeng Chen, Krista Luoma, Liine Heikkinen, Liqing Hao, Tuukka Petäjä, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 6687–6706, https://doi.org/10.5194/acp-20-6687-2020, https://doi.org/10.5194/acp-20-6687-2020, 2020
Short summary
Short summary
Ice-nucleating particle (INP) measurements were performed in the boreal environment of southern Finland in the winter–spring of 2018. It was found that no single parameter could be used to predict the INP number concentration at the measurement location during the examined time period. It was also not possible to identify physical and chemical properties of ambient INPs despite the complexity of the instrumental set-up. Therefore, this paper addresses the necessity for future INP measurements.
Laura-Hélèna Rivellini, Max Gerrit Adam, Nethmi Kasthuriarachchi, and Alex King Yin Lee
Atmos. Chem. Phys., 20, 5977–5993, https://doi.org/10.5194/acp-20-5977-2020, https://doi.org/10.5194/acp-20-5977-2020, 2020
Short summary
Short summary
This work highlights that trace metals and refractory black carbon (rBC), and their inclusion in a source–receptor model, can provide important insight into the source apportionment of carbonaceous aerosols. In Singapore, we evidenced that 90 % of rBC originated from traffic/industrial emissions. The association of aged OA with K and Rb underlines the influence of regional biomass burning sources, while rBC fragmentation patterns and V/Ni were used to identify industrial and shipping pollutants.
Zoë Y. W. Davis, Udo Frieß, Kevin B. Strawbridge, Monika Aggarwaal, Sabour Baray, Elijah G. Schnitzler, Akshay Lobo, Vitali E. Fioletov, Ihab Abboud, Chris A. McLinden, Jim Whiteway, Megan D. Willis, Alex K. Y. Lee, Jeff Brook, Jason Olfert, Jason O'Brien, Ralf Staebler, Hans D. Osthoff, Cristian Mihele, and Robert McLaren
Atmos. Meas. Tech., 13, 1129–1155, https://doi.org/10.5194/amt-13-1129-2020, https://doi.org/10.5194/amt-13-1129-2020, 2020
Short summary
Short summary
Here, we evaluate a ground-based remote sensing method (MAX-DOAS) for measuring total pollutant loading and vertical profiles of pollution in the lower atmosphere by comparing our method to a variety of other measurement methods (lidar, sunphotometer, active DOAS, and aircraft measurements). Measurements were made in the Athabasca Oil Sands Region in Alberta, Canada. The complex dataset provided a rare opportunity to evaluate the performance of MAX-DOAS under varying atmospheric conditions.
Heiko Bozem, Peter Hoor, Daniel Kunkel, Franziska Köllner, Johannes Schneider, Andreas Herber, Hannes Schulz, W. Richard Leaitch, Amir A. Aliabadi, Megan D. Willis, Julia Burkart, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 15049–15071, https://doi.org/10.5194/acp-19-15049-2019, https://doi.org/10.5194/acp-19-15049-2019, 2019
Short summary
Short summary
We present airborne trace gas measurements in the European and Canadian Arctic for July 2014 and April 2015. Based on CO and CO2 in situ data as well as 10 d kinematic back trajectories, we characterize the prevailing transport regimes and derive a tracer-based diagnostic for the determination of the polar dome boundary. Using the tracer-derived boundary, an analysis of the recent transport history of air masses within the polar dome reveals significant differences between spring and summer.
Alex K. Y. Lee, Max G. Adam, John Liggio, Shao-Meng Li, Kun Li, Megan D. Willis, Jonathan P. D. Abbatt, Travis W. Tokarek, Charles A. Odame-Ankrah, Hans D. Osthoff, Kevin Strawbridge, and Jeffery R. Brook
Atmos. Chem. Phys., 19, 12209–12219, https://doi.org/10.5194/acp-19-12209-2019, https://doi.org/10.5194/acp-19-12209-2019, 2019
Short summary
Short summary
This work provides the first direct field evidence that anthropogenic organo-nitrate contributed up to half of secondary organic aerosol (SOA) mass that was freshly produced within the emission plumes of oil sands facilities in Alberta, Canada. The findings illustrate the central role of organo-nitrate in SOA production from the oil and gas industry, with relevance for other urban and industrial regions with significant intermediate-volatility organic compounds (IVOCs) and NOx emissions.
Victoria E. Irish, Sarah J. Hanna, Yu Xi, Matthew Boyer, Elena Polishchuk, Mohamed Ahmed, Jessie Chen, Jonathan P. D. Abbatt, Michel Gosselin, Rachel Chang, Lisa A. Miller, and Allan K. Bertram
Atmos. Chem. Phys., 19, 7775–7787, https://doi.org/10.5194/acp-19-7775-2019, https://doi.org/10.5194/acp-19-7775-2019, 2019
Short summary
Short summary
The ocean is a source of atmospheric ice-nucleating particles (INPs). In this study we compared INPs measured in microlayer and bulk seawater in the Canadian Arctic in 2016 to those measured in 2014. A strong negative correlation between salinity and freezing temperatures was observed, possibly due to INPs associated with melting sea ice. In addition, although spatial patterns of INPs and salinities were similar in 2014 and 2016, the concentrations of INPs were on average higher in 2016.
Brigitte Rooney, Ran Zhao, Yuan Wang, Kelvin H. Bates, Ajay Pillarisetti, Sumit Sharma, Seema Kundu, Tami C. Bond, Nicholas L. Lam, Bora Ozaltun, Li Xu, Varun Goel, Lauren T. Fleming, Robert Weltman, Simone Meinardi, Donald R. Blake, Sergey A. Nizkorodov, Rufus D. Edwards, Ankit Yadav, Narendra K. Arora, Kirk R. Smith, and John H. Seinfeld
Atmos. Chem. Phys., 19, 7719–7742, https://doi.org/10.5194/acp-19-7719-2019, https://doi.org/10.5194/acp-19-7719-2019, 2019
Short summary
Short summary
Approximately 3 billion people worldwide cook with solid fuels, such as wood, charcoal, and agricultural residues, that are often combusted in inefficient cookstoves. Here, we simulate the distribution of the two major health-damaging outdoor pollution species (PM2.5 and O3) using state-of-the-science emissions databases and atmospheric chemical transport models to estimate the impact of household combustion on ambient air quality in India.
Betty Croft, Randall V. Martin, W. Richard Leaitch, Julia Burkart, Rachel Y.-W. Chang, Douglas B. Collins, Patrick L. Hayes, Anna L. Hodshire, Lin Huang, John K. Kodros, Alexander Moravek, Emma L. Mungall, Jennifer G. Murphy, Sangeeta Sharma, Samantha Tremblay, Gregory R. Wentworth, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 19, 2787–2812, https://doi.org/10.5194/acp-19-2787-2019, https://doi.org/10.5194/acp-19-2787-2019, 2019
Short summary
Short summary
Summertime Arctic atmospheric aerosols are strongly controlled by processes related to natural regional sources. We use a chemical transport model with size-resolved aerosol microphysics to interpret measurements made during summertime 2016 in the Canadian Arctic Archipelago. Our results explore the processes that control summertime aerosol size distributions and support a climate-relevant role for Arctic marine secondary organic aerosol formed from precursor vapors with Arctic marine sources.
Jonathan P. D. Abbatt, W. Richard Leaitch, Amir A. Aliabadi, Allan K. Bertram, Jean-Pierre Blanchet, Aude Boivin-Rioux, Heiko Bozem, Julia Burkart, Rachel Y. W. Chang, Joannie Charette, Jai P. Chaubey, Robert J. Christensen, Ana Cirisan, Douglas B. Collins, Betty Croft, Joelle Dionne, Greg J. Evans, Christopher G. Fletcher, Martí Galí, Roya Ghahreman, Eric Girard, Wanmin Gong, Michel Gosselin, Margaux Gourdal, Sarah J. Hanna, Hakase Hayashida, Andreas B. Herber, Sareh Hesaraki, Peter Hoor, Lin Huang, Rachel Hussherr, Victoria E. Irish, Setigui A. Keita, John K. Kodros, Franziska Köllner, Felicia Kolonjari, Daniel Kunkel, Luis A. Ladino, Kathy Law, Maurice Levasseur, Quentin Libois, John Liggio, Martine Lizotte, Katrina M. Macdonald, Rashed Mahmood, Randall V. Martin, Ryan H. Mason, Lisa A. Miller, Alexander Moravek, Eric Mortenson, Emma L. Mungall, Jennifer G. Murphy, Maryam Namazi, Ann-Lise Norman, Norman T. O'Neill, Jeffrey R. Pierce, Lynn M. Russell, Johannes Schneider, Hannes Schulz, Sangeeta Sharma, Meng Si, Ralf M. Staebler, Nadja S. Steiner, Jennie L. Thomas, Knut von Salzen, Jeremy J. B. Wentzell, Megan D. Willis, Gregory R. Wentworth, Jun-Wei Xu, and Jacqueline D. Yakobi-Hancock
Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, https://doi.org/10.5194/acp-19-2527-2019, 2019
Short summary
Short summary
The Arctic is experiencing considerable environmental change with climate warming, illustrated by the dramatic decrease in sea-ice extent. It is important to understand both the natural and perturbed Arctic systems to gain a better understanding of how they will change in the future. This paper summarizes new insights into the relationships between Arctic aerosol particles and climate, as learned over the past five or so years by a large Canadian research consortium, NETCARE.
Hannes Schulz, Marco Zanatta, Heiko Bozem, W. Richard Leaitch, Andreas B. Herber, Julia Burkart, Megan D. Willis, Daniel Kunkel, Peter M. Hoor, Jonathan P. D. Abbatt, and Rüdiger Gerdes
Atmos. Chem. Phys., 19, 2361–2384, https://doi.org/10.5194/acp-19-2361-2019, https://doi.org/10.5194/acp-19-2361-2019, 2019
Short summary
Short summary
Aircraft vertical profiles of black carbon (BC) aerosol from the High Canadian Arctic have shown systematic variability in different levels of the cold, stably stratified polar dome. During spring and summer, efficiencies of BC supply by transport (often from gas flaring and wildfire-affected regions) were different in the lower dome than at higher levels, as apparent from changes in mean particle size and mixing ratios with CO. Summer BC concentrations were a factor of 10 lower than in spring.
Xiaoxiao Li, Sabrina Chee, Jiming Hao, Jonathan P. D. Abbatt, Jingkun Jiang, and James N. Smith
Atmos. Chem. Phys., 19, 1555–1570, https://doi.org/10.5194/acp-19-1555-2019, https://doi.org/10.5194/acp-19-1555-2019, 2019
Short summary
Short summary
We performed lab experiments to explore the role of relative humidity, RH, in atmospheric monoterpene oxidation and new particle formation. These studies will provide insights into the most important steps in the process, while also more accurately representing the real atmosphere. We found that the detected compounds did not change with RH, and in fact could mostly be fully explained by the autoxidation of organic peroxy radicals followed by bimolecular reactions with other peroxy radicals.
Victoria E. Irish, Sarah J. Hanna, Megan D. Willis, Swarup China, Jennie L. Thomas, Jeremy J. B. Wentzell, Ana Cirisan, Meng Si, W. Richard Leaitch, Jennifer G. Murphy, Jonathan P. D. Abbatt, Alexander Laskin, Eric Girard, and Allan K. Bertram
Atmos. Chem. Phys., 19, 1027–1039, https://doi.org/10.5194/acp-19-1027-2019, https://doi.org/10.5194/acp-19-1027-2019, 2019
Short summary
Short summary
Ice nucleating particles (INPs) are atmospheric particles that catalyse the formation of ice crystals in clouds. INPs influence the Earth's radiative balance and hydrological cycle. In this study we measured the concentrations of INPs in the Canadian Arctic marine boundary layer. Average INP concentrations fell within the range measured in other marine boundary layer locations. We also found that mineral dust is a more important contributor to the INP population than sea spray aerosol.
Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 57–76, https://doi.org/10.5194/acp-19-57-2019, https://doi.org/10.5194/acp-19-57-2019, 2019
Short summary
Short summary
The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.
Travis W. Tokarek, Charles A. Odame-Ankrah, Jennifer A. Huo, Robert McLaren, Alex K. Y. Lee, Max G. Adam, Megan D. Willis, Jonathan P. D. Abbatt, Cristian Mihele, Andrea Darlington, Richard L. Mittermeier, Kevin Strawbridge, Katherine L. Hayden, Jason S. Olfert, Elijah G. Schnitzler, Duncan K. Brownsey, Faisal V. Assad, Gregory R. Wentworth, Alex G. Tevlin, Douglas E. J. Worthy, Shao-Meng Li, John Liggio, Jeffrey R. Brook, and Hans D. Osthoff
Atmos. Chem. Phys., 18, 17819–17841, https://doi.org/10.5194/acp-18-17819-2018, https://doi.org/10.5194/acp-18-17819-2018, 2018
Short summary
Short summary
Measurements of air pollutants at a ground site near Fort McKay in the Athabasca oil sands region in the summer of 2013 are presented. A large number of intermediate-volatility organic compounds (IVOCs) were observed; these molecules were shown previously to generate atmospheric particles downwind of the region. A principal component analysis was performed to identify major pollution source types, including which source(s) is(are) associated with IVOC emissions (e.g., freshly mined bitumen).
Meng Si, Victoria E. Irish, Ryan H. Mason, Jesús Vergara-Temprado, Sarah J. Hanna, Luis A. Ladino, Jacqueline D. Yakobi-Hancock, Corinne L. Schiller, Jeremy J. B. Wentzell, Jonathan P. D. Abbatt, Ken S. Carslaw, Benjamin J. Murray, and Allan K. Bertram
Atmos. Chem. Phys., 18, 15669–15685, https://doi.org/10.5194/acp-18-15669-2018, https://doi.org/10.5194/acp-18-15669-2018, 2018
Short summary
Short summary
Using the concentrations of ice-nucleating particles (INPs) and total aerosol particles measured at three coastal marine sites, the ice-nucleating ability of aerosol particles on a per number basis and a per surface-area basis were determined as a function of size. The ice-nucleating ability was strongly dependent on size, with larger particles being more efficient. This type of information can help determine the sources of INPs and constrain the future modelling of INPs and mixed-phase clouds.
Elijah G. Schnitzler and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 18, 14539–14553, https://doi.org/10.5194/acp-18-14539-2018, https://doi.org/10.5194/acp-18-14539-2018, 2018
Short summary
Short summary
Brown carbon (BrC) has significant but poorly constrained effects on climate. In this work, we investigate the effects of the OH radical on optical properties of secondary BrC in a series of smog chamber experiments. At high relative humidity (RH), we find that the evolution of the particles is complex, exhibiting rapid absorption enhancement followed by slow bleaching. At low RH, bleaching does not occur. These results further our understanding of the highly variable evolution of ambient BrC.
John K. Kodros, Sarah J. Hanna, Allan K. Bertram, W. Richard Leaitch, Hannes Schulz, Andreas B. Herber, Marco Zanatta, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 11345–11361, https://doi.org/10.5194/acp-18-11345-2018, https://doi.org/10.5194/acp-18-11345-2018, 2018
Short summary
Short summary
The mixing state of black carbon is one of the key uncertainties limiting the ability of models to estimate the direct radiative effect. In this work, we present aircraft measurements from the Canadian Arctic of coating thickness as a function of black carbon core diameter and black-carbon-containing particle number fractions. We use these measurements to inform estimates of the direct radiative effect in Arctic aerosol simulations.
Emma L. Mungall, Jonathan P. D. Abbatt, Jeremy J. B. Wentzell, Gregory R. Wentworth, Jennifer G. Murphy, Daniel Kunkel, Ellen Gute, David W. Tarasick, Sangeeta Sharma, Christopher J. Cox, Taneil Uttal, and John Liggio
Atmos. Chem. Phys., 18, 10237–10254, https://doi.org/10.5194/acp-18-10237-2018, https://doi.org/10.5194/acp-18-10237-2018, 2018
Short summary
Short summary
We measured gas-phase formic and acetic acid at Alert, Nunavut. These acids play an important role in cloud water acidity in remote environments, yet they are not well represented in chemical transport models, particularly in the Arctic. We observed high levels of formic and acetic acid under both cold, wet, and cloudy and warm, sunny, and dry conditions, suggesting that multiple sources significantly contribute to gas-phase concentrations of these species in the summer Arctic.
Shouming Zhou, Jean C. Rivera-Rios, Frank N. Keutsch, and Jonathan P. D. Abbatt
Atmos. Meas. Tech., 11, 3081–3089, https://doi.org/10.5194/amt-11-3081-2018, https://doi.org/10.5194/amt-11-3081-2018, 2018
Jianhuai Ye, Jonathan P. D. Abbatt, and Arthur W. H. Chan
Atmos. Chem. Phys., 18, 5549–5565, https://doi.org/10.5194/acp-18-5549-2018, https://doi.org/10.5194/acp-18-5549-2018, 2018
Short summary
Short summary
Synergistic effects between SOA formation and SO2 oxidation through Criegee chemistry and reactive uptake by organic peroxides were observed. The relative importance of these two pathways (Criegee vs. peroxide) varies with relative humidity. The latter SO2 loss mechanism to organic peroxides in SOA has not previously been identified. Our results suggest a new pathway of atmospheric SO2 oxidation, which may contribute to the missing mechanisms of high-sulfate production in the polluted areas.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Andrew Platt, Mike Elsasser, Lin Huang, Richard Leaitch, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Cheol-Heon Jeong, Jonathan P. D. Abbatt, and Greg J. Evans
Atmos. Chem. Phys., 18, 3485–3503, https://doi.org/10.5194/acp-18-3485-2018, https://doi.org/10.5194/acp-18-3485-2018, 2018
Short summary
Short summary
The sources of key contaminants in Arctic snow may be an important factor in understanding the rapid climate changes observed in the Arctic. Fresh snow samples collected frequently through the winter season were analyzed for major constituents. Temporally refined source apportionment via positive matrix factorization in conjunction with FLEXPART suggested potential source characteristics and locations. The identity of these sources and their relative contribution to key analytes is discussed.
Alex K. Y. Lee, Chia-Li Chen, Jun Liu, Derek J. Price, Raghu Betha, Lynn M. Russell, Xiaolu Zhang, and Christopher D. Cappa
Atmos. Chem. Phys., 17, 15055–15067, https://doi.org/10.5194/acp-17-15055-2017, https://doi.org/10.5194/acp-17-15055-2017, 2017
Short summary
Short summary
Understanding the mixing state of ambient black carbon (BC) and the chemical characteristics of its associated coatings is important to evaluate BC fate and environmental impacts. This study reports fresh secondary organic aerosol (SOA) formation near traffic emissions during daytime. Our observations suggest that BC was unlikely the major condensation sink of SOA, and a portion of SOA condensed on BC surface was chemically different from other SOA particles that were externally mixed with BC.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Thomas Klimach, Frank Helleis, Heiko Bozem, Daniel Kunkel, Peter Hoor, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 17, 13747–13766, https://doi.org/10.5194/acp-17-13747-2017, https://doi.org/10.5194/acp-17-13747-2017, 2017
Short summary
Short summary
We conducted aircraft-based single particle chemical composition measurements in the Canadian high Arctic during summer. Our results provide evidence for a marine-biogenic influence on secondary formation of particulate trimethylamine in the Arctic boundary layer. Understanding emission sources and further processes controlling aerosol number concentration and chemical composition in the pristine Arctic summer is crucial for modeling future climate in the area.
Douglas B. Collins, Julia Burkart, Rachel Y.-W. Chang, Martine Lizotte, Aude Boivin-Rioux, Marjolaine Blais, Emma L. Mungall, Matthew Boyer, Victoria E. Irish, Guillaume Massé, Daniel Kunkel, Jean-Éric Tremblay, Tim Papakyriakou, Allan K. Bertram, Heiko Bozem, Michel Gosselin, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 13119–13138, https://doi.org/10.5194/acp-17-13119-2017, https://doi.org/10.5194/acp-17-13119-2017, 2017
Short summary
Short summary
The sources of aerosol particles and their growth to sizes large enough to act as cloud droplet seeds is of major importance to climate since clouds exert substantial control over the atmospheric energy balance. Using ship-board measurements from two summers in the Canadian Arctic, aerosol formation events were related to co-sampled atmospheric and oceanic parameters, providing insight into factors that drive particle formation and motivating further study of ocean–atmosphere interactions.
Jun-Wei Xu, Randall V. Martin, Andrew Morrow, Sangeeta Sharma, Lin Huang, W. Richard Leaitch, Julia Burkart, Hannes Schulz, Marco Zanatta, Megan D. Willis, Daven K. Henze, Colin J. Lee, Andreas B. Herber, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 11971–11989, https://doi.org/10.5194/acp-17-11971-2017, https://doi.org/10.5194/acp-17-11971-2017, 2017
Short summary
Short summary
We interpret a series of recent airborne and ground-based measurements with the GEOS-Chem model and its adjoint to attribute the sources of Arctic BC. Anthropogenic emissions in eastern and southern Asia make the largest contribution to Arctic BC. Gas flaring emissions from oilfields in western Siberia and from the Tarim oilfield in western China could have striking impacts on Arctic BC loadings.
Victoria E. Irish, Pablo Elizondo, Jessie Chen, Cédric Chou, Joannie Charette, Martine Lizotte, Luis A. Ladino, Theodore W. Wilson, Michel Gosselin, Benjamin J. Murray, Elena Polishchuk, Jonathan P. D. Abbatt, Lisa A. Miller, and Allan K. Bertram
Atmos. Chem. Phys., 17, 10583–10595, https://doi.org/10.5194/acp-17-10583-2017, https://doi.org/10.5194/acp-17-10583-2017, 2017
Short summary
Short summary
The ocean is a possible source of atmospheric ice-nucleating particles (INPs). In this study we found that INPs were ubiquitous in the sea-surface microlayer and bulk seawater in the Canadian Arctic. A strong negative correlation was observed between salinity and freezing temperatures (after correcting for freezing point depression). Heat and filtration treatments of the samples showed that the INPs were likely biological material with sizes between 0.02 μm and 0.2 μm in diameter.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Sarah Hanna, Allan K. Bertram, Andrew Platt, Mike Elsasser, Lin Huang, David Tarasick, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 5775–5788, https://doi.org/10.5194/acp-17-5775-2017, https://doi.org/10.5194/acp-17-5775-2017, 2017
Short summary
Short summary
Rapid climate changes within the Arctic have highlighted existing uncertainties in the transport of contaminants to Arctic snow. Fresh snow samples collected frequently through the winter season were analyzed for major constituents creating a unique record of Arctic snow. Comparison with simultaneous atmospheric measurements provides insight into the driving processes in the transfer of contaminants from air to snow. The relative importance of deposition mechanisms over the season is proposed.
Julia Burkart, Megan D. Willis, Heiko Bozem, Jennie L. Thomas, Kathy Law, Peter Hoor, Amir A. Aliabadi, Franziska Köllner, Johannes Schneider, Andreas Herber, Jonathan P. D. Abbatt, and W. Richard Leaitch
Atmos. Chem. Phys., 17, 5515–5535, https://doi.org/10.5194/acp-17-5515-2017, https://doi.org/10.5194/acp-17-5515-2017, 2017
Short summary
Short summary
Our aircraft study for the first time systematically investigates aerosol size distributions, including ultrafine particles (5–20 nm in diameter), in the Arctic summertime atmosphere. We find that ultrafine particles occur very frequently in the boundary layer and not aloft, suggesting a surface source of these particles. Understanding aerosol properties and sources is crucial to predict climate and especially important in the Arctic as this region responds extremely fast to climate change.
Yuanlong Huang, Matthew M. Coggon, Ran Zhao, Hanna Lignell, Michael U. Bauer, Richard C. Flagan, and John H. Seinfeld
Atmos. Meas. Tech., 10, 839–867, https://doi.org/10.5194/amt-10-839-2017, https://doi.org/10.5194/amt-10-839-2017, 2017
Short summary
Short summary
We report on the development of a new laminar flow tube reactor for the study of gas-phase atmospheric chemistry and secondary organic aerosol formation. The present paper is devoted to the design and fluid dynamical characterization of the reactor. The results of gas and particle residence time distribution experiments in the reactor, together with an evaluation of the effect of non-isothermal conditions, are reported.
Quentin Libois, Liviu Ivanescu, Jean-Pierre Blanchet, Hannes Schulz, Heiko Bozem, W. Richard Leaitch, Julia Burkart, Jonathan P. D. Abbatt, Andreas B. Herber, Amir A. Aliabadi, and Éric Girard
Atmos. Chem. Phys., 16, 15689–15707, https://doi.org/10.5194/acp-16-15689-2016, https://doi.org/10.5194/acp-16-15689-2016, 2016
Short summary
Short summary
The first airborne measurements performed with the FIRR are presented. Vertical profiles of upwelling spectral radiance in the far-infrared are measured in the Arctic atmosphere for the first time. They show the impact of the temperature inversion on the radiative budget of the atmosphere, especially in the far-infrared. The presence of ice clouds also significantly alters the far-infrared budget, highlighting the critical interplay between water vapour and clouds in this very dry region.
W. Richard Leaitch, Alexei Korolev, Amir A. Aliabadi, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, Heiko Bozem, Peter Hoor, Franziska Köllner, Johannes Schneider, Andreas Herber, Christian Konrad, and Ralf Brauner
Atmos. Chem. Phys., 16, 11107–11124, https://doi.org/10.5194/acp-16-11107-2016, https://doi.org/10.5194/acp-16-11107-2016, 2016
Short summary
Short summary
Thought to be mostly unimportant for summertime Arctic liquid-water clouds, airborne observations show that atmospheric aerosol particles 50 nm in diameter or smaller and most likely from natural sources are often involved in cloud formation in the pristine Arctic summer. The result expands the reference for aerosol forcing of climate. Further, for extremely low droplet concentrations, no evidence is found for a connection between cloud liquid water and aerosol particle concentrations.
Sarvesh Garimella, Thomas Bjerring Kristensen, Karolina Ignatius, Andre Welti, Jens Voigtländer, Gourihar R. Kulkarni, Frank Sagan, Gregory Lee Kok, James Dorsey, Leonid Nichman, Daniel Alexander Rothenberg, Michael Rösch, Amélie Catharina Ruth Kirchgäßner, Russell Ladkin, Heike Wex, Theodore W. Wilson, Luis Antonio Ladino, Jon P. D. Abbatt, Olaf Stetzer, Ulrike Lohmann, Frank Stratmann, and Daniel James Cziczo
Atmos. Meas. Tech., 9, 2781–2795, https://doi.org/10.5194/amt-9-2781-2016, https://doi.org/10.5194/amt-9-2781-2016, 2016
Short summary
Short summary
The SPectrometer for Ice Nuclei (SPIN) is a commercially available ice nuclei counter manufactured by Droplet Measurement Technologies in Boulder, CO. This study characterizes the SPIN chamber, reporting data from laboratory measurements and quantifying uncertainties. Overall, we report that the SPIN is able to reproduce previous CFDC ice nucleation measurements.
Amir A. Aliabadi, Jennie L. Thomas, Andreas B. Herber, Ralf M. Staebler, W. Richard Leaitch, Hannes Schulz, Kathy S. Law, Louis Marelle, Julia Burkart, Megan D. Willis, Heiko Bozem, Peter M. Hoor, Franziska Köllner, Johannes Schneider, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 7899–7916, https://doi.org/10.5194/acp-16-7899-2016, https://doi.org/10.5194/acp-16-7899-2016, 2016
Short summary
Short summary
For the first time, ship emissions of an ice-breaker, the Amundsen, is characterized while breaking ice in the Canadian Arctic using the plume intercepts by the Polar 6 aircraft. The study is novel, estimating lower plume expansion rates over the stable Arctic marine boundary layer and different emissions factors for oxides of nitrogen, black carbon, and carbon monoxide, compared to plume intercept studies in mid latitudes. These results can inform policy making and emission inventory datasets.
Megan D. Willis, Julia Burkart, Jennie L. Thomas, Franziska Köllner, Johannes Schneider, Heiko Bozem, Peter M. Hoor, Amir A. Aliabadi, Hannes Schulz, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 7663–7679, https://doi.org/10.5194/acp-16-7663-2016, https://doi.org/10.5194/acp-16-7663-2016, 2016
Short summary
Short summary
We present a case study focused on an aerosol growth event observed in the Canadian High Arctic during summer. Using measurements of aerosol chemical and physical properties we find evidence for aerosol growth into cloud condensation nuclei-active sizes, through marine-influenced secondary organic aerosol formation. Understanding the mechanisms that control the formation and growth of aerosol is crucial for our ability to predict cloud properties, and therefore radiative balance and climate.
Alex K. Y. Lee, Jonathan P. D. Abbatt, W. Richard Leaitch, Shao-Meng Li, Steve J. Sjostedt, Jeremy J. B. Wentzell, John Liggio, and Anne Marie Macdonald
Atmos. Chem. Phys., 16, 6721–6733, https://doi.org/10.5194/acp-16-6721-2016, https://doi.org/10.5194/acp-16-6721-2016, 2016
Short summary
Short summary
Substantial biogenic secondary organic aerosol (BSOA) formation was investigated in a coniferous forest mountain region in Whistler, British Columbia. A largely biogenic aerosol growth episode was observed, providing a unique opportunity to investigate BSOA formation chemistry in a forested environment. In particular, our observations provide insights into the relative importance of different oxidation mechanisms between day and night.
Emma L. Mungall, Betty Croft, Martine Lizotte, Jennie L. Thomas, Jennifer G. Murphy, Maurice Levasseur, Randall V. Martin, Jeremy J. B. Wentzell, John Liggio, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 6665–6680, https://doi.org/10.5194/acp-16-6665-2016, https://doi.org/10.5194/acp-16-6665-2016, 2016
Short summary
Short summary
Previous work has suggested that marine emissions of dimethyl sulfide (DMS) could impact the Arctic climate through interactions with clouds. We made the first high-time-resolution measurements of summertime atmospheric DMS in the Canadian Arctic, and performed source sensitivity simulations. We found that regional marine sources dominated, but do not appear to be sufficient to explain our observations. Understanding DMS sources in the Arctic is necessary to model future climate in the region.
Alex K. Y. Lee, Megan D. Willis, Robert M. Healy, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 5561–5572, https://doi.org/10.5194/acp-16-5561-2016, https://doi.org/10.5194/acp-16-5561-2016, 2016
Short summary
Short summary
Single-particle measurements from a soot-particle aerosol mass spectrometer were performed to examine the mixing state of aerosol particles in an air mass influenced by aged biomass burning. Our observations indicate non-uniform mixing of particles within a biomass burning plume in terms of molecular weight and potassium content, and illustrate that high molecular weight organic compounds can be a key contributor to low-volatility BrC observed in biomass burning organic aerosols.
Roya Ghahreman, Ann-Lise Norman, Jonathan P. D. Abbatt, Maurice Levasseur, and Jennie L. Thomas
Atmos. Chem. Phys., 16, 5191–5202, https://doi.org/10.5194/acp-16-5191-2016, https://doi.org/10.5194/acp-16-5191-2016, 2016
Short summary
Short summary
Aerosols in six size fractions (> 0.49–7.0 microns) were collected in the Arctic (July 2014). The isotopic composition of sulfate aerosols was measured to determine the role of biogenic and anthropogenic sources in the growth of aerosols. More than 63 % of the average sulfate concentration in the fine aerosols (> 0.49 microns) was from biogenic sources. For some samples, the S isotope ratio values for SO2 and fine aerosols were close together, suggesting the same source for SO2 and aerosol sulfur.
Megan D. Willis, Robert M. Healy, Nicole Riemer, Matthew West, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, Jonathan P. D. Abbatt, and Alex K. Y. Lee
Atmos. Chem. Phys., 16, 4693–4706, https://doi.org/10.5194/acp-16-4693-2016, https://doi.org/10.5194/acp-16-4693-2016, 2016
Gregory R. Wentworth, Jennifer G. Murphy, Betty Croft, Randall V. Martin, Jeffrey R. Pierce, Jean-Sébastien Côté, Isabelle Courchesne, Jean-Éric Tremblay, Jonathan Gagnon, Jennie L. Thomas, Sangeeta Sharma, Desiree Toom-Sauntry, Alina Chivulescu, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 1937–1953, https://doi.org/10.5194/acp-16-1937-2016, https://doi.org/10.5194/acp-16-1937-2016, 2016
Short summary
Short summary
Air near the surface in the summertime Arctic is extremely clean and typically has very low concentrations of both gases and particles. However, atmospheric measurements taken throughout the Canadian Arctic in the summer of 2014 revealed higher-than-expected amounts of gaseous ammonia. It is likely the majority of this ammonia is coming from migratory seabird colonies throughout the Arctic. Seabird guano (dung) releases ammonia which could impact climate and sensitive Arctic ecosystems.
R. H. Mason, M. Si, C. Chou, V. E. Irish, R. Dickie, P. Elizondo, R. Wong, M. Brintnell, M. Elsasser, W. M. Lassar, K. M. Pierce, W. R. Leaitch, A. M. MacDonald, A. Platt, D. Toom-Sauntry, R. Sarda-Estève, C. L. Schiller, K. J. Suski, T. C. J. Hill, J. P. D. Abbatt, J. A. Huffman, P. J. DeMott, and A. K. Bertram
Atmos. Chem. Phys., 16, 1637–1651, https://doi.org/10.5194/acp-16-1637-2016, https://doi.org/10.5194/acp-16-1637-2016, 2016
N. Borduas, B. Place, G. R. Wentworth, J. P. D. Abbatt, and J. G. Murphy
Atmos. Chem. Phys., 16, 703–714, https://doi.org/10.5194/acp-16-703-2016, https://doi.org/10.5194/acp-16-703-2016, 2016
Short summary
Short summary
HNCO is a toxic molecule and can cause cardiovascular and cataract problems through protein carbamylation once inhaled. Recently reported ambient measurements of HNCO in North America raise concerns for human exposure. To better understand HNCO's loss processes and behaviour in the atmosphere, we provide thermochemical data on HNCO. The parameters allow for more accurate predictions of its lifetime in the atmosphere and consequently help define exposure of this toxic molecule.
R. H. Mason, M. Si, J. Li, C. Chou, R. Dickie, D. Toom-Sauntry, C. Pöhlker, J. D. Yakobi-Hancock, L. A. Ladino, K. Jones, W. R. Leaitch, C. L. Schiller, J. P. D. Abbatt, J. A. Huffman, and A. K. Bertram
Atmos. Chem. Phys., 15, 12547–12566, https://doi.org/10.5194/acp-15-12547-2015, https://doi.org/10.5194/acp-15-12547-2015, 2015
K. M. Badali, S. Zhou, D. Aljawhary, M. Antiñolo, W. J. Chen, A. Lok, E. Mungall, J. P. S. Wong, R. Zhao, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 7831–7840, https://doi.org/10.5194/acp-15-7831-2015, https://doi.org/10.5194/acp-15-7831-2015, 2015
Short summary
Short summary
This is the first paper to demonstrate that SOA material forms OH radicals upon UV illumination. We quantify the OH formation rates in solution and show species other than H2O2, mostly probably ROOH molecules, are the likely source of the OH. The importance of an OH source from SOA is that photochemical processing within both cloudwater and aerosol particles may arise subsequent to the formation of these radicals.
R. Zhao, A. K. Y. Lee, L. Huang, X. Li, F. Yang, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 6087–6100, https://doi.org/10.5194/acp-15-6087-2015, https://doi.org/10.5194/acp-15-6087-2015, 2015
Short summary
Short summary
Aqueous-phase photochemical decay of light absorbing organic compounds, or atmospheric brown carbon (BrC), is investigated in this study. The absorptive change of laboratory surrogates of BrC, as well as biofuel combustion samples, were monitored during photolysis and OH oxidation experiments. The major finding is the rapid change in the absorptivity of BrC during such photochemical processing. This change should be taken into account to evaluate the importance of BrC in the atmosphere.
F. Wania, Y. D. Lei, C. Wang, J. P. D. Abbatt, and K.-U. Goss
Atmos. Chem. Phys., 15, 3395–3412, https://doi.org/10.5194/acp-15-3395-2015, https://doi.org/10.5194/acp-15-3395-2015, 2015
Short summary
Short summary
The manuscript presents a new way to graphically illustrate some of the processes that occur when organic particles form in the atmosphere. In particular, this method makes it possible to see how factors such as the composition of the atmosphere and temperature affect these processes.
A. K. Y. Lee, M. D. Willis, R. M. Healy, T. B. Onasch, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 1823–1841, https://doi.org/10.5194/acp-15-1823-2015, https://doi.org/10.5194/acp-15-1823-2015, 2015
Short summary
Short summary
Understanding the impact of black carbon (BC) particles on human health and radiative forcing requires knowledge of the BC mixing state. This work investigates the mixing state of BC and other aerosol species in a typical urban area using a single particle mass spectrometry technique. Our results provide quantitative insight into the physical and chemical nature of BC-containing particles near emission and can be used as a basis for our developing understanding of BC evolution in the atmosphere.
M. D. Willis, A. K. Y. Lee, T. B. Onasch, E. C. Fortner, L. R. Williams, A. T. Lambe, D. R. Worsnop, and J. P. D. Abbatt
Atmos. Meas. Tech., 7, 4507–4516, https://doi.org/10.5194/amt-7-4507-2014, https://doi.org/10.5194/amt-7-4507-2014, 2014
F. Wania, Y. D. Lei, C. Wang, J. P. D. Abbatt, and K.-U. Goss
Atmos. Chem. Phys., 14, 13189–13204, https://doi.org/10.5194/acp-14-13189-2014, https://doi.org/10.5194/acp-14-13189-2014, 2014
Short summary
Short summary
A description of the formation of secondary organic aerosol requires the prediction of the partitioning equilibrium of organic compounds with multiple functional groups between gas and organic particle phase. While this is typically done by predicting both the saturation vapour pressure and the activity coefficient in the organic particle phase, we demonstrate here that it is feasible to predict the partitioning equilibrium directly. This direct approach has greater precision.
J. D. Yakobi-Hancock, L. A. Ladino, A. K. Bertram, J. A. Huffman, K. Jones, W. R. Leaitch, R. H. Mason, C. L. Schiller, D. Toom-Sauntry, J. P. S. Wong, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 12307–12317, https://doi.org/10.5194/acp-14-12307-2014, https://doi.org/10.5194/acp-14-12307-2014, 2014
Short summary
Short summary
As one aspect of the NETwork on Climate and Aerosols: addressing key uncertainties in Remote Canadian Environments, measurements of the cloud condensation nucleation properties of 50 nm and 100 nm aerosol particles were conducted at Ucluelet on the west coast of Vancouver Island in August 2013. The most efficient cloud condensation nuclei arose when the organic to sulfate ratio of the aerosol was lowest and when winds arrived from the west after transport through the marine boundary layer.
R. Zhao, E. L. Mungall, A. K. Y. Lee, D. Aljawhary, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 9695–9706, https://doi.org/10.5194/acp-14-9695-2014, https://doi.org/10.5194/acp-14-9695-2014, 2014
M. L. McGuire, R. Y.-W. Chang, J. G. Slowik, C.-H. Jeong, R. M. Healy, G. Lu, C. Mihele, J. P. D. Abbatt, J. R. Brook, and G. J. Evans
Atmos. Chem. Phys., 14, 8017–8042, https://doi.org/10.5194/acp-14-8017-2014, https://doi.org/10.5194/acp-14-8017-2014, 2014
Y. J. Li, D. D. Huang, H. Y. Cheung, A. K. Y. Lee, and C. K. Chan
Atmos. Chem. Phys., 14, 2871–2885, https://doi.org/10.5194/acp-14-2871-2014, https://doi.org/10.5194/acp-14-2871-2014, 2014
S. Zhou, L. Gonzalez, A. Leithead, Z. Finewax, R. Thalman, A. Vlasenko, S. Vagle, L.A. Miller, S.-M. Li, S. Bureekul, H. Furutani, M. Uematsu, R. Volkamer, and J. Abbatt
Atmos. Chem. Phys., 14, 1371–1384, https://doi.org/10.5194/acp-14-1371-2014, https://doi.org/10.5194/acp-14-1371-2014, 2014
D. Aljawhary, A. K. Y. Lee, and J. P. D. Abbatt
Atmos. Meas. Tech., 6, 3211–3224, https://doi.org/10.5194/amt-6-3211-2013, https://doi.org/10.5194/amt-6-3211-2013, 2013
J. D. Yakobi-Hancock, L. A. Ladino, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 11175–11185, https://doi.org/10.5194/acp-13-11175-2013, https://doi.org/10.5194/acp-13-11175-2013, 2013
S. N. Wren, D. J. Donaldson, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 9789–9800, https://doi.org/10.5194/acp-13-9789-2013, https://doi.org/10.5194/acp-13-9789-2013, 2013
R. D. McWhinney, S. Zhou, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 9731–9744, https://doi.org/10.5194/acp-13-9731-2013, https://doi.org/10.5194/acp-13-9731-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Heterogeneous formation and light absorption of secondary organic aerosols from acetone photochemical reactions: remarkably enhancing effects of seeds and ammonia
Experimental observation of the impact of nanostructure on hygroscopicity and reactivity of fatty acid atmospheric aerosol proxies
Technical note: High-resolution analyses of concentrations and sizes of refractory black carbon particles deposited in northwestern Greenland over the past 350 years – Part 1: Continuous flow analysis of the SIGMA-D ice core using the wide-range Single-Particle Soot Photometer and a high-efficiency nebulizer
Particulate emissions from cooking: emission factors, emission dynamics, and mass spectrometric analysis for different cooking methods
Nocturnal atmospheric synergistic oxidation reduces the formation of low-volatility organic compounds from biogenic emissions
The interplay between aqueous replacement reaction and the phase state of internally mixed organic/ammonium aerosols
Measurement report: The Fifth International Workshop on Ice Nucleation phase 1 (FIN-01): intercomparison of single-particle mass spectrometers
Enhanced Sulfate Formation in Mixed Biomass Burning and Sea-salt Particles Mediated by Photosensitization: Effects of Chloride and Nitrogen-containing Compounds
Characterization of the particle size distribution, mineralogy, and Fe mode of occurrence of dust-emitting sediments from the Mojave Desert, California, USA
The lifetimes and potential change in planetary albedo owing to the oxidation of organic films extracted from atmospheric aerosol by hydroyxl (OH) radical oxidation at the air-water interface of aerosol particles
Atmospheric oxidation of 1,3-butadiene: influence of acidity and relative humidity on SOA composition and air toxic compounds
Measurement Report: Changes of ammonia emissions since the 18th century in south-eastern Europe inferred from an Elbrus (Caucasus, Russia) ice core record
Measurement report: Effects of transition metal ions on the optical properties of humic-like substances (HULIS) reveal a structural preference – a case study of PM2.5 in Beijing, China
Exometabolomic exploration of culturable airborne microorganisms from an urban atmosphere
Probing Iceland's dust-emitting sediments: particle size distribution, mineralogy, cohesion, Fe mode of occurrence, and reflectance spectra signatures
Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust
Comparison of water-soluble and water-insoluble organic compositions attributing to different light absorption efficiency between residential coal and biomass burning emissions
Suppressed atmospheric chemical aging of cooking organic aerosol particles in wintertime conditions
Formation and loss of light absorbance by phenolic aqueous SOA by ●OH and an organic triplet excited state
Technical Note: A technique to convert NO2 to NO2− with S(IV) and its application to measuring nitrate photolysis
Distribution, chemical, and molecular composition of high and low molecular weight humic-like substances in ambient aerosols
Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics
Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole
Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning
Assessment of the contribution of residential waste burning to ambient PM10 concentrations in Hungary and Romania
Source differences in the components and cytotoxicity of PM2.5 from automobile exhaust, coal combustion, and biomass burning contributing to urban aerosol toxicity
Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism
Low-temperature ice nucleation of sea spray and secondary marine aerosols under cirrus cloud conditions
Temperature-dependent aqueous OH kinetics of C2–C10 linear and terpenoid alcohols and diols: new rate coefficients, structure–activity relationship, and atmospheric lifetimes
A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides
Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles
Variability in sediment particle size, mineralogy, and Fe mode of occurrence across dust-source inland drainage basins: the case of the lower Drâa Valley, Morocco
Gas–particle partitioning of toluene oxidation products: an experimental and modeling study
Chemically speciated air pollutant emissions from open burning of household solid waste from South Africa
Bulk and molecular-level composition of primary organic aerosol from wood, straw, cow dung, and plastic burning
Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures
Molecular fingerprints and health risks of smoke from home-use incense burning
High enrichment of heavy metals in fine particulate matter through dust aerosol generation
Production of ice-nucleating particles (INPs) by fast-growing phytoplankton
Technical note: In situ measurements and modelling of the oxidation kinetics in films of a cooking aerosol proxy using a quartz crystal microbalance with dissipation monitoring (QCM-D)
Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism
Quantifying the seasonal variations in and regional transport of PM2.5 in the Yangtze River Delta region, China: characteristics, sources, and health risks
Opinion: Atmospheric multiphase chemistry – past, present, and future
Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts
Effects of storage conditions on the molecular-level composition of organic aerosol particles
Characterization of gas and particle emissions from open burning of household solid waste from South Africa
Chemically distinct particle-phase emissions from highly controlled pyrolysis of three wood types
Predicting photooxidant concentrations in aerosol liquid water based on laboratory extracts of ambient particles
Physicochemical characterization of free troposphere and marine boundary layer ice-nucleating particles collected by aircraft in the eastern North Atlantic
Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene
Si Zhang, Yining Gao, Xinbei Xu, Luyao Chen, Can Wu, Zheng Li, Rongjie Li, Binyu Xiao, Xiaodi Liu, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 14177–14190, https://doi.org/10.5194/acp-24-14177-2024, https://doi.org/10.5194/acp-24-14177-2024, 2024
Short summary
Short summary
Secondary organic aerosols (SOAs) from acetone photooxidation in the presence of various seeds were studied to illustrate SOA formation kinetics under ammonia-rich conditions. The oxidation mechanism of acetone was investigated using an observation-based model incorporating a Master Chemical Mechanism model. A higher SOA yield of acetone was observed compared to methylglyoxal due to an enhanced uptake of the small photooxidation products of acetone.
Adam Milsom, Adam M. Squires, Ben Laurence, Ben Wōden, Andrew J. Smith, Andrew D. Ward, and Christian Pfrang
Atmos. Chem. Phys., 24, 13571–13586, https://doi.org/10.5194/acp-24-13571-2024, https://doi.org/10.5194/acp-24-13571-2024, 2024
Short summary
Short summary
We followed nano-structural changes in mixtures found in urban organic aerosol emissions (oleic acid, sodium oleate and fructose) during humidity change and ozone exposure. We demonstrate that self-assembly of fatty acid nanostructures can impact water uptake and chemical reactivity, affecting atmospheric lifetimes, urban air quality (preventing harmful emissions from degradation and enabling their long-range transport) and climate (affecting cloud formation), with implications for human health.
Kumiko Goto-Azuma, Remi Dallmayr, Yoshimi Ogawa-Tsukagawa, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Motohiro Hirabayashi, Jun Ogata, Kyotaro Kitamura, Kenji Kawamura, Koji Fujita, Sumito Matoba, Naoko Nagatsuka, Akane Tsushima, Kaori Fukuda, and Teruo Aoki
Atmos. Chem. Phys., 24, 12985–13000, https://doi.org/10.5194/acp-24-12985-2024, https://doi.org/10.5194/acp-24-12985-2024, 2024
Short summary
Short summary
We developed a continuous flow analysis system to analyze an ice core from northwestern Greenland and coupled it with an improved refractory black carbon (rBC) measurement technique. This allowed accurate high-resolution analyses of size distributions and concentrations of rBC particles with diameters of 70 nm–4 μm for the past 350 years. Our results provide crucial insights into rBC's climatic effects. We also found previous ice core studies substantially underestimated rBC mass concentrations.
Julia Pikmann, Frank Drewnick, Friederike Fachinger, and Stephan Borrmann
Atmos. Chem. Phys., 24, 12295–12321, https://doi.org/10.5194/acp-24-12295-2024, https://doi.org/10.5194/acp-24-12295-2024, 2024
Short summary
Short summary
Cooking activities can contribute substantially to indoor and ambient aerosol. We performed a comprehensive study with laboratory measurements cooking 19 different dishes and ambient measurements at two Christmas markets measuring various particle properties and trace gases of emissions in real time. Similar emission characteristics were observed for dishes with the same preparation method, mainly due to similar cooking temperature and use of oil, with barbecuing as an especially strong source.
Han Zang, Zekun Luo, Chenxi Li, Ziyue Li, Dandan Huang, and Yue Zhao
Atmos. Chem. Phys., 24, 11701–11716, https://doi.org/10.5194/acp-24-11701-2024, https://doi.org/10.5194/acp-24-11701-2024, 2024
Short summary
Short summary
Atmospheric organics are subject to synergistic oxidation by different oxidants, yet the mechanisms of such processes are poorly understood. Here, using direct measurements and kinetic modeling, we probe the nocturnal synergistic-oxidation mechanism of α-pinene by O3 and NO3 radicals and in particular the fate of peroxy radical intermediates of different origins, which will deepen our understanding of the monoterpene oxidation chemistry and its contribution to atmospheric particle formation.
Hui Yang, Fengfeng Dong, Li Xia, Qishen Huang, Shufeng Pang, and Yunhong Zhang
Atmos. Chem. Phys., 24, 11619–11635, https://doi.org/10.5194/acp-24-11619-2024, https://doi.org/10.5194/acp-24-11619-2024, 2024
Short summary
Short summary
Atmospheric secondary aerosols, composed of organic and inorganic components, undergo complex reactions that impact their phase state. Using molecular spectroscopy, we showed that ammonium-promoted aqueous replacement reaction, unique to these aerosols, is closely linked to phase behavior. The interplay between reactions and aerosol phase state can cause atypical phase transition and irreversible changes in aerosol composition during hygroscopic cycles, further impacting atmospheric processes.
Xiaoli Shen, David M. Bell, Hugh Coe, Naruki Hiranuma, Fabian Mahrt, Nicholas A. Marsden, Claudia Mohr, Daniel M. Murphy, Harald Saathoff, Johannes Schneider, Jacqueline Wilson, Maria A. Zawadowicz, Alla Zelenyuk, Paul J. DeMott, Ottmar Möhler, and Daniel J. Cziczo
Atmos. Chem. Phys., 24, 10869–10891, https://doi.org/10.5194/acp-24-10869-2024, https://doi.org/10.5194/acp-24-10869-2024, 2024
Short summary
Short summary
Single-particle mass spectrometry (SPMS) is commonly used to measure the chemical composition and mixing state of aerosol particles. Intercomparison of SPMS instruments was conducted. All instruments reported similar size ranges and common spectral features. The instrument-specific detection efficiency was found to be more dependent on particle size than type. All differentiated secondary organic aerosol, soot, and soil dust but had difficulties differentiating among minerals and dusts.
Rongzhi Tang, Jialiang Ma, Ruifeng Zhang, Weizhen Cui, Yuanyuan Qin, Yangxi Chu, Yiming Qin, Alexander L. Vogel, and Chak K. Chan
EGUsphere, https://doi.org/10.5194/egusphere-2024-2633, https://doi.org/10.5194/egusphere-2024-2633, 2024
Short summary
Short summary
This study provided laboratory evidence that the photosensitizers in biomass burning extracts can enhance the sulfate formation in NaCl particles, primarily by triggering the formation of secondary oxidants under light and air, with less contribution of direct photosensitization via triplets.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Melani Hernández-Chiriboga, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert Green, Paul Ginoux, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 9155–9176, https://doi.org/10.5194/acp-24-9155-2024, https://doi.org/10.5194/acp-24-9155-2024, 2024
Short summary
Short summary
In this research, we studied the dust-emitting properties of crusts and aeolian ripples from the Mojave Desert. These properties are key to understanding the effect of dust upon climate. We found two different playa lakes according to the groundwater regime, which implies differences in crusts' cohesion state and mineralogy, which can affect the dust emission potential and properties. We also compare them with Moroccan Sahara crusts and Icelandic top sediments.
Rosalie Shepherd, Martin King, Andrew Ward, Edward Stuckey, Rebecca Welbourn, Neil Brough, Adam Milsom, Christian Pfrang, and Thomas Arnold
EGUsphere, https://doi.org/10.5194/egusphere-2024-2367, https://doi.org/10.5194/egusphere-2024-2367, 2024
Short summary
Short summary
Thin film formation at the air-water interface from material extracted from atmospheric aerosol was demonstrated, supporting core-shell morphology. The film thicknesses were approximately 10 Å and 17 Å for urban and remote extracts. Exposure to gas-phase OH radicals showed fast reactions and short lifetimes of around 1 hour. The effect on the Earth's radiative balance indicated that removing half of the film could significantly increase the top of the atmosphere albedo for urban films.
Mohammed Jaoui, Klara Nestorowicz, Krzysztof Rudzinski, Michael Lewandowski, Tadeusz Kleindienst, Julio Torres, Ewa Bulska, Witold Danikiewicz, and Rafal Szmigielski
EGUsphere, https://doi.org/10.5194/egusphere-2024-2032, https://doi.org/10.5194/egusphere-2024-2032, 2024
Short summary
Short summary
Recent research has established the contribution of 1,3-butadiene (13BD) to organic aerosol formation with negative implications to urban air quality. Health effects studies have focused on whole particulate matter but compounds responsible for adverse health effects remain uncertain. This study provides the effect of relative humidity and acidity on the chemical composition of aerosol formed from 13BD photooxidation.
Michel Legrand, Mstislav Vorobyev, Daria Bokuchava, Stanislav Kutuzov, Andreas Plach, Andreas Stohl, Alexandra Khairedinova, Vladimir Mikhalenko, Maria Vinogradova, Sabine Eckhardt, and Susanne Preunkert
EGUsphere, https://doi.org/10.5194/egusphere-2024-1381, https://doi.org/10.5194/egusphere-2024-1381, 2024
Short summary
Short summary
A record of ammonium covering the years 1750 to 2008 was extracted from a 182-meter-long ice core drilled in 2009 at Mt. Elbrus in the Caucasus, Russia. Changes in ammonia emissions in southeastern Europe during the pre-industrial and industrial periods were investigated. The level of ammonium in 1750 indicates a significant contribution of natural sources to the ammonia budget, contrasting with present-day conditions, where agricultural emissions outweigh those from biogenic sources in Europe.
Juanjuan Qin, Leiming Zhang, Yuanyuan Qin, Shaoxuan Shi, Jingnan Li, Zhao Shu, Yuwei Gao, Ting Qi, Jihua Tan, and Xinming Wang
Atmos. Chem. Phys., 24, 7575–7589, https://doi.org/10.5194/acp-24-7575-2024, https://doi.org/10.5194/acp-24-7575-2024, 2024
Short summary
Short summary
The present research unveiled that acidity dominates while transition metal ions harmonize with the light absorption properties of humic-like substances (HULIS). Cu2+ has quenching effects on HULIS by complexation, hydrogen substitution, or electrostatic adsorption, with aromatic structures of HULIS. Such effects are less pronounced if from Mn2+, Ni2+, Zn2+, and Cu2+. Oxidized HULIS might contain electron-donating groups, whereas N-containing compounds might contain electron-withdrawing groups.
Rui Jin, Wei Hu, Peimin Duan, Ming Sheng, Dandan Liu, Ziye Huang, Mutong Niu, Libin Wu, Junjun Deng, and Pingqing Fu
EGUsphere, https://doi.org/10.5194/egusphere-2024-1880, https://doi.org/10.5194/egusphere-2024-1880, 2024
Short summary
Short summary
The metabolic capacity of atmospheric microorganisms after settling into habitats is poorly understood. We studied the molecular composition of exometabolites for cultured typical airborne microbes and traced their metabolic processes. Bacteria and fungi produce highly oxidized exometabolite and have significant variations in metabolism among different strains. These insights are pivotal for assessing the biogeochemical impacts of atmospheric microorganisms following their deposition.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert O. Green, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 6883–6910, https://doi.org/10.5194/acp-24-6883-2024, https://doi.org/10.5194/acp-24-6883-2024, 2024
Short summary
Short summary
The knowledge of properties from dust emitted in high latitudes such as in Iceland is scarce. This study focuses on the particle size, mineralogy, cohesion, and iron mode of occurrence and reflectance spectra of dust-emitting sediments. Icelandic top sediments have lower cohesion state, coarser particle size, distinctive mineralogy, and 3-fold bulk Fe content, with a large presence of magnetite compared to Saharan crusts.
Wangjin Yang, Jiawei Ma, Hongxing Yang, Fu Li, and Chong Han
Atmos. Chem. Phys., 24, 6757–6768, https://doi.org/10.5194/acp-24-6757-2024, https://doi.org/10.5194/acp-24-6757-2024, 2024
Short summary
Short summary
We provide evidence that light enhances the conversion of SO2 to sulfates on non-photoactive mineral dust, where triplet states of SO2 (3SO2) can act as a pivotal trigger to generate sulfates. Photochemical sulfate formation depends on H2O, O2, and basicity of mineral dust. The SO2 photochemistry on non-photoactive mineral dust contributes to sulfates, highlighting previously unknown pathways to better explain the missing sources of atmospheric sulfates.
Lu Zhang, Jin Li, Yaojie Li, Xinlei Liu, Zhihan Luo, Guofeng Shen, and Shu Tao
Atmos. Chem. Phys., 24, 6323–6337, https://doi.org/10.5194/acp-24-6323-2024, https://doi.org/10.5194/acp-24-6323-2024, 2024
Short summary
Short summary
Brown carbon (BrC) is related to radiative forcing and climate change. The BrC fraction from residential coal and biomass burning emissions, which were the major source of BrC, was characterized at the molecular level. The CHOS aromatic compounds explained higher light absorption efficiencies of biomass burning emissions compared to coal. The unique formulas of coal combustion aerosols were characterized by higher unsaturated compounds, and such information could be used for source appointment.
Wenli Liu, Longkun He, Yingjun Liu, Keren Liao, Qi Chen, and Mikinori Kuwata
Atmos. Chem. Phys., 24, 5625–5636, https://doi.org/10.5194/acp-24-5625-2024, https://doi.org/10.5194/acp-24-5625-2024, 2024
Short summary
Short summary
Cooking is a major source of particles in urban areas. Previous studies demonstrated that the chemical lifetimes of cooking organic aerosols (COAs) were much shorter (~minutes) than the values reported by field observations (~hours). We conducted laboratory experiments to resolve the discrepancy by considering suppressed reactivity under low temperature. The parameterized k2–T relationships and observed surface temperature data were used to estimate the chemical lifetimes of COA particles.
Stephanie Arciva, Lan Ma, Camille Mavis, Chrystal Guzman, and Cort Anastasio
Atmos. Chem. Phys., 24, 4473–4485, https://doi.org/10.5194/acp-24-4473-2024, https://doi.org/10.5194/acp-24-4473-2024, 2024
Short summary
Short summary
We measured changes in light absorption during the aqueous oxidation of six phenols with hydroxyl radical (●OH) or an organic triplet excited state (3C*). All the phenols formed light-absorbing secondary brown carbon (BrC), which then decayed with continued oxidation. Extrapolation to ambient conditions suggest ●OH is the dominant sink of secondary phenolic BrC in fog/cloud drops, while 3C* controls the lifetime of this light absorption in particle water.
Aaron Lieberman, Julietta Picco, Murat Onder, and Cort Anastasio
Atmos. Chem. Phys., 24, 4411–4419, https://doi.org/10.5194/acp-24-4411-2024, https://doi.org/10.5194/acp-24-4411-2024, 2024
Short summary
Short summary
We developed a method that uses aqueous S(IV) to quantitatively convert NO2 to NO2−, which allows both species to be quantified using the Griess method. As an example of the utility of the method, we quantified both photolysis channels of nitrate, with and without a scavenger for hydroxyl radical (·OH). The results show that without a scavenger, ·OH reacts with nitrite to form nitrogen dioxide, suppressing the apparent quantum yield of NO2− and enhancing that of NO2.
Xingjun Fan, Ao Cheng, Xufang Yu, Tao Cao, Dan Chen, Wenchao Ji, Yongbing Cai, Fande Meng, Jianzhong Song, and Ping'an Peng
Atmos. Chem. Phys., 24, 3769–3783, https://doi.org/10.5194/acp-24-3769-2024, https://doi.org/10.5194/acp-24-3769-2024, 2024
Short summary
Short summary
Molecular-level characteristics of high molecular weight (HMW) and low MW (LMW) humic-like substances (HULIS) were comprehensively investigated, where HMW HULIS had larger chromophores and larger molecular size than LMW HULIS and exhibited higher aromaticity and humification. Electrospray ionization high-resolution mass spectrometry revealed more aromatic molecules in HMW HULIS. HMW HULIS had more CHON compounds, while LMW HULIS had more CHO compounds.
Daniel A. Knopf, Markus Ammann, Thomas Berkemeier, Ulrich Pöschl, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 3445–3528, https://doi.org/10.5194/acp-24-3445-2024, https://doi.org/10.5194/acp-24-3445-2024, 2024
Short summary
Short summary
The initial step of interfacial and multiphase chemical processes involves adsorption and desorption of gas species. This study demonstrates the role of desorption energy governing the residence time of the gas species at the environmental interface. A parameterization is formulated that enables the prediction of desorption energy based on the molecular weight, polarizability, and oxygen-to-carbon ratio of the desorbing chemical species. Its application to gas–particle interactions is discussed.
Feng Jiang, Kyla Siemens, Claudia Linke, Yanxia Li, Yiwei Gong, Thomas Leisner, Alexander Laskin, and Harald Saathoff
Atmos. Chem. Phys., 24, 2639–2649, https://doi.org/10.5194/acp-24-2639-2024, https://doi.org/10.5194/acp-24-2639-2024, 2024
Short summary
Short summary
We investigated the optical properties, chemical composition, and formation mechanisms of secondary organic aerosol (SOA) and brown carbon (BrC) from the oxidation of indole with and without NO2 in the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) simulation chamber. This work is one of the very few to link the optical properties and chemical composition of indole SOA with and without NO2 by simulation chamber experiments.
Evangelia Kostenidou, Baptiste Marques, Brice Temime-Roussel, Yao Liu, Boris Vansevenant, Karine Sartelet, and Barbara D'Anna
Atmos. Chem. Phys., 24, 2705–2729, https://doi.org/10.5194/acp-24-2705-2024, https://doi.org/10.5194/acp-24-2705-2024, 2024
Short summary
Short summary
Secondary organic aerosol (SOA) from gasoline vehicles can be a significant source of particulate matter in urban areas. Here the chemical composition of secondary volatile organic compounds and SOA produced by photo-oxidation of Euro 5 gasoline vehicle emissions was studied. The volatility of the SOA formed was calculated. Except for the temperature and the concentration of the aerosol, additional parameters may play a role in the gas-to-particle partitioning.
András Hoffer, Aida Meiramova, Ádám Tóth, Beatrix Jancsek-Turóczi, Gyula Kiss, Ágnes Rostási, Erika Andrea Levei, Luminita Marmureanu, Attila Machon, and András Gelencsér
Atmos. Chem. Phys., 24, 1659–1671, https://doi.org/10.5194/acp-24-1659-2024, https://doi.org/10.5194/acp-24-1659-2024, 2024
Short summary
Short summary
Specific tracer compounds identified previously in controlled test burnings of different waste types in the laboratory were detected and quantified in ambient PM10 samples collected in five Hungarian and four Romanian settlements. Back-of-the-envelope calculations based on the relative emission factors of individual tracers suggested that the contribution of solid waste burning particulate emissions to ambient PM10 mass concentrations may be as high as a few percent.
Xiao-San Luo, Weijie Huang, Guofeng Shen, Yuting Pang, Mingwei Tang, Weijun Li, Zhen Zhao, Hanhan Li, Yaqian Wei, Longjiao Xie, and Tariq Mehmood
Atmos. Chem. Phys., 24, 1345–1360, https://doi.org/10.5194/acp-24-1345-2024, https://doi.org/10.5194/acp-24-1345-2024, 2024
Short summary
Short summary
PM2.5 are air pollutants threatening health globally, but they are a mixture of chemical compositions from many sources and result in unequal toxicity. Which composition from which source of PM2.5 as the most hazardous object is a question hindering effective pollution control policy-making. With chemical and toxicity experiments, we found automobile exhaust and coal combustion to be priority emissions with higher toxic compositions for precise air pollution control, ensuring public health.
Matthew B. Goss and Jesse H. Kroll
Atmos. Chem. Phys., 24, 1299–1314, https://doi.org/10.5194/acp-24-1299-2024, https://doi.org/10.5194/acp-24-1299-2024, 2024
Short summary
Short summary
The chemistry driving dimethyl sulfide (DMS) oxidation and subsequent sulfate particle formation in the atmosphere is poorly constrained. We oxidized two related compounds (dimethyl sulfoxide and dimethyl disulfide) in the laboratory under varied NOx conditions and measured the gas- and particle-phase products. These results demonstrate that both the OH addition and OH abstraction pathways for DMS oxidation contribute to particle formation via mechanisms that do not involve the SO2 intermediate.
Ryan J. Patnaude, Kathryn A. Moore, Russell J. Perkins, Thomas C. J. Hill, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 24, 911–928, https://doi.org/10.5194/acp-24-911-2024, https://doi.org/10.5194/acp-24-911-2024, 2024
Short summary
Short summary
In this study we examined the effect of atmospheric aging on sea spray aerosols (SSAs) to form ice and how newly formed secondary marine aerosols (SMAs) may freeze at cirrus temperatures (< −38 °C). Results show that SSAs freeze at different relative humidities (RHs) depending on the temperature and that the ice-nucleating ability of SSA was not hindered by atmospheric aging. SMAs are shown to freeze at high RHs and are likely inefficient at forming ice at cirrus temperatures.
Bartłomiej Witkowski, Priyanka Jain, Beata Wileńska, and Tomasz Gierczak
Atmos. Chem. Phys., 24, 663–688, https://doi.org/10.5194/acp-24-663-2024, https://doi.org/10.5194/acp-24-663-2024, 2024
Short summary
Short summary
This article reports the results of the kinetic measurements for the aqueous oxidation of the 29 aliphatic alcohols by hydroxyl radical (OH) at different temperatures. The data acquired and the literature data were used to optimize a model for predicting the aqueous OH reactivity of alcohols and carboxylic acids and to estimate the atmospheric lifetimes of five terpenoic alcohols. The kinetic data provided new insights into the mechanism of aqueous oxidation of aliphatic molecules by the OH.
Junting Qiu, Xinlin Shen, Jiangyao Chen, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 155–166, https://doi.org/10.5194/acp-24-155-2024, https://doi.org/10.5194/acp-24-155-2024, 2024
Short summary
Short summary
We studied reactions of secondary ozonides (SOZs) with amines. SOZs formed from ozonolysis of β-caryophyllene and α-humulene are found to be reactive to ethylamine and methylamine. Products from SOZs with various conformations reacting with the same amine had different functional groups. Our findings indicate that interaction of SOZs with amines in the atmosphere is very complicated, which is potentially a hitherto unrecognized source of N-containing compound formation.
Lan Ma, Reed Worland, Laura Heinlein, Chrystal Guzman, Wenqing Jiang, Christopher Niedek, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 24, 1–21, https://doi.org/10.5194/acp-24-1-2024, https://doi.org/10.5194/acp-24-1-2024, 2024
Short summary
Short summary
We measured concentrations of three photooxidants – the hydroxyl radical, triplet excited states of organic carbon, and singlet molecular oxygen – in fine particles collected over a year. Concentrations are highest in extracts of fresh biomass burning particles, largely because they have the highest particle concentrations and highest light absorption. When normalized by light absorption, rates of formation for each oxidant are generally similar for the four particle types we observed.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Cristina Reche, Patricia Córdoba, Natalia Moreno, Andres Alastuey, Konrad Kandler, Martina Klose, Clarissa Baldo, Roger N. Clark, Zongbo Shi, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 23, 15815–15834, https://doi.org/10.5194/acp-23-15815-2023, https://doi.org/10.5194/acp-23-15815-2023, 2023
Short summary
Short summary
The effect of dust emitted from desertic surfaces upon climate and ecosystems depends on size and mineralogy, but data from soil mineral atlases of desert soils are scarce. We performed particle-size distribution, mineralogy, and Fe speciation in southern Morocco. Results show coarser particles with high quartz proportion are near the elevated areas, while in depressed areas, sizes are finer, and proportions of clays and nano-Fe oxides are higher. This difference is important for dust modelling.
Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet
Atmos. Chem. Phys., 23, 15537–15560, https://doi.org/10.5194/acp-23-15537-2023, https://doi.org/10.5194/acp-23-15537-2023, 2023
Short summary
Short summary
Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Steven Sai Hang Ho, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 15375–15393, https://doi.org/10.5194/acp-23-15375-2023, https://doi.org/10.5194/acp-23-15375-2023, 2023
Short summary
Short summary
Open burning of municipal solid waste emits chemicals that are harmful to the environment. This paper reports source profiles and emission factors for PM2.5 species and acidic/alkali gases from laboratory combustion of 10 waste categories (including plastics and biomass) that represent open burning in South Africa. Results will be useful for health and climate impact assessments, speciated emission inventories, source-oriented dispersion models, and receptor-based source apportionment.
Jun Zhang, Kun Li, Tiantian Wang, Erlend Gammelsæter, Rico K. Y. Cheung, Mihnea Surdu, Sophie Bogler, Deepika Bhattu, Dongyu S. Wang, Tianqu Cui, Lu Qi, Houssni Lamkaddam, Imad El Haddad, Jay G. Slowik, Andre S. H. Prevot, and David M. Bell
Atmos. Chem. Phys., 23, 14561–14576, https://doi.org/10.5194/acp-23-14561-2023, https://doi.org/10.5194/acp-23-14561-2023, 2023
Short summary
Short summary
We conducted burning experiments to simulate various types of solid fuel combustion, including residential burning, wildfires, agricultural burning, cow dung, and plastic bag burning. The chemical composition of the particles was characterized using mass spectrometers, and new potential markers for different fuels were identified using statistical analysis. This work improves our understanding of emissions from solid fuel burning and offers support for refined source apportionment.
Hyun Gu Kang, Yanfang Chen, Yoojin Park, Thomas Berkemeier, and Hwajin Kim
Atmos. Chem. Phys., 23, 14307–14323, https://doi.org/10.5194/acp-23-14307-2023, https://doi.org/10.5194/acp-23-14307-2023, 2023
Short summary
Short summary
D5 is an emerging anthropogenic pollutant that is ubiquitous in indoor and urban environments, and the OH oxidation of D5 forms secondary organosiloxane aerosol (SOSiA). Application of a kinetic box model that uses a volatility basis set (VBS) showed that consideration of oxidative aging (aging-VBS) predicts SOSiA formation much better than using a standard-VBS model. Ageing-dependent parameterization is needed to accurately model SOSiA to assess the implications of siloxanes for air quality.
Kai Song, Rongzhi Tang, Jingshun Zhang, Zichao Wan, Yuan Zhang, Kun Hu, Yuanzheng Gong, Daqi Lv, Sihua Lu, Yu Tan, Ruifeng Zhang, Ang Li, Shuyuan Yan, Shichao Yan, Baoming Fan, Wenfei Zhu, Chak K. Chan, Maosheng Yao, and Song Guo
Atmos. Chem. Phys., 23, 13585–13595, https://doi.org/10.5194/acp-23-13585-2023, https://doi.org/10.5194/acp-23-13585-2023, 2023
Short summary
Short summary
Incense burning is common in Asia, posing threats to human health and air quality. However, less is known about its emissions and health risks. Full-volatility organic species from incense-burning smoke are detected and quantified. Intermediate-volatility volatile organic compounds (IVOCs) are crucial organics accounting for 19.2 % of the total emission factors (EFs) and 40.0 % of the secondary organic aerosol (SOA) estimation, highlighting the importance of incorporating IVOCs into SOA models.
Qianqian Gao, Shengqiang Zhu, Kaili Zhou, Jinghao Zhai, Shaodong Chen, Qihuang Wang, Shurong Wang, Jin Han, Xiaohui Lu, Hong Chen, Liwu Zhang, Lin Wang, Zimeng Wang, Xin Yang, Qi Ying, Hongliang Zhang, Jianmin Chen, and Xiaofei Wang
Atmos. Chem. Phys., 23, 13049–13060, https://doi.org/10.5194/acp-23-13049-2023, https://doi.org/10.5194/acp-23-13049-2023, 2023
Short summary
Short summary
Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Dust aerosols are mainly generated by wind erosion, which may have some chemical selectivity. Mn, Cd and Pb were found to be highly enriched in fine-dust (PM2.5) aerosols. In addition, estimation of heavy metal emissions from dust generation by air quality models may have errors without using proper dust profiles.
Daniel C. O. Thornton, Sarah D. Brooks, Elise K. Wilbourn, Jessica Mirrielees, Alyssa N. Alsante, Gerardo Gold-Bouchot, Andrew Whitesell, and Kiana McFadden
Atmos. Chem. Phys., 23, 12707–12729, https://doi.org/10.5194/acp-23-12707-2023, https://doi.org/10.5194/acp-23-12707-2023, 2023
Short summary
Short summary
A major uncertainty in our understanding of clouds and climate is the sources and properties of the aerosol on which clouds grow. We found that aerosol containing organic matter from fast-growing marine phytoplankton was a source of ice-nucleating particles (INPs). INPs facilitate freezing of ice crystals at warmer temperatures than otherwise possible and therefore change cloud formation and properties. Our results show that ecosystem processes and the properties of sea spray aerosol are linked.
Adam Milsom, Shaojun Qi, Ashmi Mishra, Thomas Berkemeier, Zhenyu Zhang, and Christian Pfrang
Atmos. Chem. Phys., 23, 10835–10843, https://doi.org/10.5194/acp-23-10835-2023, https://doi.org/10.5194/acp-23-10835-2023, 2023
Short summary
Short summary
Aerosols and films are found indoors and outdoors. Our study measures and models reactions of a cooking aerosol proxy with the atmospheric oxidant ozone relying on a low-cost but sensitive technique based on mass changes and film rigidity. We found that film morphology changed and film rigidity increased with evidence of surface crust formation during ozone exposure. Our modelling results demonstrate clear potential to take this robust method to the field for reaction monitoring.
Shan Zhang, Lin Du, Zhaomin Yang, Narcisse Tsona Tchinda, Jianlong Li, and Kun Li
Atmos. Chem. Phys., 23, 10809–10822, https://doi.org/10.5194/acp-23-10809-2023, https://doi.org/10.5194/acp-23-10809-2023, 2023
Short summary
Short summary
In this study, we have investigated the distinct impacts of humidity on the ozonolysis of two structurally different monoterpenes (limonene and Δ3-carene). We found that the molecular structure of precursors can largely influence the SOA formation under high RH by impacting the multi-generation reactions. Our results could advance knowledge on the roles of water content in aerosol formation and inform ongoing research on particle environmental effects and applications in models.
Yangzhihao Zhan, Min Xie, Wei Zhao, Tijian Wang, Da Gao, Pulong Chen, Jun Tian, Kuanguang Zhu, Shu Li, Bingliang Zhuang, Mengmeng Li, Yi Luo, and Runqi Zhao
Atmos. Chem. Phys., 23, 9837–9852, https://doi.org/10.5194/acp-23-9837-2023, https://doi.org/10.5194/acp-23-9837-2023, 2023
Short summary
Short summary
Although the main source contribution of pollution is secondary inorganic aerosols in Nanjing, health risks mainly come from industry sources and vehicle emissions. Therefore, the development of megacities should pay more attention to the health burden of vehicle emissions, coal combustion, and industrial processes. This study provides new insight into assessing the relationship between source apportionment and health risks and can provide valuable insight into air pollution strategies.
Jonathan P. D. Abbatt and A. R. Ravishankara
Atmos. Chem. Phys., 23, 9765–9785, https://doi.org/10.5194/acp-23-9765-2023, https://doi.org/10.5194/acp-23-9765-2023, 2023
Short summary
Short summary
With important climate and air quality impacts, atmospheric multiphase chemistry involves gas interactions with aerosol particles and cloud droplets. We summarize the status of the field and discuss potential directions for future growth. We highlight the importance of a molecular-level understanding of the chemistry, along with atmospheric field studies and modeling, and emphasize the necessity for atmospheric multiphase chemists to interact widely with scientists from neighboring disciplines.
Zhancong Liang, Zhihao Cheng, Ruifeng Zhang, Yiming Qin, and Chak K. Chan
Atmos. Chem. Phys., 23, 9585–9595, https://doi.org/10.5194/acp-23-9585-2023, https://doi.org/10.5194/acp-23-9585-2023, 2023
Short summary
Short summary
In this study, we found that the photolysis of sodium nitrate leads to a much quicker decay of free amino acids (FAAs, with glycine as an example) in the particle phase than ammonium nitrate photolysis, which is likely due to the molecular interactions between FAAs and different nitrate salts. Since sodium nitrate likely co-exists with FAAs in the coarse-mode particles, particulate nitrate photolysis can possibly contribute to a rapid decay of FAAs and affect atmospheric nitrogen cycling.
Julian Resch, Kate Wolfer, Alexandre Barth, and Markus Kalberer
Atmos. Chem. Phys., 23, 9161–9171, https://doi.org/10.5194/acp-23-9161-2023, https://doi.org/10.5194/acp-23-9161-2023, 2023
Short summary
Short summary
Detailed chemical analysis of organic aerosols is necessary to better understand their effects on climate and health. Aerosol samples are often stored for days to months before analysis. We examined the effects of storage conditions (i.e., time, temperature, and aerosol storage on filters or as solvent extracts) on composition and found significant changes in the concentration of individual compounds, indicating that sample storage can strongly affect the detailed chemical particle composition.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 8921–8937, https://doi.org/10.5194/acp-23-8921-2023, https://doi.org/10.5194/acp-23-8921-2023, 2023
Short summary
Short summary
Open burning of household and municipal solid waste is a common practice in developing countries and is a significant source of air pollution. However, few studies have measured emissions from open burning of waste. This study determined gas and particulate emissions from open burning of 10 types of household solid-waste materials. These results can improve emission inventories, air quality management, and assessment of the health and climate effects of open burning of household waste.
Anita M. Avery, Mariam Fawaz, Leah R. Williams, Tami Bond, and Timothy B. Onasch
Atmos. Chem. Phys., 23, 8837–8854, https://doi.org/10.5194/acp-23-8837-2023, https://doi.org/10.5194/acp-23-8837-2023, 2023
Short summary
Short summary
Pyrolysis is the thermal decomposition of fuels like wood which occurs during combustion or as an isolated process. During combustion, some pyrolysis products are emitted directly, while others are oxidized in the combustion process. This work describes the chemical composition of particle-phase pyrolysis products in order to investigate both the uncombusted emissions from wildfires and the fuel that participates in combustion.
Lan Ma, Reed Worland, Wenqing Jiang, Christopher Niedek, Chrystal Guzman, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 23, 8805–8821, https://doi.org/10.5194/acp-23-8805-2023, https://doi.org/10.5194/acp-23-8805-2023, 2023
Short summary
Short summary
Although photooxidants are important in airborne particles, little is known of their concentrations. By measuring oxidants in a series of particle dilutions, we predict their concentrations in aerosol liquid water (ALW). We find •OH concentrations in ALW are on the order of 10−15 M, similar to their cloud/fog values, while oxidizing triplet excited states and singlet molecular oxygen have ALW values of ca. 10−13 M and 10−12 M, respectively, roughly 10–100 times higher than in cloud/fog drops.
Daniel A. Knopf, Peiwen Wang, Benny Wong, Jay M. Tomlin, Daniel P. Veghte, Nurun N. Lata, Swarup China, Alexander Laskin, Ryan C. Moffet, Josephine Y. Aller, Matthew A. Marcus, and Jian Wang
Atmos. Chem. Phys., 23, 8659–8681, https://doi.org/10.5194/acp-23-8659-2023, https://doi.org/10.5194/acp-23-8659-2023, 2023
Short summary
Short summary
Ambient particle populations and associated ice-nucleating particles (INPs)
were examined from particle samples collected on board aircraft in the marine
boundary layer and free troposphere in the eastern North Atlantic during
summer and winter. Chemical imaging shows distinct differences in the
particle populations seasonally and with sampling altitudes, which are
reflected in the INP types. Freezing parameterizations are derived for
implementation in cloud-resolving and climate models.
Dandan Liu, Yun Zhang, Shujun Zhong, Shuang Chen, Qiaorong Xie, Donghuan Zhang, Qiang Zhang, Wei Hu, Junjun Deng, Libin Wu, Chao Ma, Haijie Tong, and Pingqing Fu
Atmos. Chem. Phys., 23, 8383–8402, https://doi.org/10.5194/acp-23-8383-2023, https://doi.org/10.5194/acp-23-8383-2023, 2023
Short summary
Short summary
Based on ultra-high-resolution mass spectrometry analysis, we found that β-pinene oxidation-derived highly oxygenated organic molecules (HOMs) exhibit higher yield at high ozone concentration, while limonene oxidation-derived HOMs exhibit higher yield at moderate ozone concentration. The distinct molecular response of HOMs and low-volatile species in different biogenic secondary organic aerosols to ozone concentrations provides a new clue for more accurate air quality prediction and management.
Cited articles
Allen, J., Balcavage, W., Ramachandran, B., and Shrout, A.: Determination of Henry's law constants by equilibrium partitioning in a closed system using a new in situ optical absorbance method, Environ. Toxicol. Chem., 17, 1216–1221, 1998.
Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud methylglyoxal reactions: Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ., 42, 1476–1490, 2008.
Arellanes, C., Paulson, S., Fine, P., and Sioutas, C.: Exceeding of Henry's law by hydrogen peroxide associated with urban aerosols, Environ. Sci. Technol., 40, 4859–4866, 2006.
Atkinson, R.: Gas-Phase Tropospheric Chemistry of Organic-Compounds - a Review, Atmos. Environ. Part A, 24, 1–41, 1990.
Bachmann, K., Hauptmann, J., Polzer, J. ,and Schutz, P.: Determination of Organic Alkyl-Hydroperoxide and 1-Hydroxy Hydroperoxide with Chemiluminescence, Fluorescence and GC/MS, Fresenius J. Anal. Chem., 342, 809–812, 1992.
Betterton, E. A. and Hoffmann, M. R.: Henry law constants of some environmentally important aldehydes, Environ. Sci. Technol., 22, 1415–1418, 1988.
Bonn, B., von Kuhlmann, R., and Lawrence, M.: High contribution of biogenic hydroperoxides to secondary organic aerosol formation, Geophys. Res. Lett., 31, L10108, https://doi.org/10.1029/2003GL019172, 2004.
Bruice, P. Y.: Organic chemistry, Pearson Education, Upper Saddle River, NJ, 2004.
Carlton, A. G., Turpin, B. J., Altieri, K. E., Seitzinger, S., Reff, A., Lim, H. J., and Ervens, B.: Atmospheric oxalic acid and SOA production from glyoxal: Results of aqueous photooxidation experiments, Atmos. Environ., 41, 7588–7602, 2007.
Carter, W., Darnall, K., Graham, R., Winer, A., and Pitts, J.: Reactions of C2 and C4 Alpha-Hydroxy Radicals with Oxygen, J. Phys. Chem., 83, 2305–2311, 1979.
Chen, Z. M., Wang, H. L., Zhu, L. H., Wang, C. X., Jie, C. Y., and Hua, W.: Aqueous-phase ozonolysis of methacrolein and methyl vinyl ketone: a potentially important source of atmospheric aqueous oxidants, Atmos. Chem. Phys., 8, 2255–2265, https://doi.org/10.5194/acp-8-2255-2008, 2008.
Claeys, M., Wang, W., Ion, A., Kourtchev, I., Gelencser, A., and Maenhaut, W.: Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide, Atmos. Environ., 38, 4093–4098, 2004.
Docherty, K., Wu, W., Lim, Y., and Ziemann, P.: Contributions of organic peroxides to secondary aerosol formed from reactions of monoterpenes with O3, Environ. Sci. Technol., 39, 4049–4059, 2005.
Ervens, B. and Volkamer, R.: Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles, Atmos. Chem. Phys., 10, 8219–8244, https://doi.org/10.5194/acp-10-8219-2010, 2010.
Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069–11102, https://doi.org/10.5194/acp-11-11069-2011, 2011.
Gäb, S., Turner, W., Wolff, S., Becker, K., Ruppert, L., and Brockmann, K.: Formation of Alkyl and Hydroxyalkyl Hydroperoxides on Ozonolysis in Water and in Air, Atmos. Environ., 29, 2401–2407, 1995.
Glushonok, G., Glushonok, T., and Shadyro, O.: Kinetics of equilibrium attainment between molecular glycolaldehyde structures in an aqueous solution, Kinetics and Catalysis, 41, 620–624, 2000.
Greenzaid, P., Luz, Z., and Samuel, D.: A Nuclear Magnetic Resonance Study of Reversible Hydration of Aliphatic Aldehydes and Ketones. I. Oxygen-17 and Proton Spectra and Equilibrium Constants, J. Am. Chem. Soc., 89, 749–756, 1967.
Hall, W. A. and Johnston, M. V.: Oligomer Formation Pathways in Secondary Organic Aerosol from MS and MS/MS Measurements with High Mass Accuracy and Resolving Power, J. Am. Soc. Mass Spectrom., 23, 1097–1108, 2012.
Hasson, A. and Paulson, S.: An investigation of the relationship between gas-phase and aerosol-borne hydroperoxides in urban air, J. Aerosol Sci., 34, 459–468, 2003.
Hasson, A., Orzechowska, G., and Paulson, S.: Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes 1. Ethene, trans-2-butene, and 2,3-dimethyl-2-butene, J. Geophys. Res., 106, 34131–34142, 2001.
Hasson, A., Chung, M., Kuwata, K., Converse, A., Krohn, D. and Paulson, S.: Reaction of Criegee intermediates with water vapor – An additional source of OH radicals in alkene ozonolysis?, J. Phys. Chem. A, 107, 6176–6182, 2003.
He, S. Z., Chen, Z. M., Zhang, X., Zhao, Y., Huang, D. M., Zhao, J. N., Zhu, T., Hu, M., and Zeng, L. M.: Measurement of atmospheric hydrogen peroxide and organic peroxides in Beijing before and during the 2008 Olympic Games: Chemical and physical factors influencing their concentrations, J. Geophys. Res., 115, D17307, https://doi.org/10.1029/2009JD013544, 2010.
Hellpointner, E. and Gäb, S.: Detection of methyl, hydroxymethyl and hydroxyethyl hydroperoxides in air and precipitation, Nature, 337, 631–634, 1989.
Herrmann, H., Hoffmann, D., Schaefer, T., Braeuer, P., and Tilgner, A.: Tropospheric Aqueous-Phase Free-Radical Chemistry: Radical Sources, Spectra, Reaction Kinetics and Prediction Tools, Chemphyschem, 11, 3796–3822, 2010.
Hewitt, C. and Kok, G.: Formation and Occurrence of Organic Hydroperoxides in the Troposphere – Laboratory and Field Observations, J. Atmos. Chem., 12, 181–194, 1991.
Kamboures, M. A., Nizkorodov, S. A., and Gerber, R. B.: Ultrafast photochemistry of methyl hydroperoxide on ice particles, P. Natl. Acad. Sci. USA, 107, 6600–6604, 2010.
Kooijman, P. and Ghijsen, W.: Properties and Constitution of the Peroxides Prepared by Oxidizing Propane and their Analysis, J. R. Neth. Chem. Soc., 66, 205–216, 1947.
Kroll, J. H. and Seinfeld, J. H.: Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere, Atmos. Environ., 42, 3593–3624, 2008.
Lee, M., Heikes, B., and Jacob, D.: Enhancements of hydroperoxides and formaldehyde in biomass burning impacted air and their effect on atmospheric oxidant cycles, J. Geophys. Res.-Atmos., 103, 13201–13212, 1998.
Lee, A. K., Zhao, R., Gao, S. S., and Abbatt, J. P.: Aqueous-phase OH oxidation of glyoxal: application of a novel analytical approach employing aerosol mass spectrometry and complementary off-line techniques, J. Phys. Chem. A, 115, 10517–10526, 2011.
Lee, M., Heikes, B., and O'Sullivan, D.: Hydrogen peroxide and organic hydroperoxide in the troposphere: A review, Atmos. Environ., 34, 3475–3494, 2000.
Lim, Y. B., Tan, Y., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Aqueous chemistry and its role in secondary organic aerosol (SOA) formation, Atmos. Chem. Phys., 10, 10521–10539, https://doi.org/10.5194/acp-10-10521-2010, 2010.
Lind, J., Lazrus, A., and Kok, G.: Aqueous Phase Oxidation of Sulfur(iv) by Hydrogen-Peroxide, Methylhydroperoxide, and Peroxyacetic Acid, J. Geophys. Res., 92, 4171–4177, 1987.
Liu, Y., Monod, A., Tritscher, T., Praplan, A. P., DeCarlo, P. F., Temime-Roussel, B., Quivet, E., Marchand, N., Dommen, J., and Baltensperger, U.: Aqueous phase processing of secondary organic aerosol from isoprene photooxidation, Atmos. Chem. Phys., 12, 5879–5895, https://doi.org/10.5194/acp-12-5879-2012, 2012.
Marklund, S.: Simultaneous Determination of Bis(hydroxymethyl)-Peroxide (BHMP), Hydroxymethylhydroperoxide (HMP), and H2O2 with Titanium(iv) – Equilibria between Peroxides and Stabilities of HMP and BHMP at Physiological Conditions, Acta Chem. Scand., 25, 3517–3531, 1971.
Martin, L. and Damschen, D.: Aqueous Oxidation of Sulfur-Dioxide by Hydrogen-Peroxide at Low pH, Atmos. Environ., 15, 1615–1621, 1981.
Matthews, J., Sinha, A., and Francisco, J.: Unimolecular dissociation and thermochemistry of CH3OOH, J. Chem. Phys., 122, 221101, https://doi.org/10.1063/1.1928228, 2005.
Milas, N. and Golubovic, A.: Studies in Organic Peroxides. 25. Preparation, Separation and Identification of Peroxides Derived from Methyl Ethyl Ketone and Hydrogen Peroxide, J. Am. Chem. Soc., 81, 5824–5826, 1959a.
Milas, N. and Golubovic, A.: Studies in Organic Peroxides. 26. Organic Peroxides Derived from Acetone and Hydrogen Peroxide, J. Am. Chem. Soc., 81, 6461–6462, 1959b.
Monod, A., Chevallier, E., Jolibois, R. D., Doussin, J. F., Picquet-Varrault, B., and Carlier, P.: Photooxidation of methylhydroperoxide and ethylhydroperoxide in the aqueous phase under simulated cloud droplet conditions, Atmos. Environ., 41, 2412–2426, 2007.
Neeb, P., Sauer, F., Horie, O., and Moortgat, G.: Formation of hydroxymethyl hydroperoxide and formic acid in alkene ozonolysis in the presence of water vapour, Atmos. Environ., 31, 1417–1423, 1997.
Ortiz-Montalvo, D. L., Lim, Y. B., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Volatility and Yield of Glycolaldehyde SOA Formed through Aqueous Photochemistry and Droplet Evaporation, Aerosol Sci. Technol., 46, 1002–1014, 2012.
OSullivan, D., Lee, M., Noone, B., and Heikes, B.: Henry's law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241–3247, 1996.
Perri, M. J., Seitzinger, S., and Turpin, B. J.: Secondary organic aerosol production from aqueous photooxidation of glycolaldehyde: Laboratory experiments, Atmos. Environ., 43, 1487–1497, 2009.
Polle, A. and Junkermann, W.: Inhibition of Apoplastic and Symplastic Peroxidase-Activity from Norway Spruce by the Photooxidant Hydroxymethyl Hydroperoxide, Plant Physiol., 104, 617–621, 1994.
Roehl, C. M., Marka, Z., Fry, J. L., and Wennberg, P. O.: Near-UV photolysis cross sections of CH3OOH and HOCH2OOH determined via action spectroscopy, Atmos. Chem. Phys., 7, 713–720, https://doi.org/10.5194/acp-7-713-2007, 2007.
Sakugawa, H., Kaplan, I., Tsai, W., and Cohen, Y.: Atmospheric Hydrogen-Peroxide, Environ. Sci. Technol., 24, 1452–1462, 1990.
Sander, E. G. and Jencks, W. P.: Equilibria for additions to carbonyl group, J. Am. Chem. Soc., 90, 6154–6162, 1968.
Satterfield, C. and Case, L.: Reaction of Aldehyde and Hydrogen Peroxide in Aqueous Solution – Kinetics of the Initial Reaction, Ind. Eng. Chem., 46, 998–1001, 1954.
Sauer, F., Schuster, G., Schafer, C., and Moortgat, G.: Determination of H2O2 and organic peroxides in cloud- and rain-water on the Kleiner Feldberg during FELDEX, Geophys. Res. Lett., 23, 2605–2608, 1996.
Sauer, F., Schafer, C., Neeb, P., Horie, O., and Moortgat, G.: Formation of hydrogen peroxide in the ozonolysis of isoprene and simple alkenes under humid conditions, Atmos. Environ., 33, 229–241, 1999.
Simpson, A. and Brown, S.: Purge NMR: Effective and easy solvent suppression, J. Magn. Reson., 175, 340–346, 2005.
Sorensen, P.: The reversible addition of water to glycolaldehyde in aqueous solution, Acta Chem. Scand., 26, 3357–3365, 1972.
Sorensen, P., Bruhn, K., and Lindelov, F.: Kinetics and Equilibria for Reversible Hydration of Aldehyde Group in Glyoxylic-Acid, Acta Chem. Scand. Ser. A, A 28, 162–168, 1974.
Stefan, M. I. and Bolton, J. R.: Reinvestigation of the acetone degradation mechanism in dilute aqueous solution by the UV/H2O2 process, Environ. Sci. Technol., 33, 870–873, 1999.
Tan, Y., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Effects of Precursor Concentration and Acidic Sulfate in Aqueous Glyoxal-OH Radical Oxidation and Implications for Secondary Organic Aerosol, Environ. Sci. Technol., 43, 8105–8112, 2009.
Tan, Y., Carlton, A. G., Seitzinger, S. P., and Turpin, B. J.: SOA from methylglyoxal in clouds and wet aerosols: Measurement and prediction of key products, Atmos. Environ., 44, 5218–5226, 2010.
Tang, I., Tridico, A., and Fung, K.: Thermodynamic and optical properties of sea salt aerosols, J. Geophys. Res., 102, 23269–23275, 1997.
Tobias, H. and Ziemann, P.: Thermal desorption mass spectrometric analysis of organic aerosol formed from reactions of 1-tetradecene and O3 in the presence of alcohols and carboxylic acids, Environ. Sci. Technol., 34, 2105–2115, 2000.
Valverde-Canossa, J., Wieprecht, W., Acker, K., and Moortgat, G.: H2O2 and organic peroxide measurements in an orographic cloud: The FEBUKO experiment, Atmos. Environ., 39, 4279–4290, 2005.
Volkamer, R., Ziemann, P. J., and Molina, M. J.: Secondary Organic Aerosol Formation from Acetylene (C2H2): seed effect on SOA yields due to organic photochemistry in the aerosol aqueous phase, Atmos. Chem. Phys., 9, 1907–1928, https://doi.org/10.5194/acp-9-1907-2009, 2009.
Wallace, T.: Quantitative-Analysis of a Mixture by NMR-Spectroscopy, J. Chem. Educ., 61, 1074–1074, 1984.
Wang, H. L., Huang, D., Zhang, X., Zhao, Y., and Chen, Z. M.: Understanding the aqueous phase ozonolysis of isoprene: distinct product distribution and mechanism from the gas phase reaction, Atmos. Chem. Phys., 12, 7187–7198, https://doi.org/10.5194/acp-12-7187-2012, 2012.
Wasa, T. and Musha, S.: Polarographic Behavior of Glyoxal and Its Related Compounds, Bull. Univ. Osaka Prefect. Set. A, 19, 169–180, 1970.
Yaylayan, V., Harty-Majors, S., and Ismail, A.: Investigation of the mechanism of dissociation of glycolaldehyde dimer (2,5-dihydroxy-1,4-dioxane) by FTIR spectroscopy, Carbohydr. Res., 309, 31–38, 1998.
Yee, L. D., Craven, J. S., Loza, C. L., Schilling, K. A., Ng, N. L., Canagaratna, M. R., Ziemann, P. J., Flagan, R. C., and Seinfeld, J. H.: Secondary Organic Aerosol Formation from Low-NOx Photooxidation of Dodecane: Evolution of Multigeneration Gas-Phase Chemistry and Aerosol Composition, J. Phys. Chem. A, 116, 6211–6230, 2012.
Yu, G., Bayer, A., Galloway, M., Korshavn, K., Fry, C., and Keutsch, F.: Glyoxal in Aqueous Ammonium Sulfate Solutions: Products, Kinetics and Hydration Effects, Environ. Sci. Technol., 45, 6336–6342, 2011.
Zhao, R., Lee, A. K. Y., and Abbatt, J. P. D.: Investigation of Aqueous-Phase Photooxidation of Glyoxal and Methylglyoxal by Aerosol Chemical Ionization Mass Spectrometry: Observation of Hydroxyhydroperoxide Formation, J. Phys. Chem. A, 116, 6253–6263, 2012.
Zhou, X. and Lee, Y.: Aqueous Solubility and Reaction-Kinetics of Hydroxymethyl Hydroperoxide, J. Phys. Chem., 96, 265–272, 1992.
Zhou, X. and Mopper, K.: Apparent Partition-Coefficients of 15 Carbonyl-Compounds between Air and Seawater and between Air and Fresh Water – Implications for Air Sea Exchange, Environ. Sci. Technol., 24, 1864–1869, 1990.
Ziemann, P. J. and Atkinson, R.: Kinetics, products, and mechanisms of secondary organic aerosol formation, Chem. Soc. Rev., 41, 6582–6605, 2012.
Altmetrics
Final-revised paper
Preprint