Articles | Volume 13, issue 24
https://doi.org/10.5194/acp-13-12363-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-12363-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Dec 2013
Research article |
| 18 Dec 2013
Climatology of pure tropospheric profiles and column contents of ozone and carbon monoxide using MOZAIC in the mid-northern latitudes (24° N to 50° N) from 1994 to 2009
R. M. Zbinden
Laboratoire d'Aérologie, UMR5560, CNRS and Université de Toulouse, Toulouse, France
now at: CNRM-GAME, UMR3589, Météo-France et CNRS, Toulouse, France
V. Thouret
Laboratoire d'Aérologie, UMR5560, CNRS and Université de Toulouse, Toulouse, France
P. Ricaud
CNRM-GAME, UMR3589, Météo-France et CNRS, Toulouse, France
F. Carminati
Laboratoire d'Aérologie, UMR5560, CNRS and Université de Toulouse, Toulouse, France
CNRM-GAME, UMR3589, Météo-France et CNRS, Toulouse, France
J.-P. Cammas
Laboratoire d'Aérologie, UMR5560, CNRS and Université de Toulouse, Toulouse, France
now at: OSUR, UMS3365, Université de la Réunion, Saint-Denis, La Réunion, France
P. Nédélec
Laboratoire d'Aérologie, UMR5560, CNRS and Université de Toulouse, Toulouse, France
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Maria Tsivlidou, Bastien Sauvage, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Eric Le Flochmoën, Philippe Nédélec, Valérie Thouret, Pawel Wolff, and Brice Barret
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Mathieu Ratynski, Sergey Khaykin, Alain Hauchecorne, Robin Wing, Jean-Pierre Cammas, Yann Hello, and Philippe Keckhut
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Alkuin M. Koenig, Olivier Magand, Bert Verreyken, Jerome Brioude, Crist Amelynck, Niels Schoon, Aurélie Colomb, Beatriz Ferreira Araujo, Michel Ramonet, Mahesh K. Sha, Jean-Pierre Cammas, Jeroen E. Sonke, and Aurélien Dommergue
Atmos. Chem. Phys., 23, 1309–1328, https://doi.org/10.5194/acp-23-1309-2023, https://doi.org/10.5194/acp-23-1309-2023, 2023
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Hannah Clark, Yasmine Bennouna, Maria Tsivlidou, Pawel Wolff, Bastien Sauvage, Brice Barret, Eric Le Flochmoën, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, Andreas Petzold, and Valérie Thouret
Atmos. Chem. Phys., 21, 16237–16256, https://doi.org/10.5194/acp-21-16237-2021, https://doi.org/10.5194/acp-21-16237-2021, 2021
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We examined 27 years of IAGOS (In-service Aircraft for a Global Observing System) profiles at Frankfurt to see if there were unusual features during the spring of 2020 related to COVID-19 lockdowns in Europe. Increased ozone near the surface was partly linked to the reduction in emissions. Carbon monoxide decreased near the surface, but the impact of the lockdowns was offset by polluted air masses from elsewhere. There were small reductions in ozone and carbon monoxide in the free troposphere.
Gaëlle Dufour, Didier Hauglustaine, Yunjiang Zhang, Maxim Eremenko, Yann Cohen, Audrey Gaudel, Guillaume Siour, Mathieu Lachatre, Axel Bense, Bertrand Bessagnet, Juan Cuesta, Jerry Ziemke, Valérie Thouret, and Bo Zheng
Atmos. Chem. Phys., 21, 16001–16025, https://doi.org/10.5194/acp-21-16001-2021, https://doi.org/10.5194/acp-21-16001-2021, 2021
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Victor Lannuque, Bastien Sauvage, Brice Barret, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Pierre Cammas, Jean-Marc Cousin, Alain Fontaine, Eric Le Flochmoën, Philippe Nédélec, Hervé Petetin, Isabelle Pfaffenzeller, Susanne Rohs, Herman G. J. Smit, Pawel Wolff, and Valérie Thouret
Atmos. Chem. Phys., 21, 14535–14555, https://doi.org/10.5194/acp-21-14535-2021, https://doi.org/10.5194/acp-21-14535-2021, 2021
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Roeland Van Malderen, Dirk De Muer, Hugo De Backer, Deniz Poyraz, Willem W. Verstraeten, Veerle De Bock, Andy W. Delcloo, Alexander Mangold, Quentin Laffineur, Marc Allaart, Frans Fierens, and Valérie Thouret
Atmos. Chem. Phys., 21, 12385–12411, https://doi.org/10.5194/acp-21-12385-2021, https://doi.org/10.5194/acp-21-12385-2021, 2021
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The main aim of initiating measurements of the vertical distribution of the ozone concentration by means of ozonesondes attached to weather balloons at Uccle in 1969 was to improve weather forecasts. Since then, this measurement technique has barely changed, but the dense, long-term, and homogeneous Uccle dataset currently remains crucial for studying the temporal evolution of ozone from the surface to the stratosphere and is also the backbone of the validation of satellite ozone retrievals.
Romain Blot, Philippe Nedelec, Damien Boulanger, Pawel Wolff, Bastien Sauvage, Jean-Marc Cousin, Gilles Athier, Andreas Zahn, Florian Obersteiner, Dieter Scharffe, Hervé Petetin, Yasmine Bennouna, Hannah Clark, and Valérie Thouret
Atmos. Meas. Tech., 14, 3935–3951, https://doi.org/10.5194/amt-14-3935-2021, https://doi.org/10.5194/amt-14-3935-2021, 2021
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A lack of information about temporal changes in measurement uncertainties is an area of concern for long-term trend studies of the key compounds which have a direct or indirect impact on climate change. The IAGOS program has measured O3 and CO within the troposphere and lower stratosphere for more than 25 years. In this study, we demonstrated that the IAGOS database can be treated as one continuous program and is therefore appropriate for studies of long-term trends.
Yann Cohen, Virginie Marécal, Béatrice Josse, and Valérie Thouret
Geosci. Model Dev., 14, 2659–2689, https://doi.org/10.5194/gmd-14-2659-2021, https://doi.org/10.5194/gmd-14-2659-2021, 2021
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Assessing long-term chemistry–climate simulations with in situ and frequent observations near the tropopause is possible with the IAGOS commercial aircraft data set. This study presents a method that distributes the IAGOS data (ozone and CO) on a monthly model grid, limiting the impact of resolution for the evaluation of the modelled chemical fields. We applied it to the CCMI REF-C1SD simulation from the MOCAGE CTM and notably highlighted well-reproduced O3 behaviour in the lower stratosphere.
Iris-Amata Dion, Cyrille Dallet, Philippe Ricaud, Fabien Carminati, Thibaut Dauhut, and Peter Haynes
Atmos. Chem. Phys., 21, 2191–2210, https://doi.org/10.5194/acp-21-2191-2021, https://doi.org/10.5194/acp-21-2191-2021, 2021
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Ice in the tropopause has a strong radiative effect on climate. The amount of ice injected (∆IWC) up to the tropical tropopause layer has been shown to be the highest over the Maritime Continent (MC), a region that includes Indonesia. ∆IWC is studied over islands and sea of the MC. Space-borne observations of ice, precipitation and lightning are used to estimate ∆IWC and are compared to ∆IWC estimated from the ERA5 reanalyses. It is shown that Java is the area of the greatest ∆IWC over the MC.
Damien Héron, Stephanie Evan, Joris Pianezze, Thibaut Dauhut, Jerome Brioude, Karen Rosenlof, Vincent Noel, Soline Bielli, Christelle Barthe, and Jean-Pierre Cammas
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-870, https://doi.org/10.5194/acp-2020-870, 2020
Publication in ACP not foreseen
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Upward transport within tropical cyclones of water vapor from the low troposphere into the colder upper troposphere/lower stratosphere can result in the moistening of this region. Balloon observations and model simulations of tropical cyclone Enawo in the less-observed Southwest Indian Ocean (the third most tropical cyclone active region on Earth) are used to show how convective overshoots within Enawo penetrate the tropopause directly, injecting water/ice into the stratosphere.
Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Kenneth C. Aikin, Teresa Campos, Hannah Clark, Róisín Commane, Bruce Daube, Glenn W. Diskin, James W. Elkins, Ru-Shan Gao, Audrey Gaudel, Eric J. Hintsa, Bryan J. Johnson, Rigel Kivi, Kathryn McKain, Fred L. Moore, David D. Parrish, Richard Querel, Eric Ray, Ricardo Sánchez, Colm Sweeney, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Jacquelyn C. Witte, Steve C. Wofsy, and Thomas B. Ryerson
Atmos. Chem. Phys., 20, 10611–10635, https://doi.org/10.5194/acp-20-10611-2020, https://doi.org/10.5194/acp-20-10611-2020, 2020
Stephanie Evan, Jerome Brioude, Karen Rosenlof, Sean M. Davis, Holger Vömel, Damien Héron, Françoise Posny, Jean-Marc Metzger, Valentin Duflot, Guillaume Payen, Hélène Vérèmes, Philippe Keckhut, and Jean-Pierre Cammas
Atmos. Chem. Phys., 20, 10565–10586, https://doi.org/10.5194/acp-20-10565-2020, https://doi.org/10.5194/acp-20-10565-2020, 2020
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The role of deep convection in the southwest Indian Ocean (the 3rd most active tropical cyclone basin) on the composition of the tropical tropopause layer (TTL) and the climate system is less understood due to scarce observations. Balloon-borne lidar and satellite measurements in the southwest Indian Ocean were used to study tropical cyclones' influence on TTL composition. This study compares the impact of a tropical storm and cyclone on the humidification of the TTL over the SW Indian Ocean.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, and Valérie Thouret
Atmos. Chem. Phys., 20, 9915–9938, https://doi.org/10.5194/acp-20-9915-2020, https://doi.org/10.5194/acp-20-9915-2020, 2020
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We provide a statistical framework for detecting trends of multiple autocorrelated time series from sparsely sampled profile data. The result is a better and more consistent quantification of trend estimates of vertical profile data. The focus was placed on the long-term ozone time series from commercial aircraft and balloon-borne ozonesonde measurements. This framework can be applied to other trace gases in the atmosphere.
Martin Cussac, Virginie Marécal, Valérie Thouret, Béatrice Josse, and Bastien Sauvage
Atmos. Chem. Phys., 20, 9393–9417, https://doi.org/10.5194/acp-20-9393-2020, https://doi.org/10.5194/acp-20-9393-2020, 2020
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Biomass burning emissions are a major source of carbon monoxide in the atmosphere. Here, the vertical transport that these emissions can undergo until the upper troposphere is investigated, as well as their contribution to carbon monoxide concentrations. It was found that boreal forest emissions were specific to the occurrence of pyroconvection directly above the fires, whereas biomass burning emissions from other regions of the globe relied more on the occurrence of deep convection.
Damien Héron, Stéphanie Evan, Jérôme Brioude, Karen Rosenlof, Françoise Posny, Jean-Marc Metzger, and Jean-Pierre Cammas
Atmos. Chem. Phys., 20, 8611–8626, https://doi.org/10.5194/acp-20-8611-2020, https://doi.org/10.5194/acp-20-8611-2020, 2020
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Using a statistical method, summer variations (between 2013 and 2016) of ozone and water vapor are characterized in the upper troposphere above Réunion island (21° S, 55° E). It suggests a convective influence between 9 and 13 km. As deep convection is rarely observed near Réunion island, this study provides new insights on the long-range impact of deep convective outflow from the Intertropical Convergence Zone (ITCZ) on the upper troposphere over a subtropical site.
Philippe Ricaud, Massimo Del Guasta, Eric Bazile, Niramson Azouz, Angelo Lupi, Pierre Durand, Jean-Luc Attié, Dana Veron, Vincent Guidard, and Paolo Grigioni
Atmos. Chem. Phys., 20, 4167–4191, https://doi.org/10.5194/acp-20-4167-2020, https://doi.org/10.5194/acp-20-4167-2020, 2020
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Thin (~ 100 m) supercooled liquid water (SLW, water staying in liquid phase below 0 °C) clouds have been detected, analysed, and modelled over the Dome C (Concordia, Antarctica) station during the austral summer 2018–2019 using observations and meteorological analyses. The SLW clouds were observed at the top of the planetary boundary layer and the SLW content was always strongly underestimated by the model indicating an incorrect simulation of the surface energy budget of the Antarctic Plateau.
Samuel Quesada-Ruiz, Jean-Luc Attié, William A. Lahoz, Rachid Abida, Philippe Ricaud, Laaziz El Amraoui, Régina Zbinden, Andrea Piacentini, Mathieu Joly, Henk Eskes, Arjo Segers, Lyana Curier, Johan de Haan, Jukka Kujanpää, Albert Christiaan Plechelmus Oude Nijhuis, Johanna Tamminen, Renske Timmermans, and Pepijn Veefkind
Atmos. Meas. Tech., 13, 131–152, https://doi.org/10.5194/amt-13-131-2020, https://doi.org/10.5194/amt-13-131-2020, 2020
Renske Timmermans, Arjo Segers, Lyana Curier, Rachid Abida, Jean-Luc Attié, Laaziz El Amraoui, Henk Eskes, Johan de Haan, Jukka Kujanpää, William Lahoz, Albert Oude Nijhuis, Samuel Quesada-Ruiz, Philippe Ricaud, Pepijn Veefkind, and Martijn Schaap
Atmos. Chem. Phys., 19, 12811–12833, https://doi.org/10.5194/acp-19-12811-2019, https://doi.org/10.5194/acp-19-12811-2019, 2019
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We present an evaluation of the added value of the Sentinel-4 and Sentinel-5P missions for air quality analyses of NO2. For this, synthetic observations for both missions are generated and combined with a chemistry transport model. While hourly Sentinel-4 NO2 observations over Europe benefit modelled NO2 analyses throughout the entire day, daily Sentinel-5P NO2 observations with global coverage show an impact up to 3–6 h after overpass. This supports the need for a combination of missions.
Iris-Amata Dion, Philippe Ricaud, Peter Haynes, Fabien Carminati, and Thibaut Dauhut
Atmos. Chem. Phys., 19, 6459–6479, https://doi.org/10.5194/acp-19-6459-2019, https://doi.org/10.5194/acp-19-6459-2019, 2019
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Water vapour and ice cirrus clouds near the tropical tropopause layer (TTL) have a strong radiative impact on climate. Based on space-borne observations, we have developed a model linking ice in the upper troposphere from the Microwave Limb Sounder (MLS) to precipitation in the troposphere from the Tropical Rainfall Measurement Mission (TRMM). Our study quantifies the amount of ice injected into the TTL by deep convection over tropical lands and oceans by investigating the diurnal cycle of ice.
Fabien Carminati, Stefano Migliorini, Bruce Ingleby, William Bell, Heather Lawrence, Stuart Newman, James Hocking, and Andrew Smith
Atmos. Meas. Tech., 12, 83–106, https://doi.org/10.5194/amt-12-83-2019, https://doi.org/10.5194/amt-12-83-2019, 2019
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The GRUAN processor is a software developed to collocate radiosonde profiles and numerical weather prediction model fields, simulate top-of-atmosphere brightness temperature at frequencies used by space-borne instruments, and propagate the radiosonde uncertainties in that simulation. This work responds to an identified lack of metrologically traceable characterisation of uncertainties in model fields that are increasingly used for the validation and calibration of space-borne instruments.
Hervé Petetin, Bastien Sauvage, Mark Parrington, Hannah Clark, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, and Valérie Thouret
Atmos. Chem. Phys., 18, 17277–17306, https://doi.org/10.5194/acp-18-17277-2018, https://doi.org/10.5194/acp-18-17277-2018, 2018
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This study derives a climatology of the impact of biomass burning versus anthropogenic emissions on the strongest CO plumes observed in the troposphere based on a dataset of about 30 000 in situ vertical profiles, combined with Lagrangian simulations coupled to CO emission. Results demonstrate the large contribution of biomass burning to the strongest CO plumes encountered in the troposphere in many locations of the world.
Hervé Petetin, Bastien Sauvage, Herman G. J. Smit, François Gheusi, Fabienne Lohou, Romain Blot, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Marc Cousin, Philippe Nedelec, Patrick Neis, Susanne Rohs, and Valérie Thouret
Atmos. Chem. Phys., 18, 9561–9581, https://doi.org/10.5194/acp-18-9561-2018, https://doi.org/10.5194/acp-18-9561-2018, 2018
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Based on the numerous profiles available since 1994, this paper investigates the vertical stratification of ozone, carbon monoxide and relative humidity in the lower part of the troposphere (planetary boundary layer, lower free troposphere). Such a characterization of the vertical distribution of pollution is notably important for better understanding vertical exchanges and evaluating models on the vertical dimension.
Nizar Jaidan, Laaziz El Amraoui, Jean-Luc Attié, Philippe Ricaud, and François Dulac
Atmos. Chem. Phys., 18, 9351–9373, https://doi.org/10.5194/acp-18-9351-2018, https://doi.org/10.5194/acp-18-9351-2018, 2018
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The Mediterranean Basin, surrounded by three continents with diverse pollution sources, is particularly sensitive to climate change due to its location and diversity of ecosystems. In this work, we investigate the future change of surface ozone from 2000 to 2100 over this region using a set of atmospheric model outputs and ground-based observations. We also highlight how the future climate change and the increase of methane concentrations can offset the benefit of the pollution reduction policy.
Fabio Boschetti, Valerie Thouret, Greet Janssens Maenhout, Kai Uwe Totsche, Julia Marshall, and Christoph Gerbig
Atmos. Chem. Phys., 18, 9225–9241, https://doi.org/10.5194/acp-18-9225-2018, https://doi.org/10.5194/acp-18-9225-2018, 2018
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Retrieving surface–atmosphere fluxes from the combination of atmospheric observations with atmospheric transport models can benefit from combining multiple species in a single inversion. The underlying effect is that species such as CO2 and CO have partially overlapping emission patterns for given sectors and fuel types and so share part of the uncertainties, both related to the a priori knowledge of emissions, and to model–data mismatch error. We show this for airborne profile data from IAGOS.
Vanessa Brocchi, Gisèle Krysztofiak, Valéry Catoire, Jonathan Guth, Virginie Marécal, Régina Zbinden, Laaziz El Amraoui, François Dulac, and Philippe Ricaud
Atmos. Chem. Phys., 18, 6887–6906, https://doi.org/10.5194/acp-18-6887-2018, https://doi.org/10.5194/acp-18-6887-2018, 2018
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The Mediterranean Basin still suffers from a limited amount of in situ measurements for a good characterization of its environmental state. This study shows that intercontinental transport of very high CO concentrations can affect the upper Mediterranean Basin troposphere. By using modeling, 5- to 12-day eastward transport of biomass burning starting from North America and Siberia impacts the mid-troposphere of the Mediterranean Basin.
Yann Cohen, Hervé Petetin, Valérie Thouret, Virginie Marécal, Béatrice Josse, Hannah Clark, Bastien Sauvage, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 18, 5415–5453, https://doi.org/10.5194/acp-18-5415-2018, https://doi.org/10.5194/acp-18-5415-2018, 2018
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Measurements of ozone and carbon monoxide were performed during 1994–2013 around the tropopause on board commercial aircraft. Seasonal cycles and trends were calculated above eight well-sampled regions in Northern Hemisphere midlatitudes. CO shows decreasing concentrations over the last 10 years, thus reflecting the impact of the legislation on anthropogenic emissions. Ozone amounts increased over the 20 years in the upper troposphere during different seasons, depending on the longitudes.
Yannick Kangah, Philippe Ricaud, Jean-Luc Attié, Naoko Saitoh, Jérôme Vidot, Pascal Brunel, and Samuel Quesada-Ruiz
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2018-21, https://doi.org/10.5194/amt-2018-21, 2018
Revised manuscript not accepted
Bastien Sauvage, Alain Fontaine, Sabine Eckhardt, Antoine Auby, Damien Boulanger, Hervé Petetin, Ronan Paugam, Gilles Athier, Jean-Marc Cousin, Sabine Darras, Philippe Nédélec, Andreas Stohl, Solène Turquety, Jean-Pierre Cammas, and Valérie Thouret
Atmos. Chem. Phys., 17, 15271–15292, https://doi.org/10.5194/acp-17-15271-2017, https://doi.org/10.5194/acp-17-15271-2017, 2017
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We provide the scientific community with a SOFT-IO tool based on the coupling of Lagrangian modeling with emission inventories and aircraft CO measurements, which is able to calculate the contribution of the sources and geographical origins of CO measurements, with good performances. Calculated CO added-value products will help scientists in interpreting large IAGOS CO data set. SOFT-IO could further be applied to other CO data sets or used to help validate emission inventories.
Uri Dayan, Philippe Ricaud, Régina Zbinden, and François Dulac
Atmos. Chem. Phys., 17, 13233–13263, https://doi.org/10.5194/acp-17-13233-2017, https://doi.org/10.5194/acp-17-13233-2017, 2017
Florian Berkes, Patrick Neis, Martin G. Schultz, Ulrich Bundke, Susanne Rohs, Herman G. J. Smit, Andreas Wahner, Paul Konopka, Damien Boulanger, Philippe Nédélec, Valerie Thouret, and Andreas Petzold
Atmos. Chem. Phys., 17, 12495–12508, https://doi.org/10.5194/acp-17-12495-2017, https://doi.org/10.5194/acp-17-12495-2017, 2017
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This study highlights the importance of independent global measurements with high and long-term accuracy to quantify long-term changes, especially in the UTLS region, and to help identify inconsistencies between different data sets of observations and models. Here we investigated temperature trends over different regions within a climate-sensitive area of the atmosphere and demonstrated the value of the IAGOS temperature observations as an anchor point for the evaluation of reanalyses.
Valentin Duflot, Jean-Luc Baray, Guillaume Payen, Nicolas Marquestaut, Francoise Posny, Jean-Marc Metzger, Bavo Langerock, Corinne Vigouroux, Juliette Hadji-Lazaro, Thierry Portafaix, Martine De Mazière, Pierre-Francois Coheur, Cathy Clerbaux, and Jean-Pierre Cammas
Atmos. Meas. Tech., 10, 3359–3373, https://doi.org/10.5194/amt-10-3359-2017, https://doi.org/10.5194/amt-10-3359-2017, 2017
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, Pawan K. Bhartia, Zhaonan Cai, Marc Allaart, Gérard Ancellet, Bertrand Calpini, Gerrie J. R. Coetzee, Emilio Cuevas-Agulló, Manuel Cupeiro, Hugo De Backer, Manvendra K. Dubey, Henry E. Fuelberg, Masatomo Fujiwara, Sophie Godin-Beekmann, Tristan J. Hall, Bryan Johnson, Everette Joseph, Rigel Kivi, Bogumil Kois, Ninong Komala, Gert König-Langlo, Giovanni Laneve, Thierry Leblanc, Marion Marchand, Kenneth R. Minschwaner, Gary Morris, Michael J. Newchurch, Shin-Ya Ogino, Nozomu Ohkawara, Ankie J. M. Piters, Françoise Posny, Richard Querel, Rinus Scheele, Frank J. Schmidlin, Russell C. Schnell, Otto Schrems, Henry Selkirk, Masato Shiotani, Pavla Skrivánková, René Stübi, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Matthew B. Tully, Roeland Van Malderen, Holger Vömel, Peter von der Gathen, Jacquelyn C. Witte, and Margarita Yela
Atmos. Meas. Tech., 10, 2455–2475, https://doi.org/10.5194/amt-10-2455-2017, https://doi.org/10.5194/amt-10-2455-2017, 2017
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It is essential to understand the data quality of +10-year OMI ozone product and impacts of the “row anomaly” (RA). We validate the OMI Ozone Profile (PROFOZ) product from Oct 2004 to Dec 2014 against ozonesonde observations globally. Generally, OMI has good agreement with ozonesondes. The spatiotemporal variation of retrieval performance suggests the need to improve OMI’s radiometric calibration especially during the post-RA period to maintain the long-term stability.
Pierre Tulet, Andréa Di Muro, Aurélie Colomb, Cyrielle Denjean, Valentin Duflot, Santiago Arellano, Brice Foucart, Jérome Brioude, Karine Sellegri, Aline Peltier, Alessandro Aiuppa, Christelle Barthe, Chatrapatty Bhugwant, Soline Bielli, Patrice Boissier, Guillaume Boudoire, Thierry Bourrianne, Christophe Brunet, Fréderic Burnet, Jean-Pierre Cammas, Franck Gabarrot, Bo Galle, Gaetano Giudice, Christian Guadagno, Fréderic Jeamblu, Philippe Kowalski, Jimmy Leclair de Bellevue, Nicolas Marquestaut, Dominique Mékies, Jean-Marc Metzger, Joris Pianezze, Thierry Portafaix, Jean Sciare, Arnaud Tournigand, and Nicolas Villeneuve
Atmos. Chem. Phys., 17, 5355–5378, https://doi.org/10.5194/acp-17-5355-2017, https://doi.org/10.5194/acp-17-5355-2017, 2017
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The STRAP campaign was conducted in 2015 to investigate the volcanic plumes of Piton de La Fournaise (La Réunion, France). For the first time, measurements were conducted at the local (near the vent) and regional scales around the island. The STRAP 2015 campaign gave a unique set of multi-disciplinary data that can now be used by modellers to improve the numerical parameterisations of the physical and chemical evolution of the volcanic plumes.
Philippe Ricaud, Eric Bazile, Massimo del Guasta, Christian Lanconelli, Paolo Grigioni, and Achraf Mahjoub
Atmos. Chem. Phys., 17, 5221–5237, https://doi.org/10.5194/acp-17-5221-2017, https://doi.org/10.5194/acp-17-5221-2017, 2017
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The novelty of the paper is to combine a large set of measurements and meteorological models to study the genesis of thick cloud and diamond dust/ice fog (ice crystals) episodes above Dome C, Antarctica. The originality of the work is to attribute the presence of thick cloud and diamond dust/ice fog to advection and microphysical processes with oceanic and continental origin of air masses, respectively. Thick cloud episodes are reproduced by the models but not diamond dust/ice fog episode.
Hélène Vérèmes, Guillaume Payen, Philippe Keckhut, Valentin Duflot, Jean-Luc Baray, Jean-Pierre Cammas, Jimmy Leclair De Bellevue, Stéphanie Evan, Françoise Posny, Franck Gabarrot, Jean-Marc Metzger, Nicolas Marquestaut, Susanne Meier, Holger Vömel, and Ruud Dirksen
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2017-32, https://doi.org/10.5194/amt-2017-32, 2017
Preprint withdrawn
Rachid Abida, Jean-Luc Attié, Laaziz El Amraoui, Philippe Ricaud, William Lahoz, Henk Eskes, Arjo Segers, Lyana Curier, Johan de Haan, Jukka Kujanpää, Albert Oude Nijhuis, Johanna Tamminen, Renske Timmermans, and Pepijn Veefkind
Atmos. Chem. Phys., 17, 1081–1103, https://doi.org/10.5194/acp-17-1081-2017, https://doi.org/10.5194/acp-17-1081-2017, 2017
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A detailed Observing System Simulation Experiment is performed to quantify the impact of future satellite instrument S-5P carbon monoxide (CO) on tropospheric analyses and forecasts. We focus on Europe for the period of northern summer 2003, when there was a severe heat wave episode. S-5P is able to capture the CO from forest fires that occurred in Portugal. Furthermore, our results provide evidence of S-5P CO benefits for monitoring processes contributing to atmospheric pollution.
Hervé Petetin, Valérie Thouret, Alain Fontaine, Bastien Sauvage, Giles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 16, 15147–15163, https://doi.org/10.5194/acp-16-15147-2016, https://doi.org/10.5194/acp-16-15147-2016, 2016
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Ozone (O3) and carbon monoxide (CO) are two compounds of major importance in the atmosphere. In this paper we investigated their variability and trends at Frankfurt based on the MOZAIC–IAGOS dataset, a unique dataset of about 21 300 vertical profiles recorded by commercial aircraft. The CO concentrations have been decreasing since 2002, while no strong tendency is observed for O3 since 1994. However, the O3 seasonal variations are changing, with the spring maximum occurring earlier and earlier.
Swagata Payra, Philippe Ricaud, Rachid Abida, Laaziz El Amraoui, Jean-Luc Attié, Emmanuel Rivière, Fabien Carminati, and Thomas von Clarmann
Atmos. Meas. Tech., 9, 4355–4373, https://doi.org/10.5194/amt-9-4355-2016, https://doi.org/10.5194/amt-9-4355-2016, 2016
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The study deals with the budget of water vapour (H2O) at the tropical tropopause. The MOCAGE-VALENTINA assimilation tool has been used to assimilate Microwave Limb Sounder H2O space-borne measurements within the 316–5 hPa range from August 2011 to March 2013. Diagnostics are developed to assess the quality of the analyses depending on several parameters. Sensitivity studies show the improvement on the analyses when assimilating measurements of better quality, mainly over the convective areas.
Hélène Angot, Olivier Magand, Detlev Helmig, Philippe Ricaud, Boris Quennehen, Hubert Gallée, Massimo Del Guasta, Francesca Sprovieri, Nicola Pirrone, Joël Savarino, and Aurélien Dommergue
Atmos. Chem. Phys., 16, 8249–8264, https://doi.org/10.5194/acp-16-8249-2016, https://doi.org/10.5194/acp-16-8249-2016, 2016
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While the Arctic has been extensively monitored, there is still much to be learned from the Antarctic continent regarding the processes that govern the budget of atmospheric mercury species. We report here the first year-round measurements of gaseous elemental mercury (Hg(0)) in the atmosphere and in snowpack interstitial air on the East Antarctic ice sheet. The striking reactivity observed on the Antarctic plateau most likely influences the cycle of atmospheric mercury on a continental scale.
D. Dionisi, P. Keckhut, Y. Courcoux, A. Hauchecorne, J. Porteneuve, J. L. Baray, J. Leclair de Bellevue, H. Vérèmes, F. Gabarrot, G. Payen, R. Decoupes, and J. P. Cammas
Atmos. Meas. Tech., 8, 1425–1445, https://doi.org/10.5194/amt-8-1425-2015, https://doi.org/10.5194/amt-8-1425-2015, 2015
A. T. J. de Laat, I. Aben, M. Deeter, P. Nédélec, H. Eskes, J.-L. Attié, P. Ricaud, R. Abida, L. El Amraoui, and J. Landgraf
Atmos. Meas. Tech., 7, 3783–3799, https://doi.org/10.5194/amt-7-3783-2014, https://doi.org/10.5194/amt-7-3783-2014, 2014
P. Ricaud, B. Sič, L. El Amraoui, J.-L. Attié, R. Zbinden, P. Huszar, S. Szopa, J. Parmentier, N. Jaidan, M. Michou, R. Abida, F. Carminati, D. Hauglustaine, T. August, J. Warner, R. Imasu, N. Saitoh, and V.-H. Peuch
Atmos. Chem. Phys., 14, 11427–11446, https://doi.org/10.5194/acp-14-11427-2014, https://doi.org/10.5194/acp-14-11427-2014, 2014
L. El Amraoui, J.-L. Attié, P. Ricaud, W. A. Lahoz, A. Piacentini, V.-H. Peuch, J. X. Warner, R. Abida, J. Barré, and R. Zbinden
Atmos. Meas. Tech., 7, 3035–3057, https://doi.org/10.5194/amt-7-3035-2014, https://doi.org/10.5194/amt-7-3035-2014, 2014
A. M. Thompson, N. V. Balashov, J. C. Witte, J. G. R. Coetzee, V. Thouret, and F. Posny
Atmos. Chem. Phys., 14, 9855–9869, https://doi.org/10.5194/acp-14-9855-2014, https://doi.org/10.5194/acp-14-9855-2014, 2014
E. Hache, J.-L. Attié, C. Tourneur, P. Ricaud, L. Coret, W. A. Lahoz, L. El Amraoui, B. Josse, P. Hamer, J. Warner, X. Liu, K. Chance, M. Höpfner, R. Spurr, V. Natraj, S. Kulawik, A. Eldering, and J. Orphal
Atmos. Meas. Tech., 7, 2185–2201, https://doi.org/10.5194/amt-7-2185-2014, https://doi.org/10.5194/amt-7-2185-2014, 2014
F. Carminati, P. Ricaud, J.-P. Pommereau, E. Rivière, S. Khaykin, J.-L. Attié, and J. Warner
Atmos. Chem. Phys., 14, 6195–6211, https://doi.org/10.5194/acp-14-6195-2014, https://doi.org/10.5194/acp-14-6195-2014, 2014
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 7, 241–266, https://doi.org/10.5194/amt-7-241-2014, https://doi.org/10.5194/amt-7-241-2014, 2014
J. X. Warner, R. Yang, Z. Wei, F. Carminati, A. Tangborn, Z. Sun, W. Lahoz, J.-L. Attié, L. El Amraoui, and B. Duncan
Atmos. Chem. Phys., 14, 103–114, https://doi.org/10.5194/acp-14-103-2014, https://doi.org/10.5194/acp-14-103-2014, 2014
J. Warner, F. Carminati, Z. Wei, W. Lahoz, and J.-L. Attié
Atmos. Chem. Phys., 13, 12469–12479, https://doi.org/10.5194/acp-13-12469-2013, https://doi.org/10.5194/acp-13-12469-2013, 2013
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 6, 3393–3406, https://doi.org/10.5194/amt-6-3393-2013, https://doi.org/10.5194/amt-6-3393-2013, 2013
J.-L. Baray, Y. Courcoux, P. Keckhut, T. Portafaix, P. Tulet, J.-P. Cammas, A. Hauchecorne, S. Godin Beekmann, M. De Mazière, C. Hermans, F. Desmet, K. Sellegri, A. Colomb, M. Ramonet, J. Sciare, C. Vuillemin, C. Hoareau, D. Dionisi, V. Duflot, H. Vérèmes, J. Porteneuve, F. Gabarrot, T. Gaudo, J.-M. Metzger, G. Payen, J. Leclair de Bellevue, C. Barthe, F. Posny, P. Ricaud, A. Abchiche, and R. Delmas
Atmos. Meas. Tech., 6, 2865–2877, https://doi.org/10.5194/amt-6-2865-2013, https://doi.org/10.5194/amt-6-2865-2013, 2013
P. D. Kalabokas, J.-P. Cammas, V. Thouret, A. Volz-Thomas, D. Boulanger, and C. C. Repapis
Atmos. Chem. Phys., 13, 10339–10352, https://doi.org/10.5194/acp-13-10339-2013, https://doi.org/10.5194/acp-13-10339-2013, 2013
P. Huszar, H. Teyssèdre, M. Michou, A. Voldoire, D. J. L. Olivié, D. Saint-Martin, D. Cariolle, S. Senesi, D. Salas Y Melia, A. Alias, F. Karcher, P. Ricaud, and T. Halenka
Atmos. Chem. Phys., 13, 10027–10048, https://doi.org/10.5194/acp-13-10027-2013, https://doi.org/10.5194/acp-13-10027-2013, 2013
A. Inness, F. Baier, A. Benedetti, I. Bouarar, S. Chabrillat, H. Clark, C. Clerbaux, P. Coheur, R. J. Engelen, Q. Errera, J. Flemming, M. George, C. Granier, J. Hadji-Lazaro, V. Huijnen, D. Hurtmans, L. Jones, J. W. Kaiser, J. Kapsomenakis, K. Lefever, J. Leitão, M. Razinger, A. Richter, M. G. Schultz, A. J. Simmons, M. Suttie, O. Stein, J.-N. Thépaut, V. Thouret, M. Vrekoussis, C. Zerefos, and the MACC team
Atmos. Chem. Phys., 13, 4073–4109, https://doi.org/10.5194/acp-13-4073-2013, https://doi.org/10.5194/acp-13-4073-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Volatile organic compound sources and impacts in an urban Mediterranean area (Marseille, France)
Short-lived organic nitrates in a suburban temperate forest: an indication of efficient assimilation of reactive nitrogen by the biosphere?
Spatiotemporal variations in atmospheric CH4 concentrations and enhancements in northern China based on a comprehensive dataset: ground-based observations, TROPOMI data, inventory data, and inversions
Marine emissions and trade winds control the atmospheric nitrous oxide in the Galapagos Islands
Measurement report: A complex street-level air quality observation campaign in a heavy-traffic area utilizing the multivariate adaptive regression splines method for field calibration of low-cost sensors
The impact of organic nitrates on summer ozone formation in Shanghai, China
Differences in the key volatile organic compound species between their emitted and ambient concentrations in ozone formation
Mechanistic insights into chloroacetic acid production from atmospheric multiphase volatile organic compound–chlorine chemistry
Understanding summertime H2O2 chemistry in North China Plain through observations and modelling studies
Accurate elucidation of oxidation under heavy ozone pollution: a full suite of radical measurements in the chemically complex atmosphere
Carbonyl compounds from typical combustion sources: emission characteristics, influencing factors, and their contribution to ozone formation
Emissions of intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from different cumulative-mileage diesel vehicles at various ambient temperatures
Characterization of nitrous acid and its potential effects on secondary pollution in the warm season in Beijing urban areas
Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation
Diurnal, seasonal, and interannual variations in δ(18O) of atmospheric O2 and its application to evaluate natural and anthropogenic changes in oxygen, carbon, and water cycles
Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer
Atmospheric carbonyl compounds are crucial in regional ozone heavy pollution: insights from the Chengdu Plain Urban Agglomeration, China
Evaluating urban methane emissions and their attributes in a megacity, Osaka, Japan, via mobile and eddy covariance measurements
Ozone (O3) observations in Saxony, Germany for 1997–2020: Trends, modelling and implications for O3 control
Understanding summertime peroxyacetyl nitrate (PAN) formation and its relation to aerosol pollution: insights from high-resolution measurements and modeling
Measurement report: Exploring the variations in ambient BTEX in urban Europe and their environmental health implications
Seasonal air concentration variability, gas–particle partitioning, precipitation scavenging, and air–water equilibrium of organophosphate esters in southern Canada
Global Ground-based Tropospheric Ozone Measurements: Reference Data and Individual Site Trends (2000–2022) from the TOAR-II/HEGIFTOM Project
Tracing elevated abundance of CH2Cl2 in the subarctic upper troposphere to the Asian Summer Monsoon
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Hemispheric differences in ozone across the stratosphere-troposphere exchange region
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
The variations in volatile organic compounds based on the policy change for Omicron in the traffic hub of Zhengzhou
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Measurement report: Long-term measurements of surface ozone and trends in semi-natural sub-Saharan African ecosystems
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant
Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Significant influence of oxygenated volatile organic compounds on atmospheric chemistry analysis: A case study in a typical industrial city in China
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Observation and modelling of atmospheric OH and HO2 radicals at a subtropical rural site and implications for secondary pollutants
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis
Measurement report: Elevated atmospheric ammonia may promote particle pH and HONO formation – insights from the COVID-19 pandemic
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Elevated oxidized mercury in the free troposphere: analytical advances and application at a remote continental mountaintop site
Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area
Real-world emission characteristics of VOCs from typical cargo ships and their potential contributions to secondary organic aerosol and O3 under low-sulfur fuel policies
Marvin Dufresne, Thérèse Salameh, Thierry Leonardis, Grégory Gille, Alexandre Armengaud, and Stéphane Sauvage
Atmos. Chem. Phys., 25, 5977–5999, https://doi.org/10.5194/acp-25-5977-2025, https://doi.org/10.5194/acp-25-5977-2025, 2025
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This paper discusses the 18-month-long measurement of non-methane hydrocarbons (NMHCs) in Marseille, where there was no measurement since early 2000, despite the impact of NMHCs on air quality and climate. Traffic-related sources are the largest contributor to NMHC concentrations in Marseille, and shipping strongly contributes to the formation of aerosols. Finally, the Covid-19 lockdown had an impact on NMHC concentrations, reaching a 50 % decrease for traffic-related sources.
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 25, 5893–5909, https://doi.org/10.5194/acp-25-5893-2025, https://doi.org/10.5194/acp-25-5893-2025, 2025
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Measurements and modelling of reactive nitrogen gases observed in a suburban temperate forest in Rambouillet, France, circa 50 km southwest of Paris in 2022 indicate that the biosphere rapidly scavenges organic nitrates of mixed biogenic and anthropogenic origin, resulting in short lifetimes for, for example, alkyl nitrates and peroxy nitrates.
Pengfei Han, Ning Zeng, Bo Yao, Wen Zhang, Weijun Quan, Pucai Wang, Ting Wang, Minqiang Zhou, Qixiang Cai, Yuzhong Zhang, Ruosi Liang, Wanqi Sun, and Shengxiang Liu
Atmos. Chem. Phys., 25, 4965–4988, https://doi.org/10.5194/acp-25-4965-2025, https://doi.org/10.5194/acp-25-4965-2025, 2025
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Methane (CH4) is a potent greenhouse gas. Northern China contributes a large proportion of CH4 emissions, yet large observation gaps exist. Here we compiled a comprehensive dataset, which is publicly available, that includes ground-based, satellite-based, inventory, and modeling results to show the CH4 concentrations, enhancements, and spatial–temporal variations. The data can benefit the research community and policy-makers for future observations, atmospheric inversions, and policy-making.
Timur Cinay, Dickon Young, Nazaret Narváez Jimenez, Cristina Vintimilla-Palacios, Ariel Pila Alonso, Paul B. Krummel, William Vizuete, and Andrew R. Babbin
Atmos. Chem. Phys., 25, 4703–4718, https://doi.org/10.5194/acp-25-4703-2025, https://doi.org/10.5194/acp-25-4703-2025, 2025
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We present the initial 15 months of nitrous oxide measurements from the Galapagos Emissions Monitoring Station. The observed variability in atmospheric mole fractions during this period can be linked to several factors: seasonal variations in trade wind speed and direction across the eastern Pacific, differences in the transport history of air masses sampled, and spatiotemporal heterogeneity in regional marine nitrous oxide emissions from the coastal upwelling systems of Peru and Chile.
Petra Bauerová, Josef Keder, Adriana Šindelářová, Ondřej Vlček, William Patiño, Pavel Krč, Jan Geletič, Hynek Řezníček, Martin Bureš, Kryštof Eben, Michal Belda, Jelena Radović, Vladimír Fuka, Radek Jareš, Igor Esau, and Jaroslav Resler
Atmos. Chem. Phys., 25, 4477–4504, https://doi.org/10.5194/acp-25-4477-2025, https://doi.org/10.5194/acp-25-4477-2025, 2025
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The study explored urban air quality in Prague using low-cost sensors and highlighted the multivariate adaptive regression splines (MARS) correction method's effectiveness in enhancing accuracy. Results showed traffic's impact on nitrogen dioxide levels and atmospheric dynamics on particulate matter. The research confirmed MARS-corrected sensors as cost-effective for monitoring, despite challenges like sensor ageing and data quality control.
Chunmeng Li, Xiaorui Chen, Haichao Wang, Tianyu Zhai, Xuefei Ma, Xinping Yang, Shiyi Chen, Min Zhou, Shengrong Lou, Xin Li, Limin Zeng, and Keding Lu
Atmos. Chem. Phys., 25, 3905–3918, https://doi.org/10.5194/acp-25-3905-2025, https://doi.org/10.5194/acp-25-3905-2025, 2025
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This study reports an observation of organic nitrate (including total peroxy nitrates and total alkyl nitrates) in Shanghai, China, during the summer of 2021, by homemade thermal dissociation cavity-enhanced absorption spectroscopy (TD-CEAS; Atmos. Meas. Tech., 14, 4033–4051, 2021). The distribution of organic nitrates and their effects on local ozone production are analyzed based on field observations in conjunction with model simulations.
Xudong Zheng and Shaodong Xie
Atmos. Chem. Phys., 25, 3807–3820, https://doi.org/10.5194/acp-25-3807-2025, https://doi.org/10.5194/acp-25-3807-2025, 2025
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To reduce uncertainties in identifying the key volatile organic compounds (VOCs) in ozone (O3) formation from ambient concentrations, this study comprehensively calculates the emitted VOC concentrations during both nighttime and daytime using the nitrate radical, O3, and hydroxyl radical reaction rates and ambient VOC concentrations. Based on the emitted concentrations, isoprene is one of the top three species contributing to O3 formation, which may be overlooked in observed concentrations.
Mingxue Li, Men Xia, Chunshui Lin, Yifan Jiang, Weihang Sun, Yurun Wang, Yingnan Zhang, Maoxia He, and Tao Wang
Atmos. Chem. Phys., 25, 3753–3764, https://doi.org/10.5194/acp-25-3753-2025, https://doi.org/10.5194/acp-25-3753-2025, 2025
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Our field campaigns observed a strong diel pattern of chloroacetic acid as well as a strong correlation between its level and that of reactive chlorine species at a coastal site. Using quantum chemical calculations and box model simulation with an updated Master Chemical Mechanism, we found that the formation pathway of chloroacetic acid involved multiphase processes. Our study enhances understanding of atmospheric organic chlorine chemistry and emphasizes the importance of multiphase reactions.
Can Ye, Pengfei Liu, Chaoyang Xue, Chenglong Zhang, Zhuobiao Ma, Chengtang Liu, Junfeng Liu, Keding Lu, Yujing Mu, and Yuanhang Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-795, https://doi.org/10.5194/egusphere-2025-795, 2025
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This study investigates H2O2 chemistry in rural North China. The observed H2O2 showed distinct diurnal variations influenced by photochemical reactions. A box model revealed that H2O2 is primarily produced by HO2 recombination and removed mainly via particle uptake. Reductions in NOx, PM2.5, and alkanes raised H2O2 levels, while cutting alkenes, aromatics, CO, and HONO lowered them. A dual strategy focusing on VOCs and NOx control is essential to reduce both H2O2 and ozone pollution.
Renzhi Hu, Guoxian Zhang, Haotian Cai, Jingyi Guo, Keding Lu, Xin Li, Shengrong Lou, Zhaofeng Tan, Changjin Hu, Pinhua Xie, and Wenqing Liu
Atmos. Chem. Phys., 25, 3011–3028, https://doi.org/10.5194/acp-25-3011-2025, https://doi.org/10.5194/acp-25-3011-2025, 2025
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A full suite of radical measurements (OH, HO2, RO2, and kOH) was established to accurately elucidate the limitations of oxidation in a chemically complex atmosphere. Sensitivity tests revealed that the incorporation of complex processes enabled a balance in both radical concentrations and coordinate ratios, effectively addressing the deficiency in the ozone generation mechanism. The full-chain radical detection bridged the gap between the photochemistry and the intensive oxidation level.
Yanjie Lu, Xinxin Feng, Yanli Feng, Minjun Jiang, Yu Peng, Tian Chen, and Yingjun Chen
EGUsphere, https://doi.org/10.5194/egusphere-2025-131, https://doi.org/10.5194/egusphere-2025-131, 2025
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The EFs of CCs from biomass burning (BB) is an order of magnitude higher than that from on-road sources. Fuel type determines the emission characteristics and composition of CCs. The formation of CCs from solid and liquid fuel sources is respectively controlled by combustion temperature and emission standards. In addition, biomass burning and agricultural machinery sources significantly contribute to the oxidizing capacity of regional atmospheres.
Shuwen Guo, Xuan Zheng, Xiao He, Lewei Zeng, Liqiang He, Xian Wu, Yifei Dai, Zihao Huang, Ting Chen, Shupei Xiao, Yan You, Sheng Xiang, Shaojun Zhang, Jingkun Jiang, and Ye Wu
Atmos. Chem. Phys., 25, 2695–2705, https://doi.org/10.5194/acp-25-2695-2025, https://doi.org/10.5194/acp-25-2695-2025, 2025
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We considered two potential influencing factors of heavy-duty diesel vehicle emissions that are rarely mentioned in the literature: cumulative mileage and ambient temperatures. The results suggest that prolonged use of heavy-duty diesel vehicles and low ambient temperatures leads to reduced engine combustion efficiency, which in turn increases tailpipe emissions significantly.
Junling Li, Chaofan Lian, Mingyuan Liu, Hao Zhang, Yongxin Yan, Yufei Song, Chun Chen, Jiaqi Wang, Haijie Zhang, Yanqin Ren, Yucong Guo, Weigang Wang, Yisheng Xu, Hong Li, Jian Gao, and Maofa Ge
Atmos. Chem. Phys., 25, 2551–2568, https://doi.org/10.5194/acp-25-2551-2025, https://doi.org/10.5194/acp-25-2551-2025, 2025
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As a key source of hydroxyl (OH) radical, nitrous acid (HONO) has attracted much attention for its important role in the atmospheric oxidant capacity (AOC) increase. In this study, we made a comparison of the ambient levels, variation patterns, sources, and formation pathway in the warm season on the basis of continuous intensive observations at an urban site of Beijing. This work highlights the importance of HONO for the AOC in the warm season.
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, Dasa Gu, and Min Shao
Atmos. Chem. Phys., 25, 2459–2472, https://doi.org/10.5194/acp-25-2459-2025, https://doi.org/10.5194/acp-25-2459-2025, 2025
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Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were conducted based on a 325 m tall tower in urban Beijing. Vertical changes in the concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Shigeyuki Ishidoya, Satoshi Sugawara, and Atsushi Okazaki
Atmos. Chem. Phys., 25, 1965–1987, https://doi.org/10.5194/acp-25-1965-2025, https://doi.org/10.5194/acp-25-1965-2025, 2025
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The 18O/16O ratio of atmospheric oxygen, δatm(18O), is higher than that of ocean water due to isotopic effects during biospheric activities. This is known as the Dole–Morita effect, and its millennial-scale variations are recorded in ice cores. However, small variations of δatm(18O) in the present day have never been detected so far. This paper presents the first observations of diurnal, seasonal, and secular variations in δatm(18O) and applies them to evaluate oxygen, carbon, and water cycles.
Delaney B. Kilgour, Christopher M. Jernigan, Olga Garmash, Sneha Aggarwal, Shengqian Zhou, Claudia Mohr, Matt E. Salter, Joel A. Thornton, Jian Wang, Paul Zieger, and Timothy H. Bertram
Atmos. Chem. Phys., 25, 1931–1947, https://doi.org/10.5194/acp-25-1931-2025, https://doi.org/10.5194/acp-25-1931-2025, 2025
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We report simultaneous measurements of dimethyl sulfide (DMS) and hydroperoxymethyl thioformate (HPMTF) in the eastern North Atlantic. We use an observationally constrained box model to show that cloud loss is the dominant sink of HPMTF in this region over 6 weeks, resulting in large reductions in DMS-derived products that contribute to aerosol formation and growth. Our findings indicate that fast cloud processing of HPMTF must be included in global models to accurately capture the sulfur cycle.
Jiemeng Bao, Xin Zhang, Zhenhai Wu, Li Zhou, Jun Qian, Qinwen Tan, Fumo Yang, Junhui Chen, Yunfeng Li, Hefan Liu, Liqun Deng, and Hong Li
Atmos. Chem. Phys., 25, 1899–1916, https://doi.org/10.5194/acp-25-1899-2025, https://doi.org/10.5194/acp-25-1899-2025, 2025
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We studied carbonyl compounds' role in ozone pollution in the Chengdu Plain Urban Agglomeration, China. During heavy pollution in August 2019, we measured carbonyls at nine sites and analyzed their impact. Areas with higher carbonyl levels, like Chengdu, had worse ozone pollution. While their abundance matters, chemical reactions with other pollutants are the main drivers. Our findings show regional cooperation is vital to reducing ozone pollution effectively.
Masahito Ueyama, Taku Umezawa, Yukio Terao, Mark Lunt, and James Lawrence France
EGUsphere, https://doi.org/10.5194/egusphere-2024-3926, https://doi.org/10.5194/egusphere-2024-3926, 2025
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Methane (CH4) emissions were measured in Megacity Osaka, Japan, using mobile and eddy covariance methods. The CH4 emissions were much higher than those reported in local inventories, with natural gas contributing up to 74 % of the emissions. Several CH4 sources not accounted for in current inventories were identified. These results emphasize the need for more comprehensive emissions tracking in urban areas to enhance climate change mitigation efforts.
Yaru Wang, Dominik van Pinxteren, Andreas Tilgner, Erik Hans Hoffmann, Max Hell, Susanne Bastian, and Hartmut Herrmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-4202, https://doi.org/10.5194/egusphere-2024-4202, 2025
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Tropospheric ground-level ozone (O3) is a global air-quality pollutant and greenhouse gas. Long-term O3 trends from 16 stations in Saxony, Germany, were compared over three periods, revealing worsened O3 pollution over the last decade. O3 formation has been volatile organic compound (VOC)-limited at traffic and urban sites for the past 20 years. To mitigate O3 pollution, moderate nitrogen oxides and additional VOC controls, particularly in solvent use, should be prioritized in the coming years.
Baoye Hu, Naihua Chen, Rui Li, Mingqiang Huang, Jinsheng Chen, Youwei Hong, Lingling Xu, Xiaolong Fan, Mengren Li, Lei Tong, Qiuping Zheng, and Yuxiang Yang
Atmos. Chem. Phys., 25, 905–921, https://doi.org/10.5194/acp-25-905-2025, https://doi.org/10.5194/acp-25-905-2025, 2025
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Box modeling with the Master Chemical Mechanism (MCM) was used to explore summertime peroxyacetyl nitrate (PAN) formation and its link to aerosol pollution under high-ozone conditions. The MCM model is effective in the study of PAN photochemical formation and performed better during the clean period than the haze period. Machine learning analysis identified ammonia, nitrate, and fine particulate matter as the top three factors contributing to simulation bias.
Xiansheng Liu, Xun Zhang, Marvin Dufresne, Tao Wang, Lijie Wu, Rosa Lara, Roger Seco, Marta Monge, Ana Maria Yáñez-Serrano, Marie Gohy, Paul Petit, Audrey Chevalier, Marie-Pierre Vagnot, Yann Fortier, Alexia Baudic, Véronique Ghersi, Grégory Gille, Ludovic Lanzi, Valérie Gros, Leïla Simon, Heidi Héllen, Stefan Reimann, Zoé Le Bras, Michelle Jessy Müller, David Beddows, Siqi Hou, Zongbo Shi, Roy M. Harrison, William Bloss, James Dernie, Stéphane Sauvage, Philip K. Hopke, Xiaoli Duan, Taicheng An, Alastair C. Lewis, James R. Hopkins, Eleni Liakakou, Nikolaos Mihalopoulos, Xiaohu Zhang, Andrés Alastuey, Xavier Querol, and Thérèse Salameh
Atmos. Chem. Phys., 25, 625–638, https://doi.org/10.5194/acp-25-625-2025, https://doi.org/10.5194/acp-25-625-2025, 2025
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This study examines BTEX (benzene, toluene, ethylbenzene, xylenes) pollution in urban areas across seven European countries. Analyzing data from 22 monitoring sites, we found traffic and industrial activities significantly impact BTEX levels, with peaks during rush hours. The risk from BTEX exposure remains moderate, especially in high-traffic and industrial zones, highlighting the need for targeted air quality management to protect public health and improve urban air quality.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
Atmos. Chem. Phys., 25, 459–472, https://doi.org/10.5194/acp-25-459-2025, https://doi.org/10.5194/acp-25-459-2025, 2025
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Organophosphate esters are important humanmade trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation, and surface water in Canada, we explore seasonal concentration variability, gas–particle partitioning, precipitation scavenging, and the air–water equilibrium. Whereas higher summer concentrations and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas–particle partitioning is puzzling.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3736, https://doi.org/10.5194/egusphere-2024-3736, 2025
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings will provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Markus Jesswein, Valentin Lauther, Nicolas Emig, Peter Hoor, Timo Keber, Hans-Christoph Lachnitt, Linda Ort, Tanja Schuck, Johannes Strobel, Ronja Van Luijt, C. Michael Volk, Franziska Weyland, and Andreas Engel
EGUsphere, https://doi.org/10.5194/egusphere-2024-3946, https://doi.org/10.5194/egusphere-2024-3946, 2025
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The study investigates transport within the Asian Summer Monsoon, focussing on how CH2Cl2 reaches the subarctic tropopause region. Using data from the PHILEAS campaign in 2023, events with increased mixing ratios were detected. Their origin, the transport paths to the tropopause region and the potential entry into the stratosphere were analysed. The East Asian Summer Monsoon was identified as the main transport pathway, with only a small contribution to the stratosphere in the following days.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
Atmos. Chem. Phys., 24, 14191–14208, https://doi.org/10.5194/acp-24-14191-2024, https://doi.org/10.5194/acp-24-14191-2024, 2024
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Comprehensive observations of HONO and NOx fluxes were conducted over paddy fields in the Huaihe River Basin. Consecutive peaks in HONO and NO fluxes suggest a potentially enhanced release of HONO and NO due to soil tillage, whereas waterlogged soil may inhibit microbial nitrification processes following irrigation. Notably, biological processes and light-driven NO2 reactions at the surface may serve as sources of HONO and influence the local HONO budget during rotary tillage.
Rodrigo J. Seguel, Charlie Opazo, Yann Cohen, Owen R. Cooper, Laura Gallardo, Björn-Martin Sinnhuber, Florian Obersteiner, Andreas Zahn, Peter Hoor, and Susanne Rohs
EGUsphere, https://doi.org/10.5194/egusphere-2024-3719, https://doi.org/10.5194/egusphere-2024-3719, 2024
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We explored differences in ozone levels between the Northern and Southern Hemispheres in the Stratosphere-troposphere exchange region. Using unique data from a research aircraft, we found significantly lower ozone levels (with stratospheric character) in the Southern Hemisphere, especially during years of severe ozone depletion. A Sudden Stratospheric Warming event in 2019 increased Southern Hemisphere ozone levels, highlighting the relationship between atmospheric events and ozone distribution.
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yuyang Li, Yi Yuan, Junchen Guo, Yiqi Zhao, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
Atmos. Chem. Phys., 24, 13793–13810, https://doi.org/10.5194/acp-24-13793-2024, https://doi.org/10.5194/acp-24-13793-2024, 2024
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Online Vocus-PTR measurements show the compositions and seasonal variations in organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various species at a level of sub-parts per trillion (ppt) and organics with multiple oxygens (≥ 3) were observed. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens, while, in other seasons, the variations in them could be influenced by mixed sources.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
Atmos. Chem. Phys., 24, 13587–13601, https://doi.org/10.5194/acp-24-13587-2024, https://doi.org/10.5194/acp-24-13587-2024, 2024
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To gain insight into the impact of changes due to epidemic control policies, we undertook continuous online monitoring of volatile organic compounds (VOCs) at an urban site in Zhengzhou over a 2-month period. This study examines the characteristics of VOCs, their sources, and their temporal evolution. It also assesses the impact of the policy change on VOC pollution during the monitoring period, thus providing a basis for further research on VOC pollution and source control.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
Atmos. Chem. Phys., 24, 13603–13631, https://doi.org/10.5194/acp-24-13603-2024, https://doi.org/10.5194/acp-24-13603-2024, 2024
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Arctic ozone depletion events (ODEs) occur every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 24, 13151–13182, https://doi.org/10.5194/acp-24-13151-2024, https://doi.org/10.5194/acp-24-13151-2024, 2024
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Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still undersampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase is found at Zoétélé (Cameroon) and Skukuza (South Africa).
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 13199–13217, https://doi.org/10.5194/acp-24-13199-2024, https://doi.org/10.5194/acp-24-13199-2024, 2024
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Biogenic volatile organic compounds (BVOCs) and organic aerosol (OA) particles were measured online in a stressed spruce-dominated forest. OA was mainly attributed to the monoterpene oxidation products. The mixing ratios of BVOCs were higher than the values previously measured in other temperate forests. The results demonstrate that BVOCs are influenced not only by meteorology and biogenic emissions but also by local anthropogenic emissions and subsequent chemical transformation processes.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 13129–13150, https://doi.org/10.5194/acp-24-13129-2024, https://doi.org/10.5194/acp-24-13129-2024, 2024
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Jingwen Dai, Kun Zhang, Yanli Feng, Xin Yi, Rui Li, Jin Xue, Qing Li, Lishu Shi, Jiaqiang Liao, Yanan Yi, Fangting Wang, Liumei Yang, Hui Chen, Ling Huang, Jiani Tan, Yangjun Wang, and Li Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-3201, https://doi.org/10.5194/egusphere-2024-3201, 2024
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Oxygenated volatile organic compounds (OVOCs) are important ozone (O3) precursors. However, most of O3 formation analysis based on the box model (OBM) don't include OVOCs constraint To access the interference of OVOCs on O3 simulation, this study conducted field campaign and OBM analysis. The results indicates that no OVOCs constraint in the OBM can lead to overestimate of OVOCs, free radicals, and O3.
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
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Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
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We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
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We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
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Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Zhouxing Zou, Tianshu Chen, Qianjie Chen, Weihang Sun, Shichun Han, Zhuoyue Ren, Xinyi Li, Wei Song, Aoqi Ge, Qi Wang, Xiao Tian, Chenglei Pei, Xinming Wang, Yanli Zhang, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3210, https://doi.org/10.5194/egusphere-2024-3210, 2024
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We measured ambient OH and HO2 concentrations at a subtropical rural site and compared our observations with model results. During warm periods, the model overestimated the concentrations of OH and HO2, leading to overestimation of ozone and nitric acid production. Our findings highlight the need to better understand how OH and HO2are formed and removed, which is important for accurate air quality and climate predictions.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
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We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
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Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
Chengzhi Xing, Cheng Liu, Chunxiang Ye, Jingkai Xue, Hongyu Wu, Xiangguang Ji, Jinping Ou, and Qihou Hu
Atmos. Chem. Phys., 24, 10093–10112, https://doi.org/10.5194/acp-24-10093-2024, https://doi.org/10.5194/acp-24-10093-2024, 2024
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We identified the contributions of ozone (O3) and nitrous acid (HONO) to the production rates of hydroxide (OH) in vertical space on the Tibetan Plateau (TP). A new insight was offered: the contributions of HONO and O3 to the production rates of OH on the TP are even greater than in lower-altitudes areas. This study enriches the understanding of vertical distribution of atmospheric components and explains the strong atmospheric oxidation capacity (AOC) on the TP.
Xinyuan Zhang, Lingling Wang, Nan Wang, Shuangliang Ma, Shenbo Wang, Ruiqin Zhang, Dong Zhang, Mingkai Wang, and Hongyu Zhang
Atmos. Chem. Phys., 24, 9885–9898, https://doi.org/10.5194/acp-24-9885-2024, https://doi.org/10.5194/acp-24-9885-2024, 2024
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This study highlights the importance of the redox reaction of NO2 with SO2 based on actual atmospheric observations. The particle pH in future China is expected to rise steadily. Consequently, this reaction could become a significant source of HONO in China. Therefore, it is crucial to coordinate the control of SO2, NOx, and NH3 emissions to avoid a rapid increase in the particle pH.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
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In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
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Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Benjamin A. Nault, Katherine R. Travis, James H. Crawford, Donald R. Blake, Pedro Campuzano-Jost, Ronald C. Cohen, Joshua P. DiGangi, Glenn S. Diskin, Samuel R. Hall, L. Gregory Huey, Jose L. Jimenez, Kyung-Eun Min, Young Ro Lee, Isobel J. Simpson, Kirk Ullmann, and Armin Wisthaler
Atmos. Chem. Phys., 24, 9573–9595, https://doi.org/10.5194/acp-24-9573-2024, https://doi.org/10.5194/acp-24-9573-2024, 2024
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Ozone (O3) is a pollutant formed from the reactions of gases emitted from various sources. In urban areas, the density of human activities can increase the O3 formation rate (P(O3)), thus impacting air quality and health. Observations collected over Seoul, South Korea, are used to constrain P(O3). A high local P(O3) was found; however, local P(O3) was partly reduced due to compounds typically ignored. These observations also provide constraints for unmeasured compounds that will impact P(O3).
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
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Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
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