Articles | Volume 25, issue 9
https://doi.org/10.5194/acp-25-4655-2025
https://doi.org/10.5194/acp-25-4655-2025
Research article
 | 
05 May 2025
Research article |  | 05 May 2025

Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids

Yuanyuan Luo, Lauri Franzon, Jiangyi Zhang, Nina Sarnela, Neil M. Donahue, Theo Kurtén, and Mikael Ehn

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Cited articles

Ahrens, J., Carlsson, P. T., Hertl, N., Olzmann, M., Pfeifle, M., Wolf, J. L., and Zeuch, T.: Infrared detection of Criegee intermediates formed during the ozonolysis of β-pinene and their reactivity towards sulfur dioxide, Angewandte Chemie International Edition, 53, 715–719, https://doi.org/10.1002/anie.201307327, 2014. 
Berndt, T., Herrmann, H., and Kurtén, T.: Direct Probing of Criegee Intermediates from Gas-Phase Ozonolysis Using Chemical Ionization Mass Spectrometry, J. Am. Chem. Soc., 139, 13387–13392, https://doi.org/10.1021/jacs.7b05849, 2017. 
Berndt, T., Mentler, B., Scholz, W., Fischer, L., Herrmann, H., Kulmala, M., and Hansel, A.: Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene, Environ. Sci. Technol., 52, 11069–11077, https://doi.org/10.1021/acs.est.8b02210, 2018. 
Chebbi, A. and Carlier, P.: Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review, Atmos. Environ., 30, 4233–4249, https://doi.org/10.1016/1352-2310(96)00102-1, 1996. 
Chhantyal-Pun, R., Davey, A., Shallcross, D. E., Percival, C. J., and Orr-Ewing, A. J.: A kinetic study of the CH2OO Criegee intermediate self-reaction, reaction with SO2 and unimolecular reaction using cavity ring-down spectroscopy, Phys. Chem. Chem. Phys., 17, 3617–3626, https://doi.org/10.1039/C4CP04198D, 2015. 
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This study explores the formation of accretion products from reactions involving highly reactive compounds, Criegee intermediates. We focused on three types of terpenes, common in nature, and their reactions with specific acids. Our findings reveal that these reactions efficiently produce expected compounds. This research enhances our understanding of how these reactions affect air quality and climate by contributing to aerosol formation, crucial for atmospheric chemistry.
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