Articles | Volume 23, issue 2
https://doi.org/10.5194/acp-23-963-2023
https://doi.org/10.5194/acp-23-963-2023
Measurement report
 | 
20 Jan 2023
Measurement report |  | 20 Jan 2023

Measurement report: Changes in light absorption and molecular composition of water-soluble humic-like substances during a winter haze bloom-decay process in Guangzhou, China

Chunlin Zou, Tao Cao, Meiju Li, Jianzhong Song, Bin Jiang, Wanglu Jia, Jun Li, Xiang Ding, Zhiqiang Yu, Gan Zhang, and Ping'an Peng

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Cited articles

An, Z., Huang, R. J., Zhang, R., Tie, X., Li, G., Cao, J., Zhou, W., Shi, Z., Han, Y., Gu, Z., and Ji, Y.: Severe haze in northern China: A synergy of anthropogenic emissions and atmospheric processes, P. Natl. Acad. Sci. USA, 116, 8657–8666, https://doi.org/10.1073/pnas.1900125116, 2019. 
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Bianco, A., Deguillaume, L., Vaitilingom, M., Nicol, E., Baray, J. L., Chaumerliac, N., and Bridoux, M.: Molecular characterization of cloud water samples collected at the Puy de Dome (France) by Fourier transform ion cyclotron resonance mass spectrometry, Environ. Sci. Technol., 52, 10275–10285, https://doi.org/10.1021/acs.est.8b01964, 2018. 
Blair, S. L., MacMillan, A. C., Drozd, G. T., Goldstein, A. H., Chu, R. K., Paša-Tolić, L., Shaw J. B., Tolić, N., Lin, P., Laskin, J., Laskin, A., and Nizkorodov, S. A.: Molecular characterization of organosulfur compounds in biodiesel and diesel fuel secondary organic aerosol. American Chemical Society, Environ. Sci. Technol., 51, 119–127, https://doi.org/10.1021/acs.est.6b03304, 2017. 
Cao, T., Li, M., Zou, C., Fan, X., Song, J., Jia, W., Yu, C., Yu, Z., and Peng, P.: Chemical composition, optical properties, and oxidative potential of water- and methanol-soluble organic compounds emitted from the combustion of biomass materials and coal, Atmos. Chem. Phys., 21, 13187–13205, https://doi.org/10.5194/acp-21-13187-2021, 2021. 
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Short summary
In this study, PM2.5 samples were obtained during a winter haze event in Guangzhou, China, and light absorption and molecular composition of humic-like substances (HULIS) were investigated by UV–Vis spectrophotometry and ultrahigh-resolution mass spectrometry. The findings obtained present some differences from the results reported in other regions of China and significantly enhanced our understanding of HULIS evolution during haze bloom-decay processes in the subtropic region of southern China.
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