Articles | Volume 22, issue 21
https://doi.org/10.5194/acp-22-14189-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-14189-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Nov 2022
Research article |
| 07 Nov 2022
| 07 Nov 2022
Satellite-derived constraints on the effect of drought stress on biogenic isoprene emissions in the southeastern US
Department of Earth and Atmospheric Sciences, University of
Houston, Houston, Texas, USA
Nan Lin
Department of Earth and Atmospheric Sciences, University of
Houston, Houston, Texas, USA
Department of Earth and Atmospheric Sciences, University of
Houston, Houston, Texas, USA
Alex Guenther
Earth System Science, University of California, Irvine, Irvine,
California, USA
Joey C. Y. Lam
Earth and Environmental Sciences Programme, Faculty of Science, The
Chinese University of Hong Kong, Hong Kong SAR, China
Amos P. K. Tai
Earth and Environmental Sciences Programme, Faculty of Science, The
Chinese University of Hong Kong, Hong Kong SAR, China
State Key Laboratory of Agrobiotechnology and Institute of
Environment, Energy and Sustainability, The Chinese University of Hong Kong,
Hong Kong SAR, China
Mark J. Potosnak
Environmental Science and Studies, DePaul University, Chicago, Illinois,
USA
Roger Seco
Institute of Environmental Assessment and Water Research
(IDAEA-CSIC), Barcelona, Spain
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This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Wei Li and Yuxuan Wang
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Preprint archived
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Enhanced rock weathering (ERW) is a CO2 removal strategy that involves applying crushed rocks (e.g., basalt) to agricultural soils. However, unintended processes within the N cycle due to soil pH changes may affect the climate benefits of C sequestration. ERW could drive changes in soil emissions of non-CO2 GHGs (N2O) and trace gases (NO and NH3) that may affect air quality. We present a new improved N cycling scheme for the land model (CLM5) to evaluate ERW effects on soil gas N emissions.
Sujan Shrestha, Shan Zhou, Manisha Mehra, Meghan Guagenti, Subin Yoon, Sergio L. Alvarez, Fangzhou Guo, Chun-Ying Chao, James H. Flynn III, Yuxuan Wang, Robert J. Griffin, Sascha Usenko, and Rebecca J. Sheesley
Atmos. Chem. Phys., 23, 10845–10867, https://doi.org/10.5194/acp-23-10845-2023, https://doi.org/10.5194/acp-23-10845-2023, 2023
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We evaluated different methods for assessing the influence of long-range transport of biomass burning (BB) plumes at a coastal site in Texas, USA. We show that the aerosol composition and optical properties exhibited good agreement, while CO and acetonitrile trends were less specific for assessing BB source influence. Our results demonstrate that the network of aerosol optical measurements can be useful for identifying the influence of aged BB plumes in anthropogenically influenced areas.
Xueying Liu, Yuxuan Wang, Shailaja Wasti, Wei Li, Ehsan Soleimanian, James Flynn, Travis Griggs, Sergio Alvarez, John T. Sullivan, Maurice Roots, Laurence Twigg, Guillaume Gronoff, Timothy Berkoff, Paul Walter, Mark Estes, Johnathan W. Hair, Taylor Shingler, Amy Jo Scarino, Marta Fenn, and Laura Judd
Geosci. Model Dev., 16, 5493–5514, https://doi.org/10.5194/gmd-16-5493-2023, https://doi.org/10.5194/gmd-16-5493-2023, 2023
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With a comprehensive suite of ground-based and airborne remote sensing measurements during the 2021 TRacking Aerosol Convection ExpeRiment – Air Quality (TRACER-AQ) campaign in Houston, this study evaluates the simulation of the planetary boundary layer (PBL) height and the ozone vertical profile by a high-resolution (1.33 km) 3-D photochemical model Weather Research and Forecasting-driven GEOS-Chem (WRF-GC).
Olivia E. Clifton, Donna Schwede, Christian Hogrefe, Jesse O. Bash, Sam Bland, Philip Cheung, Mhairi Coyle, Lisa Emberson, Johannes Flemming, Erick Fredj, Stefano Galmarini, Laurens Ganzeveld, Orestis Gazetas, Ignacio Goded, Christopher D. Holmes, László Horváth, Vincent Huijnen, Qian Li, Paul A. Makar, Ivan Mammarella, Giovanni Manca, J. William Munger, Juan L. Pérez-Camanyo, Jonathan Pleim, Limei Ran, Roberto San Jose, Sam J. Silva, Ralf Staebler, Shihan Sun, Amos P. K. Tai, Eran Tas, Timo Vesala, Tamás Weidinger, Zhiyong Wu, and Leiming Zhang
Atmos. Chem. Phys., 23, 9911–9961, https://doi.org/10.5194/acp-23-9911-2023, https://doi.org/10.5194/acp-23-9911-2023, 2023
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A primary sink of air pollutants is dry deposition. Dry deposition estimates differ across the models used to simulate atmospheric chemistry. Here, we introduce an effort to examine dry deposition schemes from atmospheric chemistry models. We provide our approach’s rationale, document the schemes, and describe datasets used to drive and evaluate the schemes. We also launch the analysis of results by evaluating against observations and identifying the processes leading to model–model differences.
Eliane Gomes Alves, Raoni Aquino Santana, Cléo Quaresma Dias-Júnior, Santiago Botía, Tyeen Taylor, Ana Maria Yáñez-Serrano, Jürgen Kesselmeier, Efstratios Bourtsoukidis, Jonathan Williams, Pedro Ivo Lembo Silveira de Assis, Giordane Martins, Rodrigo de Souza, Sérgio Duvoisin Júnior, Alex Guenther, Dasa Gu, Anywhere Tsokankunku, Matthias Sörgel, Bruce Nelson, Davieliton Pinto, Shujiro Komiya, Diogo Martins Rosa, Bettina Weber, Cybelli Barbosa, Michelle Robin, Kenneth J. Feeley, Alvaro Duque, Viviana Londoño Lemos, Maria Paula Contreras, Alvaro Idarraga, Norberto López, Chad Husby, Brett Jestrow, and Iván Mauricio Cely Toro
Atmos. Chem. Phys., 23, 8149–8168, https://doi.org/10.5194/acp-23-8149-2023, https://doi.org/10.5194/acp-23-8149-2023, 2023
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Isoprene is emitted mainly by plants and can influence atmospheric chemistry and air quality. But, there are uncertainties in model emission estimates and follow-up atmospheric processes. In our study, with long-term observational datasets of isoprene and biological and environmental factors from central Amazonia, we show that isoprene emission estimates could be improved when biological processes were mechanistically incorporated into the model.
Joey C. Y. Lam, Amos P. K. Tai, Jason A. Ducker, and Christopher D. Holmes
Geosci. Model Dev., 16, 2323–2342, https://doi.org/10.5194/gmd-16-2323-2023, https://doi.org/10.5194/gmd-16-2323-2023, 2023
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We developed a new component within an atmospheric chemistry model to better simulate plant ecophysiological processes relevant for ozone air quality. We showed that it reduces simulated biases in plant uptake of ozone in prior models. The new model enables us to explore how future climatic changes affect air quality via affecting plants, examine ozone–vegetation interactions and feedbacks, and evaluate the impacts of changing atmospheric chemistry and climate on vegetation productivity.
Lejish Vettikkat, Pasi Miettinen, Angela Buchholz, Pekka Rantala, Hao Yu, Simon Schallhart, Tuukka Petäjä, Roger Seco, Elisa Männistö, Markku Kulmala, Eeva-Stiina Tuittila, Alex B. Guenther, and Siegfried Schobesberger
Atmos. Chem. Phys., 23, 2683–2698, https://doi.org/10.5194/acp-23-2683-2023, https://doi.org/10.5194/acp-23-2683-2023, 2023
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Wetlands cover a substantial fraction of the land mass in the northern latitudes, from northern Europe to Siberia and Canada. Yet, their isoprene and terpene emissions remain understudied. Here, we used a state-of-the-art measurement technique to quantify ecosystem-scale emissions from a boreal wetland during an unusually warm spring/summer. We found that the emissions from this wetland were (a) higher and (b) even more strongly dependent on temperature than commonly thought.
Claudia Bernier, Yuxuan Wang, Guillaume Gronoff, Timothy Berkoff, K. Emma Knowland, John T. Sullivan, Ruben Delgado, Vanessa Caicedo, and Brian Carroll
Atmos. Chem. Phys., 22, 15313–15331, https://doi.org/10.5194/acp-22-15313-2022, https://doi.org/10.5194/acp-22-15313-2022, 2022
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Coastal regions are susceptible to variable and high ozone which is difficult to simulate. We developed a method to characterize large datasets of multi-dimensional measurements from lidar instruments taken in coastal regions. Using the clustered ozone groups, we evaluated model performance in simulating the coastal ozone variability vertically and diurnally. The approach allowed us to pinpoint areas where the models succeed in simulating coastal ozone and areas where there are still gaps.
Elizabeth Klovenski, Yuxuan Wang, Susanne E. Bauer, Kostas Tsigaridis, Greg Faluvegi, Igor Aleinov, Nancy Y. Kiang, Alex Guenther, Xiaoyan Jiang, Wei Li, and Nan Lin
Atmos. Chem. Phys., 22, 13303–13323, https://doi.org/10.5194/acp-22-13303-2022, https://doi.org/10.5194/acp-22-13303-2022, 2022
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Severe drought stresses vegetation and causes reduced emission of isoprene. We study the impact of including a new isoprene drought stress (yd) parameterization in NASA GISS ModelE called DroughtStress_ModelE, which is specifically tuned for ModelE. Inclusion of yd leads to better simulated isoprene emissions at the MOFLUX site during the severe drought of 2012, reduced overestimation of OMI satellite ΩHCHO (formaldehyde column), and improved simulated O3 (ozone) during drought.
Detlev Helmig, Alex Guenther, Jacques Hueber, Ryan Daly, Wei Wang, Jeong-Hoo Park, Anssi Liikanen, and Arnaud P. Praplan
Atmos. Meas. Tech., 15, 5439–5454, https://doi.org/10.5194/amt-15-5439-2022, https://doi.org/10.5194/amt-15-5439-2022, 2022
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This research demonstrates a new method for determination of the chemical reactivity of volatile organic compounds that are emitted from the leaves and needles of trees. These measurements allow elucidating if and how much of these emissions and their associated reactivity are captured and quantified by currently applicable chemical analysis methods.
Deanna C. Myers, Saewung Kim, Steven Sjostedt, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 22, 10061–10076, https://doi.org/10.5194/acp-22-10061-2022, https://doi.org/10.5194/acp-22-10061-2022, 2022
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We present the first measurements of gas-phase sulfuric acid from the Amazon basin and evaluate the efficacy of existing sulfuric acid parameterizations in this understudied region. Sulfuric acid is produced during the daytime and nighttime, though current proxies underestimate nighttime production. These results illustrate the need for better parameterizations of sulfuric acid and its precursors that are informed by measurements across a broad range of locations.
Wei Li and Yuxuan Wang
Atmos. Chem. Phys., 22, 7843–7859, https://doi.org/10.5194/acp-22-7843-2022, https://doi.org/10.5194/acp-22-7843-2022, 2022
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Fine dust is an important component of PM2.5 and can be largely modulated by droughts. In contrast to the increase in dust in the southwest USA where major dust sources are located, dust in the southeast USA is affected more by long-range transport from Africa and decreases under droughts. Both the transport and emissions of African dust are weakened when the southeast USA is under droughts, which reveals how regional-scale droughts can influence aerosol abundance through long-range transport.
Shihan Sun, Amos P. K. Tai, David H. Y. Yung, Anthony Y. H. Wong, Jason A. Ducker, and Christopher D. Holmes
Biogeosciences, 19, 1753–1776, https://doi.org/10.5194/bg-19-1753-2022, https://doi.org/10.5194/bg-19-1753-2022, 2022
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We developed and used a terrestrial biosphere model to compare and evaluate widely used empirical dry deposition schemes with different stomatal approaches and found that using photosynthesis-based stomatal approaches can reduce biases in modeled dry deposition velocities in current chemical transport models. Our study shows systematic errors in current dry deposition schemes and the importance of representing plant ecophysiological processes in models under a changing climate.
Ka Ming Fung, Maria Val Martin, and Amos P. K. Tai
Biogeosciences, 19, 1635–1655, https://doi.org/10.5194/bg-19-1635-2022, https://doi.org/10.5194/bg-19-1635-2022, 2022
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Fertilizer-induced ammonia detrimentally affects the environment by not only directly damaging ecosystems but also indirectly altering climate and soil fertility. To quantify these secondary impacts, we enabled CESM to simulate ammonia emission, chemical evolution, and deposition as a continuous cycle. If synthetic fertilizer use is to soar by 30 % from today's level, we showed that the counteracting impacts will increase the global ammonia emission by 3.3 Tg N per year.
Jiachen Zhu, Amos P. K. Tai, and Steve Hung Lam Yim
Atmos. Chem. Phys., 22, 765–782, https://doi.org/10.5194/acp-22-765-2022, https://doi.org/10.5194/acp-22-765-2022, 2022
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This study assessed O3 damage to plant and the subsequent effects on meteorology and air quality in China, whereby O3, meteorology, and vegetation can co-evolve with each other. We provided comprehensive understanding about how O3–vegetation impacts adversely affect plant growth and crop production, and contribute to global warming and severe O3 air pollution in China. Our findings clearly pinpoint the need to consider the O3 damage effects in both air quality studies and climate change studies.
Xueying Liu, Amos P. K. Tai, and Ka Ming Fung
Atmos. Chem. Phys., 21, 17743–17758, https://doi.org/10.5194/acp-21-17743-2021, https://doi.org/10.5194/acp-21-17743-2021, 2021
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With the rising food need, more intense agricultural activities will cause substantial perturbations to the nitrogen cycle, aggravating surface air pollution and imposing stress on terrestrial ecosystems. We studied how these ecosystem changes may modify biosphere–atmosphere exchanges, and further exert secondary effects on air quality, and demonstrated a link between agricultural activities and ozone air quality via the modulation of vegetation and soil biogeochemistry by nitrogen deposition.
Chinmoy Sarkar, Gracie Wong, Anne Mielnik, Sanjeevi Nagalingam, Nicole Jenna Gross, Alex B. Guenther, Taehyoung Lee, Taehyun Park, Jihee Ban, Seokwon Kang, Jin-Soo Park, Joonyoung Ahn, Danbi Kim, Hyunjae Kim, Jinsoo Choi, Beom-Keun Seo, Jong-Ho Kim, Jeong-Ho Kim, Soo Bog Park, and Saewung Kim
Atmos. Chem. Phys., 21, 11505–11518, https://doi.org/10.5194/acp-21-11505-2021, https://doi.org/10.5194/acp-21-11505-2021, 2021
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We present experimental proofs illustrating the emission of an unexplored volatile organic compound, tentatively assigned as ketene, in an industrial facility in South Korea. The emission of such a compound has rarely been reported, but our experimental data show that the emission rate is substantial. It potentially has tremendous implications for regional air quality and public health, as it is highly reactive and toxic at the same time.
Beata Opacka, Jean-François Müller, Trissevgeni Stavrakou, Maite Bauwens, Katerina Sindelarova, Jana Markova, and Alex B. Guenther
Atmos. Chem. Phys., 21, 8413–8436, https://doi.org/10.5194/acp-21-8413-2021, https://doi.org/10.5194/acp-21-8413-2021, 2021
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Isoprene is mainly emitted from plants, and about 80 % of its global emissions occur in the tropics. Current isoprene inventories are usually based on modelled vegetation maps, but high pressure on land use over the last decades has led to severe losses, especially in tropical forests, that are not considered by models. We provide a study on the present-day impact of spaceborne land cover changes on isoprene emissions and the first inventory based on high-resolution Landsat tree cover dataset.
Dianne Sanchez, Roger Seco, Dasa Gu, Alex Guenther, John Mak, Youngjae Lee, Danbi Kim, Joonyoung Ahn, Don Blake, Scott Herndon, Daun Jeong, John T. Sullivan, Thomas Mcgee, Rokjin Park, and Saewung Kim
Atmos. Chem. Phys., 21, 6331–6345, https://doi.org/10.5194/acp-21-6331-2021, https://doi.org/10.5194/acp-21-6331-2021, 2021
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We present observations of total reactive gases in a suburban forest observatory in the Seoul metropolitan area. The quantitative comparison with speciated trace gas observations illustrated significant underestimation in atmospheric reactivity from the speciated trace gas observational dataset. We present scientific discussion about potential causes.
Hui Wang, Qizhong Wu, Alex B. Guenther, Xiaochun Yang, Lanning Wang, Tang Xiao, Jie Li, Jinming Feng, Qi Xu, and Huaqiong Cheng
Atmos. Chem. Phys., 21, 4825–4848, https://doi.org/10.5194/acp-21-4825-2021, https://doi.org/10.5194/acp-21-4825-2021, 2021
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We assessed the influence of the greening trend on BVOC emission in China. The comparison among different scenarios showed that vegetation changes resulting from land cover management are the main driver of BVOC emission change in China. Climate variability contributed significantly to interannual variations but not much to the long-term trend during the study period.
Felix Leung, Karina Williams, Stephen Sitch, Amos P. K. Tai, Andy Wiltshire, Jemma Gornall, Elizabeth A. Ainsworth, Timothy Arkebauer, and David Scoby
Geosci. Model Dev., 13, 6201–6213, https://doi.org/10.5194/gmd-13-6201-2020, https://doi.org/10.5194/gmd-13-6201-2020, 2020
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Ground-level ozone (O3) is detrimental to plant productivity and crop yield. Currently, the Joint UK Land Environment Simulator (JULES) includes a representation of crops (JULES-crop). The parameters for O3 damage in soybean in JULES-crop were calibrated against photosynthesis measurements from the Soybean Free Air Concentration Enrichment (SoyFACE). The result shows good performance for yield, and it helps contribute to understanding of the impacts of climate and air pollution on food security.
Roger Seco, Thomas Holst, Mikkel Sillesen Matzen, Andreas Westergaard-Nielsen, Tao Li, Tihomir Simin, Joachim Jansen, Patrick Crill, Thomas Friborg, Janne Rinne, and Riikka Rinnan
Atmos. Chem. Phys., 20, 13399–13416, https://doi.org/10.5194/acp-20-13399-2020, https://doi.org/10.5194/acp-20-13399-2020, 2020
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Northern ecosystems exchange climate-relevant trace gases with the atmosphere, including volatile organic compounds (VOCs). We measured VOC fluxes from a subarctic permafrost-free fen and its adjacent lake in northern Sweden. The graminoid-dominated fen emitted mainly isoprene during the peak of the growing season, with a pronounced response to increasing temperatures stronger than assumed by biogenic emission models. The lake was a sink of acetone and acetaldehyde during both periods measured.
Chen Dayan, Erick Fredj, Pawel K. Misztal, Maor Gabay, Alex B. Guenther, and Eran Tas
Atmos. Chem. Phys., 20, 12741–12759, https://doi.org/10.5194/acp-20-12741-2020, https://doi.org/10.5194/acp-20-12741-2020, 2020
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We studied the emission of biogenic volatile organic compounds from both marine and terrestrial ecosystems in the Eastern Mediterranean Basin, a global warming hot spot. We focused on isoprene and dimethyl sulfide (DMS), which are well recognized for their effect on climate and strong impact on photochemical pollution by the former. We found high emissions of isoprene and a strong decadal decrease in the emission of DMS which can both be attributed to the strong increase in seawater temperature.
Lang Wang, Amos P. K. Tai, Chi-Yung Tam, Mehliyar Sadiq, Peng Wang, and Kevin K. W. Cheung
Atmos. Chem. Phys., 20, 11349–11369, https://doi.org/10.5194/acp-20-11349-2020, https://doi.org/10.5194/acp-20-11349-2020, 2020
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We investigate the effects of future land use and land cover change (LULCC) on surface ozone air quality worldwide and find that LULCC can significantly influence ozone in North America and Europe via modifying surface energy balance, boundary-layer meteorology, and regional circulation. The strength of such “biogeophysical effects” of LULCC is strongly dependent on forest type and generally greater than the “biogeochemical effects” via changing deposition and emission fluxes alone.
Sally S.-C. Wang and Yuxuan Wang
Atmos. Chem. Phys., 20, 11065–11087, https://doi.org/10.5194/acp-20-11065-2020, https://doi.org/10.5194/acp-20-11065-2020, 2020
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A model consisting of multiple machine learning algorithms is developed to predict wildfire burned area over the south central US and explains key environmental drivers. The developed model alleviates the issue of unevenly distributed data and predicts burned grids and burned areas with good accuracy. The model reveals climate variability such as relative humidity anomalies and antecedent drought severity contributes the most to the total burned area for winter–spring and summer fire season.
Archit Mehra, Jordan E. Krechmer, Andrew Lambe, Chinmoy Sarkar, Leah Williams, Farzaneh Khalaj, Alex Guenther, John Jayne, Hugh Coe, Douglas Worsnop, Celia Faiola, and Manjula Canagaratna
Atmos. Chem. Phys., 20, 10953–10965, https://doi.org/10.5194/acp-20-10953-2020, https://doi.org/10.5194/acp-20-10953-2020, 2020
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Emissions of volatile organic compounds (VOCs) from plants are important for tropospheric ozone and secondary organic aerosol (SOA) formation. Real plant emissions are much more diverse than the few proxies widely used for studies of plant SOA. Here we present the first study of SOA from Californian sage plants and the oxygenated monoterpenes representing their major emissions. We identify SOA products and show the importance of the formation of highly oxygenated organic molecules and oligomers.
Li Zhang, Meiyun Lin, Andrew O. Langford, Larry W. Horowitz, Christoph J. Senff, Elizabeth Klovenski, Yuxuan Wang, Raul J. Alvarez II, Irina Petropavlovskikh, Patrick Cullis, Chance W. Sterling, Jeff Peischl, Thomas B. Ryerson, Steven S. Brown, Zachary C. J. Decker, Guillaume Kirgis, and Stephen Conley
Atmos. Chem. Phys., 20, 10379–10400, https://doi.org/10.5194/acp-20-10379-2020, https://doi.org/10.5194/acp-20-10379-2020, 2020
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Measuring and quantifying the sources of elevated springtime ozone in the southwestern US is challenging but relevant to the implications for control policy. Here we use intensive field measurements and two global models to study ozone sources in the region. We find that ozone from the stratosphere, wildfires, and Asia is an important source of high-ozone events in the region. Our analysis also helps understand the uncertainties in ozone simulations with individual models.
Chinmoy Sarkar, Alex B. Guenther, Jeong-Hoo Park, Roger Seco, Eliane Alves, Sarah Batalha, Raoni Santana, Saewung Kim, James Smith, Julio Tóta, and Oscar Vega
Atmos. Chem. Phys., 20, 7179–7191, https://doi.org/10.5194/acp-20-7179-2020, https://doi.org/10.5194/acp-20-7179-2020, 2020
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Biogenic volatile organic compounds (BVOCs) are important components of the atmosphere due to their contribution to atmospheric chemistry and biogeochemical cycles. In this study, we report major BVOCs, e.g. isoprene and total monoterpene flux measurements with a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) using the eddy covariance (EC) method at a primary rainforest in eastern Amazonia. We used the measured data to evaluate the MEGAN2.1 model for the emission site.
Sam J. Silva, Colette L. Heald, and Alex B. Guenther
Geosci. Model Dev., 13, 2569–2585, https://doi.org/10.5194/gmd-13-2569-2020, https://doi.org/10.5194/gmd-13-2569-2020, 2020
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Simulating the influence of the biosphere on atmospheric chemistry has traditionally been computationally intensive. We describe a surrogate canopy physics model parameterized using a statistical learning technique and specifically designed for use in large-scale chemical transport models. Our surrogate model reproduces a more detailed model to within 10 % without a large computational demand, improving the process representation of biosphere–atmosphere exchange.
Archana Dayalu, J. William Munger, Yuxuan Wang, Steven C. Wofsy, Yu Zhao, Thomas Nehrkorn, Chris Nielsen, Michael B. McElroy, and Rachel Chang
Atmos. Chem. Phys., 20, 3569–3588, https://doi.org/10.5194/acp-20-3569-2020, https://doi.org/10.5194/acp-20-3569-2020, 2020
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China has pledged to reduce carbon dioxide emissions per unit GDP by 60–65 % relative to 2005 levels, and to peak carbon emissions overall by 2030. Disagreement among available inventories of Chinese emissions makes it difficult for China to track progress toward its goals and evaluate the efficacy of regional control measures. This study uses a unique set of historical atmospheric observations for the key period from 2005 to 2009 to independently evaluate three different CO2 emission estimates.
Anthony Y. H. Wong, Jeffrey A. Geddes, Amos P. K. Tai, and Sam J. Silva
Atmos. Chem. Phys., 19, 14365–14385, https://doi.org/10.5194/acp-19-14365-2019, https://doi.org/10.5194/acp-19-14365-2019, 2019
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Dry deposition is an important, but highly uncertain, sink for surface ozone. Several popular parameterizations exist to model this process, which vary with respect to how they depend on land cover and environmental variables. Here, we predict ozone dry deposition globally over 30 years, comparing four different approaches. We find that the choice of dry deposition parameterization affects the distribution, seasonal means, long-term trends, and interannual variability of surface ozone.
Daun Jeong, Roger Seco, Dasa Gu, Youngro Lee, Benjamin A. Nault, Christoph J. Knote, Tom Mcgee, John T. Sullivan, Jose L. Jimenez, Pedro Campuzano-Jost, Donald R. Blake, Dianne Sanchez, Alex B. Guenther, David Tanner, L. Gregory Huey, Russell Long, Bruce E. Anderson, Samuel R. Hall, Kirk Ullmann, Hye-jung Shin, Scott C. Herndon, Youngjae Lee, Danbi Kim, Joonyoung Ahn, and Saewung Kim
Atmos. Chem. Phys., 19, 12779–12795, https://doi.org/10.5194/acp-19-12779-2019, https://doi.org/10.5194/acp-19-12779-2019, 2019
Emma L. D'Ambro, Siegfried Schobesberger, Cassandra J. Gaston, Felipe D. Lopez-Hilfiker, Ben H. Lee, Jiumeng Liu, Alla Zelenyuk, David Bell, Christopher D. Cappa, Taylor Helgestad, Ziyue Li, Alex Guenther, Jian Wang, Matthew Wise, Ryan Caylor, Jason D. Surratt, Theran Riedel, Noora Hyttinen, Vili-Taneli Salo, Galib Hasan, Theo Kurtén, John E. Shilling, and Joel A. Thornton
Atmos. Chem. Phys., 19, 11253–11265, https://doi.org/10.5194/acp-19-11253-2019, https://doi.org/10.5194/acp-19-11253-2019, 2019
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Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important to understand its fate and role in aerosol formation and growth. A major product of its oxidation is an epoxydiol, IEPOX, which can be efficiently taken up by acidic aerosol to generate substantial amounts of secondary organic aerosol (SOA). We present chamber experiments exploring the properties of IEPOX SOA and reconcile discrepancies between field, laboratory, and model studies of this process.
Karena A. McKinney, Daniel Wang, Jianhuai Ye, Jean-Baptiste de Fouchier, Patricia C. Guimarães, Carla E. Batista, Rodrigo A. F. Souza, Eliane G. Alves, Dasa Gu, Alex B. Guenther, and Scot T. Martin
Atmos. Meas. Tech., 12, 3123–3135, https://doi.org/10.5194/amt-12-3123-2019, https://doi.org/10.5194/amt-12-3123-2019, 2019
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Volatile organic compound (VOC) emissions influence air quality and particulate distributions, particularly in major source regions such as the Amazon. A sampler for collecting VOCs from an unmanned aerial vehicle (UAV) is described. Field tests of its performance and an initial example data set collected in the Amazon are also presented. The low cost, ease of use, and maneuverability of UAVs give this method the potential to significantly advance knowledge of the spatial distribution of VOCs.
Moshe Shechner, Alex Guenther, Robert Rhew, Asher Wishkerman, Qian Li, Donald Blake, Gil Lerner, and Eran Tas
Atmos. Chem. Phys., 19, 7667–7690, https://doi.org/10.5194/acp-19-7667-2019, https://doi.org/10.5194/acp-19-7667-2019, 2019
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Along with other recent studies, our findings point to strong emission of a suite of volatile halogenated organic compounds (VHOCs) from saline soils and salt lakes. Some emitted VHOCs were not known to be emitted from terrestrial sources, and our observations point to apparent new common controls for the emission of several VHOCs. These findings are an important milestone toward a more complete understanding of the effect of VHOCs on atmospheric ozone concentrations and oxidation capacity.
Jingyuan Shao, Qianjie Chen, Yuxuan Wang, Xiao Lu, Pengzhen He, Yele Sun, Viral Shah, Randall V. Martin, Sajeev Philip, Shaojie Song, Yue Zhao, Zhouqing Xie, Lin Zhang, and Becky Alexander
Atmos. Chem. Phys., 19, 6107–6123, https://doi.org/10.5194/acp-19-6107-2019, https://doi.org/10.5194/acp-19-6107-2019, 2019
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Sulfate is a key species contributing to particle formation and growth during wintertime Chinese haze events. This study combines observations and modeling of oxygen isotope signatures in sulfate aerosol to investigate its formation mechanisms, with a focus on heterogeneous production on aerosol surface via H2O2, O3, and NO2 and trace metal catalyzed oxidation. Contributions from different formation pathways are presented.
Shaojie Song, Meng Gao, Weiqi Xu, Yele Sun, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. Jacob, and Michael B. McElroy
Atmos. Chem. Phys., 19, 1357–1371, https://doi.org/10.5194/acp-19-1357-2019, https://doi.org/10.5194/acp-19-1357-2019, 2019
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Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).
Lu Shen, Daniel J. Jacob, Loretta J. Mickley, Yuxuan Wang, and Qiang Zhang
Atmos. Chem. Phys., 18, 17489–17496, https://doi.org/10.5194/acp-18-17489-2018, https://doi.org/10.5194/acp-18-17489-2018, 2018
Archana Dayalu, J. William Munger, Steven C. Wofsy, Yuxuan Wang, Thomas Nehrkorn, Yu Zhao, Michael B. McElroy, Chris P. Nielsen, and Kristina Luus
Biogeosciences, 15, 6713–6729, https://doi.org/10.5194/bg-15-6713-2018, https://doi.org/10.5194/bg-15-6713-2018, 2018
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Accounting for the vegetation signal is critical for comprehensive CO2 budget assessment in China. We model and evaluate hourly vegetation carbon dioxide (CO2) exchange (mass per unit area per unit time) in northern China from 2005 to 2009. The model is driven by satellite and meteorological data, is linked to ground-level ecosystem observations, and is applicable to other time periods. We find vegetation uptake of CO2 in summer is comparable to emissions from fossil fuels in northern China.
Shan S. Zhou, Amos P. K. Tai, Shihan Sun, Mehliyar Sadiq, Colette L. Heald, and Jeffrey A. Geddes
Atmos. Chem. Phys., 18, 14133–14148, https://doi.org/10.5194/acp-18-14133-2018, https://doi.org/10.5194/acp-18-14133-2018, 2018
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Surface ozone pollution harms vegetation. As plants play key roles shaping air quality, the plant damage may further worsen air pollution. We use various computer models to examine such feedback effects, and find that ozone-induced decline in leaf density can lead to much higher ozone levels in forested regions, mostly due to the reduced ability of leaves to absorb pollutants. This study highlights the importance of considering the two-way interactions between plants and air pollution.
Fernando Santos, Karla Longo, Alex Guenther, Saewung Kim, Dasa Gu, Dave Oram, Grant Forster, James Lee, James Hopkins, Joel Brito, and Saulo Freitas
Atmos. Chem. Phys., 18, 12715–12734, https://doi.org/10.5194/acp-18-12715-2018, https://doi.org/10.5194/acp-18-12715-2018, 2018
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We investigated the impact of biomass burning on the chemical composition of trace gases in the Amazon. The findings corroborate the influence of biomass burning activity not only on direct emissions of particulate matter but also on the oxidative capacity to produce secondary organic aerosol. The scientists plan to use this information to improve the numerical model simulation with a better representativeness of the chemical processes, which can impact on global climate prediction.
Anna L. Hodshire, Brett B. Palm, M. Lizabeth Alexander, Qijing Bian, Pedro Campuzano-Jost, Eben S. Cross, Douglas A. Day, Suzane S. de Sá, Alex B. Guenther, Armin Hansel, James F. Hunter, Werner Jud, Thomas Karl, Saewung Kim, Jesse H. Kroll, Jeong-Hoo Park, Zhe Peng, Roger Seco, James N. Smith, Jose L. Jimenez, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 12433–12460, https://doi.org/10.5194/acp-18-12433-2018, https://doi.org/10.5194/acp-18-12433-2018, 2018
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We investigate the nucleation and growth processes that shape the aerosol size distribution inside oxidation flow reactors (OFRs) that sampled ambient air from Colorado and the Amazon rainforest. Results indicate that organics are important for both nucleation and growth, vapor uptake was limited to accumulation-mode particles, fragmentation reactions were important to limit particle growth at higher OH exposures, and an H2SO4-organics nucleation mechanism captured new particle formation well.
Eliane G. Alves, Julio Tóta, Andrew Turnipseed, Alex B. Guenther, José Oscar W. Vega Bustillos, Raoni A. Santana, Glauber G. Cirino, Julia V. Tavares, Aline P. Lopes, Bruce W. Nelson, Rodrigo A. de Souza, Dasa Gu, Trissevgeni Stavrakou, David K. Adams, Jin Wu, Scott Saleska, and Antonio O. Manzi
Biogeosciences, 15, 4019–4032, https://doi.org/10.5194/bg-15-4019-2018, https://doi.org/10.5194/bg-15-4019-2018, 2018
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This study shows that leaf quantity and leaf age have an important effect on seasonal changes in isoprene emissions and that these could play an even more important role in regulating ecosystem isoprene fluxes than light and temperature at seasonal timescales in tropical forests. These results bring novelty and new insight for future research because in the past leaf phenology was not considered as an important factor that controls biological processes in the tropics.
Chunxiang Ye, Xianliang Zhou, Dennis Pu, Jochen Stutz, James Festa, Max Spolaor, Catalina Tsai, Christopher Cantrell, Roy L. Mauldin III, Andrew Weinheimer, Rebecca S. Hornbrook, Eric C. Apel, Alex Guenther, Lisa Kaser, Bin Yuan, Thomas Karl, Julie Haggerty, Samuel Hall, Kirk Ullmann, James Smith, and John Ortega
Atmos. Chem. Phys., 18, 9107–9120, https://doi.org/10.5194/acp-18-9107-2018, https://doi.org/10.5194/acp-18-9107-2018, 2018
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Substantial levels of HONO existed during the day throughout the troposphere over the southeastern US during NOMADSS 2013. Particulate nitrate photolysis appeared to be the major volume HONO source, while NOx was an important HONO precursor only in industrial and urban plumes. HONO was not a significant OH radical precursor in the rural troposphere away from the ground surface; however, its production from particulate nitrate photolysis was an important renoxification pathway.
Maite Bauwens, Trissevgeni Stavrakou, Jean-François Müller, Bert Van Schaeybroeck, Lesley De Cruz, Rozemien De Troch, Olivier Giot, Rafiq Hamdi, Piet Termonia, Quentin Laffineur, Crist Amelynck, Niels Schoon, Bernard Heinesch, Thomas Holst, Almut Arneth, Reinhart Ceulemans, Arturo Sanchez-Lorenzo, and Alex Guenther
Biogeosciences, 15, 3673–3690, https://doi.org/10.5194/bg-15-3673-2018, https://doi.org/10.5194/bg-15-3673-2018, 2018
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Biogenic isoprene fluxes are simulated over Europe with the MEGAN–MOHYCAN model for the recent past and end-of-century climate at high spatiotemporal resolution (0.1°, 3 min). Due to climate change, fluxes increased by 40 % over 1979–2014. Climate scenarios for 2070–2099 suggest an increase by 83 % due to climate, and an even stronger increase when the potential impact of CO2 fertilization is considered (up to 141 %). Accounting for CO2 inhibition cancels out a large part of these increases.
Nan Li, Qingyang He, Jim Greenberg, Alex Guenther, Jingyi Li, Junji Cao, Jun Wang, Hong Liao, Qiyuan Wang, and Qiang Zhang
Atmos. Chem. Phys., 18, 7489–7507, https://doi.org/10.5194/acp-18-7489-2018, https://doi.org/10.5194/acp-18-7489-2018, 2018
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O3 pollution has been increasing in most Chinese cities in recent years. Our study reveals that the synergistic impact of individual source contributions to O3 formation should be considered in the formation of air pollution control strategies, especially for big cities in the vicinity of forests.
Shaojie Song, Meng Gao, Weiqi Xu, Jingyuan Shao, Guoliang Shi, Shuxiao Wang, Yuxuan Wang, Yele Sun, and Michael B. McElroy
Atmos. Chem. Phys., 18, 7423–7438, https://doi.org/10.5194/acp-18-7423-2018, https://doi.org/10.5194/acp-18-7423-2018, 2018
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Severe haze events occur frequently over northern China, especially in winter. Acidity plays a critical role in the formation of secondary PM2.5 and its toxicity. Using field measurements of gases and particles to critically evaluate two thermodynamic models routinely employed to determine particle acidity, we found that China's winter haze particles are generally within a moderately acidic range (pH 4–5) and not highly acidic (0) or neutral (7) as has been previously reported in the literature.
Danny M. Leung, Amos P. K. Tai, Loretta J. Mickley, Jonathan M. Moch, Aaron van Donkelaar, Lu Shen, and Randall V. Martin
Atmos. Chem. Phys., 18, 6733–6748, https://doi.org/10.5194/acp-18-6733-2018, https://doi.org/10.5194/acp-18-6733-2018, 2018
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This paper investigates how large-scale weather systems control fine particulate matter (PM2.5) air quality in China. We show that winter monsoons, onshore winds and frontal rains can drive daily PM2.5 variability in different regions of China. We further project future PM2.5 concentration change by 2050s due to climate change, and verify that climate change has little benefit on future PM2.5 in Beijing, implying cutting down emissions is necessary to mitigate pollutions in megacities of China.
Jingqiu Mao, Annmarie Carlton, Ronald C. Cohen, William H. Brune, Steven S. Brown, Glenn M. Wolfe, Jose L. Jimenez, Havala O. T. Pye, Nga Lee Ng, Lu Xu, V. Faye McNeill, Kostas Tsigaridis, Brian C. McDonald, Carsten Warneke, Alex Guenther, Matthew J. Alvarado, Joost de Gouw, Loretta J. Mickley, Eric M. Leibensperger, Rohit Mathur, Christopher G. Nolte, Robert W. Portmann, Nadine Unger, Mika Tosca, and Larry W. Horowitz
Atmos. Chem. Phys., 18, 2615–2651, https://doi.org/10.5194/acp-18-2615-2018, https://doi.org/10.5194/acp-18-2615-2018, 2018
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This paper is aimed at discussing progress in evaluating, diagnosing, and improving air quality and climate modeling using comparisons to SAS observations as a guide to thinking about improvements to mechanisms and parameterizations in models.
Brett B. Palm, Suzane S. de Sá, Douglas A. Day, Pedro Campuzano-Jost, Weiwei Hu, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Joel Brito, Florian Wurm, Paulo Artaxo, Ryan Thalman, Jian Wang, Lindsay D. Yee, Rebecca Wernis, Gabriel Isaacman-VanWertz, Allen H. Goldstein, Yingjun Liu, Stephen R. Springston, Rodrigo Souza, Matt K. Newburn, M. Lizabeth Alexander, Scot T. Martin, and Jose L. Jimenez
Atmos. Chem. Phys., 18, 467–493, https://doi.org/10.5194/acp-18-467-2018, https://doi.org/10.5194/acp-18-467-2018, 2018
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Ambient air was oxidized by OH or O3 in an oxidation flow reactor during both wet and dry seasons in the GoAmazon2014/5 campaign to study secondary organic aerosol (SOA) formation. We investigated how much biogenic, urban, and biomass burning sources contributed to the ambient concentrations of SOA precursor gases and how their contributions changed diurnally and seasonally. SOA yields and hygroscopicity of organic aerosol in the oxidation flow reactor were also studied.
Robert C. Rhew, Malte Julian Deventer, Andrew A. Turnipseed, Carsten Warneke, John Ortega, Steve Shen, Luis Martinez, Abigail Koss, Brian M. Lerner, Jessica B. Gilman, James N. Smith, Alex B. Guenther, and Joost A. de Gouw
Atmos. Chem. Phys., 17, 13417–13438, https://doi.org/10.5194/acp-17-13417-2017, https://doi.org/10.5194/acp-17-13417-2017, 2017
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Alkenes emanate from both natural and anthropogenic sources and can contribute to atmospheric ozone production. This study measured
lightalkene (ethene, propene and butene) fluxes from a ponderosa pine forest using a novel relaxed eddy accumulation method, revealing much larger emissions than previously estimated and accounting for a significant fraction of OH reactivity. Emissions have a diurnal cycle related to sunlight and temperature, and the forest canopy appears to be the source.
Yuxuan Wang, Yuanyu Xie, Wenhao Dong, Yi Ming, Jun Wang, and Lu Shen
Atmos. Chem. Phys., 17, 12827–12843, https://doi.org/10.5194/acp-17-12827-2017, https://doi.org/10.5194/acp-17-12827-2017, 2017
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Besides the well-known large impact on agriculture and water resources, drought is associated with significant adverse effects on air quality. Drought-induced degradation of air quality is largely due to natural processes, offsetting the effort of anthropogenic emission reduction during the past decades. Such adverse impacts should be included in modeling processes under current and future climate for mitigation policy.
Min Huang, Gregory R. Carmichael, James H. Crawford, Armin Wisthaler, Xiwu Zhan, Christopher R. Hain, Pius Lee, and Alex B. Guenther
Geosci. Model Dev., 10, 3085–3104, https://doi.org/10.5194/gmd-10-3085-2017, https://doi.org/10.5194/gmd-10-3085-2017, 2017
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Various sensitivity simulations during two airborne campaigns were performed to assess the impact of different initialization methods and model resolutions on NUWRF-modeled weather states, heat fluxes, and the follow-on MEGAN isoprene emission calculations. Proper land initialization is shown to be important to the coupled weather modeling and the follow-on emission modeling, which is also critical to accurately representing other processes in air quality modeling and data assimilation.
Yuanhong Zhao, Lin Zhang, Amos P. K. Tai, Youfan Chen, and Yuepeng Pan
Atmos. Chem. Phys., 17, 9781–9796, https://doi.org/10.5194/acp-17-9781-2017, https://doi.org/10.5194/acp-17-9781-2017, 2017
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Human activities have substantially enhanced atmospheric deposition of reactive nitrogen, inducing complex environmental consequences. This study presents a first quantitative investigation of how anthropogenic nitrogen deposition could impact surface ozone air quality through surface–atmosphere exchange processes. We find important surface ozone changes driven by nitrogen deposition, which can be comparable with those due to historical climate and land use changes.
Mehliyar Sadiq, Amos P. K. Tai, Danica Lombardozzi, and Maria Val Martin
Atmos. Chem. Phys., 17, 3055–3066, https://doi.org/10.5194/acp-17-3055-2017, https://doi.org/10.5194/acp-17-3055-2017, 2017
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Surface ozone harms vegetation, which can influence not only climate but also ozone air quality itself. We implement a scheme for ozone damage on vegetation into an Earth system model, so that for the first time simulated vegetation and ozone can coevolve in a fully coupled simulation. With ozone–vegetation coupling, simulated ozone is found to be significantly higher by up to 6 ppbv. Reduced dry deposition and enhanced isoprene emission contribute to most of these increases.
Kerneels Jaars, Pieter G. van Zyl, Johan P. Beukes, Heidi Hellén, Ville Vakkari, Micky Josipovic, Andrew D. Venter, Matti Räsänen, Leandra Knoetze, Dirk P. Cilliers, Stefan J. Siebert, Markku Kulmala, Janne Rinne, Alex Guenther, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 16, 15665–15688, https://doi.org/10.5194/acp-16-15665-2016, https://doi.org/10.5194/acp-16-15665-2016, 2016
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Biogenic volatile organic compounds (BVOCs) – important in tropospheric ozone and secondary organic aerosol formation – were measured at a savannah grassland in South Africa. Results presented are the most extensive for this type of landscape. Compared to other parts of the world, monoterpene levels were similar, while very low isoprene levels led to significantly lower total BVOC levels. BVOC levels were an order of magnitude lower compared to anthropogenic VOC levels measured at Welgegund.
Yuxuan Wang, Beixi Jia, Sing-Chun Wang, Mark Estes, Lu Shen, and Yuanyu Xie
Atmos. Chem. Phys., 16, 15265–15276, https://doi.org/10.5194/acp-16-15265-2016, https://doi.org/10.5194/acp-16-15265-2016, 2016
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This paper provides empirical evidence that the year-to-year variability of summertime ozone over Houston is linked to the Bermuda High (BH) large-scale circulation patterns. It identifies two BH indices that can explain up to 70 % of the interannual variability of summertime ozone in Houston and illustrates the mechanism underlying the BH and ozone linkage. Such a mechanism is tested for applicability to other coastal urban regions along the US Gulf Coast.
Angie Bouche, Bernhard Beck-Winchatz, and Mark J. Potosnak
Atmos. Meas. Tech., 9, 5707–5719, https://doi.org/10.5194/amt-9-5707-2016, https://doi.org/10.5194/amt-9-5707-2016, 2016
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We describe a novel method of measuring the exchange of carbon dioxide over croplands using a high-altitude balloon (HAB). Our methodology uses two balloon launches on a single day to measure atmospheric changes in carbon dioxide and then relate them to the photosynthesis and respiration of the crops. Our results are compared to satellite measures of greenness and a research site in Bondville, Illinois. A future goal is to recruit citizen scientists to perform the launches.
Ivan Kourtchev, Ricardo H. M. Godoi, Sarah Connors, James G. Levine, Alex T. Archibald, Ana F. L. Godoi, Sarah L. Paralovo, Cybelli G. G. Barbosa, Rodrigo A. F. Souza, Antonio O. Manzi, Roger Seco, Steve Sjostedt, Jeong-Hoo Park, Alex Guenther, Saewung Kim, James Smith, Scot T. Martin, and Markus Kalberer
Atmos. Chem. Phys., 16, 11899–11913, https://doi.org/10.5194/acp-16-11899-2016, https://doi.org/10.5194/acp-16-11899-2016, 2016
Weiwei Hu, Brett B. Palm, Douglas A. Day, Pedro Campuzano-Jost, Jordan E. Krechmer, Zhe Peng, Suzane S. de Sá, Scot T. Martin, M. Lizabeth Alexander, Karsten Baumann, Lina Hacker, Astrid Kiendler-Scharr, Abigail R. Koss, Joost A. de Gouw, Allen H. Goldstein, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Francesco Canonaco, André S. H. Prévôt, William H. Brune, and Jose L. Jimenez
Atmos. Chem. Phys., 16, 11563–11580, https://doi.org/10.5194/acp-16-11563-2016, https://doi.org/10.5194/acp-16-11563-2016, 2016
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IEPOX-SOA is biogenically derived secondary organic aerosol under anthropogenic influence, which has been shown to comprise a substantial fraction of OA globally. We investigated the lifetime of ambient IEPOX-SOA in the SE US and Amazonia, with an oxidation flow reactor and thermodenuder coupled with MS-based instrumentation. The low volatility and long lifetime of IEPOX-SOA against OH radicals' oxidation (> 2 weeks) was observed, which can help to constrain OA impact on air quality and climate.
Yu Fu, Amos P. K. Tai, and Hong Liao
Atmos. Chem. Phys., 16, 10369–10383, https://doi.org/10.5194/acp-16-10369-2016, https://doi.org/10.5194/acp-16-10369-2016, 2016
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The effects of climate change would partly counteract the emission-driven increase in PM2.5 in winter in most of eastern China, but exacerbate PM2.5 pollution in summer in North China Plain. Land cover and land use change might partially offset the increase in summertime PM2.5 but further enhance wintertime PM2.5 in the model by modifying the dry deposition of various PM2.5 precursors and biogenic volatile organic compound emissions, which also act as important factors in modulating air quality.
Maite Bauwens, Trissevgeni Stavrakou, Jean-François Müller, Isabelle De Smedt, Michel Van Roozendael, Guido R. van der Werf, Christine Wiedinmyer, Johannes W. Kaiser, Katerina Sindelarova, and Alex Guenther
Atmos. Chem. Phys., 16, 10133–10158, https://doi.org/10.5194/acp-16-10133-2016, https://doi.org/10.5194/acp-16-10133-2016, 2016
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Relying on a 9-year record of satellite observations of formaldehyde, we use inverse techniques to derive global top–down hydrocarbon fluxes over 2005–2013, infer seasonal and interannual variability, and detect emission trends. Our results suggest changes in fire seasonal patterns, a stronger contribution of agricultural burning, overestimated isoprene flux rates in the tropics, overly decreased isoprene emissions due to soil moisture stress in arid areas, and enhanced isoprene trends.
Pawel K. Misztal, Jeremy C. Avise, Thomas Karl, Klaus Scott, Haflidi H. Jonsson, Alex B. Guenther, and Allen H. Goldstein
Atmos. Chem. Phys., 16, 9611–9628, https://doi.org/10.5194/acp-16-9611-2016, https://doi.org/10.5194/acp-16-9611-2016, 2016
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In this study, for the first time regional BVOC models are compared with direct regional measurements of fluxes from aircraft, allowing assessment of model accuracy at scales relevant to air quality modeling. We directly assess modeled isoprene emission inventories which are important for regional air quality simulations of ozone and secondary particle concentrations.
Albert Rivas-Ubach, Yina Liu, Jordi Sardans, Malak M. Tfaily, Young-Mo Kim, Eric Bourrianne, Ljiljana Paša-Tolić, Josep Peñuelas, and Alex Guenther
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2016-209, https://doi.org/10.5194/amt-2016-209, 2016
Revised manuscript not accepted
Kathryn M. Emmerson, Ian E. Galbally, Alex B. Guenther, Clare Paton-Walsh, Elise-Andree Guerette, Martin E. Cope, Melita D. Keywood, Sarah J. Lawson, Suzie B. Molloy, Erin Dunne, Marcus Thatcher, Thomas Karl, and Simin D. Maleknia
Atmos. Chem. Phys., 16, 6997–7011, https://doi.org/10.5194/acp-16-6997-2016, https://doi.org/10.5194/acp-16-6997-2016, 2016
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We have tested how a model using a global inventory of plant-based emissions compares with four sets of measurements made in southeast Australia. This region is known for its eucalypt species, which dominate the summertime global inventory. The Australian part of the inventory has been produced using measurements made on eucalypt saplings. The model could not match the measurements, and the inventory needs to be improved by taking measurements of a wider range of Australian plant types and ages.
Chun Zhao, Maoyi Huang, Jerome D. Fast, Larry K. Berg, Yun Qian, Alex Guenther, Dasa Gu, Manish Shrivastava, Ying Liu, Stacy Walters, Gabriele Pfister, Jiming Jin, John E. Shilling, and Carsten Warneke
Geosci. Model Dev., 9, 1959–1976, https://doi.org/10.5194/gmd-9-1959-2016, https://doi.org/10.5194/gmd-9-1959-2016, 2016
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In this study, the latest version of MEGAN is coupled within CLM4 in WRF-Chem. In this implementation, MEGAN shares a consistent vegetation map with CLM4. This improved modeling framework is used to investigate the impact of two land surface schemes on BVOCs and examine the sensitivity of BVOCs to vegetation distributions in California. This study indicates that more effort is needed to obtain the most appropriate and accurate land cover data sets for climate and air quality models.
Dominique E. Young, Hwajin Kim, Caroline Parworth, Shan Zhou, Xiaolu Zhang, Christopher D. Cappa, Roger Seco, Saewung Kim, and Qi Zhang
Atmos. Chem. Phys., 16, 5427–5451, https://doi.org/10.5194/acp-16-5427-2016, https://doi.org/10.5194/acp-16-5427-2016, 2016
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Aerosol chemistry and the sources and processes driving the observed temporal and diurnal variations of PM were studied in a polluted urban environment during winter 2013. These results were compared to a similar campaign from winter 2010. Meteorology strongly influenced PM composition, both directly and indirectly. Nighttime reactions played a more important role in 2013 and the influence from a nighttime formed residual layer that mixed down in the morning was also much more intense in 2013.
Eliane G. Alves, Kolby Jardine, Julio Tota, Angela Jardine, Ana Maria Yãnez-Serrano, Thomas Karl, Julia Tavares, Bruce Nelson, Dasa Gu, Trissevgeni Stavrakou, Scot Martin, Paulo Artaxo, Antonio Manzi, and Alex Guenther
Atmos. Chem. Phys., 16, 3903–3925, https://doi.org/10.5194/acp-16-3903-2016, https://doi.org/10.5194/acp-16-3903-2016, 2016
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For a long time, it was thought that tropical rainforests are evergreen forests and the processes involved in these ecosystems do not change all year long. However, some satellite retrievals have suggested that ecophysiological processes may present seasonal variations mainly due to variation in light and leaf phenology in Amazonia. These in situ measurements are the first showing of a seasonal trend of volatile organic compound emissions, correlating with light and leaf phenology in Amazonia.
J.-W. Xu, R. V. Martin, A. van Donkelaar, J. Kim, M. Choi, Q. Zhang, G. Geng, Y. Liu, Z. Ma, L. Huang, Y. Wang, H. Chen, H. Che, P. Lin, and N. Lin
Atmos. Chem. Phys., 15, 13133–13144, https://doi.org/10.5194/acp-15-13133-2015, https://doi.org/10.5194/acp-15-13133-2015, 2015
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1. GOCI (Geostationary Ocean Color Imager) retrieval of AOD is consistent with AERONET AOD (RMSE=0.08-0.1)
2. GOCI-derived PM2.5 is in significant agreement with in situ observations (r2=0.66, rRMSE=18.3%)
3. Population-weighted GOCI-derived PM2.5 over eastern China for 2013 is 53.8 μg/m3, threatening the health of its more than 400 million residents
4. Secondary inorganics (SO42-, NO3-, NH4+) & organic matter are the most significant components of GOCI-derived PM2.5.
R. Gonzalez-Abraham, S. H. Chung, J. Avise, B. Lamb, E. P. Salathé Jr., C. G. Nolte, D. Loughlin, A. Guenther, C. Wiedinmyer, T. Duhl, Y. Zhang, and D. G. Streets
Atmos. Chem. Phys., 15, 12645–12665, https://doi.org/10.5194/acp-15-12645-2015, https://doi.org/10.5194/acp-15-12645-2015, 2015
T. Stavrakou, J.-F. Müller, M. Bauwens, I. De Smedt, M. Van Roozendael, M. De Mazière, C. Vigouroux, F. Hendrick, M. George, C. Clerbaux, P.-F. Coheur, and A. Guenther
Atmos. Chem. Phys., 15, 11861–11884, https://doi.org/10.5194/acp-15-11861-2015, https://doi.org/10.5194/acp-15-11861-2015, 2015
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Formaldehyde columns from two space sensors, GOME-2 and OMI, constrain by inverse modeling the global emissions of HCHO precursors in 2010. The resulting biogenic and pyrogenic fluxes from both optimizations show a very good degree of consistency. The isoprene fluxes are reduced globally by ca. 10%, and emissions from fires decrease by ca. 35%, compared to the prior. Anthropogenic emissions are weakly constrained except over China. Sensitivity inversions show robustness of the inferred fluxes.
F. Xiong, K. M. McAvey, K. A. Pratt, C. J. Groff, M. A. Hostetler, M. A. Lipton, T. K. Starn, J. V. Seeley, S. B. Bertman, A. P. Teng, J. D. Crounse, T. B. Nguyen, P. O. Wennberg, P. K. Misztal, A. H. Goldstein, A. B. Guenther, A. R. Koss, K. F. Olson, J. A. de Gouw, K. Baumann, E. S. Edgerton, P. A. Feiner, L. Zhang, D. O. Miller, W. H. Brune, and P. B. Shepson
Atmos. Chem. Phys., 15, 11257–11272, https://doi.org/10.5194/acp-15-11257-2015, https://doi.org/10.5194/acp-15-11257-2015, 2015
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Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.
L. Shen, L. J. Mickley, and A. P. K. Tai
Atmos. Chem. Phys., 15, 10925–10938, https://doi.org/10.5194/acp-15-10925-2015, https://doi.org/10.5194/acp-15-10925-2015, 2015
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In this study, we have examined the effect of polar jet and Bermuda High on ozone air quality in the eastern United States. In the Midwest and northeast, the poleward shift of jet wind leads to reduced polar jet frequency, resulting in increased ozone there. In the southeast, the influence of Bermuda High on ozone variability depends on the location of its west edge. Westward movement increases the ozone only when the JJA Bermuda High west edge is located west of 85.4°W.
Y. Fu and A. P. K. Tai
Atmos. Chem. Phys., 15, 10093–10106, https://doi.org/10.5194/acp-15-10093-2015, https://doi.org/10.5194/acp-15-10093-2015, 2015
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Historical land cover and land use change alone between 1980 and 2010 could lead to reduced summertime surface ozone by up to 4ppbv in East Asia. Climate change alone could lead to an increase in summertime ozone by 2-10ppbv in most of East Asia. Land cover change could offset part of the climate effect and lead to a previously unknown public health benefit. The sensitivity of surface ozone to land cover change is more dependent on dry deposition than isoprene emission in most of East Asia.
L. Zhou, R. Gierens, A. Sogachev, D. Mogensen, J. Ortega, J. N. Smith, P. C. Harley, A. J. Prenni, E. J. T. Levin, A. Turnipseed, A. Rusanen, S. Smolander, A. B. Guenther, M. Kulmala, T. Karl, and M. Boy
Atmos. Chem. Phys., 15, 8643–8656, https://doi.org/10.5194/acp-15-8643-2015, https://doi.org/10.5194/acp-15-8643-2015, 2015
P. Achakulwisut, L. J. Mickley, L. T. Murray, A. P. K. Tai, J. O. Kaplan, and B. Alexander
Atmos. Chem. Phys., 15, 7977–7998, https://doi.org/10.5194/acp-15-7977-2015, https://doi.org/10.5194/acp-15-7977-2015, 2015
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The atmosphere’s oxidative capacity determines the lifetime of many trace gases important to climate, chemistry, and human health. Yet uncertainties remain about its past variations, its controlling factors, and the radiative forcing of short-lived species it influences. To reduce these uncertainties, we must better quantify the natural emissions and chemical reaction mechanisms of organic compounds in the atmosphere, which play a role in governing the oxidative capacity.
G. Wohlfahrt, C. Amelynck, C. Ammann, A. Arneth, I. Bamberger, A. H. Goldstein, L. Gu, A. Guenther, A. Hansel, B. Heinesch, T. Holst, L. Hörtnagl, T. Karl, Q. Laffineur, A. Neftel, K. McKinney, J. W. Munger, S. G. Pallardy, G. W. Schade, R. Seco, and N. Schoon
Atmos. Chem. Phys., 15, 7413–7427, https://doi.org/10.5194/acp-15-7413-2015, https://doi.org/10.5194/acp-15-7413-2015, 2015
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Methanol is the second most abundant volatile organic compound in the troposphere and plays a significant role in atmospheric chemistry. While there is consensus about the dominant role of plants as the major source and the reaction with OH as the major sink, global methanol budgets diverge considerably in terms of source/sink estimates. Here we present micrometeorological methanol flux data from eight sites in order to provide a first cross-site synthesis of the terrestrial methanol exchange.
S. Kim, S.-Y. Kim, M. Lee, H. Shim, G. M. Wolfe, A. B. Guenther, A. He, Y. Hong, and J. Han
Atmos. Chem. Phys., 15, 4357–4371, https://doi.org/10.5194/acp-15-4357-2015, https://doi.org/10.5194/acp-15-4357-2015, 2015
R. Thalman, M. T. Baeza-Romero, S. M. Ball, E. Borrás, M. J. S. Daniels, I. C. A. Goodall, S. B. Henry, T. Karl, F. N. Keutsch, S. Kim, J. Mak, P. S. Monks, A. Muñoz, J. Orlando, S. Peppe, A. R. Rickard, M. Ródenas, P. Sánchez, R. Seco, L. Su, G. Tyndall, M. Vázquez, T. Vera, E. Waxman, and R. Volkamer
Atmos. Meas. Tech., 8, 1835–1862, https://doi.org/10.5194/amt-8-1835-2015, https://doi.org/10.5194/amt-8-1835-2015, 2015
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Measurements of α-dicarbonyl compounds, like glyoxal (CHOCHO) and methyl glyoxal (CH3C(O)CHO), are informative about the rate of hydrocarbon oxidation, oxidative capacity, and secondary organic aerosol (SOA) formation in the atmosphere. We have compared nine instruments and seven techniques to measure α-dicarbonyl, using simulation chamber facilities in the US and Europe. We assess our understanding of calibration, precision, accuracy and detection limits, as well as possible sampling biases.
C. S. Brauer, T. A. Blake, A. B. Guenther, S. W. Sharpe, R. L. Sams, and T. J. Johnson
Atmos. Meas. Tech., 7, 3839–3847, https://doi.org/10.5194/amt-7-3839-2014, https://doi.org/10.5194/amt-7-3839-2014, 2014
Y. You, V. P. Kanawade, J. A. de Gouw, A. B. Guenther, S. Madronich, M. R. Sierra-Hernández, M. Lawler, J. N. Smith, S. Takahama, G. Ruggeri, A. Koss, K. Olson, K. Baumann, R. J. Weber, A. Nenes, H. Guo, E. S. Edgerton, L. Porcelli, W. H. Brune, A. H. Goldstein, and S.-H. Lee
Atmos. Chem. Phys., 14, 12181–12194, https://doi.org/10.5194/acp-14-12181-2014, https://doi.org/10.5194/acp-14-12181-2014, 2014
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Amiens play important roles in atmospheric secondary aerosol formation and human health, but the fast response measurements of amines are lacking. Here we show measurements in a southeastern US forest and a moderately polluted midwestern site. Our results show that gas to particle conversion is an important process that controls ambient amine concentrations and that biomass burning is an important source of amines.
P. K. Misztal, T. Karl, R. Weber, H. H. Jonsson, A. B. Guenther, and A. H. Goldstein
Atmos. Chem. Phys., 14, 10631–10647, https://doi.org/10.5194/acp-14-10631-2014, https://doi.org/10.5194/acp-14-10631-2014, 2014
S. Smolander, Q. He, D. Mogensen, L. Zhou, J. Bäck, T. Ruuskanen, S. Noe, A. Guenther, H. Aaltonen, M. Kulmala, and M. Boy
Biogeosciences, 11, 5425–5443, https://doi.org/10.5194/bg-11-5425-2014, https://doi.org/10.5194/bg-11-5425-2014, 2014
K. Sindelarova, C. Granier, I. Bouarar, A. Guenther, S. Tilmes, T. Stavrakou, J.-F. Müller, U. Kuhn, P. Stefani, and W. Knorr
Atmos. Chem. Phys., 14, 9317–9341, https://doi.org/10.5194/acp-14-9317-2014, https://doi.org/10.5194/acp-14-9317-2014, 2014
R. J. Park, S. K. Hong, H.-A. Kwon, S. Kim, A. Guenther, J.-H. Woo, and C. P. Loughner
Atmos. Chem. Phys., 14, 7929–7940, https://doi.org/10.5194/acp-14-7929-2014, https://doi.org/10.5194/acp-14-7929-2014, 2014
E. A. Marais, D. J. Jacob, A. Guenther, K. Chance, T. P. Kurosu, J. G. Murphy, C. E. Reeves, and H. O. T. Pye
Atmos. Chem. Phys., 14, 7693–7703, https://doi.org/10.5194/acp-14-7693-2014, https://doi.org/10.5194/acp-14-7693-2014, 2014
J. P. Greenberg, J. Peñuelas, A. Guenther, R. Seco, A. Turnipseed, X. Jiang, I. Filella, M. Estiarte, J. Sardans, R. Ogaya, J. Llusia, and F. Rapparini
Atmos. Meas. Tech., 7, 2263–2271, https://doi.org/10.5194/amt-7-2263-2014, https://doi.org/10.5194/amt-7-2263-2014, 2014
K. Jaars, J. P. Beukes, P. G. van Zyl, A. D. Venter, M. Josipovic, J. J. Pienaar, V. Vakkari, H. Aaltonen, H. Laakso, M. Kulmala, P. Tiitta, A. Guenther, H. Hellén, L. Laakso, and H. Hakola
Atmos. Chem. Phys., 14, 7075–7089, https://doi.org/10.5194/acp-14-7075-2014, https://doi.org/10.5194/acp-14-7075-2014, 2014
J. Ortega, A. Turnipseed, A. B. Guenther, T. G. Karl, D. A. Day, D. Gochis, J. A. Huffman, A. J. Prenni, E. J. T. Levin, S. M. Kreidenweis, P. J. DeMott, Y. Tobo, E. G. Patton, A. Hodzic, Y. Y. Cui, P. C. Harley, R. S. Hornbrook, E. C. Apel, R. K. Monson, A. S. D. Eller, J. P. Greenberg, M. C. Barth, P. Campuzano-Jost, B. B. Palm, J. L. Jimenez, A. C. Aiken, M. K. Dubey, C. Geron, J. Offenberg, M. G. Ryan, P. J. Fornwalt, S. C. Pryor, F. N. Keutsch, J. P. DiGangi, A. W. H. Chan, A. H. Goldstein, G. M. Wolfe, S. Kim, L. Kaser, R. Schnitzhofer, A. Hansel, C. A. Cantrell, R. L. Mauldin, and J. N. Smith
Atmos. Chem. Phys., 14, 6345–6367, https://doi.org/10.5194/acp-14-6345-2014, https://doi.org/10.5194/acp-14-6345-2014, 2014
M. Liu, K. Rajagopalan, S. H. Chung, X. Jiang, J. Harrison, T. Nergui, A. Guenther, C. Miller, J. Reyes, C. Tague, J. Choate, E. P. Salathé, C. O. Stöckle, and J. C. Adam
Biogeosciences, 11, 2601–2622, https://doi.org/10.5194/bg-11-2601-2014, https://doi.org/10.5194/bg-11-2601-2014, 2014
R. Zhang, T. Duhl, M. T. Salam, J. M. House, R. C. Flagan, E. L. Avol, F. D. Gilliland, A. Guenther, S. H. Chung, B. K. Lamb, and T. M. VanReken
Biogeosciences, 11, 1461–1478, https://doi.org/10.5194/bg-11-1461-2014, https://doi.org/10.5194/bg-11-1461-2014, 2014
L. Kaser, T. Karl, A. Guenther, M. Graus, R. Schnitzhofer, A. Turnipseed, L. Fischer, P. Harley, M. Madronich, D. Gochis, F. N. Keutsch, and A. Hansel
Atmos. Chem. Phys., 13, 11935–11947, https://doi.org/10.5194/acp-13-11935-2013, https://doi.org/10.5194/acp-13-11935-2013, 2013
S. Situ, A. Guenther, X. Wang, X. Jiang, A. Turnipseed, Z. Wu, J. Bai, and X. Wang
Atmos. Chem. Phys., 13, 11803–11817, https://doi.org/10.5194/acp-13-11803-2013, https://doi.org/10.5194/acp-13-11803-2013, 2013
N. Unger, K. Harper, Y. Zheng, N. Y. Kiang, I. Aleinov, A. Arneth, G. Schurgers, C. Amelynck, A. Goldstein, A. Guenther, B. Heinesch, C. N. Hewitt, T. Karl, Q. Laffineur, B. Langford, K. A. McKinney, P. Misztal, M. Potosnak, J. Rinne, S. Pressley, N. Schoon, and D. Serça
Atmos. Chem. Phys., 13, 10243–10269, https://doi.org/10.5194/acp-13-10243-2013, https://doi.org/10.5194/acp-13-10243-2013, 2013
J. E. Mak, L. Su, A. Guenther, and T. Karl
Atmos. Meas. Tech., 6, 2703–2712, https://doi.org/10.5194/amt-6-2703-2013, https://doi.org/10.5194/amt-6-2703-2013, 2013
X. Tie, F. Geng, A. Guenther, J. Cao, J. Greenberg, R. Zhang, E. Apel, G. Li, A. Weinheimer, J. Chen, and C. Cai
Atmos. Chem. Phys., 13, 5655–5669, https://doi.org/10.5194/acp-13-5655-2013, https://doi.org/10.5194/acp-13-5655-2013, 2013
R. Seco, J. Peñuelas, I. Filella, J. Llusia, S. Schallhart, A. Metzger, M. Müller, and A. Hansel
Atmos. Chem. Phys., 13, 4291–4306, https://doi.org/10.5194/acp-13-4291-2013, https://doi.org/10.5194/acp-13-4291-2013, 2013
T. R. Duhl, R. Zhang, A. Guenther, S. H. Chung, M. T. Salam, J. M. House, R. C. Flagan, E. L. Avol, F. D. Gilliland, B. K. Lamb, T. M. VanReken, Y. Zhang, and E. Salathé
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmdd-6-2325-2013, https://doi.org/10.5194/gmdd-6-2325-2013, 2013
Revised manuscript not accepted
L. Kaser, T. Karl, R. Schnitzhofer, M. Graus, I. S. Herdlinger-Blatt, J. P. DiGangi, B. Sive, A. Turnipseed, R. S. Hornbrook, W. Zheng, F. M. Flocke, A. Guenther, F. N. Keutsch, E. Apel, and A. Hansel
Atmos. Chem. Phys., 13, 2893–2906, https://doi.org/10.5194/acp-13-2893-2013, https://doi.org/10.5194/acp-13-2893-2013, 2013
Y. Wang, Q. Q. Zhang, K. He, Q. Zhang, and L. Chai
Atmos. Chem. Phys., 13, 2635–2652, https://doi.org/10.5194/acp-13-2635-2013, https://doi.org/10.5194/acp-13-2635-2013, 2013
M. J. Potosnak, B. M. Baker, L. LeStourgeon, S. M. Disher, K. L. Griffin, M. S. Bret-Harte, and G. Starr
Biogeosciences, 10, 871–889, https://doi.org/10.5194/bg-10-871-2013, https://doi.org/10.5194/bg-10-871-2013, 2013
T. R. Duhl, D. Gochis, A. Guenther, S. Ferrenberg, and E. Pendall
Biogeosciences, 10, 483–499, https://doi.org/10.5194/bg-10-483-2013, https://doi.org/10.5194/bg-10-483-2013, 2013
Related subject area
Subject: Biosphere Interactions | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Temporal and spatial variations in atmospheric unintentional PCB emissions in Chinese mainland from 1960 to 2019
Biogenic isoprene emissions, dry deposition velocity, and surface ozone concentration during summer droughts, heatwaves, and normal conditions in southwestern Europe
Interactive biogenic emissions and drought stress effects on atmospheric composition in NASA GISS ModelE
Plant gross primary production, plant respiration and carbonyl sulfide emissions over the globe inferred by atmospheric inverse modelling
Evaluation of interactive and prescribed agricultural ammonia emissions for simulating atmospheric composition in CAM-chem
Responses of surface ozone to future agricultural ammonia emissions and subsequent nitrogen deposition through terrestrial ecosystem changes
Modelling the influence of biotic plant stress on atmospheric aerosol particle processes throughout a growing season
Examining the competing effects of contemporary land management vs. land cover changes on global air quality
Improved gridded ammonia emission inventory in China
The impact of nitrogen and sulfur emissions from shipping on the exceedance of critical loads in the Baltic Sea region
Indirect contributions of global fires to surface ozone through ozone–vegetation feedback
Global and regional impacts of land cover changes on isoprene emissions derived from spaceborne data and the MEGAN model
A long-term estimation of biogenic volatile organic compound (BVOC) emission in China from 2001–2016: the roles of land cover change and climate variability
The regional European atmospheric transport inversion comparison, EUROCOM: first results on European-wide terrestrial carbon fluxes for the period 2006–2015
Quantifying the effects of environmental factors on wildfire burned area in the south central US using integrated machine learning techniques
Effects of fertilization and stand age on N2O and NO emissions from tea plantations: a site-scale study in a subtropical region using a modified biogeochemical model
Temperature response measurements from eucalypts give insight into the impact of Australian isoprene emissions on air quality in 2050
Data assimilation using an ensemble of models: a hierarchical approach
Fundamentals of data assimilation applied to biogeochemistry
On what scales can GOSAT flux inversions constrain anomalies in terrestrial ecosystems?
Historical (1700–2012) global multi-model estimates of the fire emissions from the Fire Modeling Intercomparison Project (FireMIP)
Contrasting effects of CO2 fertilization, land-use change and warming on seasonal amplitude of Northern Hemisphere CO2 exchange
The 2015–2016 carbon cycle as seen from OCO-2 and the global in situ network
Representing sub-grid scale variations in nitrogen deposition associated with land use in a global Earth system model: implications for present and future nitrogen deposition fluxes over North America
Global climate forcing driven by altered BVOC fluxes from 1990 to 2010 land cover change in maritime Southeast Asia
Coupling between surface ozone and leaf area index in a chemical transport model: strength of feedback and implications for ozone air quality and vegetation health
Contrasting interannual atmospheric CO2 variabilities and their terrestrial mechanisms for two types of El Niños
Vegetation greenness and land carbon-flux anomalies associated with climate variations: a focus on the year 2015
Biomass burning at Cape Grim: exploring photochemistry using multi-scale modelling
Wildfire air pollution hazard during the 21st century
Ozone and haze pollution weakens net primary productivity in China
How can mountaintop CO2 observations be used to constrain regional carbon fluxes?
Effects of ozone–vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks
Impact of Siberian observations on the optimization of surface CO2 flux
Modelling bidirectional fluxes of methanol and acetaldehyde with the FORCAsT canopy exchange model
The impact of historical land use change from 1850 to 2000 on secondary particulate matter and ozone
Global biogenic volatile organic compound emissions in the ORCHIDEE and MEGAN models and sensitivity to key parameters
Impacts of current and projected oil palm plantation expansion on air quality over Southeast Asia
Current estimates of biogenic emissions from eucalypts uncertain for southeast Australia
Air quality impacts of European wildfire emissions in a changing climate
Validation of the Swiss methane emission inventory by atmospheric observations and inverse modelling
Land cover change impacts on atmospheric chemistry: simulating projected large-scale tree mortality in the United States
High-resolution ammonia emissions inventories in China from 1980 to 2012
Delivery of anthropogenic bioavailable iron from mineral dust and combustion aerosols to the ocean
Impact of future land-cover changes on HNO3 and O3 surface dry deposition
Impact of climate and land cover changes on tropospheric ozone air quality and public health in East Asia between 1980 and 2010
Relationships between photosynthesis and formaldehyde as a probe of isoprene emission
A modified micrometeorological gradient method for estimating O3 dry depositions over a forest canopy
Biomass burning related ozone damage on vegetation over the Amazon forest: a model sensitivity study
Influence of CO2 observations on the optimized CO2 flux in an ensemble Kalman filter
Ye Li, Ye Huang, Yunshan Zhang, Wei Du, Shanshan Zhang, Tianhao He, Yan Li, Yan Chen, Fangfang Ding, Lin Huang, Haibin Xia, Wenjun Meng, Min Liu, and Shu Tao
Atmos. Chem. Phys., 23, 1091–1101, https://doi.org/10.5194/acp-23-1091-2023, https://doi.org/10.5194/acp-23-1091-2023, 2023
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Polychlorinated biphenyls (PCBs) are typical persistent organic pollutants (POPs) listed among the 12 initial POPs that should be prohibited or limited under the Stockholm Convention. They are widely present in the environment and pose a threat to human health and ecosystems. Emission estimation for them is essential to understand and evaluate their environment fate and associated health effect. This work developed 12 dioxin-like UP-PCBs from 66 sources from 1960 to 2019 in China.
Antoine Guion, Solène Turquety, Arineh Cholakian, Jan Polcher, Antoine Ehret, and Juliette Lathière
Atmos. Chem. Phys., 23, 1043–1071, https://doi.org/10.5194/acp-23-1043-2023, https://doi.org/10.5194/acp-23-1043-2023, 2023
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At high concentrations, tropospheric ozone (O3) deteriorates air quality. Weather conditions are key to understanding the variability in O3 concentration, especially during extremes. We suggest that identifying the presence of combined heatwaves is essential to the study of droughts in canopy–troposphere interactions and O3 concentration. Even so, they are associated, on average, with an increase in O3, partly explained by an increase in precursor emissions and a decrease in dry deposition.
Elizabeth Klovenski, Yuxuan Wang, Susanne E. Bauer, Kostas Tsigaridis, Greg Faluvegi, Igor Aleinov, Nancy Y. Kiang, Alex Guenther, Xiaoyan Jiang, Wei Li, and Nan Lin
Atmos. Chem. Phys., 22, 13303–13323, https://doi.org/10.5194/acp-22-13303-2022, https://doi.org/10.5194/acp-22-13303-2022, 2022
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Severe drought stresses vegetation and causes reduced emission of isoprene. We study the impact of including a new isoprene drought stress (yd) parameterization in NASA GISS ModelE called DroughtStress_ModelE, which is specifically tuned for ModelE. Inclusion of yd leads to better simulated isoprene emissions at the MOFLUX site during the severe drought of 2012, reduced overestimation of OMI satellite ΩHCHO (formaldehyde column), and improved simulated O3 (ozone) during drought.
Marine Remaud, Frédéric Chevallier, Fabienne Maignan, Sauveur Belviso, Antoine Berchet, Alexandra Parouffe, Camille Abadie, Cédric Bacour, Sinikka Lennartz, and Philippe Peylin
Atmos. Chem. Phys., 22, 2525–2552, https://doi.org/10.5194/acp-22-2525-2022, https://doi.org/10.5194/acp-22-2525-2022, 2022
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Carbonyl sulfide (COS) has been recognized as a promising indicator of the plant gross primary production (GPP). Here, we assimilate both COS and CO2 measurements into an atmospheric transport model to obtain information on GPP, plant respiration and COS budget. A possible scenario for the period 2008–2019 leads to a global COS biospheric sink of 800 GgS yr−1 and higher oceanic emissions between 400 and 600 GgS yr−1.
Julius Vira, Peter Hess, Money Ossohou, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 22, 1883–1904, https://doi.org/10.5194/acp-22-1883-2022, https://doi.org/10.5194/acp-22-1883-2022, 2022
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Ammonia is one of the main components of nitrogen deposition. Here we use a new model to assess the ammonia emissions from agriculture, the largest anthropogenic source of ammonia. The model results are consistent with earlier estimates over industrialized regions in agreement with observations. However, the model predicts much higher emissions over sub-Saharan Africa compared to earlier estimates. Available observations from surface stations and satellites support these higher emissions.
Xueying Liu, Amos P. K. Tai, and Ka Ming Fung
Atmos. Chem. Phys., 21, 17743–17758, https://doi.org/10.5194/acp-21-17743-2021, https://doi.org/10.5194/acp-21-17743-2021, 2021
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With the rising food need, more intense agricultural activities will cause substantial perturbations to the nitrogen cycle, aggravating surface air pollution and imposing stress on terrestrial ecosystems. We studied how these ecosystem changes may modify biosphere–atmosphere exchanges, and further exert secondary effects on air quality, and demonstrated a link between agricultural activities and ozone air quality via the modulation of vegetation and soil biogeochemistry by nitrogen deposition.
Ditte Taipale, Veli-Matti Kerminen, Mikael Ehn, Markku Kulmala, and Ülo Niinemets
Atmos. Chem. Phys., 21, 17389–17431, https://doi.org/10.5194/acp-21-17389-2021, https://doi.org/10.5194/acp-21-17389-2021, 2021
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Larval feeding and fungal infections of leaves can greatly change the emission of volatile compounds from plants and thereby influence aerosol processes in the air. We developed a model that considers the dynamics of larvae and fungi and the dependency of the emission on the severity of stress. We show that the infections can be highly atmospherically relevant during long periods of time and at times more important to consider than the parameters that are currently used in emission models.
Anthony Y. H. Wong and Jeffrey A. Geddes
Atmos. Chem. Phys., 21, 16479–16497, https://doi.org/10.5194/acp-21-16479-2021, https://doi.org/10.5194/acp-21-16479-2021, 2021
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Land cover change and land management are considered to have important and distinct impacts on air quality. Here we use remote sensing products and agricultural emission inventories to characterize contemporary global land cover and land management changes for chemical transport model simulations. We find that contemporary land system change has a significant impact on global air quality, with land management dominating the effects on PM and land cover change dominating the impacts on ozone.
Baojie Li, Lei Chen, Weishou Shen, Jianbing Jin, Teng Wang, Pinya Wang, Yang Yang, and Hong Liao
Atmos. Chem. Phys., 21, 15883–15900, https://doi.org/10.5194/acp-21-15883-2021, https://doi.org/10.5194/acp-21-15883-2021, 2021
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This study focused on improving fertilizer-application-related NH3 emission inventories. We comprehensively evaluated the dates and times of fertilizer application to the major crops in China, improved the spatial allocation methods for NH3 emissions from croplands with different rice types, and established a NH3 emission inventory for mainland China in 2016. The inventory showed a higher level of accuracy than other inventories based on evaluation using the WRF-Chem and observation data.
Sara Jutterström, Filip Moldan, Jana Moldanová, Matthias Karl, Volker Matthias, and Maximilian Posch
Atmos. Chem. Phys., 21, 15827–15845, https://doi.org/10.5194/acp-21-15827-2021, https://doi.org/10.5194/acp-21-15827-2021, 2021
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For the Baltic Sea countries, shipping emissions are an important source of air pollution. This study investigates the contribution of shipping emissions to the acidification and eutrophication of soils and freshwater within the airshed of the Baltic Sea in the years 2012 and 2040. The implementation of emission control areas and improving energy efficiency significantly reduces the negative impact on ecosystems expressed as a decrease in the exceedance of critical loads for sulfur and nitrogen.
Yadong Lei, Xu Yue, Hong Liao, Lin Zhang, Yang Yang, Hao Zhou, Chenguang Tian, Cheng Gong, Yimian Ma, Lan Gao, and Yang Cao
Atmos. Chem. Phys., 21, 11531–11543, https://doi.org/10.5194/acp-21-11531-2021, https://doi.org/10.5194/acp-21-11531-2021, 2021
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We present the first estimate of ozone enhancement by fire emissions through ozone–vegetation interactions using a fully coupled chemistry–vegetation model (GC-YIBs). In fire-prone areas, fire-induced ozone causes a positive feedback to surface ozone mainly because of the inhibition effects on stomatal conductance.
Beata Opacka, Jean-François Müller, Trissevgeni Stavrakou, Maite Bauwens, Katerina Sindelarova, Jana Markova, and Alex B. Guenther
Atmos. Chem. Phys., 21, 8413–8436, https://doi.org/10.5194/acp-21-8413-2021, https://doi.org/10.5194/acp-21-8413-2021, 2021
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Isoprene is mainly emitted from plants, and about 80 % of its global emissions occur in the tropics. Current isoprene inventories are usually based on modelled vegetation maps, but high pressure on land use over the last decades has led to severe losses, especially in tropical forests, that are not considered by models. We provide a study on the present-day impact of spaceborne land cover changes on isoprene emissions and the first inventory based on high-resolution Landsat tree cover dataset.
Hui Wang, Qizhong Wu, Alex B. Guenther, Xiaochun Yang, Lanning Wang, Tang Xiao, Jie Li, Jinming Feng, Qi Xu, and Huaqiong Cheng
Atmos. Chem. Phys., 21, 4825–4848, https://doi.org/10.5194/acp-21-4825-2021, https://doi.org/10.5194/acp-21-4825-2021, 2021
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We assessed the influence of the greening trend on BVOC emission in China. The comparison among different scenarios showed that vegetation changes resulting from land cover management are the main driver of BVOC emission change in China. Climate variability contributed significantly to interannual variations but not much to the long-term trend during the study period.
Guillaume Monteil, Grégoire Broquet, Marko Scholze, Matthew Lang, Ute Karstens, Christoph Gerbig, Frank-Thomas Koch, Naomi E. Smith, Rona L. Thompson, Ingrid T. Luijkx, Emily White, Antoon Meesters, Philippe Ciais, Anita L. Ganesan, Alistair Manning, Michael Mischurow, Wouter Peters, Philippe Peylin, Jerôme Tarniewicz, Matt Rigby, Christian Rödenbeck, Alex Vermeulen, and Evie M. Walton
Atmos. Chem. Phys., 20, 12063–12091, https://doi.org/10.5194/acp-20-12063-2020, https://doi.org/10.5194/acp-20-12063-2020, 2020
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The paper presents the first results from the EUROCOM project, a regional atmospheric inversion intercomparison exercise involving six European research groups. It aims to produce an estimate of the net carbon flux between the European terrestrial ecosystems and the atmosphere for the period 2006–2015, based on constraints provided by observed CO2 concentrations and using inverse modelling techniques. The use of six different models enables us to investigate the robustness of the results.
Sally S.-C. Wang and Yuxuan Wang
Atmos. Chem. Phys., 20, 11065–11087, https://doi.org/10.5194/acp-20-11065-2020, https://doi.org/10.5194/acp-20-11065-2020, 2020
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A model consisting of multiple machine learning algorithms is developed to predict wildfire burned area over the south central US and explains key environmental drivers. The developed model alleviates the issue of unevenly distributed data and predicts burned grids and burned areas with good accuracy. The model reveals climate variability such as relative humidity anomalies and antecedent drought severity contributes the most to the total burned area for winter–spring and summer fire season.
Wei Zhang, Zhisheng Yao, Xunhua Zheng, Chunyan Liu, Rui Wang, Kai Wang, Siqi Li, Shenghui Han, Qiang Zuo, and Jianchu Shi
Atmos. Chem. Phys., 20, 6903–6919, https://doi.org/10.5194/acp-20-6903-2020, https://doi.org/10.5194/acp-20-6903-2020, 2020
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The CNMM-DNDC model was modified by improving the scientific processes of soil pH reduction due to tea growth and performed well in simulating emissions of nitrous oxide and nitric oxide. Effects of manure fertilization and stand ages on emissions of both gases were well simulated. Simulated annual emission factors correlate positively with urea or manure doses. The overall inhibitory effects on the gases' emissions in the middle to late stages during a full tea plant lifetime were simulated.
Kathryn M. Emmerson, Malcolm Possell, Michael J. Aspinwall, Sebastian Pfautsch, and Mark G. Tjoelker
Atmos. Chem. Phys., 20, 6193–6206, https://doi.org/10.5194/acp-20-6193-2020, https://doi.org/10.5194/acp-20-6193-2020, 2020
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Australian cities with a high biogenic influence will see higher pollution levels in a warmer climate. We show that four Eucalyptus species grown in future-climate conditions can emit isoprene at temperatures 9 K above the peak temperatures capping isoprene in biogenic-emission models. With these measurements, we predict up to 2 ppb increases in isoprene in 2050, causing up to 21 ppb of ozone and 0.4 µg m−3 of aerosol in Sydney. The ozone increase is one-fifth of the hourly air quality limit.
Peter Rayner
Atmos. Chem. Phys., 20, 3725–3737, https://doi.org/10.5194/acp-20-3725-2020, https://doi.org/10.5194/acp-20-3725-2020, 2020
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This work extends previous calculations of carbon dioxide sources and sinks to take account of the varying quality of atmospheric models. It uses an extended version of Bayesian statistics which includes the model as one of the unknowns. I performed the work as an example of including the model in the description of the uncertainty.
Peter J. Rayner, Anna M. Michalak, and Frédéric Chevallier
Atmos. Chem. Phys., 19, 13911–13932, https://doi.org/10.5194/acp-19-13911-2019, https://doi.org/10.5194/acp-19-13911-2019, 2019
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This paper describes the methods for combining models and data to understand how nutrients and pollutants move through natural systems. The methods are analogous to the process of weather forecasting in which previous information is combined with new observations and a model to improve our knowledge of the internal state of the physical system. The methods appear highly diverse but the paper shows that they are all examples of a single underlying formalism.
Brendan Byrne, Dylan B. A. Jones, Kimberly Strong, Saroja M. Polavarapu, Anna B. Harper, David F. Baker, and Shamil Maksyutov
Atmos. Chem. Phys., 19, 13017–13035, https://doi.org/10.5194/acp-19-13017-2019, https://doi.org/10.5194/acp-19-13017-2019, 2019
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Interannual variations in net ecosystem exchange (NEE) estimated from the Greenhouse Gases Observing Satellite (GOSAT) XCO2 measurements are shown to be correlated (P < 0.05) with temperature and FLUXCOM NEE anomalies. Furthermore, the GOSAT-informed NEE anomalies are found to be better correlated with temperature and FLUXCOM anomalies than NEE estimates from most terrestrial biosphere models, suggesting that GOSAT CO2 measurements provide a useful constraint on NEE interannual variability.
Fang Li, Maria Val Martin, Meinrat O. Andreae, Almut Arneth, Stijn Hantson, Johannes W. Kaiser, Gitta Lasslop, Chao Yue, Dominique Bachelet, Matthew Forrest, Erik Kluzek, Xiaohong Liu, Stephane Mangeon, Joe R. Melton, Daniel S. Ward, Anton Darmenov, Thomas Hickler, Charles Ichoku, Brian I. Magi, Stephen Sitch, Guido R. van der Werf, Christine Wiedinmyer, and Sam S. Rabin
Atmos. Chem. Phys., 19, 12545–12567, https://doi.org/10.5194/acp-19-12545-2019, https://doi.org/10.5194/acp-19-12545-2019, 2019
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Fire emissions are critical for atmospheric composition, climate, carbon cycle, and air quality. We provide the first global multi-model fire emission reconstructions for 1700–2012, including carbon and 33 species of trace gases and aerosols, based on the nine state-of-the-art global fire models that participated in FireMIP. We also provide information on the recent status and limitations of the model-based reconstructions and identify the main uncertainty sources in their long-term changes.
Ana Bastos, Philippe Ciais, Frédéric Chevallier, Christian Rödenbeck, Ashley P. Ballantyne, Fabienne Maignan, Yi Yin, Marcos Fernández-Martínez, Pierre Friedlingstein, Josep Peñuelas, Shilong L. Piao, Stephen Sitch, William K. Smith, Xuhui Wang, Zaichun Zhu, Vanessa Haverd, Etsushi Kato, Atul K. Jain, Sebastian Lienert, Danica Lombardozzi, Julia E. M. S. Nabel, Philippe Peylin, Benjamin Poulter, and Dan Zhu
Atmos. Chem. Phys., 19, 12361–12375, https://doi.org/10.5194/acp-19-12361-2019, https://doi.org/10.5194/acp-19-12361-2019, 2019
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Here we show that land-surface models improved their ability to simulate the increase in the amplitude of seasonal CO2-cycle exchange (SCANBP) by ecosystems compared to estimates by two atmospheric inversions. We find a dominant role of vegetation growth over boreal Eurasia to the observed increase in SCANBP, strongly driven by CO2 fertilization, and an overall negative effect of temperature on SCANBP. Biases can be explained by the sensitivity of simulated microbial respiration to temperature.
Sean Crowell, David Baker, Andrew Schuh, Sourish Basu, Andrew R. Jacobson, Frederic Chevallier, Junjie Liu, Feng Deng, Liang Feng, Kathryn McKain, Abhishek Chatterjee, John B. Miller, Britton B. Stephens, Annmarie Eldering, David Crisp, David Schimel, Ray Nassar, Christopher W. O'Dell, Tomohiro Oda, Colm Sweeney, Paul I. Palmer, and Dylan B. A. Jones
Atmos. Chem. Phys., 19, 9797–9831, https://doi.org/10.5194/acp-19-9797-2019, https://doi.org/10.5194/acp-19-9797-2019, 2019
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Space-based retrievals of carbon dioxide offer the potential to provide dense data in regions that are sparsely observed by the surface network. We find that flux estimates that are informed by the Orbiting Carbon Observatory-2 (OCO-2) show different character from that inferred using surface measurements in tropical land regions, particularly in Africa, with a much larger total emission and larger amplitude seasonal cycle.
Fabien Paulot, Sergey Malyshev, Tran Nguyen, John D. Crounse, Elena Shevliakova, and Larry W. Horowitz
Atmos. Chem. Phys., 18, 17963–17978, https://doi.org/10.5194/acp-18-17963-2018, https://doi.org/10.5194/acp-18-17963-2018, 2018
Kandice L. Harper and Nadine Unger
Atmos. Chem. Phys., 18, 16931–16952, https://doi.org/10.5194/acp-18-16931-2018, https://doi.org/10.5194/acp-18-16931-2018, 2018
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Chemistry–climate modeling finds that the induced global-mean ozone forcing for 1990–2010 maritime Southeast Asian land cover change, including expansion of high-isoprene-emitting oil palm plantations, is +9.2 mW m−2. Regional land cover change drove stronger global-mean ozone enhancements in the upper troposphere than in the lower troposphere. The results indicate that this mechanism of ozone forcing may increase in importance in future years if regional oil palm expansion continues unabated.
Shan S. Zhou, Amos P. K. Tai, Shihan Sun, Mehliyar Sadiq, Colette L. Heald, and Jeffrey A. Geddes
Atmos. Chem. Phys., 18, 14133–14148, https://doi.org/10.5194/acp-18-14133-2018, https://doi.org/10.5194/acp-18-14133-2018, 2018
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Surface ozone pollution harms vegetation. As plants play key roles shaping air quality, the plant damage may further worsen air pollution. We use various computer models to examine such feedback effects, and find that ozone-induced decline in leaf density can lead to much higher ozone levels in forested regions, mostly due to the reduced ability of leaves to absorb pollutants. This study highlights the importance of considering the two-way interactions between plants and air pollution.
Jun Wang, Ning Zeng, Meirong Wang, Fei Jiang, Jingming Chen, Pierre Friedlingstein, Atul K. Jain, Ziqiang Jiang, Weimin Ju, Sebastian Lienert, Julia Nabel, Stephen Sitch, Nicolas Viovy, Hengmao Wang, and Andrew J. Wiltshire
Atmos. Chem. Phys., 18, 10333–10345, https://doi.org/10.5194/acp-18-10333-2018, https://doi.org/10.5194/acp-18-10333-2018, 2018
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Based on the Mauna Loa CO2 records and TRENDY multi-model historical simulations, we investigate the different impacts of EP and CP El Niños on interannual carbon cycle variability. Composite analysis indicates that the evolutions of CO2 growth rate anomalies have three clear differences in terms of precursors (negative and neutral), amplitudes (strong and weak), and durations of peak (Dec–Apr and Oct–Jan) during EP and CP El Niños, respectively. We further discuss their terrestrial mechanisms.
Chao Yue, Philippe Ciais, Ana Bastos, Frederic Chevallier, Yi Yin, Christian Rödenbeck, and Taejin Park
Atmos. Chem. Phys., 17, 13903–13919, https://doi.org/10.5194/acp-17-13903-2017, https://doi.org/10.5194/acp-17-13903-2017, 2017
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The year 2015 appeared as a paradox regarding how global carbon cycle has responded to climate variation: it is the greenest year since 2000 according to satellite observation, but the atmospheric CO2 growth rate is also the highest since 1959. We found that this is due to a only moderate land carbon sink, because high growing-season sink in northern lands has been partly offset by autumn and winter release and the late-year El Niño has led to an abrupt transition to land source in the tropics.
Sarah J. Lawson, Martin Cope, Sunhee Lee, Ian E. Galbally, Zoran Ristovski, and Melita D. Keywood
Atmos. Chem. Phys., 17, 11707–11726, https://doi.org/10.5194/acp-17-11707-2017, https://doi.org/10.5194/acp-17-11707-2017, 2017
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A high-resolution chemical transport model was used to reproduce observed smoke plumes. The model output was highly sensitive to fire emission factors and meteorology, particularly for secondary pollutant ozone. Aged urban air (age = 2 days) was the major source of ozone observed, with minor contributions from the fire. This work highlights the importance of assessing model sensitivity and the use of modelling to determine the contribution from different sources to atmospheric composition.
Wolfgang Knorr, Frank Dentener, Jean-François Lamarque, Leiwen Jiang, and Almut Arneth
Atmos. Chem. Phys., 17, 9223–9236, https://doi.org/10.5194/acp-17-9223-2017, https://doi.org/10.5194/acp-17-9223-2017, 2017
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Wildfires cause considerable air pollution, and climate change is usually expected to increase both wildfire activity and air pollution from those fires. This study takes a closer look at the problem by examining the role of demographic changes in addition to climate change. It finds that demographics will be the main driver of changes in wildfire activity in many parts of the developing world. Air pollution from wildfires will remain significant, with major implications for air quality policy.
Xu Yue, Nadine Unger, Kandice Harper, Xiangao Xia, Hong Liao, Tong Zhu, Jingfeng Xiao, Zhaozhong Feng, and Jing Li
Atmos. Chem. Phys., 17, 6073–6089, https://doi.org/10.5194/acp-17-6073-2017, https://doi.org/10.5194/acp-17-6073-2017, 2017
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While it is widely recognized that air pollutants adversely affect human health and climate change, their impacts on the regional carbon balance are less well understood. We apply an Earth system model to quantify the combined effects of ozone and aerosol particles on net primary production in China. Ozone vegetation damage dominates over the aerosol effects, leading to a substantial net suppression of land carbon uptake in the present and future worlds.
John C. Lin, Derek V. Mallia, Dien Wu, and Britton B. Stephens
Atmos. Chem. Phys., 17, 5561–5581, https://doi.org/10.5194/acp-17-5561-2017, https://doi.org/10.5194/acp-17-5561-2017, 2017
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Mountainous areas can potentially serve as regions where the key greenhouse gas, carbon dioxide (CO2), can be absorbed from the atmosphere by vegetation, through photosynthesis. Variations in atmospheric CO2 can be used to understand the amount of biospheric fluxes in general. However, CO2 measured in mountains can be difficult to interpret due to the impact from complex atmospheric flows. We show how mountaintop CO2 data can be interpreted by carrying out a series of atmospheric simulations.
Mehliyar Sadiq, Amos P. K. Tai, Danica Lombardozzi, and Maria Val Martin
Atmos. Chem. Phys., 17, 3055–3066, https://doi.org/10.5194/acp-17-3055-2017, https://doi.org/10.5194/acp-17-3055-2017, 2017
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Surface ozone harms vegetation, which can influence not only climate but also ozone air quality itself. We implement a scheme for ozone damage on vegetation into an Earth system model, so that for the first time simulated vegetation and ozone can coevolve in a fully coupled simulation. With ozone–vegetation coupling, simulated ozone is found to be significantly higher by up to 6 ppbv. Reduced dry deposition and enhanced isoprene emission contribute to most of these increases.
Jinwoong Kim, Hyun Mee Kim, Chun-Ho Cho, Kyung-On Boo, Andrew R. Jacobson, Motoki Sasakawa, Toshinobu Machida, Mikhail Arshinov, and Nikolay Fedoseev
Atmos. Chem. Phys., 17, 2881–2899, https://doi.org/10.5194/acp-17-2881-2017, https://doi.org/10.5194/acp-17-2881-2017, 2017
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To investigate the effect of CO2 observations in Siberia on the surface CO2 flux analyses, two experiments using observation data sets with and without Siberian measurements were performed. While the magnitude of the optimized surface CO2 flux uptake in Siberia decreased, that in the other regions of the Northern Hemisphere increased for the experiment with Siberian observations. It is expected that the Siberian observations play an important role in estimating surface CO2 flux in the future.
Kirsti Ashworth, Serena H. Chung, Karena A. McKinney, Ying Liu, J. William Munger, Scot T. Martin, and Allison L. Steiner
Atmos. Chem. Phys., 16, 15461–15484, https://doi.org/10.5194/acp-16-15461-2016, https://doi.org/10.5194/acp-16-15461-2016, 2016
Colette L. Heald and Jeffrey A. Geddes
Atmos. Chem. Phys., 16, 14997–15010, https://doi.org/10.5194/acp-16-14997-2016, https://doi.org/10.5194/acp-16-14997-2016, 2016
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Humans have altered the surface of the Earth since preindustrial times. These changes (largely expansion of croplands and pasturelands) have modified biosphere–atmosphere fluxes. In this study we use a global model to assess the impact of these changes on the formation of secondary particulate matter and troposphere ozone. We find that there are significant air quality and climate impacts associated with these changes.
Palmira Messina, Juliette Lathière, Katerina Sindelarova, Nicolas Vuichard, Claire Granier, Josefine Ghattas, Anne Cozic, and Didier A. Hauglustaine
Atmos. Chem. Phys., 16, 14169–14202, https://doi.org/10.5194/acp-16-14169-2016, https://doi.org/10.5194/acp-16-14169-2016, 2016
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We provide BVOC emissions for the present scenario, employing the updated ORCHIDEE emission module and the MEGAN model. The modelling community still faces the problem of emission model evaluation because of the absence of adequate observations. The accurate analysis performed, employing the two models, allowed the various processes modelled to be investigated, in order to fully understand the origin of the mismatch between the model estimates and to quantify the emission uncertainties.
Sam J. Silva, Colette L. Heald, Jeffrey A. Geddes, Kemen G. Austin, Prasad S. Kasibhatla, and Miriam E. Marlier
Atmos. Chem. Phys., 16, 10621–10635, https://doi.org/10.5194/acp-16-10621-2016, https://doi.org/10.5194/acp-16-10621-2016, 2016
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We investigate the impacts of current (2010) and future (2020) oil palm plantations across Southeast Asia on surface–atmosphere exchange and air quality using satellite data, land maps, and a chemical transport model. These changes lead to increases in surface ozone and particulate matter. Oil palm plantations are likely to continue to degrade regional air quality in the coming decade and hinder efforts to achieve air quality regulations in major urban areas such as Kuala Lumpur and Singapore.
Kathryn M. Emmerson, Ian E. Galbally, Alex B. Guenther, Clare Paton-Walsh, Elise-Andree Guerette, Martin E. Cope, Melita D. Keywood, Sarah J. Lawson, Suzie B. Molloy, Erin Dunne, Marcus Thatcher, Thomas Karl, and Simin D. Maleknia
Atmos. Chem. Phys., 16, 6997–7011, https://doi.org/10.5194/acp-16-6997-2016, https://doi.org/10.5194/acp-16-6997-2016, 2016
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We have tested how a model using a global inventory of plant-based emissions compares with four sets of measurements made in southeast Australia. This region is known for its eucalypt species, which dominate the summertime global inventory. The Australian part of the inventory has been produced using measurements made on eucalypt saplings. The model could not match the measurements, and the inventory needs to be improved by taking measurements of a wider range of Australian plant types and ages.
Wolfgang Knorr, Frank Dentener, Stijn Hantson, Leiwen Jiang, Zbigniew Klimont, and Almut Arneth
Atmos. Chem. Phys., 16, 5685–5703, https://doi.org/10.5194/acp-16-5685-2016, https://doi.org/10.5194/acp-16-5685-2016, 2016
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Wildfires are generally expected to increase in frequency and severity due to climate change. For Europe this could mean increased air pollution levels during the summer. Until 2050, predicted changes are moderate, but under a scenario of strong climate change, these may increase considerably during the later part of the current century. In Portugal and several parts of the Mediterranean, emissions may become relevant for meeting WHO concentration targets.
Stephan Henne, Dominik Brunner, Brian Oney, Markus Leuenberger, Werner Eugster, Ines Bamberger, Frank Meinhardt, Martin Steinbacher, and Lukas Emmenegger
Atmos. Chem. Phys., 16, 3683–3710, https://doi.org/10.5194/acp-16-3683-2016, https://doi.org/10.5194/acp-16-3683-2016, 2016
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Greenhouse gas emissions can be assessed by "top-down" methods that combine atmospheric observations, a transport model and a mathematical optimisation framework. Here, we apply such a top-down method to the methane emissions of Switzerland, utilising observations from the recently installed CarboCount-CH network. Our Swiss total emissions largely agree with those of the national "bottom-up" inventory, whereas regional differences suggest lower than reported emissions from manure handling.
Jeffrey A. Geddes, Colette L. Heald, Sam J. Silva, and Randall V. Martin
Atmos. Chem. Phys., 16, 2323–2340, https://doi.org/10.5194/acp-16-2323-2016, https://doi.org/10.5194/acp-16-2323-2016, 2016
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Land use and land cover changes driven by anthropogenic activities or natural causes (e.g., forestry management, agriculture, wildfires) can impact climate and air quality in many complex ways. Using a state-of-the-art chemistry model, we investigate how tree mortality in the US due to insect infestation and disease outbreak may impact atmospheric composition. We find that the surface concentrations of ozone and aerosol can be altered due to changing background emissions and loss processes.
Yaning Kang, Mingxu Liu, Yu Song, Xin Huang, Huan Yao, Xuhui Cai, Hongsheng Zhang, Ling Kang, Xuejun Liu, Xiaoyuan Yan, Hong He, Qiang Zhang, Min Shao, and Tong Zhu
Atmos. Chem. Phys., 16, 2043–2058, https://doi.org/10.5194/acp-16-2043-2016, https://doi.org/10.5194/acp-16-2043-2016, 2016
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The multi-year (1980–2012) comprehensive ammonia emissions inventories were compiled for China on 1 km × 1 km grid.
Various realistic parameters (ambient temperature, wind speed, soil acidity, synthetic fertilizer types, etc.) were considered in these inventories to synthetically refine the emission factors of ammonia volatilization according to local agricultural practice.
This paper shows the interannual trend and spatial distribution of ammonia emissions in details over recent decades.
A. Ito and Z. Shi
Atmos. Chem. Phys., 16, 85–99, https://doi.org/10.5194/acp-16-85-2016, https://doi.org/10.5194/acp-16-85-2016, 2016
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A new Fe dissolution scheme is developed and is applied to an atmospheric chemistry transport model to estimate anthropogenic soluble Fe deposition. Our improved model successfully captured an inverse relationship of Fe solubility and total Fe loading. Our model estimated the low end of Fe solubility compared to the previous studies. Our model results suggest that human activities contribute to about half of bioavailable Fe supply to significant portions of the oceans in the Northern Hemisphere.
T. Verbeke, J. Lathière, S. Szopa, and N. de Noblet-Ducoudré
Atmos. Chem. Phys., 15, 13555–13568, https://doi.org/10.5194/acp-15-13555-2015, https://doi.org/10.5194/acp-15-13555-2015, 2015
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Dry deposition is a key component of surface-atmosphere exchange of compounds, acting as a sink for several chemical species and strongly driven by meteorological factors, chemical properties of the trace gas considered and land surface properties. The objective of our study is to investigate the impact of vegetation distribution change, which is still not very well quantified, on the dry deposition of key atmospheric species: ozone and nitric acid vapor.
Y. Fu and A. P. K. Tai
Atmos. Chem. Phys., 15, 10093–10106, https://doi.org/10.5194/acp-15-10093-2015, https://doi.org/10.5194/acp-15-10093-2015, 2015
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Historical land cover and land use change alone between 1980 and 2010 could lead to reduced summertime surface ozone by up to 4ppbv in East Asia. Climate change alone could lead to an increase in summertime ozone by 2-10ppbv in most of East Asia. Land cover change could offset part of the climate effect and lead to a previously unknown public health benefit. The sensitivity of surface ozone to land cover change is more dependent on dry deposition than isoprene emission in most of East Asia.
Y. Zheng, N. Unger, M. P. Barkley, and X. Yue
Atmos. Chem. Phys., 15, 8559–8576, https://doi.org/10.5194/acp-15-8559-2015, https://doi.org/10.5194/acp-15-8559-2015, 2015
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We apply two global observational data sets, gross primary productivity (GPP) and tropospheric formaldehyde column variability (HCHOv), to probe isoprene emission variability on large spatiotemporal scales. GPP and HCHOv are decoupled or weakly anticorrelated in regions and seasons when isoprene emission is high. Isoprene emission models that include soil moisture dependence demonstrate greater skill in reproducing observed seasonal GPP-HCHOv correlations in the southeast US and the Amazon.
Z. Y. Wu, L. Zhang, X. M. Wang, and J. W. Munger
Atmos. Chem. Phys., 15, 7487–7496, https://doi.org/10.5194/acp-15-7487-2015, https://doi.org/10.5194/acp-15-7487-2015, 2015
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In this study, we have developed a modified micrometeorological gradient method (MGM), although based on existing micrometeorological theory, to estimate O3 dry deposition fluxes over a forest canopy using concentration gradients between a level above and a level below the canopy top. The new method provides an alternative approach in monitoring/estimating long-term deposition fluxes of similar pollutants over tall canopies and is expected to be useful for the scientific community.
F. Pacifico, G. A. Folberth, S. Sitch, J. M. Haywood, L. V. Rizzo, F. F. Malavelle, and P. Artaxo
Atmos. Chem. Phys., 15, 2791–2804, https://doi.org/10.5194/acp-15-2791-2015, https://doi.org/10.5194/acp-15-2791-2015, 2015
J. Kim, H. M. Kim, and C.-H. Cho
Atmos. Chem. Phys., 14, 13515–13530, https://doi.org/10.5194/acp-14-13515-2014, https://doi.org/10.5194/acp-14-13515-2014, 2014
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Short summary
Drought can cause large changes in biogenic isoprene emissions. In situ field observations of isoprene emissions during droughts are confined by spatial coverage and, thus, provide limited constraints. We derived a drought stress factor based on satellite HCHO data for MEGAN2.1 in the GEOS-Chem model using water stress and temperature. This factor reduces the overestimation of isoprene emissions during severe droughts and improves the simulated O3 and organic aerosol responses to droughts.
Drought can cause large changes in biogenic isoprene emissions. In situ field observations of...
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