Articles | Volume 21, issue 10
Atmos. Chem. Phys., 21, 7845–7862, 2021
https://doi.org/10.5194/acp-21-7845-2021
Atmos. Chem. Phys., 21, 7845–7862, 2021
https://doi.org/10.5194/acp-21-7845-2021

Research article 22 May 2021

Research article | 22 May 2021

On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames

Roland Benoit et al.

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Revised manuscript under review for ACP
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Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

An, Y., Xu, J., Feng, L., Zhang, X., Liu, Y., Kang, S., Jiang, B., and Liao, Y.: Molecular characterization of organic aerosol in the Himalayas: insight from ultra-high-resolution mass spectrometry, Atmos. Chem. Phys., 19, 1115–1128, https://doi.org/10.5194/acp-19-1115-2019, 2019. 
Atkinson, R. and Carter, W. P. L.: Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2, J. Atmos. Chem., 13, 195–210, https://doi.org/10.1007/BF00115973, 1991. 
Bailey, H. C. and Norrish, R. G. W.: The oxidation of hexane in the cool-flame region, P. R. Soc. London, 212, 311–330, https://doi.org/10.1098/rspa.1952.0084, 1952. 
Baldwin, A. C. and Golden, D. M.: Alkoxy radical reactions: the isomerization of n-butoxy radicals generated from the pyrolysis of n-butyl nitrite, Chem. Phys. Lett., 60, 108–111, https://doi.org/10.1016/0009-2614(78)85722-4, 1978. 
Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Time-resolved molecular characterization of limonene/ozone aerosol using high-resolution electrospray ionization mass spectrometry, Phys. Chem. Chem. Phys., 11, 7931–7942, https://doi.org/10.1039/B905288G, 2009. 
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This study compares different modes of limonene oxidation (ozonolysis, photooxidation, and cool flame) on the basis of review articles and experimental results. Although the oxidation conditions are totally different, the results obtained present great similarities in the nature of the products but also specificities related to autooxidation such as the presence of keto-hydroperoxides.
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