Articles | Volume 21, issue 10
Atmos. Chem. Phys., 21, 7845–7862, 2021
https://doi.org/10.5194/acp-21-7845-2021
Atmos. Chem. Phys., 21, 7845–7862, 2021
https://doi.org/10.5194/acp-21-7845-2021

Research article 22 May 2021

Research article | 22 May 2021

On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames

Roland Benoit et al.

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Importance of secondary organic aerosol formation of α-pinene, limonene, and m-cresol comparing day- and nighttime radical chemistry
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SO2 and NH3 emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon
Zhaomin Yang, Li Xu, Narcisse T. Tsona, Jianlong Li, Xin Luo, and Lin Du
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Enhanced secondary organic aerosol formation from the photo-oxidation of mixed anthropogenic volatile organic compounds
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Cited articles

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Bailey, H. C. and Norrish, R. G. W.: The oxidation of hexane in the cool-flame region, P. R. Soc. London, 212, 311–330, https://doi.org/10.1098/rspa.1952.0084, 1952. 
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Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Time-resolved molecular characterization of limonene/ozone aerosol using high-resolution electrospray ionization mass spectrometry, Phys. Chem. Chem. Phys., 11, 7931–7942, https://doi.org/10.1039/B905288G, 2009. 
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Short summary
This study compares different modes of limonene oxidation (ozonolysis, photooxidation, and cool flame) on the basis of review articles and experimental results. Although the oxidation conditions are totally different, the results obtained present great similarities in the nature of the products but also specificities related to autooxidation such as the presence of keto-hydroperoxides.
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