Articles | Volume 19, issue 12
https://doi.org/10.5194/acp-19-8003-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-8003-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Jun 2019
Research article |
| 18 Jun 2019
| 18 Jun 2019
Interaction between succinic acid and sulfuric acid–base clusters
Department of Atmospheric Sciences and Department of Chemistry,
Texas A&M University, College Station, TX 77843, USA
Department of Atmospheric Sciences and Department of Chemistry,
Texas A&M University, College Station, TX 77843, USA
Guangzhou Key Laboratory Environmental Catalysis and Pollution Control, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, School of Environmental Science and Engineering, Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006, China
Yixin Li
Department of Atmospheric Sciences and Department of Chemistry,
Texas A&M University, College Station, TX 77843, USA
Jeremiah Secrest
Department of Atmospheric Sciences and Department of Chemistry,
Texas A&M University, College Station, TX 77843, USA
Aerodyne Research Inc, Billerica, MA 01821, USA
Fei Xu
Environment Research Institute, Shandong University, Qingdao 266237, China
Yuan Wang
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA 91125, USA
Taicheng An
Guangzhou Key Laboratory Environmental Catalysis and Pollution Control, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, School of Environmental Science and Engineering, Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006, China
Department of Atmospheric Sciences and Department of Chemistry,
Texas A&M University, College Station, TX 77843, USA
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Xiaojian Zheng, Baike Xi, Xiquan Dong, Timothy Logan, Yuan Wang, and Peng Wu
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Atmos. Chem. Phys., 19, 7719–7742, https://doi.org/10.5194/acp-19-7719-2019, https://doi.org/10.5194/acp-19-7719-2019, 2019
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Hao Guo, Sri Harsha Kota, Kaiyu Chen, Shovan Kumar Sahu, Jianlin Hu, Qi Ying, Yuan Wang, and Hongliang Zhang
Atmos. Chem. Phys., 18, 15219–15229, https://doi.org/10.5194/acp-18-15219-2018, https://doi.org/10.5194/acp-18-15219-2018, 2018
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Gehui Wang, Fang Zhang, Jianfei Peng, Lian Duan, Yuemeng Ji, Wilmarie Marrero-Ortiz, Jiayuan Wang, Jianjun Li, Can Wu, Cong Cao, Yuan Wang, Jun Zheng, Jeremiah Secrest, Yixin Li, Yuying Wang, Hong Li, Na Li, and Renyi Zhang
Atmos. Chem. Phys., 18, 10123–10132, https://doi.org/10.5194/acp-18-10123-2018, https://doi.org/10.5194/acp-18-10123-2018, 2018
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We have adopted a new technique for measuring glass-forming properties of atmospherically relevant organic aerosols at submicron sizes and relatively low mass concentrations. Aerosol particles are deposited in the form of a thin film with interdigitated electrodes using electrostatic precipitation. Broadband dielectric spectroscopy is used to measure the kinetically controlled glass transition temperatures of glycerol and citric acid aerosols with three atmospheric relevant cooling rates.
Pengfei Tian, Lei Zhang, Jianmin Ma, Kai Tang, Lili Xu, Yuan Wang, Xianjie Cao, Jiening Liang, Yuemeng Ji, Jonathan H. Jiang, Yuk L. Yung, and Renyi Zhang
Atmos. Chem. Phys., 18, 7815–7825, https://doi.org/10.5194/acp-18-7815-2018, https://doi.org/10.5194/acp-18-7815-2018, 2018
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The mixing of dust and anthropogenic pollution over East Asia plays a significant yet poorly quantified role in aerosol radiative effects. We have found that radiative absorption of the East Asian aerosol mixtures are significantly enhanced. Our results show that the interaction between dust and anthropogenic pollution not only represents a viable aerosol formation pathway but also results in unfavorable dispersion conditions, both exacerbating the regional air pollution in East Asia.
Jianfei Peng, Min Hu, Song Guo, Zhuofei Du, Dongjie Shang, Jing Zheng, Jun Zheng, Limin Zeng, Min Shao, Yusheng Wu, Don Collins, and Renyi Zhang
Atmos. Chem. Phys., 17, 10333–10348, https://doi.org/10.5194/acp-17-10333-2017, https://doi.org/10.5194/acp-17-10333-2017, 2017
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Rapid growth of BC particles was observed in Beijing using a new outdoor chamber, with an average growth rate of 26 ± 11 nm h−1. Secondary organic aerosol (SOA) accounted for more than 90 % of the coating mass. The hygroscopic growth factor of BC particles increased to 1.06–1.08 upon ageing. The κ (kappa) values for BC particles were calculated as only 0.035, indicating that initial photochemical ageing of BC particles does not appreciably alter the particle hygroscopicity in Beijing.
Yujiao Zhu, Caiqing Yan, Renyi Zhang, Zifa Wang, Mei Zheng, Huiwang Gao, Yang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 17, 9469–9484, https://doi.org/10.5194/acp-17-9469-2017, https://doi.org/10.5194/acp-17-9469-2017, 2017
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This study reports the distinct effects of street canyons on new particle formation (NPF) under warm or cold ambient temperature conditions because of on-road vehicle emissions; i.e., stronger condensation sinks are responsible for the reduced NPF in the springtime, but efficient nucleation and partitioning of gaseous species contribute to the enhanced NPF in the wintertime. The oxidization of biogenic organics is suggested to play an important role in growing new particles.
Pengfei Tian, Xianjie Cao, Lei Zhang, Naixiu Sun, Lu Sun, Timothy Logan, Jinsen Shi, Yuan Wang, Yuemeng Ji, Yun Lin, Zhongwei Huang, Tian Zhou, Yingying Shi, and Renyi Zhang
Atmos. Chem. Phys., 17, 2509–2523, https://doi.org/10.5194/acp-17-2509-2017, https://doi.org/10.5194/acp-17-2509-2017, 2017
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We have investigated the vertical distribution and optical properties of aerosols over China using long-term satellite observations from the Cloud–Aerosol Lidar with Orthogonal Polarization, ground-based lidar observations and Aerosol Robotic Network data. Our results provide key information on the long-term aerosol seasonal and spatial variations, optical properties, regional types, long-range transport and atmospheric stability in China for air quality and climate studies.
Xuan Zhang, Jordan E. Krechmer, Michael Groessl, Wen Xu, Stephan Graf, Michael Cubison, John T. Jayne, Jose L. Jimenez, Douglas R. Worsnop, and Manjula R. Canagaratna
Atmos. Chem. Phys., 16, 12945–12959, https://doi.org/10.5194/acp-16-12945-2016, https://doi.org/10.5194/acp-16-12945-2016, 2016
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We develop a novel two-dimensional space to probe the molecular composition of atmospheric organic aerosols.
C. He, K.-N. Liou, Y. Takano, R. Zhang, M. Levy Zamora, P. Yang, Q. Li, and L. R. Leung
Atmos. Chem. Phys., 15, 11967–11980, https://doi.org/10.5194/acp-15-11967-2015, https://doi.org/10.5194/acp-15-11967-2015, 2015
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Importance of aerosol composition and aerosol vertical profiles in global spatial variation in the relationship between PM2.5 and aerosol optical depth
The co-benefits of a low-carbon future for PM2.5 and O3 air pollution in Europe
Assessing the effectiveness of SO2, NOx, and NH3 emission reductions in mitigating winter PM2.5 in Taiwan using CMAQ
Modelling of atmospheric concentrations of fungal spores: a 2-year simulation over France using CHIMERE
Cluster-dynamics-based parameterization for sulfuric acid–dimethylamine nucleation: comparison and selection through box and three-dimensional modeling
Observed and CMIP6-model-simulated organic aerosol response to drought in the contiguous United States during summertime
Cooling radiative forcing effect enhancement of atmospheric amines and mineral particles caused by heterogeneous uptake and oxidation
Source-resolved atmospheric metal emissions, concentrations, and deposition fluxes into the East Asian seas
Quantifying the impact of global nitrate aerosol on tropospheric composition fields and its production from lightning NOx
Analysis of secondary inorganic aerosols over the greater Athens area using the EPISODE–CityChem source dispersion and photochemistry model
Global estimates of ambient reactive nitrogen components during 2000–2100 based on the multi-stage model
Quantifying the Impacts of Marine Aerosols over the Southeast Atlantic Ocean using a chemical transport model: Implications for aerosol-cloud interactions
The role of naphthalene and its derivatives in the formation of secondary organic aerosol in the Yangtze River Delta region, China
Unveiling the optimal regression model for source apportionment of the oxidative potential of PM10
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 2: Modeling chemical drivers and 3-D new particle formation occurrence
Technical note: Influence of different averaging metrics and temporal resolutions on the aerosol pH calculated by thermodynamic modeling
Dual roles of the inorganic aqueous phase on secondary organic aerosol growth from benzene and phenol
Global source apportionment of aerosols into major emission regions and sectors over 1850–2017
Modeling atmospheric brown carbon in the GISS ModelE Earth system model
Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere
Significant impact of urban tree biogenic emissions on air quality estimated by a bottom-up inventory and chemistry transport modeling
Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state
Modeling the contribution of leads to sea spray aerosol in the high Arctic
Modeling the drivers of fine PM pollution over Central Europe: impacts and contributions of emissions from different sources
Reaction of SO3 with H2SO4 and its implications for aerosol particle formation in the gas phase and at the air–water interface
Weakened aerosol–radiation interaction exacerbating ozone pollution in eastern China since China's clean air actions
Uncertainties from biomass burning aerosols in air quality models obscure public health impacts in Southeast Asia
Oxidative potential apportionment of atmospheric PM1: a new approach combining high-sensitive online analysers for chemical composition and offline OP measurement technique
Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon
An updated modeling framework to simulate Los Angeles air quality – Part 1: Model development, evaluation, and source apportionment
Frequent haze events associated with transport and stagnation over the corridor between the North China Plain and Yangtze River Delta
Evaluation of WRF-Chem-simulated meteorology and aerosols over northern India during the severe pollution episode of 2016
How well are aerosol–cloud interactions represented in climate models? – Part 1: Understanding the sulfate aerosol production from the 2014–15 Holuhraun eruption
pH regulates the formation of organosulfates and inorganic sulfate from organic peroxide reaction with dissolved SO2 in aquatic media
Technical note: Accurate, reliable, and high-resolution air quality predictions by improving the Copernicus Atmosphere Monitoring Service using a novel statistical post-processing method
Measurement report: Rapid oxidation of phenolic compounds by O3 and HO•: effects of air-water interface and mineral dust in tropospheric chemical processes
Contribution of intermediate-volatility organic compounds from on-road transport to secondary organic aerosol levels in Europe
Development of an integrated model framework for multi-air-pollutant exposure assessments in high-density cities
CAMx–UNIPAR simulation of secondary organic aerosol mass formed from multiphase reactions of hydrocarbons under the Central Valley urban atmospheres of California
Impact of urbanization on fine particulate matter concentrations over central Europe
Measurement report: Assessing the impacts of emission uncertainty on aerosol optical properties and radiative forcing from biomass burning in peninsular Southeast Asia
The Emissions Model Intercomparison Project (Emissions-MIP): quantifying model sensitivity to emission characteristics
Dynamics-based estimates of decline trend with fine temporal variations in China's PM2.5 emissions
Effects of simulated secondary organic aerosol water on PM1 levels and composition over the US
Reactive organic carbon air emissions from mobile sources in the United States
Development and evaluation of processes affecting simulation of diel fine particulate matter variation in the GEOS-Chem model
Substantially positive contributions of new particle formation to cloud condensation nuclei under low supersaturation in China based on numerical model improvements
Evolution of atmospheric age of particles and its implications for the formation of a severe haze event in eastern China
A multimodel evaluation of the potential impact of shipping on particle species in the Mediterranean Sea
How does tropospheric VOC chemistry affect climate? An investigation of preindustrial control simulations using the Community Earth System Model version 2
Haihui Zhu, Randall V. Martin, Aaron van Donkelaar, Melanie S. Hammer, Chi Li, Jun Meng, Christopher R. Oxford, Xuan Liu, Yanshun Li, Dandan Zhang, Inderjeet Singh, and Alexei Lyapustin
Atmos. Chem. Phys., 24, 11565–11584, https://doi.org/10.5194/acp-24-11565-2024, https://doi.org/10.5194/acp-24-11565-2024, 2024
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Ambient fine particulate matter (PM2.5) contributes to 4 million deaths globally each year. Satellite remote sensing of aerosol optical depth (AOD), coupled with a simulated PM2.5–AOD relationship (η), can provide global PM2.5 estimations. This study aims to understand the spatial patterns and driving factors of η to guide future measurement and modeling efforts. We quantified η globally and regionally and found that its spatial variation is strongly influenced by aerosol composition.
Connor J. Clayton, Daniel R. Marsh, Steven T. Turnock, Ailish M. Graham, Kirsty J. Pringle, Carly L. Reddington, Rajesh Kumar, and James B. McQuaid
Atmos. Chem. Phys., 24, 10717–10740, https://doi.org/10.5194/acp-24-10717-2024, https://doi.org/10.5194/acp-24-10717-2024, 2024
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We demonstrate that strong climate mitigation could improve air quality in Europe; however, less ambitious mitigation does not result in these co-benefits. We use a high-resolution atmospheric chemistry model. This allows us to demonstrate how this varies across European countries and analyse the underlying chemistry. This may help policy-facing researchers understand which sectors and regions need to be prioritised to achieve strong air quality co-benefits of climate mitigation.
Ping-Chieh Huang, Hui-Ming Hung, Hsin-Chih Lai, and Charles C.-K. Chou
Atmos. Chem. Phys., 24, 10759–10772, https://doi.org/10.5194/acp-24-10759-2024, https://doi.org/10.5194/acp-24-10759-2024, 2024
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Models were used to study ways to reduce particulate matter (PM) pollution in Taiwan during winter. After considering various factors, such as physical processes and chemical reactions, we found that reducing NOx or NH3 emissions is more effective at mitigating PM2.5 than reducing SO2 emissions. When considering both efficiency and cost, reducing NH3 emissions seems to be a more suitable policy for the studied environment in Taiwan.
Matthieu Vida, Gilles Foret, Guillaume Siour, Florian Couvidat, Olivier Favez, Gaelle Uzu, Arineh Cholakian, Sébastien Conil, Matthias Beekmann, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 24, 10601–10615, https://doi.org/10.5194/acp-24-10601-2024, https://doi.org/10.5194/acp-24-10601-2024, 2024
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We simulate 2 years of atmospheric fungal spores over France and use observations of polyols and primary biogenic factors from positive matrix factorisation. The representation of emissions taking into account a proxy for vegetation surface and specific humidity enables us to reproduce very accurately the seasonal cycle of fungal spores. Furthermore, we estimate that fungal spores can account for 20 % of PM10 and 40 % of the organic fraction of PM10 over vegetated areas in summer.
Jiewen Shen, Bin Zhao, Shuxiao Wang, An Ning, Yuyang Li, Runlong Cai, Da Gao, Biwu Chu, Yang Gao, Manish Shrivastava, Jingkun Jiang, Xiuhui Zhang, and Hong He
Atmos. Chem. Phys., 24, 10261–10278, https://doi.org/10.5194/acp-24-10261-2024, https://doi.org/10.5194/acp-24-10261-2024, 2024
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We extensively compare various cluster-dynamics-based parameterizations for sulfuric acid–dimethylamine nucleation and identify a newly developed parameterization derived from Atmospheric Cluster Dynamic Code (ACDC) simulations as being the most reliable one. This study offers a valuable reference for developing parameterizations of other nucleation systems and is meaningful for the accurate quantification of the environmental and climate impacts of new particle formation.
Wei Li and Yuxuan Wang
Atmos. Chem. Phys., 24, 9339–9353, https://doi.org/10.5194/acp-24-9339-2024, https://doi.org/10.5194/acp-24-9339-2024, 2024
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Droughts immensely increased organic aerosol (OA) in the contiguous United States in summer (1998–2019), notably in the Pacific Northwest (PNW) and Southeast (SEUS). The OA rise in the SEUS is driven by the enhanced formation of epoxydiol-derived secondary organic aerosol due to the increase in biogenic volatile organic compounds and sulfate, while in the PNW, it is caused by wildfires. A total of 10 climate models captured the OA increase in the PNW yet greatly underestimated it in the SEUS.
Weina Zhang, Jianhua Mai, Zhichao Fan, Yongpeng Ji, Yuemeng Ji, Guiying Li, Yanpeng Gao, and Taicheng An
Atmos. Chem. Phys., 24, 9019–9030, https://doi.org/10.5194/acp-24-9019-2024, https://doi.org/10.5194/acp-24-9019-2024, 2024
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This study reveals heterogeneous oxidation causes further radiative forcing effect (RFE) enhancement of amine–mineral mixed particles. Note that RFE increment is higher under clean conditions than that under polluted conditions, which is contributed to high-oxygen-content products. The enhanced RFE of amine–mineral particles caused by heterogenous oxidation is expected to alleviate warming effects.
Shenglan Jiang, Yan Zhang, Guangyuan Yu, Zimin Han, Junri Zhao, Tianle Zhang, and Mei Zheng
Atmos. Chem. Phys., 24, 8363–8381, https://doi.org/10.5194/acp-24-8363-2024, https://doi.org/10.5194/acp-24-8363-2024, 2024
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This study aims to provide gridded data on sea-wide concentrations, deposition fluxes, and soluble deposition fluxes with detailed source categories of metals using the modified CMAQ model. We developed a monthly emission inventory of six metals – Fe, Al, V, Ni, Zn, and Cu – from terrestrial anthropogenic, ship, and dust sources in East Asia in 2017. Our results reveal the contribution of each source to the emissions, concentrations, and deposition fluxes of metals in the East Asian seas.
Ashok K. Luhar, Anthony C. Jones, and Jonathan M. Wilkinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1363, https://doi.org/10.5194/egusphere-2024-1363, 2024
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Nitrate aerosol is often omitted in global chemistry-climate models due to the chemical complexity of its formation process. Using a global model, we demonstrate that including nitrate aerosol significantly impacts tropospheric composition fields, such as ozone, and radiation. Additionally, lightning-generated oxides of nitrogen influence both nitrate aerosol mass concentrations and aerosol size distribution, which has important implications for radiative fluxes and indirect aerosol effects.
Stelios Myriokefalitakis, Matthias Karl, Kim A. Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos
Atmos. Chem. Phys., 24, 7815–7835, https://doi.org/10.5194/acp-24-7815-2024, https://doi.org/10.5194/acp-24-7815-2024, 2024
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A state-of-the-art thermodynamic model has been coupled with the city-scale chemistry transport model EPISODE–CityChem to investigate the equilibrium between the inorganic gas and aerosol phases over the greater Athens area, Greece. The simulations indicate that the formation of nitrates in an urban environment is significantly affected by local nitrogen oxide emissions, as well as ambient temperature, relative humidity, photochemical activity, and the presence of non-volatile cations.
Rui Li, Yining Gao, Lijia Zhang, Yubing Shen, Tianzhao Xu, Wenwen Sun, and Gehui Wang
Atmos. Chem. Phys., 24, 7623–7636, https://doi.org/10.5194/acp-24-7623-2024, https://doi.org/10.5194/acp-24-7623-2024, 2024
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A three-stage model was developed to obtain the global maps of reactive nitrogen components during 2000–2100. The results implied that cross-validation R2 values of four species showed satisfactory performance (R2 > 0.55). Most reactive nitrogen components, except NH3, in China showed increases during 2000–2013. In the future scenarios, SSP3-7.0 (traditional-energy scenario) and SSP1-2.6 (carbon neutrality scenario) showed the highest and lowest reactive nitrogen component concentrations.
Mashiat Hossain, Rebecca M. Garland, and Hannah M. Horowitz
EGUsphere, https://doi.org/10.5194/egusphere-2024-1948, https://doi.org/10.5194/egusphere-2024-1948, 2024
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Our research examines aerosol dynamics over the southeast Atlantic, a region with significant uncertainties in aerosol radiative forcings. Using the GEOS-Chem model, we find that at cloud altitudes, organic aerosols dominate during the biomass burning season, while sulfate aerosols, driven by marine emissions, prevail during peak primary production. These findings highlight the need for accurate representation of marine aerosols in models to improve climate predictions and reduce uncertainties.
Fei Ye, Jingyi Li, Yaqin Gao, Hongli Wang, Jingyu An, Cheng Huang, Song Guo, Keding Lu, Kangjia Gong, Haowen Zhang, Momei Qin, and Jianlin Hu
Atmos. Chem. Phys., 24, 7467–7479, https://doi.org/10.5194/acp-24-7467-2024, https://doi.org/10.5194/acp-24-7467-2024, 2024
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Naphthalene (Nap) and methylnaphthalene (MN) are key precursors of secondary organic aerosol (SOA), yet their sources and sinks are often inadequately represented in air quality models. In this study, we incorporated detailed emissions, gas-phase chemistry, and SOA parameterization of Nap and MN into CMAQ to address this issue. The findings revealed remarkably high SOA formation potentials for these compounds despite their low emissions in the Yangtze River Delta region during summer.
Vy Dinh Ngoc Thuy, Jean-Luc Jaffrezo, Ian Hough, Pamela A. Dominutti, Guillaume Salque Moreton, Grégory Gille, Florie Francony, Arabelle Patron-Anquez, Olivier Favez, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 7261–7282, https://doi.org/10.5194/acp-24-7261-2024, https://doi.org/10.5194/acp-24-7261-2024, 2024
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The capacity of particulate matter (PM) to generate reactive oxygen species in vivo is represented by oxidative potential (OP). This study focuses on finding the appropriate model to evaluate the oxidative character of PM sources in six sites using the PM sources and OP. Eight regression techniques are introduced to assess the OP of PM. The study highlights the importance of selecting a model according to the input data characteristics and establishes some recommendations for the procedure.
Ming Chu, Xing Wei, Shangfei Hai, Yang Gao, Huiwang Gao, Yujiao Zhu, Biwu Chu, Nan Ma, Juan Hong, Yele Sun, and Xiaohong Yao
Atmos. Chem. Phys., 24, 6769–6786, https://doi.org/10.5194/acp-24-6769-2024, https://doi.org/10.5194/acp-24-6769-2024, 2024
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We used a 20-bin WRF-Chem model to simulate NPF events in the NCP during a three-week observational period in the summer of 2019. The model was able to reproduce the observations during June 29–July 6, which was characterized by a high frequency of NPF occurrence.
Haoqi Wang, Xiao Tian, Wanting Zhao, Jiacheng Li, Haoyu Yu, Yinchang Feng, and Shaojie Song
Atmos. Chem. Phys., 24, 6583–6592, https://doi.org/10.5194/acp-24-6583-2024, https://doi.org/10.5194/acp-24-6583-2024, 2024
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pH is a key property of ambient aerosols, which affect many atmospheric processes. As aerosol pH is a non-conservative parameter, diverse averaging metrics and temporal resolutions may influence the pH values calculated by thermodynamic models. This technical note seeks to quantitatively evaluate the average pH using varied metrics and resolutions. The ultimate goal is to establish standardized reporting practices in future research endeavors.
Jiwon Choi, Myoseon Jang, and Spencer Blau
Atmos. Chem. Phys., 24, 6567–6582, https://doi.org/10.5194/acp-24-6567-2024, https://doi.org/10.5194/acp-24-6567-2024, 2024
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Persistent phenoxy radical (PPR), formed by phenol gas oxidation and its aqueous reaction, catalytically destroys O3 and retards secondary organic aerosol (SOA) growth. Explicit gas mechanisms including the formation of PPR and low-volatility products from the oxidation of phenol or benzene are applied to the UNIPAR model to predict SOA mass via multiphase reactions of precursors. Aqueous reactions of reactive organics increase SOA mass but retard SOA growth via heterogeneously formed PPR.
Yang Yang, Shaoxuan Mou, Hailong Wang, Pinya Wang, Baojie Li, and Hong Liao
Atmos. Chem. Phys., 24, 6509–6523, https://doi.org/10.5194/acp-24-6509-2024, https://doi.org/10.5194/acp-24-6509-2024, 2024
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The variations in anthropogenic aerosol concentrations and source contributions and their subsequent radiative impact in major emission regions during historical periods are quantified based on an aerosol-tagging system in E3SMv1. Due to the industrial development and implementation of economic policies, sources of anthropogenic aerosols show different variations, which has important implications for pollution prevention and control measures and decision-making for global collaboration.
Maegan A. DeLessio, Kostas Tsigaridis, Susanne E. Bauer, Jacek Chowdhary, and Gregory L. Schuster
Atmos. Chem. Phys., 24, 6275–6304, https://doi.org/10.5194/acp-24-6275-2024, https://doi.org/10.5194/acp-24-6275-2024, 2024
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This study presents the first explicit representation of brown carbon aerosols in the GISS ModelE Earth system model (ESM). Model sensitivity to a range of brown carbon parameters and model performance compared to AERONET and MODIS retrievals of total aerosol properties were assessed. A summary of best practices for incorporating brown carbon into ModelE is also included.
Chuanyang Shen, Xiaoyan Yang, Joel Thornton, John Shilling, Chenyang Bi, Gabriel Isaacman-VanWertz, and Haofei Zhang
Atmos. Chem. Phys., 24, 6153–6175, https://doi.org/10.5194/acp-24-6153-2024, https://doi.org/10.5194/acp-24-6153-2024, 2024
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In this work, a condensed multiphase isoprene oxidation mechanism was developed to simulate isoprene SOA formation from chamber and field studies. Our results show that the measured isoprene SOA mass concentrations can be reasonably reproduced. The simulation results indicate that multifunctional low-volatility products contribute significantly to total isoprene SOA. Our findings emphasize that the pathways to produce these low-volatility species should be considered in models.
Alice Maison, Lya Lugon, Soo-Jin Park, Alexia Baudic, Christopher Cantrell, Florian Couvidat, Barbara D'Anna, Claudia Di Biagio, Aline Gratien, Valérie Gros, Carmen Kalalian, Julien Kammer, Vincent Michoud, Jean-Eudes Petit, Marwa Shahin, Leila Simon, Myrto Valari, Jérémy Vigneron, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 24, 6011–6046, https://doi.org/10.5194/acp-24-6011-2024, https://doi.org/10.5194/acp-24-6011-2024, 2024
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This study presents the development of a bottom-up inventory of urban tree biogenic emissions. Emissions are computed for each tree based on their location and characteristics and are integrated in the regional air quality model WRF-CHIMERE. The impact of these biogenic emissions on air quality is quantified for June–July 2022. Over Paris city, urban trees increase the concentrations of particulate organic matter by 4.6 %, of PM2.5 by 0.6 %, and of ozone by 1.0 % on average over 2 months.
Tommaso Galeazzo, Bernard Aumont, Marie Camredon, Richard Valorso, Yong B. Lim, Paul J. Ziemann, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 5549–5565, https://doi.org/10.5194/acp-24-5549-2024, https://doi.org/10.5194/acp-24-5549-2024, 2024
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Secondary organic aerosol (SOA) derived from n-alkanes is a major component of anthropogenic particulate matter. We provide an analysis of n-alkane SOA by chemistry modeling, machine learning, and laboratory experiments, showing that n-alkane SOA adopts low-viscous semi-solid or liquid states. Our results indicate few kinetic limitations of mass accommodation in SOA formation, supporting the application of equilibrium partitioning for simulating n-alkane SOA in large-scale atmospheric models.
Rémy Lapere, Louis Marelle, Pierre Rampal, Laurent Brodeau, Christian Melsheimer, Gunnar Spreen, and Jennie L. Thomas
EGUsphere, https://doi.org/10.5194/egusphere-2024-1271, https://doi.org/10.5194/egusphere-2024-1271, 2024
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Elongated open water areas in sea ice, called leads, can release marine aerosols into the atmosphere. In the Arctic, this source of atmospheric particles could play an important role for climate. However, the amount, seasonality and spatial distribution of such emissions are mostly unknown. Here, we propose a first parameterization for sea spray aerosols emitted through leads in sea ice and quantify their impact on aerosol populations in the high Arctic.
Lukáš Bartík, Peter Huszár, Jan Karlický, Ondřej Vlček, and Kryštof Eben
Atmos. Chem. Phys., 24, 4347–4387, https://doi.org/10.5194/acp-24-4347-2024, https://doi.org/10.5194/acp-24-4347-2024, 2024
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The presented study deals with the attribution of fine particulate matter (PM2.5) concentrations to anthropogenic emissions over Central Europe using regional-scale models. It calculates the present-day contributions of different emissions sectors to concentrations of PM2.5 and its secondary components. Moreover, the study investigates the effect of chemical nonlinearities by using multiple source attribution methods and secondary organic aerosol calculation methods.
Rui Wang, Yang Cheng, Shasha Chen, Rongrong Li, Yue Hu, Xiaokai Guo, Tianlei Zhang, Fengmin Song, and Hao Li
Atmos. Chem. Phys., 24, 4029–4046, https://doi.org/10.5194/acp-24-4029-2024, https://doi.org/10.5194/acp-24-4029-2024, 2024
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We used quantum chemical calculations, Born–Oppenheimer molecular dynamics simulations, and the ACDC kinetic model to characterize SO3–H2SO4 interaction in the gas phase and at the air–water interface and to study the effect of H2S2O7 on H2SO4–NH3-based clusters. The work expands our understanding of new pathways for the loss of SO3 in acidic polluted areas and helps reveal some missing sources of NPF in metropolitan industrial regions and understand the atmospheric organic–sulfur cycle better.
Hao Yang, Lei Chen, Hong Liao, Jia Zhu, Wenjie Wang, and Xin Li
Atmos. Chem. Phys., 24, 4001–4015, https://doi.org/10.5194/acp-24-4001-2024, https://doi.org/10.5194/acp-24-4001-2024, 2024
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The present study quantifies the response of aerosol–radiation interaction (ARI) to anthropogenic emission reduction from 2013 to 2017, with the main focus on the contribution to changed O3 concentrations over eastern China both in summer and winter using the WRF-Chem model. The weakened ARI due to decreased anthropogenic emission aggravates the summer (winter) O3 pollution by +0.81 ppb (+0.63 ppb), averaged over eastern China.
Margaret R. Marvin, Paul I. Palmer, Fei Yao, Mohd Talib Latif, and Md Firoz Khan
Atmos. Chem. Phys., 24, 3699–3715, https://doi.org/10.5194/acp-24-3699-2024, https://doi.org/10.5194/acp-24-3699-2024, 2024
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We use an atmospheric chemistry model to investigate aerosols emitted from fire activity across Southeast Asia. We find that the limited nature of measurements in this region leads to large uncertainties that significantly hinder the model representation of these aerosols and their impacts on air quality. As a result, the number of monthly attributable deaths is underestimated by as many as 4500, particularly in March at the peak of the mainland burning season.
Julie Camman, Benjamin Chazeau, Nicolas Marchand, Amandine Durand, Grégory Gille, Ludovic Lanzi, Jean-Luc Jaffrezo, Henri Wortham, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 3257–3278, https://doi.org/10.5194/acp-24-3257-2024, https://doi.org/10.5194/acp-24-3257-2024, 2024
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Fine particle (PM1) pollution is a major health issue in the city of Marseille, which is subject to numerous pollution sources. Sampling carried out during the summer enabled a fine characterization of the PM1 sources and their oxidative potential, a promising new metric as a proxy for health impact. PM1 came mainly from combustion sources, secondary ammonium sulfate, and organic nitrate, while the oxidative potential of PM1 came from these sources and from resuspended dust in the atmosphere.
Yuemeng Ji, Zhang Shi, Wenjian Li, Jiaxin Wang, Qiuju Shi, Yixin Li, Lei Gao, Ruize Ma, Weijun Lu, Lulu Xu, Yanpeng Gao, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 3079–3091, https://doi.org/10.5194/acp-24-3079-2024, https://doi.org/10.5194/acp-24-3079-2024, 2024
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The formation mechanisms for secondary brown carbon (SBrC) contributed by multifunctional reduced nitrogen compounds (RNCs) remain unclear. Hence, from combined laboratory experiments and quantum chemical calculations, we investigated the heterogeneous reactions of glyoxal (GL) with multifunctional RNCs, which are driven by four-step indirect nucleophilic addition reactions. Our results show a possible missing source for SBrC formation on urban, regional, and global scales.
Elyse A. Pennington, Yuan Wang, Benjamin C. Schulze, Karl M. Seltzer, Jiani Yang, Bin Zhao, Zhe Jiang, Hongru Shi, Melissa Venecek, Daniel Chau, Benjamin N. Murphy, Christopher M. Kenseth, Ryan X. Ward, Havala O. T. Pye, and John H. Seinfeld
Atmos. Chem. Phys., 24, 2345–2363, https://doi.org/10.5194/acp-24-2345-2024, https://doi.org/10.5194/acp-24-2345-2024, 2024
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To assess the air quality in Los Angeles (LA), we improved the CMAQ model by using dynamic traffic emissions and new secondary organic aerosol schemes to represent volatile chemical products. Source apportionment demonstrates that the urban areas of the LA Basin and vicinity are NOx-saturated, with the largest sensitivity of O3 to changes in volatile organic compounds in the urban core. The improvement and remaining issues shed light on the future direction of the model development.
Feifan Yan, Hang Su, Yafang Cheng, Rujin Huang, Hong Liao, Ting Yang, Yuanyuan Zhu, Shaoqing Zhang, Lifang Sheng, Wenbin Kou, Xinran Zeng, Shengnan Xiang, Xiaohong Yao, Huiwang Gao, and Yang Gao
Atmos. Chem. Phys., 24, 2365–2376, https://doi.org/10.5194/acp-24-2365-2024, https://doi.org/10.5194/acp-24-2365-2024, 2024
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PM2.5 pollution is a major air quality issue deteriorating human health, and previous studies mostly focus on regions like the North China Plain and Yangtze River Delta. However, the characteristics of PM2.5 concentrations between these two regions are studied less often. Focusing on the transport corridor region, we identify an interesting seesaw transport phenomenon with stagnant weather conditions, conducive to PM2.5 accumulation over this region, resulting in large health effects.
Prerita Agarwal, David S. Stevenson, and Mathew R. Heal
Atmos. Chem. Phys., 24, 2239–2266, https://doi.org/10.5194/acp-24-2239-2024, https://doi.org/10.5194/acp-24-2239-2024, 2024
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Air pollution levels across northern India are amongst some of the worst in the world, with episodic and hazardous haze events. Here, the ability of the WRF-Chem model to predict air quality over northern India is assessed against several datasets. Whilst surface wind speed and particle pollution peaks are over- and underestimated, respectively, meteorology and aerosol trends are adequately captured, and we conclude it is suitable for investigating severe particle pollution events.
George Jordan, Florent Malavelle, Ying Chen, Amy Peace, Eliza Duncan, Daniel G. Partridge, Paul Kim, Duncan Watson-Parris, Toshihiko Takemura, David Neubauer, Gunnar Myhre, Ragnhild Skeie, Anton Laakso, and James Haywood
Atmos. Chem. Phys., 24, 1939–1960, https://doi.org/10.5194/acp-24-1939-2024, https://doi.org/10.5194/acp-24-1939-2024, 2024
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The 2014–15 Holuhraun eruption caused a huge aerosol plume in an otherwise unpolluted region, providing a chance to study how aerosol alters cloud properties. This two-part study uses observations and models to quantify this relationship’s impact on the Earth’s energy budget. Part 1 suggests the models capture the observed spatial and chemical evolution of the plume, yet no model plume is exact. Understanding these differences is key for Part 2, where changes to cloud properties are explored.
Lin Du, Xiaofan Lv, Makroni Lily, Kun Li, and Narcisse Tsona Tchinda
Atmos. Chem. Phys., 24, 1841–1853, https://doi.org/10.5194/acp-24-1841-2024, https://doi.org/10.5194/acp-24-1841-2024, 2024
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This study explores the pH effect on the reaction of dissolved SO2 with selected organic peroxides. Results show that the formation of organic and/or inorganic sulfate from these peroxides strongly depends on their electronic structures, and these processes are likely to alter the chemical composition of dissolved organic matter in different ways. The rate constants of these reactions exhibit positive pH and temperature dependencies within pH 1–10 and 240–340 K ranges.
Angelo Riccio and Elena Chianese
Atmos. Chem. Phys., 24, 1673–1689, https://doi.org/10.5194/acp-24-1673-2024, https://doi.org/10.5194/acp-24-1673-2024, 2024
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Starting from the Copernicus Atmosphere Monitoring Service (CAMS), we provided a novel ensemble statistical post-processing approach to improve their air quality predictions. Our approach is able to provide reliable short-term forecasts of pollutant concentrations, which is a key challenge in supporting national authorities in their tasks related to EU Air Quality Directives, such as planning and reporting the state of air quality to the citizens.
Yanru Huo, Mingxue Li, Xueyu Wang, Jianfei Sun, Yuxin Zhou, Yuhui Ma, and Maoxia He
EGUsphere, https://doi.org/10.5194/egusphere-2023-2856, https://doi.org/10.5194/egusphere-2023-2856, 2024
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This work found that the A-W interface and TiO2 clusters promote the oxidation of phenolic compounds (PhCs) to varying degrees comparing with gas phase, and bulk water. Some by-products are more harmful than their parent compounds. This work provides important evidence for the rapid oxidation observed in the O3/HO• + PhCs experiments at the A-W interface and in the mineral dust.
Stella E. I. Manavi and Spyros N. Pandis
Atmos. Chem. Phys., 24, 891–909, https://doi.org/10.5194/acp-24-891-2024, https://doi.org/10.5194/acp-24-891-2024, 2024
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Organic vapors of intermediate volatility have often been neglected as sources of atmospheric organic aerosol. In this work we use a new approach for their simulation and quantify the contribution of these compounds emitted by transportation sources (gasoline and diesel vehicles) to particulate matter over Europe. The estimated secondary organic aerosol levels are on average 60 % higher than predicted by previous approaches. However, these estimates are probably lower limits.
Zhiyuan Li, Kin-Fai Ho, Harry Fung Lee, and Steve Hung Lam Yim
Atmos. Chem. Phys., 24, 649–661, https://doi.org/10.5194/acp-24-649-2024, https://doi.org/10.5194/acp-24-649-2024, 2024
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This study developed an integrated model framework for accurate multi-air-pollutant exposure assessments in high-density and high-rise cities. Following the proposed integrated model framework, we established multi-air-pollutant exposure models for four major PM10 chemical species as well as four criteria air pollutants with R2 values ranging from 0.73 to 0.93. The proposed framework serves as an important tool for combined exposure assessment in epidemiological studies.
Yujin Jo, Myoseon Jang, Sanghee Han, Azad Madhu, Bonyoung Koo, Yiqin Jia, Zechen Yu, Soontae Kim, and Jinsoo Park
Atmos. Chem. Phys., 24, 487–508, https://doi.org/10.5194/acp-24-487-2024, https://doi.org/10.5194/acp-24-487-2024, 2024
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The CAMx–UNIPAR model simulated the SOA budget formed via multiphase reactions of hydrocarbons and the impact of emissions and climate on SOA characteristics under California’s urban environments during winter 2018. SOA growth was dominated by daytime oxidation of long-chain alkanes and nighttime terpene oxidation with O3 and NO−3 radicals. The spatial distributions of anthropogenic SOA were affected by the northwesterly wind, whereas those of biogenic SOA were insensitive to wind directions.
Peter Huszar, Alvaro Patricio Prieto Perez, Lukáš Bartík, Jan Karlický, and Anahi Villalba-Pradas
Atmos. Chem. Phys., 24, 397–425, https://doi.org/10.5194/acp-24-397-2024, https://doi.org/10.5194/acp-24-397-2024, 2024
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Urbanization transforms rural land into artificial land, while due to human activities, it also introduces a great quantity of emissions. We quantify the impact of urbanization on the final particulate matter pollutant levels by looking not only at these emissions, but also at the way urban land cover influences meteorological conditions, how the removal of pollutants changes due to urban land cover, and how biogenic emissions from vegetation change due to less vegetation in urban areas.
Yinbao Jin, Yiming Liu, Xiao Lu, Xiaoyang Chen, Ao Shen, Haofan Wang, Yinping Cui, Yifei Xu, Siting Li, Jian Liu, Ming Zhang, Yingying Ma, and Qi Fan
Atmos. Chem. Phys., 24, 367–395, https://doi.org/10.5194/acp-24-367-2024, https://doi.org/10.5194/acp-24-367-2024, 2024
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This study aims to address these issues by evaluating eight independent biomass burning (BB) emission inventories (GFED, FINN1.5, FINN2.5 MOS, FINN2.5 MOSVIS, GFAS, FEER, QFED, and IS4FIRES) using the WRF-Chem model and analyzing their impact on aerosol optical properties (AOPs) and direct radiative forcing (DRF) during wildfire events in peninsular Southeast Asia (PSEA) that occurred in March 2019.
Hamza Ahsan, Hailong Wang, Jingbo Wu, Mingxuan Wu, Steven J. Smith, Susanne Bauer, Harrison Suchyta, Dirk Olivié, Gunnar Myhre, Hitoshi Matsui, Huisheng Bian, Jean-François Lamarque, Ken Carslaw, Larry Horowitz, Leighton Regayre, Mian Chin, Michael Schulz, Ragnhild Bieltvedt Skeie, Toshihiko Takemura, and Vaishali Naik
Atmos. Chem. Phys., 23, 14779–14799, https://doi.org/10.5194/acp-23-14779-2023, https://doi.org/10.5194/acp-23-14779-2023, 2023
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We examine the impact of the assumed effective height of SO2 injection, SO2 and BC emission seasonality, and the assumed fraction of SO2 emissions injected as SO4 on climate and chemistry model results. We find that the SO2 injection height has a large impact on surface SO2 concentrations and, in some models, radiative flux. These assumptions are a
hiddensource of inter-model variability and may be leading to bias in some climate model results.
Zhen Peng, Lili Lei, Zhe-Min Tan, Meigen Zhang, Aijun Ding, and Xingxia Kou
Atmos. Chem. Phys., 23, 14505–14520, https://doi.org/10.5194/acp-23-14505-2023, https://doi.org/10.5194/acp-23-14505-2023, 2023
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Annual PM2.5 emissions in China consistently decreased by about 3% to 5% from 2017 to 2020 with spatial variations and seasonal dependencies. High-temporal-resolution and dynamics-based PM2.5 emission estimates provide quantitative diurnal variations for each season. Significant reductions in PM2.5 emissions in the North China Plain and northeast of China in 2020 were caused by COVID-19.
Stylianos Kakavas, Spyros N. Pandis, and Athanasios Nenes
Atmos. Chem. Phys., 23, 13555–13564, https://doi.org/10.5194/acp-23-13555-2023, https://doi.org/10.5194/acp-23-13555-2023, 2023
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Water uptake from organic species in aerosol can affect the partitioning of semi-volatile inorganic compounds but are not considered in global and chemical transport models. We address this with a version of the PM-CAMx model that considers such organic water effects and use it to carry out 1-year aerosol simulations over the continental US. We show that such organic water impacts can increase dry PM1 levels by up to 2 μg m-3 when RH levels and PM1 concentrations are high.
Benjamin N. Murphy, Darrell Sonntag, Karl M. Seltzer, Havala O. T. Pye, Christine Allen, Evan Murray, Claudia Toro, Drew R. Gentner, Cheng Huang, Shantanu Jathar, Li Li, Andrew A. May, and Allen L. Robinson
Atmos. Chem. Phys., 23, 13469–13483, https://doi.org/10.5194/acp-23-13469-2023, https://doi.org/10.5194/acp-23-13469-2023, 2023
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We update methods for calculating organic particle and vapor emissions from mobile sources in the USA. Conventionally, particulate matter (PM) and volatile organic carbon (VOC) are speciated without consideration of primary semivolatile emissions. Our methods integrate state-of-the-science speciation profiles and correct for common artifacts when sampling emissions in a laboratory. We quantify impacts of the emission updates on ambient pollution with the Community Multiscale Air Quality model.
Yanshun Li, Randall V. Martin, Chi Li, Brian L. Boys, Aaron van Donkelaar, Jun Meng, and Jeffrey R. Pierce
Atmos. Chem. Phys., 23, 12525–12543, https://doi.org/10.5194/acp-23-12525-2023, https://doi.org/10.5194/acp-23-12525-2023, 2023
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We developed and evaluated processes affecting within-day (diel) variability in PM2.5 concentrations in a chemical transport model over the contiguous US. Diel variability in PM2.5 for the contiguous US is driven by early-morning accumulation into a shallow mixed layer, decreases from mid-morning through afternoon with mixed-layer growth, increases from mid-afternoon through evening as the mixed-layer collapses, and decreases overnight as emissions decrease.
Chupeng Zhang, Shangfei Hai, Yang Gao, Yuhang Wang, Shaoqing Zhang, Lifang Sheng, Bin Zhao, Shuxiao Wang, Jingkun Jiang, Xin Huang, Xiaojing Shen, Junying Sun, Aura Lupascu, Manish Shrivastava, Jerome D. Fast, Wenxuan Cheng, Xiuwen Guo, Ming Chu, Nan Ma, Juan Hong, Qiaoqiao Wang, Xiaohong Yao, and Huiwang Gao
Atmos. Chem. Phys., 23, 10713–10730, https://doi.org/10.5194/acp-23-10713-2023, https://doi.org/10.5194/acp-23-10713-2023, 2023
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New particle formation is an important source of atmospheric particles, exerting critical influences on global climate. Numerical models are vital tools to understanding atmospheric particle evolution, which, however, suffer from large biases in simulating particle numbers. Here we improve the model chemical processes governing particle sizes and compositions. The improved model reveals substantial contributions of newly formed particles to climate through effects on cloud condensation nuclei.
Xiaodong Xie, Jianlin Hu, Momei Qin, Song Guo, Min Hu, Dongsheng Ji, Hongli Wang, Shengrong Lou, Cheng Huang, Chong Liu, Hongliang Zhang, Qi Ying, Hong Liao, and Yuanhang Zhang
Atmos. Chem. Phys., 23, 10563–10578, https://doi.org/10.5194/acp-23-10563-2023, https://doi.org/10.5194/acp-23-10563-2023, 2023
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The atmospheric age of particles reflects how long particles have been formed and suspended in the atmosphere, which is closely associated with the evolution processes of particles. An analysis of the atmospheric age of PM2.5 provides a unique perspective on the evolution processes of different PM2.5 components. The results also shed lights on how to design effective emission control actions under unfavorable meteorological conditions.
Lea Fink, Matthias Karl, Volker Matthias, Sonia Oppo, Richard Kranenburg, Jeroen Kuenen, Sara Jutterström, Jana Moldanova, Elisa Majamäki, and Jukka-Pekka Jalkanen
Atmos. Chem. Phys., 23, 10163–10189, https://doi.org/10.5194/acp-23-10163-2023, https://doi.org/10.5194/acp-23-10163-2023, 2023
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The Mediterranean Sea is a heavily trafficked shipping area, and air quality monitoring stations in numerous cities along the Mediterranean coast have detected high levels of air pollutants originating from shipping emissions. The current study investigates how existing restrictions on shipping-related emissions to the atmosphere ensure compliance with legislation. Focus was laid on fine particles and particle species, which were simulated with five different chemical transport models.
Noah A. Stanton and Neil F. Tandon
Atmos. Chem. Phys., 23, 9191–9216, https://doi.org/10.5194/acp-23-9191-2023, https://doi.org/10.5194/acp-23-9191-2023, 2023
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Chemistry in Earth’s atmosphere has a potentially strong but very uncertain impact on climate. Past attempts to fully model chemistry in Earth’s troposphere (the lowest layer of the atmosphere) typically simplified the representation of Earth’s surface, which in turn limited the ability to simulate changes in climate. The cutting-edge model that we use in this study does not require such simplification, and we use it to examine the climate effects of chemical interactions in the troposphere.
Cited articles
Al Natsheh, A., Nadykto, A. B., Mikkelsen, K. V., Yu, F., and Ruuskanen, J.:
Sulfuric acid and sulfuric acid hydrates in the gas phase: A DFT
investigation, J. Phys. Chem. A, 108, 8914–8929,
https://doi.org/10.1021/jp048858o, 2004.
Anderson, K. E., Siepmann, J. I., McMurry, P. H., and VandeVondele, J.:
Importance of the Number of Acid Molecules and the Strength of the Base for
Double-Ion Formation in (H2SO4)m⚫Base⚫(H2O)6 Clusters,
J. Am. Chem. Soc., 130, 14144–14147, https://doi.org/10.1021/ja8019774,
2008.
Andreae, M. O., Rosenfeld, D., Artaxo, P., Costa, A. A., Frank, G. P.,
Longo, K. M., and Silva-Dias, M. A. F.: Smoking rain clouds over the Amazon,
Science, 303, 1337–1342, 2004.
Bianchi, F., Tröstl, J., Junninen, H., Frege, C., Henne,
S., Hoyle, C. R., Molteni, U., Herrmann, E., Adamov, A., Bukowiecki, N.,
Chen, X., Duplissy, J., Gysel, M., Hutterli, M., Kangasluoma, J., Kontkanen,
J., Kürten, A., Manninen, H. E., Münch, S., Peräkylä, O.,
Petäjä, T., Rondo, L., Williamson, C.,
Weingartner, E., Curtius, J., Worsnop, D. R., Kulmala, M., Dommen, J., and
Baltensperger, U.: New particle formation in the free troposphere: A
question of chemistry and timing, Science, 352, 1109–1112,
https://doi.org/10.1126/science.aad5456, 2016.
Blower, P. G., Ota, S. T., Valley, N. A., Wood, S. R., and Richmond, G. L.:
Sink or Surf: Atmospheric Implications for Succinic Acid at Aqueous
Surfaces, J. Phys. Chem., 117, 7887–7903, https://doi.org/10.1021/jp405067y,
2013.
Cai, R. and Jiang, J.: A new balance formula to estimate new particle formation rate: reevaluating the effect of coagulation scavenging, Atmos. Chem. Phys., 17, 12659–12675, https://doi.org/10.5194/acp-17-12659-2017, 2017.
Decesari, S., Facchini, M. C., Fuzzi, S., and Tagliavini, E.,
Characterization of water-soluble organic compounds in atmospheric aerosol:
A new approach, J. Geophys. Res.-Atmos., 105, 1481–1489,
https://doi.org/10.1029/1999JD900950, 2000.
DePalma, J. W., Bzdek, B. R., Doren, D. J., and Johnston, M. V.: Structure
and energetics of nanometer size clusters of sulfuric acid with ammonia and
dimethylamine, J. Phys. Chem. A, 116, 1030–1040,
https://doi.org/10.1021/jp210127w, 2012.
Ding, C.-G., Laasonen, K., and Laaksonen, A.: Two sulfuric acids in small
water clusters, J. Phys. Chem., 107, 8648–8658,
https://doi.org/10.1021/jp022575j, 2003.
Elm, J., Bilde, M., and Mikkelsen, K. V.: Assessment of density functional
theory in predicting structures and free energies of reaction of atmospheric
prenucleation clusters, J. Chem. Theory Comput., 8, 2071–2077,
https://doi.org/10.1021/ct300192p, 2012.
Elm, J., Kurten, T., Bilde, M., and Mikkelsen, K. V.: Molecular interaction
of pinic acid with sulfuric acid: exploring the thermodynamic landscape of
cluster growth, J. Phys. Chem. A, 118, 7892–7900,
https://doi.org/10.1021/jp503736s, 2014.
Elm, J., Jen, C. N., Kurtén, T., and Vehkamäki, H.: Strong hydrogen
bonded molecular interactions between atmospheric diamines and sulfuric
acid, J. Phys. Chem., 120, 3693–3700,
https://doi.org/10.1021/acs.jpca.6b03192, 2016a.
Elm, J., Myllys, N., Luy, J.-N., Kurtén, T., and Vehkamäki, H.: The
Effect of Water and Bases on the Clustering of a Cyclohexene Autoxidation
Product C6H8O7 with Sulfuric Acid, J. Phys. Chem., 120, 2240–2249,
https://doi.org/10.1021/acs.jpca.6b00677, 2016b.
Elm, J., Myllys, N., and Kurtén, T.: What is required for highly
oxidized molecules to form clusters with sulfuric acid?, J. Phys. Chem., 121, 4578–4587, https://doi.org/10.1021/acs.jpca.7b03759, 2017.
Erupe, M. E., Viggiano, A. A., and Lee, S.-H.: The effect of trimethylamine on atmospheric nucleation involving H2SO4, Atmos. Chem. Phys., 11, 4767–4775, https://doi.org/10.5194/acp-11-4767-2011, 2011.
Espinosa, E., Molins, E., and Lecomte, C.: Hydrogen bond strengths revealed
by topological analyses of experimentally observed electron densities, Chem.
Phys. Lett., 285, 170–173, https://doi.org/10.1016/S0009-2614(98)00036-0,
1998.
Fan, J., Zhang, R., Li, G., and Tao, W.-K.: Effects of aerosols and relative
humidity on cumulus clouds, J. Geophys. Res., 112, D14204,
https://doi.org/10.1029/2006JD008136, 2007.
Ge, X., Wexler, A. S., Clegg, S. L.: Atmospheric amines – Part I. A review,
Atmos. Environ., 45, 524, https://doi.org/10.1016/j.atmosenv.2010.10.012, 2011.
Guo, S., Hu, M., Zamora, M. L., Peng, J., Shang, D., Zheng, J., Du, Z., Wu,
Z., Shao, M., Zeng, L., Molina, M. J., and Zhang, R.: Elucidating severe
urban haze formation in China, P. Natl. Acad. Sci. USA, 111,
17373–17378, https://doi.org/10.1016/10.1073/pnas.1419604111, 2014.
Hanson, D. R. and Eisele, F. L.: Acid–base chemical reaction model for
nucleation rates in the polluted atmospheric boundary layer, J. Geophys.
Res.-Atmos., 107, 18713–18718, https://doi.org/10.1073/pnas.1210285109,
2002.
Henschel, H., Ortega, I. K., Kupiainen, O., Olenius, T., Kurtén, T., and
Vehkamäki, H.: Hydration of pure and base-Containing sulfuric acid
clusters studied by computational chemistry methods, AIP Conference
Proceedings, 1527, 218–221, https://doi.org/10.1063/1.4803243, 2013.
Henschel, H., Navarro, J. C., Yli-Juuti, T., Kupiainen-Maatta, O., Olenius,
T., Ortega, I. K., Clegg, S. L., Kurten, T., Riipinen, I., and Vehkamaki,
H.: Hydration of atmospherically relevant molecular clusters: Computational
chemistry and classical thermodynamics, J. Phys. Chem. A, 118, 2599–2611,
https://doi.org/10.1021/jp500712y, 2014.
Henschel, H., Kurtén, T., and Vehkamäki, H.: Hydration of
Atmospherically Relevant Molecular Clusters: Computational Chemistry and
Classical Thermodynamics, J. Phys. Chem., 120, 2599–2611,
https://doi.org/10.1021/jp500712y, 2016.
Ho, K. F., Cao, J. J., Lee, S. C., Kawamura, K., Zhang, R. J., Chow, J. C.,
and Watson, J. G.: Dicarboxylic acids, ketocarboxylic acids, and dicarbonyls
in the urban atmosphere of China, J. Geophys. Res., 112, D22S27,
https://doi.org/10.1029/2006JD008011, 2007.
Hsieh, L.-Y., Kuo, S.-C., Chen, C.-L., and Tsai, Y. I.: Origin of
Low-molecular-weight Dicarboxylic Acids and their Concentration and Size
Distribution Variation in Suburban Aerosol, Atmos. Environ., 41, 6648–6661,
https://doi.org/10.1016/j.atmosenv.2007.04.014 2007.
IPCC: Climate Change 2013: The Physical Science Basis. Contribution of
Working Group I to the Fifth Assessment Report of the Intergovernmental
Panel on Climate Change, Cambridge University Press, Cambridge, United
Kingdom and New York, NY, USA, available at: http://www.ipcc.ch/report/ar5/wg1/ (last access: 1 June 2019), 2013.
Kawamura, K. and Kaplan, I. R.: Motor exhaust emissions as a primary source
for dicarboxylic acids in Los Angeles ambient air, Environ. Sci. Technol.,
21, 105–110, 1987.
Kuang, C., Riipinen, I., Sihto, S.-L., Kulmala, M., McCormick, A. V., and McMurry, P. H.: An improved criterion for new particle formation in diverse atmospheric environments, Atmos. Chem. Phys., 10, 8469–8480, https://doi.org/10.5194/acp-10-8469-2010, 2010.
Kulmala, M. and Kerminen, V. M.: On the formation and growth of atmospheric
nanoparticles, Atmos. Res., 90, 132–150,
https://doi.org/10.1016/j.atmosres.2008.01.005, 2008.
Kurtén, T., Sundberg, M. R., Vehkamäki, H., Noppel, M., Blomqvist,
J., and Kulmala, M.: Ab initio and density functional theory reinvestigation
of gas-phase sulfuric acid monohydrate and ammonium hydrogen sulfate, J.
Phys. Chem., 110, 7178–7188, https://doi.org/10.1021/jp0613081, 2006.
Lane, J. R., Contreras-García, J., Piquemal, J.-P., Miller, B. J., and
Kjaergaard, H. G.: Are bond critical points really critical for hydrogen
bonding?, J. Chem. Theory Comput. 9, 3263–3266,
https://doi.org/10.1021/ct400420r, 2013.
Legrand, M., Preunkert, S., Galy-Lacaux, C., Liousse, C.,
and Wagenbach, D.: Atmospheric year-round records of
dicarboxylic acids and sulfate at three French sites located between 630 and
4360 m elevation, J. Geophys. Res.-Atmos., 110, D13302, https://doi.org/10.1029/2004JD005515, 2005.
Leverentz, H. R., Siepmann, J. I., Truhlar, D. G., Loukonen, V., and
Vehkamäki, H.: Energetics of atmospherically implicated clusters made of
sulfuric acid, ammonia, and dimethyl amine, J. Phys. Chem. A, 117,
3819–3825, https://doi.org/10.1021/jp402346u, 2013.
Li, G., Wang, Y., and Zhang, R.: Implementation of a two-moment bulk
microphysics scheme to the WRF model to investigate aerosol-cloud
interaction, J. Geophys. Res., 113, D15211,
https://doi.org/10.1029/2007JD009361, 2008.
Loukonen, V., Kurtén, T., Ortega, I. K., Vehkamäki, H., Pádua, A. A. H., Sellegri, K., and Kulmala, M.: Enhancing effect of dimethylamine in sulfuric acid nucleation in the presence of water – a computational study, Atmos. Chem. Phys., 10, 4961–4974, https://doi.org/10.5194/acp-10-4961-2010, 2010.
Lu, T. and Chen, F.: Multiwfn: A multifunctional wavefunction analyzer, J.
Comput. Chem., 33, 580–592, https://doi.org/10.1002/jcc.22885, 2012.
Lu, T. and Chen, F.: Bond order analysis based on the Laplacian of electron
density in fuzzy overlap space, J. Phys. Chem. A, 117, 3100–3108,
https://doi.org/10.1021/jp4010345, 2013.
McGraw, R. and Zhang, R.: Multivariate analysis of homogeneous nucleation
rate measurements: I. Nucleation in the p-toluic acid/sulfuric acid/water
system, J. Chem. Phys., 128, 064508, https://doi.org/10.1063/1.2830030, 2008.
Merikanto, J., Spracklen, D. V., Mann, G. W., Pickering, S. J., and Carslaw, K. S.: Impact of nucleation on global CCN, Atmos. Chem. Phys., 9, 8601–8616, https://doi.org/10.5194/acp-9-8601-2009, 2009.
Nadykto, A. B. and Yu, F.: Strong hydrogen bonding between atmospheric
nucleation precursors and common organics, Chem. Phys. Lett., 435, 14–18,
https://doi.org/10.1016/j.cplett.2006.12.050, 2007.
Nadykto, A. B., Yu, F., Jakovleva, M. V., Herb, J., and Xu, Y.: Amines in the
Earth's Atmosphere: A Density Functional Theory Study of the Thermochemistry
of Pre-Nucleation Clusters, Entropy, 13, 554–569,
https://doi.org/10.3390/e13020554, 2011.
Ortega, I. K., Kupiainen, O., Kurtén, T., Olenius, T., Wilkman, O., McGrath, M. J., Loukonen, V., and Vehkamäki, H.: From quantum chemical formation free energies to evaporation rates, Atmos. Chem. Phys., 12, 225–235, https://doi.org/10.5194/acp-12-225-2012, 2012.
Qiu, C. and Zhang, R.: Multiphase chemistry of atmospheric amines, Phys.
Chem. Chem. Phys., 15, 5738–5752, https://doi.org/10.1039/C3CP43446J, 2013.
Riccobono, F., Schobesberger, S., Scott, C. E., Dommen, J., Ortega, I. K.,
Rondo, L., Almeida, J., Amorim, A., Bianchi, F., Breitenlechner, M., David,
A., Downard, A., Dunne, E. M., Duplissy, J., Ehrhart, S., Flagan, R. C.,
Franchin, A., Hansel, A., Junninen, H., Kajos, M., Keskinen, H., Kupc, A.,
Kürten, A., Kvashin, A. N., Laaksonen, A., Lehtipalo, K.,
Makhmutov, V., Mathot, S., Nieminen, T., Onnela, A., Petäjä, T., Praplan, A. P., Santos, F. D., Schallhart, S.,
Seinfeld, J. H., Sipilä, M., Spracklen, D. V., Stozhkov,
Y., Stratmann, F., Tomeì, A., Tsagkogeorgas, G., Vaattovaara, P.,
Viisanen, Y., Vrtala, A., Wagner, P. E., Weingart- ner, E., Wex, H., Wimmer,
D., Carslaw, K. S., Curtius, J., Donahue, N. M., Kirkby, J., Kulmala, M.,
Worsnop, D. R., and Baltensperger, U.: Oxidation products of biogenic
emissions contribute to nucleation of atmospheric particles, Science, 344,
717–721, https://doi.org/10.1126/science.1243527, 2014.
Rychlik, K., Secrest, J. R., Lauc, C., Pulczinski, J., Zamora, M. L., Leal,
J., Langleya, R., Myatt, L., Raju, M., Chang, R. C.-A., Li, Y., Golding,
M. C., Rodrigues-Hoffmann, A., Molina, M. J., Zhang, R., and Johnson, N. M.: In
utero ultrafine particulate matter exposure causes offspring pulmonary
immunosuppression, P. Natl. Acad. Sci. USA, 116, 3443–3448,
https://doi.org/10.1073/pnas.1816103116, 2019.
Tröstl, J., Chuang, W. K., Gordon, H., Heinritzi, M.,
Yan, C., Molteni, U., Ahlm, L., Frege, C., Bianchi, F., Wagner, R., Simon,
M., Lehtipalo, K., Williamson, C., Craven, J. S., Duplissy, J., Adamov,
A., Almeida, J., Bernhammer, A.-K., Breitenlechner, M., Brilke, S., Dias,
A., Ehrhart, S., Flagan, R. C., Franchin, A., Fuchs, C., Guida, R., Gysel,
M., Hansel, A., Hoyle, C. R., Jokinen, T., Junninen, H., Kangasluoma, J.,
Kesk- inen, H., Kim, J., Krapf, M., Kürten, A.,
Laaksonen, A., Lawler, M., Leiminger, M., Mathot, S., Möhler, O., Nieminen, T., Onnela, A., Petäjä, T., Piel, F. M., Miettinen, P., Rissanen, M. P.,
Rondo, L., Sarnela, N., Schobesberger, S., Sengupta, K., Sipilä, M., Smith, J. N., Steiner, G., TomeÌ, A.,
Virtanen, A., Wagner, A. C., Weingartner, E., Wimmer, D., Winkler, P. M.,
Ye, P., Carslaw, K. S., Curtius, J., Dommen, J., Kirkby, J., Kulmala, M.,
Riipinen, I., Worsnop, D. R., Donahue, N. M., and Baltensperger, U.: The
role of low-volatility organic compounds in initial particle growth in the
atmosphere, Nature, 533, 527–531, https://doi.org/10.1038/nature18271, 2016.
Tsona, N. T., Henschel, H., Bork, N., Loukonen, V., and Vehkamäki, H.:
Structures, Hydration, and Electrical Mobilities of Bisulfate Ion–Sulfuric
Acid–Ammonia/Dimethylamine Clusters: A Computational Study, J. Phys. Chem.
A, 119, 9670–9679, https://doi.org/10.1021/acs.jpca.5b03030, 2015.
Wang, C.-Y., Jiang, S., Liu, Y.-R., Wen, H., Wang, Z.-Q., Han, Y.-J., Huang,
T., and Huang, W.: Synergistic Effect of Ammonia and Methylamine on Nucleation
in the Earth's Atmosphere. A Theoretical Study, J. Phys. Chem. A, 122,
3470–3479, https://doi.org/10.1021/acs.jpca.8b00681, 2018.
Wang, J., Krejci, R., Giangrande, S., Kuang, C., Barbosa, H. M. J., Brito,
J., Carbone, S., Chi, X., Comstock, J., Ditas, F., Lavric, J., Manninen, H.
E., Mei, F., Moran-Zuloaga, D., Pöhlker, C.,
Pöh- lker, M. L., Saturno, J., Schmid, B., Souza, R. A.
F., Springston, S. R., Tomlinson, J. M., Toto, T., Walter, D., Wimmer, D.,
Smith, J. N., Kulmala, M., Machado, L. A. T., Artaxo, P., Andreae, M. O.,
Petäjä, T., and Martin, S. T.: Amazon
boundary layer aerosol concentration sustained by vertical transport during
rainfall, Nature, 539, 416–419, https://doi.org/10.1038/nature19819,
2016.
Wang, L., Khalizov, A.F., Zheng, J., Xu, W., Lal, V., Ma, Y., and Zhang, R.:
Atmospheric nanoparticles formed from heterogeneous reactions of organics,
Nat. Geosci., 3, 238–242, https://doi.org/10.1038/ngeo778, 2010.
Wang, Z. B., Hu, M., Mogensen, D., Yue, D. L., Zheng, J., Zhang, R. Y., Liu, Y., Yuan, B., Li, X., Shao, M., Zhou, L., Wu, Z. J., Wiedensohler, A., and Boy, M.: The simulations of sulfuric acid concentration and new particle formation in an urban atmosphere in China, Atmos. Chem. Phys., 13, 11157–11167, https://doi.org/10.5194/acp-13-11157-2013, 2013.
Weber, K. H., Liu, Q., and Tao, F.-M.: Theoretical study on stable small clusters of oxalic acid with ammonia and water, J. Phys. Chem. A, 118, 1451–1468, https://doi.org/10.1021/jp4128226, 2014.
Wexler, A.: Vapor pressure formulation for water in range 0 to 100 C. A
revision, J. Res. Nat. Bur. Stand., 80A, 775–785, 1976.
Wu, G., Brown, J., Zamora, M. L., Miller, A., Satterfield, M. C., Meininger, C. J., Steinhauser, C. B., Johnson, G. A., Burghardt, R. C., Bazer, F. W., Li, Y., Johnson, N. M., Molina, M. J., and Zhang, R.: Adverse organogenesis and predisposed long-term metabolic syndrome from prenatal exposure to fine particulate matter, P. Natl. Acad. Sci. USA, 116, 11590–11595, https://doi.org/10.1073/pnas.1902925116, 2019.
Xu, W. and Zhang, R.: Theoretical investigation of interaction of
dicarboxylic acids with common aerosol nucleation precursors, J. Phys.
Chem., 116, 4539-4550, https://doi.org/10.1021/jp301964u, 2012.
Xu, W. and Zhang, R.: A theoretical study of hydrated molecular clusters of
amines and dicarboxylic acids, J. Chem. Phys., 139, 064312,
https://doi.org/10.1063/1.4817497, 2013.
Xu, W., Gomez-Hernandez, M., Guo, S., Secrest, J., Marrero-Ortiz, W., Zhang,
A. L., and Zhang, R.: Acid-catalyzed reactions of epoxides for atmospheric
nanoparticle growth, J. Am. Chem. Soc., 136, 15477–15480,
https://doi.org/10.1021/ja508989a, 2014.
Xu, Y., Nadykto, A. B., Yu, F., Jiang, L., and Wang, W.: Formation and
properties of hydrogen-bonded complexes of common organic oxalic acid with
atmospheric nucleation precursors, J. Mol. Struct.-Theochem., 951, 28–33,
https://doi.org/10.1016/j.theochem.2010.04.004, 2010a.
Xu, Y., Nadykto, A. B., Yu, F., Herb, J., and Wang, W.: Interaction between
common organic acids and trace nucleation species in the Earth's atmosphere,
J. Phys. Chem. A, 114, 387–396, https://doi.org/10.1021/jp9068575, 2010b.
Yao, L., Garmash, O., Bianchi, F., Zheng, J., Yan, C., Kontkanen, J.,
Junninen, H., Mazon, B. S., Ehn, M., Paasonen, P., Sipila, M., Wang, M.,
Wang, X., Xiao, S., Chen, H., Lu, Y., Zhang, B., Wang, D., Fu, Q., Geng, F.,
Li, L., Wang, H., Qiao, L., Yang, X., Chen, J., Kerminen, V.,
PetajÁ, T., Worsnop, D., Kulmala, M., and Wang, L.:
Atmospheric new particle formation from sulfuric acid and amines in a
Chinese megacity, Science, 361, 278–281,
https://doi.org/10.1126/science.aao4839, 2018.
Yu, H., McGraw, R., and Lee, S.-H.: Effects of amines on formation of sub-3
nm particles and their subsequent growth, Geophys. Res. Lett., 39, L02807,
https://doi.org/10.1029/2011GL050099, 2012.
Yue, D. L., Hu, M., Zhang, R. Y., Wang, Z. B., Zheng, J., Wu, Z. J., Wiedensohler, A., He, L. Y., Huang, X. F., and Zhu, T.: The roles of sulfuric acid in new particle formation and growth in the mega-city of Beijing, Atmos. Chem. Phys., 10, 4953–4960, https://doi.org/10.5194/acp-10-4953-2010, 2010.
Yue, D. L., Hu, M., Zhang, R. Y., Wu, Z. J., Su, H., Wang, Z. B., and
Wiedensohler, A.: Potential contribution of new particle formation to cloud
condensation nuclei in Beijing, Atmos. Environ., 45, 6070–6077,
https://doi.org/10.1016/j.atmosenv.2011.07.037, 2011.
Zhang, R.: Getting to the critical nucleus of aerosol formation, Science,
328, 1366–1367, https://doi.org/10.1126/science.1189732, 2010.
Zhang, R., Suh, I., Zhao, J., Zhang, D., Fortner, E. C., Tie, X., Molina, L.
T., and Molina, M. J.: Atmospheric new particle formation enhanced by
organic acids, Science, 304, 1487–1490,
https://doi.org/10.1126/science.1095139, 2004.
Zhang, R., Wang, L., Khalizov, A. F., Zhao, J., Zheng, J., McGraw, R. L.,
and Molina, L. T.: Formation of nanoparticles of blue haze enhanced by
anthropogenic pollution, P. Natl. Acad. Sci. USA, 106, 17650–17654,
https://doi.org/10.1073/pnas.0910125106, 2009.
Zhang, R., Khalizov, A. F., Wang, L., Hu, M., and Xu, W.: Nucleation and growth
of nanoparticles in the atmosphere, Chem. Rev., 112, 1957–2011,
https://doi.org/10.1021/cr2001756, 2012.
Zhang, R., Wang, G., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang, W.,
Hu, M., and Wang Y.: Formation of urban fine particulate matter, Chem. Rev.,
115, 3803–3855, https://doi.org/10.1021/acs.chemrev.5b00067, 2015.
Zhao, J., Khalizov, A., Zhang, R., and McGraw, R.: Hydrogen bonding
interaction of molecular complexes and clusters of aerosol nucleation
precursors, J. Phys. Chem. A, 113, 680–689,
https://doi.org/10.1021/jp806693r, 2009.
Zhu, Y. P., Liu, Y. R., Huang, T., Jiang, S., Xu, K. M., Wen, H., Zhang, W.
J., and Huang, W.: Theoretical study of the hydration of atmospheric
nucleation precursors with acetic acid, J. Phys. Chem. A, 118, 7959–7974,
https://doi.org/10.1021/jp506226z, 2014.
Short summary
We have investigated the molecular interactions between succinic acid and sulfuric acid–base clusters in the presence of hydration, including ammonia and dimethylamine. Our results indicate that the multicomponent nucleation involving organic acids, sulfuric acid, and base species promotes new particle formation in the atmosphere, particularly under polluted conditions.
We have investigated the molecular interactions between succinic acid and sulfuric acid–base...
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