Articles | Volume 19, issue 6
https://doi.org/10.5194/acp-19-3779-2019
https://doi.org/10.5194/acp-19-3779-2019
Research article
 | 
25 Mar 2019
Research article |  | 25 Mar 2019

Seasonality in the Δ33S measured in urban aerosols highlights an additional oxidation pathway for atmospheric SO2

David Au Yang, Pierre Cartigny, Karine Desboeufs, and David Widory

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Cited articles

Albrecht, B. A.: Aerosols, cloud microphysics, and fractional cloudiness, Science, 245, 1227–1230, 1989. 
Andreae, M. O. and Crutzen, P. J.: Atmospheric Aerosols: Biogeochemical Sources and Role in Atmospheric Chemistry, Science, 276, 1052–1058, https://doi.org/10.1126/science.276.5315.1052, 1997. 
Alexander, B., Park, R., Jacob, D., and Gong, S.: Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget, J. Geophys. Res.-Atmos., 114, D02309, https://doi.org/10.1029/2008JD010486, 2009. 
Alexander, B., Allman, D., Amos, H., Fairlie, T., Dachs, J., Hegg, D. A., and Sletten, R. S.: Isotopic constraints on the formation pathways of sulfate aerosol in the marine boundary layer of the subtropical northeast Atlantic Ocean, J. Geophys. Res.-Atmos., 117, D06304, https://doi.org/10.1029/2011JD016773, 2012. 
An, L., Che, H., Xue, M., Zhang, T., Wang, H., Wang, Y., Zhou, C., Zhao, H., Gui, K., and Zheng, Y.: Temporal and spatial variations in sand and dust storm events in East Asia from 2007 to 2016: Relationships with surface conditions and climate change, Sci. Total Environ., 633, 452–462, 2018. 
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Short summary
Sulfates present in urban aerosols collected worldwide usually exhibit 33S-anomalies whose origin remains unclear. Besides, the sulfate concentration is not very well modelled nowadays, which, coupled with the isotopic composition anomaly on the 33S, would highlight the presence of at least an additional oxidation pathway, different from O2+TMI, O3, OH, H2O2 and NO2. We suggest here the implication of two other possible oxidation pathways.
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