Articles | Volume 19, issue 6
https://doi.org/10.5194/acp-19-3779-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-3779-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Mar 2019
Research article |
| 25 Mar 2019
| 25 Mar 2019
Seasonality in the Δ33S measured in urban aerosols highlights an additional oxidation pathway for atmospheric SO2
David Au Yang
CORRESPONDING AUTHOR
Laboratoire de Géochimie des Isotopes Stables, Institut de
Physique du Globe de Paris, Université Paris Diderot, CNRS UMR 7154,
Sorbonne Paris-Cité, 1 rue de Jussieu, 75005 Paris, France
GEOTOP/Université du Québec à Montreal, Montreal H3C
3P8, Canada
Pierre Cartigny
Laboratoire de Géochimie des Isotopes Stables, Institut de
Physique du Globe de Paris, Université Paris Diderot, CNRS UMR 7154,
Sorbonne Paris-Cité, 1 rue de Jussieu, 75005 Paris, France
Karine Desboeufs
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583 CNRS, Université Paris 7 Denis Diderot, Université
Paris-Est Créteil, Institut Pierre-Simon Laplace, Créteil, 94010,
France
David Widory
GEOTOP/Université du Québec à Montreal, Montreal H3C
3P8, Canada
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21 citations as recorded by crossref.
- More evidence on primary sulfate emission from residential coal combustion in northern China: Insights from the size-segregated chemical profile, morphology, and sulfur isotope L. Song et al. 10.1016/j.atmosenv.2024.120467
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- Toward the Origins of Quadruple Sulfur Isotope Anomalies in Modern Sulfate: A Multitracer Approach and Implications for Paleo- and Planetary Atmospheres B. Yin et al. 10.1021/acsearthspacechem.2c00360
- Sulfur Isotope Anomalies (Δ33S) in Urban Air Pollution Linked to Mineral-Dust-Associated Sulfate S. Dasari et al. 10.1021/acs.estlett.2c00312
- Retrospective Isotopic Analysis of Summertime Urban Atmospheric Sulfate in South Asia Using Improved Source Constraints S. Dasari & D. Widory 10.1021/acsestair.3c00060
- Sulfur aerosols in the Arctic, Antarctic, and Tibetan Plateau: Current knowledge and future perspectives Q. Pei et al. 10.1016/j.earscirev.2021.103753
- The Dziani Dzaha Lake: A long‐awaited modern analogue for superheavy pyrites P. Cadeau et al. 10.1111/gbi.12486
- High-precision laser spectroscopy of H2S for simultaneous probing of multiple-sulfur isotopes J. Chaillot et al. 10.1039/D2VA00104G
- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- Oxygen and sulfur mass-independent isotopic signatures in black crusts: the complementary negative Δ<sup>33</sup>S reservoir of sulfate aerosols? I. Genot et al. 10.5194/acp-20-4255-2020
- Elucidating the sources and dynamics of PM10 aerosols in Cienfuegos (Cuba) using their multi-stable and radioactive isotope and ion compositions Y. Morera-Gómez et al. 10.1016/j.atmosres.2020.105038
- Application of Stable Isotopes in Identifying the Sources and Formation of Sulfate and Nitrate in PM2.5: A Review J. Peng et al. 10.3390/atmos15111312
- An analysis of Δ36S/Δ33S dependence on definitions of sulfur mass-independent fractionation Y. Endo et al. 10.1016/j.chemgeo.2024.122157
- Mass-independent fractionation of oxygen and sulfur isotopes M. LIN 10.3724/j.issn.1007-2802.20240026
- Carbonaceous Fractions Contents and Carbon Stable Isotope Compositions of Aerosols Collected in the Atmosphere of Montreal (Canada): Seasonality, Sources, and Implications Y. Morera-Gómez et al. 10.3389/fenvs.2021.622521
- South-hemispheric marine aerosol Hg and S isotope compositions reveal different oxidation pathways D. AuYang et al. 10.1360/nso/20220014
- Identification of potential sources of elevated PM2.5-Hg using mercury isotopes during haze events Y. Qiu et al. 10.1016/j.atmosenv.2021.118203
- Sulfur-isotope anomalies recorded in Antarctic ice cores as a potential proxy for tracing past ozone layer depletion events S. Dasari et al. 10.1093/pnasnexus/pgac170
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
19 citations as recorded by crossref.
- More evidence on primary sulfate emission from residential coal combustion in northern China: Insights from the size-segregated chemical profile, morphology, and sulfur isotope L. Song et al. 10.1016/j.atmosenv.2024.120467
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- Toward the Origins of Quadruple Sulfur Isotope Anomalies in Modern Sulfate: A Multitracer Approach and Implications for Paleo- and Planetary Atmospheres B. Yin et al. 10.1021/acsearthspacechem.2c00360
- Sulfur Isotope Anomalies (Δ33S) in Urban Air Pollution Linked to Mineral-Dust-Associated Sulfate S. Dasari et al. 10.1021/acs.estlett.2c00312
- Retrospective Isotopic Analysis of Summertime Urban Atmospheric Sulfate in South Asia Using Improved Source Constraints S. Dasari & D. Widory 10.1021/acsestair.3c00060
- Sulfur aerosols in the Arctic, Antarctic, and Tibetan Plateau: Current knowledge and future perspectives Q. Pei et al. 10.1016/j.earscirev.2021.103753
- The Dziani Dzaha Lake: A long‐awaited modern analogue for superheavy pyrites P. Cadeau et al. 10.1111/gbi.12486
- High-precision laser spectroscopy of H2S for simultaneous probing of multiple-sulfur isotopes J. Chaillot et al. 10.1039/D2VA00104G
- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- Oxygen and sulfur mass-independent isotopic signatures in black crusts: the complementary negative Δ<sup>33</sup>S reservoir of sulfate aerosols? I. Genot et al. 10.5194/acp-20-4255-2020
- Elucidating the sources and dynamics of PM10 aerosols in Cienfuegos (Cuba) using their multi-stable and radioactive isotope and ion compositions Y. Morera-Gómez et al. 10.1016/j.atmosres.2020.105038
- Application of Stable Isotopes in Identifying the Sources and Formation of Sulfate and Nitrate in PM2.5: A Review J. Peng et al. 10.3390/atmos15111312
- An analysis of Δ36S/Δ33S dependence on definitions of sulfur mass-independent fractionation Y. Endo et al. 10.1016/j.chemgeo.2024.122157
- Mass-independent fractionation of oxygen and sulfur isotopes M. LIN 10.3724/j.issn.1007-2802.20240026
- Carbonaceous Fractions Contents and Carbon Stable Isotope Compositions of Aerosols Collected in the Atmosphere of Montreal (Canada): Seasonality, Sources, and Implications Y. Morera-Gómez et al. 10.3389/fenvs.2021.622521
- South-hemispheric marine aerosol Hg and S isotope compositions reveal different oxidation pathways D. AuYang et al. 10.1360/nso/20220014
- Identification of potential sources of elevated PM2.5-Hg using mercury isotopes during haze events Y. Qiu et al. 10.1016/j.atmosenv.2021.118203
- Sulfur-isotope anomalies recorded in Antarctic ice cores as a potential proxy for tracing past ozone layer depletion events S. Dasari et al. 10.1093/pnasnexus/pgac170
2 citations as recorded by crossref.
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
Latest update: 14 Dec 2024
Short summary
Sulfates present in urban aerosols collected worldwide usually exhibit 33S-anomalies whose origin remains unclear. Besides, the sulfate concentration is not very well modelled nowadays, which, coupled with the isotopic composition anomaly on the 33S, would highlight the presence of at least an additional oxidation pathway, different from O2+TMI, O3, OH, H2O2 and NO2. We suggest here the implication of two other possible oxidation pathways.
Sulfates present in urban aerosols collected worldwide usually exhibit 33S-anomalies whose...
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