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Volume 17, issue 24
Atmos. Chem. Phys., 17, 15167–15180, 2017
https://doi.org/10.5194/acp-17-15167-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 17, 15167–15180, 2017
https://doi.org/10.5194/acp-17-15167-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 21 Dec 2017

Research article | 21 Dec 2017

Biogenic, urban, and wildfire influences on the molecular composition of dissolved organic compounds in cloud water

Ryan D. Cook et al.

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Cited articles

Aleksic, N. and Dukett, J. E.: Probabilistic relationship between liquid water content and ion concentrations in cloud water, Atmos. Res., 98, 400–405, https://doi.org/10.1016/j.atmosres.2010.08.003, 2010.
Aleksic, N., Roy, K., Sistla, G., Dukett, J., Houck, N., and Casson, P.: Analysis of cloud and precipitation chemistry at Whiteface Mountain, NY, Atmos. Environ., 43, 2709–2716, https://doi.org/10.1016/j.atmosenv.2009.02.053, 2009.
Aljawhary, D., Zhao, R., Lee, A. K. Y., Wang, C., and Abbatt, J. P. D.: Kinetics, Mechanism, and Secondary Organic Aerosol Yield of Aqueous Phase Photo-oxidation of α-Pinene Oxidation Products, J. Phys. Chem. A, 120, 1395–1407, https://doi.org/10.1021/acs.jpca.5b06237, 2016.
Altieri, K. E., Carlton, A. G., Lim, H.-J., Turpin, B. J., and Seitzinger, S. P.: Evidence for Oligomer Formation in Clouds: Reactions of Isoprene Oxidation Products, Environ. Sci. Technol., 40, 4956–4960, https://doi.org/10.1021/es052170n, 2006.
Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud methylglyoxal reactions: Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ., 42, 1476–1490, https://doi.org/10.1016/j.atmosenv.2007.11.015, 2008.
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Reactions occur within water in both atmospheric particles and cloud droplets, yet little is known about the organic compounds in cloud water. In this work, cloud water samples were collected at Whiteface Mountain, New York, and analyzed using ultra-high-resolution mass spectrometry to investigate the molecular composition of the dissolved organic compounds. The results focus on changes in cloud water composition with air mass origin – influences of forest, urban, and wildfire emissions.
Reactions occur within water in both atmospheric particles and cloud droplets, yet little is...
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