Articles | Volume 16, issue 11
https://doi.org/10.5194/acp-16-6721-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-6721-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
03 Jun 2016
Research article |
| 03 Jun 2016
Substantial secondary organic aerosol formation in a coniferous forest: observations of both day- and nighttime chemistry
Alex K. Y. Lee
CORRESPONDING AUTHOR
Department of Chemistry, University of Toronto, Toronto, Canada
Jonathan P. D. Abbatt
Department of Chemistry, University of Toronto, Toronto, Canada
W. Richard Leaitch
Science and Technology Branch, Environment Canada, Downsview, Canada
Shao-Meng Li
Science and Technology Branch, Environment Canada, Downsview, Canada
Steve J. Sjostedt
Department of Chemistry, University of Toronto, Toronto, Canada
now at: NOAA ESRL Chemical Sciences Division, Boulder, USA
Jeremy J. B. Wentzell
Science and Technology Branch, Environment Canada, Downsview, Canada
John Liggio
Science and Technology Branch, Environment Canada, Downsview, Canada
Anne Marie Macdonald
Science and Technology Branch, Environment Canada, Downsview, Canada
Related authors
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-3240, https://doi.org/10.5194/egusphere-2024-3240, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
This work advances our understanding of emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
Short summary
Short summary
The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Mutian Ma, Laura-Hélèna Rivellini, YuXi Cui, Megan D. Willis, Rio Wilkie, Jonathan P. D. Abbatt, Manjula R. Canagaratna, Junfeng Wang, Xinlei Ge, and Alex K. Y. Lee
Atmos. Meas. Tech., 14, 2799–2812, https://doi.org/10.5194/amt-14-2799-2021, https://doi.org/10.5194/amt-14-2799-2021, 2021
Short summary
Short summary
Chemical characterization of organic coatings is important to advance our understanding of the physio-chemical properties and atmospheric processing of black carbon (BC) particles. This work develops two approaches to improve the elemental analysis of oxygenated organic coatings using a soot-particle aerosol mass spectrometer. Analyzing ambient data with the new approaches indicated that secondary organics that coated on BC were likely less oxygenated compared to those externally mixed with BC.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
Short summary
Short summary
We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
Laura-Hélèna Rivellini, Max Gerrit Adam, Nethmi Kasthuriarachchi, and Alex King Yin Lee
Atmos. Chem. Phys., 20, 5977–5993, https://doi.org/10.5194/acp-20-5977-2020, https://doi.org/10.5194/acp-20-5977-2020, 2020
Short summary
Short summary
This work highlights that trace metals and refractory black carbon (rBC), and their inclusion in a source–receptor model, can provide important insight into the source apportionment of carbonaceous aerosols. In Singapore, we evidenced that 90 % of rBC originated from traffic/industrial emissions. The association of aged OA with K and Rb underlines the influence of regional biomass burning sources, while rBC fragmentation patterns and V/Ni were used to identify industrial and shipping pollutants.
Zoë Y. W. Davis, Udo Frieß, Kevin B. Strawbridge, Monika Aggarwaal, Sabour Baray, Elijah G. Schnitzler, Akshay Lobo, Vitali E. Fioletov, Ihab Abboud, Chris A. McLinden, Jim Whiteway, Megan D. Willis, Alex K. Y. Lee, Jeff Brook, Jason Olfert, Jason O'Brien, Ralf Staebler, Hans D. Osthoff, Cristian Mihele, and Robert McLaren
Atmos. Meas. Tech., 13, 1129–1155, https://doi.org/10.5194/amt-13-1129-2020, https://doi.org/10.5194/amt-13-1129-2020, 2020
Short summary
Short summary
Here, we evaluate a ground-based remote sensing method (MAX-DOAS) for measuring total pollutant loading and vertical profiles of pollution in the lower atmosphere by comparing our method to a variety of other measurement methods (lidar, sunphotometer, active DOAS, and aircraft measurements). Measurements were made in the Athabasca Oil Sands Region in Alberta, Canada. The complex dataset provided a rare opportunity to evaluate the performance of MAX-DOAS under varying atmospheric conditions.
Alex K. Y. Lee, Max G. Adam, John Liggio, Shao-Meng Li, Kun Li, Megan D. Willis, Jonathan P. D. Abbatt, Travis W. Tokarek, Charles A. Odame-Ankrah, Hans D. Osthoff, Kevin Strawbridge, and Jeffery R. Brook
Atmos. Chem. Phys., 19, 12209–12219, https://doi.org/10.5194/acp-19-12209-2019, https://doi.org/10.5194/acp-19-12209-2019, 2019
Short summary
Short summary
This work provides the first direct field evidence that anthropogenic organo-nitrate contributed up to half of secondary organic aerosol (SOA) mass that was freshly produced within the emission plumes of oil sands facilities in Alberta, Canada. The findings illustrate the central role of organo-nitrate in SOA production from the oil and gas industry, with relevance for other urban and industrial regions with significant intermediate-volatility organic compounds (IVOCs) and NOx emissions.
Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 57–76, https://doi.org/10.5194/acp-19-57-2019, https://doi.org/10.5194/acp-19-57-2019, 2019
Short summary
Short summary
The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.
Travis W. Tokarek, Charles A. Odame-Ankrah, Jennifer A. Huo, Robert McLaren, Alex K. Y. Lee, Max G. Adam, Megan D. Willis, Jonathan P. D. Abbatt, Cristian Mihele, Andrea Darlington, Richard L. Mittermeier, Kevin Strawbridge, Katherine L. Hayden, Jason S. Olfert, Elijah G. Schnitzler, Duncan K. Brownsey, Faisal V. Assad, Gregory R. Wentworth, Alex G. Tevlin, Douglas E. J. Worthy, Shao-Meng Li, John Liggio, Jeffrey R. Brook, and Hans D. Osthoff
Atmos. Chem. Phys., 18, 17819–17841, https://doi.org/10.5194/acp-18-17819-2018, https://doi.org/10.5194/acp-18-17819-2018, 2018
Short summary
Short summary
Measurements of air pollutants at a ground site near Fort McKay in the Athabasca oil sands region in the summer of 2013 are presented. A large number of intermediate-volatility organic compounds (IVOCs) were observed; these molecules were shown previously to generate atmospheric particles downwind of the region. A principal component analysis was performed to identify major pollution source types, including which source(s) is(are) associated with IVOC emissions (e.g., freshly mined bitumen).
Alex K. Y. Lee, Chia-Li Chen, Jun Liu, Derek J. Price, Raghu Betha, Lynn M. Russell, Xiaolu Zhang, and Christopher D. Cappa
Atmos. Chem. Phys., 17, 15055–15067, https://doi.org/10.5194/acp-17-15055-2017, https://doi.org/10.5194/acp-17-15055-2017, 2017
Short summary
Short summary
Understanding the mixing state of ambient black carbon (BC) and the chemical characteristics of its associated coatings is important to evaluate BC fate and environmental impacts. This study reports fresh secondary organic aerosol (SOA) formation near traffic emissions during daytime. Our observations suggest that BC was unlikely the major condensation sink of SOA, and a portion of SOA condensed on BC surface was chemically different from other SOA particles that were externally mixed with BC.
Alex K. Y. Lee, Megan D. Willis, Robert M. Healy, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 5561–5572, https://doi.org/10.5194/acp-16-5561-2016, https://doi.org/10.5194/acp-16-5561-2016, 2016
Short summary
Short summary
Single-particle measurements from a soot-particle aerosol mass spectrometer were performed to examine the mixing state of aerosol particles in an air mass influenced by aged biomass burning. Our observations indicate non-uniform mixing of particles within a biomass burning plume in terms of molecular weight and potassium content, and illustrate that high molecular weight organic compounds can be a key contributor to low-volatility BrC observed in biomass burning organic aerosols.
Megan D. Willis, Robert M. Healy, Nicole Riemer, Matthew West, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, Jonathan P. D. Abbatt, and Alex K. Y. Lee
Atmos. Chem. Phys., 16, 4693–4706, https://doi.org/10.5194/acp-16-4693-2016, https://doi.org/10.5194/acp-16-4693-2016, 2016
R. Zhao, A. K. Y. Lee, L. Huang, X. Li, F. Yang, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 6087–6100, https://doi.org/10.5194/acp-15-6087-2015, https://doi.org/10.5194/acp-15-6087-2015, 2015
Short summary
Short summary
Aqueous-phase photochemical decay of light absorbing organic compounds, or atmospheric brown carbon (BrC), is investigated in this study. The absorptive change of laboratory surrogates of BrC, as well as biofuel combustion samples, were monitored during photolysis and OH oxidation experiments. The major finding is the rapid change in the absorptivity of BrC during such photochemical processing. This change should be taken into account to evaluate the importance of BrC in the atmosphere.
A. K. Y. Lee, M. D. Willis, R. M. Healy, T. B. Onasch, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 1823–1841, https://doi.org/10.5194/acp-15-1823-2015, https://doi.org/10.5194/acp-15-1823-2015, 2015
Short summary
Short summary
Understanding the impact of black carbon (BC) particles on human health and radiative forcing requires knowledge of the BC mixing state. This work investigates the mixing state of BC and other aerosol species in a typical urban area using a single particle mass spectrometry technique. Our results provide quantitative insight into the physical and chemical nature of BC-containing particles near emission and can be used as a basis for our developing understanding of BC evolution in the atmosphere.
M. D. Willis, A. K. Y. Lee, T. B. Onasch, E. C. Fortner, L. R. Williams, A. T. Lambe, D. R. Worsnop, and J. P. D. Abbatt
Atmos. Meas. Tech., 7, 4507–4516, https://doi.org/10.5194/amt-7-4507-2014, https://doi.org/10.5194/amt-7-4507-2014, 2014
R. Zhao, E. L. Mungall, A. K. Y. Lee, D. Aljawhary, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 9695–9706, https://doi.org/10.5194/acp-14-9695-2014, https://doi.org/10.5194/acp-14-9695-2014, 2014
Y. J. Li, D. D. Huang, H. Y. Cheung, A. K. Y. Lee, and C. K. Chan
Atmos. Chem. Phys., 14, 2871–2885, https://doi.org/10.5194/acp-14-2871-2014, https://doi.org/10.5194/acp-14-2871-2014, 2014
D. Aljawhary, A. K. Y. Lee, and J. P. D. Abbatt
Atmos. Meas. Tech., 6, 3211–3224, https://doi.org/10.5194/amt-6-3211-2013, https://doi.org/10.5194/amt-6-3211-2013, 2013
R. Zhao, A. K. Y. Lee, R. Soong, A. J. Simpson, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 5857–5872, https://doi.org/10.5194/acp-13-5857-2013, https://doi.org/10.5194/acp-13-5857-2013, 2013
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-3240, https://doi.org/10.5194/egusphere-2024-3240, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
This work advances our understanding of emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Michael F. Link, Megan S. Claflin, Christina E. Cecelski, Ayomide A. Akande, Delaney Kilgour, Paul A. Heine, Matthew Coggon, Chelsea E. Stockwell, Andrew Jensen, Jie Yu, Han N. Huynh, Jenna C. Ditto, Carsten Warneke, William Dresser, Keighan Gemmell, Spiro Jorga, Rileigh L. Robertson, Joost de Gouw, Timothy Bertram, Jonathan P. D. Abbatt, Nadine Borduas-Dedekind, and Dustin Poppendieck
EGUsphere, https://doi.org/10.5194/egusphere-2024-3132, https://doi.org/10.5194/egusphere-2024-3132, 2024
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
Proton-transfer-reaction mass spectrometry (PTR-MS) is widely used for the measurement of volatile organic compounds (VOCs) both indoors and outdoors. An analytical challenge for PTR-MS measurements is the formation of unintended measurement interferences, product ion distributions (PIDs), that may appear in the data as VOCs of interest. We developed a method for quantifying PID formation and use interlaboratory comparison data to put quantitative constraints on PID formation.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
Short summary
Short summary
The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Tianran Han, Conghui Xie, Yayong Liu, Yanrong Yang, Yuheng Zhang, Yufei Huang, Xiangyu Gao, Xiaohua Zhang, Fangmin Bao, and Shao-Meng Li
Atmos. Meas. Tech., 17, 677–691, https://doi.org/10.5194/amt-17-677-2024, https://doi.org/10.5194/amt-17-677-2024, 2024
Short summary
Short summary
This study reported an integrated UAV measurement platform for GHG monitoring and its application for emission quantification from a coking plant. The key element of this system is a newly designed air sampler, consisting of a 150 m long tube with remote-controlled time stamping. When comparing the top-down results to those derived from the bottom-up inventory method, the present findings indicate that the use of IPCC emission factors for emission calculations can lead to overestimation.
Yuening Li, Faqiang Zhan, Yushan Su, Ying Duan Lei, Chubashini Shunthirasingham, Zilin Zhou, Jonathan P. D. Abbatt, Hayley Hung, and Frank Wania
Atmos. Meas. Tech., 17, 715–729, https://doi.org/10.5194/amt-17-715-2024, https://doi.org/10.5194/amt-17-715-2024, 2024
Short summary
Short summary
A simple device for sampling gases from the atmosphere without the help of pumps was calibrated for an important group of hazardous air pollutants called polycyclic aromatic compounds (PACs). While the sampler appeared to perform well when used for relatively short periods of up to several months, some PACs were lost from the sampler during longer deployments. Sampling rates that can be used to quantitatively interpret the quantities of PACs taken up in the device have been derived.
Yanrong Yang, Yuheng Zhang, Tianran Han, Conghui Xie, Yayong Liu, Yufei Huang, Jietao Zhou, Haijiong Sun, Delong Zhao, Kui Zhang, and Shao-Meng Li
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-248, https://doi.org/10.5194/amt-2023-248, 2024
Preprint withdrawn
Short summary
Short summary
The paper introduces a correction algorithm for accurate wind speed measurement in a multirotor unmanned aerial vehicle (UAV) with a sonic anemometer. Addressing propeller rotation, UAV movement, and attitude changes, it integrates computational fluid dynamics simulation and regression analysis. This comprehensive algorithm corrects rotor disturbances, motion, and attitude variations. Validation against meteorological tower data demonstrates its enhanced reliability in wind speed measurements.
Jonathan P. D. Abbatt and A. R. Ravishankara
Atmos. Chem. Phys., 23, 9765–9785, https://doi.org/10.5194/acp-23-9765-2023, https://doi.org/10.5194/acp-23-9765-2023, 2023
Short summary
Short summary
With important climate and air quality impacts, atmospheric multiphase chemistry involves gas interactions with aerosol particles and cloud droplets. We summarize the status of the field and discuss potential directions for future growth. We highlight the importance of a molecular-level understanding of the chemistry, along with atmospheric field studies and modeling, and emphasize the necessity for atmospheric multiphase chemists to interact widely with scientists from neighboring disciplines.
Taomou Zong, Zhijun Wu, Junrui Wang, Kai Bi, Wenxu Fang, Yanrong Yang, Xuena Yu, Zhier Bao, Xiangxinyue Meng, Yuheng Zhang, Song Guo, Yang Chen, Chunshan Liu, Yue Zhang, Shao-Meng Li, and Min Hu
Atmos. Meas. Tech., 16, 3679–3692, https://doi.org/10.5194/amt-16-3679-2023, https://doi.org/10.5194/amt-16-3679-2023, 2023
Short summary
Short summary
This study developed and characterized an indoor chamber system (AIR) to simulate atmospheric multiphase chemistry processes. The AIR chamber can accurately control temperature and relative humidity (RH) over a broad range and simulate diurnal variation of ambient atmospheric RH. The aerosol generation unit can generate organic-coating seed particles with different phase states. The AIR chamber demonstrates high-quality performance in simulating secondary aerosol formation.
Broghan M. Erland, Cristen Adams, Andrea Darlington, Mackenzie L. Smith, Andrew K. Thorpe, Gregory R. Wentworth, Steve Conley, John Liggio, Shao-Meng Li, Charles E. Miller, and John A. Gamon
Atmos. Meas. Tech., 15, 5841–5859, https://doi.org/10.5194/amt-15-5841-2022, https://doi.org/10.5194/amt-15-5841-2022, 2022
Short summary
Short summary
Accurately estimating greenhouse gas (GHG) emissions is essential to reaching net-zero goals to combat the climate crisis. Airborne box-flights are ideal for assessing regional GHG emissions, as they can attain small error. We compare two box-flight algorithms and found they produce similar results, but daily variability must be considered when deriving emissions inventories. Increasing the consistency and agreement between airborne methods moves us closer to achieving more accurate estimates.
Katherine L. Hayden, Shao-Meng Li, John Liggio, Michael J. Wheeler, Jeremy J. B. Wentzell, Amy Leithead, Peter Brickell, Richard L. Mittermeier, Zachary Oldham, Cristian M. Mihele, Ralf M. Staebler, Samar G. Moussa, Andrea Darlington, Mengistu Wolde, Daniel Thompson, Jack Chen, Debora Griffin, Ellen Eckert, Jenna C. Ditto, Megan He, and Drew R. Gentner
Atmos. Chem. Phys., 22, 12493–12523, https://doi.org/10.5194/acp-22-12493-2022, https://doi.org/10.5194/acp-22-12493-2022, 2022
Short summary
Short summary
In this study, airborne measurements provided the most detailed characterization, to date, of boreal forest wildfire emissions. Measurements showed a large diversity of air pollutants expanding the volatility range typically reported. A large portion of organic species was unidentified, likely comprised of complex organic compounds. Aircraft-derived emissions improve wildfire chemical speciation and can support reliable model predictions of pollution from boreal forest wildfires.
Chong Han, Hongxing Yang, Kun Li, Patrick Lee, John Liggio, Amy Leithead, and Shao-Meng Li
Atmos. Chem. Phys., 22, 10827–10839, https://doi.org/10.5194/acp-22-10827-2022, https://doi.org/10.5194/acp-22-10827-2022, 2022
Short summary
Short summary
We presented yields and compositions of Si-containing SOAs generated from the reaction of cVMSs (D3–D6) with OH radicals. NOx played a negative role in cVMS SOA formation, while ammonium sulfate seeds enhanced D3–D5 SOA yields at short photochemical ages under high-NOx conditions. The aerosol mass spectra confirmed that the components of cVMS SOAs significantly relied on OH exposure. A global cVMS-derived SOA source strength was estimated in order to understand SOA formation potentials of cVMSs.
Rachel Y.-W. Chang, Jonathan P. D. Abbatt, Matthew C. Boyer, Jai Prakash Chaubey, and Douglas B. Collins
Atmos. Chem. Phys., 22, 8059–8071, https://doi.org/10.5194/acp-22-8059-2022, https://doi.org/10.5194/acp-22-8059-2022, 2022
Short summary
Short summary
During summer 2016, the ability of newly formed particles to turn into droplets was measured in the Canadian Arctic. Our observations suggest that these small particles were growing by the condensation of organic vapours likely coming from the surrounding open waters. These particles grew large enough that they could form cloud droplets and therefore affect the earth’s radiation budget. These results are relevant as the Arctic summer rapidly warms with climate change.
Zoé Brasseur, Dimitri Castarède, Erik S. Thomson, Michael P. Adams, Saskia Drossaart van Dusseldorp, Paavo Heikkilä, Kimmo Korhonen, Janne Lampilahti, Mikhail Paramonov, Julia Schneider, Franziska Vogel, Yusheng Wu, Jonathan P. D. Abbatt, Nina S. Atanasova, Dennis H. Bamford, Barbara Bertozzi, Matthew Boyer, David Brus, Martin I. Daily, Romy Fösig, Ellen Gute, Alexander D. Harrison, Paula Hietala, Kristina Höhler, Zamin A. Kanji, Jorma Keskinen, Larissa Lacher, Markus Lampimäki, Janne Levula, Antti Manninen, Jens Nadolny, Maija Peltola, Grace C. E. Porter, Pyry Poutanen, Ulrike Proske, Tobias Schorr, Nsikanabasi Silas Umo, János Stenszky, Annele Virtanen, Dmitri Moisseev, Markku Kulmala, Benjamin J. Murray, Tuukka Petäjä, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 22, 5117–5145, https://doi.org/10.5194/acp-22-5117-2022, https://doi.org/10.5194/acp-22-5117-2022, 2022
Short summary
Short summary
The present measurement report introduces the ice nucleation campaign organized in Hyytiälä, Finland, in 2018 (HyICE-2018). We provide an overview of the campaign settings, and we describe the measurement infrastructure and operating procedures used. In addition, we use results from ice nucleation instrument inter-comparison to show that the suite of these instruments deployed during the campaign reports consistent results.
Debora Griffin, Chris A. McLinden, Enrico Dammers, Cristen Adams, Chelsea E. Stockwell, Carsten Warneke, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Kyle J. Zarzana, Jake P. Rowe, Rainer Volkamer, Christoph Knote, Natalie Kille, Theodore K. Koenig, Christopher F. Lee, Drew Rollins, Pamela S. Rickly, Jack Chen, Lukas Fehr, Adam Bourassa, Doug Degenstein, Katherine Hayden, Cristian Mihele, Sumi N. Wren, John Liggio, Ayodeji Akingunola, and Paul Makar
Atmos. Meas. Tech., 14, 7929–7957, https://doi.org/10.5194/amt-14-7929-2021, https://doi.org/10.5194/amt-14-7929-2021, 2021
Short summary
Short summary
Satellite-derived NOx emissions from biomass burning are estimated with TROPOMI observations. Two common emission estimation methods are applied, and sensitivity tests with model output were performed to determine the accuracy of these methods. The effect of smoke aerosols on TROPOMI NO2 columns is estimated and compared to aircraft observations from four different aircraft campaigns measuring biomass burning plumes in 2018 and 2019 in North America.
Sepehr Fathi, Mark Gordon, Paul A. Makar, Ayodeji Akingunola, Andrea Darlington, John Liggio, Katherine Hayden, and Shao-Meng Li
Atmos. Chem. Phys., 21, 15461–15491, https://doi.org/10.5194/acp-21-15461-2021, https://doi.org/10.5194/acp-21-15461-2021, 2021
Short summary
Short summary
We have investigated the accuracy of aircraft-based mass balance methodologies through computer model simulations of the atmosphere and air quality at a regional high-resolution scale. We have defined new quantitative metrics to reduce emission retrieval uncertainty by evaluating top-down mass balance estimates against the known simulated meteorology and input emissions. We also recommend methodologies and flight strategies for improved retrievals in future aircraft-based studies.
Konstantin Baibakov, Samuel LeBlanc, Keyvan Ranjbar, Norman T. O'Neill, Mengistu Wolde, Jens Redemann, Kristina Pistone, Shao-Meng Li, John Liggio, Katherine Hayden, Tak W. Chan, Michael J. Wheeler, Leonid Nichman, Connor Flynn, and Roy Johnson
Atmos. Chem. Phys., 21, 10671–10687, https://doi.org/10.5194/acp-21-10671-2021, https://doi.org/10.5194/acp-21-10671-2021, 2021
Short summary
Short summary
We find that the airborne measurements of the vertical extinction due to aerosols (aerosol optical depth, AOD) obtained in the Athabasca Oil Sands Region (AOSR) can significantly exceed ground-based values. This can have an effect on estimating the AOSR radiative impact and is relevant to satellite validation based on ground-based measurements. We also show that the AOD can marginally increase as the plumes are being transported away from the source and the new particles are being formed.
Katherine Hayden, Shao-Meng Li, Paul Makar, John Liggio, Samar G. Moussa, Ayodeji Akingunola, Robert McLaren, Ralf M. Staebler, Andrea Darlington, Jason O'Brien, Junhua Zhang, Mengistu Wolde, and Leiming Zhang
Atmos. Chem. Phys., 21, 8377–8392, https://doi.org/10.5194/acp-21-8377-2021, https://doi.org/10.5194/acp-21-8377-2021, 2021
Short summary
Short summary
We developed a method using aircraft measurements to determine lifetimes with respect to dry deposition for oxidized sulfur and nitrogen compounds over the boreal forest in Alberta, Canada. Atmospheric lifetimes were significantly shorter than derived from chemical transport models with differences related to modelled dry deposition velocities. The shorter lifetimes suggest models need to reassess dry deposition treatment and predictions of sulfur and nitrogen in the atmosphere and ecosystems.
Shunyao Wang, Tengyu Liu, Jinmyung Jang, Jonathan P. D. Abbatt, and Arthur W. H. Chan
Atmos. Chem. Phys., 21, 6647–6661, https://doi.org/10.5194/acp-21-6647-2021, https://doi.org/10.5194/acp-21-6647-2021, 2021
Short summary
Short summary
Discrepancies between atmospheric modeling and field observations, especially in highly polluted cities, have highlighted the lack of understanding of sulfate formation mechanisms and kinetics. Here, we directly quantify the reactive uptake coefficient of SO2 onto organic peroxides and study the important governing factors. The SO2 uptake rate was observed to depend on RH, peroxide amount and reactivity, pH, and ionic strength, which provides a framework to better predict sulfate formation.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Hannes Schulz, Daniel Kunkel, Heiko Bozem, Peter Hoor, Thomas Klimach, Frank Helleis, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 21, 6509–6539, https://doi.org/10.5194/acp-21-6509-2021, https://doi.org/10.5194/acp-21-6509-2021, 2021
Short summary
Short summary
We present in situ observations of vertically resolved particle chemical composition in the summertime Arctic lower troposphere. Our analysis demonstrates the strong vertical contrast between particle properties within the boundary layer and aloft. Emissions from vegetation fires and anthropogenic sources in northern Canada, Europe, and East Asia influenced particle composition in the free troposphere. Organics detected in Arctic aerosol particles can partly be identified as dicarboxylic acids.
Mutian Ma, Laura-Hélèna Rivellini, YuXi Cui, Megan D. Willis, Rio Wilkie, Jonathan P. D. Abbatt, Manjula R. Canagaratna, Junfeng Wang, Xinlei Ge, and Alex K. Y. Lee
Atmos. Meas. Tech., 14, 2799–2812, https://doi.org/10.5194/amt-14-2799-2021, https://doi.org/10.5194/amt-14-2799-2021, 2021
Short summary
Short summary
Chemical characterization of organic coatings is important to advance our understanding of the physio-chemical properties and atmospheric processing of black carbon (BC) particles. This work develops two approaches to improve the elemental analysis of oxygenated organic coatings using a soot-particle aerosol mass spectrometer. Analyzing ambient data with the new approaches indicated that secondary organics that coated on BC were likely less oxygenated compared to those externally mixed with BC.
Jenna C. Ditto, Megan He, Tori N. Hass-Mitchell, Samar G. Moussa, Katherine Hayden, Shao-Meng Li, John Liggio, Amy Leithead, Patrick Lee, Michael J. Wheeler, Jeremy J. B. Wentzell, and Drew R. Gentner
Atmos. Chem. Phys., 21, 255–267, https://doi.org/10.5194/acp-21-255-2021, https://doi.org/10.5194/acp-21-255-2021, 2021
Short summary
Short summary
Forest fires are an important source of reactive organic gases and aerosols to the atmosphere. We analyzed organic aerosols collected from an aircraft above a boreal forest fire and reported an increasing contribution from compounds containing oxygen, nitrogen, and sulfur as the plume aged, with sulfide and ring-bound nitrogen functionality. Our results demonstrated chemistry that is important in biomass burning but also in urban/developing regions with high local nitrogen and sulfur emissions.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
Short summary
Short summary
We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
W. Richard Leaitch, John K. Kodros, Megan D. Willis, Sarah Hanna, Hannes Schulz, Elisabeth Andrews, Heiko Bozem, Julia Burkart, Peter Hoor, Felicia Kolonjari, John A. Ogren, Sangeeta Sharma, Meng Si, Knut von Salzen, Allan K. Bertram, Andreas Herber, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 20, 10545–10563, https://doi.org/10.5194/acp-20-10545-2020, https://doi.org/10.5194/acp-20-10545-2020, 2020
Short summary
Short summary
Black carbon is a factor in the warming of the Arctic atmosphere due to its ability to absorb light, but the uncertainty is high and few observations have been made in the high Arctic above 80° N. We combine airborne and ground-based observations in the springtime Arctic, at and above 80° N, with simulations from a global model to show that light absorption by black carbon may be much larger than modelled. However, the uncertainty remains high.
Mikhail Paramonov, Saskia Drossaart van Dusseldorp, Ellen Gute, Jonathan P. D. Abbatt, Paavo Heikkilä, Jorma Keskinen, Xuemeng Chen, Krista Luoma, Liine Heikkinen, Liqing Hao, Tuukka Petäjä, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 6687–6706, https://doi.org/10.5194/acp-20-6687-2020, https://doi.org/10.5194/acp-20-6687-2020, 2020
Short summary
Short summary
Ice-nucleating particle (INP) measurements were performed in the boreal environment of southern Finland in the winter–spring of 2018. It was found that no single parameter could be used to predict the INP number concentration at the measurement location during the examined time period. It was also not possible to identify physical and chemical properties of ambient INPs despite the complexity of the instrumental set-up. Therefore, this paper addresses the necessity for future INP measurements.
Laura-Hélèna Rivellini, Max Gerrit Adam, Nethmi Kasthuriarachchi, and Alex King Yin Lee
Atmos. Chem. Phys., 20, 5977–5993, https://doi.org/10.5194/acp-20-5977-2020, https://doi.org/10.5194/acp-20-5977-2020, 2020
Short summary
Short summary
This work highlights that trace metals and refractory black carbon (rBC), and their inclusion in a source–receptor model, can provide important insight into the source apportionment of carbonaceous aerosols. In Singapore, we evidenced that 90 % of rBC originated from traffic/industrial emissions. The association of aged OA with K and Rb underlines the influence of regional biomass burning sources, while rBC fragmentation patterns and V/Ni were used to identify industrial and shipping pollutants.
Zoë Y. W. Davis, Udo Frieß, Kevin B. Strawbridge, Monika Aggarwaal, Sabour Baray, Elijah G. Schnitzler, Akshay Lobo, Vitali E. Fioletov, Ihab Abboud, Chris A. McLinden, Jim Whiteway, Megan D. Willis, Alex K. Y. Lee, Jeff Brook, Jason Olfert, Jason O'Brien, Ralf Staebler, Hans D. Osthoff, Cristian Mihele, and Robert McLaren
Atmos. Meas. Tech., 13, 1129–1155, https://doi.org/10.5194/amt-13-1129-2020, https://doi.org/10.5194/amt-13-1129-2020, 2020
Short summary
Short summary
Here, we evaluate a ground-based remote sensing method (MAX-DOAS) for measuring total pollutant loading and vertical profiles of pollution in the lower atmosphere by comparing our method to a variety of other measurement methods (lidar, sunphotometer, active DOAS, and aircraft measurements). Measurements were made in the Athabasca Oil Sands Region in Alberta, Canada. The complex dataset provided a rare opportunity to evaluate the performance of MAX-DOAS under varying atmospheric conditions.
Joelle Dionne, Knut von Salzen, Jason Cole, Rashed Mahmood, W. Richard Leaitch, Glen Lesins, Ian Folkins, and Rachel Y.-W. Chang
Atmos. Chem. Phys., 20, 29–43, https://doi.org/10.5194/acp-20-29-2020, https://doi.org/10.5194/acp-20-29-2020, 2020
Short summary
Short summary
Low clouds persist in the summer Arctic, with important consequences for the radiation budget. We found that the ability of precipitation parameterizations to reproduce observed cloud properties was more variable than their ability to represent radiative effects. Our results show that cloud properties and their parameterizations affect the radiative effects of clouds.
Heiko Bozem, Peter Hoor, Daniel Kunkel, Franziska Köllner, Johannes Schneider, Andreas Herber, Hannes Schulz, W. Richard Leaitch, Amir A. Aliabadi, Megan D. Willis, Julia Burkart, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 15049–15071, https://doi.org/10.5194/acp-19-15049-2019, https://doi.org/10.5194/acp-19-15049-2019, 2019
Short summary
Short summary
We present airborne trace gas measurements in the European and Canadian Arctic for July 2014 and April 2015. Based on CO and CO2 in situ data as well as 10 d kinematic back trajectories, we characterize the prevailing transport regimes and derive a tracer-based diagnostic for the determination of the polar dome boundary. Using the tracer-derived boundary, an analysis of the recent transport history of air masses within the polar dome reveals significant differences between spring and summer.
Roya Ghahreman, Wanmin Gong, Martí Galí, Ann-Lise Norman, Stephen R. Beagley, Ayodeji Akingunola, Qiong Zheng, Alexandru Lupu, Martine Lizotte, Maurice Levasseur, and W. Richard Leaitch
Atmos. Chem. Phys., 19, 14455–14476, https://doi.org/10.5194/acp-19-14455-2019, https://doi.org/10.5194/acp-19-14455-2019, 2019
Short summary
Short summary
Atmospheric DMS(g) is a climatically important compound and the main source of biogenic sulfate in the Arctic. Its abundance in the Arctic increases during summer due to greater ice-free sea surface and higher biological activity. In this study, we implemented DMS(g) in a regional air quality forecast model configured for the Arctic. The study showed a significant impact from DMS(g) on sulfate aerosols, particularly in the 50–100 nm size range, in the Arctic marine boundary layer during summer.
Alex K. Y. Lee, Max G. Adam, John Liggio, Shao-Meng Li, Kun Li, Megan D. Willis, Jonathan P. D. Abbatt, Travis W. Tokarek, Charles A. Odame-Ankrah, Hans D. Osthoff, Kevin Strawbridge, and Jeffery R. Brook
Atmos. Chem. Phys., 19, 12209–12219, https://doi.org/10.5194/acp-19-12209-2019, https://doi.org/10.5194/acp-19-12209-2019, 2019
Short summary
Short summary
This work provides the first direct field evidence that anthropogenic organo-nitrate contributed up to half of secondary organic aerosol (SOA) mass that was freshly produced within the emission plumes of oil sands facilities in Alberta, Canada. The findings illustrate the central role of organo-nitrate in SOA production from the oil and gas industry, with relevance for other urban and industrial regions with significant intermediate-volatility organic compounds (IVOCs) and NOx emissions.
Kun Li, John Liggio, Patrick Lee, Chong Han, Qifan Liu, and Shao-Meng Li
Atmos. Chem. Phys., 19, 9715–9731, https://doi.org/10.5194/acp-19-9715-2019, https://doi.org/10.5194/acp-19-9715-2019, 2019
Short summary
Short summary
A new oxidation flow reactor was developed and applied to study the secondary organic aerosol (SOA) formation from precursors associated with oil-sands (OS) operations. The results reveal that the SOA yields from OS precursors are related to the volatilities of precursors and that open-pit mining is the main source of SOA formed from oil sands. In addition, cyclic alkanes are found to play an important role in SOA formation from oil-sands precursors.
Victoria E. Irish, Sarah J. Hanna, Yu Xi, Matthew Boyer, Elena Polishchuk, Mohamed Ahmed, Jessie Chen, Jonathan P. D. Abbatt, Michel Gosselin, Rachel Chang, Lisa A. Miller, and Allan K. Bertram
Atmos. Chem. Phys., 19, 7775–7787, https://doi.org/10.5194/acp-19-7775-2019, https://doi.org/10.5194/acp-19-7775-2019, 2019
Short summary
Short summary
The ocean is a source of atmospheric ice-nucleating particles (INPs). In this study we compared INPs measured in microlayer and bulk seawater in the Canadian Arctic in 2016 to those measured in 2014. A strong negative correlation between salinity and freezing temperatures was observed, possibly due to INPs associated with melting sea ice. In addition, although spatial patterns of INPs and salinities were similar in 2014 and 2016, the concentrations of INPs were on average higher in 2016.
Samantha Tremblay, Jean-Christophe Picard, Jill O. Bachelder, Erik Lutsch, Kimberly Strong, Pierre Fogal, W. Richard Leaitch, Sangeeta Sharma, Felicia Kolonjari, Christopher J. Cox, Rachel Y.-W. Chang, and Patrick L. Hayes
Atmos. Chem. Phys., 19, 5589–5604, https://doi.org/10.5194/acp-19-5589-2019, https://doi.org/10.5194/acp-19-5589-2019, 2019
Short summary
Short summary
Atmospheric aerosols, tiny airborne particles, have an important impact on climate. However, a lack of understanding of the chemistry of aerosols is one of the largest contributors to uncertainty in predictions of climate change. Measurements of aerosols were carried out in the Arctic at Eureka Station, Canada, to better understand what role aerosols play in this fragile environment. It is found that organic aerosols, possibly originating from marine emissions, are ubiquitous during summertime.
Meng Si, Erin Evoy, Jingwei Yun, Yu Xi, Sarah J. Hanna, Alina Chivulescu, Kevin Rawlings, Daniel Veber, Andrew Platt, Daniel Kunkel, Peter Hoor, Sangeeta Sharma, W. Richard Leaitch, and Allan K. Bertram
Atmos. Chem. Phys., 19, 3007–3024, https://doi.org/10.5194/acp-19-3007-2019, https://doi.org/10.5194/acp-19-3007-2019, 2019
Short summary
Short summary
We investigated the importance of mineral dust, sea spray aerosol, and anthropogenic aerosol to the ice-nucleating particle (INP) population in the Canadian Arctic during spring 2016. The results suggest that mineral dust transported from the Gobi Desert was a major source of the INP population studied, and that sea spray aerosol decreased the ice-nucleating ability of mineral dust. The results should be useful for testing and improving models used to predict INPs and climate in the Arctic.
Betty Croft, Randall V. Martin, W. Richard Leaitch, Julia Burkart, Rachel Y.-W. Chang, Douglas B. Collins, Patrick L. Hayes, Anna L. Hodshire, Lin Huang, John K. Kodros, Alexander Moravek, Emma L. Mungall, Jennifer G. Murphy, Sangeeta Sharma, Samantha Tremblay, Gregory R. Wentworth, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 19, 2787–2812, https://doi.org/10.5194/acp-19-2787-2019, https://doi.org/10.5194/acp-19-2787-2019, 2019
Short summary
Short summary
Summertime Arctic atmospheric aerosols are strongly controlled by processes related to natural regional sources. We use a chemical transport model with size-resolved aerosol microphysics to interpret measurements made during summertime 2016 in the Canadian Arctic Archipelago. Our results explore the processes that control summertime aerosol size distributions and support a climate-relevant role for Arctic marine secondary organic aerosol formed from precursor vapors with Arctic marine sources.
Jonathan P. D. Abbatt, W. Richard Leaitch, Amir A. Aliabadi, Allan K. Bertram, Jean-Pierre Blanchet, Aude Boivin-Rioux, Heiko Bozem, Julia Burkart, Rachel Y. W. Chang, Joannie Charette, Jai P. Chaubey, Robert J. Christensen, Ana Cirisan, Douglas B. Collins, Betty Croft, Joelle Dionne, Greg J. Evans, Christopher G. Fletcher, Martí Galí, Roya Ghahreman, Eric Girard, Wanmin Gong, Michel Gosselin, Margaux Gourdal, Sarah J. Hanna, Hakase Hayashida, Andreas B. Herber, Sareh Hesaraki, Peter Hoor, Lin Huang, Rachel Hussherr, Victoria E. Irish, Setigui A. Keita, John K. Kodros, Franziska Köllner, Felicia Kolonjari, Daniel Kunkel, Luis A. Ladino, Kathy Law, Maurice Levasseur, Quentin Libois, John Liggio, Martine Lizotte, Katrina M. Macdonald, Rashed Mahmood, Randall V. Martin, Ryan H. Mason, Lisa A. Miller, Alexander Moravek, Eric Mortenson, Emma L. Mungall, Jennifer G. Murphy, Maryam Namazi, Ann-Lise Norman, Norman T. O'Neill, Jeffrey R. Pierce, Lynn M. Russell, Johannes Schneider, Hannes Schulz, Sangeeta Sharma, Meng Si, Ralf M. Staebler, Nadja S. Steiner, Jennie L. Thomas, Knut von Salzen, Jeremy J. B. Wentzell, Megan D. Willis, Gregory R. Wentworth, Jun-Wei Xu, and Jacqueline D. Yakobi-Hancock
Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, https://doi.org/10.5194/acp-19-2527-2019, 2019
Short summary
Short summary
The Arctic is experiencing considerable environmental change with climate warming, illustrated by the dramatic decrease in sea-ice extent. It is important to understand both the natural and perturbed Arctic systems to gain a better understanding of how they will change in the future. This paper summarizes new insights into the relationships between Arctic aerosol particles and climate, as learned over the past five or so years by a large Canadian research consortium, NETCARE.
Hannes Schulz, Marco Zanatta, Heiko Bozem, W. Richard Leaitch, Andreas B. Herber, Julia Burkart, Megan D. Willis, Daniel Kunkel, Peter M. Hoor, Jonathan P. D. Abbatt, and Rüdiger Gerdes
Atmos. Chem. Phys., 19, 2361–2384, https://doi.org/10.5194/acp-19-2361-2019, https://doi.org/10.5194/acp-19-2361-2019, 2019
Short summary
Short summary
Aircraft vertical profiles of black carbon (BC) aerosol from the High Canadian Arctic have shown systematic variability in different levels of the cold, stably stratified polar dome. During spring and summer, efficiencies of BC supply by transport (often from gas flaring and wildfire-affected regions) were different in the lower dome than at higher levels, as apparent from changes in mean particle size and mixing ratios with CO. Summer BC concentrations were a factor of 10 lower than in spring.
Xiaoxiao Li, Sabrina Chee, Jiming Hao, Jonathan P. D. Abbatt, Jingkun Jiang, and James N. Smith
Atmos. Chem. Phys., 19, 1555–1570, https://doi.org/10.5194/acp-19-1555-2019, https://doi.org/10.5194/acp-19-1555-2019, 2019
Short summary
Short summary
We performed lab experiments to explore the role of relative humidity, RH, in atmospheric monoterpene oxidation and new particle formation. These studies will provide insights into the most important steps in the process, while also more accurately representing the real atmosphere. We found that the detected compounds did not change with RH, and in fact could mostly be fully explained by the autoxidation of organic peroxy radicals followed by bimolecular reactions with other peroxy radicals.
Victoria E. Irish, Sarah J. Hanna, Megan D. Willis, Swarup China, Jennie L. Thomas, Jeremy J. B. Wentzell, Ana Cirisan, Meng Si, W. Richard Leaitch, Jennifer G. Murphy, Jonathan P. D. Abbatt, Alexander Laskin, Eric Girard, and Allan K. Bertram
Atmos. Chem. Phys., 19, 1027–1039, https://doi.org/10.5194/acp-19-1027-2019, https://doi.org/10.5194/acp-19-1027-2019, 2019
Short summary
Short summary
Ice nucleating particles (INPs) are atmospheric particles that catalyse the formation of ice crystals in clouds. INPs influence the Earth's radiative balance and hydrological cycle. In this study we measured the concentrations of INPs in the Canadian Arctic marine boundary layer. Average INP concentrations fell within the range measured in other marine boundary layer locations. We also found that mineral dust is a more important contributor to the INP population than sea spray aerosol.
Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 57–76, https://doi.org/10.5194/acp-19-57-2019, https://doi.org/10.5194/acp-19-57-2019, 2019
Short summary
Short summary
The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.
Travis W. Tokarek, Charles A. Odame-Ankrah, Jennifer A. Huo, Robert McLaren, Alex K. Y. Lee, Max G. Adam, Megan D. Willis, Jonathan P. D. Abbatt, Cristian Mihele, Andrea Darlington, Richard L. Mittermeier, Kevin Strawbridge, Katherine L. Hayden, Jason S. Olfert, Elijah G. Schnitzler, Duncan K. Brownsey, Faisal V. Assad, Gregory R. Wentworth, Alex G. Tevlin, Douglas E. J. Worthy, Shao-Meng Li, John Liggio, Jeffrey R. Brook, and Hans D. Osthoff
Atmos. Chem. Phys., 18, 17819–17841, https://doi.org/10.5194/acp-18-17819-2018, https://doi.org/10.5194/acp-18-17819-2018, 2018
Short summary
Short summary
Measurements of air pollutants at a ground site near Fort McKay in the Athabasca oil sands region in the summer of 2013 are presented. A large number of intermediate-volatility organic compounds (IVOCs) were observed; these molecules were shown previously to generate atmospheric particles downwind of the region. A principal component analysis was performed to identify major pollution source types, including which source(s) is(are) associated with IVOC emissions (e.g., freshly mined bitumen).
Sumi N. Wren, John Liggio, Yuemei Han, Katherine Hayden, Gang Lu, Cris M. Mihele, Richard L. Mittermeier, Craig Stroud, Jeremy J. B. Wentzell, and Jeffrey R. Brook
Atmos. Chem. Phys., 18, 16979–17001, https://doi.org/10.5194/acp-18-16979-2018, https://doi.org/10.5194/acp-18-16979-2018, 2018
Short summary
Short summary
We made measurements from a mobile laboratory across a large urban area and determined fleet-average vehicle emission factors (EFs) for a suite of traffic-related air pollutants. We present the first real-world EFs for isocyanic acid (HNCO) and hydrogen cyanide (HCN) and insight into their on-road variability. We find that vehicles may represent an important source of these air toxics at an urban scale. This work has implications for understanding population exposure to these species.
Meng Si, Victoria E. Irish, Ryan H. Mason, Jesús Vergara-Temprado, Sarah J. Hanna, Luis A. Ladino, Jacqueline D. Yakobi-Hancock, Corinne L. Schiller, Jeremy J. B. Wentzell, Jonathan P. D. Abbatt, Ken S. Carslaw, Benjamin J. Murray, and Allan K. Bertram
Atmos. Chem. Phys., 18, 15669–15685, https://doi.org/10.5194/acp-18-15669-2018, https://doi.org/10.5194/acp-18-15669-2018, 2018
Short summary
Short summary
Using the concentrations of ice-nucleating particles (INPs) and total aerosol particles measured at three coastal marine sites, the ice-nucleating ability of aerosol particles on a per number basis and a per surface-area basis were determined as a function of size. The ice-nucleating ability was strongly dependent on size, with larger particles being more efficient. This type of information can help determine the sources of INPs and constrain the future modelling of INPs and mixed-phase clouds.
Mark Gordon, Paul A. Makar, Ralf M. Staebler, Junhua Zhang, Ayodeji Akingunola, Wanmin Gong, and Shao-Meng Li
Atmos. Chem. Phys., 18, 14695–14714, https://doi.org/10.5194/acp-18-14695-2018, https://doi.org/10.5194/acp-18-14695-2018, 2018
Short summary
Short summary
This work uses aircraft-based measurements of smokestack plumes carried out in northern Alberta in 2013. These measurements are used to test equations used to predict how high in the air smokestack plumes rise. It is important to predict plume rise height accurately as it tells us how far downwind pollutants are carried and what air quality can be expected at the surface. We found that the equations that are typically used significantly underestimate the plume rise at this location.
Tuomo Nieminen, Veli-Matti Kerminen, Tuukka Petäjä, Pasi P. Aalto, Mikhail Arshinov, Eija Asmi, Urs Baltensperger, David C. S. Beddows, Johan Paul Beukes, Don Collins, Aijun Ding, Roy M. Harrison, Bas Henzing, Rakesh Hooda, Min Hu, Urmas Hõrrak, Niku Kivekäs, Kaupo Komsaare, Radovan Krejci, Adam Kristensson, Lauri Laakso, Ari Laaksonen, W. Richard Leaitch, Heikki Lihavainen, Nikolaos Mihalopoulos, Zoltán Németh, Wei Nie, Colin O'Dowd, Imre Salma, Karine Sellegri, Birgitta Svenningsson, Erik Swietlicki, Peter Tunved, Vidmantas Ulevicius, Ville Vakkari, Marko Vana, Alfred Wiedensohler, Zhijun Wu, Annele Virtanen, and Markku Kulmala
Atmos. Chem. Phys., 18, 14737–14756, https://doi.org/10.5194/acp-18-14737-2018, https://doi.org/10.5194/acp-18-14737-2018, 2018
Short summary
Short summary
Atmospheric aerosols have diverse effects on air quality, human health, and global climate. One important source of aerosols is their formation via nucleation and growth in the atmosphere. We have analyzed long-term observations of regional new particle formation events around the globe and provide a comprehensive view on the characteristics of this phenomenon in diverse environments. The results are useful in developing more realistic representation of atmospheric aerosols in global models.
Elijah G. Schnitzler and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 18, 14539–14553, https://doi.org/10.5194/acp-18-14539-2018, https://doi.org/10.5194/acp-18-14539-2018, 2018
Short summary
Short summary
Brown carbon (BrC) has significant but poorly constrained effects on climate. In this work, we investigate the effects of the OH radical on optical properties of secondary BrC in a series of smog chamber experiments. At high relative humidity (RH), we find that the evolution of the particles is complex, exhibiting rapid absorption enhancement followed by slow bleaching. At low RH, bleaching does not occur. These results further our understanding of the highly variable evolution of ambient BrC.
Craig A. Stroud, Paul A. Makar, Junhua Zhang, Michael D. Moran, Ayodeji Akingunola, Shao-Meng Li, Amy Leithead, Katherine Hayden, and May Siu
Atmos. Chem. Phys., 18, 13531–13545, https://doi.org/10.5194/acp-18-13531-2018, https://doi.org/10.5194/acp-18-13531-2018, 2018
Short summary
Short summary
It is shown that using measurement-derived volatile organic compound (VOC) and organic aerosol (OA) emissions in the GEM-MACH air quality model provides better overall predictions compared to using bottom-up emission inventories. This work was done to better constrain the fugitive organic emissions from the Athabasca oil sands region, which are a challenge to estimate with bottom-up emission approaches. We use observations from the 2013 Joint Oil Sands Monitoring study.
John K. Kodros, Sarah J. Hanna, Allan K. Bertram, W. Richard Leaitch, Hannes Schulz, Andreas B. Herber, Marco Zanatta, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 11345–11361, https://doi.org/10.5194/acp-18-11345-2018, https://doi.org/10.5194/acp-18-11345-2018, 2018
Short summary
Short summary
The mixing state of black carbon is one of the key uncertainties limiting the ability of models to estimate the direct radiative effect. In this work, we present aircraft measurements from the Canadian Arctic of coating thickness as a function of black carbon core diameter and black-carbon-containing particle number fractions. We use these measurements to inform estimates of the direct radiative effect in Arctic aerosol simulations.
Junhua Zhang, Michael D. Moran, Qiong Zheng, Paul A. Makar, Pegah Baratzadeh, George Marson, Peter Liu, and Shao-Meng Li
Atmos. Chem. Phys., 18, 10459–10481, https://doi.org/10.5194/acp-18-10459-2018, https://doi.org/10.5194/acp-18-10459-2018, 2018
Short summary
Short summary
This paper discusses the development of new synthesized emissions inventories and the generation of air quality model-ready emissions files for the Athabasca Oil Sands Region of Alberta, Canada, using multiple emissions inventories, continuous emissions monitoring data, and inferred emission rates based on aircraft measurements. Novel facility-specific gridded spatial surrogate fields were generated to allocate emissions spatially within each huge mining facility.
Emma L. Mungall, Jonathan P. D. Abbatt, Jeremy J. B. Wentzell, Gregory R. Wentworth, Jennifer G. Murphy, Daniel Kunkel, Ellen Gute, David W. Tarasick, Sangeeta Sharma, Christopher J. Cox, Taneil Uttal, and John Liggio
Atmos. Chem. Phys., 18, 10237–10254, https://doi.org/10.5194/acp-18-10237-2018, https://doi.org/10.5194/acp-18-10237-2018, 2018
Short summary
Short summary
We measured gas-phase formic and acetic acid at Alert, Nunavut. These acids play an important role in cloud water acidity in remote environments, yet they are not well represented in chemical transport models, particularly in the Arctic. We observed high levels of formic and acetic acid under both cold, wet, and cloudy and warm, sunny, and dry conditions, suggesting that multiple sources significantly contribute to gas-phase concentrations of these species in the summer Arctic.
Paul A. Makar, Ayodeji Akingunola, Julian Aherne, Amanda S. Cole, Yayne-abeba Aklilu, Junhua Zhang, Isaac Wong, Katherine Hayden, Shao-Meng Li, Jane Kirk, Ken Scott, Michael D. Moran, Alain Robichaud, Hazel Cathcart, Pegah Baratzedah, Balbir Pabla, Philip Cheung, Qiong Zheng, and Dean S. Jeffries
Atmos. Chem. Phys., 18, 9897–9927, https://doi.org/10.5194/acp-18-9897-2018, https://doi.org/10.5194/acp-18-9897-2018, 2018
Short summary
Short summary
Complex computer model output was compared to and fused with observation data, to estimate potential damage due to acidifying precipitation for ecosystems in the Canadian provinces of Alberta and Saskatchewan. Estimated deposition was compared to the maximum no-damage ecosystem capacity for sulfur and/or nitrogen uptake; these critical loads were exceeded, for areas between 10 000 and 330 000 square kilometres, depending on ecosystem type: ecosystem damage will occur at 2013 emission levels.
Monika Aggarwal, James Whiteway, Jeffrey Seabrook, Lawrence Gray, Kevin Strawbridge, Peter Liu, Jason O'Brien, Shao-Meng Li, and Robert McLaren
Atmos. Meas. Tech., 11, 3829–3849, https://doi.org/10.5194/amt-11-3829-2018, https://doi.org/10.5194/amt-11-3829-2018, 2018
Short summary
Short summary
Aircraft-based laser remote sensing measurements of atmospheric aerosol and ozone were conducted to study air pollution from the oil sands extraction industry in northern Alberta. The ozone mixing ratio measured in the polluted boundary layer air was equal to or less than the background ozone mixing ratio. The lidar measurements detected a layer of forest fire smoke above the surface boundary layer in which the measured ozone mixing ratio was substantially greater than the background amount.
Ayodeji Akingunola, Paul A. Makar, Junhua Zhang, Andrea Darlington, Shao-Meng Li, Mark Gordon, Michael D. Moran, and Qiong Zheng
Atmos. Chem. Phys., 18, 8667–8688, https://doi.org/10.5194/acp-18-8667-2018, https://doi.org/10.5194/acp-18-8667-2018, 2018
Short summary
Short summary
We examine the manner in which air-quality models simulate lofting of buoyant plumes of emissions from stacks (plume rise) and the impact of the level of detail in algorithms simulating particles' variation in size (particle size distribution). The most commonly used plume rise algorithm underestimates the height of plumes compared to observations, while a revised algorithm has much better performance. A 12-bin size distribution reduced the forecast 2-bin size distribution bias error by 32 %.
Jun Liu, Jeramy Dedrick, Lynn M. Russell, Gunnar I. Senum, Janek Uin, Chongai Kuang, Stephen R. Springston, W. Richard Leaitch, Allison C. Aiken, and Dan Lubin
Atmos. Chem. Phys., 18, 8571–8587, https://doi.org/10.5194/acp-18-8571-2018, https://doi.org/10.5194/acp-18-8571-2018, 2018
Short summary
Short summary
Observations of the organic components of the natural aerosol are scarce in Antarctica, which limits our understanding of natural aerosols and their connection to cloud albedo. We took yearlong measurements of organic aerosols at McMurdo Station. The natural organic aerosol was 150 times higher in summer than in winter. We showed the natural sources of OM were characterized by amide, which may be from seabird populations. Acid was high in summer and likely formed by secondary reactions.
Shouming Zhou, Jean C. Rivera-Rios, Frank N. Keutsch, and Jonathan P. D. Abbatt
Atmos. Meas. Tech., 11, 3081–3089, https://doi.org/10.5194/amt-11-3081-2018, https://doi.org/10.5194/amt-11-3081-2018, 2018
Sabour Baray, Andrea Darlington, Mark Gordon, Katherine L. Hayden, Amy Leithead, Shao-Meng Li, Peter S. K. Liu, Richard L. Mittermeier, Samar G. Moussa, Jason O'Brien, Ralph Staebler, Mengistu Wolde, Doug Worthy, and Robert McLaren
Atmos. Chem. Phys., 18, 7361–7378, https://doi.org/10.5194/acp-18-7361-2018, https://doi.org/10.5194/acp-18-7361-2018, 2018
Short summary
Short summary
Methane emissions from major oil sands facilities in the Athabasca Oil Sands Region (AOSR) of Alberta were measured in the summer of 2013 using two related aircraft mass-balance approaches. Tailings ponds and fugitive emissions of methane from open pit mines were found to be the major sources of methane in the region. Total methane emissions in the AOSR were measured to be ~ 20 tonnes of CH4 per hour, which is 48 % higher than the Canadian Greenhouse Gas Reporting Program Emissions Inventory.
Jianhuai Ye, Jonathan P. D. Abbatt, and Arthur W. H. Chan
Atmos. Chem. Phys., 18, 5549–5565, https://doi.org/10.5194/acp-18-5549-2018, https://doi.org/10.5194/acp-18-5549-2018, 2018
Short summary
Short summary
Synergistic effects between SOA formation and SO2 oxidation through Criegee chemistry and reactive uptake by organic peroxides were observed. The relative importance of these two pathways (Criegee vs. peroxide) varies with relative humidity. The latter SO2 loss mechanism to organic peroxides in SOA has not previously been identified. Our results suggest a new pathway of atmospheric SO2 oxidation, which may contribute to the missing mechanisms of high-sulfate production in the polluted areas.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Andrew Platt, Mike Elsasser, Lin Huang, Richard Leaitch, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Cheol-Heon Jeong, Jonathan P. D. Abbatt, and Greg J. Evans
Atmos. Chem. Phys., 18, 3485–3503, https://doi.org/10.5194/acp-18-3485-2018, https://doi.org/10.5194/acp-18-3485-2018, 2018
Short summary
Short summary
The sources of key contaminants in Arctic snow may be an important factor in understanding the rapid climate changes observed in the Arctic. Fresh snow samples collected frequently through the winter season were analyzed for major constituents. Temporally refined source apportionment via positive matrix factorization in conjunction with FLEXPART suggested potential source characteristics and locations. The identity of these sources and their relative contribution to key analytes is discussed.
W. Richard Leaitch, Lynn M. Russell, Jun Liu, Felicia Kolonjari, Desiree Toom, Lin Huang, Sangeeta Sharma, Alina Chivulescu, Dan Veber, and Wendy Zhang
Atmos. Chem. Phys., 18, 3269–3287, https://doi.org/10.5194/acp-18-3269-2018, https://doi.org/10.5194/acp-18-3269-2018, 2018
Short summary
Short summary
Over 2 years of atmospheric aerosol organic functional group and microphysics measurements at the world's northernmost land observatory offer a unique high-latitude dataset. Lower organic mass (OM) concentrations and higher OM fractions accompany smaller particles during summer, with opposite results during winter to spring. Seasonally, the OM oxidation level is highest in winter, associated with primary marine alcohol groups. In summer, secondary processes dominate the marine influence on OM.
Yuan Cheng, Shao-Meng Li, Mark Gordon, and Peter Liu
Atmos. Chem. Phys., 18, 2653–2667, https://doi.org/10.5194/acp-18-2653-2018, https://doi.org/10.5194/acp-18-2653-2018, 2018
Short summary
Short summary
An aircraft campaign was conducted over the Athabasca oil sands (OS) region to characterize refractory black carbon (rBC) particles as they were emitted from the sources and as they were transported downwind; rBC size distributions were consistent at different downwind distances from the source area whereas coating thicknesses on the rBC cores increased considerably as the OS plumes were transported downwind. These results provide insights into the evolution of BC aerosol in the real atmosphere.
Sangeeta Sharma, W. Richard Leaitch, Lin Huang, Daniel Veber, Felicia Kolonjari, Wendy Zhang, Sarah J. Hanna, Allan K. Bertram, and John A. Ogren
Atmos. Chem. Phys., 17, 15225–15243, https://doi.org/10.5194/acp-17-15225-2017, https://doi.org/10.5194/acp-17-15225-2017, 2017
Short summary
Short summary
A new and unique data set on BC properties at the highest latitude observatory in the world, at Alert, Canada, evaluates three techniques for estimating black carbon (BC) and gives seasonal best estimates of the BC mass concentrations and BC mass absorption coefficients (MAC) for 2.5 years of data. As a short-lived climate forcer, better estimates of the properties of BC are necessary to ensure accurate modelling of aerosol climate forcing of the Arctic atmosphere for mitigation purposes.
Alex K. Y. Lee, Chia-Li Chen, Jun Liu, Derek J. Price, Raghu Betha, Lynn M. Russell, Xiaolu Zhang, and Christopher D. Cappa
Atmos. Chem. Phys., 17, 15055–15067, https://doi.org/10.5194/acp-17-15055-2017, https://doi.org/10.5194/acp-17-15055-2017, 2017
Short summary
Short summary
Understanding the mixing state of ambient black carbon (BC) and the chemical characteristics of its associated coatings is important to evaluate BC fate and environmental impacts. This study reports fresh secondary organic aerosol (SOA) formation near traffic emissions during daytime. Our observations suggest that BC was unlikely the major condensation sink of SOA, and a portion of SOA condensed on BC surface was chemically different from other SOA particles that were externally mixed with BC.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Thomas Klimach, Frank Helleis, Heiko Bozem, Daniel Kunkel, Peter Hoor, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 17, 13747–13766, https://doi.org/10.5194/acp-17-13747-2017, https://doi.org/10.5194/acp-17-13747-2017, 2017
Short summary
Short summary
We conducted aircraft-based single particle chemical composition measurements in the Canadian high Arctic during summer. Our results provide evidence for a marine-biogenic influence on secondary formation of particulate trimethylamine in the Arctic boundary layer. Understanding emission sources and further processes controlling aerosol number concentration and chemical composition in the pristine Arctic summer is crucial for modeling future climate in the area.
Douglas B. Collins, Julia Burkart, Rachel Y.-W. Chang, Martine Lizotte, Aude Boivin-Rioux, Marjolaine Blais, Emma L. Mungall, Matthew Boyer, Victoria E. Irish, Guillaume Massé, Daniel Kunkel, Jean-Éric Tremblay, Tim Papakyriakou, Allan K. Bertram, Heiko Bozem, Michel Gosselin, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 13119–13138, https://doi.org/10.5194/acp-17-13119-2017, https://doi.org/10.5194/acp-17-13119-2017, 2017
Short summary
Short summary
The sources of aerosol particles and their growth to sizes large enough to act as cloud droplet seeds is of major importance to climate since clouds exert substantial control over the atmospheric energy balance. Using ship-board measurements from two summers in the Canadian Arctic, aerosol formation events were related to co-sampled atmospheric and oceanic parameters, providing insight into factors that drive particle formation and motivating further study of ocean–atmosphere interactions.
Jun-Wei Xu, Randall V. Martin, Andrew Morrow, Sangeeta Sharma, Lin Huang, W. Richard Leaitch, Julia Burkart, Hannes Schulz, Marco Zanatta, Megan D. Willis, Daven K. Henze, Colin J. Lee, Andreas B. Herber, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 11971–11989, https://doi.org/10.5194/acp-17-11971-2017, https://doi.org/10.5194/acp-17-11971-2017, 2017
Short summary
Short summary
We interpret a series of recent airborne and ground-based measurements with the GEOS-Chem model and its adjoint to attribute the sources of Arctic BC. Anthropogenic emissions in eastern and southern Asia make the largest contribution to Arctic BC. Gas flaring emissions from oilfields in western Siberia and from the Tarim oilfield in western China could have striking impacts on Arctic BC loadings.
Victoria E. Irish, Pablo Elizondo, Jessie Chen, Cédric Chou, Joannie Charette, Martine Lizotte, Luis A. Ladino, Theodore W. Wilson, Michel Gosselin, Benjamin J. Murray, Elena Polishchuk, Jonathan P. D. Abbatt, Lisa A. Miller, and Allan K. Bertram
Atmos. Chem. Phys., 17, 10583–10595, https://doi.org/10.5194/acp-17-10583-2017, https://doi.org/10.5194/acp-17-10583-2017, 2017
Short summary
Short summary
The ocean is a possible source of atmospheric ice-nucleating particles (INPs). In this study we found that INPs were ubiquitous in the sea-surface microlayer and bulk seawater in the Canadian Arctic. A strong negative correlation was observed between salinity and freezing temperatures (after correcting for freezing point depression). Heat and filtration treatments of the samples showed that the INPs were likely biological material with sizes between 0.02 μm and 0.2 μm in diameter.
Roya Ghahreman, Ann-Lise Norman, Betty Croft, Randall V. Martin, Jeffrey R. Pierce, Julia Burkart, Ofelia Rempillo, Heiko Bozem, Daniel Kunkel, Jennie L. Thomas, Amir A. Aliabadi, Gregory R. Wentworth, Maurice Levasseur, Ralf M. Staebler, Sangeeta Sharma, and W. Richard Leaitch
Atmos. Chem. Phys., 17, 8757–8770, https://doi.org/10.5194/acp-17-8757-2017, https://doi.org/10.5194/acp-17-8757-2017, 2017
Short summary
Short summary
We present spring and summertime vertical profile measurements of Arctic dimethyl sulfide (DMS), together with model simulations to consider what these profiles indicate about DMS sources and lifetimes in the Arctic. Our results highlight the role of local open water as the source of DMS(g) during July 2014 and the influence of long-range transport of DMS(g) from further afield in the Arctic during April 2015.
John Liggio, Samar G. Moussa, Jeremy Wentzell, Andrea Darlington, Peter Liu, Amy Leithead, Katherine Hayden, Jason O'Brien, Richard L. Mittermeier, Ralf Staebler, Mengistu Wolde, and Shao-Meng Li
Atmos. Chem. Phys., 17, 8411–8427, https://doi.org/10.5194/acp-17-8411-2017, https://doi.org/10.5194/acp-17-8411-2017, 2017
Short summary
Short summary
The emission and formation of gaseous organic acids from the oil sands industry in Canada is explored through aircraft measurements directly over and downwind wind of industrial facilities. Results demonstrated that the formation of organic acids through atmospheric chemical reactions dominated over the direct emissions from mining activities but could not be explicitly modeled. The results highlight the need for improved understanding of photochemical mechanisms leading to these species.
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Sarah Hanna, Allan K. Bertram, Andrew Platt, Mike Elsasser, Lin Huang, David Tarasick, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 17, 5775–5788, https://doi.org/10.5194/acp-17-5775-2017, https://doi.org/10.5194/acp-17-5775-2017, 2017
Short summary
Short summary
Rapid climate changes within the Arctic have highlighted existing uncertainties in the transport of contaminants to Arctic snow. Fresh snow samples collected frequently through the winter season were analyzed for major constituents creating a unique record of Arctic snow. Comparison with simultaneous atmospheric measurements provides insight into the driving processes in the transfer of contaminants from air to snow. The relative importance of deposition mechanisms over the season is proposed.
Julia Burkart, Megan D. Willis, Heiko Bozem, Jennie L. Thomas, Kathy Law, Peter Hoor, Amir A. Aliabadi, Franziska Köllner, Johannes Schneider, Andreas Herber, Jonathan P. D. Abbatt, and W. Richard Leaitch
Atmos. Chem. Phys., 17, 5515–5535, https://doi.org/10.5194/acp-17-5515-2017, https://doi.org/10.5194/acp-17-5515-2017, 2017
Short summary
Short summary
Our aircraft study for the first time systematically investigates aerosol size distributions, including ultrafine particles (5–20 nm in diameter), in the Arctic summertime atmosphere. We find that ultrafine particles occur very frequently in the boundary layer and not aloft, suggesting a surface source of these particles. Understanding aerosol properties and sources is crucial to predict climate and especially important in the Arctic as this region responds extremely fast to climate change.
Andrew D. Teakles, Rita So, Bruce Ainslie, Robert Nissen, Corinne Schiller, Roxanne Vingarzan, Ian McKendry, Anne Marie Macdonald, Daniel A. Jaffe, Allan K. Bertram, Kevin B. Strawbridge, W. Richard Leaitch, Sarah Hanna, Desiree Toom, Jonathan Baik, and Lin Huang
Atmos. Chem. Phys., 17, 2593–2611, https://doi.org/10.5194/acp-17-2593-2017, https://doi.org/10.5194/acp-17-2593-2017, 2017
Short summary
Short summary
We present a case study of an intense wildfire smoke plume from Siberia that affected the air quality across the Pacific Northwest on 6–10 July 2012. The transport, entrainment, and chemical composition of the plume are examined to characterize the event. Ambient O3 and PM2.5 from surface monitoring is contrast to modelled baseline air quality estimates to show the overall contribution of the plume to exceedances in O3 and PM2.5 air quality standards and objectives that occurred.
Quentin Libois, Liviu Ivanescu, Jean-Pierre Blanchet, Hannes Schulz, Heiko Bozem, W. Richard Leaitch, Julia Burkart, Jonathan P. D. Abbatt, Andreas B. Herber, Amir A. Aliabadi, and Éric Girard
Atmos. Chem. Phys., 16, 15689–15707, https://doi.org/10.5194/acp-16-15689-2016, https://doi.org/10.5194/acp-16-15689-2016, 2016
Short summary
Short summary
The first airborne measurements performed with the FIRR are presented. Vertical profiles of upwelling spectral radiance in the far-infrared are measured in the Arctic atmosphere for the first time. They show the impact of the temperature inversion on the radiative budget of the atmosphere, especially in the far-infrared. The presence of ice clouds also significantly alters the far-infrared budget, highlighting the critical interplay between water vapour and clouds in this very dry region.
Yuemei Han, Craig A. Stroud, John Liggio, and Shao-Meng Li
Atmos. Chem. Phys., 16, 13929–13944, https://doi.org/10.5194/acp-16-13929-2016, https://doi.org/10.5194/acp-16-13929-2016, 2016
Short summary
Short summary
This study investigates the acidity effect on the yield and chemical composition of α-pinene secondary organic aerosol based on a series of laboratory experiments performed using a photochemical reaction chamber under high- and low-NOx conditions. We have found that the acidity effect largely depends on NOx level and the inorganic acidity has a significant role to play in determining various organic aerosol chemical properties such as mass yields, oxidation state, and organic nitrate content.
Ivan Kourtchev, Ricardo H. M. Godoi, Sarah Connors, James G. Levine, Alex T. Archibald, Ana F. L. Godoi, Sarah L. Paralovo, Cybelli G. G. Barbosa, Rodrigo A. F. Souza, Antonio O. Manzi, Roger Seco, Steve Sjostedt, Jeong-Hoo Park, Alex Guenther, Saewung Kim, James Smith, Scot T. Martin, and Markus Kalberer
Atmos. Chem. Phys., 16, 11899–11913, https://doi.org/10.5194/acp-16-11899-2016, https://doi.org/10.5194/acp-16-11899-2016, 2016
Weiwei Hu, Brett B. Palm, Douglas A. Day, Pedro Campuzano-Jost, Jordan E. Krechmer, Zhe Peng, Suzane S. de Sá, Scot T. Martin, M. Lizabeth Alexander, Karsten Baumann, Lina Hacker, Astrid Kiendler-Scharr, Abigail R. Koss, Joost A. de Gouw, Allen H. Goldstein, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Francesco Canonaco, André S. H. Prévôt, William H. Brune, and Jose L. Jimenez
Atmos. Chem. Phys., 16, 11563–11580, https://doi.org/10.5194/acp-16-11563-2016, https://doi.org/10.5194/acp-16-11563-2016, 2016
Short summary
Short summary
IEPOX-SOA is biogenically derived secondary organic aerosol under anthropogenic influence, which has been shown to comprise a substantial fraction of OA globally. We investigated the lifetime of ambient IEPOX-SOA in the SE US and Amazonia, with an oxidation flow reactor and thermodenuder coupled with MS-based instrumentation. The low volatility and long lifetime of IEPOX-SOA against OH radicals' oxidation (> 2 weeks) was observed, which can help to constrain OA impact on air quality and climate.
W. Richard Leaitch, Alexei Korolev, Amir A. Aliabadi, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, Heiko Bozem, Peter Hoor, Franziska Köllner, Johannes Schneider, Andreas Herber, Christian Konrad, and Ralf Brauner
Atmos. Chem. Phys., 16, 11107–11124, https://doi.org/10.5194/acp-16-11107-2016, https://doi.org/10.5194/acp-16-11107-2016, 2016
Short summary
Short summary
Thought to be mostly unimportant for summertime Arctic liquid-water clouds, airborne observations show that atmospheric aerosol particles 50 nm in diameter or smaller and most likely from natural sources are often involved in cloud formation in the pristine Arctic summer. The result expands the reference for aerosol forcing of climate. Further, for extremely low droplet concentrations, no evidence is found for a connection between cloud liquid water and aerosol particle concentrations.
Carsten Warneke, Michael Trainer, Joost A. de Gouw, David D. Parrish, David W. Fahey, A. R. Ravishankara, Ann M. Middlebrook, Charles A. Brock, James M. Roberts, Steven S. Brown, Jonathan A. Neuman, Brian M. Lerner, Daniel Lack, Daniel Law, Gerhard Hübler, Iliana Pollack, Steven Sjostedt, Thomas B. Ryerson, Jessica B. Gilman, Jin Liao, John Holloway, Jeff Peischl, John B. Nowak, Kenneth C. Aikin, Kyung-Eun Min, Rebecca A. Washenfelder, Martin G. Graus, Mathew Richardson, Milos Z. Markovic, Nick L. Wagner, André Welti, Patrick R. Veres, Peter Edwards, Joshua P. Schwarz, Timothy Gordon, William P. Dube, Stuart A. McKeen, Jerome Brioude, Ravan Ahmadov, Aikaterini Bougiatioti, Jack J. Lin, Athanasios Nenes, Glenn M. Wolfe, Thomas F. Hanisco, Ben H. Lee, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Frank N. Keutsch, Jennifer Kaiser, Jingqiu Mao, and Courtney D. Hatch
Atmos. Meas. Tech., 9, 3063–3093, https://doi.org/10.5194/amt-9-3063-2016, https://doi.org/10.5194/amt-9-3063-2016, 2016
Short summary
Short summary
In this paper we describe the experimental approach, the science goals and early results of the NOAA SENEX campaign, which was focused on studying the interactions between biogenic and anthropogenic emissions to form secondary pollutants.
During SENEX, the NOAA WP-3D aircraft conducted 20 research flights between 27 May and 10 July 2013 based out of Smyrna, TN. The SENEX flights included day- and nighttime flights in the Southeast as well as flights over areas with intense shale gas extraction.
Vitali E. Fioletov, Chris A. McLinden, Alexander Cede, Jonathan Davies, Cristian Mihele, Stoyka Netcheva, Shao-Meng Li, and Jason O'Brien
Atmos. Meas. Tech., 9, 2961–2976, https://doi.org/10.5194/amt-9-2961-2016, https://doi.org/10.5194/amt-9-2961-2016, 2016
Sarvesh Garimella, Thomas Bjerring Kristensen, Karolina Ignatius, Andre Welti, Jens Voigtländer, Gourihar R. Kulkarni, Frank Sagan, Gregory Lee Kok, James Dorsey, Leonid Nichman, Daniel Alexander Rothenberg, Michael Rösch, Amélie Catharina Ruth Kirchgäßner, Russell Ladkin, Heike Wex, Theodore W. Wilson, Luis Antonio Ladino, Jon P. D. Abbatt, Olaf Stetzer, Ulrike Lohmann, Frank Stratmann, and Daniel James Cziczo
Atmos. Meas. Tech., 9, 2781–2795, https://doi.org/10.5194/amt-9-2781-2016, https://doi.org/10.5194/amt-9-2781-2016, 2016
Short summary
Short summary
The SPectrometer for Ice Nuclei (SPIN) is a commercially available ice nuclei counter manufactured by Droplet Measurement Technologies in Boulder, CO. This study characterizes the SPIN chamber, reporting data from laboratory measurements and quantifying uncertainties. Overall, we report that the SPIN is able to reproduce previous CFDC ice nucleation measurements.
Amir A. Aliabadi, Jennie L. Thomas, Andreas B. Herber, Ralf M. Staebler, W. Richard Leaitch, Hannes Schulz, Kathy S. Law, Louis Marelle, Julia Burkart, Megan D. Willis, Heiko Bozem, Peter M. Hoor, Franziska Köllner, Johannes Schneider, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 7899–7916, https://doi.org/10.5194/acp-16-7899-2016, https://doi.org/10.5194/acp-16-7899-2016, 2016
Short summary
Short summary
For the first time, ship emissions of an ice-breaker, the Amundsen, is characterized while breaking ice in the Canadian Arctic using the plume intercepts by the Polar 6 aircraft. The study is novel, estimating lower plume expansion rates over the stable Arctic marine boundary layer and different emissions factors for oxides of nitrogen, black carbon, and carbon monoxide, compared to plume intercept studies in mid latitudes. These results can inform policy making and emission inventory datasets.
Megan D. Willis, Julia Burkart, Jennie L. Thomas, Franziska Köllner, Johannes Schneider, Heiko Bozem, Peter M. Hoor, Amir A. Aliabadi, Hannes Schulz, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 7663–7679, https://doi.org/10.5194/acp-16-7663-2016, https://doi.org/10.5194/acp-16-7663-2016, 2016
Short summary
Short summary
We present a case study focused on an aerosol growth event observed in the Canadian High Arctic during summer. Using measurements of aerosol chemical and physical properties we find evidence for aerosol growth into cloud condensation nuclei-active sizes, through marine-influenced secondary organic aerosol formation. Understanding the mechanisms that control the formation and growth of aerosol is crucial for our ability to predict cloud properties, and therefore radiative balance and climate.
Emma L. Mungall, Betty Croft, Martine Lizotte, Jennie L. Thomas, Jennifer G. Murphy, Maurice Levasseur, Randall V. Martin, Jeremy J. B. Wentzell, John Liggio, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 6665–6680, https://doi.org/10.5194/acp-16-6665-2016, https://doi.org/10.5194/acp-16-6665-2016, 2016
Short summary
Short summary
Previous work has suggested that marine emissions of dimethyl sulfide (DMS) could impact the Arctic climate through interactions with clouds. We made the first high-time-resolution measurements of summertime atmospheric DMS in the Canadian Arctic, and performed source sensitivity simulations. We found that regional marine sources dominated, but do not appear to be sufficient to explain our observations. Understanding DMS sources in the Arctic is necessary to model future climate in the region.
Alex K. Y. Lee, Megan D. Willis, Robert M. Healy, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 5561–5572, https://doi.org/10.5194/acp-16-5561-2016, https://doi.org/10.5194/acp-16-5561-2016, 2016
Short summary
Short summary
Single-particle measurements from a soot-particle aerosol mass spectrometer were performed to examine the mixing state of aerosol particles in an air mass influenced by aged biomass burning. Our observations indicate non-uniform mixing of particles within a biomass burning plume in terms of molecular weight and potassium content, and illustrate that high molecular weight organic compounds can be a key contributor to low-volatility BrC observed in biomass burning organic aerosols.
Roya Ghahreman, Ann-Lise Norman, Jonathan P. D. Abbatt, Maurice Levasseur, and Jennie L. Thomas
Atmos. Chem. Phys., 16, 5191–5202, https://doi.org/10.5194/acp-16-5191-2016, https://doi.org/10.5194/acp-16-5191-2016, 2016
Short summary
Short summary
Aerosols in six size fractions (> 0.49–7.0 microns) were collected in the Arctic (July 2014). The isotopic composition of sulfate aerosols was measured to determine the role of biogenic and anthropogenic sources in the growth of aerosols. More than 63 % of the average sulfate concentration in the fine aerosols (> 0.49 microns) was from biogenic sources. For some samples, the S isotope ratio values for SO2 and fine aerosols were close together, suggesting the same source for SO2 and aerosol sulfur.
Megan D. Willis, Robert M. Healy, Nicole Riemer, Matthew West, Jon M. Wang, Cheol-Heon Jeong, John C. Wenger, Greg J. Evans, Jonathan P. D. Abbatt, and Alex K. Y. Lee
Atmos. Chem. Phys., 16, 4693–4706, https://doi.org/10.5194/acp-16-4693-2016, https://doi.org/10.5194/acp-16-4693-2016, 2016
Betty Croft, Randall V. Martin, W. Richard Leaitch, Peter Tunved, Thomas J. Breider, Stephen D. D'Andrea, and Jeffrey R. Pierce
Atmos. Chem. Phys., 16, 3665–3682, https://doi.org/10.5194/acp-16-3665-2016, https://doi.org/10.5194/acp-16-3665-2016, 2016
Short summary
Short summary
Measurements at high-Arctic sites show a strong annual cycle in atmospheric particle number and size. Previous studies identified poor scientific understanding related to global model representation of Arctic particle number and size, limiting ability to simulate this environment. Here we evaluate state-of-science ability to simulate Arctic particles using GEOS-Chem-TOMAS model, documenting key roles and interconnections of particle formation, cloud-related processes and remaining uncertainties.
S. Gagné, L. P. MacDonald, W. R. Leaitch, and J. R. Pierce
Atmos. Meas. Tech., 9, 619–630, https://doi.org/10.5194/amt-9-619-2016, https://doi.org/10.5194/amt-9-619-2016, 2016
Short summary
Short summary
Measurements of clouds with an aircraft are essential to understand how clouds form and how they affect the Earth's climate. These measurements are used in climate models to help predict how our climate might develop in the next century. Aircraft measurements are, however, difficult for modellers to interpret because the way they were acquired and analyzed varies from one team of scientists to the next. We present a software platform for scientists to share and compare their analysis tools.
Bin Yuan, John Liggio, Jeremy Wentzell, Shao-Meng Li, Harald Stark, James M. Roberts, Jessica Gilman, Brian Lerner, Carsten Warneke, Rui Li, Amy Leithead, Hans D. Osthoff, Robert Wild, Steven S. Brown, and Joost A. de Gouw
Atmos. Chem. Phys., 16, 2139–2153, https://doi.org/10.5194/acp-16-2139-2016, https://doi.org/10.5194/acp-16-2139-2016, 2016
Short summary
Short summary
We describe high-resolution measurements of nitrated phenols using a time-of-flight chemical ionization mass spectrometer (ToF-CIMS). Strong diurnal profiles were observed for nitrated phenols, with concentration maxima at night. Box model simulations were able to reproduce the measured nitrated phenols.
Gregory R. Wentworth, Jennifer G. Murphy, Betty Croft, Randall V. Martin, Jeffrey R. Pierce, Jean-Sébastien Côté, Isabelle Courchesne, Jean-Éric Tremblay, Jonathan Gagnon, Jennie L. Thomas, Sangeeta Sharma, Desiree Toom-Sauntry, Alina Chivulescu, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 1937–1953, https://doi.org/10.5194/acp-16-1937-2016, https://doi.org/10.5194/acp-16-1937-2016, 2016
Short summary
Short summary
Air near the surface in the summertime Arctic is extremely clean and typically has very low concentrations of both gases and particles. However, atmospheric measurements taken throughout the Canadian Arctic in the summer of 2014 revealed higher-than-expected amounts of gaseous ammonia. It is likely the majority of this ammonia is coming from migratory seabird colonies throughout the Arctic. Seabird guano (dung) releases ammonia which could impact climate and sensitive Arctic ecosystems.
R. H. Mason, M. Si, C. Chou, V. E. Irish, R. Dickie, P. Elizondo, R. Wong, M. Brintnell, M. Elsasser, W. M. Lassar, K. M. Pierce, W. R. Leaitch, A. M. MacDonald, A. Platt, D. Toom-Sauntry, R. Sarda-Estève, C. L. Schiller, K. J. Suski, T. C. J. Hill, J. P. D. Abbatt, J. A. Huffman, P. J. DeMott, and A. K. Bertram
Atmos. Chem. Phys., 16, 1637–1651, https://doi.org/10.5194/acp-16-1637-2016, https://doi.org/10.5194/acp-16-1637-2016, 2016
N. Borduas, B. Place, G. R. Wentworth, J. P. D. Abbatt, and J. G. Murphy
Atmos. Chem. Phys., 16, 703–714, https://doi.org/10.5194/acp-16-703-2016, https://doi.org/10.5194/acp-16-703-2016, 2016
Short summary
Short summary
HNCO is a toxic molecule and can cause cardiovascular and cataract problems through protein carbamylation once inhaled. Recently reported ambient measurements of HNCO in North America raise concerns for human exposure. To better understand HNCO's loss processes and behaviour in the atmosphere, we provide thermochemical data on HNCO. The parameters allow for more accurate predictions of its lifetime in the atmosphere and consequently help define exposure of this toxic molecule.
S. D. D'Andrea, J. Y. Ng, J. K. Kodros, S. A. Atwood, M. J. Wheeler, A. M. Macdonald, W. R. Leaitch, and J. R. Pierce
Atmos. Chem. Phys., 16, 383–396, https://doi.org/10.5194/acp-16-383-2016, https://doi.org/10.5194/acp-16-383-2016, 2016
Short summary
Short summary
We evaluate aerosol size distributions predicted by GEOS-Chem-TOMAS using measurements from the peak of Whistler Mountain. We improve model-measurement comparisons of aerosol number, size, and composition during periods of free-tropospheric and boundary-layer influence by developing simple filtering techniques, and determine the influence of Asian anthropogenic and biomass burning emissions. The low-cost filtering techniques and source apportionment methods can be used for other mountain sites.
F. Yu, G. Luo, S. C. Pryor, P. R. Pillai, S. H. Lee, J. Ortega, J. J. Schwab, A. G. Hallar, W. R. Leaitch, V. P. Aneja, J. N. Smith, J. T. Walker, O. Hogrefe, and K. L. Demerjian
Atmos. Chem. Phys., 15, 13993–14003, https://doi.org/10.5194/acp-15-13993-2015, https://doi.org/10.5194/acp-15-13993-2015, 2015
Short summary
Short summary
The role of low-volatility organics in new particle formation (NPF) in the atmosphere is assessed. An empirical formulation in which formation rate is a function of the concentrations of sulfuric acid and low-volatility organics significantly overpredicts NPF in the summer.
Two different schemes predict quite different nucleation rates (including their spatial patterns), concentrations of cloud condensation nuclei, and aerosol first indirect radiative forcing in North America.
M. W. Shephard, C. A. McLinden, K. E. Cady-Pereira, M. Luo, S. G. Moussa, A. Leithead, J. Liggio, R. M. Staebler, A. Akingunola, P. Makar, P. Lehr, J. Zhang, D. K. Henze, D. B. Millet, J. O. Bash, L. Zhu, K. C. Wells, S. L. Capps, S. Chaliyakunnel, M. Gordon, K. Hayden, J. R. Brook, M. Wolde, and S.-M. Li
Atmos. Meas. Tech., 8, 5189–5211, https://doi.org/10.5194/amt-8-5189-2015, https://doi.org/10.5194/amt-8-5189-2015, 2015
Short summary
Short summary
This study provides direct validations of Tropospheric Emission Spectrometer (TES) satellite retrieved profiles against coincident aircraft profiles of carbon monoxide, ammonia, methanol, and formic acid, all of which are of interest for air quality. The comparisons are performed over the Canadian oil sands region during an intensive field campaign in support of the Joint Canada-Alberta Implementation Plan for the Oil Sands Monitoring (JOSM). Initial model evaluations are also provided.
Y. Liu, J. Liggio, R. Staebler, and S.-M. Li
Atmos. Chem. Phys., 15, 13569–13584, https://doi.org/10.5194/acp-15-13569-2015, https://doi.org/10.5194/acp-15-13569-2015, 2015
Short summary
Short summary
This work for the first time demonstrated that organonitrogen compounds (NOC) can be formed efficiently via the uptake of ammonia by newly formed secondary organic aerosol using a smog chamber equipped with a HR-ToF-AMS. Based on the measured kinetics, this study suggests that light absorption by NOC in atmospheric particles may be important in regions where the BC contribution is minimal and NOC from ammonia should be considered with respect to overall deposition of nitrogen to ecosystems.
R. H. Mason, M. Si, J. Li, C. Chou, R. Dickie, D. Toom-Sauntry, C. Pöhlker, J. D. Yakobi-Hancock, L. A. Ladino, K. Jones, W. R. Leaitch, C. L. Schiller, J. P. D. Abbatt, J. A. Huffman, and A. K. Bertram
Atmos. Chem. Phys., 15, 12547–12566, https://doi.org/10.5194/acp-15-12547-2015, https://doi.org/10.5194/acp-15-12547-2015, 2015
M. Gordon, S.-M. Li, R. Staebler, A. Darlington, K. Hayden, J. O'Brien, and M. Wolde
Atmos. Meas. Tech., 8, 3745–3765, https://doi.org/10.5194/amt-8-3745-2015, https://doi.org/10.5194/amt-8-3745-2015, 2015
Short summary
Short summary
Aircraft-based measurements of air pollutants from sources in the Canadian oil sands were made during a summer intensive field campaign in 2013. This paper describes the top-down emission rate retrieval algorithm (TERRA) to determine facility emissions of pollutants, using SO2 and CH4 as examples. Uncertainty of the emission rates estimated with TERRA is estimated as less than 30%, which is primarily due to the unknown SO2 and CH4 mixing ratios near the surface below the lowest flight level.
K. M. Badali, S. Zhou, D. Aljawhary, M. Antiñolo, W. J. Chen, A. Lok, E. Mungall, J. P. S. Wong, R. Zhao, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 7831–7840, https://doi.org/10.5194/acp-15-7831-2015, https://doi.org/10.5194/acp-15-7831-2015, 2015
Short summary
Short summary
This is the first paper to demonstrate that SOA material forms OH radicals upon UV illumination. We quantify the OH formation rates in solution and show species other than H2O2, mostly probably ROOH molecules, are the likely source of the OH. The importance of an OH source from SOA is that photochemical processing within both cloudwater and aerosol particles may arise subsequent to the formation of these radicals.
N. D. Rider, Y. M. Taha, C. A. Odame-Ankrah, J. A. Huo, T. W. Tokarek, E. Cairns, S. G. Moussa, J. Liggio, and H. D. Osthoff
Atmos. Meas. Tech., 8, 2737–2748, https://doi.org/10.5194/amt-8-2737-2015, https://doi.org/10.5194/amt-8-2737-2015, 2015
Short summary
Short summary
A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone (acetone, diethyl-, di-isopropyl, or di-n-propyl ketone) in the presence of oxygen and nitric oxide is photodissociated by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The source output was analyzed by gas chromatography and thermal dissociation cavity ring-down spectroscopy and modeled using the Master Chemical Mechanism.
R. Zhao, A. K. Y. Lee, L. Huang, X. Li, F. Yang, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 6087–6100, https://doi.org/10.5194/acp-15-6087-2015, https://doi.org/10.5194/acp-15-6087-2015, 2015
Short summary
Short summary
Aqueous-phase photochemical decay of light absorbing organic compounds, or atmospheric brown carbon (BrC), is investigated in this study. The absorptive change of laboratory surrogates of BrC, as well as biofuel combustion samples, were monitored during photolysis and OH oxidation experiments. The major finding is the rapid change in the absorptivity of BrC during such photochemical processing. This change should be taken into account to evaluate the importance of BrC in the atmosphere.
F. Wania, Y. D. Lei, C. Wang, J. P. D. Abbatt, and K.-U. Goss
Atmos. Chem. Phys., 15, 3395–3412, https://doi.org/10.5194/acp-15-3395-2015, https://doi.org/10.5194/acp-15-3395-2015, 2015
Short summary
Short summary
The manuscript presents a new way to graphically illustrate some of the processes that occur when organic particles form in the atmosphere. In particular, this method makes it possible to see how factors such as the composition of the atmosphere and temperature affect these processes.
B. Yuan, P. R. Veres, C. Warneke, J. M. Roberts, J. B. Gilman, A. Koss, P. M. Edwards, M. Graus, W. C. Kuster, S.-M. Li, R. J. Wild, S. S. Brown, W. P. Dubé, B. M. Lerner, E. J. Williams, J. E. Johnson, P. K. Quinn, T. S. Bates, B. Lefer, P. L. Hayes, J. L. Jimenez, R. J. Weber, R. Zamora, B. Ervens, D. B. Millet, B. Rappenglück, and J. A. de Gouw
Atmos. Chem. Phys., 15, 1975–1993, https://doi.org/10.5194/acp-15-1975-2015, https://doi.org/10.5194/acp-15-1975-2015, 2015
Short summary
Short summary
In this work, secondary formation of formic acid at an urban site and a site in an oil and gas production region is studied. We investigated various gas phase formation pathways of formic acid, including those recently proposed, using a box model. The contributions from aerosol-related processes, fog events and air-snow exchange to formic acid are also quantified.
A. K. Y. Lee, M. D. Willis, R. M. Healy, T. B. Onasch, and J. P. D. Abbatt
Atmos. Chem. Phys., 15, 1823–1841, https://doi.org/10.5194/acp-15-1823-2015, https://doi.org/10.5194/acp-15-1823-2015, 2015
Short summary
Short summary
Understanding the impact of black carbon (BC) particles on human health and radiative forcing requires knowledge of the BC mixing state. This work investigates the mixing state of BC and other aerosol species in a typical urban area using a single particle mass spectrometry technique. Our results provide quantitative insight into the physical and chemical nature of BC-containing particles near emission and can be used as a basis for our developing understanding of BC evolution in the atmosphere.
J. C. Schroder, S. J. Hanna, R. L. Modini, A. L. Corrigan, S. M. Kreidenwies, A. M. Macdonald, K. J. Noone, L. M. Russell, W. R. Leaitch, and A. K. Bertram
Atmos. Chem. Phys., 15, 1367–1383, https://doi.org/10.5194/acp-15-1367-2015, https://doi.org/10.5194/acp-15-1367-2015, 2015
C. Warneke, P. Veres, S. M. Murphy, J. Soltis, R. A. Field, M. G. Graus, A. Koss, S.-M. Li, R. Li, B. Yuan, J. M. Roberts, and J. A. de Gouw
Atmos. Meas. Tech., 8, 411–420, https://doi.org/10.5194/amt-8-411-2015, https://doi.org/10.5194/amt-8-411-2015, 2015
I. Nuaaman, S.-M. Li, K. L. Hayden, T. B. Onasch, P. Massoli, D. Sueper, D. R. Worsnop, T. S. Bates, P. K. Quinn, and R. McLaren
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-2085-2015, https://doi.org/10.5194/acpd-15-2085-2015, 2015
Revised manuscript has not been submitted
Short summary
Short summary
In this paper, we focus on the measurement and reporting of mass concentrations of particulate chloride and sea salt in a marine area off the coast of California using a High Resolution Aerosol Mass Spectrometer. We outline a method of deconvolving the total aerosol chloride mass into refractory and non-refractory components, previously not reported in the literature. This can be important in regions where refractory sea salt aerosols can contribute to the aerosol chloride signal measured with t
M. D. Willis, A. K. Y. Lee, T. B. Onasch, E. C. Fortner, L. R. Williams, A. T. Lambe, D. R. Worsnop, and J. P. D. Abbatt
Atmos. Meas. Tech., 7, 4507–4516, https://doi.org/10.5194/amt-7-4507-2014, https://doi.org/10.5194/amt-7-4507-2014, 2014
F. Wania, Y. D. Lei, C. Wang, J. P. D. Abbatt, and K.-U. Goss
Atmos. Chem. Phys., 14, 13189–13204, https://doi.org/10.5194/acp-14-13189-2014, https://doi.org/10.5194/acp-14-13189-2014, 2014
Short summary
Short summary
A description of the formation of secondary organic aerosol requires the prediction of the partitioning equilibrium of organic compounds with multiple functional groups between gas and organic particle phase. While this is typically done by predicting both the saturation vapour pressure and the activity coefficient in the organic particle phase, we demonstrate here that it is feasible to predict the partitioning equilibrium directly. This direct approach has greater precision.
L. Huang, S. L. Gong, M. Gordon, J. Liggio, R. Staebler, C. A. Stroud, G. Lu, C. Mihele, J. R. Brook, and C. Q. Jia
Atmos. Chem. Phys., 14, 12631–12648, https://doi.org/10.5194/acp-14-12631-2014, https://doi.org/10.5194/acp-14-12631-2014, 2014
B. H. Samset, G. Myhre, A. Herber, Y. Kondo, S.-M. Li, N. Moteki, M. Koike, N. Oshima, J. P. Schwarz, Y. Balkanski, S. E. Bauer, N. Bellouin, T. K. Berntsen, H. Bian, M. Chin, T. Diehl, R. C. Easter, S. J. Ghan, T. Iversen, A. Kirkevåg, J.-F. Lamarque, G. Lin, X. Liu, J. E. Penner, M. Schulz, Ø. Seland, R. B. Skeie, P. Stier, T. Takemura, K. Tsigaridis, and K. Zhang
Atmos. Chem. Phys., 14, 12465–12477, https://doi.org/10.5194/acp-14-12465-2014, https://doi.org/10.5194/acp-14-12465-2014, 2014
Short summary
Short summary
Far from black carbon (BC) emission sources, present climate models are unable to reproduce flight measurements. By comparing recent models with data, we find that the atmospheric lifetime of BC may be overestimated in models. By adjusting modeled BC concentrations to measurements in remote regions - over oceans and at high altitudes - we arrive at a reduced estimate for BC radiative forcing over the industrial era.
J. D. Yakobi-Hancock, L. A. Ladino, A. K. Bertram, J. A. Huffman, K. Jones, W. R. Leaitch, R. H. Mason, C. L. Schiller, D. Toom-Sauntry, J. P. S. Wong, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 12307–12317, https://doi.org/10.5194/acp-14-12307-2014, https://doi.org/10.5194/acp-14-12307-2014, 2014
Short summary
Short summary
As one aspect of the NETwork on Climate and Aerosols: addressing key uncertainties in Remote Canadian Environments, measurements of the cloud condensation nucleation properties of 50 nm and 100 nm aerosol particles were conducted at Ucluelet on the west coast of Vancouver Island in August 2013. The most efficient cloud condensation nuclei arose when the organic to sulfate ratio of the aerosol was lowest and when winds arrived from the west after transport through the marine boundary layer.
Y. Liu, L. Huang, S.-M. Li, T. Harner, and J. Liggio
Atmos. Chem. Phys., 14, 12195–12207, https://doi.org/10.5194/acp-14-12195-2014, https://doi.org/10.5194/acp-14-12195-2014, 2014
R. Li, C. Warneke, M. Graus, R. Field, F. Geiger, P. R. Veres, J. Soltis, S.-M. Li, S. M. Murphy, C. Sweeney, G. Pétron, J. M. Roberts, and J. de Gouw
Atmos. Meas. Tech., 7, 3597–3610, https://doi.org/10.5194/amt-7-3597-2014, https://doi.org/10.5194/amt-7-3597-2014, 2014
R. Zhao, E. L. Mungall, A. K. Y. Lee, D. Aljawhary, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 9695–9706, https://doi.org/10.5194/acp-14-9695-2014, https://doi.org/10.5194/acp-14-9695-2014, 2014
Y. Liu, S.-M. Li, and J. Liggio
Atmos. Chem. Phys., 14, 9201–9211, https://doi.org/10.5194/acp-14-9201-2014, https://doi.org/10.5194/acp-14-9201-2014, 2014
M. Gordon, A. Vlasenko, R. M. Staebler, C. Stroud, P. A. Makar, J. Liggio, S.-M. Li, and S. Brown
Atmos. Chem. Phys., 14, 9087–9097, https://doi.org/10.5194/acp-14-9087-2014, https://doi.org/10.5194/acp-14-9087-2014, 2014
J. R. Pierce, D. M. Westervelt, S. A. Atwood, E. A. Barnes, and W. R. Leaitch
Atmos. Chem. Phys., 14, 8647–8663, https://doi.org/10.5194/acp-14-8647-2014, https://doi.org/10.5194/acp-14-8647-2014, 2014
M. L. McGuire, R. Y.-W. Chang, J. G. Slowik, C.-H. Jeong, R. M. Healy, G. Lu, C. Mihele, J. P. D. Abbatt, J. R. Brook, and G. J. Evans
Atmos. Chem. Phys., 14, 8017–8042, https://doi.org/10.5194/acp-14-8017-2014, https://doi.org/10.5194/acp-14-8017-2014, 2014
T. P. Riedel, G. M. Wolfe, K. T. Danas, J. B. Gilman, W. C. Kuster, D. M. Bon, A. Vlasenko, S.-M. Li, E. J. Williams, B. M. Lerner, P. R. Veres, J. M. Roberts, J. S. Holloway, B. Lefer, S. S. Brown, and J. A. Thornton
Atmos. Chem. Phys., 14, 3789–3800, https://doi.org/10.5194/acp-14-3789-2014, https://doi.org/10.5194/acp-14-3789-2014, 2014
Y. J. Li, D. D. Huang, H. Y. Cheung, A. K. Y. Lee, and C. K. Chan
Atmos. Chem. Phys., 14, 2871–2885, https://doi.org/10.5194/acp-14-2871-2014, https://doi.org/10.5194/acp-14-2871-2014, 2014
A. Steffen, J. Bottenheim, A. Cole, R. Ebinghaus, G. Lawson, and W. R. Leaitch
Atmos. Chem. Phys., 14, 2219–2231, https://doi.org/10.5194/acp-14-2219-2014, https://doi.org/10.5194/acp-14-2219-2014, 2014
G. M. Buffaloe, D. A. Lack, E. J. Williams, D. Coffman, K. L. Hayden, B. M. Lerner, S.-M. Li, I. Nuaaman, P. Massoli, T. B. Onasch, P. K. Quinn, and C. D. Cappa
Atmos. Chem. Phys., 14, 1881–1896, https://doi.org/10.5194/acp-14-1881-2014, https://doi.org/10.5194/acp-14-1881-2014, 2014
S. Zhou, L. Gonzalez, A. Leithead, Z. Finewax, R. Thalman, A. Vlasenko, S. Vagle, L.A. Miller, S.-M. Li, S. Bureekul, H. Furutani, M. Uematsu, R. Volkamer, and J. Abbatt
Atmos. Chem. Phys., 14, 1371–1384, https://doi.org/10.5194/acp-14-1371-2014, https://doi.org/10.5194/acp-14-1371-2014, 2014
C. D. Cappa, E. J. Williams, D. A. Lack, G. M. Buffaloe, D. Coffman, K. L. Hayden, S. C. Herndon, B. M. Lerner, S.-M. Li, P. Massoli, R. McLaren, I. Nuaaman, T. B. Onasch, and P. K. Quinn
Atmos. Chem. Phys., 14, 1337–1352, https://doi.org/10.5194/acp-14-1337-2014, https://doi.org/10.5194/acp-14-1337-2014, 2014
S. D. D'Andrea, S. A. K. Häkkinen, D. M. Westervelt, C. Kuang, E. J. T. Levin, V. P. Kanawade, W. R. Leaitch, D. V. Spracklen, I. Riipinen, and J. R. Pierce
Atmos. Chem. Phys., 13, 11519–11534, https://doi.org/10.5194/acp-13-11519-2013, https://doi.org/10.5194/acp-13-11519-2013, 2013
D. Aljawhary, A. K. Y. Lee, and J. P. D. Abbatt
Atmos. Meas. Tech., 6, 3211–3224, https://doi.org/10.5194/amt-6-3211-2013, https://doi.org/10.5194/amt-6-3211-2013, 2013
J. D. Yakobi-Hancock, L. A. Ladino, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 11175–11185, https://doi.org/10.5194/acp-13-11175-2013, https://doi.org/10.5194/acp-13-11175-2013, 2013
S. N. Wren, D. J. Donaldson, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 9789–9800, https://doi.org/10.5194/acp-13-9789-2013, https://doi.org/10.5194/acp-13-9789-2013, 2013
R. D. McWhinney, S. Zhou, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 9731–9744, https://doi.org/10.5194/acp-13-9731-2013, https://doi.org/10.5194/acp-13-9731-2013, 2013
A. Petzold, J. A. Ogren, M. Fiebig, P. Laj, S.-M. Li, U. Baltensperger, T. Holzer-Popp, S. Kinne, G. Pappalardo, N. Sugimoto, C. Wehrli, A. Wiedensohler, and X.-Y. Zhang
Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, https://doi.org/10.5194/acp-13-8365-2013, 2013
M. D. Gibson, J. R. Pierce, D. Waugh, J. S. Kuchta, L. Chisholm, T. J. Duck, J. T. Hopper, S. Beauchamp, G. H. King, J. E. Franklin, W. R. Leaitch, A. J. Wheeler, Z. Li, G. A. Gagnon, and P. I. Palmer
Atmos. Chem. Phys., 13, 7199–7213, https://doi.org/10.5194/acp-13-7199-2013, https://doi.org/10.5194/acp-13-7199-2013, 2013
R. Zhao, A. K. Y. Lee, R. Soong, A. J. Simpson, and J. P. D. Abbatt
Atmos. Chem. Phys., 13, 5857–5872, https://doi.org/10.5194/acp-13-5857-2013, https://doi.org/10.5194/acp-13-5857-2013, 2013
B. Ervens, Y. Wang, J. Eagar, W. R. Leaitch, A. M. Macdonald, K. T. Valsaraj, and P. Herckes
Atmos. Chem. Phys., 13, 5117–5135, https://doi.org/10.5194/acp-13-5117-2013, https://doi.org/10.5194/acp-13-5117-2013, 2013
L. Ahlm, K. M. Shakya, L. M. Russell, J. C. Schroder, J. P. S. Wong, S. J. Sjostedt, K. L. Hayden, J. Liggio, J. J. B. Wentzell, H. A. Wiebe, C. Mihele, W. R. Leaitch, and A. M. Macdonald
Atmos. Chem. Phys., 13, 3393–3407, https://doi.org/10.5194/acp-13-3393-2013, https://doi.org/10.5194/acp-13-3393-2013, 2013
J. Liggio and S.-M. Li
Atmos. Chem. Phys., 13, 2989–3002, https://doi.org/10.5194/acp-13-2989-2013, https://doi.org/10.5194/acp-13-2989-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Opinion: How will advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution?
Measurement report: Intra-annual variability of black carbon and brown carbon and their interrelation with meteorological conditions over Gangtok, Sikkim
Long-range transport of air pollutants increases the concentration of hazardous components of PM2.5 in northern South America
Dominant influence of biomass combustion and cross-border transport on nitrogen-containing organic compound levels in the southeastern Tibetan Plateau
Impacts of elevated anthropogenic emissions on physicochemical characteristics of black-carbon-containing particles over the Tibetan Plateau
Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses
Atmospheric evolution of environmentally persistent free radicals in the rural North China Plain: effects on water solubility and PM2.5 oxidative potential
Two distinct ship emission profiles for organic-sulfate source apportionment of PM in sulfur emission control areas
Automated compound speciation, cluster analysis, and quantification of organic vapors and aerosols using comprehensive two-dimensional gas chromatography and mass spectrometry
Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints
Bridging gas and aerosol properties between the northeastern US and Bermuda: analysis of eight transit flights
The behaviour of charged particles (ions) during new particle formation events in urban Leipzig, Germany
Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China
Measurement report: Characteristics of airborne black-carbon-containing particles during the 2021 summer COVID-19 lockdown in a typical Yangtze River Delta city, China
Aerosol optical properties within the atmospheric boundary layer predicted from ground-based observations compared to Raman lidar retrievals during RITA-2021
Hygroscopic growth and activation changed submicron aerosol composition and properties in the North China Plain
Measurement report: Formation of tropospheric brown carbon in a lifting air mass
Vertical variability of aerosol properties and trace gases over a remote marine region: a case study over Bermuda
Differences in aerosol and cloud properties along the central California coast when winds change from northerly to southerly
International airport emissions and their impact on local air quality: chemical speciation of ambient aerosols at Madrid–Barajas Airport during the AVIATOR campaign
Significant role of biomass burning in heavy haze formation in a megacity: Molecular-level insights from intensive PM2.5 sampling on winter hazy days
The local ship speed reduction effect on black carbon emissions measured at a remote marine station
High-altitude aerosol chemical characterization and source identification: insights from the CALISHTO campaign
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – a short-term case study in Beijing
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Impact of cloud processes on secondary organic aerosols at a forested mountain site in southeastern China
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Seasonal Investigation of Ultrafine Particle Composition in an Eastern Amazonian Rainforest
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic in Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Technical note: Quantified organic aerosol subsaturated hygroscopicity by a simple optical scatter monitor system through field measurements
Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean
The water-insoluble organic carbon in PM2.5 of typical Chinese urban areas: light-absorbing properties, potential sources, radiative forcing effects, and a possible light-absorbing continuum
Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
A Multi-site Passive Approach for Studying the Emissions and Evolution of Smoke from Prescribed Fires
Non-sea-salt aerosols that contain trace bromine and iodine are widespread in the remote troposphere
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
High-resolution analyses of concentrations and sizes of black carbon particles deposited on northwest Greenland over the past 350 years – Part 2: Seasonal and temporal trends in black carbon originated from fossil fuel combustion and biomass burning
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Formation and chemical evolution of SOA in two different environments: A dual chamber study
Enhanced daytime secondary aerosol formation driven by gas-particle partitioning in downwind urban plumes
Multiple eco-regions contribute to the seasonal cycle of Antarctic aerosol size distributions
Impact assessment of terrestrial and marine air-mass on the constituents and intermixing of bioaerosols over coastal atmosphere
Imad El Haddad, Danielle Vienneau, Kaspar R. Daellenbach, Robin Modini, Jay G. Slowik, Abhishek Upadhyay, Petros N. Vasilakos, David Bell, Kees de Hoogh, and Andre S. H. Prevot
Atmos. Chem. Phys., 24, 11981–12011, https://doi.org/10.5194/acp-24-11981-2024, https://doi.org/10.5194/acp-24-11981-2024, 2024
Short summary
Short summary
This opinion paper explores how advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution. We advocate for a shift in the way we target PM pollution, focusing on the most harmful anthropogenic emissions. We highlight key observations, modelling developments, and emission measurements needed to achieve this shift.
Pramod Kumar, Khushboo Sharma, Ankita Malu, Rajeev Rajak, Aparna Gupta, Bidyutjyoti Baruah, Shailesh Yadav, Thupstan Angchuk, Jayant Sharma, Rakesh Kumar Ranjan, Anil Kumar Misra, and Nishchal Wanjari
Atmos. Chem. Phys., 24, 11585–11601, https://doi.org/10.5194/acp-24-11585-2024, https://doi.org/10.5194/acp-24-11585-2024, 2024
Short summary
Short summary
This work monitors and assesses air pollution, especially black and brown carbon, its controlling factor, and its effect on the environment of Sikkim Himalayan region. The huge urban sprawl in recent decades has led to regional human-induced air pollution in the region. Black carbon was highest in April 2021 and March 2022, exceeding the WHO limit. The monsoon season causes huge rainfall over the region, which reduces the pollutants by scavenging (rainout and washout).
Maria P. Velásquez-García, K. Santiago Hernández, James A. Vergara-Correa, Richard J. Pope, Miriam Gómez-Marín, and Angela M. Rendón
Atmos. Chem. Phys., 24, 11497–11520, https://doi.org/10.5194/acp-24-11497-2024, https://doi.org/10.5194/acp-24-11497-2024, 2024
Short summary
Short summary
In the Aburrá Valley, northern South America, local emissions determine air quality conditions. However, we found that external sources, such as regional fires, Saharan dust, and volcanic emissions, increase particulate concentrations and worsen chemical composition by introducing elements like heavy metals. Dry winds and source variability contribute to seasonal influences on these events. This study assesses the air quality risks posed by such events, which can affect broad regions worldwide.
Meng Wang, Qiyuan Wang, Steven Sai Hang Ho, Jie Tian, Yong Zhang, Shun-cheng Lee, and Junji Cao
Atmos. Chem. Phys., 24, 11175–11189, https://doi.org/10.5194/acp-24-11175-2024, https://doi.org/10.5194/acp-24-11175-2024, 2024
Short summary
Short summary
We studied nitrogen-containing organic compounds (NOCs) in particulate matter <2.5 µm particles on the southeastern Tibetan Plateau. We found that biomass burning and transboundary transport are the main sources of NOCs in the high-altitude area. Understanding these aerosol sources informs how they add to regional and potentially global climate changes. Our findings could help shape effective environmental policies to enhance air quality and address climate impacts in this sensitive region.
Jinbo Wang, Jiaping Wang, Yuxuan Zhang, Tengyu Liu, Xuguang Chi, Xin Huang, Dafeng Ge, Shiyi Lai, Caijun Zhu, Lei Wang, Qiaozhi Zha, Ximeng Qi, Wei Nie, Congbin Fu, and Aijun Ding
Atmos. Chem. Phys., 24, 11063–11080, https://doi.org/10.5194/acp-24-11063-2024, https://doi.org/10.5194/acp-24-11063-2024, 2024
Short summary
Short summary
In this study, we found large spatial discrepancies in the physical and chemical properties of black carbon over the Tibetan Plateau (TP). Elevated anthropogenic emissions from low-altitude regions can significantly change the mass concentration, mixing state and chemical composition of black-carbon-containing aerosol in the TP region, further altering its light absorption ability. Our study emphasizes the vulnerability of remote plateau regions to intense anthropogenic influences.
Liyuan Zhou, Qianyun Liu, Christian M. Salvador, Michael Le Breton, Mattias Hallquist, Jian Zhen Yu, Chak K. Chan, and Åsa M. Hallquist
Atmos. Chem. Phys., 24, 11045–11061, https://doi.org/10.5194/acp-24-11045-2024, https://doi.org/10.5194/acp-24-11045-2024, 2024
Short summary
Short summary
Our research on city bus emissions reveals that alternative fuels (compressed natural gas and biofuels) reduce fresh particle emissions compared to diesel. However, all fuels lead to secondary air pollution. Aiming at guiding better environmental policies, we studied 76 buses using advanced emission measurement techniques. This work sheds light on the complex effects of bus fuels on urban air quality, emphasizing the need for comprehensive evaluations of future transportation technologies.
Xu Yang, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi He, and Haijie Tong
Atmos. Chem. Phys., 24, 11029–11043, https://doi.org/10.5194/acp-24-11029-2024, https://doi.org/10.5194/acp-24-11029-2024, 2024
Short summary
Short summary
A study in the rural North China Plain showed environmentally persistent free radicals (EPFRs) in atmospheric particulate matter (PM), with a notable water-soluble fraction likely from atmospheric oxidation during transport. Significant positive correlations between EPFRs and the water-soluble oxidative potential of PM2.5 were found, primarily attributable to the water-soluble fractions of EPFRs. These findings emphasize understanding EPFRs' atmospheric evolution for climate and health impacts.
Kirsten N. Fossum, Chunshui Lin, Niall O'Sullivan, Lu Lei, Stig Hellebust, Darius Ceburnis, Aqeel Afzal, Anja Tremper, David Green, Srishti Jain, Steigvilė Byčenkienė, Colin O'Dowd, John Wenger, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 24, 10815–10831, https://doi.org/10.5194/acp-24-10815-2024, https://doi.org/10.5194/acp-24-10815-2024, 2024
Short summary
Short summary
The chemical composition and sources of submicron aerosol in the Dublin Port area were investigated over a month-long campaign. Two distinct types of ship emissions were identified and characterised: sulfate-rich plumes from the use of heavy fuel oil with scrubbers and organic-rich plumes from the use of low-sulfur fuels. The latter were more frequent, emitting double the particle number and having a typical V / Ni ratio for ship emission.
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
Atmos. Chem. Phys., 24, 10655–10666, https://doi.org/10.5194/acp-24-10655-2024, https://doi.org/10.5194/acp-24-10655-2024, 2024
Short summary
Short summary
This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Yu Xu, Tang Liu, Yi-Jia Ma, Qi-Bin Sun, Hong-Wei Xiao, Hao Xiao, Hua-Yun Xiao, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, https://doi.org/10.5194/acp-24-10531-2024, 2024
Short summary
Short summary
This study investigates the characteristics of aminiums and ammonium in PM2.5 on clean and polluted winter days in 11 Chinese cities, highlighting the possibility of the competitive uptake of ammonia versus amines on acidic aerosols or the displacement of aminiums by ammonia under high-ammonia conditions. The overall results deepen the understanding of the spatiotemporal differences in aminium characteristics and formation in China.
Cassidy Soloff, Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Francesca Gallo, Johnathan W. Hair, Miguel Ricardo A. Hilario, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 10385–10408, https://doi.org/10.5194/acp-24-10385-2024, https://doi.org/10.5194/acp-24-10385-2024, 2024
Short summary
Short summary
Using aircraft measurements over the northwestern Atlantic between the US East Coast and Bermuda and trajectory modeling of continental outflow, we identify trace gas and particle properties that exhibit gradients with offshore distance and quantify these changes with high-resolution measurements of concentrations and particle chemistry, size, and scattering properties. This work furthers our understanding of the complex interactions between continental and marine environments.
Alex Rowell, James Brean, David C. S. Beddows, Zongbo Shi, Avinash Kumar, Matti Rissanen, Miikka Dal Maso, Peter Mettke, Kay Weinhold, Maik Merkel, and Roy M. Harrison
Atmos. Chem. Phys., 24, 10349–10361, https://doi.org/10.5194/acp-24-10349-2024, https://doi.org/10.5194/acp-24-10349-2024, 2024
Short summary
Short summary
Ions enhance the formation and growth rates of new particles, affecting the Earth's radiation budget. Despite these effects, there is little published data exploring the sources of ions in the urban environment and their role in new particle formation (NPF). Here we show that natural ion sources dominate in urban environments, while traffic is a secondary source. Ions contribute up to 12.7 % of the formation rate of particles, indicating that they are important for forming urban PM.
Yuan Cheng, Xu-bing Cao, Sheng-qiang Zhu, Zhi-qing Zhang, Jiu-meng Liu, Hong-liang Zhang, Qiang Zhang, and Ke-bin He
Atmos. Chem. Phys., 24, 9869–9883, https://doi.org/10.5194/acp-24-9869-2024, https://doi.org/10.5194/acp-24-9869-2024, 2024
Short summary
Short summary
The agreement between observational and modeling results is essential for the development of efficient air pollution control strategies. Here we constrained the modeling results of carbonaceous aerosols by field observation in Northeast China, a historically overlooked but recently targeted region of national clean-air actions. Our study suggested that the simulation of agricultural fire emissions and secondary organic aerosols remains challenging.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
Atmos. Chem. Phys., 24, 9733–9748, https://doi.org/10.5194/acp-24-9733-2024, https://doi.org/10.5194/acp-24-9733-2024, 2024
Short summary
Short summary
Short-term strict emission control can improve air quality, but its effectiveness needs assessment. During the 2021 summer COVID-19 lockdown in Yangzhou, we found that PM2.5 levels did not decrease despite reduced primary emissions. Aged black-carbon particles increased substantially due to higher O3 levels and transported pollutants. High humidity and low wind also played key roles. The results highlight the importance of a regionally balanced control strategy for future air quality management.
Xinya Liu, Diego Alves Gouveia, Bas Henzing, Arnoud Apituley, Arjan Hensen, Danielle van Dinther, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 9597–9614, https://doi.org/10.5194/acp-24-9597-2024, https://doi.org/10.5194/acp-24-9597-2024, 2024
Short summary
Short summary
The vertical distribution of aerosol optical properties is important for their effect on climate. This is usually measured by lidar, which has limitations, most notably the assumption of a lidar ratio. Our study shows that routine surface-level aerosol measurements are able to predict this lidar ratio reasonably well within the lower layers of the atmosphere and thus provide a relatively simple and cost-effective method to improve lidar measurements.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
Atmos. Chem. Phys., 24, 9387–9399, https://doi.org/10.5194/acp-24-9387-2024, https://doi.org/10.5194/acp-24-9387-2024, 2024
Short summary
Short summary
We deployed an advanced aerosol–fog sampling system at a rural site in the North China Plain to investigate impacts of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient relative humidity (RH) conditions and that RH levels significantly impact aerosol sampling through the aerosol swelling effect.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 9263–9275, https://doi.org/10.5194/acp-24-9263-2024, https://doi.org/10.5194/acp-24-9263-2024, 2024
Short summary
Short summary
Brown carbon (BrC) is prevalent in the troposphere and can efficiently absorb solar and terrestrial radiation. Our observations show that the enhanced light absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Johnathan W. Hair, Miguel Ricardo A. Hilario, Chris A. Hostetler, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Cassidy Soloff, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9197–9218, https://doi.org/10.5194/acp-24-9197-2024, https://doi.org/10.5194/acp-24-9197-2024, 2024
Short summary
Short summary
This study uses airborne data to examine vertical profiles of trace gases, aerosol particles, and meteorological variables over a remote marine area (Bermuda). Results show distinct differences based on both air mass source region (North America, Ocean, Caribbean/North Africa) and altitude for a given air mass type. This work highlights the sensitivity of remote marine areas to long-range transport and the importance of considering the vertical dependence of trace gas and aerosol properties.
Kira Zeider, Grace Betito, Anthony Bucholtz, Peng Xian, Annette Walker, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9059–9083, https://doi.org/10.5194/acp-24-9059-2024, https://doi.org/10.5194/acp-24-9059-2024, 2024
Short summary
Short summary
The predominant wind direction along the California coast (northerly) reverses several times during the summer (to southerly). The effects of these wind reversals on aerosol and cloud characteristics are not well understood. Using data from multiple datasets we found that southerly flow periods had enhanced signatures of anthropogenic emissions due to shipping and continental sources, and clouds had more but smaller droplets.
Saleh Alzahrani, Doğuşhan Kılıç, Michael Flynn, Paul I. Williams, and James Allan
Atmos. Chem. Phys., 24, 9045–9058, https://doi.org/10.5194/acp-24-9045-2024, https://doi.org/10.5194/acp-24-9045-2024, 2024
Short summary
Short summary
This paper investigates emissions from aviation activities at an international airport to evaluate their impact on local air quality. The study provides detailed insights into the chemical composition of aerosols and key pollutants in the airport environment. Source apportionment analysis using positive matrix factorisation (PMF) identified three significant sources: less oxidised oxygenated organic aerosol, alkane organic aerosol, and more oxidised oxygenated organic aerosol.
Mingjie Kang, Mengying Bao, Wenhuai Song, Aduburexiati Abulimiti, Fang Cao, Sönke Szidat, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2098, https://doi.org/10.5194/egusphere-2024-2098, 2024
Short summary
Short summary
Reports on the molecular level knowledge of high temporal resolution PM2.5 components on hazy days are still limited. This study investigated many individual PM2.5 species and sources. The results show biomass burning (BB) was the main source of organic carbon. Moreover, BB enhanced fungal spore emissions and secondary aerosol formation. The contribution of non-fossils increased with increasing haze pollution. These findings suggest BB may be an important driver of haze events in winter.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
Atmos. Chem. Phys., 24, 8927–8941, https://doi.org/10.5194/acp-24-8927-2024, https://doi.org/10.5194/acp-24-8927-2024, 2024
Short summary
Short summary
Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams per kilogram of fuel. Ships with an exhaust gas cleaning system (EGCS) were found to have median BC emissions per fuel consumed 5 times lower than ships without an EGCS. However, this might be because of non-EGCS ships running at low engine loads rather than the EGCS itself. A local speed restriction would increase BC emissions of ships.
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 24, 8911–8926, https://doi.org/10.5194/acp-24-8911-2024, https://doi.org/10.5194/acp-24-8911-2024, 2024
Short summary
Short summary
Characterization of PM1 and positive matrix factorization (PMF) source apportionment of organic and inorganic fractions were conducted at the high-altitude station (HAC)2. Cloud presence reduced PM1, affecting sulfate more than organics. Free-troposphere (FT) conditions showed more black carbon (eBC) than planetary boundary layer (PBL) conditions.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
Short summary
Short summary
Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROSs) play an active role in the atmosphere. Despite control measures having effectively reduced their emissions, reductions were less than in PM2.5. Emission control measures performed well in achieving Parade Blue, but reducing the impact of the atmosphere on human health remains challenging. Thus, there is a need to reassess emission control measures to better address the challenges posed by EPFRs and ROSs.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 24, 8507–8518, https://doi.org/10.5194/acp-24-8507-2024, https://doi.org/10.5194/acp-24-8507-2024, 2024
Short summary
Short summary
The water solubility of secondary organic aerosols (SOAs) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOAs with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyan Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
Atmos. Chem. Phys., 24, 8473–8488, https://doi.org/10.5194/acp-24-8473-2024, https://doi.org/10.5194/acp-24-8473-2024, 2024
Short summary
Short summary
We investigated aerosol composition and sources and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more oxidized SOA; however, cloud evaporation leads to the production of less oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
Atmos. Chem. Phys., 24, 8397–8411, https://doi.org/10.5194/acp-24-8397-2024, https://doi.org/10.5194/acp-24-8397-2024, 2024
Short summary
Short summary
Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
EGUsphere, https://doi.org/10.5194/egusphere-2024-2230, https://doi.org/10.5194/egusphere-2024-2230, 2024
Short summary
Short summary
We present measurements of the composition of ultrafine particles collected from the eastern Amazon, a relatively understudied region that is subjected to increasing human influence. We find that while isoprene chemistry is likely significant to ultrafine particle growth throughout the year, compounds related to other sources such as biological spore emissions and biomass burning exhibit striking seasonal differences, implying an extensive variation in regional ultrafine particle sources.
Maya Abou-Ghanem, Daniel M. Murphy, Gregory P. Schill, Michael J. Lawler, and Karl D. Froyd
Atmos. Chem. Phys., 24, 8263–8275, https://doi.org/10.5194/acp-24-8263-2024, https://doi.org/10.5194/acp-24-8263-2024, 2024
Short summary
Short summary
Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
Atmos. Chem. Phys., 24, 8049–8066, https://doi.org/10.5194/acp-24-8049-2024, https://doi.org/10.5194/acp-24-8049-2024, 2024
Short summary
Short summary
To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate in Barbados and compared them to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable, except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions in sulfur dioxide (SO2) in the US and Europe; then it increased in the 2000s, likely due to anthropogenic emissions from Africa.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
EGUsphere, https://doi.org/10.5194/egusphere-2024-1390, https://doi.org/10.5194/egusphere-2024-1390, 2024
Short summary
Short summary
This study shows the derived organic aerosol hygroscopicity under high humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), after knowing the aerosol chemical composition.
Jiao Xue, Tian Zhang, Keyhong Park, Jinpei Yan, Young Jun Yoon, Jiyeon Park, and Bingbing Wang
Atmos. Chem. Phys., 24, 7731–7754, https://doi.org/10.5194/acp-24-7731-2024, https://doi.org/10.5194/acp-24-7731-2024, 2024
Short summary
Short summary
Ice formation by particles is an important way of making mixed-phase and ice clouds. We found that particles collected in the marine atmosphere exhibit diverse ice nucleation abilities and mixing states. Sea salt mixed-sulfate particles were enriched in ice-nucleating particles. Selective aging on sea salt particles made particle populations more externally mixed. Characterizations of particles and their mixing state are needed for a better understanding of aerosol–cloud interactions.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 24, 7755–7772, https://doi.org/10.5194/acp-24-7755-2024, https://doi.org/10.5194/acp-24-7755-2024, 2024
Short summary
Short summary
In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %) were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibiting the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O'Dowd
Atmos. Chem. Phys., 24, 7687–7698, https://doi.org/10.5194/acp-24-7687-2024, https://doi.org/10.5194/acp-24-7687-2024, 2024
Short summary
Short summary
The chemical composition of atmospheric particles has shown significant changes in recent years. We investigated the potential effects of changes in inorganics on aerosol water uptake and, thus, secondary organic aerosol formation in wintertime haze based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, northwestern China. We highlight the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
Short summary
Short summary
Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
Short summary
Short summary
The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
Short summary
Short summary
The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
Short summary
Short summary
We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
Short summary
Short summary
Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
Short summary
Short summary
Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Rime El Asmar, Zongrun Li, David J. Tanner, Yongtao Hu, Susan O’Neill, L. Gregory Huey, M. Talat Odman, and Rodney J. Weber
EGUsphere, https://doi.org/10.5194/egusphere-2024-1485, https://doi.org/10.5194/egusphere-2024-1485, 2024
Short summary
Short summary
Prescribed burning is an important method for managing ecosystems and preventing wildfires, however, smoke from prescribed fires can have a significant impact on air quality. Here, using a network of fixed sites and sampling throughout an extended prescribed burning period in two different years, we characterize the emissions and evolution up to 8 hours of PM2.5 mass, BC, and BrC in smoke from burning of forested lands in the southeastern US.
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Tomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
EGUsphere, https://doi.org/10.5194/egusphere-2024-1399, https://doi.org/10.5194/egusphere-2024-1399, 2024
Short summary
Short summary
Using single-particle mass spectrometry, we show that trace concentrations of bromine and iodine are ubiquitous in remote tropospheric aerosol, and suggest that aerosols are an important part of the global reactive iodine budget. Comparisons to a global climate model with detailed iodine chemistry are favorable in the background atmosphere; however, the model cannot replicate our measurements near the ocean surface, in biomass burning plumes, and in the stratosphere.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
Short summary
Short summary
Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
Short summary
Short summary
Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, and Teruo Aoki
EGUsphere, https://doi.org/10.5194/egusphere-2024-1498, https://doi.org/10.5194/egusphere-2024-1498, 2024
Short summary
Short summary
Monthly records spanning 350 years from a Greenland ice core reveal trends in black carbon (BC) concentrations and sizes. BC concentrations have risen since the late 19th century due to the inflow of anthropogenic BC, with these particles being larger than those from biomass burning (BB). High BB BC concentration peaks in summer originating from BB could reduce albedo. However, BB BC showed no upward trend until the early 2000s. Our findings are crucial for validating aerosol and climate models.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
Short summary
Short summary
In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Andreas Aktypis, Dontavious Sippial, Christina Vasilakopoulou, Angeliki Matrali, Christos Kaltsonoudis, Andrea Simonati, Marco Paglione, Matteo Rinaldi, Stefano Decesari, and Spyros Pandis
EGUsphere, https://doi.org/10.5194/egusphere-2024-1317, https://doi.org/10.5194/egusphere-2024-1317, 2024
Short summary
Short summary
A dual chamber system was deployed in two different environments (Po Valley, Italy and Pertouli forest, Greece) to study the potential of ambient air directly injected into the chambers, to form secondary aerosol. In the Po Valley, the system reacts rapidly forming large amounts of SOA, while in Pertouli the corresponding SOA formation chemistry appears to have been practically terminated before the beginning of most experiments, so there is little additional SOA formation potential left.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
Short summary
Short summary
This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
James Brean, David C. S. Beddows, Eija Asmi, Ari Virkkula, Lauriane L. J. Quéléver, Mikko Sipilä, Floortje Van Den Heuvel, Thomas Lachlan-Cope, Anna Jones, Markus Frey, Angelo Lupi, Jiyeon Park, Young Jun Yoon, Ralf Weller, Giselle L. Marincovich, Gabriela C. Mulena, Roy M. Harrison, and Manuel Dall´Osto
EGUsphere, https://doi.org/10.5194/egusphere-2024-987, https://doi.org/10.5194/egusphere-2024-987, 2024
Short summary
Short summary
Our results emphasize how understanding the geographical variation in surface types across the Antarctic is key to understanding secondary aerosol sources.
Qun He, Zhaowen Wang, Houfeng Liu, Pengju Xu, Rongbao Duan, Caihong Xu, Jianmin Chen, and Min Wei
EGUsphere, https://doi.org/10.5194/egusphere-2024-841, https://doi.org/10.5194/egusphere-2024-841, 2024
Short summary
Short summary
Coastal environments provide an ideal setting for investigating the intermixing processes of terrestrial and marine aerosols. Terrestrial air mass constituted a larger proportion during severe air pollution, harboring more animal and human pathogens. A relative shift towards marine air-mass with respect to pollution elimination, where saprophytic bacteria and fungi were predominant. Mixed air-mass reveals the intermixing processes of terrestrial and marine sources.
Cited articles
Ahlm, L., Shakya, K. M., Russell, L. M., Schroder, J. C., Wong, J. P. S., Sjostedt, S. J., Hayden, K. L., Liggio, J., Wentzell, J. J. B., Wiebe, H. A., Mihele, C., Leaitch, W. R., and Macdonald, A. M.: Temperature-dependent accumulation mode particle and cloud nuclei concentrations from biogenic sources during WACS 2010, Atmos. Chem. Phys., 13, 3393–3407, https://doi.org/10.5194/acp-13-3393-2013, 2013.
Aiken, A. C., Decarlo, P. F., Kroll, J. H., Worsnop, D. R., Huffman, J. A., Docherty, K. S., Ulbrich, I. M., Mohr, C., Kimmel, J. R., Sueper, D., Sun, Y., Zhang, Q., Trimborn, A., Northway, M., Ziemann, P. J., Canagaratna, M. R., Onasch, T. B., Alfarra, M. R., Prevot, A. S. H., Dommen, J., Duplissy, J., Metzger, A., Baltensperger, U., and Jimenez, J. L.: O / C and OM / OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry, Environ. Sci. Technol., 42, 4478–4485, 2008.
Allan, J., Delia, A., Coe, H., Bower, K., Alfarra, M., Jimenez, J., Middlebrook, A., Drewnick, F., Onasch, T., Canagaratna, M., Jayne, J., and Worsnop, D.: A generalised method for the extraction of chemically resolved mass spectra from aerodyne aerosol mass spectrometer data, J. Aerosol Sci., 35, 909–922, 2004.
Berresheim, H., Elste, T., Plass-Dulmer, C., Eisele, F. L., and Tanner, D. J.: Chemical ionization mass spectrometer for long-term measurements of atmospheric OH and H2SO4, Int. J. Mass Spectrom., 202, 91–109, 2000.
Blake, R. S., Monks, P. S., and Ellis, A. M.: Proton-Transfer Reaction Mass Spectrometry, Chem. Rev., 109, 861–896, 2009.
Boyd, C. M., Sanchez, J., Xu, L., Eugene, A. J., Nah, T., Tuet, W. Y., Guzman, M. I., and Ng, N. L.: Secondary organic aerosol formation from the β-pinene+NO3 system: effect of humidity and peroxy radical fate, Atmos. Chem. Phys., 15, 7497–7522, https://doi.org/10.5194/acp-15-7497-2015, 2015.
Canagaratna, M. R., Jimenez, J. L., Kroll, J. H., Chen, Q., Kessler, S. H., Massoli, P., Hildebrandt Ruiz, L., Fortner, E., Williams, L. R., Wilson, K. R., Surratt, J. D., Donahue, N. M., Jayne, J. T., and Worsnop, D. R.: Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications, Atmos. Chem. Phys., 15, 253–272, https://doi.org/10.5194/acp-15-253-2015, 2015.
Chen, Q., Farmer, D. K., Schneider, J., Zorn, S. R., Heald, C. L., Karl, T. G., Guenther, A., Allan, J. D., Robinson, N., Coe, H., Kimmel, J. R., Pauliquevis, T., Borrmann, S., Poeschl, U., Andreae, M. O., Artaxo, P., Jimenez, J. L., and Martin, S. T.: Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin, Geophys. Res. Lett., 36, L20806, https://doi.org/10.1029/2009GL039880, 2009.
Chen, Q., Farmer, D. K., Rizzo, L. V., Pauliquevis, T., Kuwata, M., Karl, T. G., Guenther, A., Allan, J. D., Coe, H., Andreae, M. O., Pöschl, U., Jimenez, J. L., Artaxo, P., and Martin, S. T.: Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08), Atmos. Chem. Phys., 15, 3687–3701, https://doi.org/10.5194/acp-15-3687-2015, 2015.
Chhabra, P. S., Flagan, R. C., and Seinfeld, J. H.: Elemental analysis of chamber organic aerosol using an aerodyne high-resolution aerosol mass spectrometer, Atmos. Chem. Phys., 10, 4111–4131, https://doi.org/10.5194/acp-10-4111-2010, 2010.
DeCarlo, P. F., Kimmel, J. R., Trimborn, A., Northway, M. J., Jayne, J. T., Aiken, A. C., Gonin, M., Fuhrer, K., Horvath, T., Docherty, K. S., Worsnop, D. R., and Jimenez, J. L.: Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer, Anal. Chem., 78, 8281–8289, 2006.
de Gouw, J. and Warneke, C.: Measurements of volatile organic compounds in the earths atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrom. Rev., 26, 223–257, 2007.
Donahue, N. M., Kroll, J. H., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution, Atmos. Chem. Phys., 12, 615–634, https://doi.org/10.5194/acp-12-615-2012, 2012.
Ehn, M., Kleist, E., Junninen, H., Petäjä, T., Lönn, G., Schobesberger, S., Dal Maso, M., Trimborn, A., Kulmala, M., Worsnop, D. R., Wahner, A., Wildt, J., and Mentel, Th. F.: Gas phase formation of extremely oxidized pinene reaction products in chamber and ambient air, Atmos. Chem. Phys., 12, 5113–5127, https://doi.org/10.5194/acp-12-5113-2012, 2012.
Ehn, M., Thornton, J. A., Kleist, E., Sipila, M., Junninen, H., Pullinen, I., Springer, M., Rubach, F., Tillmann, R., Lee, B., Lopez-Hilfiker, F., Andres, S., Acir, I., Rissanen, M., Jokinen, T., Schobesberger, S., Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurten, T., Nielsen, L. B., Jorgensen, S., Kjaergaard, H. G., Canagaratna, M., Dal Maso, M., Berndt, T., Petaja, T., Wahner, A., Kerminen, V., Kulmala, M., Worsnop, D. R., Wildt, J., and Mentel, T. F.: A large source of low-volatility secondary organic aerosol, Nature, 506, 476–479, https://doi.org/10.1038/nature13032, 2014.
Farmer, D. K., Matsunaga, A., Docherty, K. S., Surratt, J. D., Seinfeld, J. H., Ziemann, P. J., and Jimenez, J. L.: Response of an aerosol mass spectrometer to organonitrates and organosulfates and implications for atmospheric chemistry, P. Natl. Acad. Sci. USA, 107, 6670–6675, 2010.
Finessi, E., Decesari, S., Paglione, M., Giulianelli, L., Carbone, C., Gilardoni, S., Fuzzi, S., Saarikoski, S., Raatikainen, T., Hillamo, R., Allan, J., Mentel, Th. F., Tiitta, P., Laaksonen, A., Petäjä, T., Kulmala, M., Worsnop, D. R., and Facchini, M. C.: Determination of the biogenic secondary organic aerosol fraction in the boreal forest by NMR spectroscopy, Atmos. Chem. Phys., 12, 941–959, https://doi.org/10.5194/acp-12-941-2012, 2012.
Fröhlich, R., Crenn, V., Setyan, A., Belis, C. A., Canonaco, F., Favez, O., Riffault, V., Slowik, J. G., Aas, W., Aijälä, M., Alastuey, A., Artiñano, B., Bonnaire, N., Bozzetti, C., Bressi, M., Carbone, C., Coz, E., Croteau, P. L., Cubison, M. J., Esser-Gietl, J. K., Green, D. C., Gros, V., Heikkinen, L., Herrmann, H., Jayne, J. T., Lunder, C. R., Minguillón, M. C., Močnik, G., O'Dowd, C. D., Ovadnevaite, J., Petralia, E., Poulain, L., Priestman, M., Ripoll, A., Sarda-Estève, R., Wiedensohler, A., Baltensperger, U., Sciare, J., and Prévôt, A. S. H.: ACTRIS ACSM intercomparison – Part 2: Intercomparison of ME-2 organic source apportionment results from 15 individual, co-located aerosol mass spectrometers, Atmos. Meas. Tech., 8, 2555–2576, https://doi.org/10.5194/amt-8-2555-2015, 2015.
Fry, J. L., Kiendler-Scharr, A., Rollins, A. W., Wooldridge, P. J., Brown, S. S., Fuchs, H., Dubé, W., Mensah, A., dal Maso, M., Tillmann, R., Dorn, H.-P., Brauers, T., and Cohen, R. C.: Organic nitrate and secondary organic aerosol yield from NO3 oxidation of β-pinene evaluated using a gas-phase kinetics/aerosol partitioning model, Atmos. Chem. Phys., 9, 1431–1449, https://doi.org/10.5194/acp-9-1431-2009, 2009.
Goldstein, A. H., Koven, C. D., Heald, C. L., and Fung, I. Y.: Biogenic carbon and anthropogenic pollutants combine to form a cooling haze over the southeastern United States, P. Natl. Acad. Sci. USA, 106, 8835–8840, 2009.
Gratien, A., Johnson, S. N., Ezell, M. J., Dawson, M. L., Bennett, R., and Finlayson-Pitts, B. J.: Surprising formation of p-cymene in the oxidation of alpha-pinene in air by the atmospheric oxidants OH, O3, and NO3, Environ. Sci. Technol., 45, 2755–2760, 2011.
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009.
Han, Y., Iwamoto, Y., Nakayama, T., Kawamura, K., and Mochida, M.: Formation and evolution of biogenic secondary organic aerosol over a forest site in Japan, J. Geophys. Res.-Atmos., 119, 259–273, 2014.
Harrison, D., Hunter, M. C., Lewis, A. C., Seakins, P. W., Bonsang, B., Gros, V., Kanakidou, M., Touaty, M., Kavouras, I., Mihalopoulos, N., Stephanou, E., Alves, C., Nunes, T., and Pio, C.: Ambient isoprene and monoterpene concentrations in a Greek fir (Abies Borisii-regis) forest. Reconciliation with emissions measurements and effects on measured OH concentrations, Atmos. Environ., 35, 4699–4711, 2001.
Hu, W. W., Campuzano-Jost, P., Palm, B. B., Day, D. A., Ortega, A. M., Hayes, P. L., Krechmer, J. E., Chen, Q., Kuwata, M., Liu, Y. J., de Sá, S. S., McKinney, K., Martin, S. T., Hu, M., Budisulistiorini, S. H., Riva, M., Surratt, J. D., St. Clair, J. M., Isaacman-Van Wertz, G., Yee, L. D., Goldstein, A. H., Carbone, S., Brito, J., Artaxo, P., de Gouw, J. A., Koss, A., Wisthaler, A., Mikoviny, T., Karl, T., Kaser, L., Jud, W., Hansel, A., Docherty, K. S., Alexander, M. L., Robinson, N. H., Coe, H., Allan, J. D., Canagaratna, M. R., Paulot, F., and Jimenez, J. L.: Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements, Atmos. Chem. Phys., 15, 11807–11833, https://doi.org/10.5194/acp-15-11807-2015, 2015.
Huffman, J. A., Docherty, K. S., Aiken, A. C., Cubison, M. J., Ulbrich, I. M., DeCarlo, P. F., Sueper, D., Jayne, J. T., Worsnop, D. R., Ziemann, P. J., and Jimenez, J. L.: Chemically-resolved aerosol volatility measurements from two megacity field studies, Atmos. Chem. Phys., 9, 7161–7182, https://doi.org/10.5194/acp-9-7161-2009, 2009.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, https://doi.org/10.5194/acp-5-1053-2005, 2005.
Kiendler-Scharr, A., Zhang, Q., Hohaus, T., Kleist, E., Mensah, A., Mentel, T. F., Spindler, C., Uerlings, R., Tillmann, R., and Wildt, J.: Aerosol Mass Spectrometric Features of Biogenic SOA: Observations from a Plant Chamber and in Rural Atmospheric Environments, Environ. Sci. Technol., 43, 8166–8172, 2009.
Leaitch, W. R., Macdonald, A. M., Brickell, P. C., Liggio, J., Sjostedt, S. J., Vlasenko, A., Bottenheim, J. W., Huang, L., Li, S.-M., Liu, P. S. K., Toom-Sauntry, D., Hayden, K. A., Sharma, S., Shantz, N. C., Wiebe, H. A., Zhang, W., Abbatt, J. P. D., Slowik, J. G., Chang, R. Y. W., Russell, L. M., Schwartz, R. E., Takahama, S., Jayne, J. T., and Ng, N. L.: Temperature response of the submicron organic aerosol from temperate forests, Atmos. Environ., 45, 6696–6704, https://doi.org/10.1016/j.atmosenv.2011.08.047, 2011.
Lee, A., Goldstein, A. H., Keywood, M. D., Gao, S., Varutbangkul, V., Bahreini, R., Ng, N. L., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes, J. Geophys. Res.-Atmos., 111, D07302, https://doi.org/10.1029/2005JD006437, 2006a.
Lee, A., Goldstein, A. H., Kroll, J. H., Ng, N. L., Varutbangkul, V., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the photooxidation of 16 different terpenes, J. Geophys. Res.-Atmos., 111, D17305, https://doi.org/10.1029/2006JD007050, 2006b.
Lee, A. K. Y., Hayden, K. L., Herckes, P., Leaitch, W. R., Liggio, J., Macdonald, A. M., and Abbatt, J. P. D.: Characterization of aerosol and cloud water at a mountain site during WACS 2010: secondary organic aerosol formation through oxidative cloud processing, Atmos. Chem. Phys., 12, 7103–7116, https://doi.org/10.5194/acp-12-7103-2012, 2012.
Liggio, J. and Li, S.: Reactive uptake of pinonaldehyde on acidic aerosols, J. Geophys. Res.-Atmos., 111, D24303, https://doi.org/10.1029/2005JD006978, 2006.
Martin, S. T., Andreae, M. O., Althausen, D., Artaxo, P., Baars, H., Borrmann, S., Chen, Q., Farmer, D. K., Guenther, A., Gunthe, S. S., Jimenez, J. L., Karl, T., Longo, K., Manzi, A., Müller, T., Pauliquevis, T., Petters, M. D., Prenni, A. J., Pöschl, U., Rizzo, L. V., Schneider, J., Smith, J. N., Swietlicki, E., Tota, J., Wang, J., Wiedensohler, A., and Zorn, S. R.: An overview of the Amazonian Aerosol Characterization Experiment 2008 (AMAZE-08), Atmos. Chem. Phys., 10, 11415–11438, https://doi.org/10.5194/acp-10-11415-2010, 2010.
McLafferty, L. W. and Turecek, F.: Interpretation of Mass Spectra, University Science Books, Mill Valley, CA, 238–240, 1993.
Müller, L., Reinnig, M.-C., Naumann, K. H., Saathoff, H., Mentel, T. F., Donahue, N. M., and Hoffmann, T.: Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid – a mass spectrometric study of SOA aging, Atmos. Chem. Phys., 12, 1483–1496, https://doi.org/10.5194/acp-12-1483-2012, 2012.
Ng, N. L., Kwan, A. J., Surratt, J. D., Chan, A. W. H., Chhabra, P. S., Sorooshian, A., Pye, H. O. T., Crounse, J. D., Wennberg, P. O., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO3), Atmos. Chem. Phys., 8, 4117–4140, https://doi.org/10.5194/acp-8-4117-2008, 2008.
Ng, N. L., Canagaratna, M. R., Zhang, Q., Jimenez, J. L., Tian, J., Ulbrich, I. M., Kroll, J. H., Docherty, K. S., Chhabra, P. S., Bahreini, R., Murphy, S. M., Seinfeld, J. H., Hildebrandt, L., Donahue, N. M., DeCarlo, P. F., Lanz, V. A., Prévôt, A. S. H., Dinar, E., Rudich, Y., and Worsnop, D. R.: Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry, Atmos. Chem. Phys., 10, 4625–4641, https://doi.org/10.5194/acp-10-4625-2010, 2010.
Ng, N. L., Canagaratna, M. R., Jimenez, J. L., Zhang, Q., Ulbrich, I. M., and Worsnop, D. R.: Real-time methods for estimating organic component mass concentrations from aerosol mass spectrometer data, Environ. Sci. Technol., 45, 910–916, 2011.
Paatero, P. and Tapper, U.: Positive matrix factorization: A non-negative factor model with optimal utilization of error estimate of data values, Environmetrics, 5, 111–126, 1994.
Pierce, J. R., Leaitch, W. R., Liggio, J., Westervelt, D. M., Wainwright, C. D., Abbatt, J. P. D., Ahlm, L., Al-Basheer, W., Cziczo, D. J., Hayden, K. L., Lee, A. K. Y., Li, S.-M., Russell, L. M., Sjostedt, S. J., Strawbridge, K. B., Travis, M., Vlasenko, A., Wentzell, J. J. B., Wiebe, H. A., Wong, J. P. S., and Macdonald, A. M.: Nucleation and condensational growth to CCN sizes during a sustained pristine biogenic SOA event in a forested mountain valley, Atmos. Chem. Phys., 12, 3147–3163, https://doi.org/10.5194/acp-12-3147-2012, 2012.
Rinne, H., Guenther, A., Greenberg, J., and Harley, P.: Isoprene and monoterpene fluxes measured above Amazonian rainforest and their dependence on light and temperature, Atmos. Environ., 36, 2421–2426, 2002.
Robinson, N. H., Hamilton, J. F., Allan, J. D., Langford, B., Oram, D. E., Chen, Q., Docherty, K., Farmer, D. K., Jimenez, J. L., Ward, M. W., Hewitt, C. N., Barley, M. H., Jenkin, M. E., Rickard, A. R., Martin, S. T., McFiggans, G., and Coe, H.: Evidence for a significant proportion of Secondary Organic Aerosol from isoprene above a maritime tropical forest, Atmos. Chem. Phys., 11, 1039–1050, https://doi.org/10.5194/acp-11-1039-2011, 2011.
Setyan, A., Zhang, Q., Merkel, M., Knighton, W. B., Sun, Y., Song, C., Shilling, J. E., Onasch, T. B., Herndon, S. C., Worsnop, D. R., Fast, J. D., Zaveri, R. A., Berg, L. K., Wiedensohler, A., Flowers, B. A., Dubey, M. K., and Subramanian, R.: Characterization of submicron particles influenced by mixed biogenic and anthropogenic emissions using high-resolution aerosol mass spectrometry: results from CARES, Atmos. Chem. Phys., 12, 8131–8156, https://doi.org/10.5194/acp-12-8131-2012, 2012.
Shilling, J. E., Chen, Q., King, S. M., Rosenoern, T., Kroll, J. H., Worsnop, D. R., DeCarlo, P. F., Aiken, A. C., Sueper, D., Jimenez, J. L., and Martin, S. T.: Loading-dependent elemental composition of α-pinene SOA particles, Atmos. Chem. Phys., 9, 771–782, https://doi.org/10.5194/acp-9-771-2009, 2009.
Shilling, J. E., Zaveri, R. A., Fast, J. D., Kleinman, L., Alexander, M. L., Canagaratna, M. R., Fortner, E., Hubbe, J. M., Jayne, J. T., Sedlacek, A., Setyan, A., Springston, S., Worsnop, D. R., and Zhang, Q.: Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign, Atmos. Chem. Phys., 13, 2091–2113, https://doi.org/10.5194/acp-13-2091-2013, 2013.
Sjostedt, S. J., Huey, L. G., Tanner, D. J., Peischl, J., Chen, G., Dibb, J. E., Lefer, B., Hutterli, M. A., Beyersdorf, A. J., Blake, N. J., Blake, D. R., Sueper, D., Ryerson, T., Burkhart, J., and Stohl, A.: Observations of hydroxyl and the sum of peroxy radicals at Summit, Greenland during summer 2003, Atmos. Environ., 41, 5122–5137, 2007.
Slowik, J. G., Stroud, C., Bottenheim, J. W., Brickell, P. C., Chang, R. Y.-W., Liggio, J., Makar, P. A., Martin, R. V., Moran, M. D., Shantz, N. C., Sjostedt, S. J., van Donkelaar, A., Vlasenko, A., Wiebe, H. A., Xia, A. G., Zhang, J., Leaitch, W. R., and Abbatt, J. P. D.: Characterization of a large biogenic secondary organic aerosol event from eastern Canadian forests, Atmos. Chem. Phys., 10, 2825–2845, https://doi.org/10.5194/acp-10-2825-2010, 2010.
Slowik, J. G., Wong, J. P. S., and Abbatt, J. P. D.: Real-time, controlled OH-initiated oxidation of biogenic secondary organic aerosol, Atmos. Chem. Phys., 12, 9775–9790, https://doi.org/10.5194/acp-12-9775-2012, 2012.
Tanner, D. J., Jefferson, A., and Eisele, F. L.: Selected ion chemical ionization mass spectrometric measurement of OH, J. Geophys. Res.-Atmos., 102, 6415–6425, 1997.
Ulbrich, I. M., Canagaratna, M. R., Zhang, Q., Worsnop, D. R., and Jimenez, J. L.: Interpretation of organic components from Positive Matrix Factorization of aerosol mass spectrometric data, Atmos. Chem. Phys., 9, 2891–2918, https://doi.org/10.5194/acp-9-2891-2009, 2009.
Xu, L., Guo, H., Boyd, C. M., Klein, M., Bougiatioti, A., Cerully, K. M., Hite, J. R., Isaacman-VanWertz, G., Kreisberg, N. M., Knote, C., Olson, K., Koss, A., Goldstein, A. H., Hering, S. V., de Gouw, J., Baumann, K., Lee, S., Nenes, A., Weber, R. J., and Ng, N. L.: Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States, P Natl. Acad. Sci. USA, 112, 37–42, 2015.
Zhang, X., Cappa, C. D., Jathar, S. H., McVay, R. C., Ensberg, J. J., Kleeman, M. J., and Seinfeld, J. H.: Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol, P. Natl. Acad. Sci. USA, 111, 5802–5807, 2014.
Zhang, X., Schwantes, R. H., McVay, R. C., Lignell, H., Coggon, M. M., Flagan, R. C., and Seinfeld, J. H.: Vapor wall deposition in Teflon chambers, Atmos. Chem. Phys., 15, 4197–4214, https://doi.org/10.5194/acp-15-4197-2015, 2015.
Short summary
Substantial biogenic secondary organic aerosol (BSOA) formation was investigated in a coniferous forest mountain region in Whistler, British Columbia. A largely biogenic aerosol growth episode was observed, providing a unique opportunity to investigate BSOA formation chemistry in a forested environment. In particular, our observations provide insights into the relative importance of different oxidation mechanisms between day and night.
Substantial biogenic secondary organic aerosol (BSOA) formation was investigated in a coniferous...
Altmetrics
Final-revised paper
Preprint