Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1417-2016
https://doi.org/10.5194/acp-16-1417-2016
Research article
 | 
08 Feb 2016
Research article |  | 08 Feb 2016

Impact of chamber wall loss of gaseous organic compounds on secondary organic aerosol formation: explicit modeling of SOA formation from alkane and alkene oxidation

Y. S. La, M. Camredon, P. J. Ziemann, R. Valorso, A. Matsunaga, V. Lannuque, J. Lee-Taylor, A. Hodzic, S. Madronich, and B. Aumont

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Cited articles

Aschmann, S. M., Arey, J., and Atkinson, R.: Kinetics and Products of the Reaction of OH Radicals with 3-Methoxy-3-methyl-1-butanol., Environ. Sci. Technol., 45, 6896–6901, 2011.
Atkinson, R.: Rate constants for the atmospheric reactions of alkoxy radicals: An updated estimation method, Atmos. Environ., 41, 8468–8485, https://doi.org/10.1016/j.atmosenv.2007.07.002, 2007.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Atkinson, R., Arey, J., and Aschmann, S. M.: Atmospheric chemistry of alkanes: Review and recent developments, Atmos. Environ., 42, 5859–5871, https://doi.org/10.1016/j.atmosenv.2007.08.040, 2008.
Aumont, B., Szopa, S., and Madronich, S.: Modelling the evolution of organic carbon during its gas-phase tropospheric oxidation: development of an explicit model based on a self generating approach, Atmos. Chem. Phys., 5, 2497–2517, https://doi.org/10.5194/acp-5-2497-2005, 2005.
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The potential impact of chamber walls on the loss of gaseous organic species and secondary organic aerosol (SOA) formation has been explored using the GECKO-A modeling tool, which explicitly represents SOA formation and gas-wall partitioning. The model was compared with 41 smog chamber experiments of SOA formation under OH oxidation of alkane and alkene serie. The organic vapor loss to the chamber walls is found to affect SOA yields as well as the composition of the gas and the particle phase.
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