Articles | Volume 15, issue 4
https://doi.org/10.5194/acp-15-2119-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-2119-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
26 Feb 2015
Research article |
| 26 Feb 2015
Dependence of the vertical distribution of bromine monoxide in the lower troposphere on meteorological factors such as wind speed and stability
P. K. Peterson
Department of Chemistry and Biochemistry, Geophysical Institute, University of Alaska Fairbanks, Fairbanks, Alaska, USA
Department of Chemistry and Biochemistry, Geophysical Institute, University of Alaska Fairbanks, Fairbanks, Alaska, USA
K. A. Pratt
Department of Chemistry, Purdue University, West Lafayette, Indiana, USA
now at: Department of Chemistry and Department of Earth & Environmental Sciences, University of Michigan, Ann Arbor, Michigan, USA
P. B. Shepson
Department of Chemistry, Purdue University, West Lafayette, Indiana, USA
Department of Earth, Atmospheric and Planetary Sciences, Purdue University, West Lafayette, Indiana, USA
Institute for Environmental Physics, University of Heidelberg, Heidelberg, Germany
J. Zielcke
Institute for Environmental Physics, University of Heidelberg, Heidelberg, Germany
U. Platt
Institute for Environmental Physics, University of Heidelberg, Heidelberg, Germany
S. J. Walsh
Department of Chemistry and Biochemistry, Geophysical Institute, University of Alaska Fairbanks, Fairbanks, Alaska, USA
S. V. Nghiem
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
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Brandon Bottorff, Michelle M. Lew, Youngjun Woo, Pamela Rickly, Matthew D. Rollings, Benjamin Deming, Daniel C. Anderson, Ezra Wood, Hariprasad D. Alwe, Dylan B. Millet, Andrew Weinheimer, Geoff Tyndall, John Ortega, Sebastien Dusanter, Thierry Leonardis, James Flynn, Matt Erickson, Sergio Alvarez, Jean C. Rivera-Rios, Joshua D. Shutter, Frank Keutsch, Detlev Helmig, Wei Wang, Hannah M. Allen, Johnathan H. Slade, Paul B. Shepson, Steven Bertman, and Philip S. Stevens
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Robert G. Ryan, Eloise A. Marais, Eleanor Gershenson-Smith, Robbie Ramsay, Jan-Peter Muller, Jan-Lukas Tirpitz, and Udo Frieß
Atmos. Chem. Phys., 23, 7121–7139, https://doi.org/10.5194/acp-23-7121-2023, https://doi.org/10.5194/acp-23-7121-2023, 2023
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We describe the first data retrieval from a newly installed instrument providing measurements of vertical profiles of air pollution over Central London during heatwaves in summer 2022. We use these observations with surface air quality network measurements to support interpretation that an exponential increase in biogenic emissions of isoprene during heatwaves provides the limiting ingredient for severe ozone pollution, leading to non-compliance with the national ozone air quality standard.
Eleftherios Ioannidis, Kathy S. Law, Jean-Christophe Raut, Louis Marelle, Tatsuo Onishi, Rachel M. Kirpes, Lucia M. Upchurch, Thomas Tuch, Alfred Wiedensohler, Andreas Massling, Henrik Skov, Patricia K. Quinn, and Kerri A. Pratt
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Remote and local anthropogenic emissions contribute to wintertime Arctic haze, with enhanced aerosol concentrations, but natural sources, which also contribute, are less well studied. Here, modelled wintertime sea-spray aerosols are improved in WRF-Chem over the wider Arctic by including updated wind speed and temperature-dependent treatments. As a result, anthropogenic nitrate aerosols are also improved. Open leads are confirmed to be the main source of sea-spray aerosols over northern Alaska.
Ka Lok Chan, Pieter Valks, Klaus-Peter Heue, Ronny Lutz, Pascal Hedelt, Diego Loyola, Gaia Pinardi, Michel Van Roozendael, François Hendrick, Thomas Wagner, Vinod Kumar, Alkis Bais, Ankie Piters, Hitoshi Irie, Hisahiro Takashima, Yugo Kanaya, Yongjoo Choi, Kihong Park, Jihyo Chong, Alexander Cede, Udo Frieß, Andreas Richter, Jianzhong Ma, Nuria Benavent, Robert Holla, Oleg Postylyakov, Claudia Rivera Cárdenas, and Mark Wenig
Earth Syst. Sci. Data, 15, 1831–1870, https://doi.org/10.5194/essd-15-1831-2023, https://doi.org/10.5194/essd-15-1831-2023, 2023
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Henning Finkenzeller, Denis Pöhler, Martin Horbanski, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 16, 1343–1356, https://doi.org/10.5194/amt-16-1343-2023, https://doi.org/10.5194/amt-16-1343-2023, 2023
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Udo Frieß, Karin Kreher, Richard Querel, Holger Schmithüsen, Dan Smale, Rolf Weller, and Ulrich Platt
Atmos. Chem. Phys., 23, 3207–3232, https://doi.org/10.5194/acp-23-3207-2023, https://doi.org/10.5194/acp-23-3207-2023, 2023
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Reactive bromine compounds, emitted by the sea ice during polar spring, play an important role in the atmospheric chemistry of the coastal regions of Antarctica. We investigate the sources and impacts of reactive bromine in detail using many years of measurements at two Antarctic sites located at opposite sides of the Antarctic continent. Using a multitude of meteorological observations, we were able to identify the main triggers and source regions for reactive bromine in Antarctica.
Bianca Lauster, Steffen Dörner, Carl-Fredrik Enell, Udo Frieß, Myojeong Gu, Janis Puķīte, Uwe Raffalski, and Thomas Wagner
Atmos. Chem. Phys., 22, 15925–15942, https://doi.org/10.5194/acp-22-15925-2022, https://doi.org/10.5194/acp-22-15925-2022, 2022
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Polar stratospheric clouds (PSCs) are an important component in ozone chemistry. Here, we use two differential optical absorption spectroscopy (DOAS) instruments in the Antarctic and Arctic to investigate the occurrence of PSCs based on the colour index, i.e. the colour of the zenith sky. Additionally using radiative transfer simulations, the variability and the seasonal cycle of PSC occurrence are analysed and an unexpectedly high signal during spring suggests the influence of volcanic aerosol.
Qianjie Chen, Jessica A. Mirrielees, Sham Thanekar, Nicole A. Loeb, Rachel M. Kirpes, Lucia M. Upchurch, Anna J. Barget, Nurun Nahar Lata, Angela R. W. Raso, Stephen M. McNamara, Swarup China, Patricia K. Quinn, Andrew P. Ault, Aaron Kennedy, Paul B. Shepson, Jose D. Fuentes, and Kerri A. Pratt
Atmos. Chem. Phys., 22, 15263–15285, https://doi.org/10.5194/acp-22-15263-2022, https://doi.org/10.5194/acp-22-15263-2022, 2022
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During a spring field campaign in the coastal Arctic, ultrafine particles were enhanced during high wind speeds, and coarse-mode particles were reduced during blowing snow. Calculated periods blowing snow were overpredicted compared to observations. Sea spray aerosols produced by sea ice leads affected the composition of aerosols and snowpack. An improved understanding of aerosol emissions from leads and blowing snow is critical for predicting the future climate of the rapidly warming Arctic.
William F. Swanson, Chris D. Holmes, William R. Simpson, Kaitlyn Confer, Louis Marelle, Jennie L. Thomas, Lyatt Jaeglé, Becky Alexander, Shuting Zhai, Qianjie Chen, Xuan Wang, and Tomás Sherwen
Atmos. Chem. Phys., 22, 14467–14488, https://doi.org/10.5194/acp-22-14467-2022, https://doi.org/10.5194/acp-22-14467-2022, 2022
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Radical bromine molecules are seen at higher concentrations during the Arctic spring. We use the global model GEOS-Chem to test whether snowpack and wind-blown snow sources can explain high bromine concentrations. We run this model for the entire year of 2015 and compare results to observations of bromine from floating platforms on the Arctic Ocean and at Utqiaġvik. We find that the model performs best when both sources are enabled but may overestimate bromine production in summer and fall.
Maximilian Herrmann, Moritz Schöne, Christian Borger, Simon Warnach, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 22, 13495–13526, https://doi.org/10.5194/acp-22-13495-2022, https://doi.org/10.5194/acp-22-13495-2022, 2022
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Ozone depletion events (ODEs) are a common occurrence in the boundary layer during Arctic spring. Ozone is depleted by bromine species in an autocatalytic reaction cycle. Previous modeling studies assumed an infinite bromine source at the ground. An alternative emission scheme is presented in which a finite amount of bromide in the snow is tracked over time. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) is used to study ODEs in the Arctic from February to May 2019.
Gaia Pinardi, Michel Van Roozendael, François Hendrick, Andreas Richter, Pieter Valks, Ramina Alwarda, Kristof Bognar, Udo Frieß, José Granville, Myojeong Gu, Paul Johnston, Cristina Prados-Roman, Richard Querel, Kimberly Strong, Thomas Wagner, Folkard Wittrock, and Margarita Yela Gonzalez
Atmos. Meas. Tech., 15, 3439–3463, https://doi.org/10.5194/amt-15-3439-2022, https://doi.org/10.5194/amt-15-3439-2022, 2022
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We report on the GOME-2A and GOME-2B OClO dataset (2007 to 2016, from the EUMETSAT's AC SAF) validation using data from nine NDACC zenith-scattered-light DOAS (ZSL-DOAS) instruments distributed in both the Arctic and Antarctic. Specific sensitivity tests are performed on the ground-based data to estimate the impact of the different OClO DOAS analysis settings and their typical errors. Good agreement is found for both the inter-annual variability and the overall OClO seasonal behavior.
Tianlang Zhao, Jingqiu Mao, William R. Simpson, Isabelle De Smedt, Lei Zhu, Thomas F. Hanisco, Glenn M. Wolfe, Jason M. St. Clair, Gonzalo González Abad, Caroline R. Nowlan, Barbara Barletta, Simone Meinardi, Donald R. Blake, Eric C. Apel, and Rebecca S. Hornbrook
Atmos. Chem. Phys., 22, 7163–7178, https://doi.org/10.5194/acp-22-7163-2022, https://doi.org/10.5194/acp-22-7163-2022, 2022
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Monitoring formaldehyde (HCHO) can help us understand Arctic vegetation change. Here, we compare satellite data and model and show that Alaska summertime HCHO is largely dominated by a background from methane oxidation during mild wildfire years and is dominated by wildfire (largely from direct emission of fire) during strong fire years. Consequently, it is challenging to use satellite HCHO to study vegetation change in the Arctic region.
M. Dolores Andrés Hernández, Andreas Hilboll, Helmut Ziereis, Eric Förster, Ovid O. Krüger, Katharina Kaiser, Johannes Schneider, Francesca Barnaba, Mihalis Vrekoussis, Jörg Schmidt, Heidi Huntrieser, Anne-Marlene Blechschmidt, Midhun George, Vladyslav Nenakhov, Theresa Harlass, Bruna A. Holanda, Jennifer Wolf, Lisa Eirenschmalz, Marc Krebsbach, Mira L. Pöhlker, Anna B. Kalisz Hedegaard, Linlu Mei, Klaus Pfeilsticker, Yangzhuoran Liu, Ralf Koppmann, Hans Schlager, Birger Bohn, Ulrich Schumann, Andreas Richter, Benjamin Schreiner, Daniel Sauer, Robert Baumann, Mariano Mertens, Patrick Jöckel, Markus Kilian, Greta Stratmann, Christopher Pöhlker, Monica Campanelli, Marco Pandolfi, Michael Sicard, José L. Gómez-Amo, Manuel Pujadas, Katja Bigge, Flora Kluge, Anja Schwarz, Nikos Daskalakis, David Walter, Andreas Zahn, Ulrich Pöschl, Harald Bönisch, Stephan Borrmann, Ulrich Platt, and John P. Burrows
Atmos. Chem. Phys., 22, 5877–5924, https://doi.org/10.5194/acp-22-5877-2022, https://doi.org/10.5194/acp-22-5877-2022, 2022
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EMeRGe provides a unique set of in situ and remote sensing airborne measurements of trace gases and aerosol particles along selected flight routes in the lower troposphere over Europe. The interpretation uses also complementary collocated ground-based and satellite measurements. The collected data help to improve the current understanding of the complex spatial distribution of trace gases and aerosol particles resulting from mixing, transport, and transformation of pollution plumes over Europe.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Jan-Lukas Tirpitz, Udo Frieß, Robert Spurr, and Ulrich Platt
Atmos. Meas. Tech., 15, 2077–2098, https://doi.org/10.5194/amt-15-2077-2022, https://doi.org/10.5194/amt-15-2077-2022, 2022
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MAX-DOAS is a widely used measurement technique for the remote detection of atmospheric aerosol and trace gases. It relies on the analysis of ultra-violet and visible radiation spectra of skylight. To date, information contained in the skylight's polarisation state has not been utilised. On the basis of synthetic data, we carried out sensitivity analyses to assess the potential of polarimetry for MAX-DOAS applications.
Leon Kuhn, Jonas Kuhn, Thomas Wagner, and Ulrich Platt
Atmos. Meas. Tech., 15, 1395–1414, https://doi.org/10.5194/amt-15-1395-2022, https://doi.org/10.5194/amt-15-1395-2022, 2022
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We present a novel instrument for imaging measurements of NO2 with high spatiotemporal resolution based on gas correlation spectroscopy, called the GCS NO2 camera. The instrument works by placing two gas cells (cuvettes) in front of two photosensor arrays, one filled with air and one filled with a high concentration of NO2, acting as a non-dispersive spectral filter. NO2 images are then generated on the basis of the signal ratio of the two channels in the spectral region of 430–445 nm.
Kathryn D. Kulju, Stephen M. McNamara, Qianjie Chen, Hannah S. Kenagy, Jacinta Edebeli, Jose D. Fuentes, Steven B. Bertman, and Kerri A. Pratt
Atmos. Chem. Phys., 22, 2553–2568, https://doi.org/10.5194/acp-22-2553-2022, https://doi.org/10.5194/acp-22-2553-2022, 2022
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N2O5 uptake by chloride-containing surfaces produces ClNO2, which photolyzes, producing NO2 and highly reactive Cl radicals that impact air quality. In the inland urban atmosphere, ClNO2 was elevated during lower air turbulence and over snow-covered ground, from snowpack ClNO2 production. N2O5 and ClNO2 levels were lowest, on average, during rainfall and fog because of scavenging, with N2O5 scavenging by fog droplets likely contributing to observed increased particulate nitrate concentrations.
Jonas Kuhn, Nicole Bobrowski, Thomas Wagner, and Ulrich Platt
Atmos. Meas. Tech., 14, 7873–7892, https://doi.org/10.5194/amt-14-7873-2021, https://doi.org/10.5194/amt-14-7873-2021, 2021
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We propose spectrograph implementations using Fabry–Pérot interferometers for atmospheric trace gas remote sensing. Compared with widely used grating spectrographs, we find substantial light throughput and mobility advantages for high resolving powers. Besides lowering detection limits and increasing the spatial and temporal resolution of many atmospheric trace gas measurements, this approach might enable remote sensing of further important gases such as tropospheric OH radicals.
Jānis Puķīte, Christian Borger, Steffen Dörner, Myojeong Gu, Udo Frieß, Andreas Carlos Meier, Carl-Fredrik Enell, Uwe Raffalski, Andreas Richter, and Thomas Wagner
Atmos. Meas. Tech., 14, 7595–7625, https://doi.org/10.5194/amt-14-7595-2021, https://doi.org/10.5194/amt-14-7595-2021, 2021
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Chlorine dioxide (OClO) is used as an indicator for chlorine activation. We present a new differential optical absorption spectroscopy retrieval algorithm for OClO from measurements of TROPOMI on the Sentinel-5P satellite. To achieve a substantially improved accuracy for the weak absorber OClO, we consider several additional fit parameters accounting for various higher-order spectral effects. The retrieved OClO slant column densities are compared with ground-based zenith sky measurements.
Nicole Jacobs, William R. Simpson, Kelly A. Graham, Christopher Holmes, Frank Hase, Thomas Blumenstock, Qiansi Tu, Matthias Frey, Manvendra K. Dubey, Harrison A. Parker, Debra Wunch, Rigel Kivi, Pauli Heikkinen, Justus Notholt, Christof Petri, and Thorsten Warneke
Atmos. Chem. Phys., 21, 16661–16687, https://doi.org/10.5194/acp-21-16661-2021, https://doi.org/10.5194/acp-21-16661-2021, 2021
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Spatial patterns of carbon dioxide seasonal cycle amplitude and summer drawdown timing derived from the OCO-2 satellite over northern high latitudes agree well with corresponding estimates from two models. The Asian boreal forest is anomalous with the largest amplitude and earliest seasonal drawdown. Modeled land contact tracers suggest that accumulated CO2 exchanges during atmospheric transport play a major role in shaping carbon dioxide seasonality in northern high-latitude regions.
Ulrich Platt, Thomas Wagner, Jonas Kuhn, and Thomas Leisner
Atmos. Meas. Tech., 14, 6867–6883, https://doi.org/10.5194/amt-14-6867-2021, https://doi.org/10.5194/amt-14-6867-2021, 2021
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Absorption spectroscopy of scattered sunlight is extremely useful for the analysis of atmospheric trace gas distributions. A central parameter for the achievable sensitivity of spectroscopic instruments is the light throughput, which can be enhanced in a number of ways. We present new ideas and considerations of how instruments could be optimized. Particular emphasis is on arrays of massively parallel instruments. Such arrays can reduce the size and weight of instruments by orders of magnitude.
Dandan Wei, Hariprasad D. Alwe, Dylan B. Millet, Brandon Bottorff, Michelle Lew, Philip S. Stevens, Joshua D. Shutter, Joshua L. Cox, Frank N. Keutsch, Qianwen Shi, Sarah C. Kavassalis, Jennifer G. Murphy, Krystal T. Vasquez, Hannah M. Allen, Eric Praske, John D. Crounse, Paul O. Wennberg, Paul B. Shepson, Alexander A. T. Bui, Henry W. Wallace, Robert J. Griffin, Nathaniel W. May, Megan Connor, Jonathan H. Slade, Kerri A. Pratt, Ezra C. Wood, Mathew Rollings, Benjamin L. Deming, Daniel C. Anderson, and Allison L. Steiner
Geosci. Model Dev., 14, 6309–6329, https://doi.org/10.5194/gmd-14-6309-2021, https://doi.org/10.5194/gmd-14-6309-2021, 2021
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Over the past decade, understanding of isoprene oxidation has improved, and proper representation of isoprene oxidation and isoprene-derived SOA (iSOA) formation in canopy–chemistry models is now recognized to be important for an accurate understanding of forest–atmosphere exchange. The updated FORCAsT version 2.0 improves the estimation of some isoprene oxidation products and is one of the few canopy models currently capable of simulating SOA formation from monoterpenes and isoprene.
Taylor S. Jones, Jonathan E. Franklin, Jia Chen, Florian Dietrich, Kristian D. Hajny, Johannes C. Paetzold, Adrian Wenzel, Conor Gately, Elaine Gottlieb, Harrison Parker, Manvendra Dubey, Frank Hase, Paul B. Shepson, Levi H. Mielke, and Steven C. Wofsy
Atmos. Chem. Phys., 21, 13131–13147, https://doi.org/10.5194/acp-21-13131-2021, https://doi.org/10.5194/acp-21-13131-2021, 2021
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Methane emissions from leaks in natural gas pipes are often a large source in urban areas, but they are difficult to measure on a city-wide scale. Here we use an array of innovative methane sensors distributed around the city of Indianapolis and a new method of combining their data with an atmospheric model to accurately determine the magnitude of these emissions, which are about 70 % larger than predicted. This method can serve as a framework for cities trying to account for their emissions.
Florian Dinger, Timo Kleinbek, Steffen Dörner, Nicole Bobrowski, Ulrich Platt, Thomas Wagner, Martha Ibarra, and Eveling Espinoza
Atmos. Chem. Phys., 21, 9367–9404, https://doi.org/10.5194/acp-21-9367-2021, https://doi.org/10.5194/acp-21-9367-2021, 2021
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Monitoring magnitude or chemical composition of volcanic gas emissions can help to forecast volcanic eruptions and provides empirical data on the impact of volcanoes on the chemistry in the local and global atmosphere. This study reports and discusses continuous time series of the sulfur and bromine emission fluxes of Masaya from 2014 to 2020. We observed an annual cyclicity in the BrO / SO2 molar ratio, possibly caused by the annual variability in the atmospheric humidity.
Maximilian Herrmann, Holger Sihler, Udo Frieß, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 21, 7611–7638, https://doi.org/10.5194/acp-21-7611-2021, https://doi.org/10.5194/acp-21-7611-2021, 2021
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Time-dependent 3D numerical simulations of tropospheric bromine release and ozone depletion events (ODEs) in the Arctic polar spring of 2009 are compared to observations. Simulation results agree well with the observations at both Utqiaġvik, Alaska, and at Summit, Greenland. In a parameter study, different settings for the bromine release mechanism are evaluated. An enhancement of the bromine release mechanism improves the agreement regarding the occurrence of ODEs with the observations.
Santiago Arellano, Bo Galle, Fredy Apaza, Geoffroy Avard, Charlotte Barrington, Nicole Bobrowski, Claudia Bucarey, Viviana Burbano, Mike Burton, Zoraida Chacón, Gustavo Chigna, Christian Joseph Clarito, Vladimir Conde, Fidel Costa, Maarten De Moor, Hugo Delgado-Granados, Andrea Di Muro, Deborah Fernandez, Gustavo Garzón, Hendra Gunawan, Nia Haerani, Thor H. Hansteen, Silvana Hidalgo, Salvatore Inguaggiato, Mattias Johansson, Christoph Kern, Manne Kihlman, Philippe Kowalski, Pablo Masias, Francisco Montalvo, Joakim Möller, Ulrich Platt, Claudia Rivera, Armando Saballos, Giuseppe Salerno, Benoit Taisne, Freddy Vásconez, Gabriela Velásquez, Fabio Vita, and Mathieu Yalire
Earth Syst. Sci. Data, 13, 1167–1188, https://doi.org/10.5194/essd-13-1167-2021, https://doi.org/10.5194/essd-13-1167-2021, 2021
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This study presents a dataset of volcanic sulfur dioxide (SO2) emissions from 2005–2017. Measurements were obtained by Network for Observation of Volcanic and Atmospheric Change (NOVAC) scanning differential optical absorption spectrometer (ScanDOAS) instruments at 32 volcanoes and processed using a standardized procedure. We show statistics of volcanic gas emissions under a variety of conditions and compare them with averages derived from measurements from space and historical inventories.
Christopher Fuchs, Jonas Kuhn, Nicole Bobrowski, and Ulrich Platt
Atmos. Meas. Tech., 14, 295–307, https://doi.org/10.5194/amt-14-295-2021, https://doi.org/10.5194/amt-14-295-2021, 2021
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We present first measurements of volcanic SO2 emissions with a novel imaging technique for atmospheric trace gases in the UV and visible spectral range. Periodic spectral Fabry–Pérot interferometer transmission features are matched to differential absorption cross sections of the investigated trace gas, yielding high selectivity and sensitivity. The technique can be extended to measure many other trace gases with high spatio-temporal resolution.
Ana C. Morales, Thilina Jayarathne, Jonathan H. Slade, Alexander Laskin, and Paul B. Shepson
Atmos. Chem. Phys., 21, 129–145, https://doi.org/10.5194/acp-21-129-2021, https://doi.org/10.5194/acp-21-129-2021, 2021
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Organic nitrates formed from the oxidation of biogenic volatile organic compounds impact both ozone and particulate matter as they remove nitrogen oxides, but they represent important aerosol precursors. We conducted a series of reaction chamber experiments that quantified the total organic nitrate and secondary organic aerosol yield from the OH-radical-initiated oxidation of ocimene, and also measured their hydrolysis lifetimes in the aqueous phase, as a function of pH.
Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a ground-based remote sensing measurement technique that derives atmospheric aerosol and trace gas vertical profiles from skylight spectra. In this study, consistency and reliability of MAX-DOAS profiles are assessed by applying nine different evaluation algorithms to spectral data recorded during an intercomparison campaign in the Netherlands and by comparing the results to colocated supporting observations.
Gaia Pinardi, Michel Van Roozendael, François Hendrick, Nicolas Theys, Nader Abuhassan, Alkiviadis Bais, Folkert Boersma, Alexander Cede, Jihyo Chong, Sebastian Donner, Theano Drosoglou, Anatoly Dzhola, Henk Eskes, Udo Frieß, José Granville, Jay R. Herman, Robert Holla, Jari Hovila, Hitoshi Irie, Yugo Kanaya, Dimitris Karagkiozidis, Natalia Kouremeti, Jean-Christopher Lambert, Jianzhong Ma, Enno Peters, Ankie Piters, Oleg Postylyakov, Andreas Richter, Julia Remmers, Hisahiro Takashima, Martin Tiefengraber, Pieter Valks, Tim Vlemmix, Thomas Wagner, and Folkard Wittrock
Atmos. Meas. Tech., 13, 6141–6174, https://doi.org/10.5194/amt-13-6141-2020, https://doi.org/10.5194/amt-13-6141-2020, 2020
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We validate several GOME-2 and OMI tropospheric NO2 products with 23 MAX-DOAS and 16 direct sun instruments distributed worldwide, highlighting large horizontal inhomogeneities at several sites affecting the validation results. We propose a method for quantification and correction. We show the application of such correction reduces the satellite underestimation in almost all heterogeneous cases, but a negative bias remains over the MAX-DOAS and direct sun network ensemble for both satellites.
Yang Wang, Arnoud Apituley, Alkiviadis Bais, Steffen Beirle, Nuria Benavent, Alexander Borovski, Ilya Bruchkouski, Ka Lok Chan, Sebastian Donner, Theano Drosoglou, Henning Finkenzeller, Martina M. Friedrich, Udo Frieß, David Garcia-Nieto, Laura Gómez-Martín, François Hendrick, Andreas Hilboll, Junli Jin, Paul Johnston, Theodore K. Koenig, Karin Kreher, Vinod Kumar, Aleksandra Kyuberis, Johannes Lampel, Cheng Liu, Haoran Liu, Jianzhong Ma, Oleg L. Polyansky, Oleg Postylyakov, Richard Querel, Alfonso Saiz-Lopez, Stefan Schmitt, Xin Tian, Jan-Lukas Tirpitz, Michel Van Roozendael, Rainer Volkamer, Zhuoru Wang, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Thomas Wagner
Atmos. Meas. Tech., 13, 5087–5116, https://doi.org/10.5194/amt-13-5087-2020, https://doi.org/10.5194/amt-13-5087-2020, 2020
Nicole Jacobs, William R. Simpson, Debra Wunch, Christopher W. O'Dell, Gregory B. Osterman, Frank Hase, Thomas Blumenstock, Qiansi Tu, Matthias Frey, Manvendra K. Dubey, Harrison A. Parker, Rigel Kivi, and Pauli Heikkinen
Atmos. Meas. Tech., 13, 5033–5063, https://doi.org/10.5194/amt-13-5033-2020, https://doi.org/10.5194/amt-13-5033-2020, 2020
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The boreal forest is the largest seasonally varying biospheric CO2-exchange region on Earth. This region is also undergoing amplified climate warming, leading to concerns about the potential for altered regional carbon exchange. Satellite missions, such as the Orbiting Carbon Observatory-2 (OCO-2) project, can measure CO2 abundance over the boreal forest but need validation for the assurance of accuracy. Therefore, we carried out a ground-based validation of OCO-2 CO2 data at three locations.
Karin Kreher, Michel Van Roozendael, Francois Hendrick, Arnoud Apituley, Ermioni Dimitropoulou, Udo Frieß, Andreas Richter, Thomas Wagner, Johannes Lampel, Nader Abuhassan, Li Ang, Monica Anguas, Alkis Bais, Nuria Benavent, Tim Bösch, Kristof Bognar, Alexander Borovski, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Henning Finkenzeller, David Garcia-Nieto, Clio Gielen, Laura Gómez-Martín, Nan Hao, Bas Henzing, Jay R. Herman, Christian Hermans, Syedul Hoque, Hitoshi Irie, Junli Jin, Paul Johnston, Junaid Khayyam Butt, Fahim Khokhar, Theodore K. Koenig, Jonas Kuhn, Vinod Kumar, Cheng Liu, Jianzhong Ma, Alexis Merlaud, Abhishek K. Mishra, Moritz Müller, Monica Navarro-Comas, Mareike Ostendorf, Andrea Pazmino, Enno Peters, Gaia Pinardi, Manuel Pinharanda, Ankie Piters, Ulrich Platt, Oleg Postylyakov, Cristina Prados-Roman, Olga Puentedura, Richard Querel, Alfonso Saiz-Lopez, Anja Schönhardt, Stefan F. Schreier, André Seyler, Vinayak Sinha, Elena Spinei, Kimberly Strong, Frederik Tack, Xin Tian, Martin Tiefengraber, Jan-Lukas Tirpitz, Jeroen van Gent, Rainer Volkamer, Mihalis Vrekoussis, Shanshan Wang, Zhuoru Wang, Mark Wenig, Folkard Wittrock, Pinhua H. Xie, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 13, 2169–2208, https://doi.org/10.5194/amt-13-2169-2020, https://doi.org/10.5194/amt-13-2169-2020, 2020
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In September 2016, 36 spectrometers from 24 institutes measured a number of key atmospheric pollutants during an instrument intercomparison campaign (CINDI-2) at Cabauw, the Netherlands. Here we report on the outcome of this intercomparison exercise. The three major goals were to characterise the differences between the participating instruments, to define a robust methodology for performance assessment, and to contribute to the harmonisation of the measurement settings and retrieval methods.
Zoë Y. W. Davis, Udo Frieß, Kevin B. Strawbridge, Monika Aggarwaal, Sabour Baray, Elijah G. Schnitzler, Akshay Lobo, Vitali E. Fioletov, Ihab Abboud, Chris A. McLinden, Jim Whiteway, Megan D. Willis, Alex K. Y. Lee, Jeff Brook, Jason Olfert, Jason O'Brien, Ralf Staebler, Hans D. Osthoff, Cristian Mihele, and Robert McLaren
Atmos. Meas. Tech., 13, 1129–1155, https://doi.org/10.5194/amt-13-1129-2020, https://doi.org/10.5194/amt-13-1129-2020, 2020
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Here, we evaluate a ground-based remote sensing method (MAX-DOAS) for measuring total pollutant loading and vertical profiles of pollution in the lower atmosphere by comparing our method to a variety of other measurement methods (lidar, sunphotometer, active DOAS, and aircraft measurements). Measurements were made in the Athabasca Oil Sands Region in Alberta, Canada. The complex dataset provided a rare opportunity to evaluate the performance of MAX-DOAS under varying atmospheric conditions.
Sebastian Donner, Jonas Kuhn, Michel Van Roozendael, Alkiviadis Bais, Steffen Beirle, Tim Bösch, Kristof Bognar, Ilya Bruchkouski, Ka Lok Chan, Steffen Dörner, Theano Drosoglou, Caroline Fayt, Udo Frieß, François Hendrick, Christian Hermans, Junli Jin, Ang Li, Jianzhong Ma, Enno Peters, Gaia Pinardi, Andreas Richter, Stefan F. Schreier, André Seyler, Kimberly Strong, Jan-Lukas Tirpitz, Yang Wang, Pinhua Xie, Jin Xu, Xiaoyi Zhao, and Thomas Wagner
Atmos. Meas. Tech., 13, 685–712, https://doi.org/10.5194/amt-13-685-2020, https://doi.org/10.5194/amt-13-685-2020, 2020
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The calibration of the elevation angles of MAX-DOAS instruments is important for the correct interpretation of such MAX-DOAS measurements. We present and evaluate different methods for the elevation calibration of MAX-DOAS instruments which were applied during the CINDI-2 field campaign.
Ulrich Platt and Jonas Kuhn
Atmos. Meas. Tech., 12, 6259–6272, https://doi.org/10.5194/amt-12-6259-2019, https://doi.org/10.5194/amt-12-6259-2019, 2019
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Measurements of atmospheric trace gases by absorption spectroscopy are frequently supported by recording the amount of trace gas in absorption cells. These are typically small glass (or quartz) cylinders containing the gas to be studied. Here we show in the example of NO2-absorption cells that the effective amount of gas seen by the instrument can deviate greatly from expected values (by orders of magnitude in severe cases). Some suggestions for improving the situation are discussed.
Olivia E. Salmon, Lisa R. Welp, Michael E. Baldwin, Kristian D. Hajny, Brian H. Stirm, and Paul B. Shepson
Atmos. Chem. Phys., 19, 11525–11543, https://doi.org/10.5194/acp-19-11525-2019, https://doi.org/10.5194/acp-19-11525-2019, 2019
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We conducted airborne vertical profile measurements of water vapor stable isotopes to examine how boundary layer, cloud, and mixing processes influence the vertical structure of deuterium excess in the lower troposphere. We discuss reasons our observations are consistent with water vapor isotope theory on some days and not others. Deuterium excess may be useful for understanding complex processes occurring at the top of the boundary layer, including cloud formation, evaporation, and air mixing.
Maximilian Herrmann, Le Cao, Holger Sihler, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 19, 10161–10190, https://doi.org/10.5194/acp-19-10161-2019, https://doi.org/10.5194/acp-19-10161-2019, 2019
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The oscillations of tropospheric ODEs in the Arctic spring is studied numerically. After the termination of an ODE, the reactive bromine is deposited onto aerosols/the snow surface, and the ozone may regenerate. The replenished ozone is available for the next autocatalytic bromine release, leading to the oscillation of an ODE. Its dependence on the NOx mixing ratio, the inversion layer strength, the ambient temperature, the aerosol density, and the solar radiation is investigated.
Jan-Marcus Nasse, Philipp G. Eger, Denis Pöhler, Stefan Schmitt, Udo Frieß, and Ulrich Platt
Atmos. Meas. Tech., 12, 4149–4169, https://doi.org/10.5194/amt-12-4149-2019, https://doi.org/10.5194/amt-12-4149-2019, 2019
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We present several changes to the setup of long-path differential optical absorption spectroscopy (LP-DOAS) instruments, including the application of a laser-driven light source, a modified coupling of the measurement signal between components, improved stray-light suppression, and better signal homogenization measures. These changes reduce detection limits of typical trace-gas species by a factor of 3–4 compared to previous setups and enable automated long-term observations in Antarctica.
Dyre O. Dammann, Leif E. B. Eriksson, Son V. Nghiem, Erin C. Pettit, Nathan T. Kurtz, John G. Sonntag, Thomas E. Busche, Franz J. Meyer, and Andrew R. Mahoney
The Cryosphere, 13, 1861–1875, https://doi.org/10.5194/tc-13-1861-2019, https://doi.org/10.5194/tc-13-1861-2019, 2019
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We validate TanDEM-X interferometry as a tool for deriving iceberg subaerial morphology using Operation IceBridge data. This approach enables a volumetric classification of icebergs, according to volume relevant to iceberg drift and decay, freshwater contribution, and potential impact on structures. We find iceberg volumes to generally match within 7 %. These results suggest that TanDEM-X could pave the way for future interferometric systems of scientific and operational iceberg classification.
Martin Horbanski, Denis Pöhler, Johannes Lampel, and Ulrich Platt
Atmos. Meas. Tech., 12, 3365–3381, https://doi.org/10.5194/amt-12-3365-2019, https://doi.org/10.5194/amt-12-3365-2019, 2019
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ICAD allows a precise in situ measurement of gases like NO2 in a relatively simple and compact setup. The main advantage in comparison to most other optical methods is that it does not require a stable total light intensity. This allows a simpler and mobile instrument setup and additionally it features no observed cross-interferences. We validated the high quality for an ICAD NO2 instrument in different inter-comparisons with a detection limit of 0.02 ppbv.
Florian Dinger, Stefan Bredemeyer, Santiago Arellano, Nicole Bobrowski, Ulrich Platt, and Thomas Wagner
Solid Earth, 10, 725–740, https://doi.org/10.5194/se-10-725-2019, https://doi.org/10.5194/se-10-725-2019, 2019
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Evidence for tidal impacts on volcanism have been gathered by numerous empirical studies. This paper elucidates whether a causal link from the tidal forces to a variation in the volcanic degassing can be traced analytically. We model the response of a simplified magmatic system to the local tidal gravity variations, find that the tide-induced dynamics may significantly alter the bubble coalescence rate, and discuss the consequences for volcanic degassing behaviour.
Thomas Wagner, Steffen Beirle, Nuria Benavent, Tim Bösch, Ka Lok Chan, Sebastian Donner, Steffen Dörner, Caroline Fayt, Udo Frieß, David García-Nieto, Clio Gielen, David González-Bartolome, Laura Gomez, François Hendrick, Bas Henzing, Jun Li Jin, Johannes Lampel, Jianzhong Ma, Kornelia Mies, Mónica Navarro, Enno Peters, Gaia Pinardi, Olga Puentedura, Janis Puķīte, Julia Remmers, Andreas Richter, Alfonso Saiz-Lopez, Reza Shaiganfar, Holger Sihler, Michel Van Roozendael, Yang Wang, and Margarita Yela
Atmos. Meas. Tech., 12, 2745–2817, https://doi.org/10.5194/amt-12-2745-2019, https://doi.org/10.5194/amt-12-2745-2019, 2019
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In this study the consistency between MAX-DOAS measurements and radiative transfer simulations of the atmospheric O4 absorption is investigated. The study is based on measurements (2 selected days during the MADCAT campaign) as well as synthetic spectra. The uncertainties of all relevant aspects (spectral retrieval and radiative transfer simulations) are quantified. For one of the selected days, measurements and simulations do not agree within their uncertainties.
John W. Halfacre, Paul B. Shepson, and Kerri A. Pratt
Atmos. Chem. Phys., 19, 4917–4931, https://doi.org/10.5194/acp-19-4917-2019, https://doi.org/10.5194/acp-19-4917-2019, 2019
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In this study, we found that a chemical called hydroxyl radical can help create chlorine, bromine, and iodine (i.e., halogens) from acidic frozen imitation seawater. Even more halogens are created if we also add ozone. This result helps our understanding of how halogens are released from the frozen Arctic ice and snow into the atmosphere, where they alter the atmosphere's oxidation ability.
Udo Frieß, Steffen Beirle, Leonardo Alvarado Bonilla, Tim Bösch, Martina M. Friedrich, François Hendrick, Ankie Piters, Andreas Richter, Michel van Roozendael, Vladimir V. Rozanov, Elena Spinei, Jan-Lukas Tirpitz, Tim Vlemmix, Thomas Wagner, and Yang Wang
Atmos. Meas. Tech., 12, 2155–2181, https://doi.org/10.5194/amt-12-2155-2019, https://doi.org/10.5194/amt-12-2155-2019, 2019
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a widely used measurement technique for the detection of a variety of atmospheric trace gases. It enables the retrieval of aerosol and trace gas vertical profiles in the atmospheric boundary layer using appropriate retrieval algorithms. In this study, the ability of eight profile retrieval algorithms to reconstruct vertical profiles is assessed on the basis of synthetic measurements.
Shino Toma, Steve Bertman, Christopher Groff, Fulizi Xiong, Paul B. Shepson, Paul Romer, Kaitlin Duffey, Paul Wooldridge, Ronald Cohen, Karsten Baumann, Eric Edgerton, Abigail R. Koss, Joost de Gouw, Allen Goldstein, Weiwei Hu, and Jose L. Jimenez
Atmos. Chem. Phys., 19, 1867–1880, https://doi.org/10.5194/acp-19-1867-2019, https://doi.org/10.5194/acp-19-1867-2019, 2019
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Acyl peroxy nitrates (APN) were measured near the ground in Alabama using GC in summer 2013 to study biosphere–atmosphere interactions. APN were lower than measured in the SE USA over the past 2 decades. Historical data showed APN in 2013 was limited by NOx and production was dominated by biogenic precursors more than in the past. Isoprene-derived MPAN correlated with isoprene hydroxynitrates as NOx-dependent products. MPAN varied with aerosol growth, but not with N-containing particles.
Jonas Kuhn, Ulrich Platt, Nicole Bobrowski, and Thomas Wagner
Atmos. Meas. Tech., 12, 735–747, https://doi.org/10.5194/amt-12-735-2019, https://doi.org/10.5194/amt-12-735-2019, 2019
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We study a novel remote-sensing technique for atmospheric trace gases absorbing in the UV and visible spectral range. Using Fabry–Perot interferometers with a spectral transmission matched to the trace gas's spectral absorption allows for imaging trace gases with high sensitivity and selectivity. The thereby achieved high spatio-temporal resolution enables the study of small-scale and dynamic processes in the atmosphere. We present sample calculations and a proof-of-concept study.
Jessie M. Creamean, Rachel M. Kirpes, Kerri A. Pratt, Nicholas J. Spada, Maximilian Maahn, Gijs de Boer, Russell C. Schnell, and Swarup China
Atmos. Chem. Phys., 18, 18023–18042, https://doi.org/10.5194/acp-18-18023-2018, https://doi.org/10.5194/acp-18-18023-2018, 2018
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Warm-temperature ice nucleating particles (INPs) were observed during a springtime transition period of the melting of frozen surfaces in Northern Alaska. Such INPs were likely biological and from marine and terrestrial (tundra) sources. Influxes of these efficient INPs may have important implications for Arctic cloud ice formation and, consequently, the surface energy budget.
Michael R. Giordano, Lars E. Kalnajs, J. Douglas Goetz, Anita M. Avery, Erin Katz, Nathaniel W. May, Anna Leemon, Claire Mattson, Kerri A. Pratt, and Peter F. DeCarlo
Atmos. Chem. Phys., 18, 16689–16711, https://doi.org/10.5194/acp-18-16689-2018, https://doi.org/10.5194/acp-18-16689-2018, 2018
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The 2ODIAC field campaign was the first deployment of a high-resolution, real-time mass spectrometer to continental Antarctica. Using the real-time aerosol measurements, we investigate how the composition of Antarctic submicron aerosol changes as a function of meteorological parameters such as wind speed. We observe blowing snow and increasing aerosol concentration and changing composition, in particular halogens, as the wind increases beyond 8 m s−1.
Robert G. Ryan, Steve Rhodes, Matthew Tully, Stephen Wilson, Nicholas Jones, Udo Frieß, and Robyn Schofield
Atmos. Chem. Phys., 18, 13969–13985, https://doi.org/10.5194/acp-18-13969-2018, https://doi.org/10.5194/acp-18-13969-2018, 2018
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Nitrous acid (HONO) plays a crucial role in the self-cleansing capacity of the atmosphere but its formation mechanisms and spatial distributions are not well understood. This paper presents spectroscopic measurements of HONO, NO2 and aerosol measurements from Melbourne, Australia. HONO levels are at a maximum in the middle of the day, which is unprecedented for an urban area, and these measurements provide evidence for the existence of a strong ground-based, daytime nitrogen oxide source.
Stephen Broccardo, Klaus-Peter Heue, David Walter, Christian Meyer, Alexander Kokhanovsky, Ronald van der A, Stuart Piketh, Kristy Langerman, and Ulrich Platt
Atmos. Meas. Tech., 11, 2797–2819, https://doi.org/10.5194/amt-11-2797-2018, https://doi.org/10.5194/amt-11-2797-2018, 2018
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Measurements of nitrogen dioxide, known to originate from industrial and automotive combustion sources, have been made from space for two decades. Successive generations of instrument bring improvements in ground-pixel resolution; however features in the atmosphere are known to be smaller than what the satellites can resolve. Measurements of urban and industrial areas using a high-resolution airborne instrument allow the impact of the satellite's relatively low resolution to be evaluated.
David W. T. Griffith, Denis Pöhler, Stefan Schmitt, Samuel Hammer, Sanam N. Vardag, and Ulrich Platt
Atmos. Meas. Tech., 11, 1549–1563, https://doi.org/10.5194/amt-11-1549-2018, https://doi.org/10.5194/amt-11-1549-2018, 2018
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Measurements of atmospheric trace gases over an open path complement in situ measurements by spatial averaging. This paper describes the first open-path measurements of CO2, CH4 and other trace gases by near-infrared Fourier transform spectroscopy. The measurements were made in Heidelberg, Germany, for 4 months in 2014 over a 1.5 km path and compared to in situ measurements made at one end of the path. The experiment setup and methods (and the comparisons of open path to in situ) are described.
Rachel M. Kirpes, Amy L. Bondy, Daniel Bonanno, Ryan C. Moffet, Bingbing Wang, Alexander Laskin, Andrew P. Ault, and Kerri A. Pratt
Atmos. Chem. Phys., 18, 3937–3949, https://doi.org/10.5194/acp-18-3937-2018, https://doi.org/10.5194/acp-18-3937-2018, 2018
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Arctic atmospheric particles have important climate impacts via cloud formation and precipitation, particularly in the wintertime. We show that sulfate, formed during atmospheric transport, is within individual sea spray particles and organic particles measured in the Alaskan Arctic. Greater contributions of combustion emissions were observed when the wind direction came from the Prudhoe Bay oil fields, showing its regional influence.
Matthew J. Gunsch, Nathaniel W. May, Miao Wen, Courtney L. H. Bottenus, Daniel J. Gardner, Timothy M. VanReken, Steven B. Bertman, Philip K. Hopke, Andrew P. Ault, and Kerri A. Pratt
Atmos. Chem. Phys., 18, 3701–3715, https://doi.org/10.5194/acp-18-3701-2018, https://doi.org/10.5194/acp-18-3701-2018, 2018
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During summer 2014, atmospheric particulate matter in northern Michigan was impacted by wildfire emissions under all air mass conditions (Canadian wildfires, US urban, and Canadian forest influences). Biomass burning particles coated with secondary organic aerosol contributed the majority of the submicron aerosol mass. Given increasing wildfires, the impacts of biomass burning on air quality must be assessed, particularly for downwind areas impacted by long-range transport.
Florian Dinger, Nicole Bobrowski, Simon Warnach, Stefan Bredemeyer, Silvana Hidalgo, Santiago Arellano, Bo Galle, Ulrich Platt, and Thomas Wagner
Solid Earth, 9, 247–266, https://doi.org/10.5194/se-9-247-2018, https://doi.org/10.5194/se-9-247-2018, 2018
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We monitored the bromine monoxide-to-sulfur dioxide molar ratio in the effusive gas plume of Cotopaxi volcano in order to gain insight into the geological processes which control the pressure regime of the volcanic system. We observed a conspicuous periodic pattern with a periodicity of about 2 weeks, which significantly correlates with the Earth tidal forcing. Our results support a possible Earth tidal impact on volcanic activity, in particular for the Cotopaxi eruption 2015.
Christoph Kleinschmitt, Olivier Boucher, and Ulrich Platt
Atmos. Chem. Phys., 18, 2769–2786, https://doi.org/10.5194/acp-18-2769-2018, https://doi.org/10.5194/acp-18-2769-2018, 2018
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We use a state-of-the-art stratospheric aerosol model to study geoengineering through stratospheric sulfur injections. We find that the efficiency may decrease more drastically for larger injections than previously estimated and that injections at higher altitude are not more effective. This study may provide additional evidence that this proposed geoengineering technique is still more complicated, probably less effective, and may implicate stronger side effects than initially thought.
Johannes Lampel, Johannes Zielcke, Stefan Schmitt, Denis Pöhler, Udo Frieß, Ulrich Platt, and Thomas Wagner
Atmos. Chem. Phys., 18, 1671–1683, https://doi.org/10.5194/acp-18-1671-2018, https://doi.org/10.5194/acp-18-1671-2018, 2018
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Previous publications on the absorptions of the oxygen dimer O2–O2 (or short: O4) list absorption peaks at 328 nm and 419 nm, for which no spectrally resolved literature cross sections are available. As these absorptions potentially influence the spectral retrieval of various other trace gases, their shape and magnitude need to be quantified. We approximate the absorption peaks at 328 nm and 419 nm by their respective neighboring absorption peaks to estimate their magnitude and peak wavelength.
Ryan D. Cook, Ying-Hsuan Lin, Zhuoyu Peng, Eric Boone, Rosalie K. Chu, James E. Dukett, Matthew J. Gunsch, Wuliang Zhang, Nikola Tolic, Alexander Laskin, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 15167–15180, https://doi.org/10.5194/acp-17-15167-2017, https://doi.org/10.5194/acp-17-15167-2017, 2017
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Reactions occur within water in both atmospheric particles and cloud droplets, yet little is known about the organic compounds in cloud water. In this work, cloud water samples were collected at Whiteface Mountain, New York, and analyzed using ultra-high-resolution mass spectrometry to investigate the molecular composition of the dissolved organic compounds. The results focus on changes in cloud water composition with air mass origin – influences of forest, urban, and wildfire emissions.
Johannes Lampel, Yang Wang, Andreas Hilboll, Steffen Beirle, Holger Sihler, Janis Puķīte, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech., 10, 4819–4831, https://doi.org/10.5194/amt-10-4819-2017, https://doi.org/10.5194/amt-10-4819-2017, 2017
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Experience of differential atmospheric absorption spectroscopy (DOAS) shows that a spectral shift between measurement and reference spectrum is frequently required in order to achieve optimal fit results. The shift is often attributed to temporal instabilities of the instrument but implicitly solved the problem of the tilt effect discussed in this paper. The tilt effect results from the finite resolution of the measurements and amounts to 2 pm for the example data set.
Matthew J. Gunsch, Rachel M. Kirpes, Katheryn R. Kolesar, Tate E. Barrett, Swarup China, Rebecca J. Sheesley, Alexander Laskin, Alfred Wiedensohler, Thomas Tuch, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 10879–10892, https://doi.org/10.5194/acp-17-10879-2017, https://doi.org/10.5194/acp-17-10879-2017, 2017
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Arctic sea ice loss is leading to increasing petroleum extraction and shipping. It is necessary to identify emissions from these activities for improved Arctic air quality and climate assessment. Atmospheric particles were measured from August to September 2015 in Utqiaġvik, AK. For periods influenced by Prudhoe Bay, significant influence associated with combustion emissions was observed, compared to fresh sea spray influence during Arctic Ocean periods.
Christoph Kleinschmitt, Olivier Boucher, Slimane Bekki, François Lott, and Ulrich Platt
Geosci. Model Dev., 10, 3359–3378, https://doi.org/10.5194/gmd-10-3359-2017, https://doi.org/10.5194/gmd-10-3359-2017, 2017
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Stratospheric aerosols play an important role in the climate system by affecting the Earth's radiative budget. In this article we present the newly developed LMDZ-S3A model and assess its performance against observations in periods of low and high aerosol loading. The model may serve as a tool to study the climate impacts of volcanic eruptions, as well as the deliberate injection of aerosols into the stratosphere, which has been proposed as a method of geoengineering to abate global warming.
William R. Simpson, Peter K. Peterson, Udo Frieß, Holger Sihler, Johannes Lampel, Ulrich Platt, Chris Moore, Kerri Pratt, Paul Shepson, John Halfacre, and Son V. Nghiem
Atmos. Chem. Phys., 17, 9291–9309, https://doi.org/10.5194/acp-17-9291-2017, https://doi.org/10.5194/acp-17-9291-2017, 2017
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We investigated Arctic atmospheric bromine chemistry during March–April 2012 to improve understanding of the role of sea ice and cracks in sea ice (leads) in this phenomenon. We find that leads vertically redistribute reactive bromine but that open/re-freezing leads are not major direct reactive halogen sources. Surface ozone depletion affects the vertical distribution and amount of reactive halogens, and aerosol particles are necessary but not sufficient to maintain reactive bromine aloft.
Jonathan H. Slade, Chloé de Perre, Linda Lee, and Paul B. Shepson
Atmos. Chem. Phys., 17, 8635–8650, https://doi.org/10.5194/acp-17-8635-2017, https://doi.org/10.5194/acp-17-8635-2017, 2017
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This study provides new insight into the oxidation of polyolefinic monoterpenes and the dependence of the formation and yields of organic nitrates (ON) and secondary organic aerosol (SOA) on hydrocarbon structure. Here we have elucidated the ON, hydroxy nitrate, and SOA yields from the NO3 oxidation of γ-terpinene, a potentially relevant nighttime ON precursor in the Midwestern US. The results advance our understanding of the chemistry that influences NOx, O3 production, and aerosol formation.
Peter K. Peterson, Denis Pöhler, Holger Sihler, Johannes Zielcke, Stephan General, Udo Frieß, Ulrich Platt, William R. Simpson, Son V. Nghiem, Paul B. Shepson, Brian H. Stirm, Suresh Dhaniyala, Thomas Wagner, Dana R. Caulton, Jose D. Fuentes, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 7567–7579, https://doi.org/10.5194/acp-17-7567-2017, https://doi.org/10.5194/acp-17-7567-2017, 2017
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High-spatial-resolution aircraft measurements in the Arctic showed the sustained transport of reactive bromine in a lofted layer via heterogeneous reactions on aerosol particles. This process provides an explanation for free tropospheric reactive bromine and the significant spatial extent of satellite-observed bromine monoxide. The knowledge gained herein improves our understanding of the fate and transport of atmospheric pollutants in the Arctic.
Angelika Klein, Peter Lübcke, Nicole Bobrowski, Jonas Kuhn, and Ulrich Platt
Atmos. Meas. Tech., 10, 979–987, https://doi.org/10.5194/amt-10-979-2017, https://doi.org/10.5194/amt-10-979-2017, 2017
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While measuring sulfur dioxide fluxes in volcanic plumes with a UV-sensitive camera, the wind direction can influence the retrieved fluxes. If the volcanic plume is tilted in the field of view of the camera, it can lead to over- or underestimations of the determined fluxes. This paper presents a method to deal with such a circumstance. Additionally, it provides the possibility to determine the wind direction of the plume directly from the image time series themselves.
Chelsea R. Thompson, Paul B. Shepson, Jin Liao, L. Greg Huey, Chris Cantrell, Frank Flocke, and John Orlando
Atmos. Chem. Phys., 17, 3401–3421, https://doi.org/10.5194/acp-17-3401-2017, https://doi.org/10.5194/acp-17-3401-2017, 2017
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The generally accepted mechanism leading to ozone depletion events in the Arctic assumes efficient gas-phase recycling of bromine atoms, such that the rate of ozone depletion has often been estimated as the rate that Br atoms regenerate through gas-phase BrO + BrO and BrO + ClO reactions. Using a large suite of data from the OASIS2009 campaign, our modeling results show that the gas-phase regeneration of Br is less efficient than expected and that heterogeneous recycling on surfaces is critical.
Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Herrmann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert McLaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, and Rahul A. Zaveri
Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, https://doi.org/10.5194/acp-17-2103-2017, 2017
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Oxidation of biogenic volatile organic compounds by NO3 is an important interaction between anthropogenic
and natural emissions. This review results from a June 2015 workshop and includes the recent literature
on kinetics, mechanisms, organic aerosol yields, and heterogeneous chemistry; advances in analytical
instrumentation; the current state NO3-BVOC chemistry in atmospheric models; and critical needs for
future research in modeling, field observations, and laboratory studies.
Johannes Lampel, Denis Pöhler, Oleg L. Polyansky, Aleksandra A. Kyuberis, Nikolai F. Zobov, Jonathan Tennyson, Lorenzo Lodi, Udo Frieß, Yang Wang, Steffen Beirle, Ulrich Platt, and Thomas Wagner
Atmos. Chem. Phys., 17, 1271–1295, https://doi.org/10.5194/acp-17-1271-2017, https://doi.org/10.5194/acp-17-1271-2017, 2017
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Water vapour is known to absorb radiation from the microwave region to the blue part of the visible spectrum.
Ab initio approaches to model individual absorption lines of the gaseous water molecule predict absorption lines
until its dissociation limit at 243 nm.
We present first evidence of water vapour absorption near 363 nm from field measurements using data
from multi-axis differential optical absorption spectroscopy (MAX-DOAS) and long-path (LP)-DOAS measurements.
Joel D. Rindelaub, Carlos H. Borca, Matthew A. Hostetler, Jonathan H. Slade, Mark A. Lipton, Lyudmila V. Slipchenko, and Paul B. Shepson
Atmos. Chem. Phys., 16, 15425–15432, https://doi.org/10.5194/acp-16-15425-2016, https://doi.org/10.5194/acp-16-15425-2016, 2016
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This study provides new insight into the hydrolysis reaction mechanism, which was elucidated for atmospherically relevant organic nitrates using kinetic measurements, product identification, and theoretical calculations. The results help broaden our knowledge of the organic chemistry that impacts the fate of NOx, ozone production, aerosol phase processing, and aerosol composition.
Peter Lübcke, Johannes Lampel, Santiago Arellano, Nicole Bobrowski, Florian Dinger, Bo Galle, Gustavo Garzón, Silvana Hidalgo, Zoraida Chacón Ortiz, Leif Vogel, Simon Warnach, and Ulrich Platt
Atmos. Meas. Tech., 9, 5677–5698, https://doi.org/10.5194/amt-9-5677-2016, https://doi.org/10.5194/amt-9-5677-2016, 2016
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We evaluated spectra from a scanning spectrometer network for the monitoring of volcanic gas emissions using a modelled background spectrum. Statistical methods were applied in order to improve the quality of the spectroscopic evaluation. We used this technique to assess the robustness of standard retrievals at two volcanos: Nevado del Ruiz (Colombia) and Tungurahua (Ecuador).
Christoph Hörmann, Holger Sihler, Steffen Beirle, Marloes Penning de Vries, Ulrich Platt, and Thomas Wagner
Atmos. Chem. Phys., 16, 13015–13034, https://doi.org/10.5194/acp-16-13015-2016, https://doi.org/10.5194/acp-16-13015-2016, 2016
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We present 10 years of bromine monoxide (BrO) satellite observations by the Ozone Monitoring Instrument (OMI) over the Rann of Kutch salt marsh. The measurements reveal a typical seasonal cycle of BrO with maximum concentrations during April/May. The results indicate that the Rann of Kutch is probably one of the strongest natural point sources of reactive bromine compounds outside the polar regions and is thought to have a significant impact on local and regional ozone chemistry.
Shanshan Wang, Carlos A. Cuevas, Udo Frieß, and Alfonso Saiz-Lopez
Atmos. Meas. Tech., 9, 5089–5101, https://doi.org/10.5194/amt-9-5089-2016, https://doi.org/10.5194/amt-9-5089-2016, 2016
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements were performed in the urban environment of Madrid, Spain, where Sahara dust intrusion sometimes occurs. The study shows a high performances in the retrieval of aerosol optical depth, the surface extinction coefficient and an elevated layer during dust episodes, validated by AERONET in situ and modeling data. It is essential to capture the extinction properties of both local aerosol and Saharan dust.
Helmke Hepach, Birgit Quack, Susann Tegtmeier, Anja Engel, Astrid Bracher, Steffen Fuhlbrügge, Luisa Galgani, Elliot L. Atlas, Johannes Lampel, Udo Frieß, and Kirstin Krüger
Atmos. Chem. Phys., 16, 12219–12237, https://doi.org/10.5194/acp-16-12219-2016, https://doi.org/10.5194/acp-16-12219-2016, 2016
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We present surface seawater measurements of bromo- and iodocarbons, which are involved in numerous atmospheric processes such as tropospheric and stratospheric ozone chemistry, from the highly productive Peruvian upwelling. By combining trace gas measurements, characterization of organic matter and phytoplankton species, and tropospheric modelling, we show that large amounts of iodocarbons produced from the pool of organic matter may contribute strongly to local tropospheric iodine loading.
Nathaniel W. May, Jessica L. Axson, Alexa Watson, Kerri A. Pratt, and Andrew P. Ault
Atmos. Meas. Tech., 9, 4311–4325, https://doi.org/10.5194/amt-9-4311-2016, https://doi.org/10.5194/amt-9-4311-2016, 2016
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Aerosols are generated every time a wave breaks, as bubbles are formed that rise to the surface and burst. A great deal is known about sea spray aerosol from oceans, but very little is known about particles formed from freshwater, such as lakes and rivers. This study determines how "lake spray aerosol" is formed, which leads to distinctly different sizes and chemical composition from sea spray aerosol. These differences impact climate, weather, and human health near bodies of freshwater.
Erna Frins, Reza Shaiganfar, Ulrich Platt, and Thomas Wagner
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2016-255, https://doi.org/10.5194/amt-2016-255, 2016
Revised manuscript has not been submitted
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Standard methods like in-situ measurements can hardly register NOx (= NO + NO2) emissions from aircrafts during take-off, when engines run at high load and thus an important amount of fuel is consumed and most of the harmful emissions are produced . The goal of this work is to show that it is possible to measure aircraft emissions generated during take-off (and initial part of the climb) by a remote spectroscopic method like automobile – based – Differential Optical Absorption Spectroscopy (DOAS).
U. Frieß, H. Klein Baltink, S. Beirle, K. Clémer, F. Hendrick, B. Henzing, H. Irie, G. de Leeuw, A. Li, M. M. Moerman, M. van Roozendael, R. Shaiganfar, T. Wagner, Y. Wang, P. Xie, S. Yilmaz, and P. Zieger
Atmos. Meas. Tech., 9, 3205–3222, https://doi.org/10.5194/amt-9-3205-2016, https://doi.org/10.5194/amt-9-3205-2016, 2016
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This article describes the first direct comparison of aerosol extinction profiles from Multi-Axis DOAS measurements of the oxygen collision complex using five different retrieval algorithms. A comparison of the retrieved profiles with co-located aerosol measurements shows good agreement with respect to profile shape and aerosol optical thickness. This study shows that MAX-DOAS is a simple, versatile and cost-effective method for the measurement of aerosol properties in the lower troposphere.
Le Cao, Ulrich Platt, Chenggang Wang, Nianwen Cao, and Qing Qin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-553, https://doi.org/10.5194/acp-2016-553, 2016
Revised manuscript has not been submitted
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A snowpack module which represents the mass transfer between the ambient air and the snowpack is implemented in a box model, aiming to clarify the influences of the snowpack on the ozone depletion events (ODEs) and the associated bromine explosion in the springtime of Arctic. The size of snow grains, volume fraction of the liquid-like layer (LLL), and the rate of the mass exchange between the snow interstitial air and the snow particles are shown to be critical parameters.
Luping Su, Edward G. Patton, Jordi Vilà-Guerau de Arellano, Alex B. Guenther, Lisa Kaser, Bin Yuan, Fulizi Xiong, Paul B. Shepson, Li Zhang, David O. Miller, William H. Brune, Karsten Baumann, Eric Edgerton, Andrew Weinheimer, Pawel K. Misztal, Jeong-Hoo Park, Allen H. Goldstein, Kate M. Skog, Frank N. Keutsch, and John E. Mak
Atmos. Chem. Phys., 16, 7725–7741, https://doi.org/10.5194/acp-16-7725-2016, https://doi.org/10.5194/acp-16-7725-2016, 2016
Jenny A. Fisher, Daniel J. Jacob, Katherine R. Travis, Patrick S. Kim, Eloise A. Marais, Christopher Chan Miller, Karen Yu, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Jingqiu Mao, Paul O. Wennberg, John D. Crounse, Alex P. Teng, Tran B. Nguyen, Jason M. St. Clair, Ronald C. Cohen, Paul Romer, Benjamin A. Nault, Paul J. Wooldridge, Jose L. Jimenez, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Paul B. Shepson, Fulizi Xiong, Donald R. Blake, Allen H. Goldstein, Pawel K. Misztal, Thomas F. Hanisco, Glenn M. Wolfe, Thomas B. Ryerson, Armin Wisthaler, and Tomas Mikoviny
Atmos. Chem. Phys., 16, 5969–5991, https://doi.org/10.5194/acp-16-5969-2016, https://doi.org/10.5194/acp-16-5969-2016, 2016
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We use new airborne and ground-based observations from two summer 2013 campaigns in the southeastern US, interpreted with a chemical transport model, to understand the impact of isoprene and monoterpene chemistry on the atmospheric NOx budget via production of organic nitrates (RONO2). We find that a diversity of species contribute to observed RONO2. Our work implies that the NOx sink to RONO2 production is only sensitive to NOx emissions in regions where they are already low.
Fulizi Xiong, Carlos H. Borca, Lyudmila V. Slipchenko, and Paul B. Shepson
Atmos. Chem. Phys., 16, 5595–5610, https://doi.org/10.5194/acp-16-5595-2016, https://doi.org/10.5194/acp-16-5595-2016, 2016
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Here we report on a detailed study of the photochemistry and fate of a nitrooxy enal that is produced from the reaction of NO3 with isoprene. We synthesized the 4,1-nitrooxy enal, purified it, and measured the O3 and OH reaction rate constants, and determined the atmospheric photodissociation rate constant for specified radiation conditions. The determined fast photolysis rate and high reactivity toward OH lead to a lifetime of less than 1 hour, with photolysis being a dominant daytime sink.
N. Sobanski, M. J. Tang, J. Thieser, G. Schuster, D. Pöhler, H. Fischer, W. Song, C. Sauvage, J. Williams, J. Fachinger, F. Berkes, P. Hoor, U. Platt, J. Lelieveld, and J. N. Crowley
Atmos. Chem. Phys., 16, 4867–4883, https://doi.org/10.5194/acp-16-4867-2016, https://doi.org/10.5194/acp-16-4867-2016, 2016
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The nitrate radical (NO3) is an important nocturnal oxidant. By measuring NO3, its precursors (nitrogen dioxide and ozone) and several trace gases with which it reacts, we examined the chemical and meteorological factors influencing the lifetime of NO3 at a semi-rural mountain site. Unexpectedly long lifetimes, approaching 1 h, were observed on several nights and were associated with a low-lying residual layer. We discuss the role of other reactions that convert NO2 to NO3.
J. Lampel, D. Pöhler, J. Tschritter, U. Frieß, and U. Platt
Atmos. Meas. Tech., 8, 4329–4346, https://doi.org/10.5194/amt-8-4329-2015, https://doi.org/10.5194/amt-8-4329-2015, 2015
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In recent updates of the HITRAN water vapour H2O spectroscopic compilation covering the blue spectral region (here 394–-480 nm) significant changes for the absorption bands at 416 and 426 nm were reported. In order to investigate the consistency of the different cross sections calculated from these compilations, H2O vapour column density ratios for different spectral intervals were retrieved from long-path and multi-axis differential optical absorption spectroscopy measurements.
F. Xiong, K. M. McAvey, K. A. Pratt, C. J. Groff, M. A. Hostetler, M. A. Lipton, T. K. Starn, J. V. Seeley, S. B. Bertman, A. P. Teng, J. D. Crounse, T. B. Nguyen, P. O. Wennberg, P. K. Misztal, A. H. Goldstein, A. B. Guenther, A. R. Koss, K. F. Olson, J. A. de Gouw, K. Baumann, E. S. Edgerton, P. A. Feiner, L. Zhang, D. O. Miller, W. H. Brune, and P. B. Shepson
Atmos. Chem. Phys., 15, 11257–11272, https://doi.org/10.5194/acp-15-11257-2015, https://doi.org/10.5194/acp-15-11257-2015, 2015
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Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.
K. D. Custard, C. R. Thompson, K. A. Pratt, P B. Shepson, J. Liao, L. G. Huey, J. J. Orlando, A. J. Weinheimer, E. Apel, S. R. Hall, F. Flocke, L. Mauldin, R. S. Hornbrook, D. Pöhler, S. General, J. Zielcke, W. R. Simpson, U. Platt, A. Fried, P. Weibring, B. C. Sive, K. Ullmann, C. Cantrell, D. J. Knapp, and D. D. Montzka
Atmos. Chem. Phys., 15, 10799–10809, https://doi.org/10.5194/acp-15-10799-2015, https://doi.org/10.5194/acp-15-10799-2015, 2015
J. Lampel, U. Frieß, and U. Platt
Atmos. Meas. Tech., 8, 3767–3787, https://doi.org/10.5194/amt-8-3767-2015, https://doi.org/10.5194/amt-8-3767-2015, 2015
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In remote sensing applications, such as differential optical absorption spectroscopy (DOAS), atmospheric scattering processes need to be considered. Inelastic scattering on air molecules can lead to filling-in of absorption lines. The contribution of rotational Raman scattering is typically corrected for. The magnitude of vibrational Raman scattering (VRS) is known from theory and agrees with our first DOAS observations of this effect. Its impact on trace-gas measurements of NO2 is discussed.
C. R. Thompson, P. B. Shepson, J. Liao, L. G. Huey, E. C. Apel, C. A. Cantrell, F. Flocke, J. Orlando, A. Fried, S. R. Hall, R. S. Hornbrook, D. J. Knapp, R. L. Mauldin III, D. D. Montzka, B. C. Sive, K. Ullmann, P. Weibring, and A. Weinheimer
Atmos. Chem. Phys., 15, 9651–9679, https://doi.org/10.5194/acp-15-9651-2015, https://doi.org/10.5194/acp-15-9651-2015, 2015
J. Gliß, N. Bobrowski, L. Vogel, D. Pöhler, and U. Platt
Atmos. Chem. Phys., 15, 5659–5681, https://doi.org/10.5194/acp-15-5659-2015, https://doi.org/10.5194/acp-15-5659-2015, 2015
J. Kuhn, N. Bobrowski, P. Lübcke, L. Vogel, and U. Platt
Atmos. Meas. Tech., 7, 3705–3715, https://doi.org/10.5194/amt-7-3705-2014, https://doi.org/10.5194/amt-7-3705-2014, 2014
S. General, D. Pöhler, H. Sihler, N. Bobrowski, U. Frieß, J. Zielcke, M. Horbanski, P. B. Shepson, B. H. Stirm, W. R. Simpson, K. Weber, C. Fischer, and U. Platt
Atmos. Meas. Tech., 7, 3459–3485, https://doi.org/10.5194/amt-7-3459-2014, https://doi.org/10.5194/amt-7-3459-2014, 2014
M. O. L. Cambaliza, P. B. Shepson, D. R. Caulton, B. Stirm, D. Samarov, K. R. Gurney, J. Turnbull, K. J. Davis, A. Possolo, A. Karion, C. Sweeney, B. Moser, A. Hendricks, T. Lauvaux, K. Mays, J. Whetstone, J. Huang, I. Razlivanov, N. L. Miles, and S. J. Richardson
Atmos. Chem. Phys., 14, 9029–9050, https://doi.org/10.5194/acp-14-9029-2014, https://doi.org/10.5194/acp-14-9029-2014, 2014
P. L. Joyce, R. von Glasow, and W. R. Simpson
Atmos. Chem. Phys., 14, 7601–7616, https://doi.org/10.5194/acp-14-7601-2014, https://doi.org/10.5194/acp-14-7601-2014, 2014
K.-P. Heue, H. Riede, D. Walter, C. A. M. Brenninkmeijer, T. Wagner, U. Frieß, U. Platt, A. Zahn, G. Stratmann, and H. Ziereis
Atmos. Chem. Phys., 14, 6621–6642, https://doi.org/10.5194/acp-14-6621-2014, https://doi.org/10.5194/acp-14-6621-2014, 2014
P. Lübcke, N. Bobrowski, S. Arellano, B. Galle, G. Garzón, L. Vogel, and U. Platt
Solid Earth, 5, 409–424, https://doi.org/10.5194/se-5-409-2014, https://doi.org/10.5194/se-5-409-2014, 2014
J. W. Halfacre, T. N. Knepp, P. B. Shepson, C. R. Thompson, K. A. Pratt, B. Li, P. K. Peterson, S. J. Walsh, W. R. Simpson, P. A. Matrai, J. W. Bottenheim, S. Netcheva, D. K. Perovich, and A. Richter
Atmos. Chem. Phys., 14, 4875–4894, https://doi.org/10.5194/acp-14-4875-2014, https://doi.org/10.5194/acp-14-4875-2014, 2014
T. Wagner, A. Apituley, S. Beirle, S. Dörner, U. Friess, J. Remmers, and R. Shaiganfar
Atmos. Meas. Tech., 7, 1289–1320, https://doi.org/10.5194/amt-7-1289-2014, https://doi.org/10.5194/amt-7-1289-2014, 2014
S. Bleicher, J. C. Buxmann, R. Sander, T. P. Riedel, J. A. Thornton, U. Platt, and C. Zetzsch
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-10135-2014, https://doi.org/10.5194/acpd-14-10135-2014, 2014
Revised manuscript has not been submitted
L. Cao, H. Sihler, U. Platt, and E. Gutheil
Atmos. Chem. Phys., 14, 3771–3787, https://doi.org/10.5194/acp-14-3771-2014, https://doi.org/10.5194/acp-14-3771-2014, 2014
C. Liu, S. Beirle, T. Butler, P. Hoor, C. Frankenberg, P. Jöckel, M. Penning de Vries, U. Platt, A. Pozzer, M. G. Lawrence, J. Lelieveld, H. Tost, and T. Wagner
Atmos. Chem. Phys., 14, 1717–1732, https://doi.org/10.5194/acp-14-1717-2014, https://doi.org/10.5194/acp-14-1717-2014, 2014
J. D. Rindelaub, K. M. McAvey, and P. B. Shepson
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-3301-2014, https://doi.org/10.5194/acpd-14-3301-2014, 2014
Revised manuscript not accepted
D. J. Hoch, J. Buxmann, H. Sihler, D. Pöhler, C. Zetzsch, and U. Platt
Atmos. Meas. Tech., 7, 199–214, https://doi.org/10.5194/amt-7-199-2014, https://doi.org/10.5194/amt-7-199-2014, 2014
R. M. Varma, S. M. Ball, T. Brauers, H.-P. Dorn, U. Heitmann, R. L. Jones, U. Platt, D. Pöhler, A. A. Ruth, A. J. L. Shillings, J. Thieser, A. Wahner, and D. S. Venables
Atmos. Meas. Tech., 6, 3115–3130, https://doi.org/10.5194/amt-6-3115-2013, https://doi.org/10.5194/amt-6-3115-2013, 2013
A. Steffen, J. Bottenheim, A. Cole, T. A. Douglas, R. Ebinghaus, U. Friess, S. Netcheva, S. Nghiem, H. Sihler, and R. Staebler
Atmos. Chem. Phys., 13, 7007–7021, https://doi.org/10.5194/acp-13-7007-2013, https://doi.org/10.5194/acp-13-7007-2013, 2013
S. M. Griffith, R. F. Hansen, S. Dusanter, P. S. Stevens, M. Alaghmand, S. B. Bertman, M. A. Carroll, M. Erickson, M. Galloway, N. Grossberg, J. Hottle, J. Hou, B. T. Jobson, A. Kammrath, F. N. Keutsch, B. L. Lefer, L. H. Mielke, A. O'Brien, P. B. Shepson, M. Thurlow, W. Wallace, N. Zhang, and X. L. Zhou
Atmos. Chem. Phys., 13, 5403–5423, https://doi.org/10.5194/acp-13-5403-2013, https://doi.org/10.5194/acp-13-5403-2013, 2013
C. Hörmann, H. Sihler, N. Bobrowski, S. Beirle, M. Penning de Vries, U. Platt, and T. Wagner
Atmos. Chem. Phys., 13, 4749–4781, https://doi.org/10.5194/acp-13-4749-2013, https://doi.org/10.5194/acp-13-4749-2013, 2013
H.-P. Dorn, R. L. Apodaca, S. M. Ball, T. Brauers, S. S. Brown, J. N. Crowley, W. P. Dubé, H. Fuchs, R. Häseler, U. Heitmann, R. L. Jones, A. Kiendler-Scharr, I. Labazan, J. M. Langridge, J. Meinen, T. F. Mentel, U. Platt, D. Pöhler, F. Rohrer, A. A. Ruth, E. Schlosser, G. Schuster, A. J. L. Shillings, W. R. Simpson, J. Thieser, R. Tillmann, R. Varma, D. S. Venables, and A. Wahner
Atmos. Meas. Tech., 6, 1111–1140, https://doi.org/10.5194/amt-6-1111-2013, https://doi.org/10.5194/amt-6-1111-2013, 2013
K. Großmann, U. Frieß, E. Peters, F. Wittrock, J. Lampel, S. Yilmaz, J. Tschritter, R. Sommariva, R. von Glasow, B. Quack, K. Krüger, K. Pfeilsticker, and U. Platt
Atmos. Chem. Phys., 13, 3363–3378, https://doi.org/10.5194/acp-13-3363-2013, https://doi.org/10.5194/acp-13-3363-2013, 2013
P. Lübcke, N. Bobrowski, S. Illing, C. Kern, J. M. Alvarez Nieves, L. Vogel, J. Zielcke, H. Delgado Granados, and U. Platt
Atmos. Meas. Tech., 6, 677–696, https://doi.org/10.5194/amt-6-677-2013, https://doi.org/10.5194/amt-6-677-2013, 2013
G. Pinardi, M. Van Roozendael, N. Abuhassan, C. Adams, A. Cede, K. Clémer, C. Fayt, U. Frieß, M. Gil, J. Herman, C. Hermans, F. Hendrick, H. Irie, A. Merlaud, M. Navarro Comas, E. Peters, A. J. M. Piters, O. Puentedura, A. Richter, A. Schönhardt, R. Shaiganfar, E. Spinei, K. Strong, H. Takashima, M. Vrekoussis, T. Wagner, F. Wittrock, and S. Yilmaz
Atmos. Meas. Tech., 6, 167–185, https://doi.org/10.5194/amt-6-167-2013, https://doi.org/10.5194/amt-6-167-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
The variations in volatile organic compounds based on the policy change for Omicron in the traffic hub of Zhengzhou
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Measurement report: Long-term measurements of surface ozone and trends in semi-natural sub-Saharan African ecosystems
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant
Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis
Understanding summertime peroxyacetyl nitrate (PAN) formation and its relation to aerosol pollution: Insights from high-resolution measurements and modeling
Measurement report: Elevated atmospheric ammonia may promote particle pH and HONO formation – insights from the COVID-19 pandemic
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Elevated oxidized mercury in the free troposphere: analytical advances and application at a remote continental mountaintop site
Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area
Real-world emission characteristics of VOCs from typical cargo ships and their potential contributions to secondary organic aerosol and O3 under low-sulfur fuel policies
NO3 reactivity during a summer period in a temperate forest below and above the canopy
The role of oceanic ventilation and terrestrial outflow in atmospheric non-methane hydrocarbons over the Chinese marginal seas
Concentration and source changes of nitrous acid (HONO) during the COVID-19 lockdown in Beijing
Characteristics and sources of nonmethane volatile organic compounds (NMVOCs) and O3–NOx–NMVOC relationships in Zhengzhou, China
Seasonal Air Concentration Variability, Gas/Particle Partitioning, Precipitation Scavenging, and Air-Water Equilibrium of Organophosphate Esters in Southern Canada
Exploring the variations in ambient BTEX in urban Europe and its environmental health implications
Cloud processing of DMS oxidation products limits SO2 and OCS production in the Eastern North Atlantic marine boundary layer
Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements
Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany
Exploring the Crucial Role of Atmospheric Carbonyl Compounds in Regional Ozone heavy Pollution: Insights from Intensive Field Observations and Observation-based modelling in the Chengdu Plain Urban Agglomeration, China
Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry
Opinion: Strengthening research in the Global South – atmospheric science opportunities in South America and Africa
Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea
Contribution of cooking emissions to the urban volatile organic compounds in Las Vegas, NV
Reanalysis of NOAA H2 observations: implications for the H2 budget
A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation
Diurnal, seasonal, and interannual variations in δ(18O) of atmospheric O2 and its application to evaluate changes in oxygen, carbon, and water cycles
Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion)
Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater
Comment on “Transport of substantial stratospheric ozone to the surface by a dying typhoon and shallow convection” by Chen et al. (2022)
Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction
Individual coal mine methane emissions constrained by eddy covariance measurements: low bias and missing sources
Measurement report: Observations of ground-level ozone concentration gradients perpendicular to the Lake Ontario shoreline
Measurement report: The Palau Atmospheric Observatory and its ozonesonde record – continuous monitoring of tropospheric composition and dynamics in the tropical western Pacific
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
Atmos. Chem. Phys., 24, 14191–14208, https://doi.org/10.5194/acp-24-14191-2024, https://doi.org/10.5194/acp-24-14191-2024, 2024
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Comprehensive observations of HONO and NOx fluxes were conducted over paddy fields in the Huaihe River Basin. Consecutive peaks in HONO and NO fluxes suggest a potentially enhanced release of HONO and NO due to soil tillage, whereas waterlogged soil may inhibit microbial nitrification processes following irrigation. Notably, biological processes and light-driven NO2 reactions at the surface may serve as sources of HONO and influence the local HONO budget during rotary tillage.
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yuyang Li, Yi Yuan, Junchen Guo, Yiqi Zhao, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
Atmos. Chem. Phys., 24, 13793–13810, https://doi.org/10.5194/acp-24-13793-2024, https://doi.org/10.5194/acp-24-13793-2024, 2024
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Online Vocus-PTR measurements show the compositions and seasonal variations in organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various species at a level of sub-parts per trillion (ppt) and organics with multiple oxygens (≥ 3) were observed. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens, while, in other seasons, the variations in them could be influenced by mixed sources.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
Atmos. Chem. Phys., 24, 13587–13601, https://doi.org/10.5194/acp-24-13587-2024, https://doi.org/10.5194/acp-24-13587-2024, 2024
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To gain insight into the impact of changes due to epidemic control policies, we undertook continuous online monitoring of volatile organic compounds (VOCs) at an urban site in Zhengzhou over a 2-month period. This study examines the characteristics of VOCs, their sources, and their temporal evolution. It also assesses the impact of the policy change on VOC pollution during the monitoring period, thus providing a basis for further research on VOC pollution and source control.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
Atmos. Chem. Phys., 24, 13603–13631, https://doi.org/10.5194/acp-24-13603-2024, https://doi.org/10.5194/acp-24-13603-2024, 2024
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Arctic ozone depletion events (ODEs) occur every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 24, 13151–13182, https://doi.org/10.5194/acp-24-13151-2024, https://doi.org/10.5194/acp-24-13151-2024, 2024
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Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still undersampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase is found at Zoétélé (Cameroon) and Skukuza (South Africa).
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 13199–13217, https://doi.org/10.5194/acp-24-13199-2024, https://doi.org/10.5194/acp-24-13199-2024, 2024
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Biogenic volatile organic compounds (BVOCs) and organic aerosol (OA) particles were measured online in a stressed spruce-dominated forest. OA was mainly attributed to the monoterpene oxidation products. The mixing ratios of BVOCs were higher than the values previously measured in other temperate forests. The results demonstrate that BVOCs are influenced not only by meteorology and biogenic emissions but also by local anthropogenic emissions and subsequent chemical transformation processes.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 13129–13150, https://doi.org/10.5194/acp-24-13129-2024, https://doi.org/10.5194/acp-24-13129-2024, 2024
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
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Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
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We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
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We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
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Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
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We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
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Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
Chengzhi Xing, Cheng Liu, Chunxiang Ye, Jingkai Xue, Hongyu Wu, Xiangguang Ji, Jinping Ou, and Qihou Hu
Atmos. Chem. Phys., 24, 10093–10112, https://doi.org/10.5194/acp-24-10093-2024, https://doi.org/10.5194/acp-24-10093-2024, 2024
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We identified the contributions of ozone (O3) and nitrous acid (HONO) to the production rates of hydroxide (OH) in vertical space on the Tibetan Plateau (TP). A new insight was offered: the contributions of HONO and O3 to the production rates of OH on the TP are even greater than in lower-altitudes areas. This study enriches the understanding of vertical distribution of atmospheric components and explains the strong atmospheric oxidation capacity (AOC) on the TP.
Baoye Hu, Naihua Chen, Rui Li, Mingqiang Huang, Jinsheng Chen, Youwei Hong, Lingling Xu, Xiaolong Fan, Mengren Li, Lei Tong, Qiuping Zheng, and Yuxiang Yang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2631, https://doi.org/10.5194/egusphere-2024-2631, 2024
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Box modeling with the master chemical mechanism (MCM) was used to address the puzzle of summertime PAN formation and its association with aerosol pollution under high ozone conditions. The MCM model proves to be an ideal tool for investigating PAN photochemical formation (IOA=0.75). The model performed better during the clean period than during the haze period. Through the machine learning method of XGBoost, we found that the top three factors leading to simulation bias were NH3, NO3, and PM2.5.
Xinyuan Zhang, Lingling Wang, Nan Wang, Shuangliang Ma, Shenbo Wang, Ruiqin Zhang, Dong Zhang, Mingkai Wang, and Hongyu Zhang
Atmos. Chem. Phys., 24, 9885–9898, https://doi.org/10.5194/acp-24-9885-2024, https://doi.org/10.5194/acp-24-9885-2024, 2024
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This study highlights the importance of the redox reaction of NO2 with SO2 based on actual atmospheric observations. The particle pH in future China is expected to rise steadily. Consequently, this reaction could become a significant source of HONO in China. Therefore, it is crucial to coordinate the control of SO2, NOx, and NH3 emissions to avoid a rapid increase in the particle pH.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
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In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
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Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Benjamin A. Nault, Katherine R. Travis, James H. Crawford, Donald R. Blake, Pedro Campuzano-Jost, Ronald C. Cohen, Joshua P. DiGangi, Glenn S. Diskin, Samuel R. Hall, L. Gregory Huey, Jose L. Jimenez, Kyung-Eun Min, Young Ro Lee, Isobel J. Simpson, Kirk Ullmann, and Armin Wisthaler
Atmos. Chem. Phys., 24, 9573–9595, https://doi.org/10.5194/acp-24-9573-2024, https://doi.org/10.5194/acp-24-9573-2024, 2024
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Ozone (O3) is a pollutant formed from the reactions of gases emitted from various sources. In urban areas, the density of human activities can increase the O3 formation rate (P(O3)), thus impacting air quality and health. Observations collected over Seoul, South Korea, are used to constrain P(O3). A high local P(O3) was found; however, local P(O3) was partly reduced due to compounds typically ignored. These observations also provide constraints for unmeasured compounds that will impact P(O3).
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
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Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024, https://doi.org/10.5194/acp-24-8983-2024, 2024
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In the scope of a field campaign in a suburban forest near Paris in the summer of 2022, we measured the reactivity of the nitrate radical NO3 towards biogenic volatile organic compounds (BVOCs; e.g. monoterpenes) mainly below but also above the canopy. NO3 reactivity was the highest during nights with strong temperature inversions and decreased strongly with height. Reactions with BVOCs were the main removal process of NO3 throughout the diel cycle below the canopy.
Jian Wang, Lei Xue, Qianyao Ma, Feng Xu, Gaobin Xu, Shibo Yan, Jiawei Zhang, Jianlong Li, Honghai Zhang, Guiling Zhang, and Zhaohui Chen
Atmos. Chem. Phys., 24, 8721–8736, https://doi.org/10.5194/acp-24-8721-2024, https://doi.org/10.5194/acp-24-8721-2024, 2024
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This study investigated the distribution and sources of non-methane hydrocarbons (NMHCs) in the lower atmosphere over the marginal seas of China. NMHCs, a subset of volatile organic compounds (VOCs), play a crucial role in atmospheric chemistry. Derived from systematic atmospheric sampling in coastal cities and marginal sea regions, this study offers valuable insights into the interaction between land and sea in shaping offshore atmospheric NMHCs.
Yusheng Zhang, Feixue Zheng, Zemin Feng, Chaofan Lian, Weigang Wang, Xiaolong Fan, Wei Ma, Zhuohui Lin, Chang Li, Gen Zhang, Chao Yan, Ying Zhang, Veli-Matti Kerminen, Federico Bianch, Tuukka Petäjä, Juha Kangasluoma, Markku Kulmala, and Yongchun Liu
Atmos. Chem. Phys., 24, 8569–8587, https://doi.org/10.5194/acp-24-8569-2024, https://doi.org/10.5194/acp-24-8569-2024, 2024
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The nitrous acid (HONO) budget was validated during a COVID-19 lockdown event. The main conclusions are (1) HONO concentrations showed a significant decrease from 0.97 to 0.53 ppb during lockdown; (2) vehicle emissions accounted for 53 % of nighttime sources, with the heterogeneous conversion of NO2 on ground surfaces more important than aerosol; and (3) the dominant daytime source shifted from the homogenous reaction between NO and OH (51 %) to nitrate photolysis (53 %) during lockdown.
Dong Zhang, Xiao Li, Minghao Yuan, Yifei Xu, Qixiang Xu, Fangcheng Su, Shenbo Wang, and Ruiqin Zhang
Atmos. Chem. Phys., 24, 8549–8567, https://doi.org/10.5194/acp-24-8549-2024, https://doi.org/10.5194/acp-24-8549-2024, 2024
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The increasing concentration of O3 precursors and unfavorable meteorological conditions are key factors in the formation of O3 pollution in Zhengzhou. Vehicular exhausts (28 %), solvent usage (27 %), and industrial production (22 %) are identified as the main sources of NMVOCs. Moreover, O3 formation in Zhengzhou is found to be in an anthropogenic volatile organic compound (AVOC)-limited regime. Thus, to reduce O3 formation, a minimum AVOCs / NOx reduction ratio ≥ 3 : 1 is recommended.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
EGUsphere, https://doi.org/10.5194/egusphere-2024-1883, https://doi.org/10.5194/egusphere-2024-1883, 2024
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Organophosphate esters are important man-made trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation and surface water from Canada, we explore seasonal concentration variability, gas/particle partitioning, precipitation scavenging, and air-water equilibrium. Whereas higher concentrations in summer and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas-particle partitioning is puzzling.
Xiansheng Liu, Xun Zhang, Marvin Dufresne, Tao Wang, Lijie Wu, Rosa Lara, Roger Seco , Marta Monge, Ana Maria Yáñez-Serrano, Marie Gohy, Paul Petit, Audrey Chevalier, Marie-Pierre Vagnot, Yann Fortier, Alexia Baudic, Véronique Ghersi, Grégory Gille, Ludovic Lanzi, Valérie Gros, Leïla Simon, Heidi Hellen, Stefan Reimann, Zoé Le Bras, Michelle Jessy Müller, David Beddows, Siqi Hou, Zongbo Shi, Roy M. Harrison, William Bloss, James Dernie, Stéphane Sauvage, Philip K. Hopke, Xiaoli Duan, Taicheng An, Alastair Lewis, Jim Hopkins, Eleni Liakakou, Nikolaos Mihalopoulos, Xiaohu Zhang, Andrés Alastuey, Xavier Querol, and Thérèse Salameh
EGUsphere, https://doi.org/10.5194/egusphere-2024-2309, https://doi.org/10.5194/egusphere-2024-2309, 2024
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This study examines BTEX (benzene, toluene, ethylbenzene, xylenes) pollution in urban areas across 7 European countries. Analyzing data from 22 monitoring sites, we found traffic and industrial activities significantly impact BTEX levels, with peaks during rush hours. Despite improvements, the risk from BTEX exposure remains moderate, especially in high-traffic and industrial zones. It highlights the need for targeted air quality management to protect public health and improve urban air quality.
Delaney B. Kilgour, Christopher M. Jernigan, Olga Garmash, Sneha Aggarwal, Claudia Mohr, Matt E. Salter, Joel A. Thornton, Jian Wang, Paul Zieger, and Timothy H. Bertram
EGUsphere, https://doi.org/10.5194/egusphere-2024-1975, https://doi.org/10.5194/egusphere-2024-1975, 2024
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We report simultaneous measurements of dimethyl sulfide (DMS) and hydroperoxymethyl thioformate (HPMTF) in the Eastern North Atlantic. We use an observationally constrained box model to show cloud loss is the dominant sink of HPMTF in this region over six weeks, resulting in large reductions in DMS-derived products that contribute to aerosol formation and growth. Our findings indicate that fast cloud processing of HPMTF must be included in global models to accurately capture the sulfur cycle.
Arianna Peron, Martin Graus, Marcus Striednig, Christian Lamprecht, Georg Wohlfahrt, and Thomas Karl
Atmos. Chem. Phys., 24, 7063–7083, https://doi.org/10.5194/acp-24-7063-2024, https://doi.org/10.5194/acp-24-7063-2024, 2024
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The anthropogenic fraction of non-methane volatile organic compound (NMVOC) emissions associated with biogenic sources (e.g., terpenes) is investigated based on eddy covariance observations. The anthropogenic fraction of terpene emissions is strongly dependent on season. When analyzing volatile chemical product (VCP) emissions in urban environments, we caution that observations from short-term campaigns might over-/underestimate their significance depending on local and seasonal circumstances.
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024, https://doi.org/10.5194/acp-24-7101-2024, 2024
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Emissions of reactive organic gases from industrial volatile chemical product sources are measured. There are large differences among these industrial sources. We show that oxygenated species account for significant contributions to reactive organic gas emissions, especially for industrial sources utilizing water-borne chemicals.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
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Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Junwei Song, Harald Saathoff, Feng Jiang, Linyu Gao, Hengheng Zhang, and Thomas Leisner
Atmos. Chem. Phys., 24, 6699–6717, https://doi.org/10.5194/acp-24-6699-2024, https://doi.org/10.5194/acp-24-6699-2024, 2024
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This study presents concurrent online measurements of organic gas and particles (VOCs and OA) at a forested site in summer. Both VOCs and OA were largely contributed by oxygenated organic compounds. Semi-volatile oxygenated OA and organic nitrate formed from monoterpenes and sesquiterpenes contributed significantly to nighttime particle growth. The results help us to understand the causes of nighttime particle growth regularly observed in summer in central European rural forested environments.
Jiemeng Bao, Xin Zhang, Zhenhai Wu, Li Zhou, Jun Qian, Qinwen Tan, Fumo Yang, Junhui Chen, Yunfeng Li, Hefan Liu, Liqun Deng, and Hong Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-1204, https://doi.org/10.5194/egusphere-2024-1204, 2024
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Our research in the Chengdu Plain Urban Agglomeration (CPUA), China, reveals significant correlations between carbonyl compounds and ozone pollution, particularly in Chengdu. Formaldehyde, acetone, and acetaldehyde are key contributors to ozone formation. Urgent collaborative actions among cities are needed to mitigate carbonyl-related ozone pollution, stressing the control of NOx and VOCs emissions. Our study offers crucial insights for crafting effective regional pollution control strategies.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
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This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Rebecca M. Garland, Katye E. Altieri, Laura Dawidowski, Laura Gallardo, Aderiana Mbandi, Nestor Y. Rojas, and N'datchoh E. Touré
Atmos. Chem. Phys., 24, 5757–5764, https://doi.org/10.5194/acp-24-5757-2024, https://doi.org/10.5194/acp-24-5757-2024, 2024
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This opinion piece focuses on two geographical areas in the Global South where the authors are based that are underrepresented in atmospheric science. This opinion provides context on common challenges and constraints, with suggestions on how the community can address these. The focus is on the strengths of atmospheric science research in these regions. It is these strengths, we believe, that highlight the critical role of Global South researchers in the future of atmospheric science research.
Heidi Hellén, Rostislav Kouznetsov, Kaisa Kraft, Jukka Seppälä, Mika Vestenius, Jukka-Pekka Jalkanen, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 24, 4717–4731, https://doi.org/10.5194/acp-24-4717-2024, https://doi.org/10.5194/acp-24-4717-2024, 2024
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Mixing ratios of C2-C5 NMHCs and methanethiol were measured on an island in the Baltic Sea using an in situ gas chromatograph. Shipping emissions were found to be an important source of ethene, ethyne, propene, and benzene. High summertime mixing ratios of methanethiol and dependence of mixing ratios on seawater temperature and height indicated the biogenic origin to possibly be phytoplankton or macroalgae. These emissions may have a strong impact on SO2 production and new particle formation.
Matthew M. Coggon, Chelsea E. Stockwell, Lu Xu, Jeff Peischl, Jessica B. Gilman, Aaron Lamplugh, Henry J. Bowman, Kenneth Aikin, Colin Harkins, Qindan Zhu, Rebecca H. Schwantes, Jian He, Meng Li, Karl Seltzer, Brian McDonald, and Carsten Warneke
Atmos. Chem. Phys., 24, 4289–4304, https://doi.org/10.5194/acp-24-4289-2024, https://doi.org/10.5194/acp-24-4289-2024, 2024
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Residential and commercial cooking emits pollutants that degrade air quality. Here, ambient observations show that cooking is an important contributor to anthropogenic volatile organic compounds (VOCs) emitted in Las Vegas, NV. These emissions are not fully presented in air quality models, and more work may be needed to quantify emissions from important sources, such as commercial restaurants.
Fabien Paulot, Gabrielle Pétron, Andrew M. Crotwell, and Matteo B. Bertagni
Atmos. Chem. Phys., 24, 4217–4229, https://doi.org/10.5194/acp-24-4217-2024, https://doi.org/10.5194/acp-24-4217-2024, 2024
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New data from the National Oceanic and Atmospheric Administration show that hydrogen (H2) concentrations increased from 2010 to 2019, which is consistent with the simulated increase in H2 photochemical production (mainly from methane). But this cannot be reconciled with the expected decrease (increase) in H2 anthropogenic emissions (soil deposition) in the same period. This shows gaps in our knowledge of the H2 biogeochemical cycle that must be resolved to quantify the impact of higher H2 usage.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
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This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Shigeyuki Ishidoya, Satoshi Sugawara, and Atsushi Okazaki
EGUsphere, https://doi.org/10.5194/egusphere-2024-654, https://doi.org/10.5194/egusphere-2024-654, 2024
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Diurnal, seasonal, and interannual variations of the present-day stable isotopic ratio of atmospheric O2, in other words slight variations in the Dole-Morita effect, have been detected firstly. A box model that incorporated biological and water processes associated with the Dole-Morita effect reproduced the general characteristics of the observational results. Based on the findings, we proposed some applications to evaluate oxygen, carbon, and water cycles.
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024, https://doi.org/10.5194/acp-24-3785-2024, 2024
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Using mass spectrometry data collected at the Maïdo Observatory (2160 m a.s.l., Réunion), we provide the first detailed analysis of molecular cluster chemical composition specifically in the marine free troposphere. The abundance of the identified species is related both to in situ meteorological parameters and air mass history, which also provide insight into their origin. Our work makes an important contribution to documenting the chemistry and physics of the marine free troposphere.
Delaney B. Kilgour, Gordon A. Novak, Megan S. Claflin, Brian M. Lerner, and Timothy H. Bertram
Atmos. Chem. Phys., 24, 3729–3742, https://doi.org/10.5194/acp-24-3729-2024, https://doi.org/10.5194/acp-24-3729-2024, 2024
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Laboratory experiments with seawater mimics suggest ozone deposition to the surface ocean can be a source of reactive carbon to the marine atmosphere. We conduct both field and laboratory measurements to assess abiotic VOC composition and yields from ozonolysis of real surface seawater. We show that C5–C11 aldehydes contribute to the observed VOC emission flux. We estimate that VOCs generated by the ozonolysis of surface seawater are competitive with biological VOC production and emission.
Xiangdong Zheng, Wen Yang, Yuting Sun, Chunmei Geng, Yingying Liu, and Xiaobin Xu
Atmos. Chem. Phys., 24, 3759–3768, https://doi.org/10.5194/acp-24-3759-2024, https://doi.org/10.5194/acp-24-3759-2024, 2024
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Chen et al. (2022) attributed the nocturnal ozone enhancement (NOE) during the night of 31 July 2021 in the North China Plain (NCP) to "the direct stratospheric intrusion to reach the surface". We analyzed in situ data from the NCP. Our results do not suggest that there was a significant impact from the stratosphere on surface ozone during the NOE. We argue that the NOE was not caused by stratospheric intrusion but originated from fresh photochemical production in the lower troposphere.
James M. Roberts, Siyuan Wang, Patrick R. Veres, J. Andrew Neuman, Michael A. Robinson, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Hannah M. Allen, John D. Crounse, Paul O. Wennberg, Samuel R. Hall, Kirk Ullmann, Simone Meinardi, Isobel J. Simpson, and Donald Blake
Atmos. Chem. Phys., 24, 3421–3443, https://doi.org/10.5194/acp-24-3421-2024, https://doi.org/10.5194/acp-24-3421-2024, 2024
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We measured cyanogen bromide (BrCN) in the troposphere for the first time. BrCN is a product of the same active bromine chemistry that destroys ozone and removes mercury in polar surface environments and is a previously unrecognized sink for active Br compounds. BrCN has an apparent lifetime against heterogeneous loss in the range 1–10 d, so it serves as a cumulative marker of Br-radical chemistry. Accounting for BrCN chemistry is an important part of understanding polar Br cycling.
Kai Qin, Wei Hu, Qin He, Fan Lu, and Jason Blake Cohen
Atmos. Chem. Phys., 24, 3009–3028, https://doi.org/10.5194/acp-24-3009-2024, https://doi.org/10.5194/acp-24-3009-2024, 2024
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We compute CH4 emissions and uncertainty on a mine-by-mine basis, including underground, overground, and abandoned mines. Mine-by-mine gas and flux data and 30 min observations from a flux tower located next to a mine shaft are integrated. The observed variability and bias correction are propagated over the emissions dataset, demonstrating that daily observations may not cover the range of variability. Comparisons show both an emissions magnitude and spatial mismatch with current inventories.
Yao Yan Huang and D. James Donaldson
Atmos. Chem. Phys., 24, 2387–2398, https://doi.org/10.5194/acp-24-2387-2024, https://doi.org/10.5194/acp-24-2387-2024, 2024
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Ground-level ozone interacts at the lake–land boundary; this is important to our understanding and modelling of atmospheric chemistry and air pollution in the lower atmosphere. We show that a steep ozone gradient occurs year-round moving inland up to 1 km from the lake and that this gradient is influenced by seasonal factors on the local land environment, where more rural areas are more greatly affected seasonally.
Katrin Müller, Jordis S. Tradowsky, Peter von der Gathen, Christoph Ritter, Sharon Patris, Justus Notholt, and Markus Rex
Atmos. Chem. Phys., 24, 2169–2193, https://doi.org/10.5194/acp-24-2169-2024, https://doi.org/10.5194/acp-24-2169-2024, 2024
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The Palau Atmospheric Observatory is introduced as an ideal site to detect changes in atmospheric composition and dynamics above the remote tropical western Pacific. We focus on the ozone sounding program from 2016–2021, including El Niño 2016. The year-round high convective activity is reflected in dominant low tropospheric ozone and high relative humidity. Their seasonal distributions are unique compared to other tropical sites and are modulated by the Intertropical Convergence Zone.
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Short summary
We developed methods to measure the vertical distribution of bromine monoxide, a gas that oxidizes pollutants, above sea ice based upon MAX-DOAS observations from Barrow, Alaska, and find that atmospheric stability exerts a strong control on BrO's vertical distribution. Specifically, more stable (temperature inversion) situations result in BrO being closer to the ground while more neutral (not inverted) atmospheres allow BrO to ascend further aloft and grow to larger column abundance.
We developed methods to measure the vertical distribution of bromine monoxide, a gas that...
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