Articles | Volume 21, issue 8
https://doi.org/10.5194/acp-21-5983-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-5983-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Apr 2021
Research article |
| 21 Apr 2021
| 21 Apr 2021
Temperature and acidity dependence of secondary organic aerosol formation from α-pinene ozonolysis with a compact chamber system
Yange Deng
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
Sathiyamurthi Ramasamy
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
Yu Morino
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
Shinichi Enami
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
Hiroshi Tanimoto
National Institute for Environmental Studies, Tsukuba 305-8506, Japan
Related authors
Yange Deng, Hiroshi Tanimoto, Kohei Ikeda, Sohiko Kameyama, Sachiko Okamoto, Jinyoung Jung, Young Jun Yoon, Eun Jin Yang, and Sung-Ho Kang
Atmos. Chem. Phys., 24, 6339–6357, https://doi.org/10.5194/acp-24-6339-2024, https://doi.org/10.5194/acp-24-6339-2024, 2024
Short summary
Short summary
Black carbon (BC) aerosols play important roles in Arctic climate change, yet they are not well understood because of limited observational data. We observed BC mass concentrations (mBC) in the western Arctic Ocean during summer and early autumn 2016–2020. The mean mBC in 2019 was much higher than in other years. Biomass burning was likely the dominant BC source. Boreal fire BC transport occurring near the surface and/or in the mid-troposphere contributed to high-BC events in the Arctic Ocean.
Yange Deng, Hiroaki Fujinari, Hikari Yai, Kojiro Shimada, Yuzo Miyazaki, Eri Tachibana, Dhananjay K. Deshmukh, Kimitaka Kawamura, Tomoki Nakayama, Shiori Tatsuta, Mingfu Cai, Hanbing Xu, Fei Li, Haobo Tan, Sho Ohata, Yutaka Kondo, Akinori Takami, Shiro Hatakeyama, and Michihiro Mochida
Atmos. Chem. Phys., 22, 5515–5533, https://doi.org/10.5194/acp-22-5515-2022, https://doi.org/10.5194/acp-22-5515-2022, 2022
Short summary
Short summary
Offline analyses of the hygroscopicity and composition of atmospheric aerosols are complementary to online analyses in view of the applicability to broader sizes, specific compound groups, and investigations at remote sites. This offline study characterized the composition of water-soluble matter in aerosols and their humidity-dependent hygroscopicity on Okinawa, a receptor site of East Asian outflow. Further, comparison with online analyses showed the appropriateness of the offline method.
Vincent Enders, Astrid Müller, Matthias Max Frey, Frank Hase, Ralph Kleinschek, Marvin Knapp, Benedikt Löw, Isamu Morino, Shin-Ichiro Nakaoka, Hideki Nara, Hiroshi Tanimoto, Sanam N. Vardag, Karolin Voss, and André Butz
EGUsphere, https://doi.org/10.5194/egusphere-2025-4552, https://doi.org/10.5194/egusphere-2025-4552, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
We have deployed two spectrometers on a ship traveling along the coast of Japan. By that, we were able to repeatedly measure the greenhouse gas and air pollutant emissions of power plants, large industrial facilities, and cities. Using the ratios between the different gases, we are able to identify sources based on their unique signature. In addition, we are able to show that spectrometers can be operated on a ship, while still fulfilling the high standards of land-based observation networks.
Kohei Sakata, Shotaro Takano, Atsushi Matsuki, Yasuo Takeichi, Hiroshi Tanimoto, Aya Sakaguchi, Minako Kurisu, and Yoshio Takahashi
Atmos. Chem. Phys., 25, 11087–11107, https://doi.org/10.5194/acp-25-11087-2025, https://doi.org/10.5194/acp-25-11087-2025, 2025
Short summary
Short summary
Deposition of aerosol iron (Fe) into the ocean stimulates primary production and influences the global carbon cycle, although the factors governing the aerosol Fe solubility remain uncertain. Our observations in Japan revealed that both mineral dust and anthropogenic aerosols are significant sources of dissolved Fe, and that atmospheric chemical weathering enhances their solubility. This finding is expected to play a crucial role in estimating the supply of dissolved iron to the ocean.
Yosuke Niwa, Yasunori Tohjima, Yukio Terao, Tazu Saeki, Akihiko Ito, Taku Umezawa, Kyohei Yamada, Motoki Sasakawa, Toshinobu Machida, Shin-Ichiro Nakaoka, Hideki Nara, Hiroshi Tanimoto, Hitoshi Mukai, Yukio Yoshida, Shinji Morimoto, Shinya Takatsuji, Kazuhiro Tsuboi, Yousuke Sawa, Hidekazu Matsueda, Kentaro Ishijima, Ryo Fujita, Daisuke Goto, Xin Lan, Kenneth Schuldt, Michal Heliasz, Tobias Biermann, Lukasz Chmura, Jarsolaw Necki, Irène Xueref-Remy, and Damiano Sferlazzo
Atmos. Chem. Phys., 25, 6757–6785, https://doi.org/10.5194/acp-25-6757-2025, https://doi.org/10.5194/acp-25-6757-2025, 2025
Short summary
Short summary
This study estimated regional and sectoral emission contributions to the unprecedented surge of atmospheric methane for 2020–2022. The methane is the second most important greenhouse gas, and its emissions reduction is urgently required to mitigate global warming. Numerical modeling-based estimates with three different sets of atmospheric observations consistently suggested large contributions of biogenic emissions from South Asia and Southeast Asia to the surge of atmospheric methane.
Johannes Heuser, Claudia Di Biagio, Jérôme Yon, Mathieu Cazaunau, Antonin Bergé, Edouard Pangui, Marco Zanatta, Laura Renzi, Angela Marinoni, Satoshi Inomata, Chenjie Yu, Vera Bernardoni, Servanne Chevaillier, Daniel Ferry, Paolo Laj, Michel Maillé, Dario Massabò, Federico Mazzei, Gael Noyalet, Hiroshi Tanimoto, Brice Temime-Roussel, Roberta Vecchi, Virginia Vernocchi, Paola Formenti, Bénédicte Picquet-Varrault, and Jean-François Doussin
Atmos. Chem. Phys., 25, 6407–6428, https://doi.org/10.5194/acp-25-6407-2025, https://doi.org/10.5194/acp-25-6407-2025, 2025
Short summary
Short summary
The spectral optical properties of combustion soot aerosols with varying black (BC) and brown carbon (BrC) content were studied in an atmospheric simulation chamber. Measurements of the mass spectral absorption cross section (MAC), supplemented by literature data, allowed us to establish a generalised exponential relationship between the spectral absorption and the elemental-to-total-carbon ratio (EC / TC) in soot. This relationship can provide a useful tool for modelling the properties of soot.
Sachiko Okamoto, Juan Cuesta, Gaëlle Dufour, Maxmim Eremenko, Kazuyuki Miyazaki, Cathy Boonne, Hiroshi Tanimoto, Jeff Peischl, and Chelsea Thompson
EGUsphere, https://doi.org/10.5194/egusphere-2024-3758, https://doi.org/10.5194/egusphere-2024-3758, 2024
Short summary
Short summary
We analyse the distribution of tropospheric ozone over the South and Tropical Atlantic during February 2017 using a multispectral satellite approach called IASI+GOME2, three chemistry reanalysis products and in situ airborne measurements. It reveals that a significant overestimation of three chemistry reanalysis products of lowermost troposphere ozone over the Atlantic in the Northern Hemisphere due to the overestimations of ozone precursors from anthropogenic sources from North America.
Yange Deng, Hiroshi Tanimoto, Kohei Ikeda, Sohiko Kameyama, Sachiko Okamoto, Jinyoung Jung, Young Jun Yoon, Eun Jin Yang, and Sung-Ho Kang
Atmos. Chem. Phys., 24, 6339–6357, https://doi.org/10.5194/acp-24-6339-2024, https://doi.org/10.5194/acp-24-6339-2024, 2024
Short summary
Short summary
Black carbon (BC) aerosols play important roles in Arctic climate change, yet they are not well understood because of limited observational data. We observed BC mass concentrations (mBC) in the western Arctic Ocean during summer and early autumn 2016–2020. The mean mBC in 2019 was much higher than in other years. Biomass burning was likely the dominant BC source. Boreal fire BC transport occurring near the surface and/or in the mid-troposphere contributed to high-BC events in the Arctic Ocean.
Astrid Müller, Hiroshi Tanimoto, Takafumi Sugita, Prabir K. Patra, Shin-ichiro Nakaoka, Toshinobu Machida, Isamu Morino, André Butz, and Kei Shiomi
Atmos. Meas. Tech., 17, 1297–1316, https://doi.org/10.5194/amt-17-1297-2024, https://doi.org/10.5194/amt-17-1297-2024, 2024
Short summary
Short summary
Satellite CH4 observations with high accuracy are needed to understand changes in atmospheric CH4 concentrations. But over oceans, reference data are limited. We combine various ship and aircraft observations with the help of atmospheric chemistry models to derive observation-based column-averaged mixing ratios of CH4 (obs. XCH4). We discuss three different approaches and demonstrate the applicability of the new reference dataset for carbon cycle studies and satellite evaluation.
Adedayo R. Adedeji, Stephen J. Andrews, Matthew J. Rowlinson, Mathew J. Evans, Alastair C. Lewis, Shigeru Hashimoto, Hitoshi Mukai, Hiroshi Tanimoto, Yasunori Tohjima, and Takuya Saito
Atmos. Chem. Phys., 23, 9229–9244, https://doi.org/10.5194/acp-23-9229-2023, https://doi.org/10.5194/acp-23-9229-2023, 2023
Short summary
Short summary
We use the GEOS-Chem model to interpret observations of CO, C2H6, C3H8, NOx, NOy and O3 made from Hateruma Island in 2018. The model captures many synoptic-scale events and the seasonality of most pollutants at the site but underestimates C2H6 and C3H8 during the winter. These underestimates are unlikely to be reconciled by increases in biomass burning emissions but could be reconciled by increasing the Asian anthropogenic source of C2H6 and C3H8 by factors of around 2 and 3, respectively.
Sachiko Okamoto, Juan Cuesta, Matthias Beekmann, Gaëlle Dufour, Maxim Eremenko, Kazuyuki Miyazaki, Cathy Boonne, Hiroshi Tanimoto, and Hajime Akimoto
Atmos. Chem. Phys., 23, 7399–7423, https://doi.org/10.5194/acp-23-7399-2023, https://doi.org/10.5194/acp-23-7399-2023, 2023
Short summary
Short summary
We present a detailed analysis of the daily evolution of the lowermost tropospheric ozone documented by IASI+GOME2 multispectral satellite observations and that of its precursors from TCR-2 tropospheric chemistry reanalysis. It reveals that the ozone outbreak across Europe in July 2017 was produced during favorable condition for photochemical production of ozone and was associated with multiple sources of ozone precursors: biogenic, anthropogenic, and biomass burning emissions.
Kohei Sakata, Minako Kurisu, Yasuo Takeichi, Aya Sakaguchi, Hiroshi Tanimoto, Yusuke Tamenori, Atsushi Matsuki, and Yoshio Takahashi
Atmos. Chem. Phys., 22, 9461–9482, https://doi.org/10.5194/acp-22-9461-2022, https://doi.org/10.5194/acp-22-9461-2022, 2022
Short summary
Short summary
Iron (Fe) species in size-fractionated aerosol particles collected in the western Pacific Ocean were determined to identify factors controlling fractional Fe solubility. We found that labile Fe was mainly present in submicron aerosol particles, and the Fe species were ferric organic complexes combined with humic-like substances (Fe(III)-HULIS). The Fe(III)-HULIS was formed by atmospheric processes. Thus, atmospheric processes play a significant role in controlling Fe solubility.
Yange Deng, Hiroaki Fujinari, Hikari Yai, Kojiro Shimada, Yuzo Miyazaki, Eri Tachibana, Dhananjay K. Deshmukh, Kimitaka Kawamura, Tomoki Nakayama, Shiori Tatsuta, Mingfu Cai, Hanbing Xu, Fei Li, Haobo Tan, Sho Ohata, Yutaka Kondo, Akinori Takami, Shiro Hatakeyama, and Michihiro Mochida
Atmos. Chem. Phys., 22, 5515–5533, https://doi.org/10.5194/acp-22-5515-2022, https://doi.org/10.5194/acp-22-5515-2022, 2022
Short summary
Short summary
Offline analyses of the hygroscopicity and composition of atmospheric aerosols are complementary to online analyses in view of the applicability to broader sizes, specific compound groups, and investigations at remote sites. This offline study characterized the composition of water-soluble matter in aerosols and their humidity-dependent hygroscopicity on Okinawa, a receptor site of East Asian outflow. Further, comparison with online analyses showed the appropriateness of the offline method.
Hao Xu, Urumu Tsunogai, Fumiko Nakagawa, Keiichi Sato, and Hiroshi Tanimoto
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-1099, https://doi.org/10.5194/acp-2021-1099, 2022
Revised manuscript not accepted
Short summary
Short summary
Using triple oxygen isotopic composition (Δ17O) of ozone as a new tracer, we estimated the absolute concentrations of stratospheric ozone supplied through stratosphere-troposphere transport in the troposphere. We observed the diurnal variations in the Δ17O of ozone, which could have affected studies (field measurements, atmospheric modeling) using Δ17O to constrain atmospheric chemical paths. Our study provides an important basis for a better understanding of ozone behavior in the troposphere.
Carlos Alberti, Frank Hase, Matthias Frey, Darko Dubravica, Thomas Blumenstock, Angelika Dehn, Paolo Castracane, Gregor Surawicz, Roland Harig, Bianca C. Baier, Caroline Bès, Jianrong Bi, Hartmut Boesch, André Butz, Zhaonan Cai, Jia Chen, Sean M. Crowell, Nicholas M. Deutscher, Dragos Ene, Jonathan E. Franklin, Omaira García, David Griffith, Bruno Grouiez, Michel Grutter, Abdelhamid Hamdouni, Sander Houweling, Neil Humpage, Nicole Jacobs, Sujong Jeong, Lilian Joly, Nicholas B. Jones, Denis Jouglet, Rigel Kivi, Ralph Kleinschek, Morgan Lopez, Diogo J. Medeiros, Isamu Morino, Nasrin Mostafavipak, Astrid Müller, Hirofumi Ohyama, Paul I. Palmer, Mahesh Pathakoti, David F. Pollard, Uwe Raffalski, Michel Ramonet, Robbie Ramsay, Mahesh Kumar Sha, Kei Shiomi, William Simpson, Wolfgang Stremme, Youwen Sun, Hiroshi Tanimoto, Yao Té, Gizaw Mengistu Tsidu, Voltaire A. Velazco, Felix Vogel, Masataka Watanabe, Chong Wei, Debra Wunch, Marcia Yamasoe, Lu Zhang, and Johannes Orphal
Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
Short summary
Short summary
Space-borne greenhouse gas missions require ground-based validation networks capable of providing fiducial reference measurements. Here, considerable refinements of the calibration procedures for the COllaborative Carbon Column Observing Network (COCCON) are presented. Laboratory and solar side-by-side procedures for the characterization of the spectrometers have been refined and extended. Revised calibration factors for XCO2, XCO and XCH4 are provided, incorporating 47 new spectrometers.
Sonya L. Fiddes, Matthew T. Woodhouse, Steve Utembe, Robyn Schofield, Simon P. Alexander, Joel Alroe, Scott D. Chambers, Zhenyi Chen, Luke Cravigan, Erin Dunne, Ruhi S. Humphries, Graham Johnson, Melita D. Keywood, Todd P. Lane, Branka Miljevic, Yuko Omori, Alain Protat, Zoran Ristovski, Paul Selleck, Hilton B. Swan, Hiroshi Tanimoto, Jason P. Ward, and Alastair G. Williams
Atmos. Chem. Phys., 22, 2419–2445, https://doi.org/10.5194/acp-22-2419-2022, https://doi.org/10.5194/acp-22-2419-2022, 2022
Short summary
Short summary
Coral reefs have been found to produce the climatically relevant chemical compound dimethyl sulfide (DMS). It has been suggested that corals can modify their environment via the production of DMS. We use an atmospheric chemistry model to test this theory at a regional scale for the first time. We find that it is unlikely that coral-reef-derived DMS has an influence over local climate, in part due to the proximity to terrestrial and anthropogenic aerosol sources.
Jun Zhou, Kei Sato, Yu Bai, Yukiko Fukusaki, Yuka Kousa, Sathiyamurthi Ramasamy, Akinori Takami, Ayako Yoshino, Tomoki Nakayama, Yasuhiro Sadanaga, Yoshihiro Nakashima, Jiaru Li, Kentaro Murano, Nanase Kohno, Yosuke Sakamoto, and Yoshizumi Kajii
Atmos. Chem. Phys., 21, 12243–12260, https://doi.org/10.5194/acp-21-12243-2021, https://doi.org/10.5194/acp-21-12243-2021, 2021
Short summary
Short summary
HO2 radicals play key roles in tropospheric chemistry, their levels in ambient air not yet fully explained by sophisticated models. Here we measured HO2 uptake kinetics onto ambient aerosols in real time using a self-built online system and investigated the impacting factors on such processes by coupling with other instrumentations. The role of the HO2 uptake process in O3 formation is also discussed. Results give useful information for coordinated control of aerosol and ozone pollutants.
Yosuke Niwa, Yousuke Sawa, Hideki Nara, Toshinobu Machida, Hidekazu Matsueda, Taku Umezawa, Akihiko Ito, Shin-Ichiro Nakaoka, Hiroshi Tanimoto, and Yasunori Tohjima
Atmos. Chem. Phys., 21, 9455–9473, https://doi.org/10.5194/acp-21-9455-2021, https://doi.org/10.5194/acp-21-9455-2021, 2021
Short summary
Short summary
Fires in Equatorial Asia release a large amount of carbon into the atmosphere. Extensively using high-precision atmospheric carbon dioxide (CO2) data from a commercial aircraft observation project, we estimated fire carbon emissions in Equatorial Asia induced by the big El Niño event in 2015. Additional shipboard measurement data elucidated the validity of the analysis and the best estimate indicated 273 Tg C for fire emissions during September–October 2015.
Astrid Müller, Hiroshi Tanimoto, Takafumi Sugita, Toshinobu Machida, Shin-ichiro Nakaoka, Prabir K. Patra, Joshua Laughner, and David Crisp
Atmos. Chem. Phys., 21, 8255–8271, https://doi.org/10.5194/acp-21-8255-2021, https://doi.org/10.5194/acp-21-8255-2021, 2021
Short summary
Short summary
Over oceans, high uncertainties in satellite CO2 retrievals exist due to limited reference data. We combine commercial ship and aircraft observations and, with the aid of model calculations, obtain column-averaged mixing ratios of CO2 (XCO2) data over the Pacific Ocean. This new dataset has great potential as a robust reference for XCO2 measured from space and can help to better understand changes in the carbon cycle in response to climate change using satellite observations.
Cited articles
Aschmann, S. M., Reissell, A., Atkinson, R., and Arey, J.: Products of the
gas phase reactions of the OH radical with α- and β-pinene in the
presence of NO, J. Geophys. Res.-Atmos., 103, 25553–25561, https://doi.org/10.1029/98jd01676, 1998.
Aschmann, S. M., Atkinson, R., and Arey, J.: Products of reaction of OH
radicals with α-pinene, J. Geophys. Res.-Atmos.,
107, 4191, https://doi.org/10.1029/2001jd001098, 2002.
Bateman, A. P., Walser, M. L., Desyaterik, Y., Laskin, J., Laskin, A., and
Nizkorodov, S. A.: The effect of solvent on the analysis of secondary
organic aerosol using electrospray ionization mass
spectrometry, Environ. Sci. Technol., 42, 7341–7346, https://doi.org/10.1021/es801226w,
2008.
Brüggemann, M., Poulain, L., Held, A., Stelzer, T., Zuth, C., Richters, S., Mutzel, A., van Pinxteren, D., Iinuma, Y., Katkevica, S., Rabe, R., Herrmann, H., and Hoffmann, T.: Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study, Atmos. Chem. Phys., 17, 1453–1469, https://doi.org/10.5194/acp-17-1453-2017, 2017.
Brüggemann, M., van Pinxteren, D., Wang, Y. C., Yu, J. Z., and Herrmann, H.:
Quantification of known and unknown terpenoid organosulfates in PM10 using
untargeted LC-HRMS/MS: contrasting summertime rural Germany and the North
China Plain, Environ. Chem., 16, 333–346, https://doi.org/10.1071/en19089, 2019.
Brüggemann, M., Xu, R. S., Tilgner, A., Kwong, K. C., Mutzel, A., Poon, H.
Y., Otto, T., Schaefer, T., Poulain, L., Chan, M. N., and Herrmann, H.:
Organosulfates in Ambient Aerosol: State of Knowledge and Future Research
Directions on Formation, Abundance, Fate, and Importance, Environ. Sci. Technol., 54, 3767–3782, https://doi.org/10.1021/acs.est.9b06751, 2020.
Capouet, M., Mueller, J. F., Ceulemans, K., Compernolle, S., Vereecken, L.,
and Peeters, J.: Modeling aerosol formation in α-pinene photo-oxidation
experiments, J. Geophys. Res.-Atmos., 113, D02308, https://doi.org/10.1029/2007jd008995, 2008.
Carlton, A. G., Bhave, P. V., Napelenok, S. L., Edney, E. D., Sarwar, G.,
Pinder, R. W., Pouliot, G. A., and Houyoux, M.: Model Representation of
Secondary Organic Aerosol in CMAQv4.7, Environ. Sci. Technol., 44, 8553–8560, https://doi.org/10.1021/es100636q, 2010.
Chu, S. H., Paisie, J. W., and Jang, B. W. L.: PM data analysis – a
comparison of two urban areas: Fresno and Atlanta, Atmos. Environ.,
38, 3155–3164, https://doi.org/10.1016/j.atmosenv.2004.03.018, 2004.
Czoschke, N. M. and Jang, M.: Acidity effects on the formation of
α-pinene ozone SOA in the presence of inorganic seed, Atmos. Environ., 40, 4370–4380, https://doi.org/10.1016/j.atmosenv.2006.03.030, 2006.
Czoschke, N. M., Jang, M., and Kamens, R. M.: Effect of acidic seed on
biogenic secondary organic aerosol growth, Atmos. Environ., 37,
4287–4299, https://doi.org/10.1016/s1352-2310(03)00511-9, 2003.
Donahue, N. M., Robinson, A. L., Stanier, C. O., and Pandis, S. N.: Coupled
partitioning, dilution, and chemical aging of semivolatile organics, Environ. Sci. Technol., 40, 2635–2643, https://doi.org/10.1021/es052297c, 2006.
Duporte, G., Flaud, P. M., Geneste, E., Augagneur, S., Pangui, E.,
Lamkaddam, H., Gratien, A., Doussin, J. F., Budzinski, H., Villenave, E.,
and Perraudin, E.: Experimental Study of the Formation of Organosulfates
from α-Pinene Oxidation, Part I: Product Identification, Formation
Mechanisms and Effect of Relative Humidity, J. Phys. Chem. A,
120, 7909–7923, https://doi.org/10.1021/acs.jpca.6b08504, 2016.
Duporte, G., Flaud, P. M., Kammer, J., Geneste, E., Augagneur, S., Pangui,
E., Lamkaddam, H., Gratien, A., Doussin, J. F., Budzinski, H., Villenave,
E., and Perraudin, E.: Experimental Study of the Formation of Organosulfates
from α-Pinene Oxidation, 2. Time Evolution and Effect of Particle
Acidity, J. Phys. Chem. A, 124, 409–421, https://doi.org/10.1021/acs.jpca.9b07156, 2020.
Eddingsaas, N. C., Loza, C. L., Yee, L. D., Chan, M., Schilling, K. A., Chhabra, P. S., Seinfeld, J. H., and Wennberg, P. O.: α-pinene photooxidation under controlled chemical conditions – Part 2: SOA yield and composition in low- and high-NOx environments, Atmos. Chem. Phys., 12, 7413–7427, https://doi.org/10.5194/acp-12-7413-2012, 2012.
Enami, S. and Colussi, A. J.: Criegee Chemistry on Aqueous Organic
Surfaces, J. Phys. Chem. Lett., 8, 1615–1623, https://doi.org/10.1021/acs.jpclett.7b00434, 2017.
Epstein, S. A., Riipinen, I., and Donahue, N. M.: A Semiempirical
Correlation between Enthalpy of Vaporization and Saturation Concentration
for Organic Aerosol, Environ. Sci. Technol., 44, 743–748, https://doi.org/10.1021/es902497z, 2010.
Faust, J. A., Wong, J. P. S., Lee, A. K. Y., and Abbatt, J. P. D.: Role of
Aerosol Liquid Water in Secondary Organic Aerosol Formation from Volatile
Organic Compounds, Environ. Sci. Technol., 51, 1405–1413, https://doi.org/10.1021/acs.est.6b04700, 2017.
Gao, S., Ng, N. L., Keywood, M., Varutbangkul, V., Bahreini, R., Nenes, A.,
He, J. W., Yoo, K. Y., Beauchamp, J. L., Hodyss, R. P., Flagan, R. C., and
Seinfeld, J. H.: Particle phase acidity and oligomer formation in secondary
organic aerosol, Environ. Sci. Technol., 38, 6582–6589, https://doi.org/10.1021/es049125k, 2004.
Gaona-Colmán, E., Blanco, M. B., Barnes, I., Wiesen, P., and Teruel, M. A.:
OH- and O3-initiated atmospheric degradation of camphene: temperature dependent rate coefficients, product yields and
mechanisms, RSC Adv., 7, 2733–2744, https://doi.org/10.1039/c6ra26656h, 2017.
Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., and Wang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471–1492, https://doi.org/10.5194/gmd-5-1471-2012, 2012.
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009.
Hettiyadura, A. P. S., Al-Naiema, I. M., Hughes, D. D., Fang, T., and Stone, E. A.: Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation, Atmos. Chem. Phys., 19, 3191–3206, https://doi.org/10.5194/acp-19-3191-2019, 2019.
Hilal, S. H., Karickhoff, S. W., and Carreira, L. A.: Prediction of the
vapor pressure boiling point, heat of vaporization and diffusion coefficient
of organic compounds, QSAR Comb. Sci., 22, 565–574, https://doi.org/10.1002/qsar.200330812, 2003.
Hinkley, J. T., Bridgman, H. A., Buhre, B. J. P., Gupta, R. P., Nelson, P.
F., and Wall, T. F.: Semi-quantitative characterisation of ambient ultrafine
aerosols resulting from emissions of coal fired power
stations, Sci. Total Environ., 391, 104–113, https://doi.org/10.1016/j.scitotenv.2007.10.017, 2008.
Hu, C. J., Cheng, Y., Pan, G., Gai, Y. B., Gu, X. J., Zhao, W. X., Wang, Z.
Y., Zhang, W. J., Chen, J., Liu, F. Y., Shan, X. B., and Sheng, L. S.: A
Smog Chamber Facility for Qualitative and Quantitative Study on Atmospheric
Chemistry and Secondary Organic Aerosol, Chinese J. Chem. Phys., 27, 631–639, https://doi.org/10.1063/1674-0068/27/06/631-639, 2014.
Iinuma, Y., Boge, O., Gnauk, T., and Herrmann, H.: Aerosol-chamber study of
the α-pinene/O3 reaction: influence of particle acidity on aerosol yields and products, Atmos. Environ., 38, 761–773, https://doi.org/10.1016/j.atmosenv.2003.10.015, 2004.
Iinuma, Y., Boge, O., Miao, Y., Sierau, B., Gnauk, T., and Herrmann, H.:
Laboratory studies on secondary organic aerosol formation from terpenes,
Faraday Discuss., 130, 279–294, https://doi.org/10.1039/b502160j, 2005.
Iinuma, Y., Müller, C., Boge, O., Gnauk, T., and Herrmann, H.: The formation
of organic sulfate esters in the limonene ozonolysis secondary organic
aerosol (SOA) under acidic conditions, Atmos. Environ., 41,
5571–5583, https://doi.org/10.1016/j.atmosenv.2007.03.007, 2007.
Iinuma, Y., Boge, O., Kahnt, A., and Herrmann, H.: Laboratory chamber
studies on the formation of organosulfates from reactive uptake of
monoterpene oxides, Phys. Chem. Chem. Phys., 11, 7985–7997, https://doi.org/10.1039/b904025k, 2009.
Jackson, S. R., Ham, J. E., Harrison, J. C., and Wells, J. R.:
Identification and quantification of carbonyl-containing α-pinene
ozonolysis products using O-tert-butylhydroxylamine hydrochloride,
J. Atmos. Chem., 74, 325–338, https://doi.org/10.1007/s10874-016-9344-6, 2017.
Jang, M., Czoschke, N. M., Lee, S., and Kamens, R. M.: Heterogeneous
atmospheric aerosol production by acid-catalyzed particle-phase reactions,
Science, 298, 814–817, https://doi.org/10.1126/science.1075798, 2002.
Jang, M., Czoschke, N. M., Northcross, A. L., Cao, G., and Shaof, D.: SOA
formation from partitioning and heterogeneous reactions: Model study in the
presence of inorganic species, Environ. Sci. Technol., 40,
3013–3022, https://doi.org/10.1021/es0511220, 2006.
Jang, M., Cao, G., and Paul, J.: Colorimetric particle acidity analysis of
secondary organic aerosol coating on submicron acidic
aerosols, Aerosol Sci. Tech., 42, 409–420, https://doi.org/10.1080/02786820802154861, 2008.
Kahnt, A., Iinuma, Y., Blockhuys, F., Mutzel, A., Vermeylen, R.,
Kleindienst, T. E., Jaoui, M., Offenberg, J. H., Lewandowski, M., Boge, O.,
Herrmann, H., Maenhaut, W., and Claeys, M.: 2-Hydroxyterpenylic Acid: An
Oxygenated Marker Compound for α-Pinene Secondary Organic Aerosol in
Ambient Fine Aerosol, Environ. Sci. Technol., 48, 4901–4908, https://doi.org/10.1021/es500377d, 2014a.
Kahnt, A., Iinuma, Y., Mutzel, A., Böge, O., Claeys, M., and Herrmann, H.: Campholenic aldehyde ozonolysis: a mechanism leading to specific biogenic secondary organic aerosol constituents, Atmos. Chem. Phys., 14, 719–736, https://doi.org/10.5194/acp-14-719-2014, 2014b.
Kelly, J. M., Doherty, R. M., O'Connor, F. M., and Mann, G. W.: The impact of biogenic, anthropogenic, and biomass burning volatile organic compound emissions on regional and seasonal variations in secondary organic aerosol, Atmos. Chem. Phys., 18, 7393–7422, https://doi.org/10.5194/acp-18-7393-2018, 2018.
Kenseth, C. M., Hafeman, N. J., Huang, Y. L., Dalleska, N. F., Stoltz, B.
M., and Seinfeld, J. H.: Synthesis of Carboxylic Acid and Dimer Ester
Surrogates to Constrain the Abundance and Distribution of Molecular Products
in α-Pinene and β-Pinene Secondary Organic Aerosol, Environ. Sci. Technol., 54, 12829–12839, https://doi.org/10.1021/acs.est.0c01566, 2020.
Krechmer, J. E., Pagonis, D., Ziemann, P. J., and Jimenez, J. L.:
Quantification of Gas-Wall Partitioning in Teflon Environmental Chambers
Using Rapid Bursts of Low-Volatility Oxidized Species Generated in Situ, Environ. Sci. Technol., 50, 5757–5765, https://doi.org/10.1021/acs.est.6b00606, 2016.
Kristensen, K., Cui, T., Zhang, H., Gold, A., Glasius, M., and Surratt, J. D.: Dimers in α-pinene secondary organic aerosol: effect of hydroxyl radical, ozone, relative humidity and aerosol acidity, Atmos. Chem. Phys., 14, 4201–4218, https://doi.org/10.5194/acp-14-4201-2014, 2014.
Kristensen, K., Jensen, L. N., Glasius, M., and Bilde, M.: The effect of
sub-zero temperature on the formation and composition of secondary organic
aerosol from ozonolysis of
α-pinene, Environ. Sci.-Proc. Imp., 19, 1220–1234, https://doi.org/10.1039/c7em00231a, 2017.
Lai, A. C. K. and Nazaroff, W. W.: Modeling indoor particle deposition from
turbulent flow onto smooth surfaces, J. Aerosol Sci., 31, 463–476, 2000.
Lane, T. E., Donahue, N. M., and Pandis, S. N.: Simulating secondary organic
aerosol formation using the volatility basis-set approach in a chemical
transport model, Atmos. Environ., 42, 7439–7451, https://doi.org/10.1016/j.atmosenv.2008.06.026, 2008.
Lewandowski, M., Jaoui, M., Kleindienst, T. E., Offenberg, J. H., and Edney,
E. O.: Composition of PM2.5 during the summer of 2003 in Research Triangle Park, North Carolina, Atmos. Environ., 41, 4073–4083, https://doi.org/10.1016/j.atmosenv.2007.01.012, 2007.
Li, Y., Pöschl, U., and Shiraiwa, M.: Molecular corridors and parameterizations of volatility in the chemical evolution of organic aerosols, Atmos. Chem. Phys., 16, 3327–3344, https://doi.org/10.5194/acp-16-3327-2016, 2016.
Liggio, J. and Li, S. M.: Organosulfate formation during the uptake of
pinonaldehyde on acidic sulfate aerosols, Geophys. Res. Lett., 33,
L13808, https://doi.org/10.1029/2006gl026079, 2006.
Ma, Y., Russell, A. T., and Marston, G.: Mechanisms for the formation of
secondary organic aerosol components from the gas-phase ozonolysis of
α-pinene, Phys. Chem. Chem. Phys., 10, 4294–4312, https://doi.org/10.1039/b803283a, 2008.
Ma, Y., Xu, X. K., Song, W. H., Geng, F. H., and Wang, L.: Seasonal and
diurnal variations of particulate organosulfates in urban Shanghai, China, Atmos. Environ., 85, 152–160, https://doi.org/10.1016/j.atmosenv.2013.12.017, 2014.
Meade, L. E., Riva, M., Blomberg, M. Z., Brock, A. K., Qualters, E. M.,
Siejack, R. A., Ramakrishnan, K., Surratt, J. D., and Kautzman, K. E.:
Seasonal variations of fine particulate organosulfates derived from biogenic
and anthropogenic hydrocarbons in the mid-Atlantic United States, Atmos. Environ., 145, 405–414, https://doi.org/10.1016/j.atmosenv.2016.09.028, 2016.
Mei, F., Hayes, P. L., Ortega, A., Taylor, J. W., Allan, J. D., Gilman, J.,
Kuster, W., de Gouw, J., Jimenez, J. L., and Wang, J.: Droplet activation
properties of organic aerosols observed at an urban site during CalNex-LA,
J. Geophys. Res.-Atmos., 118, 2903–2917, https://doi.org/10.1002/jgrd.50285, 2013.
Messina, P., Lathière, J., Sindelarova, K., Vuichard, N., Granier, C., Ghattas, J., Cozic, A., and Hauglustaine, D. A.: Global biogenic volatile organic compound emissions in the ORCHIDEE and MEGAN models and sensitivity to key parameters, Atmos. Chem. Phys., 16, 14169–14202, https://doi.org/10.5194/acp-16-14169-2016, 2016.
Morino, Y., Sato, K., Jathar, S. H., Tanabe, K., Inomata, S., Fujitani, Y.,
Ramasamy, S., and Cappa, C. D.: Modeling the Effects of Dimerization and
Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol
Formed from α-Pinene and
1,3,5-Trimethylbenzene, ACS Earth Space Chem., 4, 1931–1946, https://doi.org/10.1021/acsearthspacechem.0c00106, 2020.
Na, K., Song, C., Switzer, C., and Cocker, D. R.: Effect of ammonia on
secondary organic aerosol formation from α-Pinene ozonolysis in dry and humid conditions, Environ. Sci. Technol., 41, 6096–6102, https://doi.org/10.1021/es061956y, 2007.
Nah, T., McVay, R. C., Zhang, X., Boyd, C. M., Seinfeld, J. H., and Ng, N. L.: Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with α-pinene ozonolysis, Atmos. Chem. Phys., 16, 9361–9379, https://doi.org/10.5194/acp-16-9361-2016, 2016.
Nah, T., McVay, R. C., Pierce, J. R., Seinfeld, J. H., and Ng, N. L.: Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments, Atmos. Chem. Phys., 17, 2297–2310, https://doi.org/10.5194/acp-17-2297-2017, 2017.
Ng, N. L., Kroll, J. H., Keywood, M. D., Bahreini, R., Varutbangkul, V.,
Flagan, R. C., Seinfeld, J. H., Lee, A., and Goldstein, A. H.: Contribution
of first- versus second-generation products to secondary organic aerosols
formed in the oxidation of biogenic hydrocarbons, Environ. Sci. Technol., 40, 2283–2297, https://doi.org/10.1021/es052269u, 2006.
Northcross, A. L. and Jang, M.: Heterogeneous SOA yield from ozonolysis of
monoterpenes in the presence of inorganic acid, Atmos. Environ., 41,
1483–1493, https://doi.org/10.1016/j.atmosenv.2006.10.009, 2007.
Nozière, B., Ekstrom, S., Alsberg, T., and Holmstrom, S.: Radical-initiated
formation of organosulfates and surfactants in atmospheric aerosols, Geophys. Res. Lett., 37, L05806, https://doi.org/10.1029/2009gl041683, 2010.
Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., and
Seinfeld, J. H.: Gas/particle partitioning and secondary organic aerosol
yields, Environ. Sci. Technol., 30, 2580–2585, https://doi.org/10.1021/es950943+, 1996.
Parrish, D. D., Singh, H. B., Molina, L., and Madronich, S.: Air quality
progress in North American megacities: A review, Atmos. Environ.,
45, 7015–7025, https://doi.org/10.1016/j.atmosenv.2011.09.039, 2011.
Pathak, R. K., Presto, A. A., Lane, T. E., Stanier, C. O., Donahue, N. M., and Pandis, S. N.: Ozonolysis of α-pinene: parameterization of secondary organic aerosol mass fraction, Atmos. Chem. Phys., 7, 3811–3821, https://doi.org/10.5194/acp-7-3811-2007, 2007a.
Pathak, R. K., Stanier, C. O., Donahue, N. M., and Pandis, S. N.: Ozonolysis
of α-pinene at atmospherically relevant concentrations: Temperature
dependence of aerosol mass fractions (yields), J. Geophys. Res.-Atmos., 112, D03201, https://doi.org/10.1029/2006jd007436, 2007b.
Peltier, R. E., Sullivan, A. P., Weber, R. J., Brock, C. A., Wollny, A. G., Holloway, J. S., de Gouw, J. A., and Warneke, C.: Fine aerosol bulk composition measured on WP-3D research aircraft in vicinity of the Northeastern United States – results from NEAQS, Atmos. Chem. Phys., 7, 3231–3247, https://doi.org/10.5194/acp-7-3231-2007, 2007.
Reinnig, M. C., Warnke, J., and Hoffmann, T.: Identification of organic
hydroperoxides and hydroperoxy acids in secondary organic aerosol formed
during the ozonolysis of different monoterpenes and sesquiterpenes by
on-line analysis using atmospheric pressure chemical ionization ion trap
mass spectrometry, Rapid Commun. Mass Sp., 23, 1735–1741, https://doi.org/10.1002/rcm.4065, 2009.
Rengarajan, R., Sudheer, A. K., and Sarin, M. M.: Aerosol acidity and
secondary organic aerosol formation during wintertime over urban environment
in western India, Atmos. Environ., 45, 1940–1945, https://doi.org/10.1016/j.atmosenv.2011.01.026, 2011.
Riva, M., Tomaz, S., Cui, T. Q., Lin, Y. H., Perraudin, E., Gold, A., Stone,
E. A., Villenave, E., and Surratt, J. D.: Evidence for an Unrecognized
Secondary Anthropogenic Source of Organosulfates and Sulfonates: Gas-Phase
Oxidation of Polycyclic Aromatic Hydrocarbons in the Presence of Sulfate
Aerosol, Environ. Sci. Technol., 49, 6654–6664, https://doi.org/10.1021/acs.est.5b00836, 2015.
Riva, M., Da Silva Barbosa, T., Lin, Y.-H., Stone, E. A., Gold, A., and Surratt, J. D.: Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes, Atmos. Chem. Phys., 16, 11001–11018, https://doi.org/10.5194/acp-16-11001-2016, 2016.
Saathoff, H., Naumann, K.-H., Möhler, O., Jonsson, Å. M., Hallquist, M., Kiendler-Scharr, A., Mentel, Th. F., Tillmann, R., and Schurath, U.: Temperature dependence of yields of secondary organic aerosols from the ozonolysis of α-pinene and limonene, Atmos. Chem. Phys., 9, 1551–1577, https://doi.org/10.5194/acp-9-1551-2009, 2009.
Saha, P. K. and Grieshop, A. P.: Exploring Divergent Volatility Properties
from Yield and Thermodenuder Measurements of Secondary Organic Aerosol from
α-Pinene Ozonolysis, Environ. Sci. Technol., 50,
5740–5749, https://doi.org/10.1021/acs.est.6b00303, 2016.
Sato, K., Hatakeyama, S., and Imamura, T.: Secondary organic aerosol
formation during the photooxidation of toluene: NOx dependence of chemical composition, J. Phys. Chem. A, 111, 9796–9808, https://doi.org/10.1021/jp071419f, 2007.
Sato, K., Fujitani, Y., Inomata, S., Morino, Y., Tanabe, K., Ramasamy, S., Hikida, T., Shimono, A., Takami, A., Fushimi, A., Kondo, Y., Imamura, T., Tanimoto, H., and Sugata, S.: Studying volatility from composition, dilution, and heating measurements of secondary organic aerosols formed during α-pinene ozonolysis, Atmos. Chem. Phys., 18, 5455–5466, https://doi.org/10.5194/acp-18-5455-2018, 2018.
Sato, K., Fujitani, Y., Inomata, S., Morino, Y., Tanabe, K., Hikida, T., Shimono, A., Takami, A., Fushimi, A., Kondo, Y., Imamura, T., Tanimoto, H., and Sugata, S.: A study of volatility by composition, heating, and dilution measurements of secondary organic aerosol from 1,3,5-trimethylbenzene, Atmos. Chem. Phys., 19, 14901–14915, https://doi.org/10.5194/acp-19-14901-2019, 2019.
Sekimoto, K., Fukuyama, D., and Inomata, S.: Accurate identification of
dimers from α-pinene oxidation using high-resolution collision-induced
dissociation mass spectrometry, J. Mass Spectrom., 55, e4508, https://doi.org/10.1002/jms.4508, 2020.
Seubold, F. H. and Vaughan, W. E.: Acid-catalyzed decomposition of cumene
hydroproxide, J. Am. Chem. Soc., 75, 3790–3792, https://doi.org/10.1021/ja01111a055, 1953.
Shiraiwa, M., Yee, L. D., Schilling, K. A., Loza, C. L., Craven, J. S.,
Zuend, A., Ziemann, P. J., and Seinfeld, J. H.: Size distribution dynamics
reveal particle-phase chemistry in organic aerosol formation, P. Natl. Acad. Sci. USA, 110, 11746–11750, https://doi.org/10.1073/pnas.1307501110, 2013a.
Shiraiwa, M., Zuend, A., Bertram, A. K., and Seinfeld, J. H.: Gas-particle
partitioning of atmospheric aerosols: interplay of physical state, non-ideal
mixing and morphology, Phys. Chem. Chem. Phys., 15, 11441–11453, https://doi.org/10.1039/c3cp51595h, 2013b.
Shiraiwa, M., Ueda, K., Pozzer, A., Lammel, G., Kampf, C. J., Fushimi, A.,
Enami, S., Arangio, A. M., Frohlich-Nowoisky, J., Fujitani, Y., Furuyama,
A., Lakey, P. S. J., Lelieveld, J., Lucas, K., Morino, Y., Poschl, U.,
Takaharna, S., Takami, A., Tong, H. J., Weber, B., Yoshino, A., and Sato,
K.: Aerosol Health Effects from Molecular to Global Scales, Environ. Sci. Technol., 51, 13545–13567, https://doi.org/10.1021/acs.est.7b04417, 2017.
Shrivastava, M., Cappa, C. D., Fan, J. W., Goldstein, A. H., Guenther, A.
B., Jimenez, J. L., Kuang, C., Laskin, A., Martin, S. T., Ng, N. L., Petaja,
T., Pierce, J. R., Rasch, P. J., Roldin, P., Seinfeld, J. H., Shilling, J.,
Smith, J. N., Thornton, J. A., Volkamer, R., Wang, J., Worsnop, D. R.,
Zaveri, R. A., Zelenyuk, A., and Zhang, Q.: Recent advances in understanding
secondary organic aerosol: Implications for global climate
forcing, Rev. Geophys., 55, 509–559, https://doi.org/10.1002/2016rg000540, 2017.
Stangl, C. M., Krasnomowitz, J. M., Apsokardu, M. J., Tiszenkel, L., Ouyang,
Q., Lee, S., and Johnston, M. V.: Sulfur Dioxide Modifies Aerosol Particle
Formation and Growth by Ozonolysis of Monoterpenes and Isoprene, J. Geophys. Res.-Atmos., 124, 4800–4811, https://doi.org/10.1029/2018jd030064, 2019.
Stocker, T. F., Qin, D. H., Plattner, G. K., Alexander, L. V., Allen, S. K.,
Bindoff, N. L., Breon, F. M., Church, J. A., Cubasch, U., Emori, S.,
Forster, P., Friedlingstein, P., Gillett, N., Gregory, J. M., Hartmann, D.
L., Jansen, E., Kirtman, B., Knutti, R., Kanikicharla, K. K., Lemke, P.,
Marotzke, J., Masson-Delmotte, V., Meehl, G. A., Mokhov, I., Piao, S. L.,
Ramaswamy, V., Randall, D., Rhein, M., Rojas, M., Sabine, C., Shindell, D.,
Talley, L. D., Vaughan, D. G., and Xie, S. P.: Climate Change 2013 – The Physical Science Basis, Working Group I Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, USA, 1552 pp., 2014.
Surratt, J. D., Kroll, J. H., Kleindienst, T. E., Edney, E. O., Claeys, M.,
Sorooshian, A., Ng, N. L., Offenberg, J. H., Lewandowski, M., Jaoui, M.,
Flagan, R. C., and Seinfeld, J. H.: Evidence for organosulfates in secondary
organic aerosol, Environ. Sci. Technol., 41, 517–527, https://doi.org/10.1021/es062081q, 2007.
Surratt, J. D., Gomez-Gonzalez, Y., Chan, A. W. H., Vermeylen, R.,
Shahgholi, M., Kleindienst, T. E., Edney, E. O., Offenberg, J. H.,
Lewandowski, M., Jaoui, M., Maenhaut, W., Claeys, M., Flagan, R. C., and
Seinfeld, J. H.: Organosulfate formation in biogenic secondary organic
aerosol, J. Phys. Chem. A, 112, 8345–8378, https://doi.org/10.1021/jp802310p, 2008.
Takahama, S., Davidson, C. I., and Pandis, S. N.: Semicontinuous
measurements of organic carbon and acidity during the Pittsburgh air quality
study: Implications for acid-catalyzed organic aerosol formation, Environ. Sci. Technol., 40, 2191–2199, https://doi.org/10.1021/es050856+, 2006.
Tang, I. N. and Munkelwitz, H. R.: Aerosol growth studies – III ammonium
bisulfate aerosols in a moist atmosphere, J. Aerosol Sci., 8,
321–330, https://doi.org/10.1016/0021-8502(77)90019-2, 1977.
Tanner, R. L., Olszyna, K. J., Edgerton, E. S., Knipping, E., and Shaw, S.
L.: Searching for evidence of acid-catalyzed enhancement of secondary
organic aerosol formation using ambient aerosol data, Atmos. Environ., 43, 3440–3444, https://doi.org/10.1016/j.atmosenv.2009.03.045, 2009.
Tao, S., Lu, X., Levac, N., Bateman, A. P., Nguyen, T. B., Bones, D. L.,
Nizkorodov, S. A., Laskin, J., Laskin, A., and Yang, X.: Molecular
Characterization of Organosulfates in Organic Aerosols from Shanghai and Los
Angeles Urban Areas by Nanospray-Desorption Electrospray Ionization
High-Resolution Mass Spectrometry, Environ. Sci. Technol.,
48, 10993–11001, https://doi.org/10.1021/es5024674, 2014.
Tilmes, S., Hodzic, A., Emmons, L. K., Mills, M. J., Gettelman, A.,
Kinnison, D. E., Park, M., Lamarque, J. F., Vitt, F., Shrivastava, M.,
Campuzano-Jost, P., Jimenez, J. L., and Liu, X.: Climate Forcing and Trends
of Organic Aerosols in the Community Earth System Model (CESM2),
J. Adv. Model. Earth Sy., 11, 4323–4351, https://doi.org/10.1029/2019ms001827, 2019.
von Hessberg, C., von Hessberg, P., Pöschl, U., Bilde, M., Nielsen, O. J., and Moortgat, G. K.: Temperature and humidity dependence of secondary organic aerosol yield from the ozonolysis of β-pinene, Atmos. Chem. Phys., 9, 3583–3599, https://doi.org/10.5194/acp-9-3583-2009, 2009.
Wang, J., Doussin, J. F., Perrier, S., Perraudin, E., Katrib, Y., Pangui, E., and Picquet-Varrault, B.: Design of a new multi-phase experimental simulation chamber for atmospheric photosmog, aerosol and cloud chemistry research, Atmos. Meas. Tech., 4, 2465–2494, https://doi.org/10.5194/amt-4-2465-2011, 2011.
Wang, N., Jorga, S. D., Pierce, J. R., Donahue, N. M., and Pandis, S. N.: Particle wall-loss correction methods in smog chamber experiments, Atmos. Meas. Tech., 11, 6577–6588, https://doi.org/10.5194/amt-11-6577-2018, 2018a.
Wang, S. Y., Zhou, S. M., Tao, Y., Tsui, W. G., Ye, J. H., Yu, J. Z.,
Murphy, J. G., McNeill, V. F., Abbatt, J. P. D., and Chan, A. W. H.: Organic
Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate, Environ. Sci. Technol., 53, 10695–10704, https://doi.org/10.1021/acs.est.9b02591, 2019.
Wang, X., Liu, T., Bernard, F., Ding, X., Wen, S., Zhang, Y., Zhang, Z., He, Q., Lü, S., Chen, J., Saunders, S., and Yu, J.: Design and characterization of a smog chamber for studying gas-phase chemical mechanisms and aerosol formation, Atmos. Meas. Tech., 7, 301–313, https://doi.org/10.5194/amt-7-301-2014, 2014.
Wang, X. K., Rossignol, S., Ma, Y., Yao, L., Wang, M. Y., Chen, J. M., George, C., and Wang, L.: Molecular characterization of atmospheric particulate organosulfates in three megacities at the middle and lower reaches of the Yangtze River, Atmos. Chem. Phys., 16, 2285–2298, https://doi.org/10.5194/acp-16-2285-2016, 2016.
Wang, Y., Hu, M., Guo, S., Wang, Y., Zheng, J., Yang, Y., Zhu, W., Tang, R., Li, X., Liu, Y., Le Breton, M., Du, Z., Shang, D., Wu, Y., Wu, Z., Song, Y., Lou, S., Hallquist, M., and Yu, J.: The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing, Atmos. Chem. Phys., 18, 10693–10713, https://doi.org/10.5194/acp-18-10693-2018, 2018b.
Yasmeen, F., Vermeylen, R., Szmigielski, R., Iinuma, Y., Böge, O., Herrmann, H., Maenhaut, W., and Claeys, M.: Terpenylic acid and related compounds: precursors for dimers in secondary organic aerosol from the ozonolysis of α- and β-pinene, Atmos. Chem. Phys., 10, 9383–9392, https://doi.org/10.5194/acp-10-9383-2010, 2010.
Yassine, M. M., Dabek-Zlotorzynska, E., Harir, M., and Schmitt-Kopplin, P.:
Identification of Weak and Strong Organic Acids in Atmospheric Aerosols by
Capillary Electrophoresis/Mass Spectrometry and Ultra-High-Resolution
Fourier Transform Ion Cyclotron Resonance Mass
Spectrometry, Anal. Chem., 84, 6586–6594, https://doi.org/10.1021/ac300798g, 2012.
Ye, J., Abbatt, J. P. D., and Chan, A. W. H.: Novel pathway of SO2 oxidation in the atmosphere: reactions with monoterpene ozonolysis intermediates and secondary organic aerosol, Atmos. Chem. Phys., 18, 5549–5565, https://doi.org/10.5194/acp-18-5549-2018, 2018.
Yu, J. Z., Cocker, D. R., Griffin, R. J., Flagan, R. C., and Seinfeld, J.
H.: Gas-phase ozone oxidation of monoterpenes: Gaseous and particulate
products, J. Atmos. Chem., 34, 207–258, https://doi.org/10.1023/a:1006254930583, 1999.
Zhang, Q., Jimenez, J. L., Worsnop, D. R., and Canagaratna, M.: A case study
of urban particle acidity and its influence on secondary organic aerosol, Environ. Sci. Technol., 41, 3213–3219, https://doi.org/10.1021/es061812j, 2007.
Zhang, X., Cappa, C. D., Jathar, S. H., McVay, R. C., Ensberg, J. J.,
Kleeman, M. J., and Seinfeld, J. H.: Influence of vapor wall loss in
laboratory chambers on yields of secondary organic aerosol, P. Natl. Acad. Sci. USA, 111, 5802–5807, https://doi.org/10.1073/pnas.1404727111, 2014.
Zhang, X., McVay, R. C., Huang, D. D., Dalleska, N. F., Aumont, B., Flagan,
R. C., and Seinfeld, J. H.: Formation and evolution of molecular products in
α-pinene secondary organic aerosol, P. Natl. Acad. Sci. USA, 112, 14168–14173, https://doi.org/10.1073/pnas.1517742112, 2015.
Zhang, X., Lambe, A. T., Upshur, M. A., Brooks, W. A., Be, A. G., Thomson,
R. J., Geiger, F. M., Surratt, J. D., Zhang, Z. F., Gold, A., Graf, S.,
Cubison, M. J., Groessl, M., Jayne, J. T., Worsnop, D. R., and Canagaratna,
M. R.: Highly Oxygenated Multifunctional Compounds in α-Pinene Secondary Organic Aerosol, Environ. Sci. Technol., 51, 5932–5940, https://doi.org/10.1021/acs.est.6b06588, 2017.
Zhao, R., Kenseth, C. M., Huang, Y. L., Dalleska, N. F., Kuang, X. B. M.,
Chen, J. R., Paulson, S. E., and Seinfeld, J. H.: Rapid Aqueous-Phase
Hydrolysis of Ester Hydroperoxides Arising from Criegee Intermediates and
Organic Acids, J. Phys. Chem. A, 122, 5190–5201, https://doi.org/10.1021/acs.jpca.8b02195, 2018.
Zhou, S. M., Shiraiwa, M., McWhinney, R. D., Poschl, U., and Abbatt, J. P.
D.: Kinetic limitations in gas-particle reactions arising from slow
diffusion in secondary organic aerosol, Faraday Discuss., 165, 391–406, https://doi.org/10.1039/c3fd00030c, 2013.
Zhou, S. Z., Wang, Z., Gao, R., Xue, L. K., Yuan, C., Wang, T., Gao, X. M.,
Wang, X. F., Nie, W., Xu, Z., Zhang, Q. Z., and Wang, W. X.: Formation of
secondary organic carbon and long-range transport of carbonaceous aerosols
at Mount Heng in South China, Atmos. Environ., 63, 203–212, https://doi.org/10.1016/j.atmosenv.2012.09.021, 2012.
Ziemann, P. J. and Atkinson, R.: Kinetics, products, and mechanisms of
secondary organic aerosol formation, Chem. Soc. Rev., 41,
6582–6605, https://doi.org/10.1039/c2cs35122f, 2012.
Short summary
The temperature and acidity dependence of yields and chemical compositions of the α-pinene ozonolysis SOA were systematically investigated using a newly developed compact chamber system. Increases in SOA yields were observed with the decrease in temperature and under acidic seed conditions. The differences in chemical compositions between acidic and neutral seed conditions were characterized and explained from the viewpoints of acid-catalyzed reactions. Some organosulfates were newly detected.
The temperature and acidity dependence of yields and chemical compositions of the α-pinene...
Altmetrics
Final-revised paper
Preprint