Articles | Volume 21, issue 23
https://doi.org/10.5194/acp-21-17759-2021
https://doi.org/10.5194/acp-21-17759-2021
Research article
 | 
06 Dec 2021
Research article |  | 06 Dec 2021

Synergetic effects of NH3 and NOx on the production and optical absorption of secondary organic aerosol formation from toluene photooxidation

Shijie Liu, Dandan Huang, Yiqian Wang, Si Zhang, Xiaodi Liu, Can Wu, Wei Du, and Gehui Wang

Related authors

Different physicochemical behaviors of nitrate and ammonium during transport: a case study on Mt. Hua, China
Can Wu, Cong Cao, Jianjun Li, Shaojun Lv, Jin Li, Xiaodi Liu, Si Zhang, Shijie Liu, Fan Zhang, Jingjing Meng, and Gehui Wang
Atmos. Chem. Phys., 22, 15621–15635, https://doi.org/10.5194/acp-22-15621-2022,https://doi.org/10.5194/acp-22-15621-2022, 2022
Short summary
Photooxidation of cyclohexene in the presence of SO2: SOA yield and chemical composition
Shijie Liu, Long Jia, Yongfu Xu, Narcisse T. Tsona, Shuangshuang Ge, and Lin Du
Atmos. Chem. Phys., 17, 13329–13343, https://doi.org/10.5194/acp-17-13329-2017,https://doi.org/10.5194/acp-17-13329-2017, 2017
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Nocturnal atmospheric synergistic oxidation reduces the formation of low-volatility organic compounds from biogenic emissions
Han Zang, Zekun Luo, Chenxi Li, Ziyue Li, Dandan Huang, and Yue Zhao
Atmos. Chem. Phys., 24, 11701–11716, https://doi.org/10.5194/acp-24-11701-2024,https://doi.org/10.5194/acp-24-11701-2024, 2024
Short summary
The interplay between aqueous replacement reaction and the phase state of internally mixed organic/ammonium aerosols
Hui Yang, Fengfeng Dong, Li Xia, Qishen Huang, Shufeng Pang, and Yunhong Zhang
Atmos. Chem. Phys., 24, 11619–11635, https://doi.org/10.5194/acp-24-11619-2024,https://doi.org/10.5194/acp-24-11619-2024, 2024
Short summary
Measurement report: The Fifth International Workshop on Ice Nucleation phase 1 (FIN-01): intercomparison of single-particle mass spectrometers
Xiaoli Shen, David M. Bell, Hugh Coe, Naruki Hiranuma, Fabian Mahrt, Nicholas A. Marsden, Claudia Mohr, Daniel M. Murphy, Harald Saathoff, Johannes Schneider, Jacqueline Wilson, Maria A. Zawadowicz, Alla Zelenyuk, Paul J. DeMott, Ottmar Möhler, and Daniel J. Cziczo
Atmos. Chem. Phys., 24, 10869–10891, https://doi.org/10.5194/acp-24-10869-2024,https://doi.org/10.5194/acp-24-10869-2024, 2024
Short summary
Enhanced Sulfate Formation in Mixed Biomass Burning and Sea-salt Particles Mediated by Photosensitization: Effects of Chloride and Nitrogen-containing Compounds
Rongzhi Tang, Jialiang Ma, Ruifeng Zhang, Weizhen Cui, Yuanyuan Qin, Yangxi Chu, Yiming Qin, Alexander L. Vogel, and Chak K. Chan
EGUsphere, https://doi.org/10.5194/egusphere-2024-2633,https://doi.org/10.5194/egusphere-2024-2633, 2024
Short summary
Characterization of the particle size distribution, mineralogy, and Fe mode of occurrence of dust-emitting sediments from the Mojave Desert, California, USA
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Melani Hernández-Chiriboga, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert Green, Paul Ginoux, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 9155–9176, https://doi.org/10.5194/acp-24-9155-2024,https://doi.org/10.5194/acp-24-9155-2024, 2024
Short summary

Cited articles

Alfarra, M. R., Paulsen, D., Gysel, M., Garforth, A. A., Dommen, J., Prévôt, A. S. H., Worsnop, D. R., Baltensperger, U., and Coe, H.: A mass spectrometric study of secondary organic aerosols formed from the photooxidation of anthropogenic and biogenic precursors in a reaction chamber, Atmos. Chem. Phys., 6, 5279–5293, https://doi.org/10.5194/acp-6-5279-2006, 2006. 
Babar, Z. B., Park, J.-H., and Lim, H.-J.: Influence of NH3 on secondary organic aerosols from the ozonolysis and photooxidation of α-pinene in a flow reactor, Atmos. Environ., 164, 71–84, https://doi.org/10.1016/j.atmosenv.2017.05.034, 2017. 
Bates, K., Jacob, D., Li, K., Ivatt, P., Evans, M., Yan, Y., and Lin, J.: Development and evaluation of a new compact mechanism for aromatic oxidation in atmospheric models, Atmos. Chem. Phys. Discuss. [preprint], https://doi.org/10.5194/acp-2021-605, in review, 2021. 
Berkemeier, T., Ammann, M., Mentel, T. F., Poschl, U., and Shiraiwa, M.: Organic nitrate contribution to new particle formation and growth in secondary organic aerosols from α-pinene ozonolysis, Environ. Sci. Technol., 50, 6334–6342, https://doi.org/10.1021/acs.est.6b00961, 2016. 
Chen, Y. and Bond, T. C.: Light absorption by organic carbon from wood combustion, Atmos. Chem. Phys., 10, 1773–1787, https://doi.org/10.5194/acp-10-1773-2010, 2010. 
Download
Short summary
A series of chamber experiments was performed to probe the individual and common effects of NH3 and NOx on toluene secondary organic aerosol (SOA) formation through OH photooxidation. The synergetic effects of NH3 and NOx on the toluene SOA concentration and optical absorption were observed. The higher-volatility products formed in the presence of NOx could precipitate into the particle phase when NH3 was added. The formation pathways of N-containing OAs through NOx or NH3 are also discussed.
Altmetrics
Final-revised paper
Preprint