Articles | Volume 21, issue 23
https://doi.org/10.5194/acp-21-17759-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-17759-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Synergetic effects of NH3 and NOx on the production and optical absorption of secondary organic aerosol formation from toluene photooxidation
Shijie Liu
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Dandan Huang
State Environmental Protection Key Laboratory of Formation and
Prevention of the Urban Air Pollution Complex, Shanghai Academy of
Environmental Sciences, Shanghai 200233, China
Yiqian Wang
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Si Zhang
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Xiaodi Liu
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Can Wu
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Wei Du
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Key Lab of Geographic Information Science of the Ministry of
Education, School of Geographic Sciences, East China Normal University,
Shanghai 210062, China
Institute of Eco-Chongming, Cuiniao Road, Chengjia Zheng, Shanghai
202150, China
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Cited
35 citations as recorded by crossref.
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al.
- Significant coal combustion contribution to water-soluble brown carbon during winter in Xingtai, China: Optical properties and sources D. Li et al.
- Mechanism in the synergistic effects of NH3 and NOx on secondary organic aerosol formation via α-pinene photooxidation S. Liu et al.
- Measurement report: simultaneous measurement on gas- and particle-phase water-soluble organics in Shanghai: enhanced light absorption of transported Asian dust Z. Li et al.
- Characterization of secondary organic aerosol (SOA) formation and toxicity from α-pinene photo-oxidation under effects of nitrogen oxides (NOx) and ammonia (NH3) K. Lui et al.
- Gas-to-Aerosol Phase Partitioning of Atmospheric Water-Soluble Organic Compounds at a Rural Site in China: An Enhancing Effect of NH3 on SOA Formation S. Lv et al.
- Source variability and atmospheric processing of NHx using δ15N: Linkages with WSOC fluorescence indices C. Shaw et al.
- The synergistic effect of NOx and SO2 on the formation and light absorption of secondary organic aerosols from ο-xylene photooxidation S. Liu et al.
- Changes in gas-to-aerosol-phase partitioning ratio of semi-volatile products affect secondary organic aerosol formation from α-pinene photooxidation S. Liu et al.
- NH3 converts Criegee intermediates to nitrogenous organics X. Li et al.
- Characterization of Chemical Components and Optical Properties of Toluene Secondary Organic Aerosol in Presence of Ferric Chloride Fine Particles W. Wang et al.
- Formation of secondary aerosol from emissions of a Euro 6d-compliant gasoline vehicle with a particle filter A. Paul et al.
- Integrating cheminformatics and high-resolution mass spectrometry to elucidate mechanisms of secondary organic aerosol formation from VOCs N. Kien et al.
- Unveiling the distinct differences in synergistic effect of different ammonia emission sources abatement and S-N sources on PM2.5 pollution C. Wen et al.
- Effects of NO2 and RH on secondary organic aerosol formation and light absorption from OH oxidation of ο-xylene S. Liu et al.
- The Combined Effect of NOx and NH3 on Toluene Photooxidation and SOA Formation L. Shijie et al.
- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al.
- Heterogeneous formation and light absorption of secondary organic aerosols from acetone photochemical reactions: remarkably enhancing effects of seeds and ammonia S. Zhang et al.
- Continuous Measurement and Molecular Compositions of Atmospheric Water‐Soluble Brown Carbon in the Nearshore Marine Boundary Layer of Northern China: Secondary Formation and Influencing Factors H. Li et al.
- Smog chamber study on the NOx dependence of SOA from isoprene photo-oxidation: Implication on RO2 chemistry X. Xu et al.
- High-resolution mass spectrometry characterization of secondary organic aerosol formation: Comparative effects of NH3 on biotic and abiotic precursors G. Park et al.
- Organosulfate-driven amplification of secondary organic aerosol formation from isoprene oxidation intermediates: Coupled effects of SO2 and relative humidity S. Wang et al.
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al.
- Secondary organic aerosol in urban China: A distinct chemical regime for air pollution studies R. Huang et al.
- Agricultural fire impacts on brown carbon during different seasons in Northeast China Y. Cheng et al.
- Oligomeric amide formation in secondary organic aerosol from the photooxidation of aromatics in the presence of ammonia P. Dao et al.
- Enhanced secondary organic aerosol formation in the presence of ammonia under NOx- and SO2-rich humid conditions F. Ashraf et al.
- Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China Y. Hong et al.
- NH3-enhanced formation mechanism of highly oxygenated organic molecules from the photooxidation of aromatic and biogenic volatile organic compounds S. Lee et al.
- Measurement report: Formation of tropospheric brown carbon in a lifting air mass C. Wu et al.
- Insights into the spatiotemporal differences of brown carbon in North China plain: Composition, optical properties and sources Y. Sun et al.
- High Contribution of Secondary Formation to Brown Carbon in China Humid Haze: Enhancing Role of Ammonia and Amines B. Xiao et al.
- Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole F. Jiang et al.
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al.
35 citations as recorded by crossref.
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al.
- Significant coal combustion contribution to water-soluble brown carbon during winter in Xingtai, China: Optical properties and sources D. Li et al.
- Mechanism in the synergistic effects of NH3 and NOx on secondary organic aerosol formation via α-pinene photooxidation S. Liu et al.
- Measurement report: simultaneous measurement on gas- and particle-phase water-soluble organics in Shanghai: enhanced light absorption of transported Asian dust Z. Li et al.
- Characterization of secondary organic aerosol (SOA) formation and toxicity from α-pinene photo-oxidation under effects of nitrogen oxides (NOx) and ammonia (NH3) K. Lui et al.
- Gas-to-Aerosol Phase Partitioning of Atmospheric Water-Soluble Organic Compounds at a Rural Site in China: An Enhancing Effect of NH3 on SOA Formation S. Lv et al.
- Source variability and atmospheric processing of NHx using δ15N: Linkages with WSOC fluorescence indices C. Shaw et al.
- The synergistic effect of NOx and SO2 on the formation and light absorption of secondary organic aerosols from ο-xylene photooxidation S. Liu et al.
- Changes in gas-to-aerosol-phase partitioning ratio of semi-volatile products affect secondary organic aerosol formation from α-pinene photooxidation S. Liu et al.
- NH3 converts Criegee intermediates to nitrogenous organics X. Li et al.
- Characterization of Chemical Components and Optical Properties of Toluene Secondary Organic Aerosol in Presence of Ferric Chloride Fine Particles W. Wang et al.
- Formation of secondary aerosol from emissions of a Euro 6d-compliant gasoline vehicle with a particle filter A. Paul et al.
- Integrating cheminformatics and high-resolution mass spectrometry to elucidate mechanisms of secondary organic aerosol formation from VOCs N. Kien et al.
- Unveiling the distinct differences in synergistic effect of different ammonia emission sources abatement and S-N sources on PM2.5 pollution C. Wen et al.
- Effects of NO2 and RH on secondary organic aerosol formation and light absorption from OH oxidation of ο-xylene S. Liu et al.
- The Combined Effect of NOx and NH3 on Toluene Photooxidation and SOA Formation L. Shijie et al.
- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al.
- Heterogeneous formation and light absorption of secondary organic aerosols from acetone photochemical reactions: remarkably enhancing effects of seeds and ammonia S. Zhang et al.
- Continuous Measurement and Molecular Compositions of Atmospheric Water‐Soluble Brown Carbon in the Nearshore Marine Boundary Layer of Northern China: Secondary Formation and Influencing Factors H. Li et al.
- Smog chamber study on the NOx dependence of SOA from isoprene photo-oxidation: Implication on RO2 chemistry X. Xu et al.
- High-resolution mass spectrometry characterization of secondary organic aerosol formation: Comparative effects of NH3 on biotic and abiotic precursors G. Park et al.
- Organosulfate-driven amplification of secondary organic aerosol formation from isoprene oxidation intermediates: Coupled effects of SO2 and relative humidity S. Wang et al.
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al.
- Secondary organic aerosol in urban China: A distinct chemical regime for air pollution studies R. Huang et al.
- Agricultural fire impacts on brown carbon during different seasons in Northeast China Y. Cheng et al.
- Oligomeric amide formation in secondary organic aerosol from the photooxidation of aromatics in the presence of ammonia P. Dao et al.
- Enhanced secondary organic aerosol formation in the presence of ammonia under NOx- and SO2-rich humid conditions F. Ashraf et al.
- Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China Y. Hong et al.
- NH3-enhanced formation mechanism of highly oxygenated organic molecules from the photooxidation of aromatic and biogenic volatile organic compounds S. Lee et al.
- Measurement report: Formation of tropospheric brown carbon in a lifting air mass C. Wu et al.
- Insights into the spatiotemporal differences of brown carbon in North China plain: Composition, optical properties and sources Y. Sun et al.
- High Contribution of Secondary Formation to Brown Carbon in China Humid Haze: Enhancing Role of Ammonia and Amines B. Xiao et al.
- Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole F. Jiang et al.
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al.
Saved (final revised paper)
Latest update: 16 May 2026
Short summary
A series of chamber experiments was performed to probe the individual and common effects of NH3 and NOx on toluene secondary organic aerosol (SOA) formation through OH photooxidation. The synergetic effects of NH3 and NOx on the toluene SOA concentration and optical absorption were observed. The higher-volatility products formed in the presence of NOx could precipitate into the particle phase when NH3 was added. The formation pathways of N-containing OAs through NOx or NH3 are also discussed.
A series of chamber experiments was performed to probe the individual and common effects of NH3...
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