Articles | Volume 21, issue 15
https://doi.org/10.5194/acp-21-11781-2021
https://doi.org/10.5194/acp-21-11781-2021
Research article
 | 
06 Aug 2021
Research article |  | 06 Aug 2021

The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest

Luis M. F. Barreira, Arttu Ylisirniö, Iida Pullinen, Angela Buchholz, Zijun Li, Helina Lipp, Heikki Junninen, Urmas Hõrrak, Steffen M. Noe, Alisa Krasnova, Dmitrii Krasnov, Kaia Kask, Eero Talts, Ülo Niinemets, Jose Ruiz-Jimenez, and Siegfried Schobesberger

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Cited articles

Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, 197–219, https://doi.org/10.1016/S1352-2310(03)00391-1, 2003. 
Barreira, L. M. F., Helin, A., Aurela, M., Teinilä, K., Friman, M., Kangas, L., Niemi, J. V., Portin, H., Kousa, A., Pirjola, L., Rönkkö, T., Saarikoski, S., and Timonen, H.: In-depth characterization of submicron particulate matter inter-annual variations at a street canyon site in northern Europe, Atmos. Chem. Phys., 21, 6297–6314, https://doi.org/10.5194/acp-21-6297-2021, 2021. 
Buchholz, A., Ylisirniö, A., Huang, W., Mohr, C., Canagaratna, M., Worsnop, D. R., Schobesberger, S., and Virtanen, A.: Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation, Atmos. Chem. Phys., 20, 7693–7716, https://doi.org/10.5194/acp-20-7693-2020, 2020. 
Chan, M. N., Surratt, J. D., Chan, A. W. H., Schilling, K., Offenberg, J. H., Lewandowski, M., Edney, E. O., Kleindienst, T. E., Jaoui, M., Edgerton, E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., and Seinfeld, J. H.: Influence of aerosol acidity on the chemical composition of secondary organic aerosol from β-caryophyllene, Atmos. Chem. Phys., 11, 1735–1751, https://doi.org/10.5194/acp-11-1735-2011, 2011. 
Copolovici, L. and Niinemets, Ü.: Temperature dependencies of Henry's law constants for different plant sesquiterpenes, Chemosphere, 138, 751–757, https://doi.org/10.1016/j.chemosphere.2015.07.075, 2015. 
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Short summary
We present results from PM1 atmospheric composition and concentration measurements performed in a springtime hemiboreal forest. Sesquiterpene mixing ratios and particle-phase concentrations of corresponding oxidation products were rapidly increasing on some early mornings. The particle volatility suggested that condensable sesquiterpene oxidation products are rapidly formed in the atmosphere. The results revealed the importance of sesquiterpenes for secondary organic aerosol particulate mass.
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