Articles | Volume 21, issue 15
https://doi.org/10.5194/acp-21-11781-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-11781-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Aug 2021
Research article |
| 06 Aug 2021
| 06 Aug 2021
The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest
Luis M. F. Barreira
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Atmospheric Composition Research, Finnish Meteorological Institute,
Helsinki, Finland
Arttu Ylisirniö
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Iida Pullinen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Angela Buchholz
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Helina Lipp
Laboratory of Environmental Physics, Institute of Physics, University of Tartu, Tartu, Estonia
Heikki Junninen
Laboratory of Environmental Physics, Institute of Physics, University of Tartu, Tartu, Estonia
Urmas Hõrrak
Laboratory of Environmental Physics, Institute of Physics, University of Tartu, Tartu, Estonia
Steffen M. Noe
Institute of Forestry and Rural Engineering, Estonian University of
Life Sciences, Tartu, Estonia
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Alisa Krasnova
Institute of Forestry and Rural Engineering, Estonian University of
Life Sciences, Tartu, Estonia
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Dmitrii Krasnov
Institute of Forestry and Rural Engineering, Estonian University of
Life Sciences, Tartu, Estonia
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Kaia Kask
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Eero Talts
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Ülo Niinemets
Institute of Agricultural and Environmental Sciences, Estonian
University of Life Sciences, Tartu, Estonia
Jose Ruiz-Jimenez
Department of Chemistry, University of Helsinki, P.O. Box 55, 00014
Helsinki, Finland
Institute for Atmospheric and Earth System Research, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Siegfried Schobesberger
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
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Cited
22 citations as recorded by crossref.
- Composition, concentration, and oxidant reactivity of sesquiterpenes in the southeastern U.S. G. Frazier et al. 10.1039/D2EA00059H
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al. 10.1021/acs.estlett.2c00959
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Modeling daytime and nighttime secondary organic aerosol formation via multiphase reactions of biogenic hydrocarbons S. Han & M. Jang 10.5194/acp-23-1209-2023
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- European aerosol phenomenology − 8: Harmonised source apportionment of organic aerosol using 22 Year-long ACSM/AMS datasets G. Chen et al. 10.1016/j.envint.2022.107325
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- Decreasing the Uncertainty in the Comparison of Molecular Fingerprints of Organic Aerosols with H/D Exchange Mass Spectrometry A. Zherebker et al. 10.1021/acs.est.4c06749
- Molecular Characterization of Brown Carbon Chromophores in Atmospherically Relevant Samples and Their Gas‐Particle Distribution and Diurnal Variation in the Atmosphere C. Xing et al. 10.1029/2022JD038142
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Undetected biogenic volatile organic compounds from Norway spruce drive total ozone reactivity measurements S. Thomas et al. 10.5194/acp-23-14627-2023
- Missing Measurements of Sesquiterpene Ozonolysis Rates and Composition Limit Understanding of Atmospheric Reactivity G. Isaacman-VanWertz et al. 10.1021/acs.est.3c10348
- High emission rates and strong temperature response make boreal wetlands a large source of isoprene and terpenes L. Vettikkat et al. 10.5194/acp-23-2683-2023
- Characterizing winter-time brown carbon: Insights into chemical and light-absorption properties in residential and traffic environments L. Barreira et al. 10.1016/j.scitotenv.2024.177089
22 citations as recorded by crossref.
- Composition, concentration, and oxidant reactivity of sesquiterpenes in the southeastern U.S. G. Frazier et al. 10.1039/D2EA00059H
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al. 10.1021/acs.estlett.2c00959
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Modeling daytime and nighttime secondary organic aerosol formation via multiphase reactions of biogenic hydrocarbons S. Han & M. Jang 10.5194/acp-23-1209-2023
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- European aerosol phenomenology − 8: Harmonised source apportionment of organic aerosol using 22 Year-long ACSM/AMS datasets G. Chen et al. 10.1016/j.envint.2022.107325
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- Decreasing the Uncertainty in the Comparison of Molecular Fingerprints of Organic Aerosols with H/D Exchange Mass Spectrometry A. Zherebker et al. 10.1021/acs.est.4c06749
- Molecular Characterization of Brown Carbon Chromophores in Atmospherically Relevant Samples and Their Gas‐Particle Distribution and Diurnal Variation in the Atmosphere C. Xing et al. 10.1029/2022JD038142
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Undetected biogenic volatile organic compounds from Norway spruce drive total ozone reactivity measurements S. Thomas et al. 10.5194/acp-23-14627-2023
- Missing Measurements of Sesquiterpene Ozonolysis Rates and Composition Limit Understanding of Atmospheric Reactivity G. Isaacman-VanWertz et al. 10.1021/acs.est.3c10348
- High emission rates and strong temperature response make boreal wetlands a large source of isoprene and terpenes L. Vettikkat et al. 10.5194/acp-23-2683-2023
- Characterizing winter-time brown carbon: Insights into chemical and light-absorption properties in residential and traffic environments L. Barreira et al. 10.1016/j.scitotenv.2024.177089
Latest update: 20 Nov 2024
Short summary
We present results from PM1 atmospheric composition and concentration measurements performed in a springtime hemiboreal forest. Sesquiterpene mixing ratios and particle-phase concentrations of corresponding oxidation products were rapidly increasing on some early mornings. The particle volatility suggested that condensable sesquiterpene oxidation products are rapidly formed in the atmosphere. The results revealed the importance of sesquiterpenes for secondary organic aerosol particulate mass.
We present results from PM1 atmospheric composition and concentration measurements performed in...
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