Articles | Volume 19, issue 14
https://doi.org/10.5194/acp-19-9563-2019
https://doi.org/10.5194/acp-19-9563-2019
Research article
 | 
30 Jul 2019
Research article |  | 30 Jul 2019

Peroxy radical measurements by ethane – nitric oxide chemical amplification and laser-induced fluorescence during the IRRONIC field campaign in a forest in Indiana

Shuvashish Kundu, Benjamin L. Deming, Michelle M. Lew, Brandon P. Bottorff, Pamela Rickly, Philip S. Stevens, Sebastien Dusanter, Sofia Sklaveniti, Thierry Leonardis, Nadine Locoge, and Ezra C. Wood

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Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Anderson, D. C., Pavelec, J., Daube, C., Herndon, S. C., Knighton, W. B., Lerner, B. M., Roscioli, J. R., Yacovitch, T. I., and Wood, E. C.: Characterization of ozone production in San Antonio, Texas, using measurements of total peroxy radicals, Atmos. Chem. Phys., 19, 2845–2860, https://doi.org/10.5194/acp-19-2845-2019, 2019. 
Andrés-Hernández, M. D., Stone, D., Brookes, D. M., Commane, R., Reeves, C. E., Huntrieser, H., Heard, D. E., Monks, P. S., Burrows, J. P., Schlager, H., Kartal, D., Evans, M. J., Floquet, C. F. A., Ingham, T., Methven, J., and Parker, A. E.: Peroxy radical partitioning during the AMMA radical intercomparison exercise, Atmos. Chem. Phys., 10, 10621–10638, https://doi.org/10.5194/acp-10-10621-2010, 2010. 
Atkinson, R., Aschmann, S. M., Carter, W. P., Winer, A. M., and Pitts Jr., J. N.: Alkyl nitrate formation from the nitrogen oxide (NOx)-air photooxidations of C2–C8 n-alkanes, J. Phys. Chem., 86, 4563–4569, 1982. 
Atkinson, R.: Atmospheric reactions of alkoxy and β-hydroxyalkoxy radicals, Int. J. Chem. Kinet., 29, 99–111, 1997. 
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Short summary
Compounds emitted into the atmosphere are chemically transformed, often leading to new compounds which can affect air pollution and climate. Studying the radicals OH, HO2, and RO2 (organic peroxy radicals) is a crucial activity for assessing how well we understand the rates and products of chemical transformations. In this paper we describe the performance of a new instrument, ECHAMP, for measuring peroxy radicals during its first field deployment.
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