Articles | Volume 19, issue 19
https://doi.org/10.5194/acp-19-12141-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-12141-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
30 Sep 2019
Research article |
| 30 Sep 2019
| 30 Sep 2019
Assessment of the theoretical limit in instrumental detectability of northern high-latitude methane sources using δ13CCH4 atmospheric signals
Thibaud Thonat
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Marielle Saunois
CORRESPONDING AUTHOR
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Isabelle Pison
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Antoine Berchet
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Thomas Hocking
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
Brett F. Thornton
Department of Geological Sciences and Bolin Centre for Climate
Research, Stockholm University, Svante Arrhenius väg 8, 106 91 Stockholm, Sweden
Patrick M. Crill
Department of Geological Sciences and Bolin Centre for Climate
Research, Stockholm University, Svante Arrhenius väg 8, 106 91 Stockholm, Sweden
Philippe Bousquet
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France
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Yunsong Liu, Jean-Daniel Paris, Gregoire Broquet, Violeta Bescós Roy, Tania Meixus Fernandez, Rasmus Andersen, Andrés Russu Berlanga, Emil Christensen, Yann Courtois, Sebastian Dominok, Corentin Dussenne, Travis Eckert, Andrew Finlayson, Aurora Fernández de la Fuente, Catlin Gunn, Ram Hashmonay, Juliano Grigoleto Hayashi, Jonathan Helmore, Soeren Honsel, Fabrizio Innocenti, Matti Irjala, Torgrim Log, Cristina Lopez, Francisco Cortés Martínez, Jonathan Martinez, Adrien Massardier, Helle Gottschalk Nygaard, Paula Agregan Reboredo, Elodie Rousset, Axel Scherello, Matthias Ulbricht, Damien Weidmann, Oliver Williams, Nigel Yarrow, Murès Zarea, Robert Ziegler, Jean Sciare, Mihalis Vrekoussis, and Philippe Bousquet
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Accurate estimation of fluxes of carbon dioxide from the land surface is essential for understanding future impacts of greenhouse gas emissions on the climate system. A wide variety of methods currently exist to estimate these sources and sinks. We are continuing work to develop annual comparisons of these diverse methods in order to clarify what they all actually calculate and to resolve apparent disagreement, in addition to highlighting opportunities for increased understanding.
Sara M. Defratyka, James L. France, Rebecca E. Fisher, Dave Lowry, Julianne M. Fernandez, Semra Bakkaloglu, Camille Yver-Kwok, Jean-Daniel Paris, Philippe Bousquet, Tim Arnold, Chris Rennick, Jon Helmore, Nigel Yarrow, and Euan G. Nisbet
EGUsphere, https://doi.org/10.5194/egusphere-2023-1490, https://doi.org/10.5194/egusphere-2023-1490, 2023
Preprint archived
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We are focused on verification of δ13CH4 measurements in near-source conditions and we have provided an insight into the impact of chosen calculation methods for determined isotopic signatures. Our study offers a step forward for establishing an unified, robust, and reliable analytical technique to determine δ13CH4 of methane sources. Our recommended analytical approach reduces biases and uncertainties coming from measurement conditions, data clustering and various available fitting methods.
Sophie Wittig, Antoine Berchet, Isabelle Pison, Marielle Saunois, Joël Thanwerdas, Adrien Martinez, Jean-Daniel Paris, Toshinobu Machida, Motoki Sasakawa, Douglas E. J. Worthy, Xin Lan, Rona L. Thompson, Espen Sollum, and Mikhail Arshinov
Atmos. Chem. Phys., 23, 6457–6485, https://doi.org/10.5194/acp-23-6457-2023, https://doi.org/10.5194/acp-23-6457-2023, 2023
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Here, an inverse modelling approach is applied to estimate CH4 sources and sinks in the Arctic from 2008 to 2019. We study the magnitude, seasonal patterns and trends from different sources during recent years. We also assess how the current observation network helps to constrain fluxes. We find that constraints are only significant for North America and, to a lesser extent, West Siberia, where the observation network is relatively dense. We find no clear trend over the period of inversion.
Ana Maria Roxana Petrescu, Chunjing Qiu, Matthew J. McGrath, Philippe Peylin, Glen P. Peters, Philippe Ciais, Rona L. Thompson, Aki Tsuruta, Dominik Brunner, Matthias Kuhnert, Bradley Matthews, Paul I. Palmer, Oksana Tarasova, Pierre Regnier, Ronny Lauerwald, David Bastviken, Lena Höglund-Isaksson, Wilfried Winiwarter, Giuseppe Etiope, Tuula Aalto, Gianpaolo Balsamo, Vladislav Bastrikov, Antoine Berchet, Patrick Brockmann, Giancarlo Ciotoli, Giulia Conchedda, Monica Crippa, Frank Dentener, Christine D. Groot Zwaaftink, Diego Guizzardi, Dirk Günther, Jean-Matthieu Haussaire, Sander Houweling, Greet Janssens-Maenhout, Massaer Kouyate, Adrian Leip, Antti Leppänen, Emanuele Lugato, Manon Maisonnier, Alistair J. Manning, Tiina Markkanen, Joe McNorton, Marilena Muntean, Gabriel D. Oreggioni, Prabir K. Patra, Lucia Perugini, Isabelle Pison, Maarit T. Raivonen, Marielle Saunois, Arjo J. Segers, Pete Smith, Efisio Solazzo, Hanqin Tian, Francesco N. Tubiello, Timo Vesala, Guido R. van der Werf, Chris Wilson, and Sönke Zaehle
Earth Syst. Sci. Data, 15, 1197–1268, https://doi.org/10.5194/essd-15-1197-2023, https://doi.org/10.5194/essd-15-1197-2023, 2023
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This study updates the state-of-the-art scientific overview of CH4 and N2O emissions in the EU27 and UK in Petrescu et al. (2021a). Yearly updates are needed to improve the different respective approaches and to inform on the development of formal verification systems. It integrates the most recent emission inventories, process-based model and regional/global inversions, comparing them with UNFCCC national GHG inventories, in support to policy to facilitate real-time verification procedures.
Clément Narbaud, Jean-Daniel Paris, Sophie Wittig, Antoine Berchet, Marielle Saunois, Philippe Nédélec, Boris D. Belan, Mikhail Y. Arshinov, Sergei B. Belan, Denis Davydov, Alexander Fofonov, and Artem Kozlov
Atmos. Chem. Phys., 23, 2293–2314, https://doi.org/10.5194/acp-23-2293-2023, https://doi.org/10.5194/acp-23-2293-2023, 2023
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We measured CH4 and CO2 from aircraft over the Russian Arctic. Analyzing our data with the Lagrangian model FLEXPART, we find a sharp east–west gradient in atmospheric composition. Western Siberia is influenced by strong wetland CH4 emissions, deep CO2 gradient from biospheric uptake, and long-range transport from Europe and North America. Eastern flights document less variability. Over the Arctic Ocean, we find a small influence from marine CH4 emissions compatible with reasonable inventories.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, and Bo Zheng
Atmos. Chem. Phys., 23, 789–807, https://doi.org/10.5194/acp-23-789-2023, https://doi.org/10.5194/acp-23-789-2023, 2023
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The large uncertainties in OH simulated by atmospheric chemistry models hinder accurate estimates of CH4 chemical loss through the bottom-up method. This study presents a new approach based on OH precursor observations and a chemical box model to improve the tropospheric OH distributions simulated by atmospheric chemistry models. Through this approach, both the global OH burden and the corresponding methane chemical loss reach consistency with the top-down method based on MCF inversions.
Joël Thanwerdas, Marielle Saunois, Isabelle Pison, Didier Hauglustaine, Antoine Berchet, Bianca Baier, Colm Sweeney, and Philippe Bousquet
Atmos. Chem. Phys., 22, 15489–15508, https://doi.org/10.5194/acp-22-15489-2022, https://doi.org/10.5194/acp-22-15489-2022, 2022
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Atmospheric methane (CH4) concentrations have been rising since 2007, resulting from an imbalance between CH4 sources and sinks. The CH4 budget is generally estimated through top-down approaches using CH4 and δ13C(CH4) observations as constraints. The oxidation by chlorine (Cl) contributes little to the total oxidation of CH4 but strongly influences δ13C(CH4). Here, we compare multiple recent Cl fields and quantify the influence of Cl concentrations on CH4, δ13C(CH4), and CH4 budget estimates.
Elise Potier, Grégoire Broquet, Yilong Wang, Diego Santaren, Antoine Berchet, Isabelle Pison, Julia Marshall, Philippe Ciais, François-Marie Bréon, and Frédéric Chevallier
Atmos. Meas. Tech., 15, 5261–5288, https://doi.org/10.5194/amt-15-5261-2022, https://doi.org/10.5194/amt-15-5261-2022, 2022
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Atmospheric inversion at local–regional scales over Europe and pseudo-data assimilation are used to evaluate how CO2 and 14CO2 ground-based measurement networks could complement satellite CO2 imagers to monitor fossil fuel (FF) CO2 emissions. This combination significantly improves precision in the FF emission estimates in areas with a dense network but does not strongly support the separation of the FF from the biogenic signals or the spatio-temporal extrapolation of the satellite information.
Yunsong Liu, Jean-Daniel Paris, Mihalis Vrekoussis, Panayiota Antoniou, Christos Constantinides, Maximilien Desservettaz, Christos Keleshis, Olivier Laurent, Andreas Leonidou, Carole Philippon, Panagiotis Vouterakos, Pierre-Yves Quéhé, Philippe Bousquet, and Jean Sciare
Atmos. Meas. Tech., 15, 4431–4442, https://doi.org/10.5194/amt-15-4431-2022, https://doi.org/10.5194/amt-15-4431-2022, 2022
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This paper details laboratory-based and field developments of a cost-effective and compacted UAV CO2 sensor system to address the challenge of measuring CO2 with sufficient precision and acquisition frequency. We assess its performance extensively through laboratory and field tests and provide a case study in an urban area (Nicosia, Cyprus). We therefore expect that this portable system will be widely used for measuring CO2 emission and distribution in natural or urban environments.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, Bruce H. Vaughn, Sylvia Englund Michel, and Philippe Bousquet
Geosci. Model Dev., 15, 4831–4851, https://doi.org/10.5194/gmd-15-4831-2022, https://doi.org/10.5194/gmd-15-4831-2022, 2022
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Estimating CH4 sources by exploiting observations within an inverse modeling framework is a powerful approach. Here, a new system designed to assimilate δ13C(CH4) observations together with CH4 observations is presented. By optimizing both the emissions and associated source signatures of multiple emission categories, this new system can efficiently differentiate the co-located emission categories and provide estimates of CH4 sources that are consistent with isotopic data.
Zhu Deng, Philippe Ciais, Zitely A. Tzompa-Sosa, Marielle Saunois, Chunjing Qiu, Chang Tan, Taochun Sun, Piyu Ke, Yanan Cui, Katsumasa Tanaka, Xin Lin, Rona L. Thompson, Hanqin Tian, Yuanzhi Yao, Yuanyuan Huang, Ronny Lauerwald, Atul K. Jain, Xiaoming Xu, Ana Bastos, Stephen Sitch, Paul I. Palmer, Thomas Lauvaux, Alexandre d'Aspremont, Clément Giron, Antoine Benoit, Benjamin Poulter, Jinfeng Chang, Ana Maria Roxana Petrescu, Steven J. Davis, Zhu Liu, Giacomo Grassi, Clément Albergel, Francesco N. Tubiello, Lucia Perugini, Wouter Peters, and Frédéric Chevallier
Earth Syst. Sci. Data, 14, 1639–1675, https://doi.org/10.5194/essd-14-1639-2022, https://doi.org/10.5194/essd-14-1639-2022, 2022
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In support of the global stocktake of the Paris Agreement on climate change, we proposed a method for reconciling the results of global atmospheric inversions with data from UNFCCC national greenhouse gas inventories (NGHGIs). Here, based on a new global harmonized database that we compiled from the UNFCCC NGHGIs and a comprehensive framework presented in this study to process the results of inversions, we compared their results of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O).
Marine Remaud, Frédéric Chevallier, Fabienne Maignan, Sauveur Belviso, Antoine Berchet, Alexandra Parouffe, Camille Abadie, Cédric Bacour, Sinikka Lennartz, and Philippe Peylin
Atmos. Chem. Phys., 22, 2525–2552, https://doi.org/10.5194/acp-22-2525-2022, https://doi.org/10.5194/acp-22-2525-2022, 2022
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Carbonyl sulfide (COS) has been recognized as a promising indicator of the plant gross primary production (GPP). Here, we assimilate both COS and CO2 measurements into an atmospheric transport model to obtain information on GPP, plant respiration and COS budget. A possible scenario for the period 2008–2019 leads to a global COS biospheric sink of 800 GgS yr−1 and higher oceanic emissions between 400 and 600 GgS yr−1.
Philippe Ciais, Ana Bastos, Frédéric Chevallier, Ronny Lauerwald, Ben Poulter, Josep G. Canadell, Gustaf Hugelius, Robert B. Jackson, Atul Jain, Matthew Jones, Masayuki Kondo, Ingrid T. Luijkx, Prabir K. Patra, Wouter Peters, Julia Pongratz, Ana Maria Roxana Petrescu, Shilong Piao, Chunjing Qiu, Celso Von Randow, Pierre Regnier, Marielle Saunois, Robert Scholes, Anatoly Shvidenko, Hanqin Tian, Hui Yang, Xuhui Wang, and Bo Zheng
Geosci. Model Dev., 15, 1289–1316, https://doi.org/10.5194/gmd-15-1289-2022, https://doi.org/10.5194/gmd-15-1289-2022, 2022
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The second phase of the Regional Carbon Cycle Assessment and Processes (RECCAP) will provide updated quantification and process understanding of CO2, CH4, and N2O emissions and sinks for ten regions of the globe. In this paper, we give definitions, review different methods, and make recommendations for estimating different components of the total land–atmosphere carbon exchange for each region in a consistent and complete approach.
Jan C. Minx, William F. Lamb, Robbie M. Andrew, Josep G. Canadell, Monica Crippa, Niklas Döbbeling, Piers M. Forster, Diego Guizzardi, Jos Olivier, Glen P. Peters, Julia Pongratz, Andy Reisinger, Matthew Rigby, Marielle Saunois, Steven J. Smith, Efisio Solazzo, and Hanqin Tian
Earth Syst. Sci. Data, 13, 5213–5252, https://doi.org/10.5194/essd-13-5213-2021, https://doi.org/10.5194/essd-13-5213-2021, 2021
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We provide a synthetic dataset on anthropogenic greenhouse gas (GHG) emissions for 1970–2018 with a fast-track extension to 2019. We show that GHG emissions continued to rise across all gases and sectors. Annual average GHG emissions growth slowed, but absolute decadal increases have never been higher in human history. We identify a number of data gaps and data quality issues in global inventories and highlight their importance for monitoring progress towards international climate goals.
David Olefeldt, Mikael Hovemyr, McKenzie A. Kuhn, David Bastviken, Theodore J. Bohn, John Connolly, Patrick Crill, Eugénie S. Euskirchen, Sarah A. Finkelstein, Hélène Genet, Guido Grosse, Lorna I. Harris, Liam Heffernan, Manuel Helbig, Gustaf Hugelius, Ryan Hutchins, Sari Juutinen, Mark J. Lara, Avni Malhotra, Kristen Manies, A. David McGuire, Susan M. Natali, Jonathan A. O'Donnell, Frans-Jan W. Parmentier, Aleksi Räsänen, Christina Schädel, Oliver Sonnentag, Maria Strack, Suzanne E. Tank, Claire Treat, Ruth K. Varner, Tarmo Virtanen, Rebecca K. Warren, and Jennifer D. Watts
Earth Syst. Sci. Data, 13, 5127–5149, https://doi.org/10.5194/essd-13-5127-2021, https://doi.org/10.5194/essd-13-5127-2021, 2021
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Wetlands, lakes, and rivers are important sources of the greenhouse gas methane to the atmosphere. To understand current and future methane emissions from northern regions, we need maps that show the extent and distribution of specific types of wetlands, lakes, and rivers. The Boreal–Arctic Wetland and Lake Dataset (BAWLD) provides maps of five wetland types, seven lake types, and three river types for northern regions and will improve our ability to predict future methane emissions.
McKenzie A. Kuhn, Ruth K. Varner, David Bastviken, Patrick Crill, Sally MacIntyre, Merritt Turetsky, Katey Walter Anthony, Anthony D. McGuire, and David Olefeldt
Earth Syst. Sci. Data, 13, 5151–5189, https://doi.org/10.5194/essd-13-5151-2021, https://doi.org/10.5194/essd-13-5151-2021, 2021
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Methane (CH4) emissions from the boreal–Arctic region are globally significant, but the current magnitude of annual emissions is not well defined. Here we present a dataset of surface CH4 fluxes from northern wetlands, lakes, and uplands that was built alongside a compatible land cover dataset, sharing the same classifications. We show CH4 fluxes can be split by broad land cover characteristics. The dataset is useful for comparison against new field data and model parameterization or validation.
Patryk Łakomiec, Jutta Holst, Thomas Friborg, Patrick Crill, Niklas Rakos, Natascha Kljun, Per-Ola Olsson, Lars Eklundh, Andreas Persson, and Janne Rinne
Biogeosciences, 18, 5811–5830, https://doi.org/10.5194/bg-18-5811-2021, https://doi.org/10.5194/bg-18-5811-2021, 2021
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Methane emission from the subarctic mire with heterogeneous permafrost status was measured for the years 2014–2016. Lower methane emission was measured from the palsa mire sector while the thawing wet sector emitted more. Both sectors have a similar annual pattern with a gentle rise during spring and a decrease during autumn. The highest emission was observed in the late summer. Winter emissions were positive during the measurement period and have a significant impact on the annual budgets.
Malika Menoud, Carina van der Veen, Jaroslaw Necki, Jakub Bartyzel, Barbara Szénási, Mila Stanisavljević, Isabelle Pison, Philippe Bousquet, and Thomas Röckmann
Atmos. Chem. Phys., 21, 13167–13185, https://doi.org/10.5194/acp-21-13167-2021, https://doi.org/10.5194/acp-21-13167-2021, 2021
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Using measurements of methane isotopes in ambient air and a 3D atmospheric transport model, in Krakow, Poland, we mainly detected fossil-fuel-related sources, coming from coal mining in Silesia and from the use of natural gas in the city. Emission inventories report large emissions from coal mine activity in Silesia, which is in agreement with our measurements. However, methane sources in the urban area of Krakow related to the use of fossil fuels might be underestimated in the inventories.
Antoine Berchet, Espen Sollum, Rona L. Thompson, Isabelle Pison, Joël Thanwerdas, Grégoire Broquet, Frédéric Chevallier, Tuula Aalto, Adrien Berchet, Peter Bergamaschi, Dominik Brunner, Richard Engelen, Audrey Fortems-Cheiney, Christoph Gerbig, Christine D. Groot Zwaaftink, Jean-Matthieu Haussaire, Stephan Henne, Sander Houweling, Ute Karstens, Werner L. Kutsch, Ingrid T. Luijkx, Guillaume Monteil, Paul I. Palmer, Jacob C. A. van Peet, Wouter Peters, Philippe Peylin, Elise Potier, Christian Rödenbeck, Marielle Saunois, Marko Scholze, Aki Tsuruta, and Yuanhong Zhao
Geosci. Model Dev., 14, 5331–5354, https://doi.org/10.5194/gmd-14-5331-2021, https://doi.org/10.5194/gmd-14-5331-2021, 2021
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We present here the Community Inversion Framework (CIF) to help rationalize development efforts and leverage the strengths of individual inversion systems into a comprehensive framework. The CIF is a programming protocol to allow various inversion bricks to be exchanged among researchers.
The ensemble of bricks makes a flexible, transparent and open-source Python-based tool. We describe the main structure and functionalities and demonstrate it in a simple academic case.
Yi Yin, Frederic Chevallier, Philippe Ciais, Philippe Bousquet, Marielle Saunois, Bo Zheng, John Worden, A. Anthony Bloom, Robert J. Parker, Daniel J. Jacob, Edward J. Dlugokencky, and Christian Frankenberg
Atmos. Chem. Phys., 21, 12631–12647, https://doi.org/10.5194/acp-21-12631-2021, https://doi.org/10.5194/acp-21-12631-2021, 2021
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The growth of methane, the second-most important anthropogenic greenhouse gas after carbon dioxide, has been accelerating in recent years. Using an ensemble of multi-tracer atmospheric inversions constrained by surface or satellite observations, we show that global methane emissions increased by nearly 1 % per year from 2010–2017, with leading contributions from the tropics and East Asia.
Jean-Daniel Paris, Aurélie Riandet, Efstratios Bourtsoukidis, Marc Delmotte, Antoine Berchet, Jonathan Williams, Lisa Ernle, Ivan Tadic, Hartwig Harder, and Jos Lelieveld
Atmos. Chem. Phys., 21, 12443–12462, https://doi.org/10.5194/acp-21-12443-2021, https://doi.org/10.5194/acp-21-12443-2021, 2021
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We measured atmospheric methane and CO2 by ship in the Middle East. We probe the origin of methane with a combination of light alkane measurements and modeling. We find strong influence from nearby oil and gas production over the Arabian Gulf. Comparing our data to inventories indicates that inventories overestimate sources from the upstream gas industry but underestimate emissions from oil extraction and processing. The Red Sea was under a complex mixture of sources due to human activity.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Ana Maria Roxana Petrescu, Chunjing Qiu, Philippe Ciais, Rona L. Thompson, Philippe Peylin, Matthew J. McGrath, Efisio Solazzo, Greet Janssens-Maenhout, Francesco N. Tubiello, Peter Bergamaschi, Dominik Brunner, Glen P. Peters, Lena Höglund-Isaksson, Pierre Regnier, Ronny Lauerwald, David Bastviken, Aki Tsuruta, Wilfried Winiwarter, Prabir K. Patra, Matthias Kuhnert, Gabriel D. Oreggioni, Monica Crippa, Marielle Saunois, Lucia Perugini, Tiina Markkanen, Tuula Aalto, Christine D. Groot Zwaaftink, Hanqin Tian, Yuanzhi Yao, Chris Wilson, Giulia Conchedda, Dirk Günther, Adrian Leip, Pete Smith, Jean-Matthieu Haussaire, Antti Leppänen, Alistair J. Manning, Joe McNorton, Patrick Brockmann, and Albertus Johannes Dolman
Earth Syst. Sci. Data, 13, 2307–2362, https://doi.org/10.5194/essd-13-2307-2021, https://doi.org/10.5194/essd-13-2307-2021, 2021
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This study is topical and provides a state-of-the-art scientific overview of data availability from bottom-up and top-down CH4 and N2O emissions in the EU27 and UK. The data integrate recent emission inventories with process-based model data and regional/global inversions for the European domain, aiming at reconciling them with official country-level UNFCCC national GHG inventories in support to policy and to facilitate real-time verification procedures.
Audrey Fortems-Cheiney, Isabelle Pison, Grégoire Broquet, Gaëlle Dufour, Antoine Berchet, Elise Potier, Adriana Coman, Guillaume Siour, and Lorenzo Costantino
Geosci. Model Dev., 14, 2939–2957, https://doi.org/10.5194/gmd-14-2939-2021, https://doi.org/10.5194/gmd-14-2939-2021, 2021
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Up-to-date and accurate emission inventories for air pollutants are essential for understanding their role in the formation of tropospheric ozone and particulate matter, for anticipating pollution peaks and for identifying the key drivers that could help mitigate their emissions. Complementarily with bottom-up inventories, the system described here aims at updating and improving the knowledge on the high spatiotemporal variability of emissions of air pollutants.
Benjamin Gaubert, Louisa K. Emmons, Kevin Raeder, Simone Tilmes, Kazuyuki Miyazaki, Avelino F. Arellano Jr., Nellie Elguindi, Claire Granier, Wenfu Tang, Jérôme Barré, Helen M. Worden, Rebecca R. Buchholz, David P. Edwards, Philipp Franke, Jeffrey L. Anderson, Marielle Saunois, Jason Schroeder, Jung-Hun Woo, Isobel J. Simpson, Donald R. Blake, Simone Meinardi, Paul O. Wennberg, John Crounse, Alex Teng, Michelle Kim, Russell R. Dickerson, Hao He, Xinrong Ren, Sally E. Pusede, and Glenn S. Diskin
Atmos. Chem. Phys., 20, 14617–14647, https://doi.org/10.5194/acp-20-14617-2020, https://doi.org/10.5194/acp-20-14617-2020, 2020
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This study investigates carbon monoxide pollution in East Asia during spring using a numerical model, satellite remote sensing, and aircraft measurements. We found an underestimation of emission sources. Correcting the emission bias can improve air quality forecasting of carbon monoxide and other species including ozone. Results also suggest that controlling VOC and CO emissions, in addition to widespread NOx controls, can improve ozone pollution over East Asia.
Kuang-Yu Chang, William J. Riley, Patrick M. Crill, Robert F. Grant, and Scott R. Saleska
Biogeosciences, 17, 5849–5860, https://doi.org/10.5194/bg-17-5849-2020, https://doi.org/10.5194/bg-17-5849-2020, 2020
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Methane (CH4) is a strong greenhouse gas that can accelerate climate change and offset mitigation efforts. A key assumption embedded in many large-scale climate models is that ecosystem CH4 emissions can be estimated by fixed temperature relations. Here, we demonstrate that CH4 emissions cannot be parameterized by emergent temperature response alone due to variability driven by microbial and abiotic interactions. We also provide mechanistic understanding for observed CH4 emission hysteresis.
Samuel T. Wilson, Alia N. Al-Haj, Annie Bourbonnais, Claudia Frey, Robinson W. Fulweiler, John D. Kessler, Hannah K. Marchant, Jana Milucka, Nicholas E. Ray, Parvadha Suntharalingam, Brett F. Thornton, Robert C. Upstill-Goddard, Thomas S. Weber, Damian L. Arévalo-Martínez, Hermann W. Bange, Heather M. Benway, Daniele Bianchi, Alberto V. Borges, Bonnie X. Chang, Patrick M. Crill, Daniela A. del Valle, Laura Farías, Samantha B. Joye, Annette Kock, Jabrane Labidi, Cara C. Manning, John W. Pohlman, Gregor Rehder, Katy J. Sparrow, Philippe D. Tortell, Tina Treude, David L. Valentine, Bess B. Ward, Simon Yang, and Leonid N. Yurganov
Biogeosciences, 17, 5809–5828, https://doi.org/10.5194/bg-17-5809-2020, https://doi.org/10.5194/bg-17-5809-2020, 2020
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The oceans are a net source of the major greenhouse gases; however there has been little coordination of oceanic methane and nitrous oxide measurements. The scientific community has recently embarked on a series of capacity-building exercises to improve the interoperability of dissolved methane and nitrous oxide measurements. This paper derives from a workshop which discussed the challenges and opportunities for oceanic methane and nitrous oxide research in the near future.
Roger Seco, Thomas Holst, Mikkel Sillesen Matzen, Andreas Westergaard-Nielsen, Tao Li, Tihomir Simin, Joachim Jansen, Patrick Crill, Thomas Friborg, Janne Rinne, and Riikka Rinnan
Atmos. Chem. Phys., 20, 13399–13416, https://doi.org/10.5194/acp-20-13399-2020, https://doi.org/10.5194/acp-20-13399-2020, 2020
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Northern ecosystems exchange climate-relevant trace gases with the atmosphere, including volatile organic compounds (VOCs). We measured VOC fluxes from a subarctic permafrost-free fen and its adjacent lake in northern Sweden. The graminoid-dominated fen emitted mainly isoprene during the peak of the growing season, with a pronounced response to increasing temperatures stronger than assumed by biogenic emission models. The lake was a sink of acetone and acetaldehyde during both periods measured.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 20, 13011–13022, https://doi.org/10.5194/acp-20-13011-2020, https://doi.org/10.5194/acp-20-13011-2020, 2020
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Decadal trends and variations in OH are critical for understanding atmospheric CH4 evolution. We quantify the impacts of OH trends and variations on the CH4 budget by conducting CH4 inversions on a decadal scale with an ensemble of OH fields. We find the negative OH anomalies due to enhanced fires can reduce the optimized CH4 emissions by up to 10 Tg yr−1 during El Niño years and the positive OH trend from 1986 to 2010 results in a ∼ 23 Tg yr−1 additional increase in optimized CH4 emissions.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Edward J. Dlugokencky, Ray L. Langenfelds, Michel Ramonet, Doug Worthy, and Bo Zheng
Atmos. Chem. Phys., 20, 9525–9546, https://doi.org/10.5194/acp-20-9525-2020, https://doi.org/10.5194/acp-20-9525-2020, 2020
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The hydroxyl radical (OH), which is the dominant sink of methane (CH4), plays a key role in closing the global methane budget. This study quantifies how uncertainties in the hydroxyl radical can influence top-down estimates of CH4 emissions based on 4D Bayesian inversions with different OH fields and the same surface observations. We show that uncertainties in CH4 emissions driven by different OH fields are comparable to the uncertainties given by current bottom-up and top-down estimations.
Tuukka Petäjä, Ella-Maria Duplissy, Ksenia Tabakova, Julia Schmale, Barbara Altstädter, Gerard Ancellet, Mikhail Arshinov, Yurii Balin, Urs Baltensperger, Jens Bange, Alison Beamish, Boris Belan, Antoine Berchet, Rossana Bossi, Warren R. L. Cairns, Ralf Ebinghaus, Imad El Haddad, Beatriz Ferreira-Araujo, Anna Franck, Lin Huang, Antti Hyvärinen, Angelika Humbert, Athina-Cerise Kalogridis, Pavel Konstantinov, Astrid Lampert, Matthew MacLeod, Olivier Magand, Alexander Mahura, Louis Marelle, Vladimir Masloboev, Dmitri Moisseev, Vaios Moschos, Niklas Neckel, Tatsuo Onishi, Stefan Osterwalder, Aino Ovaska, Pauli Paasonen, Mikhail Panchenko, Fidel Pankratov, Jakob B. Pernov, Andreas Platis, Olga Popovicheva, Jean-Christophe Raut, Aurélie Riandet, Torsten Sachs, Rosamaria Salvatori, Roberto Salzano, Ludwig Schröder, Martin Schön, Vladimir Shevchenko, Henrik Skov, Jeroen E. Sonke, Andrea Spolaor, Vasileios K. Stathopoulos, Mikko Strahlendorff, Jennie L. Thomas, Vito Vitale, Sterios Vratolis, Carlo Barbante, Sabine Chabrillat, Aurélien Dommergue, Konstantinos Eleftheriadis, Jyri Heilimo, Kathy S. Law, Andreas Massling, Steffen M. Noe, Jean-Daniel Paris, André S. H. Prévôt, Ilona Riipinen, Birgit Wehner, Zhiyong Xie, and Hanna K. Lappalainen
Atmos. Chem. Phys., 20, 8551–8592, https://doi.org/10.5194/acp-20-8551-2020, https://doi.org/10.5194/acp-20-8551-2020, 2020
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The role of polar regions is increasing in terms of megatrends such as globalization, new transport routes, demography, and the use of natural resources with consequent effects on regional and transported pollutant concentrations. Here we summarize initial results from our integrative project exploring the Arctic environment and pollution to deliver data products, metrics, and indicators for stakeholders.
Marielle Saunois, Ann R. Stavert, Ben Poulter, Philippe Bousquet, Josep G. Canadell, Robert B. Jackson, Peter A. Raymond, Edward J. Dlugokencky, Sander Houweling, Prabir K. Patra, Philippe Ciais, Vivek K. Arora, David Bastviken, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Kimberly M. Carlson, Mark Carrol, Simona Castaldi, Naveen Chandra, Cyril Crevoisier, Patrick M. Crill, Kristofer Covey, Charles L. Curry, Giuseppe Etiope, Christian Frankenberg, Nicola Gedney, Michaela I. Hegglin, Lena Höglund-Isaksson, Gustaf Hugelius, Misa Ishizawa, Akihiko Ito, Greet Janssens-Maenhout, Katherine M. Jensen, Fortunat Joos, Thomas Kleinen, Paul B. Krummel, Ray L. Langenfelds, Goulven G. Laruelle, Licheng Liu, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Joe McNorton, Paul A. Miller, Joe R. Melton, Isamu Morino, Jurek Müller, Fabiola Murguia-Flores, Vaishali Naik, Yosuke Niwa, Sergio Noce, Simon O'Doherty, Robert J. Parker, Changhui Peng, Shushi Peng, Glen P. Peters, Catherine Prigent, Ronald Prinn, Michel Ramonet, Pierre Regnier, William J. Riley, Judith A. Rosentreter, Arjo Segers, Isobel J. Simpson, Hao Shi, Steven J. Smith, L. Paul Steele, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Francesco N. Tubiello, Aki Tsuruta, Nicolas Viovy, Apostolos Voulgarakis, Thomas S. Weber, Michiel van Weele, Guido R. van der Werf, Ray F. Weiss, Doug Worthy, Debra Wunch, Yi Yin, Yukio Yoshida, Wenxin Zhang, Zhen Zhang, Yuanhong Zhao, Bo Zheng, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
Earth Syst. Sci. Data, 12, 1561–1623, https://doi.org/10.5194/essd-12-1561-2020, https://doi.org/10.5194/essd-12-1561-2020, 2020
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Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. We have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. This is the second version of the review dedicated to the decadal methane budget, integrating results of top-down and bottom-up estimates.
Nguyen Thanh Duc, Samuel Silverstein, Martin Wik, Patrick Crill, David Bastviken, and Ruth K. Varner
Hydrol. Earth Syst. Sci., 24, 3417–3430, https://doi.org/10.5194/hess-24-3417-2020, https://doi.org/10.5194/hess-24-3417-2020, 2020
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Under rapid ongoing climate change, accurate quantification of natural greenhouse gas emissions in aquatic environments such as lakes and ponds is needed to understand regulation and feedbacks. Building on the rapid development in wireless communication, sensors, and computation technology, we present a low-cost, open-source, automated and remotely accessed and controlled device for carbon dioxide and methane fluxes from open-water environments along with tests showing their potential.
Joachim Jansen, Brett F. Thornton, Alicia Cortés, Jo Snöälv, Martin Wik, Sally MacIntyre, and Patrick M. Crill
Biogeosciences, 17, 1911–1932, https://doi.org/10.5194/bg-17-1911-2020, https://doi.org/10.5194/bg-17-1911-2020, 2020
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Lakes are important emitters of the greenhouse gas methane. We use field observations and a model to evaluate the importance of known drivers of methane production and release. Fast and slow changes of the diffusive flux were governed by wind speed and sediment temperature, respectively. Increased turbulence enhanced release, but storms depleted the lakes of gas and limited emissions. Our findings may inform model studies on the effects of weather and climate change on lake methane emissions.
Antoine Berchet, Isabelle Pison, Patrick M. Crill, Brett Thornton, Philippe Bousquet, Thibaud Thonat, Thomas Hocking, Joël Thanwerdas, Jean-Daniel Paris, and Marielle Saunois
Atmos. Chem. Phys., 20, 3987–3998, https://doi.org/10.5194/acp-20-3987-2020, https://doi.org/10.5194/acp-20-3987-2020, 2020
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Methane isotopes in the atmosphere can help us differentiate between emission processes. A large variety of natural and anthropogenic emission types are active in the Arctic and are unsatisfactorily understood and documented up to now. A ship-based campaign was carried out in summer 2014, providing a unique dataset of isotopic measurements in the Arctic Ocean. Using a chemistry-transport model, we link these measurements to circumpolar emissions and retrieve information about their signature.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Didier A. Hauglustaine, Sophie Szopa, Ann R. Stavert, Nathan Luke Abraham, Alex T. Archibald, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Béatrice Josse, Douglas Kinnison, Ole Kirner, Virginie Marécal, Fiona M. O'Connor, David A. Plummer, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 19, 13701–13723, https://doi.org/10.5194/acp-19-13701-2019, https://doi.org/10.5194/acp-19-13701-2019, 2019
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The role of hydroxyl radical changes in methane trends is debated, hindering our understanding of the methane cycle. This study quantifies how uncertainties in the hydroxyl radical may influence methane abundance in the atmosphere based on the inter-model comparison of hydroxyl radical fields and model simulations of CH4 abundance with different hydroxyl radical scenarios during 2000–2016. We show that hydroxyl radical changes could contribute up to 54 % of model-simulated methane biases.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, Didier Hauglustaine, Michel Ramonet, Cyril Crevoisier, Bianca Baier, Colm Sweeney, and Philippe Bousquet
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-925, https://doi.org/10.5194/acp-2019-925, 2019
Revised manuscript not accepted
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Oxidation by the hydroxyl radical (OH) is the dominant atmospheric sink for methane, contributing to approximately 90 % of the total methane loss. Chemical losses by reaction with atomic oxygen (O1D) and chlorine radicals (Cl) in the stratosphere are other sinks, contributing about 3 % to the total methane destruction. We assess here the impact of atomic Cl on atmospheric methane mixing ratios, methane atmospheric loss and atmospheric isotopic δ13C-CH4 values.
Kuang-Yu Chang, William J. Riley, Patrick M. Crill, Robert F. Grant, Virginia I. Rich, and Scott R. Saleska
The Cryosphere, 13, 647–663, https://doi.org/10.5194/tc-13-647-2019, https://doi.org/10.5194/tc-13-647-2019, 2019
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Permafrost peatlands store large amounts of carbon potentially vulnerable to decomposition under changing climate. We estimated effects of climate forcing biases on carbon cycling at a thawing permafrost peatland in subarctic Sweden. Our results indicate that many climate reanalysis products are cold and wet biased in our study region, leading to erroneous active layer depth and carbon budget estimates. Future studies should recognize the effects of climate forcing uncertainty on carbon cycling.
Marine Remaud, Frédéric Chevallier, Anne Cozic, Xin Lin, and Philippe Bousquet
Geosci. Model Dev., 11, 4489–4513, https://doi.org/10.5194/gmd-11-4489-2018, https://doi.org/10.5194/gmd-11-4489-2018, 2018
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We compare several versions of a global atmospheric transport model for the simulation of CO2. The representation of subgrid-scale processes modulates the interhemispheric gradient and the amplitude of the seasonal cycle in the Northern Hemisphere. It has the largest impact over Brazil. Refining the horizontal resolution improves the simulation near emission hotspots or along the coastlines. The sensitivities to the land surface model and to the increase in vertical resolution are marginal.
Maarten Krol, Marco de Bruine, Lars Killaars, Huug Ouwersloot, Andrea Pozzer, Yi Yin, Frederic Chevallier, Philippe Bousquet, Prabir Patra, Dmitry Belikov, Shamil Maksyutov, Sandip Dhomse, Wuhu Feng, and Martyn P. Chipperfield
Geosci. Model Dev., 11, 3109–3130, https://doi.org/10.5194/gmd-11-3109-2018, https://doi.org/10.5194/gmd-11-3109-2018, 2018
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The TransCom inter-comparison project regularly carries out studies to quantify errors in simulated atmospheric transport. This paper presents the first results of an age of air (AoA) inter-comparison of six global transport models. Following a protocol, six models simulated five tracers from which atmospheric transport times can easily be deduced. Results highlight that inter-model differences associated with atmospheric transport are still large and require further analysis.
Xin Lin, Philippe Ciais, Philippe Bousquet, Michel Ramonet, Yi Yin, Yves Balkanski, Anne Cozic, Marc Delmotte, Nikolaos Evangeliou, Nuggehalli K. Indira, Robin Locatelli, Shushi Peng, Shilong Piao, Marielle Saunois, Panangady S. Swathi, Rong Wang, Camille Yver-Kwok, Yogesh K. Tiwari, and Lingxi Zhou
Atmos. Chem. Phys., 18, 9475–9497, https://doi.org/10.5194/acp-18-9475-2018, https://doi.org/10.5194/acp-18-9475-2018, 2018
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We simulate CH4 and CO2 using a zoomed global transport model with a horizontal resolution of ~50 km over South and East Asia, as well as a standard model version for comparison. Model performance is evaluated for both gases and versions at multiple timescales against a new collection of surface stations over this key GHG-emitting region. The evaluation at different timescales and comparisons between gases and model versions have implications for possible model improvements and inversions.
Abdelhadi El Yazidi, Michel Ramonet, Philippe Ciais, Gregoire Broquet, Isabelle Pison, Amara Abbaris, Dominik Brunner, Sebastien Conil, Marc Delmotte, Francois Gheusi, Frederic Guerin, Lynn Hazan, Nesrine Kachroudi, Giorgos Kouvarakis, Nikolaos Mihalopoulos, Leonard Rivier, and Dominique Serça
Atmos. Meas. Tech., 11, 1599–1614, https://doi.org/10.5194/amt-11-1599-2018, https://doi.org/10.5194/amt-11-1599-2018, 2018
Isabelle Pison, Antoine Berchet, Marielle Saunois, Philippe Bousquet, Grégoire Broquet, Sébastien Conil, Marc Delmotte, Anita Ganesan, Olivier Laurent, Damien Martin, Simon O'Doherty, Michel Ramonet, T. Gerard Spain, Alex Vermeulen, and Camille Yver Kwok
Atmos. Chem. Phys., 18, 3779–3798, https://doi.org/10.5194/acp-18-3779-2018, https://doi.org/10.5194/acp-18-3779-2018, 2018
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Methane emissions on the national scale in France in 2012 are inferred by assimilating continuous atmospheric mixing ratio measurements from nine stations of the European network ICOS. Two complementary inversion set-ups are computed and analysed: (i) a regional run correcting for the spatial distribution of fluxes in France and (ii) a sectorial run correcting fluxes for activity sectors on the national scale. The results are compared with existing inventories and other regional inversions.
Magnus Gålfalk, Martin Karlson, Patrick Crill, Philippe Bousquet, and David Bastviken
Biogeosciences, 15, 1549–1557, https://doi.org/10.5194/bg-15-1549-2018, https://doi.org/10.5194/bg-15-1549-2018, 2018
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We describe a quick in situ method for mapping ground surface cover, calculating areas of each surface type in a 10 x 10 m plot for each measurement. The method is robust, weather-independent, easily carried out, and uses wide-field imaging with a standard remote-controlled camera mounted on a very long extendible monopod from a height of 3–4.5 m. The method enables collection of detailed field reference data, critical in many remote sensing applications, such as wetland mapping.
Peter Bergamaschi, Ute Karstens, Alistair J. Manning, Marielle Saunois, Aki Tsuruta, Antoine Berchet, Alexander T. Vermeulen, Tim Arnold, Greet Janssens-Maenhout, Samuel Hammer, Ingeborg Levin, Martina Schmidt, Michel Ramonet, Morgan Lopez, Jost Lavric, Tuula Aalto, Huilin Chen, Dietrich G. Feist, Christoph Gerbig, László Haszpra, Ove Hermansen, Giovanni Manca, John Moncrieff, Frank Meinhardt, Jaroslaw Necki, Michal Galkowski, Simon O'Doherty, Nina Paramonova, Hubertus A. Scheeren, Martin Steinbacher, and Ed Dlugokencky
Atmos. Chem. Phys., 18, 901–920, https://doi.org/10.5194/acp-18-901-2018, https://doi.org/10.5194/acp-18-901-2018, 2018
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European methane (CH4) emissions are estimated for 2006–2012 using atmospheric in situ measurements from 18 European monitoring stations and 7 different inverse models. Our analysis highlights the potential significant contribution of natural emissions from wetlands (including peatlands and wet soils) to the total European emissions. The top-down estimates of total EU-28 CH4 emissions are broadly consistent with the sum of reported anthropogenic CH4 emissions and the estimated natural emissions.
Sébastien Ars, Grégoire Broquet, Camille Yver Kwok, Yelva Roustan, Lin Wu, Emmanuel Arzoumanian, and Philippe Bousquet
Atmos. Meas. Tech., 10, 5017–5037, https://doi.org/10.5194/amt-10-5017-2017, https://doi.org/10.5194/amt-10-5017-2017, 2017
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This study presents a new concept for estimating the pollutant emission rates of a site combining the tracer release method, local-scale atmospheric transport modelling and a statistical atmospheric inversion approach. The potential of this new concept is evaluated with a practical implementation based on a series of inversions of controlled methane and tracer point sources in different spatial configurations to assess the efficiency of the method in comparison with the classic tracer method.
Mathilde Jammet, Sigrid Dengel, Ernesto Kettner, Frans-Jan W. Parmentier, Martin Wik, Patrick Crill, and Thomas Friborg
Biogeosciences, 14, 5189–5216, https://doi.org/10.5194/bg-14-5189-2017, https://doi.org/10.5194/bg-14-5189-2017, 2017
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The quantitative importance of northern lakes in terrestrial carbon budgets is uncertain, as year-round observations of carbon fluxes are rare. We measured CH4 and CO2 fluxes from a subarctic lake and nearby fen during 2.5 years with one eddy covariance system. We identified drivers of seasonal variability in lake fluxes and show the importance of winter and spring for annual carbon exchange in both ecosystems. The lake as a source of atmospheric carbon partially compensates the fen carbon sink.
Zhiting Wang, Thorsten Warneke, Nicholas M. Deutscher, Justus Notholt, Ute Karstens, Marielle Saunois, Matthias Schneider, Ralf Sussmann, Harjinder Sembhi, David W. T. Griffith, Dave F. Pollard, Rigel Kivi, Christof Petri, Voltaire A. Velazco, Michel Ramonet, and Huilin Chen
Atmos. Chem. Phys., 17, 13283–13295, https://doi.org/10.5194/acp-17-13283-2017, https://doi.org/10.5194/acp-17-13283-2017, 2017
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In this paper we separate the biases of atmospheric methane models into stratospheric and tropospheric parts. It is observed in other studies that simulated total columns of atmospheric methane present a latitudinal bias compared to measurements. The latitudinal gradients are considered to be from the stratosphere. However, our results show that the latitudinal biases could come from the troposphere in two of three models evaluated in this study.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Ray Weiss, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Atmos. Chem. Phys., 17, 11135–11161, https://doi.org/10.5194/acp-17-11135-2017, https://doi.org/10.5194/acp-17-11135-2017, 2017
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Following the Global Methane Budget 2000–2012 published in Saunois et al. (2016), we use the same dataset of bottom-up and top-down approaches to discuss the variations in methane emissions over the period 2000–2012. The changes in emissions are discussed both in terms of trends and quasi-decadal changes. The ensemble gathered here allows us to synthesise the robust changes in terms of regional and sectorial contributions to the increasing methane emissions.
Antoine Berchet, Katrin Zink, Dietmar Oettl, Jürg Brunner, Lukas Emmenegger, and Dominik Brunner
Geosci. Model Dev., 10, 3441–3459, https://doi.org/10.5194/gmd-10-3441-2017, https://doi.org/10.5194/gmd-10-3441-2017, 2017
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We evaluate a new cost-effective method to simulate pollutant dispersion at high resolution on a city-wide domain. The method is based on a catalogue of reference simulations matched to weather observations to produce a sequence of hourly pollution maps. A total of 2 years of simulations are compared with continuous measurements and passive NO2 samplers in the city of Zurich. Spatial and temporal variability proved to be very well reproduced by the method.
Thibaud Thonat, Marielle Saunois, Philippe Bousquet, Isabelle Pison, Zeli Tan, Qianlai Zhuang, Patrick M. Crill, Brett F. Thornton, David Bastviken, Ed J. Dlugokencky, Nikita Zimov, Tuomas Laurila, Juha Hatakka, Ove Hermansen, and Doug E. J. Worthy
Atmos. Chem. Phys., 17, 8371–8394, https://doi.org/10.5194/acp-17-8371-2017, https://doi.org/10.5194/acp-17-8371-2017, 2017
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Atmospheric methane simulations in the Arctic have been made for 2012 and compared to continuous observations at six measurement sites. All methane sources significantly affect the measurements at all stations, at least at the synoptic scale, except for biomass burning. An appropriate modelling framework combined with continuous observations of atmospheric methane enables us to gain knowledge on regional methane sources, including those which are usually poorly represented, such as freshwater.
Zhiting Wang, Thorsten Warneke, Bart Dils, Justus Notholt, and Marielle Saunois
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-435, https://doi.org/10.5194/acp-2017-435, 2017
Revised manuscript not accepted
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It is important to know to what extent the chemistry transport model represents tracer transport in the atmosphere correctly. In this study we evaluate performances of three models in the stratosphere in describing mixing processes there. The results reveal that deficiencies exist in representing mixing processes in mid-latitudes of southern stratosphere. Another related problem of the models is in representing tracer gradients across transport barrier.
Erik Gustafsson, Christoph Humborg, Göran Björk, Christian Stranne, Leif G. Anderson, Marc C. Geibel, Carl-Magnus Mörth, Marcus Sundbom, Igor P. Semiletov, Brett F. Thornton, and Bo G. Gustafsson
Biogeosciences Discuss., https://doi.org/10.5194/bg-2017-115, https://doi.org/10.5194/bg-2017-115, 2017
Preprint withdrawn
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In this study we quantify key carbon cycling processes on the East Siberian Arctic Shelf. A specific aim is to determine the pathways of terrestrial organic carbon (OC) supplied by rivers and coastline erosion – and particularly to what extent degradation of terrestrial OC contributes to air-sea CO2 exchange. We estimate that the shelf is a weak CO2 sink, although this sink is considerably reduced mainly by degradation of eroded OC and to a lesser extent by degradation of riverine OC.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Victor Brovkin, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Charles Curry, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Julia Marshall, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Catherine Prigent, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Paul Steele, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Michiel van Weele, Guido R. van der Werf, Ray Weiss, Christine Wiedinmyer, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Earth Syst. Sci. Data, 8, 697–751, https://doi.org/10.5194/essd-8-697-2016, https://doi.org/10.5194/essd-8-697-2016, 2016
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An accurate assessment of the methane budget is important to understand the atmospheric methane concentrations and trends and to provide realistic pathways for climate change mitigation. The various and diffuse sources of methane as well and its oxidation by a very short lifetime radical challenge this assessment. We quantify the methane sources and sinks as well as their uncertainties based on both bottom-up and top-down approaches provided by a broad international scientific community.
Shushi Peng, Shilong Piao, Philippe Bousquet, Philippe Ciais, Bengang Li, Xin Lin, Shu Tao, Zhiping Wang, Yuan Zhang, and Feng Zhou
Atmos. Chem. Phys., 16, 14545–14562, https://doi.org/10.5194/acp-16-14545-2016, https://doi.org/10.5194/acp-16-14545-2016, 2016
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Methane is an important greenhouse gas, which accounts for about 20 % of the warming induced by long-lived greenhouse gases since 1750. Anthropogenic methane emissions from China may have been growing rapidly in the past decades because of increased coal mining and fast growing livestock. A good long-term methane emissions dataset is still lacking. Here, we produced a detailed bottom-up inventory of anthropogenic methane emissions from the eight major source sectors in China during 1980–2010.
Andreas Ostler, Ralf Sussmann, Prabir K. Patra, Sander Houweling, Marko De Bruine, Gabriele P. Stiller, Florian J. Haenel, Johannes Plieninger, Philippe Bousquet, Yi Yin, Marielle Saunois, Kaley A. Walker, Nicholas M. Deutscher, David W. T. Griffith, Thomas Blumenstock, Frank Hase, Thorsten Warneke, Zhiting Wang, Rigel Kivi, and John Robinson
Atmos. Meas. Tech., 9, 4843–4859, https://doi.org/10.5194/amt-9-4843-2016, https://doi.org/10.5194/amt-9-4843-2016, 2016
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Our evaluation of column-averaged methane (XCH4) in models and TCCON reveals latitudinal biases between 0.4 % and 2.1 % originating from an inter-model spread in stratospheric CH4. Substituting model stratospheric CH4 fields by satellite data significantly reduces the large XCH4 bias observed for one model. For other models, showing only minor biases, the impact is ambiguous; i.e., the satellite uncertainty range hinders a more accurate model evaluation needed to improve inverse modeling.
Cindy Cressot, Isabelle Pison, Peter J. Rayner, Philippe Bousquet, Audrey Fortems-Cheiney, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 9089–9108, https://doi.org/10.5194/acp-16-9089-2016, https://doi.org/10.5194/acp-16-9089-2016, 2016
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Several hypothesis have been made to attribute current trends in atmospheric methane to particular regions. In this context, this work aims at evaluating how well anomalies in methane emissions can be detected at the regional scale with currently available observing systems: two space-borne instruments and a surface network. Our results show that inter-annual analyses of methane emissions inferred by atmospheric inversions should always include an uncertainty assessment.
Alex Boon, Grégoire Broquet, Deborah J. Clifford, Frédéric Chevallier, David M. Butterfield, Isabelle Pison, Michel Ramonet, Jean-Daniel Paris, and Philippe Ciais
Atmos. Chem. Phys., 16, 6735–6756, https://doi.org/10.5194/acp-16-6735-2016, https://doi.org/10.5194/acp-16-6735-2016, 2016
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We measured carbon dioxide and methane concentrations at four near-ground sites located in London, 2012. We investigated the potential for using these measurements, alongside numerical modelling, to help us to understand urban greenhouse gas emissions. Low-level sites were highly sensitive to local emissions, which questions our ability to use measurements from near-ground sites in cities in some modelling applications. A gradient approach was found to be beneficial to reduce model–data errors.
Antoine Berchet, Philippe Bousquet, Isabelle Pison, Robin Locatelli, Frédéric Chevallier, Jean-Daniel Paris, Ed J. Dlugokencky, Tuomas Laurila, Juha Hatakka, Yrjo Viisanen, Doug E. J. Worthy, Euan Nisbet, Rebecca Fisher, James France, David Lowry, Viktor Ivakhov, and Ove Hermansen
Atmos. Chem. Phys., 16, 4147–4157, https://doi.org/10.5194/acp-16-4147-2016, https://doi.org/10.5194/acp-16-4147-2016, 2016
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We propose insights based on atmospheric observations around the Arctic circle to evaluate estimates of methane emissions to the atmosphere from the East Siberian Arctic Shelf. Based on a comprehensive statistical analysis of the observations and of high-resolution transport simulations, annual methane emissions from ESAS are estimated to range from 0.0 to 4.5 TgCH4 yr−1, with a maximum in summer and very low emissions in winter.
Norbert Pirk, Mikhail Mastepanov, Frans-Jan W. Parmentier, Magnus Lund, Patrick Crill, and Torben R. Christensen
Biogeosciences, 13, 903–912, https://doi.org/10.5194/bg-13-903-2016, https://doi.org/10.5194/bg-13-903-2016, 2016
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The exchange of greenhouse gases between the land and the atmosphere is often measured by monitoring the gas concentrations inside a chamber which is placed on the ground. We investigated different ways to calculate the gas exchange rate and identified several different processes which influence the gas exchange measurement.
Y. Yin, F. Chevallier, P. Ciais, G. Broquet, A. Fortems-Cheiney, I. Pison, and M. Saunois
Atmos. Chem. Phys., 15, 13433–13451, https://doi.org/10.5194/acp-15-13433-2015, https://doi.org/10.5194/acp-15-13433-2015, 2015
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We studied the global CO concentration decline over the recent decade with a sophisticated atmospheric inversion system assimilating MOPITT CO retrievals, surface methane and surface methyl chloroform in situ measurements. The inversion interprets the CO concentration decline as a 23% decrease in the CO emissions from 2002 to 2011, twice the negative trend estimated by emission inventories. In contrast to bottom-up inventories, we find negative trends over China and South-east Asia.
T. Thonat, C. Crevoisier, N. A. Scott, A. Chédin, R. Armante, and L. Crépeau
Atmos. Chem. Phys., 15, 13041–13057, https://doi.org/10.5194/acp-15-13041-2015, https://doi.org/10.5194/acp-15-13041-2015, 2015
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Based on 5 years of CO columns derived from the IASI sounder, we show that tropospheric CO displays a diurnal signal with a seasonality and intensity that agrees well with the evolution of fires. We suggest that at night, after the passing of IASI at 21:30, a large amount of CO emissions from the smoldering phase is trapped in the boundary layer before being uplifted the next morning by natural and pyroconvection up to the free troposphere.
A. Berchet, I. Pison, F. Chevallier, J.-D. Paris, P. Bousquet, J.-L. Bonne, M. Y. Arshinov, B. D. Belan, C. Cressot, D. K. Davydov, E. J. Dlugokencky, A. V. Fofonov, A. Galanin, J. Lavrič, T. Machida, R. Parker, M. Sasakawa, R. Spahni, B. D. Stocker, and J. Winderlich
Biogeosciences, 12, 5393–5414, https://doi.org/10.5194/bg-12-5393-2015, https://doi.org/10.5194/bg-12-5393-2015, 2015
R. Locatelli, P. Bousquet, M. Saunois, F. Chevallier, and C. Cressot
Atmos. Chem. Phys., 15, 9765–9780, https://doi.org/10.5194/acp-15-9765-2015, https://doi.org/10.5194/acp-15-9765-2015, 2015
M. S. Torn, A. Chabbi, P. Crill, P. J. Hanson, I. A. Janssens, Y. Luo, C. H. Pries, C. Rumpel, M. W. I. Schmidt, J. Six, M. Schrumpf, and B. Zhu
SOIL, 1, 575–582, https://doi.org/10.5194/soil-1-575-2015, https://doi.org/10.5194/soil-1-575-2015, 2015
A. Berchet, I. Pison, F. Chevallier, P. Bousquet, J.-L. Bonne, and J.-D. Paris
Geosci. Model Dev., 8, 1525–1546, https://doi.org/10.5194/gmd-8-1525-2015, https://doi.org/10.5194/gmd-8-1525-2015, 2015
R. Locatelli, P. Bousquet, F. Hourdin, M. Saunois, A. Cozic, F. Couvreux, J.-Y. Grandpeix, M.-P. Lefebvre, C. Rio, P. Bergamaschi, S. D. Chambers, U. Karstens, V. Kazan, S. van der Laan, H. A. J. Meijer, J. Moncrieff, M. Ramonet, H. A. Scheeren, C. Schlosser, M. Schmidt, A. Vermeulen, and A. G. Williams
Geosci. Model Dev., 8, 129–150, https://doi.org/10.5194/gmd-8-129-2015, https://doi.org/10.5194/gmd-8-129-2015, 2015
P. Bergamaschi, M. Corazza, U. Karstens, M. Athanassiadou, R. L. Thompson, I. Pison, A. J. Manning, P. Bousquet, A. Segers, A. T. Vermeulen, G. Janssens-Maenhout, M. Schmidt, M. Ramonet, F. Meinhardt, T. Aalto, L. Haszpra, J. Moncrieff, M. E. Popa, D. Lowry, M. Steinbacher, A. Jordan, S. O'Doherty, S. Piacentino, and E. Dlugokencky
Atmos. Chem. Phys., 15, 715–736, https://doi.org/10.5194/acp-15-715-2015, https://doi.org/10.5194/acp-15-715-2015, 2015
E. Sundqvist, P. Vestin, P. Crill, T. Persson, and A. Lindroth
Biogeosciences, 11, 6095–6105, https://doi.org/10.5194/bg-11-6095-2014, https://doi.org/10.5194/bg-11-6095-2014, 2014
J. Deng, C. Li, S. Frolking, Y. Zhang, K. Bäckstrand, and P. Crill
Biogeosciences, 11, 4753–4770, https://doi.org/10.5194/bg-11-4753-2014, https://doi.org/10.5194/bg-11-4753-2014, 2014
R. L. Thompson, K. Ishijima, E. Saikawa, M. Corazza, U. Karstens, P. K. Patra, P. Bergamaschi, F. Chevallier, E. Dlugokencky, R. G. Prinn, R. F. Weiss, S. O'Doherty, P. J. Fraser, L. P. Steele, P. B. Krummel, A. Vermeulen, Y. Tohjima, A. Jordan, L. Haszpra, M. Steinbacher, S. Van der Laan, T. Aalto, F. Meinhardt, M. E. Popa, J. Moncrieff, and P. Bousquet
Atmos. Chem. Phys., 14, 6177–6194, https://doi.org/10.5194/acp-14-6177-2014, https://doi.org/10.5194/acp-14-6177-2014, 2014
R. L. Thompson, P. K. Patra, K. Ishijima, E. Saikawa, M. Corazza, U. Karstens, C. Wilson, P. Bergamaschi, E. Dlugokencky, C. Sweeney, R. G. Prinn, R. F. Weiss, S. O'Doherty, P. J. Fraser, L. P. Steele, P. B. Krummel, M. Saunois, M. Chipperfield, and P. Bousquet
Atmos. Chem. Phys., 14, 4349–4368, https://doi.org/10.5194/acp-14-4349-2014, https://doi.org/10.5194/acp-14-4349-2014, 2014
C. Cressot, F. Chevallier, P. Bousquet, C. Crevoisier, E. J. Dlugokencky, A. Fortems-Cheiney, C. Frankenberg, R. Parker, I. Pison, R. A. Scheepmaker, S. A. Montzka, P. B. Krummel, L. P. Steele, and R. L. Langenfelds
Atmos. Chem. Phys., 14, 577–592, https://doi.org/10.5194/acp-14-577-2014, https://doi.org/10.5194/acp-14-577-2014, 2014
I. Pison, B. Ringeval, P. Bousquet, C. Prigent, and F. Papa
Atmos. Chem. Phys., 13, 11609–11623, https://doi.org/10.5194/acp-13-11609-2013, https://doi.org/10.5194/acp-13-11609-2013, 2013
R. Locatelli, P. Bousquet, F. Chevallier, A. Fortems-Cheney, S. Szopa, M. Saunois, A. Agusti-Panareda, D. Bergmann, H. Bian, P. Cameron-Smith, M. P. Chipperfield, E. Gloor, S. Houweling, S. R. Kawa, M. Krol, P. K. Patra, R. G. Prinn, M. Rigby, R. Saito, and C. Wilson
Atmos. Chem. Phys., 13, 9917–9937, https://doi.org/10.5194/acp-13-9917-2013, https://doi.org/10.5194/acp-13-9917-2013, 2013
M. Lopez, M. Schmidt, M. Delmotte, A. Colomb, V. Gros, C. Janssen, S. J. Lehman, D. Mondelain, O. Perrussel, M. Ramonet, I. Xueref-Remy, and P. Bousquet
Atmos. Chem. Phys., 13, 7343–7358, https://doi.org/10.5194/acp-13-7343-2013, https://doi.org/10.5194/acp-13-7343-2013, 2013
A. Berchet, I. Pison, F. Chevallier, P. Bousquet, S. Conil, M. Geever, T. Laurila, J. Lavrič, M. Lopez, J. Moncrieff, J. Necki, M. Ramonet, M. Schmidt, M. Steinbacher, and J. Tarniewicz
Atmos. Chem. Phys., 13, 7115–7132, https://doi.org/10.5194/acp-13-7115-2013, https://doi.org/10.5194/acp-13-7115-2013, 2013
L. Menut, B. Bessagnet, D. Khvorostyanov, M. Beekmann, N. Blond, A. Colette, I. Coll, G. Curci, G. Foret, A. Hodzic, S. Mailler, F. Meleux, J.-L. Monge, I. Pison, G. Siour, S. Turquety, M. Valari, R. Vautard, and M. G. Vivanco
Geosci. Model Dev., 6, 981–1028, https://doi.org/10.5194/gmd-6-981-2013, https://doi.org/10.5194/gmd-6-981-2013, 2013
C. Crevoisier, D. Nobileau, R. Armante, L. Crépeau, T. Machida, Y. Sawa, H. Matsueda, T. Schuck, T. Thonat, J. Pernin, N. A. Scott, and A. Chédin
Atmos. Chem. Phys., 13, 4279–4289, https://doi.org/10.5194/acp-13-4279-2013, https://doi.org/10.5194/acp-13-4279-2013, 2013
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Seasonal, regional, and vertical characteristics of high-carbon-monoxide plumes along with their associated ozone anomalies, as seen by IAGOS between 2002 and 2019
The potential of drone observations to improve air quality predictions by 4D-Var
Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York
Ozone source attribution in polluted European areas during summer 2017 as simulated with MECO(n)
Opinion: Challenges and needs of tropospheric chemical mechanism development
The atmospheric oxidizing capacity in China – Part 2: Sensitivity to emissions of primary pollutants
Role of chemical production and depositional losses on formaldehyde in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM)
Review of source analyses of ambient volatile organic compounds considering reactive losses: methods of reducing loss effects, impacts of losses, and sources
Interpreting summertime hourly variation of NO2 columns with implications for geostationary satellite applications
An investigation into atmospheric nitrous acid (HONO) processes in South Korea
Performance evaluation of UKESM1 for surface ozone across the pan-tropics
Constraining light dependency in modeled emissions through comparison to observed biogenic volatile organic compound (BVOC) concentrations in a southeastern US forest
A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021
Tropospheric ozone precursors: global and regional distributions, trends, and variability
The contribution of transport emissions to ozone mixing ratios and methane lifetime in 2015 and 2050 in the Shared Socioeconomic Pathways (SSPs)
Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis
ACEIC: a comprehensive anthropogenic chlorine emission inventory for China
Impact of methane and other precursor emission reductions on surface ozone in Europe: scenario analysis using the European Monitoring and Evaluation Programme (EMEP) Meteorological Synthesizing Centre – West (MSC-W) model
Verifying national inventory-based combustion emissions of CO2 across the UK and mainland Europe using satellite observations of atmospheric CO and CO2
An improved estimate of inorganic iodine emissions from the ocean using a coupled surface microlayer box model
Impact of improved representation of volatile organic compound emissions and production of NOx reservoirs on modeled urban ozone production
The effect of different climate and air quality policies in China on in situ ozone production in Beijing
Assessing the relative impacts of satellite ozone and its precursor observations to improve global tropospheric ozone analysis using multiple chemical reanalysis systems
Evaluating present-day and future impacts of agricultural ammonia emissions on atmospheric chemistry and climate
Enhancing long-term trend simulation of the global tropospheric hydroxyl (TOH) and its drivers from 2005 to 2019: a synergistic integration of model simulations and satellite observations
Intercomparison of GEOS-Chem and CAM-chem tropospheric oxidant chemistry within the Community Earth System Model version 2 (CESM2)
Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation
Air pollution satellite-based CO2 emission inversion: system evaluation, sensitivity analysis, and future perspective
Anthropogenic emission controls reduce summertime ozone-temperature sensitivity in the United States
Large contributions of soil emissions to the atmospheric nitrogen budget and their impacts on air quality and temperature rise in North China
Why did ozone concentrations remain high during Shanghai's static management? A statistical and radical-chemistry perspective
Impact of introducing electric vehicles on ground-level O3 and PM2.5 in the Greater Tokyo Area: Yearly trends and the importance of changes in the Urban Heat Island effect
Revising VOC emissions speciation improves the simulation of global background ethane and propane
Changes in South American surface ozone trends: exploring the influences of precursors and extreme events
Evaluating NOx stack plume emissions using a high-resolution atmospheric chemistry model and satellite-derived NO2 columns
NOx emissions in France in 2019–2021 as estimated by the high-spatial-resolution assimilation of TROPOMI NO2 observations
Urban ozone formation and sensitivities to volatile chemical products, cooking emissions, and NOx across the Los Angeles Basin
Aggravated surface O3 pollution primarily driven by meteorological variations in China during the 2020 COVID-19 pandemic lockdown period
Identifying decadal trends in deweathered concentrations of criteria air pollutants in Canadian urban atmospheres with machine learning approaches
Evaluation of modelled versus observed non-methane volatile organic compounds at European Monitoring and Evaluation Programme sites in Europe
Constraining non-methane VOC emissions with TROPOMI HCHO observations: impact on summertime ozone simulation in August 2022 in China
Insights on ozone pollution control in urban areas by decoupling meteorological factors based on machine learning
Revealing the significant acceleration of hydrofluorocarbon (HFC) emissions in eastern Asia through long-term atmospheric observations
Interpreting Geostationary Environment Monitoring Spectrometer (GEMS) geostationary satellite observations of the diurnal variation in nitrogen dioxide (NO2) over East Asia
An intercomparison of satellite, airborne, and ground-level observations with WRF–CAMx simulations of NO2 columns over Houston, Texas, during the September 2021 TRACER-AQ campaign
Investigating processes influencing simulation of local Arctic wintertime anthropogenic pollution in Fairbanks, Alaska during ALPACA-2022
Interannual variability of summertime formaldehyde (HCHO) vertical column density and its main drivers at northern high latitudes
The impact of multi-decadal changes in VOC speciation on urban ozone chemistry: a case study in Birmingham, United Kingdom
Technical note: Challenges in detecting free tropospheric ozone trends in a sparsely sampled environment
Combined assimilation of NOAA surface and MIPAS satellite observations to constrain the global budget of carbonyl sulfide
Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Our study examines intense-carbon-monoxide (CO) pollution events measured by commercial aircraft from the In-service Aircraft for a Global Observing System (IAGOS) research infrastructure. We combine these measurements with the SOFT-IO model to trace the origin of the observed CO. A comprehensive analysis of the geographical origin, source type, seasonal variation, and ozone levels of these pollution events is provided.
Hassnae Erraji, Philipp Franke, Astrid Lampert, Tobias Schuldt, Ralf Tillmann, Andreas Wahner, and Anne Caroline Lange
Atmos. Chem. Phys., 24, 13913–13934, https://doi.org/10.5194/acp-24-13913-2024, https://doi.org/10.5194/acp-24-13913-2024, 2024
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Four-dimensional variational data assimilation allows for the simultaneous optimisation of initial values and emission rates by using trace-gas profiles from drone observations in a regional air quality model. Assimilated profiles positively impact the representation of air pollutants in the model by improving their vertical distribution and ground-level concentrations. This case study highlights the potential of drone data to enhance air quality analyses including local emission evaluation.
Christopher Lawrence, Mary Barth, John Orlando, Paul Casson, Richard Brandt, Daniel Kelting, Elizabeth Yerger, and Sara Lance
Atmos. Chem. Phys., 24, 13693–13713, https://doi.org/10.5194/acp-24-13693-2024, https://doi.org/10.5194/acp-24-13693-2024, 2024
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This work uses chemical transport and box modeling to study the gas- and aqueous-phase production of organic acid concentrations measured in cloud water at the summit of Whiteface Mountain on 1 July 2018. Isoprene was the major source of formic, acetic, and oxalic acid. Gas-phase chemistry greatly underestimated formic and acetic acid, indicating missing sources, while cloud chemistry was a key source of oxalic acid. More studies of organic acids are required to better constrain their sources.
Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 24, 13503–13523, https://doi.org/10.5194/acp-24-13503-2024, https://doi.org/10.5194/acp-24-13503-2024, 2024
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Anthropogenic emissions are a major source of precursors of tropospheric ozone. As ozone formation is highly non-linear, we apply a global–regional chemistry–climate model with a source attribution method (tagging) to quantify the contribution of anthropogenic emissions to ozone. Our analysis shows that the contribution of European anthropogenic emissions largely increases during large ozone periods, indicating that emissions from these sectors drive ozone values.
Barbara Ervens, Andrew Rickard, Bernard Aumont, William P. L. Carter, Max McGillen, Abdelwahid Mellouki, John Orlando, Bénédicte Picquet-Varrault, Paul Seakins, William R. Stockwell, Luc Vereecken, and Timothy J. Wallington
Atmos. Chem. Phys., 24, 13317–13339, https://doi.org/10.5194/acp-24-13317-2024, https://doi.org/10.5194/acp-24-13317-2024, 2024
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Chemical mechanisms describe the chemical processes in atmospheric models that are used to describe the changes in the atmospheric composition. Therefore, accurate chemical mechanisms are necessary to predict the evolution of air pollution and climate change. The article describes all steps that are needed to build chemical mechanisms and discusses the advances and needs of experimental and theoretical research activities needed to build reliable chemical mechanisms.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
Atmos. Chem. Phys., 24, 12943–12962, https://doi.org/10.5194/acp-24-12943-2024, https://doi.org/10.5194/acp-24-12943-2024, 2024
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This paper employs a regional chemical transport model to quantify the sensitivity of air pollutants and photochemical parameters to specified emission reductions in China for representative winter and summer conditions. The study provides insights into further air quality control in China with reduced primary emissions.
T. Nash Skipper, Emma L. D'Ambro, Forwood C. Wiser, V. Faye McNeill, Rebecca H. Schwantes, Barron H. Henderson, Ivan R. Piletic, Colleen B. Baublitz, Jesse O. Bash, Andrew R. Whitehill, Lukas C. Valin, Asher P. Mouat, Jennifer Kaiser, Glenn M. Wolfe, Jason M. St. Clair, Thomas F. Hanisco, Alan Fried, Bryan K. Place, and Havala O.T. Pye
Atmos. Chem. Phys., 24, 12903–12924, https://doi.org/10.5194/acp-24-12903-2024, https://doi.org/10.5194/acp-24-12903-2024, 2024
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We develop the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) version 2 to improve predictions of formaldehyde in ambient air compared to satellite-, aircraft-, and ground-based observations. With the updated chemistry, we estimate the cancer risk from inhalation exposure to ambient formaldehyde across the contiguous USA and predict that 40 % of this risk is controllable through reductions in anthropogenic emissions of nitrogen oxides and reactive organic carbon.
Baoshuang Liu, Yao Gu, Yutong Wu, Qili Dai, Shaojie Song, Yinchang Feng, and Philip K. Hopke
Atmos. Chem. Phys., 24, 12861–12879, https://doi.org/10.5194/acp-24-12861-2024, https://doi.org/10.5194/acp-24-12861-2024, 2024
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Reactive loss of volatile organic compounds (VOCs) is a long-term issue yet to be resolved in VOC source analyses. We assess common methods of, and existing issues in, reducing losses, impacts of losses, and sources in current source analyses. We offer a potential supporting role for solving issues of VOC conversion. Source analyses of consumed VOCs that reacted to produce ozone and secondary organic aerosols can play an important role in the effective control of secondary pollution in air.
Deepangsu Chatterjee, Randall V. Martin, Chi Li, Dandan Zhang, Haihui Zhu, Daven K. Henze, James H. Crawford, Ronald C. Cohen, Lok N. Lamsal, and Alexander M. Cede
Atmos. Chem. Phys., 24, 12687–12706, https://doi.org/10.5194/acp-24-12687-2024, https://doi.org/10.5194/acp-24-12687-2024, 2024
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We investigate the hourly variation of NO2 columns and surface concentrations by applying the GEOS-Chem model to interpret aircraft and ground-based measurements over the US and Pandora sun photometer measurements over the US, Europe, and Asia. Corrections to the Pandora columns and finer model resolution improve the modeled representation of the summertime hourly variation of total NO2 columns to explain the weaker hourly variation in NO2 columns than at the surface.
Kiyeon Kim, Kyung Man Han, Chul Han Song, Hyojun Lee, Ross Beardsley, Jinhyeok Yu, Greg Yarwood, Bonyoung Koo, Jasper Madalipay, Jung-Hun Woo, and Seogju Cho
Atmos. Chem. Phys., 24, 12575–12593, https://doi.org/10.5194/acp-24-12575-2024, https://doi.org/10.5194/acp-24-12575-2024, 2024
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We incorporated each HONO process into the current CMAQ modeling framework to enhance the accuracy of HONO mixing ratio predictions. These results expand our understanding of HONO photochemistry and identify crucial sources of HONO that impact the total HONO budget in Seoul, South Korea. Through this investigation, we contribute to resolving discrepancies in understanding chemical transport models, with implications for better air quality management and environmental protection in the region.
Flossie Brown, Gerd Folberth, Stephen Sitch, Paulo Artaxo, Marijn Bauters, Pascal Boeckx, Alexander W. Cheesman, Matteo Detto, Ninong Komala, Luciana Rizzo, Nestor Rojas, Ines dos Santos Vieira, Steven Turnock, Hans Verbeeck, and Alfonso Zambrano
Atmos. Chem. Phys., 24, 12537–12555, https://doi.org/10.5194/acp-24-12537-2024, https://doi.org/10.5194/acp-24-12537-2024, 2024
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Ozone is a pollutant that is detrimental to human and plant health. Ozone monitoring sites in the tropics are limited, so models are often used to understand ozone exposure. We use measurements from the tropics to evaluate ozone from the UK Earth system model, UKESM1. UKESM1 is able to capture the pattern of ozone in the tropics, except in southeast Asia, although it systematically overestimates it at all sites. This work highlights that UKESM1 can capture seasonal and hourly variability.
Namrata Shanmukh Panji, Deborah F. McGlynn, Laura E. R. Barry, Todd M. Scanlon, Manuel T. Lerdau, Sally E. Pusede, and Gabriel Isaacman-VanWertz
Atmos. Chem. Phys., 24, 12495–12507, https://doi.org/10.5194/acp-24-12495-2024, https://doi.org/10.5194/acp-24-12495-2024, 2024
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Climate change will bring about changes in parameters that are currently used in global-scale models to calculate biogenic emissions. This study seeks to understand the factors driving these models by comparing long-term datasets of biogenic compounds to modeled emissions. We note that the light-dependent fractions currently used in models do not accurately represent regional observations. We provide evidence for the time-dependent variation in this parameter for future modifications to models.
Martin Vojta, Andreas Plach, Saurabh Annadate, Sunyoung Park, Gawon Lee, Pallav Purohit, Florian Lindl, Xin Lan, Jens Mühle, Rona L. Thompson, and Andreas Stohl
Atmos. Chem. Phys., 24, 12465–12493, https://doi.org/10.5194/acp-24-12465-2024, https://doi.org/10.5194/acp-24-12465-2024, 2024
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We constrain the global emissions of the very potent greenhouse gas sulfur hexafluoride (SF6) between 2005 and 2021. We show that SF6 emissions are decreasing in the USA and in the EU, while they are substantially growing in China, leading overall to an increasing global emission trend. The national reports for the USA, EU, and China all underestimated their SF6 emissions. However, stringent mitigation measures can successfully reduce SF6 emissions, as can be seen in the EU emission trend.
Yasin Elshorbany, Jerald R. Ziemke, Sarah Strode, Hervé Petetin, Kazuyuki Miyazaki, Isabelle De Smedt, Kenneth Pickering, Rodrigo J. Seguel, Helen Worden, Tamara Emmerichs, Domenico Taraborrelli, Maria Cazorla, Suvarna Fadnavis, Rebecca R. Buchholz, Benjamin Gaubert, Néstor Y. Rojas, Thiago Nogueira, Thérèse Salameh, and Min Huang
Atmos. Chem. Phys., 24, 12225–12257, https://doi.org/10.5194/acp-24-12225-2024, https://doi.org/10.5194/acp-24-12225-2024, 2024
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We investigated tropospheric ozone spatial variability and trends from 2005 to 2019 and related those to ozone precursors on global and regional scales. We also investigate the spatiotemporal characteristics of the ozone formation regime in relation to ozone chemical sources and sinks. Our analysis is based on remote sensing products of the tropospheric column of ozone and its precursors, nitrogen dioxide, formaldehyde, and total column CO, as well as ozonesonde data and model simulations.
Mariano Mertens, Sabine Brinkop, Phoebe Graf, Volker Grewe, Johannes Hendricks, Patrick Jöckel, Anna Lanteri, Sigrun Matthes, Vanessa S. Rieger, Mattia Righi, and Robin N. Thor
Atmos. Chem. Phys., 24, 12079–12106, https://doi.org/10.5194/acp-24-12079-2024, https://doi.org/10.5194/acp-24-12079-2024, 2024
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We quantified the contributions of land transport, shipping, and aviation emissions to tropospheric ozone; its radiative forcing; and the reductions of the methane lifetime using chemistry-climate model simulations. The contributions were analysed for the conditions of 2015 and for three projections for the year 2050. The results highlight the challenges of mitigating ozone formed by emissions of the transport sector, caused by the non-linearitiy of the ozone chemistry and the long lifetime.
Lauri Franzon, Marie Camredon, Richard Valorso, Bernard Aumont, and Theo Kurtén
Atmos. Chem. Phys., 24, 11679–11699, https://doi.org/10.5194/acp-24-11679-2024, https://doi.org/10.5194/acp-24-11679-2024, 2024
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In this article we investigate the formation of large, sticky molecules from various organic compounds entering the atmosphere as primary emissions and the degree to which these processes may contribute to organic aerosol particle mass. More specifically, we qualitatively investigate a recently discovered chemical reaction channel for one of the most important short-lived radical compounds, peroxy radicals, and discover which of these reactions are most atmospherically important.
Siting Li, Yiming Liu, Yuqi Zhu, Yinbao Jin, Yingying Hong, Ao Shen, Yifei Xu, Haofan Wang, Haichao Wang, Xiao Lu, Shaojia Fan, and Qi Fan
Atmos. Chem. Phys., 24, 11521–11544, https://doi.org/10.5194/acp-24-11521-2024, https://doi.org/10.5194/acp-24-11521-2024, 2024
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This study establishes an inventory of anthropogenic chlorine emissions in China in 2019 with expanded species (HCl, Cl-, Cl2, HOCl) and sources (41 specific sources). The inventory is validated by a modeling study against the observations. This study enhances the understanding of anthropogenic chlorine emissions in the atmosphere, identifies key sources, and provides scientific support for pollution control and climate change.
Willem E. van Caspel, Zbigniew Klimont, Chris Heyes, and Hilde Fagerli
Atmos. Chem. Phys., 24, 11545–11563, https://doi.org/10.5194/acp-24-11545-2024, https://doi.org/10.5194/acp-24-11545-2024, 2024
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Methane in the atmosphere contributes to the production of ozone gas – an air pollutant and greenhouse gas. Our results highlight that simultaneous reductions in methane emissions help avoid offsetting the air pollution benefits already achieved by the already-approved precursor emission reductions by 2050 in the European Monitoring and Evaluation Programme region, while also playing an important role in bringing air pollution further down towards World Health Organization guideline limits.
Tia R. Scarpelli, Paul I. Palmer, Mark Lunt, Ingrid Super, and Arjan Droste
Atmos. Chem. Phys., 24, 10773–10791, https://doi.org/10.5194/acp-24-10773-2024, https://doi.org/10.5194/acp-24-10773-2024, 2024
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Under the Paris Agreement, countries must track their anthropogenic greenhouse gas emissions. This study describes a method to determine self-consistent estimates for combustion emissions and natural fluxes of CO2 from atmospheric data. We report consistent estimates inferred using this approach from satellite data and ground-based data over Europe, suggesting that satellite data can be used to determine national anthropogenic CO2 emissions for countries where ground-based CO2 data are absent.
Ryan J. Pound, Lucy V. Brown, Mat J. Evans, and Lucy J. Carpenter
Atmos. Chem. Phys., 24, 9899–9921, https://doi.org/10.5194/acp-24-9899-2024, https://doi.org/10.5194/acp-24-9899-2024, 2024
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Iodine-mediated loss of ozone to the ocean surface and the subsequent emission of iodine species has a large effect on the troposphere. Here we combine recent experimental insights to develop a box model of the process, which we then parameterize and incorporate into the GEOS-Chem transport model. We find that these new insights have a small impact on the total emission of iodine but significantly change its distribution.
Katherine R. Travis, Benjamin A. Nault, James H. Crawford, Kelvin H. Bates, Donald R. Blake, Ronald C. Cohen, Alan Fried, Samuel R. Hall, L. Gregory Huey, Young Ro Lee, Simone Meinardi, Kyung-Eun Min, Isobel J. Simpson, and Kirk Ullman
Atmos. Chem. Phys., 24, 9555–9572, https://doi.org/10.5194/acp-24-9555-2024, https://doi.org/10.5194/acp-24-9555-2024, 2024
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Human activities result in the emission of volatile organic compounds (VOCs) that contribute to air pollution. Detailed VOC measurements were taken during a field study in South Korea. When compared to VOC inventories, large discrepancies showed underestimates from chemical products, liquefied petroleum gas, and long-range transport. Improved emissions and chemistry of these VOCs better described urban pollution. The new chemical scheme is relevant to urban areas and other VOC sources.
Beth S. Nelson, Zhenze Liu, Freya A. Squires, Marvin Shaw, James R. Hopkins, Jacqueline F. Hamilton, Andrew R. Rickard, Alastair C. Lewis, Zongbo Shi, and James D. Lee
Atmos. Chem. Phys., 24, 9031–9044, https://doi.org/10.5194/acp-24-9031-2024, https://doi.org/10.5194/acp-24-9031-2024, 2024
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The impact of combined air quality and carbon neutrality policies on O3 formation in Beijing was investigated. Emissions inventory data were used to estimate future pollutant mixing ratios relative to ground-level observations. O3 production was found to be most sensitive to changes in alkenes, but large reductions in less reactive compounds led to larger reductions in future O3 production. This study highlights the importance of understanding the emissions of organic pollutants.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
EGUsphere, https://doi.org/10.5194/egusphere-2024-2426, https://doi.org/10.5194/egusphere-2024-2426, 2024
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Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursors measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows for evaluating dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying the magnitudes among the systems.
Maureen Beaudor, Didier Hauglustaine, Juliette Lathière, Martin Van Damme, Lieven Clarisse, and Nicolas Vuichard
EGUsphere, https://doi.org/10.5194/egusphere-2024-2022, https://doi.org/10.5194/egusphere-2024-2022, 2024
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Agriculture is the biggest ammonia (NH3) source, impacting air quality, climate, and ecosystems. Because of food demand, NH3 emissions are projected to rise by 2100. Using a global model, we analyzed the impact of present and future NH3 emissions generated from a land model. Our results show improved ammonia patterns compared to a reference inventory. Future scenarios predict up to 70 % increase in global NH3 burden, significant changes in radiative forcing, and could significantly elevate N2O.
Amir H. Souri, Bryan N. Duncan, Sarah A. Strode, Daniel C. Anderson, Michael E. Manyin, Junhua Liu, Luke D. Oman, Zhen Zhang, and Brad Weir
Atmos. Chem. Phys., 24, 8677–8701, https://doi.org/10.5194/acp-24-8677-2024, https://doi.org/10.5194/acp-24-8677-2024, 2024
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We explore a new method of using the wealth of information obtained from satellite observations of Aura OMI NO2, HCHO, and MERRA-2 reanalysis in NASA’s GEOS model equipped with an efficient tropospheric OH (TOH) estimator to enhance the representation of TOH spatial distribution and its long-term trends. This new framework helps us pinpoint regional inaccuracies in TOH and differentiate between established prior knowledge and newly acquired information from satellites on TOH trends.
Haipeng Lin, Louisa K. Emmons, Elizabeth W. Lundgren, Laura Hyesung Yang, Xu Feng, Ruijun Dang, Shixian Zhai, Yunxiao Tang, Makoto M. Kelp, Nadia K. Colombi, Sebastian D. Eastham, Thibaud M. Fritz, and Daniel J. Jacob
Atmos. Chem. Phys., 24, 8607–8624, https://doi.org/10.5194/acp-24-8607-2024, https://doi.org/10.5194/acp-24-8607-2024, 2024
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Tropospheric ozone is a major air pollutant, a greenhouse gas, and a major indicator of model skill. Global atmospheric chemistry models show large differences in simulations of tropospheric ozone, but isolating sources of differences is complicated by different model environments. By implementing the GEOS-Chem model side by side to CAM-chem within a common Earth system model, we identify and evaluate specific differences between the two models and their impacts on key chemical species.
Victor Lannuque and Karine Sartelet
Atmos. Chem. Phys., 24, 8589–8606, https://doi.org/10.5194/acp-24-8589-2024, https://doi.org/10.5194/acp-24-8589-2024, 2024
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation and speciation from naphthalene oxidation. This study details the development of the first near-explicit chemical scheme for naphthalene oxidation by OH, which includes kinetic and mechanistic data, and is able to reproduce most of the experimentally identified products in both gas and particle phases.
Hui Li, Jiaxin Qiu, and Bo Zheng
EGUsphere, https://doi.org/10.5194/egusphere-2024-1986, https://doi.org/10.5194/egusphere-2024-1986, 2024
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We conduct a sensitivity analysis on various factors including prior, model resolution, satellite constraint, and inversion system configuration to assess the vulnerability of emission estimates across temporal, sectoral, and regional dimensions. Our analysis first reveals the robustness of emissions estimated by this air pollution satellite sensor-based CO2 emission inversion system, with relative change between tests and Base inversion below 4.0 % for national annual NOx and CO2 emissions.
Shuai Li, Xiao Lu, and Haolin Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1889, https://doi.org/10.5194/egusphere-2024-1889, 2024
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We report that the summertime ozone-temperature sensitivity decreased by 50 % from 3.0 ppbv/K in 1990 to 1.5 ppb/K in 2021 in the US. GEOS-Chem simulations show that anthropogenic NOx emission reduction is the dominant driver of the ozone-temperature sensitivity decline, through influencing both the temperature-direct and temperature-indirect processes. Reduced ozone-temperature sensitivity has decreased the ozone enhancement from low to high temperatures by an average of 6.8 ppbv across the US.
Tong Sha, Siyu Yang, Qingcai Chen, Liangqing Li, Xiaoyan Ma, Yan-Lin Zhang, Zhaozhong Feng, K. Folkert Boersma, and Jun Wang
Atmos. Chem. Phys., 24, 8441–8455, https://doi.org/10.5194/acp-24-8441-2024, https://doi.org/10.5194/acp-24-8441-2024, 2024
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Using an updated soil reactive nitrogen emission scheme in the Unified Inputs for Weather Research and Forecasting coupled with Chemistry (UI-WRF-Chem) model, we investigate the role of soil NO and HONO (Nr) emissions in air quality and temperature in North China. Contributions of soil Nr emissions to O3 and secondary pollutants are revealed, exceeding effects of soil NOx or HONO emission. Soil Nr emissions play an important role in mitigating O3 pollution and addressing climate change.
Jian Zhu, Shanshan Wang, Chuanqi Gu, Zhiwen Jiang, Sanbao Zhang, Ruibin Xue, Yuhao Yan, and Bin Zhou
Atmos. Chem. Phys., 24, 8383–8395, https://doi.org/10.5194/acp-24-8383-2024, https://doi.org/10.5194/acp-24-8383-2024, 2024
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In 2022, Shanghai implemented city-wide static management measures during the high-ozone season in April and May, providing a chance to study ozone pollution control. Despite significant emissions reductions, ozone levels increased by 23 %. Statistically, the number of days with higher ozone diurnal variation types increased during the lockdown period. The uneven decline in VOC and NO2 emissions led to heightened photochemical processes, resulting in the observed ozone level rise.
Hiroo Hata, Norifumi Mizushima, and Tomohiko Ihara
EGUsphere, https://doi.org/10.5194/egusphere-2024-1961, https://doi.org/10.5194/egusphere-2024-1961, 2024
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The introduction of battery electric vehicles (BEV) is expected to reduce the primary air pollutants from vehicular exhaust and evaporative emissions while reducing the anthropogenic heat produced by vehicles, ultimately decreasing the urban heat island effect (UHI). This study revealed the impact of introducing BEVs on the decrease in UHI and the effects of BEVs on the formation of tropospheric ozone and fine particulate matter in the Greater Tokyo Area of Japan.
Matthew J. Rowlinson, Mat J. Evans, Lucy J. Carpenter, Katie A. Read, Shalini Punjabi, Adedayo Adedeji, Luke Fakes, Ally Lewis, Ben Richmond, Neil Passant, Tim Murrells, Barron Henderson, Kelvin H. Bates, and Detlev Helmig
Atmos. Chem. Phys., 24, 8317–8342, https://doi.org/10.5194/acp-24-8317-2024, https://doi.org/10.5194/acp-24-8317-2024, 2024
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Ethane and propane are volatile organic compounds emitted from human activities which help to form ozone, a pollutant and greenhouse gas, and also affect the chemistry of the lower atmosphere. Atmospheric models tend to do a poor job of reproducing the abundance of these compounds in the atmosphere. By using regional estimates of their emissions, rather than globally consistent estimates, we can significantly improve the simulation of ethane in the model and make some improvement for propane.
Rodrigo J. Seguel, Lucas Castillo, Charlie Opazo, Néstor Y. Rojas, Thiago Nogueira, María Cazorla, Mario Gavidia-Calderón, Laura Gallardo, René Garreaud, Tomás Carrasco-Escaff, and Yasin Elshorbany
Atmos. Chem. Phys., 24, 8225–8242, https://doi.org/10.5194/acp-24-8225-2024, https://doi.org/10.5194/acp-24-8225-2024, 2024
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Trends of surface ozone were examined across South America. Our findings indicate that ozone trends in major South American cities either increase or remain steady, with no signs of decline. The upward trends can be attributed to chemical regimes that efficiently convert nitric oxide into nitrogen dioxide. Additionally, our results suggest a climate penalty for ozone driven by meteorological conditions that favor wildfire propagation in Chile and extensive heat waves in southern Brazil.
Maarten Krol, Bart van Stratum, Isidora Anglou, and Klaas Folkert Boersma
Atmos. Chem. Phys., 24, 8243–8262, https://doi.org/10.5194/acp-24-8243-2024, https://doi.org/10.5194/acp-24-8243-2024, 2024
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This paper presents detailed plume simulations of nitrogen oxides and carbon dioxide that are emitted from four large industrial facilities world-wide. Results from the high-resolution simulations that include atmospheric chemistry are compared to nitrogen dioxide observations from satellites. We find good performance of the model and show that common assumptions that are used in simplified models need revision. This work is important for the monitoring of emissions using satellite data.
Robin Plauchu, Audrey Fortems-Cheiney, Grégoire Broquet, Isabelle Pison, Antoine Berchet, Elise Potier, Gaëlle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, and Henk Eskes
Atmos. Chem. Phys., 24, 8139–8163, https://doi.org/10.5194/acp-24-8139-2024, https://doi.org/10.5194/acp-24-8139-2024, 2024
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This study uses the Community Inversion Framework and CHIMERE model to assess the potential of TROPOMI-S5P PAL NO2 tropospheric column data to estimate NOx emissions in France (2019–2021). Results show a 3 % decrease in average emissions compared to the 2016 CAMS-REG/INS, lower than the 14 % decrease from CITEPA. The study highlights challenges in capturing emission anomalies due to limited data coverage and error levels but shows promise for local inventory improvements.
Chelsea E. Stockwell, Matthew M. Coggon, Rebecca H. Schwantes, Colin Harkins, Bert Verreyken, Congmeng Lyu, Qindan Zhu, Lu Xu, Jessica B. Gilman, Aaron Lamplugh, Jeff Peischl, Michael A. Robinson, Patrick R. Veres, Meng Li, Andrew W. Rollins, Kristen Zuraski, Sunil Baidar, Shang Liu, Toshihiro Kuwayama, Steven S. Brown, Brian C. McDonald, and Carsten Warneke
EGUsphere, https://doi.org/10.5194/egusphere-2024-1899, https://doi.org/10.5194/egusphere-2024-1899, 2024
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In urban areas, emissions from everyday products like paints, cleaners, and personal care products, along with non-traditional sources such as cooking are important sources that impact air quality. This study used a model to evaluate how these emissions impact ozone in the Los Angeles Basin, and quantifies the impact of gaseous cooking emissions for the first time. Accurate representation of these and other man-made sources in inventories is crucial to inform effective air quality policies.
Zhendong Lu, Jun Wang, Yi Wang, Daven K. Henze, Xi Chen, Tong Sha, and Kang Sun
Atmos. Chem. Phys., 24, 7793–7813, https://doi.org/10.5194/acp-24-7793-2024, https://doi.org/10.5194/acp-24-7793-2024, 2024
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In contrast with past work showing that the reduction of emissions was the dominant factor for the nationwide increase of surface O3 during the lockdown in China, this study finds that the variation in meteorology (temperature and other parameters) plays a more important role. This result is obtained through sensitivity simulations using a chemical transport model constrained by satellite (TROPOMI) data and calibrated with surface observations.
Xiaohong Yao and Leiming Zhang
Atmos. Chem. Phys., 24, 7773–7791, https://doi.org/10.5194/acp-24-7773-2024, https://doi.org/10.5194/acp-24-7773-2024, 2024
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This study investigates long-term trends of criteria air pollutants, including NO2, CO, SO2, O3 and PM2.5, and NO2+O3 measured in 10 Canadian cities during the last 2 to 3 decades. We also investigate associated driving forces in terms of emission reductions, perturbations from varying weather conditions and large-scale wildfires, as well as changes in O3 sources and sinks.
Yao Ge, Sverre Solberg, Mathew R. Heal, Stefan Reimann, Willem van Caspel, Bryan Hellack, Thérèse Salameh, and David Simpson
Atmos. Chem. Phys., 24, 7699–7729, https://doi.org/10.5194/acp-24-7699-2024, https://doi.org/10.5194/acp-24-7699-2024, 2024
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Atmospheric volatile organic compounds (VOCs) constitute many species, acting as precursors to ozone and aerosol. Given the uncertainties in VOC emissions, lack of evaluation studies, and recent changes in emissions, this work adapts the EMEP MSC-W to evaluate emission inventories in Europe. We focus on the varying agreement between modelled and measured VOCs across different species and underscore potential inaccuracies in total and sector-specific emission estimates.
Shuzhuang Feng, Fei Jiang, Tianlu Qian, Nan Wang, Mengwei Jia, Songci Zheng, Jiansong Chen, Fang Ying, and Weimin Ju
Atmos. Chem. Phys., 24, 7481–7498, https://doi.org/10.5194/acp-24-7481-2024, https://doi.org/10.5194/acp-24-7481-2024, 2024
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We developed a multi-air-pollutant inversion system to estimate non-methane volatile organic compound (NMVOC) emissions using TROPOMI formaldehyde retrievals. We found that the inversion significantly improved formaldehyde simulations and reduced NMVOC emission uncertainties. The optimized NMVOC emissions effectively corrected the overestimation of O3 levels, mainly by decreasing the rate of the RO2 + NO reaction and increasing the rate of the NO2 + OH reaction.
Yuqing Qiu, Xin Li, Wenxuan Chai, Yi Liu, Mengdi Song, Xudong Tian, Qiaoli Zou, Wenjun Lou, Wangyao Zhang, Juan Li, and Yuanhang Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1576, https://doi.org/10.5194/egusphere-2024-1576, 2024
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The chemical reactions of ozone (O3) formation are related to meteorology and local emissions. Here, a random forest approach was used to eliminate the effects of meteorological factors (dispersion or transport) on O3 and its precursors. Variations in the sensitivity of O3 formation and the apportionment of emission sources were revealed after meteorological normalization. Our results suggest that meteorological variations should be considered when diagnosing O3 formation.
Haklim Choi, Alison L. Redington, Hyeri Park, Jooil Kim, Rona L. Thompson, Jens Mühle, Peter K. Salameh, Christina M. Harth, Ray F. Weiss, Alistair J. Manning, and Sunyoung Park
Atmos. Chem. Phys., 24, 7309–7330, https://doi.org/10.5194/acp-24-7309-2024, https://doi.org/10.5194/acp-24-7309-2024, 2024
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We analyzed with an inversion model the atmospheric abundance of hydrofluorocarbons (HFCs), potent greenhouse gases, from 2008 to 2020 at Gosan station in South Korea and revealed a significant increase in emissions, especially from eastern China and Japan. This increase contradicts reported data, underscoring the need for accurate monitoring and reporting. Our findings are crucial for understanding and managing global HFCs emissions, highlighting the importance of efforts to reduce HFCs.
Laura Hyesung Yang, Daniel J. Jacob, Ruijun Dang, Yujin J. Oak, Haipeng Lin, Jhoon Kim, Shixian Zhai, Nadia K. Colombi, Drew C. Pendergrass, Ellie Beaudry, Viral Shah, Xu Feng, Robert M. Yantosca, Heesung Chong, Junsung Park, Hanlim Lee, Won-Jin Lee, Soontae Kim, Eunhye Kim, Katherine R. Travis, James H. Crawford, and Hong Liao
Atmos. Chem. Phys., 24, 7027–7039, https://doi.org/10.5194/acp-24-7027-2024, https://doi.org/10.5194/acp-24-7027-2024, 2024
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The Geostationary Environment Monitoring Spectrometer (GEMS) provides hourly measurements of NO2. We use the chemical transport model to find how emissions, chemistry, and transport drive the changes in NO2 observed by GEMS at different times of the day. In winter, the chemistry plays a minor role, and high daytime emissions dominate the diurnal variation in NO2, balanced by transport. In summer, emissions, chemistry, and transport play an important role in shaping the diurnal variation in NO2.
M. Omar Nawaz, Jeremiah Johnson, Greg Yarwood, Benjamin de Foy, Laura Judd, and Daniel L. Goldberg
Atmos. Chem. Phys., 24, 6719–6741, https://doi.org/10.5194/acp-24-6719-2024, https://doi.org/10.5194/acp-24-6719-2024, 2024
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NO2 is a gas with implications for air pollution. A campaign conducted in Houston provided an opportunity to compare NO2 from different instruments and a model. Aircraft and satellite observations agreed well with measurements on the ground; however, the latter estimated lower values. We find that model-simulated NO2 was lower than observations, especially downtown, suggesting that NO2 sources associated with the urban core of Houston, such as vehicle emissions, may be underestimated.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonne, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1450, https://doi.org/10.5194/egusphere-2024-1450, 2024
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Processes influencing dispersion of local anthropogenic emissions in Arctic wintertime are investigated with dispersion model simulations. Modelled power plant plume rise that considers surface and elevated temperature inversions improves results compared to observations. Modelled near-surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching -35 °C are required to reproduce observed NOx.
Tianlang Zhao, Jingqiu Mao, Zolal Ayazpour, Gonzalo González Abad, Caroline R. Nowlan, and Yiqi Zheng
Atmos. Chem. Phys., 24, 6105–6121, https://doi.org/10.5194/acp-24-6105-2024, https://doi.org/10.5194/acp-24-6105-2024, 2024
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HCHO variability is a key tracer in understanding VOC emissions in response to climate change. We investigate the role of methane oxidation and biogenic and wildfire emissions in HCHO interannual variability over northern high latitudes in summer, emphasizing wildfires as a key driver of HCHO interannual variability in Alaska, Siberia and northern Canada using satellite HCHO and SIF retrievals and then GEOS-Chem model. We show SIF is a tool to understand biogenic HCHO variability in this region.
Jianghao Li, Alastair C. Lewis, Jim R. Hopkins, Stephen J. Andrews, Tim Murrells, Neil Passant, Ben Richmond, Siqi Hou, William J. Bloss, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 24, 6219–6231, https://doi.org/10.5194/acp-24-6219-2024, https://doi.org/10.5194/acp-24-6219-2024, 2024
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A summertime ozone event at an urban site in Birmingham is sensitive to volatile organic compounds (VOCs) – particularly those of oxygenated VOCs. The roles of anthropogenic VOC sources in urban ozone chemistry are examined by integrating the 1990–2019 national atmospheric emission inventory into model scenarios. Road transport remains the most powerful means of further reducing ozone in this case study, but the benefits may be offset if solvent emissions of VOCs continue to increase.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Jin Ma, Linda M. J. Kooijmans, Norbert Glatthor, Stephen A. Montzka, Marc von Hobe, Thomas Röckmann, and Maarten C. Krol
Atmos. Chem. Phys., 24, 6047–6070, https://doi.org/10.5194/acp-24-6047-2024, https://doi.org/10.5194/acp-24-6047-2024, 2024
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The global budget of atmospheric COS can be optimised by inverse modelling using TM5-4DVAR, with the co-constraints of NOAA surface observations and MIPAS satellite data. We found reduced COS biosphere uptake from inversions and improved land and ocean separation using MIPAS satellite data assimilation. Further improvements are expected from better quantification of COS ocean and biosphere fluxes.
Cited articles
Anthony, K. M. W., Anthony, P., Grosse, G., and Chanton, J. P.: Geologic
methane seeps along boundaries of Arctic permafrost thaw and melting
glaciers, Nat. Geosci., 5, 419–426, https://doi.org/10.1038/ngeo1480, 2012.
Bastviken, D., Tranvik, L. J., Downing, J. A., Crill, P. M., and
Enrich-Prast, A.: Freshwater methane emissions offset the continental carbon
sink, Science, 331, 50 pp., https://doi.org/10.1126/science.1196808, 2011.
Berchet, A., Pison, I., Chevallier, F., Paris, J.-D., Bousquet, P., Bonne, J.-L., Arshinov, M. Y., Belan, B. D., Cressot, C., Davydov, D. K., Dlugokencky, E. J., Fofonov, A. V., Galanin, A., Lavrič, J., Machida, T., Parker, R., Sasakawa, M., Spahni, R., Stocker, B. D., and Winderlich, J.: Natural and anthropogenic methane fluxes in Eurasia: a mesoscale quantification by generalized atmospheric inversion, Biogeosciences, 12, 5393–5414, https://doi.org/10.5194/bg-12-5393-2015, 2015.
Berchet, A., Bousquet, P., Pison, I., Locatelli, R., Chevallier, F., Paris, J.-D., Dlugokencky, E. J., Laurila, T., Hatakka, J., Viisanen, Y., Worthy, D. E. J., Nisbet, E., Fisher, R., France, J., Lowry, D., Ivakhov, V., and Hermansen, O.: Atmospheric constraints on the methane emissions from the East Siberian Shelf, Atmos. Chem. Phys., 16, 4147–4157, https://doi.org/10.5194/acp-16-4147-2016, 2016.
Bergamaschi, P., Lubina, C., Königstedt, R., Fischer, H., Veltkamp, A.
C., and Zwaagstra, O.: Stable isotopic signatures (δ13C, δD)
of methane from European landfill sites, J. Geophys. Res., 103, 8251–8265,
https://doi.org/10.1029/98JD00105, 1998.
Bernard, S.: Evolution temporelle du méthane et du protoxyde d'azote
dans l'atmosphère: contrainte par l'analyse de leurs isotopes stables
dans le névé et la glace polaires, PhD dissertation, Univ. Grenoble
1, available at: https://tel.archives-ouvertes.fr/tel-00701325 (last access: 18 September 2019), 2004.
Bilek, R. S., Tyler, S. C., Kurihara, M., and Yagi, K.: Investigation of
cattle methane production and emission over a 24-hour period using
measurements of δ13C and δD of emitted CH4 and rumen water,
J. Geophys. Res., 106, 15405–15413, https://doi.org/10.1029/2001JD900177,
2001.
Bohn, T. J., Melton, J. R., Ito, A., Kleinen, T., Spahni, R., Stocker, B. D., Zhang, B., Zhu, X., Schroeder, R., Glagolev, M. V., Maksyutov, S., Brovkin, V., Chen, G., Denisov, S. N., Eliseev, A. V., Gallego-Sala, A., McDonald, K. C., Rawlins, M. A., Riley, W. J., Subin, Z. M., Tian, H., Zhuang, Q., and Kaplan, J. O.: WETCHIMP-WSL: intercomparison of wetland methane emissions models over West Siberia, Biogeosciences, 12, 3321–3349, https://doi.org/10.5194/bg-12-3321-2015, 2015.
Bouchard, F., Laurion, I., Prėskienis, V., Fortier, D., Xu, X., and Whiticar, M. J.: Modern to millennium-old greenhouse gases emitted from ponds and lakes of the Eastern Canadian Arctic (Bylot Island, Nunavut), Biogeosciences, 12, 7279–7298, https://doi.org/10.5194/bg-12-7279-2015, 2015.
Bousquet, P., Ciais, P., Miller, J., Dlugokencky, E., Hauglustaine, D.,
Prigent, C., Van der Werf, G., Peylin, P., Brunke, E.-G., and Carouge, C.:
Contribution of anthropogenic and natural sources to atmospheric methane
variability, Nature, 443, 439–443, 2006.
Bousquet, P., Pierangelo, C., Bacour, C., Marshall, J., Peylin, P., Ayar, P. V., Ehret, G., Bréon, F.-M., Chevallier, F., Crevoisier, C., Gibert, F., Rairoux, P., Kiemle, C., Armante, R., Bès, C., Cassé, V., Chinaud, J., Chomette, O., Delahaye, T., Edouart, D., Estève, F., Fix, A., Friker, A., Klonecki, A., Wirth, M., alpers, M., and Millet, B.: Error budget of the MEthane Remote LIdar missioN and its impact on the uncertainties of the global methane budget, J. Geophys. Res.-Atmos., 123, 11766–11785, https://doi.org/10.1029/2018JD028907, 2018.
Brosius, L. S., Walter Anthony, K. M., Grosse, G., Chanton, J. P.,
Farquharson, L. M., Overduin, P. P., and Meyer, H.: Using the deuterium
isotope composition of permafrost meltwater to constrain thermokarst lake
contributions to atmospheric CH4 during the last deglaciation, J. Geophys.
Res., 117, G01022, https://doi.org/10.1029/2011JG001810, 2012.
Brunskill, G. J., Burns, K. A., and Zagorskis, I.: Natural flux of
greenhouse methane from the Timor Sea to the atmosphere, J. Geophys. Res.,
116, G02024, https://doi.org/10.1029/2010JG001444, 2011.
Cain, M., Warwick, N. J., Fisher, R. E., Lowry, D., Lanoisellé, M., Nisbet, E. G., France, J., Pitt, J., O'Shea, S., Bower, K. N., Allen, G., Illingworth, S., Manning, A. J., Bauguitte, S., Pisso, I., and Pyle, J. A.: A cautionary tale: A study of a methane enhancement over the North Sea, J. Geophys. Res. Atmos., 122, 7630–7645, https://doi.org/10.1002/2017JD026626, 2017.
Chanton, J. P., Rutkowski, C. M., and Mosher, B.: Quantifying methane
oxidation from landfills using stable isotope analysis of downwind plumes,
Environ. Sci. Tech., 33, 3755–3760, https://doi.org/10.1021/es9904033, 1999.
Chanton, J. P., Rutkowski, C. M., Schwartz, C. C., Ward, D. E., and Boring,
L.: Factors influencing the stable carbon isotopic signature of methane from
combustion and biomass burning, J. Geophys. Res., 105, 1867–1877,
https://doi.org/10.1029/1999JD900909, 2000.
Chasar, L. S., Chanton, J. P., Glaser, P. H., and Siegel, D. I.: Methane
concentration and stable isotope distribution as evidence of rhizospheric
processes: comparison of a fen and bog in the glacial lake Agassiz peatland
complex, Ann. Bot., 86, 655–663, https://doi.org/10.1006/anbo.2000.1172,
2000.
Ciais, P., Sabine, C., Bala, G., Bopp, L., Brovkin, V., Canadell, J., Chhabra, A., DeFries, R., Galloway, J., Heimann, M., Jones, C., Le Quéré, C., Myneni, R. B., Piao, S., and Thornton, P.: Carbon and Other Biogeochemical Cycles, in: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 2013.
Craig, H.: Isotopic standards for carbon and oxygen and correction factors
for mass spectrometric analysis of carbon dioxide, Geochim. Cosmochim. Ac.,
12, 133–149, 1957.
Cramer, B. and Franke, D.: Indications for an active petroleum system in the Laptev Sea, NE Siberia, J. Petrol. Geol., 28, 369–384, https://doi.org/10.1111/j.1747-5457.2005.tb00088.x, 2005.
Dlugokencky, E. J., Steele, L. P., Lang, P. M., and Masarie, K. A.: The
growth rate and distribution of atmospheric methane, J. Geophys. Res., 99,
17021–17043, https://doi.org/10.1029/94JD01245, 1994.
Dlugokencky, E. J., Nisbet, E. G., Fisher, R., and Lowry, D.: Global
atmospheric methane: budget, changes and dangers, Philos. T. Roy. Soc. A,
369, 2058–2072, https://doi.org/10.1098/rsta.2010.0341, 2011.
Dmitrenko, I. A., Kirillov, S. A., Tremblay, L. B., Kassens, H., Anisimov,
O. A., Lavrov, S. A., Razumov, S. O., and Grigoriev, M. N.: Recent changes
in shelf hydrography in the Siberian Arctic: Potential for subsea permafrost
instability, J. Geophys. Res., 116, C10027,
https://doi.org/10.1029/2011JC007218, 2011.
Etiope, G.: Natural emissions of geological methane in Europe, Atmos.
Environ., 43, 1430–1443, https://doi.org/10.1016/j.atmosenv.2008.03.014,
2009
Etiope, G.: Natural gas seepage, The Earth's hydrocarbon degassing, Springer
International Publishing,
Switzerland, https://doi.org/10.1007/978-3-319-14601-0, 2015.
Etiope, G., Ciotoli, G., Schwietzke, S., and Schoell, M.: Gridded maps of geological methane emissions and their isotopic signature, Earth Syst. Sci. Data, 11, 1–22, https://doi.org/10.5194/essd-11-1-2019, 2019.
Etminan, M., Myhre, G., Highwood, E. J., and Shine, K. P. : Radiative
forcing of carbon dioxide, methane, and nitrous oxide: A significant
revision of the methane radiative forcing, Geophys. Res. Lett., 43, 12614–12623, https://doi.org/10.1002/2016GL071930, 2016.
Fisher, R. E., Sriskantharajah, S., Lowry, D., Lanoisellé, M., Fowler, C. M. R., James, R. H., Hermansen, O., Lund Myhre, C., Stohl, A., Greinert, J., Nisbet‐Jones, P. B. R., Mienert, J., and Nisbet, E. G.: Arctic methane sources: Isotopic evidence for atmospheric
inputs, Geophys. Res. Lett., 38, L21803,
https://doi.org/10.1029/2011GL049319, 2011.
Fisher, R., Lowry, D., Wilkin, O., Sriskantharajah, S., and Nisbet, E. G.: High‐precision, automated stable isotope analysis of atmospheric methane and carbon dioxide using continuous‐flow isotope‐ratio mass spectrometry, Rapid Commun. Mass Spectrom., 20, 200–208, https://doi.org/10.1002/rcm.2300, 2006.
Fisher, R. E., France, J. L., Lowry, D., Lanoisellé, M., Brownlow, R.,
Pyle, J. A., Cain, M., Warwick, N., Skiba, U. M., Drewer, J., Dinsmore, K.
J., Leeson, S. R., Bauguitte, S. J.-B., Wellpott, A., O'Shea, S. J., Allen,
G., Gallagher, M. W., Pitt, J., Percival, C. J., Bower, K., George, C.,
Hayman, G. D., Aalto, T., Lohila, A., Aurela, M., Laurila, T., Crill, P. M.,
McCalley, C. K., and Nisbet, E. G.: Measurements of the 13C isotopic
signature of methane emissions from northern European wetlands, G.
Biogeochem. Cy., 31, 605-623, https://doi.org/10.1002/2016GB005504, 2017.
France, J. L., Cain, M., Fisher, R. E., Lowry, D., Allen, G., O'Shea, S. J.,
Illingworth, S., Pyle, J., Warwick, N., Jones, B. T., Gallagher, M. W.,
Bower, K., Le Breton, M., Percival, C., Muller, J., Bauguitte, S., George,
C., Hayman, G. D., Manning, A. J., Lund Myhre, C., Lanoisellé, M., and
Nisbet, E. G.: Measurements of δ13C in CH4 and using particle
dispersion modeling to characterize sources of Arctic methane within an air
mass, J. Geophys. Res., 121, 14257–14270, https://doi.org/10.1002/2016JD026006, 2016.
Galand, P. E., Yrjälä, K., and Conrad, R.: Stable carbon isotope fractionation during methanogenesis in three boreal peatland ecosystems, Biogeosciences, 7, 3893–3900, https://doi.org/10.5194/bg-7-3893-2010, 2010.
Giglio, L., Randerson, J. T., and van der Werf, G.: Analysis of daily,
monthly, and annual burned area using the fourth-generation global fire
emissions database (GFED4), J. Geophys. Res., 118, 317–328,
https://doi.org/10.1002/jgrg.20042, 2013.
Hein, R., Crutzen, P. J., and Heimann, M.: An inverse modeling approach to investigate the global atmospheric methane cycle, Global Biogeochem. Cy., 11, 43–76, https://doi.org/10.1029/96GB03043, 1997.
Hourdin, F., Musat, I., Bony, S., Braconnot, P., Codron, F., Dufresne, J.-L., Fairhead, L., Filiberti, M.-A., Friedlingstein, P., Grandpeix, J.-Y., Krinner, G., LeVan, P., Li, Z.-X., and Lott, F.: The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection, Clim. Dynam., 27, 787–813,
https://doi.org/10.1007/s00382-006-0158-0, 2006.
Houweling, S., Röckmann, T., Aben, I., Keppler, F., Krol, M., Meirink,
J. F., Dlugokencky, E. J., and Frankenberg, C.: Atmospheric constraints on
global emissions of methane from plants, Geophys. Res. Let., 33, L15821,
https://doi.org/10.1029/2006GL026162, 2006.
Kirschke, S., Bousquet, P., Ciais, P., Saunois, M., Canadell, J. G., Dlugokencky, E. J., Bergamaschi, P., Bergmann, D., Blake, D. R., Bruhwiler, L., Cameron-Smith, P., Castaldi, S., Chevallier, F., Feng, L., Fraser, A., Heimann, M., Hodson, E. L., Houweling, S., Josse, B., Fraser, P. J., Krummel, P. B., Lamarque, J. F., Langenfelds, R. L., Le Quere, C., Naik, V., O'Doherty, S., Palmer, P. I., Pison, I., Plummer, D., Poulter, B., Prinn, R. G., Rigby, M., Ringeval, B., Santini, M., Schmidt, M., Shindell, D. T., Simpson, I. J., Spahni, R., Steele, L. P., Strode, S. A., Sudo, K., Szopa, S., van derWerf, G. R., Voulgarakis, A., vanWeele, M., Weiss, R. F., Williams, J. E., and Zeng, G.: Three decades of global methane sources and sinks, Nat. Geosci., 6, 813–823, 2013.
Klevenhusen, F., Bernasconi, S. M., Kreuzer, M., and Soliva, C.:
Experimental validation of the Intergovernmental Panel on Climate Change
default values for ruminant-derived methane and its carbon-isotope
signature, Anim. Prod. Sci., 50, 159–167, https://doi/org/10.1071/AN09112,
2010.
Lassey, K. R., Etheridge, D. M., Lowe, D. C., Smith, A. M., and Ferretti, D. F.: Centennial evolution of the atmospheric methane budget: what do the carbon isotopes tell us?, Atmos. Chem. Phys., 7, 2119–2139, https://doi.org/10.5194/acp-7-2119-2007, 2007.
Lehner, B. and Döll, P.: Development and validation of a global
database of lakes, reservoirs and wetlands, J. Hydrol., 296, 1–22,
https://doi.org/10.1016/j.jhydrol.2004.03.028, 2004.
Levin, I., Glatzel-Mattheier, H., Marik, T., Cuntz, M., and Schmidt, M.:
Verification of German methane emission inventories and their recent changes
based on atmospheric observations, J. Geophys. Res., 104, 3447–3456,
https://doi.org/10.1029/1998JD100064, 1999.
McCalley, C. K., Woodcroft, B. J., Hodgkins, S. B., Wehr, R. A., Kim, E.-H.,
Mondav, R., Crill, P. M., Chanton, J. P., Rich, V. I., Tyson, G. W., and
Saleska, S. R.: Methane dynamics regulated by microbial community response
to permafrost thaw, Nature, 514, 478–481,
https://doi.org/10.1038/nature13798, 2014.
McManus, J. B., Nelson, D. D., and Zahniser, M. S.: Long-term continuous
sampling of 12CO2, 13CO2 and 12C18O16O in
ambient air with a quantum cascade laser spectrometer, Isotopes Environ.
Health Stud., 46, 49–63, https://doi.org/10.1080/10256011003661326, 2010.
McNorton, J., Gloor, E., Wilson, C., Hayman, G. D., Gedney, N., Comyn-Platt,
E., Marthews, T., Parker, R. J., Boesch, H., and Chipperfield, M. P.: Role
of regional wetland emissions in atmospheric methane variability, Geophys.
Res. Lett., 43, 11433–11444, https://doi.org/10.1002/2016GL070649, 2016.
Menut, L., Bessagnet, B., Khvorostyanov, D., Beekmann, M., Blond, N., Colette, A., Coll, I., Curci, G., Foret, G., Hodzic, A., Mailler, S., Meleux, F., Monge, J.-L., Pison, I., Siour, G., Turquety, S., Valari, M., Vautard, R., and Vivanco, M. G.: CHIMERE 2013: a model for regional atmospheric composition modelling, Geosci. Model Dev., 6, 981–1028, https://doi.org/10.5194/gmd-6-981-2013, 2013.
Mikaloff Fletcher, S. E. M., Tans, P. P. , Bruhwiler, L. M., Miller, J. B., and Heimann, M.: CH4 sources estimated from atmospheric observations of
CH4 and its C-13/C-12 isotopic ratios: 1. Inverse modeling of source
processes, Global Biogeochem. Cy., 18, GB4004,
https://doi/org/4010.1029/2004GB002223, 2004.
Monteil, G., Houweling, S., Dlugockenky, E. J., Maenhout, G., Vaughn, B. H., White, J. W. C., and Rockmann, T.: Interpreting methane variations in the past two decades using measurements of CH4 mixing ratio and isotopic composition, Atmos. Chem. Phys., 11, 9141–9153, https://doi.org/10.5194/acp-11-9141-2011, 2011.
Naus, S., Montzka, S. A., Pandey, S., Basu, S., Dlugokencky, E. J., and Krol, M.: Constraints and biases in a tropospheric two-box model of OH, Atmos. Chem. Phys., 19, 407–424, https://doi.org/10.5194/acp-19-407-2019, 2019.
Nelson, D. D., McManus, B., Urbanski, S., Herndon, S., and Zahniser, M. S.: High
precision measurements of atmospheric nitrous oxide and methane using
thermoelectrically cooled mid-infrared quantum cascade lasers and detectors,
Spectrochim. Acta A, 60, 3325–3335,
https://doi.org/10.1016/j.saa.2004.01.033, 2004.
Nisbet, E. G., Dlugokencky, E. J., Manning, M. R., Lowry, D., Fisher, R. E.,
France, J. L., Michel, S. E., Miller, J. B., White, J. W. C., Vaughn, B.,
Bousquet, P., Pyle, J. A., Warwick, N. J., Cain, M., Brwnlow, R., Zazzeri,
G., Lanoisellé, M., Manning, A. C., Gloor, E., Worthy, D. E. J., Brunke,
E.-G., Labuschagne, C., Wolff, E. W., and Ganesan, A. L.: Rising atmospheric
methane: 2007–2014 growth and isotopic shift, Global Biogeochem. Cy., 30,
1356–1370, https://doi.org/10.1002/2016GB005406, 2016.
Olivier, J. and Janssens-Maenhout, G.: Greenhouse gas emissions,
Part III, in: CO2 emissions from fuel combustion, 2012 Edition,
International Energy Agency (IEA), Paris, 2012.
O'Shea, S. J., Allen, G., Gallagher, M. W., Bower, K., Illingworth, S. M., Muller, J. B. A., Jones, B. T., Percival, C. J., Bauguitte, S. J.-B., Cain, M., Warwick, N., Quiquet, A., Skiba, U., Drewer, J., Dinsmore, K., Nisbet, E. G., Lowry, D., Fisher, R. E., France, J. L., Aurela, M., Lohila, A., Hayman, G., George, C., Clark, D. B., Manning, A. J., Friend, A. D., and Pyle, J.: Methane and carbon dioxide fluxes and their regional scalability for the European Arctic wetlands during the MAMM project in summer 2012, Atmos. Chem. Phys., 14, 13159–13174, https://doi.org/10.5194/acp-14-13159-2014, 2014.
Overduin, P. P., Liebner, S., Knoblauch, C., Günther, F., Wetterich, S.,
Schirrmeister, L., Hubberten, H.-W., and Grigoriev, M. N.: Methane oxidation
following submarine permafrost degradation: Measurements from a central
Laptev Sea shelf borehole, J. Geophys. Res., 120, 965–978,
https://doi.org/10.1002/2014JG002862, 2015.
Patra, P. K., Takigawa, M., Watanabe, S., Chandra, N., Ishijima, K., and Yamashita, Y.: Improved Chemical Tracer Simulation by MIROC4.0-based Atmospheric Chemistry-Transport Model (MIROC4-ACTM), SOLA, 14, 91–96, https://doi.org/10.2151/sola.2018-016, 2018.
Pisso, I., Myhre, C. L., Platt, S. M., Eckhardt, S., Hermansen, O., Schmidbauer, N., Mienert, J., Vadakkepuliyambatta, S., Bauguitte, S., Pitt, J., Allen, G., Bower, K. N., O'Shea, S., Gallagher, M. W., Percival, C. J., Pyle, J., Cain, M., and Stohl, A.: Constraints on oceanic methane emissions west of Svalbard from atmospheric in situ measurements and Lagrangian transport modeling, J. Geophys. Res.-Atmos., 16, 121, 14188–14200,
https://doi.org/10.1002/2016JD025590, 2016.
Podbaronova, J.: Assessment of coals fro Russia and countries of former
Soviet Union for utility fluidized bed boilers, Master's thesis,
Lappeenranta University of Technology, Faculty of Technology, Bioenergy
Technology, 2010.
Rice, D. D.: Composition and origins of coalbed gas: Hydrocarbons from coal,
AAPG Studies in Geology, 38, 159–184, 1993.
Rigby, M., Manning, A. J., and Prinn, R. G.: The value of high-frequency,
high-precision methane isotopologue measurements for source and sink
estimation, J. Geophys. Res.-Atmos., 117, D12312, https://doi.org/10.1029/2011JD017384, 2012.
Rigby, M., Montzka, S. A., Prinn, R. G., White, J. W. C., Young, D., O'Doherty, S., Lunt, M. F., Ganesan, A. L., Manning, A. J., Simmonds, P. G., Salameh, P. K., Harth, C. M., Mühle, J., Weiss, R. F., Fraser, P. J., Steele, L. P., Krummel, P. B., McCulloch, A., and Park, S.: Role of OH in recent methane growth,
P. Natl. Acad. Sci. USA, 114, 5373–5377, https://doi.org/10.1073/pnas.1616426114, 2017.
Ringeval, B., de Noblet-Ducoudré, N., Ciais, P., Bousquet, P., Prigent,
C., Papa, F., and Rossow, W. B.: An attempt to quantify the impact of
changes in wetland extent on methane emissions on the seasonal and
interannual time scales, Global Biogeochem. Cy., 24, 1–12,
https://doi.org/10.1029/2008GB003354, 2010.
Ringeval, B., Friedlingstein, P., Koven, C., Ciais, P., de Noblet-Ducoudré, N., Decharme, B., and Cadule, P.: Climate-CH4 feedback from wetlands and its interaction with the climate-CO2 feedback, Biogeosciences, 8, 2137–2157, https://doi.org/10.5194/bg-8-2137-2011, 2011.
Röckmann, T., Eyer, S., van der Veen, C., Popa, M. E., Tuzson, B., Monteil, G., Houweling, S., Harris, E., Brunner, D., Fischer, H., Zazzeri, G., Lowry, D., Nisbet, E. G., Brand, W. A., Necki, J. M., Emmenegger, L., and Mohn, J.: In situ observations of the isotopic composition of methane at the Cabauw tall tower site, Atmos. Chem. Phys., 16, 10469–10487, https://doi.org/10.5194/acp-16-10469-2016, 2016.
Ruppel, C.: Permafrost-Associated Gas Hydrate: Is It Really Approximately 1 % of the Global System, or: Special Issue in honor of E. Dendy Sloan on
the occasion of his 70th Birthday, J. Chem. Eng. Data, 60, 429–436, https://doi.org/10.1021/je500770m, 2015.
Santoni, G. W., Lee, B. H., Goodrich, J. P., Varner, R. K., Crill, P. M.,
McManus, J. B., Nelson, D. D., Zahniser, M. S., and Wofsy, S. C.: Mass fluxes
and isofluxes of methane (CH4) at a New Hampshire fen measured by a
continuous wave quantum cascade laser spectrometer, J. Geophys. Res., 117,
D10301, https://doi.org/10.1029/2011JD016960, 2012.
Sapart, C. J., Shakhova, N., Semiletov, I., Jansen, J., Szidat, S., Kosmach, D., Dudarev, O., van der Veen, C., Egger, M., Sergienko, V., Salyuk, A., Tumskoy, V., Tison, J.-L., and Röckmann, T.: The origin of methane in the East Siberian Arctic Shelf unraveled with triple isotope analysis, Biogeosciences, 14, 2283–2292, https://doi.org/10.5194/bg-14-2283-2017, 2017.
Saueressig, G., Crowley, J. N., Bergamaschi, P., Brühl, C., Brenninkmeijer, C. A. M., and Fischer, H.: Carbon 13 and D kinetic isotope effects in the reactions of CH4 with O(1 D) and OH: New laboratory measurements and their implications for the isotopic composition of stratospheric methane, J. Geophys. Res., 106, 23127–23138, https://doi.org/10.1029/2000JD000120, 2001.
Saunois, M., Bousquet, P., Poulter, B., Peregon, A., Ciais, P., Canadell, J. G., Dlugokencky, E. J., Etiope, G., Bastviken, D., Houweling, S., Janssens-Maenhout, G., Tubiello, F. N., Castaldi, S., Jackson, R. B., Alexe, M., Arora, V. K., Beerling, D. J., Bergamaschi, P., Blake, D. R., Brailsford, G., Bruhwiler, L., Crevoisier, C., Crill, P., Covey, K., Frankenberg, C., Gedney, N., Höglund-Isaksson, L., Ishizawa, M., Ito, A., Joos, F., Kim, H.-S., Kleinen, T., Krummel, P., Lamarque, J.-F., Langenfelds, R., Locatelli, R., Machida, T., Maksyutov, S., Melton, J. R., Morino, I., Naik, V., O'Doherty, S., Parmentier, F.-J. W., Patra, P. K., Peng, C., Peng, S., Peters, G. P., Pison, I., Prinn, R., Ramonet, M., Riley, W. J., Saito, M., Santini, M., Schroeder, R., Simpson, I. J., Spahni, R., Takizawa, A., Thornton, B. F., Tian, H., Tohjima, Y., Viovy, N., Voulgarakis, A., Weiss, R., Wilton, D. J., Wiltshire, A., Worthy, D., Wunch, D., Xu, X., Yoshida, Y., Zhang, B., Zhang, Z., and Zhu, Q.: Variability and quasi-decadal changes in the methane budget over the period 2000–2012, Atmos. Chem. Phys., 17, 11135–11161, https://doi.org/10.5194/acp-17-11135-2017, 2017.
Schaefer, H., Fletcher, S. E., Veidt, C., Lassey, K. R., Brailsford, G. W.,
Bromley, T. M., Dlugokencky, E. J., Michel, S. E., Miller, J. B., Levin, I.,
Lowe, D. C., Martin, R. J., Vaughn, B. H., and White, J. W.: A 21st century
shift from fossil-fuel to biogenic methane emissions indicated by 13CH4,
Science, 352, 80–84, https://doi.org/10.1126/science.aad2705, 2016.
Schoell, M.: The hydrogen and carbon isotopic composition of methane from
natural gases of various origins, Geochim. Cosmochim. Ac., 44, 649–661,
1980.
Schuur, E. A. G., McGuire, A. D., Schädel, C., Grosse, G., Harden, J.
W., Hayes, D. J., Hugelius, G., Koven, C. D., Kuhry, P., Lawrence, D. M.,
Natali, S. M., Olefeldt, D., Romanovsky, V. E., Schaefer, K., Turetsky, M.
R., Treat, C. C., and Vonk, J. E.: Climate change and the permafrost carbon
feedback, Nature, 520, 171–179, https://doi.org/10.1038/nature14338, 2015.
Schwietzke, S., Sherwood, O. A., Bruhwiler, L. M. P., Miller, J. B., Etiope,
G., Dlugokencky, E. J., Michel, S. E., Arling, V. A., Vaughn, B. H., White,
J. W. C., and Tans, P. P.: Upward revision of global fossil fuel methane
emissions based on isotope database, Nature, 58, 88–91,
https://doi.org/10.1038/nature19797, 2016.
Shakhova, N., Semiletov, I., Salyuk, A., Yusupov, V., Kosmach, D., and
Gustafsson, O.: Extensive Methane Venting to the Atmosphere from Sediments
of the East Siberian Arctic Shelf, Science, 327, 1246–1250,
https://doi.org/10.1126/science.1182221, 2010.
Sherwood, O. A., Schwietzke, S., Arling, V. A., and Etiope, G.: Global Inventory of Gas Geochemistry Data from Fossil Fuel, Microbial and Burning Sources, version 2017, Earth Syst. Sci. Data, 9, 639–656, https://doi.org/10.5194/essd-9-639-2017, 2017.
Sriskantharajah, S., Fisher, R. E., Lowry, D., Aalto, T., Hatakka, J.,
Aurela, M., Laurila, T., Lohila, A., Kuitunen, E., and Nisbet, E. G.: Stable
carbon isotope signatures of methane from a Finnish subarctic wetland,
Tellus B, 64, 18818, https://doi.org/10.3402/tellusb.v64i0.18818, 2012.
Sweeney, C., Dlugokencky, E., Miller, C. E., Wofsy, S., Karion, A., Dinardo,
S., Chang, R. Y.-W., Miller, J. B., Bruhwiler, L., Crotwell, A. M.,
Newberger, T., McKain, K., Stone, R. S., Wolter, S. E., Lang, P. E., and
Tans, P.: No significant increase in long-term CH4 emissions on North Slope
of Alaska despite significant increase in air temperature, Geophys. Res.
Lett., 43, 6604–6611, https://doi.org/10.1002/2016GL069292, 2016.
Tan, Z. and Zhuang, Q.: Arctic lakes are continuous methane sources to the
atmosphere under global warming, Environ. Res. Lett., 10, 054016,
https://doi.org/10.1088/1748-9326/10/5/054016, 2015.
Tans, P. P.: A note on isotopic ratios and the global atmospheric methane
budget, Global. Biogeochem. Cy., 11, 77–81,
https://doi.org/10.1029/96GB03940, 1997.
Thompson, H. A, White, J. R., Pratt, L. M., and Sauer, P. E.: Spatial
variation in flux, δ13C and δ2H of methane in a small Arctic
lake with fringing wetland in western Greenland, Biogeochemistry, 131,
17–33, https://doi.org/10.1007/s10533-016-0261-1, 2016.
Thompson, R. L., Sasakawa, M., Machida, T., Aalto, T., Worthy, D., Lavric, J. V., Lund Myhre, C., and Stohl, A.: Methane fluxes in the high northern latitudes for 2005–2013 estimated using a Bayesian atmospheric inversion, Atmos. Chem. Phys., 17, 3553–3572, https://doi.org/10.5194/acp-17-3553-2017, 2017.
Thonat, T., Saunois, M., Bousquet, P., Pison, I., Tan, Z., Zhuang, Q., Crill, P. M., Thornton, B. F., Bastviken, D., Dlugokencky, E. J., Zimov, N., Laurila, T., Hatakka, J., Hermansen, O., and Worthy, D. E. J.: Detectability of Arctic methane sources at six sites performing continuous atmospheric measurements, Atmos. Chem. Phys., 17, 8371–8394, https://doi.org/10.5194/acp-17-8371-2017, 2017.
Thornton, B. F., Geibel, M. C., Crill, P. M., Humborg, C., and Mörth,
C.-M.: Methane fluxes from the sea to the atmosphere across the Siberian
shelf seas, Geophys. Res. Lett., 43, 5869–5877, https://doi.org/10.1002/2016GL068977,
2016a.
Thornton, B. F., Wik, M., and Crill, P. M.: Double-counting challenges the
accuracy of high-latitude methane inventories, Geophys. Res. Lett., 43,
12569–12577, https://doi.org/10.1002/2016GL071772, 2016b.
Turner, A. J., Frankenberg, C., Wennberg, P. O., and Jacob, D. J.: Decadal trends in atmospheric methane and OH,
P. Natl. Acad. Sci. USA, 114, 5367–5372, https://doi.org/10.1073/pnas.1616020114, 2017.
Tyler, S. C., Rice, A. L., and Ajie, H. O.: Stable isotope ratios in
atmospheric CH4: Implications for seasonal sources and sinks, J. Geophys.
Res.-Atmos., 112, D03303, https://doi.org/10.1029/2006JD007231, 2007.
van der Werf, G. R., Randerson, J. T., Giglio, L., Collatz, G. J., Mu, M., Kasibhatla, P. S., Morton, D. C., DeFries, R. S., Jin, Y., and van Leeuwen, T. T.: Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997–2009), Atmos. Chem. Phys., 10, 11707–11735, https://doi.org/10.5194/acp-10-11707-2010, 2010.
Vautard, R., Beekmann, M., Roux, J., and Gombert, D.: Validation of a hybrid
forecasting system for the ozone concentrations over the Paris area, Atmos.
Environ., 35, 2449–2461, https://doi.org/10.1016/S1352-2310(00)00466-0,
2001.
Walter, K. M., Smith, L. C., and Chapin III, F. S.: Methane bubbling from
northern lakes: present and future contributions to the global budget, Phil.
Trans. R. Soc. A, 365, 1657–1676, https://doi.org/10.1098/rsta.2007.2036,
2007.
Walter, K. M., Chanton, J. P., Chapin, F. S., Schuur, E. A. G., and Zimov,
S. A.: Methane production and bubble emissions from arctic lakes: Isotopic
implications for source pathways and ages, J. Geophys. Res., 113, G00A8,
https://doi.org/10.1029/2007JG000569, 2008.
Warwick, N. J., Cain, M. L., Fisher, R., France, J. L., Lowry, D., Michel, S. E., Nisbet, E. G., Vaughn, B. H., White, J. W. C., and Pyle, J. A.: Using δ13C-CH4 and δD-CH4 to constrain Arctic methane emissions, Atmos. Chem. Phys., 16, 14891–14908, https://doi.org/10.5194/acp-16-14891-2016, 2016.
WDCGG: World Data Centre Greenhouse Gases Data Center, operated by: JMA in collaboration with WMO under the Global Atmosphere Watch (GAW) Program, https://gaw/kishou.go.jp, last access: 18 September 2019.
White, J. W. C., Vaughn, B. H., and Michel, S. E.: University of Colorado,
Institute of Arctic and Alpine Research (INSTAAR), Stable Isotopic
Composition of Atmospheric Methane (13C) from the NOAA ESRL Carbon Cycle
Cooperative Global Air Sampling Network, 1998–2017, Version: 2018-09-24,
available at: ftp://aftp.cmdl.noaa.gov/data/trace_gases/ch4c13/flask/ (last access: 18 September 2019), 2018.
Whiticar, M. J.: Carbon and hydrogen isotope systematics of bacterial
formation and oxidation of methane, Chem. Geol., 161, 291–314, 1999.
Whiticar, M. and Schaefer, H.: Constraining past global tropospheric methane
budgets with carbon and hydrogen isotope ratios in ice, Philos. T. R. Soc.
S.-A, 365, 1793–1828, 2007.
Wik, M.: Emission of methane from Northern lakes and ponds, PhD
dissertation, Stockholm Univ., 2016.
Wik, M., Varner, R. K., Walter Anthony, K., MacIntyre, S., and Bastviken,
D.: Climate-sensitive northern lakes and ponds are critical components of
methane release, Nat. Geosci., 9, 99–105, https://doi.org/10.1038/ngeo2578,
2016.
Worden, J. R., Bloom, A. A., Pandey, S., Jiang, Z., Worden, H. M., Walker, T. W., Houweling, S., and Röckmann, T.: Reduced biomass burning emissions reconcile conflicting estimates of the post-2006 atmospheric methane budget, Nat. Commun., 8, 2227, 2017.
Yamada, K., Ozaki, Y., Nakagawa, F., Sudo, S., Tsuruta, H., and Yoshida, N.:
Hydrogen and carbon isotopic measurements of methane from agricultural
combustion: Implications for isotopic signatures of global biomass burning
sources, J. Geophys. Res., 111, D16306, https://doi.org/10.1029/2005JD006750, 2006.
Zazzeri, G., Lowry, D., Fisher, R. E., France, J. L., Lanoisellé, M., Kelly, B. F. J., Necki, J. M., Iverach, C. P., Ginty, E., Zimnoch, M., Jasek, A., and Nisbet, E. G.: Carbon isotopic signature of coal-derived methane emissions to the atmosphere: from coalification to alteration, Atmos. Chem. Phys., 16, 13669–13680, https://doi.org/10.5194/acp-16-13669-2016, 2016.
Short summary
This paper discusses the methane isotopic signals that could be detected at instrumental surface sites in the northern high latitudes using a 3–D chemistry transport model. Isotopic signals may be used in atmospheric inverse systems to better characterize methane emissions and changes. We show that depending on the source magnitude and the location of the site, detecting isotopic signals of specific individual sources may be challenging for the new generation of methane isotope instruments.
This paper discusses the methane isotopic signals that could be detected at instrumental surface...
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