Articles | Volume 17, issue 16
Atmos. Chem. Phys., 17, 9853–9868, 2017
https://doi.org/10.5194/acp-17-9853-2017
Atmos. Chem. Phys., 17, 9853–9868, 2017
https://doi.org/10.5194/acp-17-9853-2017
Research article
22 Aug 2017
Research article | 22 Aug 2017

Multiphase composition changes and reactive oxygen species formation during limonene oxidation in the new Cambridge Atmospheric Simulation Chamber (CASC)

Peter J. Gallimore et al.

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Cited articles

Abbatt, J. P. D., Lee, A. K. Y., and Thornton, J. A.: Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges, Chem. Soc. Rev., 41, 6555–6581, https://doi.org/10.1039/c2cs35052a, 2012.
Anglada, J. M., Martins-Costa, M., Francisco, J. S., and Ruiz-lo, M. F.: Interconnection of Reactive Oxygen Species Chemistry across the Interfaces of Atmospheric, Environmental, and Biological Processes, Accounts Chem. Res., 48, 575–83, https://doi.org/10.1021/ar500412p, 2015.
Apel, K. and Hirt, H.: Reactive oxygen species?: Metabolism, Oxidative Stress, and Signal Transduction, Annu. Rev. Plant Biol., 55, 373–99, https://doi.org/10.1146/annurev.arplant.55.031903.141701, 2004.
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Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Time-resolved molecular characterization of limonene/ozone aerosol using high-resolution electrospray ionization mass spectrometry, Phys. Chem. Chem. Phys., 11, 7931–7942, https://doi.org/10.1039/b916865f, 2009.
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Short summary
Limonene is emitted in substantial quantities by plants, and also has indoor sources from air fresheners and cleaning products. We studied particle formation from the oxidation of limonene and found substantial quantities of oxidising components which are thought to be associated with the negative health effects of particulates. State-of-the-art measurements of the products of limonene–ozone chemistry were also presented.
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