Articles | Volume 17, issue 16
https://doi.org/10.5194/acp-17-9853-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-9853-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
22 Aug 2017
Research article |
| 22 Aug 2017
Multiphase composition changes and reactive oxygen species formation during limonene oxidation in the new Cambridge Atmospheric Simulation Chamber (CASC)
Peter J. Gallimore
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Brendan M. Mahon
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Francis P. H. Wragg
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Stephen J. Fuller
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Chiara Giorio
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
now at: Aix Marseille Univ, CNRS, LCE Marseille, France
Ivan Kourtchev
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
now at: Department of Chemistry, University College Cork, College
Road, Cork, Ireland
Markus Kalberer
CORRESPONDING AUTHOR
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
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Cited
34 citations as recorded by crossref.
- Investigation of RH Effect on Uncommon Limonene Ozonolysis Products and SOA Formation in Indoor Air with Real Time Measurement Techniques K. Pytel & B. Zabiegała 10.2139/ssrn.4160355
- Real-time evaluation of terpene emissions and exposures during the use of scented wax products in residential buildings with PTR-TOF-MS J. Liu et al. 10.1016/j.buildenv.2024.111314
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Development of a Physiologically Relevant Online Chemical Assay To Quantify Aerosol Oxidative Potential S. Campbell et al. 10.1021/acs.analchem.9b03282
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Inflammatory responses to secondary organic aerosols (SOA) generated from biogenic and anthropogenic precursors W. Tuet et al. 10.5194/acp-17-11423-2017
- Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol J. Zhou et al. 10.5194/acp-19-14703-2019
- Dynamic Wood Smoke Aerosol Toxicity during Oxidative Atmospheric Aging S. Wang et al. 10.1021/acs.est.2c05929
- A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets S. Paulson et al. 10.1126/sciadv.aav7689
- Evaluating the use of biosensors for monitoring of Penicillium digitatum infection in citrus fruit D. Chalupowicz et al. 10.1016/j.snb.2020.127896
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Use of Dithiothreitol Assay to Evaluate the Oxidative Potential of Atmospheric Aerosols H. Jiang et al. 10.3390/atmos10100571
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Recent advances on SOA formation in indoor air, fate and strategies for SOA characterization in indoor air - A review K. Pytel et al. 10.1016/j.scitotenv.2022.156948
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała 10.1016/j.chemosphere.2023.140854
- The Interplay Between Hydrogen Bonding and Coulombic Forces in Determining the Structure of Sulfuric Acid-Amine Clusters S. Waller et al. 10.1021/acs.jpclett.8b00161
- Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules H. Tong et al. 10.1021/acs.est.9b05149
- Limononic Acid Oxidation by Hydroxyl Radicals and Ozone in the Aqueous Phase B. Witkowski et al. 10.1021/acs.est.7b04867
- Particle-bound reactive oxygen species in cooking emissions: Aging effects and cytotoxicity L. Lu et al. 10.1016/j.atmosenv.2023.120309
- Direct detection of monoterpenes in evacuated air atmospheres by glow discharge plasma source for mass spectrometry Y. Nunome et al. 10.1016/j.sab.2024.106975
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Atmospheric conditions and composition that influence PM<sub>2.5</sub> oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Viable route and DFT study for the synthesis of optically active limonaketone: A barely available natural feedstock in Cedrus atlantica A. Mekkaoui et al. 10.1016/j.molstruc.2021.130221
- Conformational landscape and internal dynamics of limona ketone, a key oxidation product of limonene N. Osseiran et al. 10.1016/j.jms.2022.111643
- Quantification of Particle-Bound Organic Radicals in Secondary Organic Aerosol S. Campbell et al. 10.1021/acs.est.9b00825
- Are reactive oxygen species (ROS) a suitable metric to predict toxicity of carbonaceous aerosol particles? Z. Zhang et al. 10.5194/acp-22-1793-2022
- Superoxide Formation from Aqueous Reactions of Biogenic Secondary Organic Aerosols J. Wei et al. 10.1021/acs.est.0c07789
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Investigation of the Dynamism of Nanosized SOA Particle Formation in Indoor Air by a Scanning Mobility Particle Sizer and Proton-Transfer-Reaction Mass Spectrometry K. Pytel et al. 10.3390/molecules25092202
- Characterisation of the Manchester Aerosol Chamber facility Y. Shao et al. 10.5194/amt-15-539-2022
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
- Online molecular characterisation of organic aerosols in an atmospheric chamber using extractive electrospray ionisation mass spectrometry P. Gallimore et al. 10.5194/acp-17-14485-2017
33 citations as recorded by crossref.
- Investigation of RH Effect on Uncommon Limonene Ozonolysis Products and SOA Formation in Indoor Air with Real Time Measurement Techniques K. Pytel & B. Zabiegała 10.2139/ssrn.4160355
- Real-time evaluation of terpene emissions and exposures during the use of scented wax products in residential buildings with PTR-TOF-MS J. Liu et al. 10.1016/j.buildenv.2024.111314
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Development of a Physiologically Relevant Online Chemical Assay To Quantify Aerosol Oxidative Potential S. Campbell et al. 10.1021/acs.analchem.9b03282
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Inflammatory responses to secondary organic aerosols (SOA) generated from biogenic and anthropogenic precursors W. Tuet et al. 10.5194/acp-17-11423-2017
- Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol J. Zhou et al. 10.5194/acp-19-14703-2019
- Dynamic Wood Smoke Aerosol Toxicity during Oxidative Atmospheric Aging S. Wang et al. 10.1021/acs.est.2c05929
- A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets S. Paulson et al. 10.1126/sciadv.aav7689
- Evaluating the use of biosensors for monitoring of Penicillium digitatum infection in citrus fruit D. Chalupowicz et al. 10.1016/j.snb.2020.127896
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Use of Dithiothreitol Assay to Evaluate the Oxidative Potential of Atmospheric Aerosols H. Jiang et al. 10.3390/atmos10100571
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Recent advances on SOA formation in indoor air, fate and strategies for SOA characterization in indoor air - A review K. Pytel et al. 10.1016/j.scitotenv.2022.156948
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała 10.1016/j.chemosphere.2023.140854
- The Interplay Between Hydrogen Bonding and Coulombic Forces in Determining the Structure of Sulfuric Acid-Amine Clusters S. Waller et al. 10.1021/acs.jpclett.8b00161
- Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules H. Tong et al. 10.1021/acs.est.9b05149
- Limononic Acid Oxidation by Hydroxyl Radicals and Ozone in the Aqueous Phase B. Witkowski et al. 10.1021/acs.est.7b04867
- Particle-bound reactive oxygen species in cooking emissions: Aging effects and cytotoxicity L. Lu et al. 10.1016/j.atmosenv.2023.120309
- Direct detection of monoterpenes in evacuated air atmospheres by glow discharge plasma source for mass spectrometry Y. Nunome et al. 10.1016/j.sab.2024.106975
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Atmospheric conditions and composition that influence PM<sub>2.5</sub> oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Viable route and DFT study for the synthesis of optically active limonaketone: A barely available natural feedstock in Cedrus atlantica A. Mekkaoui et al. 10.1016/j.molstruc.2021.130221
- Conformational landscape and internal dynamics of limona ketone, a key oxidation product of limonene N. Osseiran et al. 10.1016/j.jms.2022.111643
- Quantification of Particle-Bound Organic Radicals in Secondary Organic Aerosol S. Campbell et al. 10.1021/acs.est.9b00825
- Are reactive oxygen species (ROS) a suitable metric to predict toxicity of carbonaceous aerosol particles? Z. Zhang et al. 10.5194/acp-22-1793-2022
- Superoxide Formation from Aqueous Reactions of Biogenic Secondary Organic Aerosols J. Wei et al. 10.1021/acs.est.0c07789
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Investigation of the Dynamism of Nanosized SOA Particle Formation in Indoor Air by a Scanning Mobility Particle Sizer and Proton-Transfer-Reaction Mass Spectrometry K. Pytel et al. 10.3390/molecules25092202
- Characterisation of the Manchester Aerosol Chamber facility Y. Shao et al. 10.5194/amt-15-539-2022
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
Latest update: 25 Dec 2024
Short summary
Limonene is emitted in substantial quantities by plants, and also has indoor sources from
air freshenersand cleaning products. We studied particle formation from the oxidation of limonene and found substantial quantities of oxidising components which are thought to be associated with the negative health effects of particulates. State-of-the-art measurements of the products of limonene–ozone chemistry were also presented.
Limonene is emitted in substantial quantities by plants, and also has indoor sources from
air...
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