Articles | Volume 17, issue 23
Atmos. Chem. Phys., 17, 14485–14500, 2017
https://doi.org/10.5194/acp-17-14485-2017
Atmos. Chem. Phys., 17, 14485–14500, 2017
https://doi.org/10.5194/acp-17-14485-2017
Research article
06 Dec 2017
Research article | 06 Dec 2017

Online molecular characterisation of organic aerosols in an atmospheric chamber using extractive electrospray ionisation mass spectrometry

Peter J. Gallimore et al.

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Cited articles

Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Time-resolved molecular characterization of limonene/ozone aerosol using high-resolution electrospray ionization mass spectrometry, Phys. Chem. Chem. Phys., 11, 7931–7942, https://doi.org/10.1039/b916865f, 2009.
Bilde, M. and Pandis, S. N.: Evaporation Rates and Vapor Pressures of Individual Aerosol Species Formed in the Atmospheric Oxidation of alpha- and beta-Pinene, Environ. Sci. Technol., 35, 3344–3349, 2001.
Blake, R. S., Monks, P. S., and Ellis, A. M.: Proton-transfer reaction mass spectrometry, Chem. Rev., 109, 861–96, https://doi.org/10.1021/cr800364q, 2009.
Boucher, O., Randall, D., Artaxo, P., Bretherton, C., Feingold, G., Forster, P., Kerminen, V.-M., Kondo, Y., Liao, H., Lohmann, U., Rasch, P., Satheesh, S. K., Sherwood, S., Stevens, B., and Zhang, X. Y.: Clouds and Aerosols, in: Climate Change 2013: The Physical Science Basis, Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., 2013.
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This work helps to better understand the potential climate and health impacts of airborne aerosol particles. We applied a new technique to provide a diagnostic fingerprint of the organic compounds present in aerosols. We followed changes in this fingerprint over time in lab experiments which mimic the conversion of plant emissions into aerosols. Our results compare well with computer simulations of the reactions and we conclude that the technique merits continuing use and development in future.
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