Articles | Volume 17, issue 23
https://doi.org/10.5194/acp-17-14485-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-17-14485-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Dec 2017
Research article |
| 06 Dec 2017
| 06 Dec 2017
Online molecular characterisation of organic aerosols in an atmospheric chamber using extractive electrospray ionisation mass spectrometry
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Chiara Giorio
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
now at: Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via Marzolo 1, 13 35131 Padua, Italy
Brendan M. Mahon
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
Markus Kalberer
CORRESPONDING AUTHOR
Department of Chemistry, University of Cambridge, Lensfield Road,
Cambridge, CB2 1EW, UK
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Cited
18 citations as recorded by crossref.
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Comparison of Measurement-Based Methodologies to Apportion Secondary Organic Carbon (SOC) in PM2.5: A Review of Recent Studies D. Srivastava et al. 10.3390/atmos9110452
- An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles F. Lopez-Hilfiker et al. 10.5194/amt-12-4867-2019
- Probing autoxidation of oleic acid at air-water interface: A neglected and significant pathway for secondary organic aerosols formation J. He et al. 10.1016/j.envres.2022.113232
- Decreasing the Uncertainty in the Comparison of Molecular Fingerprints of Organic Aerosols with H/D Exchange Mass Spectrometry A. Zherebker et al. 10.1021/acs.est.4c06749
- Online Aerosol Chemical Characterization by Extractive Electrospray Ionization–Ultrahigh-Resolution Mass Spectrometry (EESI-Orbitrap) C. Lee et al. 10.1021/acs.est.9b07090
- Real‐time organic aerosol chemical speciation in the indoor environment using extractive electrospray ionization mass spectrometry W. Brown et al. 10.1111/ina.12721
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman 10.1146/annurev-anchem-061516-045135
- Rapid Droplet Sampling Interface for Low-Volume, High-Throughput Mass Spectrometry Analysis J. Cahill & V. Kertesz 10.1021/acs.analchem.3c04015
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. 10.1021/acs.analchem.0c03697
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Insights on the Working Principles of Secondary Electrospray Ionization High-Resolution Mass Spectrometry for Quantitative Analysis of Aerosol Chemical Composition X. Xu et al. 10.1007/s41810-021-00091-9
- Ultrahigh-Resolution Mass Spectrometry in Real Time: Atmospheric Pressure Chemical Ionization Orbitrap Mass Spectrometry of Atmospheric Organic Aerosol C. Zuth et al. 10.1021/acs.analchem.8b00671
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- Indoor Illumination of Terpenes and Bleach Emissions Leads to Particle Formation and Growth C. Wang et al. 10.1021/acs.est.9b04261
- New Mechanism of Extractive Electrospray Ionization Mass Spectrometry for Heterogeneous Solid Particles S. Kumbhani et al. 10.1021/acs.analchem.7b04164
17 citations as recorded by crossref.
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Comparison of Measurement-Based Methodologies to Apportion Secondary Organic Carbon (SOC) in PM2.5: A Review of Recent Studies D. Srivastava et al. 10.3390/atmos9110452
- An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles F. Lopez-Hilfiker et al. 10.5194/amt-12-4867-2019
- Probing autoxidation of oleic acid at air-water interface: A neglected and significant pathway for secondary organic aerosols formation J. He et al. 10.1016/j.envres.2022.113232
- Decreasing the Uncertainty in the Comparison of Molecular Fingerprints of Organic Aerosols with H/D Exchange Mass Spectrometry A. Zherebker et al. 10.1021/acs.est.4c06749
- Online Aerosol Chemical Characterization by Extractive Electrospray Ionization–Ultrahigh-Resolution Mass Spectrometry (EESI-Orbitrap) C. Lee et al. 10.1021/acs.est.9b07090
- Real‐time organic aerosol chemical speciation in the indoor environment using extractive electrospray ionization mass spectrometry W. Brown et al. 10.1111/ina.12721
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman 10.1146/annurev-anchem-061516-045135
- Rapid Droplet Sampling Interface for Low-Volume, High-Throughput Mass Spectrometry Analysis J. Cahill & V. Kertesz 10.1021/acs.analchem.3c04015
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. 10.1021/acs.analchem.0c03697
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Insights on the Working Principles of Secondary Electrospray Ionization High-Resolution Mass Spectrometry for Quantitative Analysis of Aerosol Chemical Composition X. Xu et al. 10.1007/s41810-021-00091-9
- Ultrahigh-Resolution Mass Spectrometry in Real Time: Atmospheric Pressure Chemical Ionization Orbitrap Mass Spectrometry of Atmospheric Organic Aerosol C. Zuth et al. 10.1021/acs.analchem.8b00671
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- Indoor Illumination of Terpenes and Bleach Emissions Leads to Particle Formation and Growth C. Wang et al. 10.1021/acs.est.9b04261
Latest update: 14 Dec 2024
Short summary
This work helps to better understand the potential climate and health impacts of airborne aerosol particles. We applied a new technique to provide a diagnostic fingerprint of the organic compounds present in aerosols. We followed changes in this fingerprint over time in lab experiments which mimic the conversion of plant emissions into aerosols. Our results compare well with computer simulations of the reactions and we conclude that the technique merits continuing use and development in future.
This work helps to better understand the potential climate and health impacts of airborne...
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