Articles | Volume 16, issue 17
Atmos. Chem. Phys., 16, 11001–11018, 2016
https://doi.org/10.5194/acp-16-11001-2016
Atmos. Chem. Phys., 16, 11001–11018, 2016
https://doi.org/10.5194/acp-16-11001-2016
Research article
06 Sep 2016
Research article | 06 Sep 2016

Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes

Matthieu Riva et al.

Related authors

Assessing the impact of anthropogenic pollution on isoprene-derived secondary organic aerosol formation in PM2.5 collected from the Birmingham, Alabama, ground site during the 2013 Southern Oxidant and Aerosol Study
Weruka Rattanavaraha, Kevin Chu, Sri Hapsari Budisulistiorini, Matthieu Riva, Ying-Hsuan Lin, Eric S. Edgerton, Karsten Baumann, Stephanie L. Shaw, Hongyu Guo, Laura King, Rodney J. Weber, Miranda E. Neff, Elizabeth A. Stone, John H. Offenberg, Zhenfa Zhang, Avram Gold, and Jason D. Surratt
Atmos. Chem. Phys., 16, 4897–4914, https://doi.org/10.5194/acp-16-4897-2016,https://doi.org/10.5194/acp-16-4897-2016, 2016
Short summary
Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements
W. W. Hu, P. Campuzano-Jost, B. B. Palm, D. A. Day, A. M. Ortega, P. L. Hayes, J. E. Krechmer, Q. Chen, M. Kuwata, Y. J. Liu, S. S. de Sá, K. McKinney, S. T. Martin, M. Hu, S. H. Budisulistiorini, M. Riva, J. D. Surratt, J. M. St. Clair, G. Isaacman-Van Wertz, L. D. Yee, A. H. Goldstein, S. Carbone, J. Brito, P. Artaxo, J. A. de Gouw, A. Koss, A. Wisthaler, T. Mikoviny, T. Karl, L. Kaser, W. Jud, A. Hansel, K. S. Docherty, M. L. Alexander, N. H. Robinson, H. Coe, J. D. Allan, M. R. Canagaratna, F. Paulot, and J. L. Jimenez
Atmos. Chem. Phys., 15, 11807–11833, https://doi.org/10.5194/acp-15-11807-2015,https://doi.org/10.5194/acp-15-11807-2015, 2015
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Optical and chemical properties and oxidative potential of aqueous-phase products from OH and 3C-initiated photooxidation of eugenol
Xudong Li, Ye Tao, Longwei Zhu, Shuaishuai Ma, Shipeng Luo, Zhuzi Zhao, Ning Sun, Xinlei Ge, and Zhaolian Ye
Atmos. Chem. Phys., 22, 7793–7814, https://doi.org/10.5194/acp-22-7793-2022,https://doi.org/10.5194/acp-22-7793-2022, 2022
Short summary
The relationship between PM2.5 and anticyclonic wave activity during summer over the United States
Ye Wang, Natalie Mahowald, Peter Hess, Wenxiu Sun, and Gang Chen
Atmos. Chem. Phys., 22, 7575–7592, https://doi.org/10.5194/acp-22-7575-2022,https://doi.org/10.5194/acp-22-7575-2022, 2022
Short summary
Iron from coal combustion particles dissolves much faster than mineral dust under simulated atmospheric acidic conditions
Clarissa Baldo, Akinori Ito, Michael D. Krom, Weijun Li, Tim Jones, Nick Drake, Konstantin Ignatyev, Nicholas Davidson, and Zongbo Shi
Atmos. Chem. Phys., 22, 6045–6066, https://doi.org/10.5194/acp-22-6045-2022,https://doi.org/10.5194/acp-22-6045-2022, 2022
Short summary
Cellulose in atmospheric particulate matter at rural and urban sites across France and Switzerland
Adam Brighty, Véronique Jacob, Gaëlle Uzu, Lucille Borlaza, Sébastien Conil, Christoph Hueglin, Stuart K. Grange, Olivier Favez, Cécile Trébuchon, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 22, 6021–6043, https://doi.org/10.5194/acp-22-6021-2022,https://doi.org/10.5194/acp-22-6021-2022, 2022
Short summary
Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K
Linyu Gao, Junwei Song, Claudia Mohr, Wei Huang, Magdalena Vallon, Feng Jiang, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 22, 6001–6020, https://doi.org/10.5194/acp-22-6001-2022,https://doi.org/10.5194/acp-22-6001-2022, 2022
Short summary

Cited articles

Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. Environ., 34, 2063–2101, 2000.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, 2003.
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry, Atmos. Chem. Phys., 9, 2533–2542, https://doi.org/10.5194/acp-9-2533-2009, 2009.
Attygalle, A.B., Garcia-Rubio, S., Ta, J., and Meinwald, J.: Collisionally-induced dissociation mass spectra of organic sulfate anions, J. Chem. Soc., 2, 498–506, 2001.
Boone, E. J., Laskin, A., Laskin, J., Wirth, C., Shepson, P. B., Stirm, B. H., and Pratt, K. A.: Aqueous processing of atmospheric organic particles in cloud water collected via aircraft sampling, Environ. Sci. Technol., 49, 8523–8530, 2015.
Download
Short summary
Formation of organosulfates (OSs) in secondary organic aerosol from the photooxidation of alkanes is reported from smog chamber experiments. Effects of acidity and relative humidity on OS formation were examined. Most of the OSs identified could be explained by formation of gaseous epoxide and/or hydroperoxide precursors with subsequent acid-catalyzed multiphase chemistry onto sulfate aerosol. The OSs identified here were also observed and quantified in aerosols collected in two urban areas.
Altmetrics
Final-revised paper
Preprint