Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-11001-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-11001-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes
Matthieu Riva
CORRESPONDING AUTHOR
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, NC 27599, USA
Thais Da Silva Barbosa
CAPES Foundation, Brazil Ministry of Education, Brasilia, DF
70.040-020, Brazil
Departamento de Química, Instituto de Ciências Exatas,
Universidade Federal Rural do Rio de Janeiro, Seropédica, Brazil
Ying-Hsuan Lin
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, NC 27599, USA
now at: Michigan Society of Fellows, Department of Chemistry,
University of Michigan, Ann Arbor, MI 48109, USA
Elizabeth A. Stone
Department of Chemistry, University of Iowa, Iowa City, IA 52242,
USA
Avram Gold
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, NC 27599, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, NC 27599, USA
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Short summary
Formation of organosulfates (OSs) in secondary organic aerosol from the photooxidation of alkanes is reported from smog chamber experiments. Effects of acidity and relative humidity on OS formation were examined. Most of the OSs identified could be explained by formation of gaseous epoxide and/or hydroperoxide precursors with subsequent acid-catalyzed multiphase chemistry onto sulfate aerosol. The OSs identified here were also observed and quantified in aerosols collected in two urban areas.
Formation of organosulfates (OSs) in secondary organic aerosol from the photooxidation of...
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