Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-10809-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-10809-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Technical note
| 
31 Aug 2016
Technical note |
| 31 Aug 2016
Technical note: Mineralogical, chemical, morphological, and optical interrelationships of mineral dust re-suspensions
Desert Research Institute (DRI), Reno, Nevada 89512-1095, USA
Hans Moosmüller
Desert Research Institute (DRI), Reno, Nevada 89512-1095, USA
Samuel Pincock
Desert Research Institute (DRI), Reno, Nevada 89512-1095, USA
R. K. M. Jayanty
RTI International, Raleigh, North Carolina 27675-9000, USA
Traci Lersch
RJ Lee Group, Inc., Monroeville, Pennsylvania 15146, USA
Gary Casuccio
RJ Lee Group, Inc., Monroeville, Pennsylvania 15146, USA
Related authors
Natalie M. Mahowald, Longlei Li, Julius Vira, Marje Prank, Douglas S. Hamilton, Hitoshi Matsui, Ron L. Miller, Louis Lu, Ezgi Akyuz, Daphne Meidan, Peter G. Hess, Heikki Lihavainen, Christine Wiedinmyer, Jenny Hand, Maria Grazia Alaimo, Célia Alves, Andres Alastuey, Paulo Artaxo, Africa Barreto, Francisco Barraza, Silvia Becagli, Giulia Calzolai, Shankararaman Chellam, Ying Chen, Patrick Chuang, David D. Cohen, Cristina Colombi, Evangelia Diapouli, Gaetano Dongarra, Konstantinos Eleftheriadis, Johann Engelbrecht, Corinne Galy-Lacaux, Cassandra Gaston, Dario Gomez, Yenny González Ramos, Roy M. Harrison, Chris Heyes, Barak Herut, Philip Hopke, Christoph Hüglin, Maria Kanakidou, Zsofia Kertesz, Zbigniew Klimont, Katriina Kyllönen, Fabrice Lambert, Xiaohong Liu, Remi Losno, Franco Lucarelli, Willy Maenhaut, Beatrice Marticorena, Randall V. Martin, Nikolaos Mihalopoulos, Yasser Morera-Gomez, Adina Paytan, Joseph Prospero, Sergio Rodríguez, Patricia Smichowski, Daniela Varrica, Brenna Walsh, Crystal Weagle, and Xi Zhao
EGUsphere, https://doi.org/10.5194/egusphere-2024-1617, https://doi.org/10.5194/egusphere-2024-1617, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Aerosol particles are an important part of the Earth system, but their concentrations are spatially and temporally heterogeneous, as well as variable in size and composition. Here we present a new compilation of PM2.5 and PM10 aerosol observations, focusing on the spatial variability across different observational stations, including composition, and demonstrate a method for comparing the datasets to model output.
Johann P. Engelbrecht, Georgiy Stenchikov, P. Jish Prakash, Traci Lersch, Anatolii Anisimov, and Illia Shevchenko
Atmos. Chem. Phys., 17, 11467–11490, https://doi.org/10.5194/acp-17-11467-2017, https://doi.org/10.5194/acp-17-11467-2017, 2017
Short summary
Short summary
Desert dust has a profound impact on peoples health, visibility, damage to equipment, and global climate. This research is on dust from the Arabian Peninsula and aims at collecting and analyzing mineralogical, physical, and chemical composition of dust deposits from the atmosphere at the KAUST campus along the Red Sea in Saudi Arabia. The results will be used to assess the input of nutrients to the Red Sea, and will support dust modeling in the Middle East.
P. Jish Prakash, Georgiy Stenchikov, Weichun Tao, Tahir Yapici, Bashir Warsama, and Johann P. Engelbrecht
Atmos. Chem. Phys., 16, 11991–12004, https://doi.org/10.5194/acp-16-11991-2016, https://doi.org/10.5194/acp-16-11991-2016, 2016
Short summary
Short summary
The study is on the mineralogical, chemical and physical properties of surface soil samples from the Arabian Red Sea coastal plain. The sampled sites were previously identified to be potential source areas for windblown mineral dust. Results from this study will improve dust transport and other types of modeling, and also provide a better assessment of the impact of coastal dust on the Red Sea.
Y. Zhang, N. Mahowald, R. A. Scanza, E. Journet, K. Desboeufs, S. Albani, J. F. Kok, G. Zhuang, Y. Chen, D. D. Cohen, A. Paytan, M. D. Patey, E. P. Achterberg, J. P. Engelbrecht, and K. W. Fomba
Biogeosciences, 12, 5771–5792, https://doi.org/10.5194/bg-12-5771-2015, https://doi.org/10.5194/bg-12-5771-2015, 2015
Short summary
Short summary
A new technique to determine a size-fractionated global soil elemental emission inventory based on a global soil and mineralogical data set is introduced. Spatial variability of mineral dust elemental fractions (8 elements, e.g., Ca, Fe, Al) is identified on a global scale, particularly for Ca. The Ca/Al ratio ranged between 0.1 and 5.0 and is confirmed as an indicator of dust source regions by a global dust model. Total and soluble dust element fluxes into different ocean basins are estimated.
Natalie M. Mahowald, Longlei Li, Julius Vira, Marje Prank, Douglas S. Hamilton, Hitoshi Matsui, Ron L. Miller, Louis Lu, Ezgi Akyuz, Daphne Meidan, Peter G. Hess, Heikki Lihavainen, Christine Wiedinmyer, Jenny Hand, Maria Grazia Alaimo, Célia Alves, Andres Alastuey, Paulo Artaxo, Africa Barreto, Francisco Barraza, Silvia Becagli, Giulia Calzolai, Shankararaman Chellam, Ying Chen, Patrick Chuang, David D. Cohen, Cristina Colombi, Evangelia Diapouli, Gaetano Dongarra, Konstantinos Eleftheriadis, Johann Engelbrecht, Corinne Galy-Lacaux, Cassandra Gaston, Dario Gomez, Yenny González Ramos, Roy M. Harrison, Chris Heyes, Barak Herut, Philip Hopke, Christoph Hüglin, Maria Kanakidou, Zsofia Kertesz, Zbigniew Klimont, Katriina Kyllönen, Fabrice Lambert, Xiaohong Liu, Remi Losno, Franco Lucarelli, Willy Maenhaut, Beatrice Marticorena, Randall V. Martin, Nikolaos Mihalopoulos, Yasser Morera-Gomez, Adina Paytan, Joseph Prospero, Sergio Rodríguez, Patricia Smichowski, Daniela Varrica, Brenna Walsh, Crystal Weagle, and Xi Zhao
EGUsphere, https://doi.org/10.5194/egusphere-2024-1617, https://doi.org/10.5194/egusphere-2024-1617, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Aerosol particles are an important part of the Earth system, but their concentrations are spatially and temporally heterogeneous, as well as variable in size and composition. Here we present a new compilation of PM2.5 and PM10 aerosol observations, focusing on the spatial variability across different observational stations, including composition, and demonstrate a method for comparing the datasets to model output.
Myungje Choi, Alexei Lyapustin, Gregory L. Schuster, Sujung Go, Yujie Wang, Sergey Korkin, Ralph Kahn, Jeffrey S. Reid, Edward J. Hyer, Thomas F. Eck, Mian Chin, David J. Diner, Olga Kalashnikova, Oleg Dubovik, Jhoon Kim, and Hans Moosmüller
EGUsphere, https://doi.org/10.5194/egusphere-2024-1327, https://doi.org/10.5194/egusphere-2024-1327, 2024
Short summary
Short summary
This paper introduces a retrieval algorithm to estimate two key absorbing components in smoke, black carbon and brown carbon, using DSCOVR EPIC measurements. Our analysis reveals distinct smoke properties, including spectral absorption, layer height, and black carbon and brown carbon, over North America and Central Africa. The retrieved smoke properties offer valuable observational constraints for modeling radiative forcing and informing health-related studies.
Deep Sengupta, Vera Samburova, Chiranjivi Bhattarai, Adam C. Watts, Hans Moosmüller, and Andrey Y. Khlystov
Atmos. Chem. Phys., 20, 8227–8250, https://doi.org/10.5194/acp-20-8227-2020, https://doi.org/10.5194/acp-20-8227-2020, 2020
Short summary
Short summary
This paper presents important results on the atmospheric chemistry of combustion emissions. Organic compounds from these emissions can contribute significantly to chemical and physical properties of atmospheric aerosols. In this paper, a detailed chemical analysis of gas- and particle-phase polar organic compounds from the laboratory combustion of globally important fuels is presented. The aging experiments were performed to understand the fate of biomass-burning organics in the atmosphere.
Nicholas D. Beres, Deep Sengupta, Vera Samburova, Andrey Y. Khlystov, and Hans Moosmüller
Atmos. Chem. Phys., 20, 6095–6114, https://doi.org/10.5194/acp-20-6095-2020, https://doi.org/10.5194/acp-20-6095-2020, 2020
Short summary
Short summary
Brown carbon (BrC) aerosol can be produced by the smoldering combustion of peat, a wildland fuel common at high latitude, often adjacent to the cryosphere. However, little is known about how BrC deposition onto snow changes snow optical and radiative properties. Here, we artificially deposited BrC onto natural snow surfaces, monitored changes of the spectral surface albedo, characterized optical properties of deposited aerosol, and compared to modeled values of albedo and radiative forcing.
Nicholas D. Beres and Hans Moosmüller
Atmos. Meas. Tech., 11, 6803–6813, https://doi.org/10.5194/amt-11-6803-2018, https://doi.org/10.5194/amt-11-6803-2018, 2018
Short summary
Short summary
Particulate matter found in the atmosphere, or aerosols, can deposit on snow and ice and significantly change its reflectivity. Consequently, the timing of snow melt and snow water runoff is also changed. To study these processes, it is important to be able to deposit aerosols in a controlled manner on snow surfaces. Here, we present the design and demonstrate the use of an apparatus for deposition of common mineral dust and combustion aerosols.
Deep Sengupta, Vera Samburova, Chiranjivi Bhattarai, Elena Kirillova, Lynn Mazzoleni, Michealene Iaukea-Lum, Adam Watts, Hans Moosmüller, and Andrey Khlystov
Atmos. Chem. Phys., 18, 10849–10867, https://doi.org/10.5194/acp-18-10849-2018, https://doi.org/10.5194/acp-18-10849-2018, 2018
Short summary
Short summary
Optical properties of polar and non-polar extracts of biomass burning organic aerosols (BBOAs) generated by burning of globally and regionally important fuels were studied. The non-polar fraction of BBOAs was found to be more light absorbing than the polar fraction. Laboratory aging of BBOAs produced by flaming fuels increased aerosol light absorption attributed to the formation of organo-nitrogen compounds. Refractive indices were retrieved for both polar and non-polar extracts of BBOAs.
Johann P. Engelbrecht, Georgiy Stenchikov, P. Jish Prakash, Traci Lersch, Anatolii Anisimov, and Illia Shevchenko
Atmos. Chem. Phys., 17, 11467–11490, https://doi.org/10.5194/acp-17-11467-2017, https://doi.org/10.5194/acp-17-11467-2017, 2017
Short summary
Short summary
Desert dust has a profound impact on peoples health, visibility, damage to equipment, and global climate. This research is on dust from the Arabian Peninsula and aims at collecting and analyzing mineralogical, physical, and chemical composition of dust deposits from the atmosphere at the KAUST campus along the Red Sea in Saudi Arabia. The results will be used to assess the input of nutrients to the Red Sea, and will support dust modeling in the Middle East.
Luka Drinovec, Asta Gregorič, Peter Zotter, Robert Wolf, Emily Anne Bruns, André S. H. Prévôt, Jean-Eudes Petit, Olivier Favez, Jean Sciare, Ian J. Arnold, Rajan K. Chakrabarty, Hans Moosmüller, Agnes Filep, and Griša Močnik
Atmos. Meas. Tech., 10, 1043–1059, https://doi.org/10.5194/amt-10-1043-2017, https://doi.org/10.5194/amt-10-1043-2017, 2017
Short summary
Short summary
Black carbon measurements are usually conducted with absorption filter photometers, which are prone to the filter-loading effect – a saturation of the instrumental response due to the accumulation of the sample in the filter matrix. In this paper, we conducted several field campaigns to investigate the hypothesis that this filter-loading effect depends on the optical properties of particles present in the filter matrix, especially on the coating of black carbon particles.
P. Jish Prakash, Georgiy Stenchikov, Weichun Tao, Tahir Yapici, Bashir Warsama, and Johann P. Engelbrecht
Atmos. Chem. Phys., 16, 11991–12004, https://doi.org/10.5194/acp-16-11991-2016, https://doi.org/10.5194/acp-16-11991-2016, 2016
Short summary
Short summary
The study is on the mineralogical, chemical and physical properties of surface soil samples from the Arabian Red Sea coastal plain. The sampled sites were previously identified to be potential source areas for windblown mineral dust. Results from this study will improve dust transport and other types of modeling, and also provide a better assessment of the impact of coastal dust on the Red Sea.
Rajan K. Chakrabarty, Madhu Gyawali, Reddy L. N. Yatavelli, Apoorva Pandey, Adam C. Watts, Joseph Knue, Lung-Wen A. Chen, Robert R. Pattison, Anna Tsibart, Vera Samburova, and Hans Moosmüller
Atmos. Chem. Phys., 16, 3033–3040, https://doi.org/10.5194/acp-16-3033-2016, https://doi.org/10.5194/acp-16-3033-2016, 2016
Short summary
Short summary
Brown carbon aerosols dominate particulate emissions from the burning of Alaskan and Siberian peatlands. They physically occur as amorphous "tar balls" with negligible black carbon mixing. They absorb very strongly in the shorter visible wavelengths, characterized by a mean Ångström coefficient of ≈ 9. These aerosols could result in a net warming of the atmosphere, provided the albedo of the underlying surface is greater than 0.6.
Y. Zhang, N. Mahowald, R. A. Scanza, E. Journet, K. Desboeufs, S. Albani, J. F. Kok, G. Zhuang, Y. Chen, D. D. Cohen, A. Paytan, M. D. Patey, E. P. Achterberg, J. P. Engelbrecht, and K. W. Fomba
Biogeosciences, 12, 5771–5792, https://doi.org/10.5194/bg-12-5771-2015, https://doi.org/10.5194/bg-12-5771-2015, 2015
Short summary
Short summary
A new technique to determine a size-fractionated global soil elemental emission inventory based on a global soil and mineralogical data set is introduced. Spatial variability of mineral dust elemental fractions (8 elements, e.g., Ca, Fe, Al) is identified on a global scale, particularly for Ca. The Ca/Al ratio ranged between 0.1 and 5.0 and is confirmed as an indicator of dust source regions by a global dust model. Total and soluble dust element fluxes into different ocean basins are estimated.
Related subject area
Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement report: Effects of transition metal ions on the optical properties of humic-like substances (HULIS) reveal a structural preference – a case study of PM2.5 in Beijing, China
Probing Iceland's dust-emitting sediments: particle size distribution, mineralogy, cohesion, Fe mode of occurrence, and reflectance spectra signatures
Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust
Comparison of water-soluble and water-insoluble organic compositions attributing to different light absorption efficiency between residential coal and biomass burning emissions
Suppressed atmospheric chemical aging of cooking organic aerosol particles in wintertime conditions
Formation and loss of light absorbance by phenolic aqueous SOA by ●OH and an organic triplet excited state
Technical Note: A technique to convert NO2 to NO2− with S(IV) and its application to measuring nitrate photolysis
Distribution, chemical, and molecular composition of high and low molecular weight humic-like substances in ambient aerosols
Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics
Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole
Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning
Characterization of the particle size distribution, mineralogy and Fe mode of occurrence of dust-emitting sediments across the Mojave Desert, California, USA
Assessment of the contribution of residential waste burning to ambient PM10 concentrations in Hungary and Romania
Source differences in the components and cytotoxicity of PM2.5 from automobile exhaust, coal combustion, and biomass burning contributing to urban aerosol toxicity
Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism
Low-temperature ice nucleation of sea spray and secondary marine aerosols under cirrus cloud conditions
Temperature-dependent aqueous OH kinetics of C2–C10 linear and terpenoid alcohols and diols: new rate coefficients, structure–activity relationship, and atmospheric lifetimes
A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides
Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles
Variability in sediment particle size, mineralogy, and Fe mode of occurrence across dust-source inland drainage basins: the case of the lower Drâa Valley, Morocco
Gas–particle partitioning of toluene oxidation products: an experimental and modeling study
Chemically speciated air pollutant emissions from open burning of household solid waste from South Africa
Bulk and molecular-level composition of primary organic aerosol from wood, straw, cow dung, and plastic burning
Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures
Molecular fingerprints and health risks of smoke from home-use incense burning
High enrichment of heavy metals in fine particulate matter through dust aerosol generation
Production of ice-nucleating particles (INPs) by fast-growing phytoplankton
Technical note: In situ measurements and modelling of the oxidation kinetics in films of a cooking aerosol proxy using a quartz crystal microbalance with dissipation monitoring (QCM-D)
Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism
Quantifying the seasonal variations in and regional transport of PM2.5 in the Yangtze River Delta region, China: characteristics, sources, and health risks
Opinion: Atmospheric multiphase chemistry – past, present, and future
Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts
Effects of storage conditions on the molecular-level composition of organic aerosol particles
Characterization of gas and particle emissions from open burning of household solid waste from South Africa
Chemically distinct particle-phase emissions from highly controlled pyrolysis of three wood types
Predicting photooxidant concentrations in aerosol liquid water based on laboratory extracts of ambient particles
Physicochemical characterization of free troposphere and marine boundary layer ice-nucleating particles collected by aircraft in the eastern North Atlantic
Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene
Impact of fossil and non-fossil fuel sources on the molecular compositions of water-soluble humic-like substances in PM2.5 at a suburban site of Yangtze River Delta, China
Technical note: Improved synthetic routes to cis- and trans-(2-methyloxirane-2,3-diyl)dimethanol (cis- and trans-β-isoprene epoxydiol)
Technical note: Intercomparison study of the elemental carbon radiocarbon analysis methods using synthetic known samples
Chemical evolution of primary and secondary biomass burning aerosols during daytime and nighttime
Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway
Measurement report: Atmospheric aging of combustion-derived particles – impact on stable free radical concentration and its ability to produce reactive oxygen species in aqueous media
Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants
An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles
Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry
Photo-induced shrinking of aqueous glycine aerosol droplets
Sulfate formation via aerosol-phase SO2 oxidation by model biomass burning photosensitizers: 3,4-dimethoxybenzaldehyde, vanillin and syringaldehyde using single-particle mixing-state analysis
Yields and molecular composition of gas-phase and secondary organic aerosol from the photooxidation of the volatile consumer product benzyl alcohol: formation of highly oxygenated and hydroxy nitro-aromatic compounds
Juanjuan Qin, Leiming Zhang, Yuanyuan Qin, Shaoxuan Shi, Jingnan Li, Zhao Shu, Yuwei Gao, Ting Qi, Jihua Tan, and Xinming Wang
Atmos. Chem. Phys., 24, 7575–7589, https://doi.org/10.5194/acp-24-7575-2024, https://doi.org/10.5194/acp-24-7575-2024, 2024
Short summary
Short summary
The present research unveiled that acidity dominates while transition metal ions harmonize with the light absorption properties of humic-like substances (HULIS). Cu2+ has quenching effects on HULIS by complexation, hydrogen substitution, or electrostatic adsorption, with aromatic structures of HULIS. Such effects are less pronounced if from Mn2+, Ni2+, Zn2+, and Cu2+. Oxidized HULIS might contain electron-donating groups, whereas N-containing compounds might contain electron-withdrawing groups.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert O. Green, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 6883–6910, https://doi.org/10.5194/acp-24-6883-2024, https://doi.org/10.5194/acp-24-6883-2024, 2024
Short summary
Short summary
The knowledge of properties from dust emitted in high latitudes such as in Iceland is scarce. This study focuses on the particle size, mineralogy, cohesion, and iron mode of occurrence and reflectance spectra of dust-emitting sediments. Icelandic top sediments have lower cohesion state, coarser particle size, distinctive mineralogy, and 3-fold bulk Fe content, with a large presence of magnetite compared to Saharan crusts.
Wangjin Yang, Jiawei Ma, Hongxing Yang, Fu Li, and Chong Han
Atmos. Chem. Phys., 24, 6757–6768, https://doi.org/10.5194/acp-24-6757-2024, https://doi.org/10.5194/acp-24-6757-2024, 2024
Short summary
Short summary
We provide evidence that light enhances the conversion of SO2 to sulfates on non-photoactive mineral dust, where triplet states of SO2 (3SO2) can act as a pivotal trigger to generate sulfates. Photochemical sulfate formation depends on H2O, O2, and basicity of mineral dust. The SO2 photochemistry on non-photoactive mineral dust contributes to sulfates, highlighting previously unknown pathways to better explain the missing sources of atmospheric sulfates.
Lu Zhang, Jin Li, Yaojie Li, Xinlei Liu, Zhihan Luo, Guofeng Shen, and Shu Tao
Atmos. Chem. Phys., 24, 6323–6337, https://doi.org/10.5194/acp-24-6323-2024, https://doi.org/10.5194/acp-24-6323-2024, 2024
Short summary
Short summary
Brown carbon (BrC) is related to radiative forcing and climate change. The BrC fraction from residential coal and biomass burning emissions, which were the major source of BrC, was characterized at the molecular level. The CHOS aromatic compounds explained higher light absorption efficiencies of biomass burning emissions compared to coal. The unique formulas of coal combustion aerosols were characterized by higher unsaturated compounds, and such information could be used for source appointment.
Wenli Liu, Longkun He, Yingjun Liu, Keren Liao, Qi Chen, and Mikinori Kuwata
Atmos. Chem. Phys., 24, 5625–5636, https://doi.org/10.5194/acp-24-5625-2024, https://doi.org/10.5194/acp-24-5625-2024, 2024
Short summary
Short summary
Cooking is a major source of particles in urban areas. Previous studies demonstrated that the chemical lifetimes of cooking organic aerosols (COAs) were much shorter (~minutes) than the values reported by field observations (~hours). We conducted laboratory experiments to resolve the discrepancy by considering suppressed reactivity under low temperature. The parameterized k2–T relationships and observed surface temperature data were used to estimate the chemical lifetimes of COA particles.
Stephanie Arciva, Lan Ma, Camille Mavis, Chrystal Guzman, and Cort Anastasio
Atmos. Chem. Phys., 24, 4473–4485, https://doi.org/10.5194/acp-24-4473-2024, https://doi.org/10.5194/acp-24-4473-2024, 2024
Short summary
Short summary
We measured changes in light absorption during the aqueous oxidation of six phenols with hydroxyl radical (●OH) or an organic triplet excited state (3C*). All the phenols formed light-absorbing secondary brown carbon (BrC), which then decayed with continued oxidation. Extrapolation to ambient conditions suggest ●OH is the dominant sink of secondary phenolic BrC in fog/cloud drops, while 3C* controls the lifetime of this light absorption in particle water.
Aaron Lieberman, Julietta Picco, Murat Onder, and Cort Anastasio
Atmos. Chem. Phys., 24, 4411–4419, https://doi.org/10.5194/acp-24-4411-2024, https://doi.org/10.5194/acp-24-4411-2024, 2024
Short summary
Short summary
We developed a method that uses aqueous S(IV) to quantitatively convert NO2 to NO2−, which allows both species to be quantified using the Griess method. As an example of the utility of the method, we quantified both photolysis channels of nitrate, with and without a scavenger for hydroxyl radical (·OH). The results show that without a scavenger, ·OH reacts with nitrite to form nitrogen dioxide, suppressing the apparent quantum yield of NO2− and enhancing that of NO2.
Xingjun Fan, Ao Cheng, Xufang Yu, Tao Cao, Dan Chen, Wenchao Ji, Yongbing Cai, Fande Meng, Jianzhong Song, and Ping'an Peng
Atmos. Chem. Phys., 24, 3769–3783, https://doi.org/10.5194/acp-24-3769-2024, https://doi.org/10.5194/acp-24-3769-2024, 2024
Short summary
Short summary
Molecular-level characteristics of high molecular weight (HMW) and low MW (LMW) humic-like substances (HULIS) were comprehensively investigated, where HMW HULIS had larger chromophores and larger molecular size than LMW HULIS and exhibited higher aromaticity and humification. Electrospray ionization high-resolution mass spectrometry revealed more aromatic molecules in HMW HULIS. HMW HULIS had more CHON compounds, while LMW HULIS had more CHO compounds.
Daniel A. Knopf, Markus Ammann, Thomas Berkemeier, Ulrich Pöschl, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 3445–3528, https://doi.org/10.5194/acp-24-3445-2024, https://doi.org/10.5194/acp-24-3445-2024, 2024
Short summary
Short summary
The initial step of interfacial and multiphase chemical processes involves adsorption and desorption of gas species. This study demonstrates the role of desorption energy governing the residence time of the gas species at the environmental interface. A parameterization is formulated that enables the prediction of desorption energy based on the molecular weight, polarizability, and oxygen-to-carbon ratio of the desorbing chemical species. Its application to gas–particle interactions is discussed.
Feng Jiang, Kyla Siemens, Claudia Linke, Yanxia Li, Yiwei Gong, Thomas Leisner, Alexander Laskin, and Harald Saathoff
Atmos. Chem. Phys., 24, 2639–2649, https://doi.org/10.5194/acp-24-2639-2024, https://doi.org/10.5194/acp-24-2639-2024, 2024
Short summary
Short summary
We investigated the optical properties, chemical composition, and formation mechanisms of secondary organic aerosol (SOA) and brown carbon (BrC) from the oxidation of indole with and without NO2 in the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) simulation chamber. This work is one of the very few to link the optical properties and chemical composition of indole SOA with and without NO2 by simulation chamber experiments.
Evangelia Kostenidou, Baptiste Marques, Brice Temime-Roussel, Yao Liu, Boris Vansevenant, Karine Sartelet, and Barbara D'Anna
Atmos. Chem. Phys., 24, 2705–2729, https://doi.org/10.5194/acp-24-2705-2024, https://doi.org/10.5194/acp-24-2705-2024, 2024
Short summary
Short summary
Secondary organic aerosol (SOA) from gasoline vehicles can be a significant source of particulate matter in urban areas. Here the chemical composition of secondary volatile organic compounds and SOA produced by photo-oxidation of Euro 5 gasoline vehicle emissions was studied. The volatility of the SOA formed was calculated. Except for the temperature and the concentration of the aerosol, additional parameters may play a role in the gas-to-particle partitioning.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Melani Hernández-Chiriboga, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert Green, Paul Ginoux, Xavier Querol, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2024-434, https://doi.org/10.5194/egusphere-2024-434, 2024
Short summary
Short summary
In this research, we studied the dust-emitting properties of crusts and aeolian ripples from the Mojave Desert. These properties are key to understand the effect of dust upon climate. We found two different playa lakes according to the groundwater regime which implies differences on crusts cohesion state and its mineralogy, which can affect the dust emission potential and properties. We also compare them with Moroccan Sahara crusts and Icelandic top sediments.
András Hoffer, Aida Meiramova, Ádám Tóth, Beatrix Jancsek-Turóczi, Gyula Kiss, Ágnes Rostási, Erika Andrea Levei, Luminita Marmureanu, Attila Machon, and András Gelencsér
Atmos. Chem. Phys., 24, 1659–1671, https://doi.org/10.5194/acp-24-1659-2024, https://doi.org/10.5194/acp-24-1659-2024, 2024
Short summary
Short summary
Specific tracer compounds identified previously in controlled test burnings of different waste types in the laboratory were detected and quantified in ambient PM10 samples collected in five Hungarian and four Romanian settlements. Back-of-the-envelope calculations based on the relative emission factors of individual tracers suggested that the contribution of solid waste burning particulate emissions to ambient PM10 mass concentrations may be as high as a few percent.
Xiao-San Luo, Weijie Huang, Guofeng Shen, Yuting Pang, Mingwei Tang, Weijun Li, Zhen Zhao, Hanhan Li, Yaqian Wei, Longjiao Xie, and Tariq Mehmood
Atmos. Chem. Phys., 24, 1345–1360, https://doi.org/10.5194/acp-24-1345-2024, https://doi.org/10.5194/acp-24-1345-2024, 2024
Short summary
Short summary
PM2.5 are air pollutants threatening health globally, but they are a mixture of chemical compositions from many sources and result in unequal toxicity. Which composition from which source of PM2.5 as the most hazardous object is a question hindering effective pollution control policy-making. With chemical and toxicity experiments, we found automobile exhaust and coal combustion to be priority emissions with higher toxic compositions for precise air pollution control, ensuring public health.
Matthew B. Goss and Jesse H. Kroll
Atmos. Chem. Phys., 24, 1299–1314, https://doi.org/10.5194/acp-24-1299-2024, https://doi.org/10.5194/acp-24-1299-2024, 2024
Short summary
Short summary
The chemistry driving dimethyl sulfide (DMS) oxidation and subsequent sulfate particle formation in the atmosphere is poorly constrained. We oxidized two related compounds (dimethyl sulfoxide and dimethyl disulfide) in the laboratory under varied NOx conditions and measured the gas- and particle-phase products. These results demonstrate that both the OH addition and OH abstraction pathways for DMS oxidation contribute to particle formation via mechanisms that do not involve the SO2 intermediate.
Ryan J. Patnaude, Kathryn A. Moore, Russell J. Perkins, Thomas C. J. Hill, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 24, 911–928, https://doi.org/10.5194/acp-24-911-2024, https://doi.org/10.5194/acp-24-911-2024, 2024
Short summary
Short summary
In this study we examined the effect of atmospheric aging on sea spray aerosols (SSAs) to form ice and how newly formed secondary marine aerosols (SMAs) may freeze at cirrus temperatures (< −38 °C). Results show that SSAs freeze at different relative humidities (RHs) depending on the temperature and that the ice-nucleating ability of SSA was not hindered by atmospheric aging. SMAs are shown to freeze at high RHs and are likely inefficient at forming ice at cirrus temperatures.
Bartłomiej Witkowski, Priyanka Jain, Beata Wileńska, and Tomasz Gierczak
Atmos. Chem. Phys., 24, 663–688, https://doi.org/10.5194/acp-24-663-2024, https://doi.org/10.5194/acp-24-663-2024, 2024
Short summary
Short summary
This article reports the results of the kinetic measurements for the aqueous oxidation of the 29 aliphatic alcohols by hydroxyl radical (OH) at different temperatures. The data acquired and the literature data were used to optimize a model for predicting the aqueous OH reactivity of alcohols and carboxylic acids and to estimate the atmospheric lifetimes of five terpenoic alcohols. The kinetic data provided new insights into the mechanism of aqueous oxidation of aliphatic molecules by the OH.
Junting Qiu, Xinlin Shen, Jiangyao Chen, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 155–166, https://doi.org/10.5194/acp-24-155-2024, https://doi.org/10.5194/acp-24-155-2024, 2024
Short summary
Short summary
We studied reactions of secondary ozonides (SOZs) with amines. SOZs formed from ozonolysis of β-caryophyllene and α-humulene are found to be reactive to ethylamine and methylamine. Products from SOZs with various conformations reacting with the same amine had different functional groups. Our findings indicate that interaction of SOZs with amines in the atmosphere is very complicated, which is potentially a hitherto unrecognized source of N-containing compound formation.
Lan Ma, Reed Worland, Laura Heinlein, Chrystal Guzman, Wenqing Jiang, Christopher Niedek, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 24, 1–21, https://doi.org/10.5194/acp-24-1-2024, https://doi.org/10.5194/acp-24-1-2024, 2024
Short summary
Short summary
We measured concentrations of three photooxidants – the hydroxyl radical, triplet excited states of organic carbon, and singlet molecular oxygen – in fine particles collected over a year. Concentrations are highest in extracts of fresh biomass burning particles, largely because they have the highest particle concentrations and highest light absorption. When normalized by light absorption, rates of formation for each oxidant are generally similar for the four particle types we observed.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Cristina Reche, Patricia Córdoba, Natalia Moreno, Andres Alastuey, Konrad Kandler, Martina Klose, Clarissa Baldo, Roger N. Clark, Zongbo Shi, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 23, 15815–15834, https://doi.org/10.5194/acp-23-15815-2023, https://doi.org/10.5194/acp-23-15815-2023, 2023
Short summary
Short summary
The effect of dust emitted from desertic surfaces upon climate and ecosystems depends on size and mineralogy, but data from soil mineral atlases of desert soils are scarce. We performed particle-size distribution, mineralogy, and Fe speciation in southern Morocco. Results show coarser particles with high quartz proportion are near the elevated areas, while in depressed areas, sizes are finer, and proportions of clays and nano-Fe oxides are higher. This difference is important for dust modelling.
Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet
Atmos. Chem. Phys., 23, 15537–15560, https://doi.org/10.5194/acp-23-15537-2023, https://doi.org/10.5194/acp-23-15537-2023, 2023
Short summary
Short summary
Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Steven Sai Hang Ho, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 15375–15393, https://doi.org/10.5194/acp-23-15375-2023, https://doi.org/10.5194/acp-23-15375-2023, 2023
Short summary
Short summary
Open burning of municipal solid waste emits chemicals that are harmful to the environment. This paper reports source profiles and emission factors for PM2.5 species and acidic/alkali gases from laboratory combustion of 10 waste categories (including plastics and biomass) that represent open burning in South Africa. Results will be useful for health and climate impact assessments, speciated emission inventories, source-oriented dispersion models, and receptor-based source apportionment.
Jun Zhang, Kun Li, Tiantian Wang, Erlend Gammelsæter, Rico K. Y. Cheung, Mihnea Surdu, Sophie Bogler, Deepika Bhattu, Dongyu S. Wang, Tianqu Cui, Lu Qi, Houssni Lamkaddam, Imad El Haddad, Jay G. Slowik, Andre S. H. Prevot, and David M. Bell
Atmos. Chem. Phys., 23, 14561–14576, https://doi.org/10.5194/acp-23-14561-2023, https://doi.org/10.5194/acp-23-14561-2023, 2023
Short summary
Short summary
We conducted burning experiments to simulate various types of solid fuel combustion, including residential burning, wildfires, agricultural burning, cow dung, and plastic bag burning. The chemical composition of the particles was characterized using mass spectrometers, and new potential markers for different fuels were identified using statistical analysis. This work improves our understanding of emissions from solid fuel burning and offers support for refined source apportionment.
Hyun Gu Kang, Yanfang Chen, Yoojin Park, Thomas Berkemeier, and Hwajin Kim
Atmos. Chem. Phys., 23, 14307–14323, https://doi.org/10.5194/acp-23-14307-2023, https://doi.org/10.5194/acp-23-14307-2023, 2023
Short summary
Short summary
D5 is an emerging anthropogenic pollutant that is ubiquitous in indoor and urban environments, and the OH oxidation of D5 forms secondary organosiloxane aerosol (SOSiA). Application of a kinetic box model that uses a volatility basis set (VBS) showed that consideration of oxidative aging (aging-VBS) predicts SOSiA formation much better than using a standard-VBS model. Ageing-dependent parameterization is needed to accurately model SOSiA to assess the implications of siloxanes for air quality.
Kai Song, Rongzhi Tang, Jingshun Zhang, Zichao Wan, Yuan Zhang, Kun Hu, Yuanzheng Gong, Daqi Lv, Sihua Lu, Yu Tan, Ruifeng Zhang, Ang Li, Shuyuan Yan, Shichao Yan, Baoming Fan, Wenfei Zhu, Chak K. Chan, Maosheng Yao, and Song Guo
Atmos. Chem. Phys., 23, 13585–13595, https://doi.org/10.5194/acp-23-13585-2023, https://doi.org/10.5194/acp-23-13585-2023, 2023
Short summary
Short summary
Incense burning is common in Asia, posing threats to human health and air quality. However, less is known about its emissions and health risks. Full-volatility organic species from incense-burning smoke are detected and quantified. Intermediate-volatility volatile organic compounds (IVOCs) are crucial organics accounting for 19.2 % of the total emission factors (EFs) and 40.0 % of the secondary organic aerosol (SOA) estimation, highlighting the importance of incorporating IVOCs into SOA models.
Qianqian Gao, Shengqiang Zhu, Kaili Zhou, Jinghao Zhai, Shaodong Chen, Qihuang Wang, Shurong Wang, Jin Han, Xiaohui Lu, Hong Chen, Liwu Zhang, Lin Wang, Zimeng Wang, Xin Yang, Qi Ying, Hongliang Zhang, Jianmin Chen, and Xiaofei Wang
Atmos. Chem. Phys., 23, 13049–13060, https://doi.org/10.5194/acp-23-13049-2023, https://doi.org/10.5194/acp-23-13049-2023, 2023
Short summary
Short summary
Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Dust aerosols are mainly generated by wind erosion, which may have some chemical selectivity. Mn, Cd and Pb were found to be highly enriched in fine-dust (PM2.5) aerosols. In addition, estimation of heavy metal emissions from dust generation by air quality models may have errors without using proper dust profiles.
Daniel C. O. Thornton, Sarah D. Brooks, Elise K. Wilbourn, Jessica Mirrielees, Alyssa N. Alsante, Gerardo Gold-Bouchot, Andrew Whitesell, and Kiana McFadden
Atmos. Chem. Phys., 23, 12707–12729, https://doi.org/10.5194/acp-23-12707-2023, https://doi.org/10.5194/acp-23-12707-2023, 2023
Short summary
Short summary
A major uncertainty in our understanding of clouds and climate is the sources and properties of the aerosol on which clouds grow. We found that aerosol containing organic matter from fast-growing marine phytoplankton was a source of ice-nucleating particles (INPs). INPs facilitate freezing of ice crystals at warmer temperatures than otherwise possible and therefore change cloud formation and properties. Our results show that ecosystem processes and the properties of sea spray aerosol are linked.
Adam Milsom, Shaojun Qi, Ashmi Mishra, Thomas Berkemeier, Zhenyu Zhang, and Christian Pfrang
Atmos. Chem. Phys., 23, 10835–10843, https://doi.org/10.5194/acp-23-10835-2023, https://doi.org/10.5194/acp-23-10835-2023, 2023
Short summary
Short summary
Aerosols and films are found indoors and outdoors. Our study measures and models reactions of a cooking aerosol proxy with the atmospheric oxidant ozone relying on a low-cost but sensitive technique based on mass changes and film rigidity. We found that film morphology changed and film rigidity increased with evidence of surface crust formation during ozone exposure. Our modelling results demonstrate clear potential to take this robust method to the field for reaction monitoring.
Shan Zhang, Lin Du, Zhaomin Yang, Narcisse Tsona Tchinda, Jianlong Li, and Kun Li
Atmos. Chem. Phys., 23, 10809–10822, https://doi.org/10.5194/acp-23-10809-2023, https://doi.org/10.5194/acp-23-10809-2023, 2023
Short summary
Short summary
In this study, we have investigated the distinct impacts of humidity on the ozonolysis of two structurally different monoterpenes (limonene and Δ3-carene). We found that the molecular structure of precursors can largely influence the SOA formation under high RH by impacting the multi-generation reactions. Our results could advance knowledge on the roles of water content in aerosol formation and inform ongoing research on particle environmental effects and applications in models.
Yangzhihao Zhan, Min Xie, Wei Zhao, Tijian Wang, Da Gao, Pulong Chen, Jun Tian, Kuanguang Zhu, Shu Li, Bingliang Zhuang, Mengmeng Li, Yi Luo, and Runqi Zhao
Atmos. Chem. Phys., 23, 9837–9852, https://doi.org/10.5194/acp-23-9837-2023, https://doi.org/10.5194/acp-23-9837-2023, 2023
Short summary
Short summary
Although the main source contribution of pollution is secondary inorganic aerosols in Nanjing, health risks mainly come from industry sources and vehicle emissions. Therefore, the development of megacities should pay more attention to the health burden of vehicle emissions, coal combustion, and industrial processes. This study provides new insight into assessing the relationship between source apportionment and health risks and can provide valuable insight into air pollution strategies.
Jonathan P. D. Abbatt and A. R. Ravishankara
Atmos. Chem. Phys., 23, 9765–9785, https://doi.org/10.5194/acp-23-9765-2023, https://doi.org/10.5194/acp-23-9765-2023, 2023
Short summary
Short summary
With important climate and air quality impacts, atmospheric multiphase chemistry involves gas interactions with aerosol particles and cloud droplets. We summarize the status of the field and discuss potential directions for future growth. We highlight the importance of a molecular-level understanding of the chemistry, along with atmospheric field studies and modeling, and emphasize the necessity for atmospheric multiphase chemists to interact widely with scientists from neighboring disciplines.
Zhancong Liang, Zhihao Cheng, Ruifeng Zhang, Yiming Qin, and Chak K. Chan
Atmos. Chem. Phys., 23, 9585–9595, https://doi.org/10.5194/acp-23-9585-2023, https://doi.org/10.5194/acp-23-9585-2023, 2023
Short summary
Short summary
In this study, we found that the photolysis of sodium nitrate leads to a much quicker decay of free amino acids (FAAs, with glycine as an example) in the particle phase than ammonium nitrate photolysis, which is likely due to the molecular interactions between FAAs and different nitrate salts. Since sodium nitrate likely co-exists with FAAs in the coarse-mode particles, particulate nitrate photolysis can possibly contribute to a rapid decay of FAAs and affect atmospheric nitrogen cycling.
Julian Resch, Kate Wolfer, Alexandre Barth, and Markus Kalberer
Atmos. Chem. Phys., 23, 9161–9171, https://doi.org/10.5194/acp-23-9161-2023, https://doi.org/10.5194/acp-23-9161-2023, 2023
Short summary
Short summary
Detailed chemical analysis of organic aerosols is necessary to better understand their effects on climate and health. Aerosol samples are often stored for days to months before analysis. We examined the effects of storage conditions (i.e., time, temperature, and aerosol storage on filters or as solvent extracts) on composition and found significant changes in the concentration of individual compounds, indicating that sample storage can strongly affect the detailed chemical particle composition.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 8921–8937, https://doi.org/10.5194/acp-23-8921-2023, https://doi.org/10.5194/acp-23-8921-2023, 2023
Short summary
Short summary
Open burning of household and municipal solid waste is a common practice in developing countries and is a significant source of air pollution. However, few studies have measured emissions from open burning of waste. This study determined gas and particulate emissions from open burning of 10 types of household solid-waste materials. These results can improve emission inventories, air quality management, and assessment of the health and climate effects of open burning of household waste.
Anita M. Avery, Mariam Fawaz, Leah R. Williams, Tami Bond, and Timothy B. Onasch
Atmos. Chem. Phys., 23, 8837–8854, https://doi.org/10.5194/acp-23-8837-2023, https://doi.org/10.5194/acp-23-8837-2023, 2023
Short summary
Short summary
Pyrolysis is the thermal decomposition of fuels like wood which occurs during combustion or as an isolated process. During combustion, some pyrolysis products are emitted directly, while others are oxidized in the combustion process. This work describes the chemical composition of particle-phase pyrolysis products in order to investigate both the uncombusted emissions from wildfires and the fuel that participates in combustion.
Lan Ma, Reed Worland, Wenqing Jiang, Christopher Niedek, Chrystal Guzman, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 23, 8805–8821, https://doi.org/10.5194/acp-23-8805-2023, https://doi.org/10.5194/acp-23-8805-2023, 2023
Short summary
Short summary
Although photooxidants are important in airborne particles, little is known of their concentrations. By measuring oxidants in a series of particle dilutions, we predict their concentrations in aerosol liquid water (ALW). We find •OH concentrations in ALW are on the order of 10−15 M, similar to their cloud/fog values, while oxidizing triplet excited states and singlet molecular oxygen have ALW values of ca. 10−13 M and 10−12 M, respectively, roughly 10–100 times higher than in cloud/fog drops.
Daniel A. Knopf, Peiwen Wang, Benny Wong, Jay M. Tomlin, Daniel P. Veghte, Nurun N. Lata, Swarup China, Alexander Laskin, Ryan C. Moffet, Josephine Y. Aller, Matthew A. Marcus, and Jian Wang
Atmos. Chem. Phys., 23, 8659–8681, https://doi.org/10.5194/acp-23-8659-2023, https://doi.org/10.5194/acp-23-8659-2023, 2023
Short summary
Short summary
Ambient particle populations and associated ice-nucleating particles (INPs)
were examined from particle samples collected on board aircraft in the marine
boundary layer and free troposphere in the eastern North Atlantic during
summer and winter. Chemical imaging shows distinct differences in the
particle populations seasonally and with sampling altitudes, which are
reflected in the INP types. Freezing parameterizations are derived for
implementation in cloud-resolving and climate models.
Dandan Liu, Yun Zhang, Shujun Zhong, Shuang Chen, Qiaorong Xie, Donghuan Zhang, Qiang Zhang, Wei Hu, Junjun Deng, Libin Wu, Chao Ma, Haijie Tong, and Pingqing Fu
Atmos. Chem. Phys., 23, 8383–8402, https://doi.org/10.5194/acp-23-8383-2023, https://doi.org/10.5194/acp-23-8383-2023, 2023
Short summary
Short summary
Based on ultra-high-resolution mass spectrometry analysis, we found that β-pinene oxidation-derived highly oxygenated organic molecules (HOMs) exhibit higher yield at high ozone concentration, while limonene oxidation-derived HOMs exhibit higher yield at moderate ozone concentration. The distinct molecular response of HOMs and low-volatile species in different biogenic secondary organic aerosols to ozone concentrations provides a new clue for more accurate air quality prediction and management.
Mengying Bao, Yan-Lin Zhang, Fang Cao, Yihang Hong, Yu-Chi Lin, Mingyuan Yu, Hongxing Jiang, Zhineng Cheng, Rongshuang Xu, and Xiaoying Yang
Atmos. Chem. Phys., 23, 8305–8324, https://doi.org/10.5194/acp-23-8305-2023, https://doi.org/10.5194/acp-23-8305-2023, 2023
Short summary
Short summary
The interaction between the sources and molecular compositions of humic-like substances (HULIS) at Nanjing, China, was explored. Significant fossil fuel source contributions to HULIS were found in the 14C results from biomass burnng and traffic emissions. Increasing biogenic secondary organic aerosol (SOA) products and anthropogenic aromatic compounds were detected in summer and winter, respectively.
Molly Frauenheim, Jason D. Surratt, Zhenfa Zhang, and Avram Gold
Atmos. Chem. Phys., 23, 7859–7866, https://doi.org/10.5194/acp-23-7859-2023, https://doi.org/10.5194/acp-23-7859-2023, 2023
Short summary
Short summary
We report synthesis of the isoprene-derived photochemical oxidation products trans- and cis-β-epoxydiols in high overall yields from inexpensive, readily available starting compounds. Protection/deprotection steps or time-consuming purification is not required, and the reactions can be scaled up to gram quantities. The procedures provide accessibility of these important compounds to atmospheric chemistry laboratories with only basic capabilities in organic synthesis.
Xiangyun Zhang, Jun Li, Sanyuan Zhu, Junwen Liu, Ping Ding, Shutao Gao, Chongguo Tian, Yingjun Chen, Ping'an Peng, and Gan Zhang
Atmos. Chem. Phys., 23, 7495–7502, https://doi.org/10.5194/acp-23-7495-2023, https://doi.org/10.5194/acp-23-7495-2023, 2023
Short summary
Short summary
The results show that 14C elemental carbon (EC) was not only related to the isolation method but also to the types and proportions of the biomass sources in the sample. The hydropyrolysis (Hypy) method, which can be used to isolate a highly stable portion of ECHypy and avoid charring, is a more effective and stable approach for the matrix-independent 14C quantification of EC in aerosols, and the 13C–ECHypy and non-fossil ECHypy values of SRM1649b were –24.9 ‰ and 11 %, respectively.
Amir Yazdani, Satoshi Takahama, John K. Kodros, Marco Paglione, Mauro Masiol, Stefania Squizzato, Kalliopi Florou, Christos Kaltsonoudis, Spiro D. Jorga, Spyros N. Pandis, and Athanasios Nenes
Atmos. Chem. Phys., 23, 7461–7477, https://doi.org/10.5194/acp-23-7461-2023, https://doi.org/10.5194/acp-23-7461-2023, 2023
Short summary
Short summary
Organic aerosols directly emitted from wood and pellet stove combustion are found to chemically transform (approximately 15 %–35 % by mass) under daytime aging conditions simulated in an environmental chamber. A new marker for lignin-like compounds is found to degrade at a different rate than previously identified biomass burning markers and can potentially provide indication of aging time in ambient samples.
Hao Luo, Luc Vereecken, Hongru Shen, Sungah Kang, Iida Pullinen, Mattias Hallquist, Hendrik Fuchs, Andreas Wahner, Astrid Kiendler-Scharr, Thomas F. Mentel, and Defeng Zhao
Atmos. Chem. Phys., 23, 7297–7319, https://doi.org/10.5194/acp-23-7297-2023, https://doi.org/10.5194/acp-23-7297-2023, 2023
Short summary
Short summary
Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime oxidant, forms many highly oxygenated organic molecules (HOMs), including C10-20 compounds. HOMs play an important role in new particle formation and growth. HOM formation can be explained by the chemistry of peroxy radicals. We found that a minor branching ratio initial pathway plays an unexpected, significant role. Considering this pathway enables accurate simulations of HOMs and other concentrations.
Heather L. Runberg and Brian J. Majestic
Atmos. Chem. Phys., 23, 7213–7223, https://doi.org/10.5194/acp-23-7213-2023, https://doi.org/10.5194/acp-23-7213-2023, 2023
Short summary
Short summary
Environmentally persistent free radicals (EPFRs) are an emerging pollutant found in soot particles. Understanding how these change as they move through the atmosphere is important to human health. Here, soot was generated in the laboratory and exposed to simulated sunlight. The concentrations and characteristics of EPFRs in the soot were measured and found to be unchanged. However, it was also found that the ability of soot to form hydroxyl radicals was stronger for fresh soot.
Wenqing Jiang, Christopher Niedek, Cort Anastasio, and Qi Zhang
Atmos. Chem. Phys., 23, 7103–7120, https://doi.org/10.5194/acp-23-7103-2023, https://doi.org/10.5194/acp-23-7103-2023, 2023
Short summary
Short summary
We studied how aqueous-phase secondary organic aerosol (aqSOA) form and evolve from a phenolic carbonyl commonly present in biomass burning smoke. The composition and optical properties of the aqSOA are significantly affected by photochemical reactions and are dependent on the oxidants' concentration and identity in water. During photoaging, the aqSOA initially becomes darker, but prolonged aging leads to the formation of volatile products, resulting in significant mass loss and photobleaching.
Lucía Caudillo, Mihnea Surdu, Brandon Lopez, Mingyi Wang, Markus Thoma, Steffen Bräkling, Angela Buchholz, Mario Simon, Andrea C. Wagner, Tatjana Müller, Manuel Granzin, Martin Heinritzi, Antonio Amorim, David M. Bell, Zoé Brasseur, Lubna Dada, Jonathan Duplissy, Henning Finkenzeller, Xu-Cheng He, Houssni Lamkaddam, Naser G. A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Roy L. Mauldin, Bernhard Mentler, Antti Onnela, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Ana A. Piedehierro, Birte Rörup, Wiebke Scholz, Jiali Shen, Dominik Stolzenburg, Christian Tauber, Ping Tian, António Tomé, Nsikanabasi Silas Umo, Dongyu S. Wang, Yonghong Wang, Stefan K. Weber, André Welti, Marcel Zauner-Wieczorek, Urs Baltensperger, Richard C. Flagan, Armin Hansel, Jasper Kirkby, Markku Kulmala, Katrianne Lehtipalo, Douglas R. Worsnop, Imad El Haddad, Neil M. Donahue, Alexander L. Vogel, Andreas Kürten, and Joachim Curtius
Atmos. Chem. Phys., 23, 6613–6631, https://doi.org/10.5194/acp-23-6613-2023, https://doi.org/10.5194/acp-23-6613-2023, 2023
Short summary
Short summary
In this study, we present an intercomparison of four different techniques for measuring the chemical composition of nanoparticles. The intercomparison was performed based on the observed chemical composition, calculated volatility, and analysis of the thermograms. We found that the methods generally agree on the most important compounds that are found in the nanoparticles. However, they do see different parts of the organic spectrum. We suggest potential explanations for these differences.
Ruifeng Zhang and Chak Keung Chan
Atmos. Chem. Phys., 23, 6113–6126, https://doi.org/10.5194/acp-23-6113-2023, https://doi.org/10.5194/acp-23-6113-2023, 2023
Short summary
Short summary
Research into sulfate and nitrate formation from co-uptake of NO2 and SO2, especially under irradiation, is rare. We studied the co-uptake of NO2 and SO2 by NaCl droplets under various conditions, including irradiation and dark, and RHs, using Raman spectroscopy flow cell and kinetic model simulation. Significant nitrate formation from NO2 hydrolysis can be photolyzed to generate OH radicals that can further react with chloride to produce reactive chlorine species and promote sulfate formation.
Shinnosuke Ishizuka, Oliver Reich, Grégory David, and Ruth Signorell
Atmos. Chem. Phys., 23, 5393–5402, https://doi.org/10.5194/acp-23-5393-2023, https://doi.org/10.5194/acp-23-5393-2023, 2023
Short summary
Short summary
Photosensitizers play an important role in the photochemistry of atmospheric aerosols. Our study provides evidence that mesoscopic glycine clusters forming in aqueous droplets act as unconventional photosensitizers in the visible light spectrum. We observed the influence of these photoactive molecular aggregates in single optically trapped aqueous droplets. Such mesoscopic photosensitizers might be more important for aerosol photochemistry than previously anticipated.
Liyuan Zhou, Zhancong Liang, Beatrix Rosette Go Mabato, Rosemarie Ann Infante Cuevas, Rongzhi Tang, Mei Li, Chunlei Cheng, and Chak K. Chan
Atmos. Chem. Phys., 23, 5251–5261, https://doi.org/10.5194/acp-23-5251-2023, https://doi.org/10.5194/acp-23-5251-2023, 2023
Short summary
Short summary
This study reveals the sulfate formation in photosensitized particles from biomass burning under UV and SO2, of which the relative atmospheric importance in sulfate production was qualitatively compared to nitrate photolysis. On the basis of single-particle aerosol mass spectrometry measurements, the number percentage of sulfate-containing particles and relative peak area of sulfate in single-particle spectra exhibited a descending order of 3,4-dimethoxybenzaldehyde > vanillin > syringaldehyde.
Mohammed Jaoui, Kenneth S. Docherty, Michael Lewandowski, and Tadeusz E. Kleindienst
Atmos. Chem. Phys., 23, 4637–4661, https://doi.org/10.5194/acp-23-4637-2023, https://doi.org/10.5194/acp-23-4637-2023, 2023
Short summary
Short summary
VCPs are a class of chemicals widely used in industrial and consumer products (e.g., coatings, adhesives, inks, personal care products) and are an important component of total VOCs in urban atmospheres. This study provides SOA yields and detailed chemical analysis of the gas- and aerosol-phase products of the photooxidation of one of these VCPs, benzyl alcohol. These results will allow better links between characterized sources and their resulting criteria for pollutant formation.
Cited articles
Adams, K. D. and Sada, D. W.: Black Rock Playa, Northwestern Nevada: Physical Processes and Aquatic Life, Desert Research Institute, Reno, Nevada, 1–20, 2010.
Alastuey, A., Querol, X., Castillo, S., Escudero, M., Avila, A., Cuevas, E., Torres, C., Romero, P., Exposito, F., and Garcia, O.: Characterisation of TSP and PM2.5 at Izaña and Sta. Cruz de Tenerife (Canary Islands, Spain) during a Saharan Dust Episode (July 2002), Atmos. Environ., 39, 4715–4728, 2005.
Al-Awadhi, J. M.: Dust fallout characteristics in Kuwait: a case study, Kuwait J. Sci. Eng., 32, 135–151, 2005.
Al-Dousari, A. and Al-Awadhi, J.: Dust fallout in northern Kuwait, major sources and characteristics, Kuwait J. Sci. Eng., 39, 171–187, 2012.
Alexander, J. M., Meland, B., Laskina, O., Young, M. A., Grassian, V. H., and Kleiber, P. D.: Light scattering from diatomaceous earth aerosol, J. Quant. Spectrosc. Ra., 125, 33–37, https://doi.org/10.1016/j.jqsrt.2013.04.013, 2013.
Arnott, W. P., Moosmüller, H., Rogers, C. F., Jin, T., and Bruch, R.: Photoacoustic spectrometer for measuring light absorption by aerosol: Instrument Description, Atmos. Environ., 33, 2845–2852, 1999.
Arnott, W. P., Moosmüller, H., and Walker, J. W.: Nitrogen Dioxide and Kerosene-Flame Soot Calibration of Photoacoustic Instruments for Measurement of Light Absorption by Aerosols, Rev. Sci. Instrum., 71, 4545–4552, 2000.
Avila, A., Queralt-Mitjans, I., and Alarçon, M.: Mineralogical composition of African dust delivered by red rains over northeastern Spain, J. Geophys. Res., 102, 21977–21996, 1997.
Ben-Ami, Y., Koren, I., Rudich, Y., Artaxo, P., Martin, S. T., and Andreae, M. O.: Transport of North African dust from the Bodélé depression to the Amazon Basin: a case study, Atmos. Chem. Phys., 10, 7533–7544, https://doi.org/10.5194/acp-10-7533-2010, 2010.
Bergametti, G., Gomes, L., Coudé-Gaussen, G., Rognon, P., and Le Coustumer, M. N.: African dust observed over Canary Islands: source-regions identification and transport pattern for some summer situations, J. Geophys. Res., 94, 14855–14864, 1989.
Bergstrom, R. W., Pilewskie, P., Russell, P. B., Redemann, J., Bond, T. C., Quinn, P. K., and Sierau, B.: Spectral absorption properties of atmospheric aerosols, Atmos. Chem. Phys., 7, 5937–5943, https://doi.org/10.5194/acp-7-5937-2007, 2007.
Betzer, P., Carder, K., Duce, R., and Merrill, J.: Long range transport of giant mineral aerosol particles, Nature, 336, 568–571, 1988.
Birkeland, P. W.: Soils and Geomorphology, Third Edition, Oxford University Press, Inc., New York, 430 pp., 1999.
Blanco, A., Dee Tomasi, F., Filippo, E., Manno, D., Perrone, M. R., Serra, A., Tafuro, A. M., and Tepore, A.: Characterization of African dust over southern Italy, Atmos. Chem. Phys., 3, 2147–2159, https://doi.org/10.5194/acp-3-2147-2003, 2003.
Borchard, G. A., Harward, M. E., and Knox, E. G.: Trace element concentration in amorphous clays of volcanic ash soils in Oregon, Clay. Clay. Miner., 19, 375–382, 1971.
Bristow, C. S., Hudson-Edwards, K. A., and Chappell, A.: Fertilizing the Amazon and equatorial Atlantic with West African dust, Geophys. Res. Lett., 37, L14807, https://doi.org/10.1029/2010GL043486, 2010.
Buch, M. W. and Rose, D.: Mineralogy and geochemistry of the sediments of the Etosha Pan Region in northern Namibia: a reconstruction of the depositional environment, J. Afr. Earth Sci., 22, 355–378, 1996.
Burbank, D. W. and Jijun, L.: Age and palaeoclimatic significance of the loess of Lanzhou, north China, Nature, 316, 429–431, 1985.
Buringh, P.: Soils and Soil Conditions in Iraq, Directorate General of Agricultural Research and Projects, Ministry of Agriculture, Baghdad, Republic of Iraq, 1–322, 1960.
Caquineau, S., Magonthier, M.-C., Gaudichet, A., and Gomes, L.: An improved procedure for the X-ray diffraction analysis of low-mass atmospheric dust samples, Eur. J. Mineral., 9, 157–166, 1997.
Chadwick, O. A., Derry, L. A., Vitousek, P. M., Huebert, B. J., and Hedin, L. O.: Changing sources of nutrients during four million years of ecosystem development, Nature, 397, 491–497, 1999.
Chappell, A., Warren, A., O'Donoghue, A., Robinson, A., Thomas, A., and Bristow, C. S.: The implications for dust emission modeling of spatial and vertical variations in horizontal dust flux and particle size in the Bodélé Depression, Northern Chad, J. Geophys. Res., 113, D04214, https://doi.org/10.1029/2007JD009032, 2008.
Choate, L. M., Ranville, J. F., Bunge, A. L., and Macalady, D. L.: Dermally Adhered Soil: 2. Reconstruction of Dry-Sieve Particle-Size Distributions from Wet-Sieve Data, Integrated Environmental Assessment and Management, 2, 385–390, 2006.
Chow, J. C. and Watson, J. G.: Ion Chromatography in elemental analysis of airborne particles, Elemental Analysis of Airborne Particles, edited by: Landsberger, S., a. M. C., Gordon and Breach Science, Amsterdam, 97–137, 1999.
Chung, F. H.: Quantitative interpretation of X-ray diffraction patterns of mixtures. I. Matrix-flushing method for quantitative multicomponent analysis, J. Appl. Crystallogr., 7, 519–525, https://doi.org/10.1107/S0021889874010375, 1974.
Chýlek, P. and Wong, J.: Effect of Absorbing Aerosol on Global Radiation Budget, Geophys. Res. Lett., 22, 929–931, 1995.
Coudé-Gaussen, G., Rognon, P., Bergametti, G., Gomes, L., Strauss, B., Gros, J. M., and le Coustumer, M.-N.: Saharan dust on Fuerteventura Island (Canaries): chemical and mineralogical characteristics, air mass trajectories and probable sources, J. Geophys. Res., 92, 9753–9771, 1987.
Criado, C. and Dorta, P.: An unusual “blood rain” over the Canary Islands (Spain). The storm of January 1999, J. Arid Environ., 55, 765–783, https://doi.org/10.1016/S0140-1963(02)00320-8, 2003.
Cuadros, J., Diaz-Hernandez, J. L., Sanchez-Navas, A., and Garcia-Casco, A.: Role of clay minerals in the formation of atmospheric aggregates of Saharan dust, Atmos. Environ., 120, 160–172, 2015.
Deer, W. A., Howie, R. A., and Zussman, J.: Rock-Forming Minerals, Vol. 3, Sheet Silicates, Longman, Green and Co. Ltd, London, 1962.
Derbyshire, E., Meng, X., and Kemp, R. A.: Provenance, transport and characteristics of modern aeolian dust in western Gansu Province, China, and interpretation of the Quaternary loess record, J. Arid Environ., 39, 497–516, 1998.
Díaz-Hernández, J. L. and Párraga, J.: The nature and tropospheric formation of iberulites: Pinkish mineral microspherulites, Geochim. Cosmochim. Ac., 72, 3883–3906, 2008.
Draxler, R. R., Gillette, D. A., Kirkpatrick, J. S., and Heller, J.: Estimating PM10 air concentrations from dust storms in Iraq, Kuwait and Saudi Arabia, Atmos. Environ., 35, 4315–4330, 2001.
Engelbrecht, J. P., McDonald, E. V., Gillies, J. A., and Gertler, A. W.: Department of Defense Enhanced Particulate Matter Surveillance Program (EPMSP), Desert Research InstituteContract Number: W9124R-05-C-0135/SUBCLIN 000101-ACRN-AB, 57, 2008.
Engelbrecht, J. P., McDonald, E. V., Gillies, J. A., Jayanty, R. K. M., Casuccio, G., and Gertler, A. W.: Characterizing mineral dusts and other aerosols from the Middle East – Part 1: Ambient sampling, Inhal. Toxicol., 21, 297–326, 2009a.
Engelbrecht, J. P., McDonald, E. V., Gillies, J. A., Jayanty, R. K. M., Casuccio, G., and Gertler, A. W.: Characterizing mineral dusts and other aerosols from the Middle East – Part 2: Grab samples and re-suspensions, Inhal. Toxicol., 21, 327–336, 2009b.
Engelbrecht, J. P., Gillies, J. A., Etyemezian, V., Kuhns, H., Baker, S. E., Zhu, D., Nikolich, G., and Kohl, S. D.: Controls on mineral dust emissions at four arid locations in the western USA, Aeolian Res., 6, 41–54, 2012.
Engelbrecht, J. P., Menéndez, I., and Derbyshire, E.: Sources of PM2.5 impacting on Gran Canaria, Spain, Catena, 117, 119–132, 2014.
Engelstaedter, S., Tegen, I., and Washington, R.: North African Dust Emissions and Transport, Earth-Sci. Rev., 79, 73–100, 2006.
Esteve, V., Rius, J., Ochando, L. E., and Amigó, J. M.: Quantitative x-ray diffraction phase analysis of coarse airborne particulate collected by cascade impactor sampling, Atmos. Environ., 31, 3963–3967, https://doi.org/10.1016/S1352-2310(97)00257-4, 1997.
Field, J. P., Belnap, J., Breshears, D. D., Neff, J. C., Okin, G. S., Whicker, J. J., Painter, T. H., Ravi, S., Reheis, M. C., and Reynolds, R. L.: The ecology of dust, Front. Ecol. Environ., 8, 423–430, https://doi.org/10.1890/090050, 2010.
Fordham, A. W.: Weathering of biotite into dioctahedral clay minerals, Clay Minerals, 25, 51–63, 1990.
Formenti, P., Andrea, M. O., Lange, L., Roberts, G., Cafmeyer, J., Rajta, I., Maenhaut, W., Holben, B. N., Artaxo, P., and Lelieveld, J.: Saharan dust in Brazil and Surinam during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia (LBA) – Cooperative LBA Regional Experiment (CLAIRE) in March 1998, J. Geophys. Res., 106, 14919–14934, 2001.
Fubini, B. and Fenoglio, I.: Toxic potential of mineral dusts, Elements, 3, 407–414, 2007.
Gee, G. W. and Or, D.: Particle-size analysis, in: Methods of Soil Analysis: Part 4 – Physical Methods, No. 5, edited by: Dane, J. H. and Topp, G. C., Soil Science Society of America, Madison, WI, 255–293, 2002.
Gelado-Caballero, M. D., Rodríguez, M. J., Hernández, J. J., Brito De Acevedo, E. M., Llinás, O., Collado, C., Cardona, P., and López, P.: Dust deposition fluxes to north-eastern subtropical Atlantic (Canary Islands),Geophys. Res. Abstr., EGU2005-08399, EGU General Assembly 2005, Vienna, Austria, 2005.
Ghio, A. J., Kummarapurupu, S. T., Tong, H., Soukup, J. M., Dailey, L. A., Boykin, E., Gilmour, M. I., Ingram, P., Roggli, V. L., Goldstein, H. L., and Reynolds, R. L.: Biologic effects of desert dust in respiratory epithelial cells and a murine model, Inhal. Toxicol., 26, 299–309, https://doi.org/10.3109/08958378.2014.888109, 2014.
Gillies, J. A., Kuhns, H., Engelbrecht, J. P., Uppapalli, S., Etyemezian, V., and Nikolich, G.: Particulate emissions from U.S. Departement of Defense artillery backblast testing, J. Air Waste Manage., 57, 551–560, 2007.
Gillies, J. A., Etyemezian, V., Kuhns, H., McAlpine, J. D., King, J., Uppapalli, S., Nikolich, G., and Engelbrecht, J. P.: Dust emissions created by low-level rotary-winged aircraft flight over desert surfaces, Atmos. Environ., 44, 1043–1053, 2010.
Ginoux, P., Prospero, J. M., Gill, T. E., Hsu, N. C., and Zhao, M.: Global-scale attribution of anthropogenic and natural dust sources and their emission rates based on Modis Deep Blue aerosol products, Rev. Geophys., 50, RG3005, https://doi.org/10.1029/2012rg000388, 2012.
Goudie, A. S. and Middleton, N. J.: Saharan dust storms: nature and consequences, Earth-Sci. Rev., 56, 179–204, https://doi.org/10.1016/S0012-8252(01)00067-8, 2001.
Hassan, T., Moosmüller, H., and Chung, C. E.: Coefficients of an Analytical Aerosol Forcing Equation Determined with a Monte-Carlo Radiation Model, J. Quant. Spectrosc. Ra., 164, 129–136, 2015.
Heintzenberg, J.: Experiment over Southern Morocco: Overview and introduction, Tellus B, 61, 2–11, 2009.
Jaafar, M., Baalbaki, R., Mrad, R., Daher, N., Shihadeh, A., Sioutas, C., and Saliba, N. A.: Dust episodes in Beirut and their effect on the chemical composition of coarse and fine particulate matter, Sci. Total Environ., 496, 75–83, 2014.
Jahn, R. and Stahr, K.: Development of soils and site qualities on basic volcanoclastics with special reference to the semiarid environment of Lanzarote, Canary Islands, Spain, Rev. Mex. Cienc. Geol., 13, 104–112, 1996.
Jeong, G. Y. and Nousiainen, T.: TEM analysis of the internal structures and mineralogy of Asian dust particles and the implications for optical modeling, Atmos. Chem. Phys., 14, 7233–7254, https://doi.org/10.5194/acp-14-7233-2014, 2014.
Jeong, G. Y., Kim, J. Y., Seo, J., Kim, G. M., Jin, H. C., and Chun, Y.: Long-range transport of giant particles in Asian dust identified by physical, mineralogical, and meteorological analysis, Atmos. Chem. Phys., 14, 505–521, https://doi.org/10.5194/acp-14-505-2014, 2014.
Kahlaf, F. I., Al-Kadi, A., and Al-Saleh, S.: Mineralogical composition and potential sources of dust fallout deposits in Kuwait, Sediment. Geol., 42, 225–278, 1985.
Kandler, K., Benker, N., Bundke, U., Cuevas, E., Ebert, M., Knippertz, P., Rodríguez, S., Schütz, L., and Weinbruch, S.: Chemical composition and complex refractive index of Saharan mineral dust at Izaña, Tenerife (Spain) derived by electron microscopy, Atmos. Environ., 41, 8058–8074, 2007.
Kandler, K., Schütz, L., Deutscher, C., Ebert, M., Hofmann, H., Jäckel, S., Jaenicke, R., Knippertz, P., Lieke, K., Massling, A., Petzold, A., Schladitz, A., Weinzierl, B., Wiedensohler, A., Zorn, S., and Weinbruch, S.: Size distribution, mass concentration, chemical and mineralogical composition and derived optical parameters of the boundary layer aerosol at Tinfou, Morocco, during SAMUM 2006, Tellus B, 61, 32–50, 2009.
Kars, M., Lerouge, C., Grangeon, S., Aubourg, C., Tournassat, C., Madé, B., and Claret, F.: Identification of nanocrystalline goethite in reduced clay formations: Application to the Callovian-Oxfordian formation of Bure (France), Am. Mineral., 100, 1544–1553, 2015.
Kohfeld, K. E. and Harrison, S. P.: Glacial-interglacial changes in dust deposition on the Chinese Loess Plateau, Quaternary Sci. Rev., 22, 1859–1878, 2003.
Kok, J. F.: A scaling theory for the size distribution of emitted dust aerosols suggests climate models underestimate the size of the global dust cycle, P. Natl. Acad. Sci. USA, 108, 1016–1021, https://doi.org/10.1073/pnas.1014798108, 2011.
Koren, I., Kaufman, Y. J., Washington, R., Todd, M. C., Rudich, Y., Martins, J. V., and Rosenfeld, D.: The Bodélé Depression: a single spot in the Sahara that provides most of the mineral dust to the Amazon forest, Environ. Res. Lett., 1, 014005, https://doi.org/10.1088/1748-9326/1/1/014005, 2006.
Lafon, S., Sokolik, I. N., Rajot, J. L., Caquineau, S., and Gaudichet, A.: Characterization of iron oxides in mineral dust aerosols: Implications for light absorption, J. Geophys. Res., 111, D21207, https://doi.org/10.1029/2005JD007016, 2006.
Lawrence, C. R. and Neff, J. C.: The contemporary physical and chemical flux of aeolian dust: A synthesis of direct measurements of dust deposition, Chem. Geol., 267, 46–63, https://doi.org/10.1016/j.chemgeo.2009.02.005, 2009.
Lewis, G. C., Fosberg, M. A., Falen, A. L., and Miller, B. J.: Identification of loess by particle size distribution using the Coulter Counter TA II1, Soil Sci., 137, 172–176, 1984.
Lewis, K., Arnott, W. P., Moosmüller, H., and Wold, C. E.: Strong spectral variation of biomass smoke light absorption and single scattering albedo observed with a novel dual-wavelength photoacoustic instruments, J. Geophys. Res., 113, D16203, https://doi.org/10.1029/2007JD009699, 2008.
Maring, H., Savoie, D. L., Izaguirre, M. A., McCormick, C., Arimoto, R., Prospero, J. M., and Pilinis, C.: Aerosol physical and optical properties and their relationship to aerosol composition in the free troposphere at Izaña, Tenerife, Canary Islands, during July 1995, J. Geophys. Res., 105, 14677–14700, 2000.
Maring, H., Savoie, D. L., Izaguirre, M. A., Custals, L., and Reid, J. S.: Mineral dust aerosol size distribution change during atmospheric transport, J. Geophys. Res., 108, 8592, https://doi.org/10.1029/2002JD002536, 2003.
Marković, S. B., Hambach, U., Catto, N., Jovanović, M., Buggle, B., Machalett, B., Zöller, L., Glaser, B., and Frechen, M.: Middle and Late Pleistocene loess sequences at Batajnica, Vojvodina, Serbia, Quaternary Int., 198, 255–266, 2009.
Marković, S. B., Hambach, U., Stevens, T., Kukla, G. J., Heller, F., McCoy, W. D., Oches, E. A., Buggle, B., and Zöller, L.: The last million years recorded at the Stari Slankamen (Northern Serbia) loess-palaeosol sequence: revised chronostratigraphy and long-term environmental trends, Quaternary Sci. Rev., 30, 1142–1154, 2011.
Marx, S. K., McGowan, H. A., and Kamber, B. S.: Long-range dust transport from eastern Australia: a proxy for Holocene aridity and ENSO induced climate variability, Earth Planet. Sc. Lett., 282, 167–177, 2009.
McGowan, H. A. and Clark, A.: A vertical profile of PM10 dust concentrations measured during a regional dust event identified by MODIS Terra, western Queensland, Australia, J. Geophys. Res., 113, F02S03, https://doi.org/10.1029/2007JF000765, 2008.
McGowan, H. A., Kamber, B. S., McTainsh, G. H., and Marx, S. K.: High resolution provenancing of long travelled dust deposition in the Southern Alps, New Zealand, Geomorphology, 69, 208–221, 2005.
McKay, C. P., Friedmann, E. I., Gomez-Silva, B., Caceres, L., Andersen, D. T., and Landheim, R.: Temperature and moisture conditions for life in the extreme arid region of the Atacama Desert: four years of observations including the El Nino of 1997–1998, Astrobiology, 3, 393–406, 2003.
McTainsh, G. H., Nickling, W. G., and Lynch, A. W.: Dust deposition and particle size in Mali, West Africa, CATENA, 29, 307–322, https://doi.org/10.1016/S0341-8162(96)00075-6, 1997.
Menéndez, I., Díaz-Hernandez, J. L., Mangas, J., Alonso, I., and Sánchez-Soto, P. J.: Airborne dust accumulation and soil development in the North-East sector of Gran Canaria (Canary Island, Spain), J. Arid Environ., 71, 57–81, 2007.
Menéndez, I., Derbyshire, E., Engelbrecht, J. P., Suchodoletz, H., von Zöller, L., Dorta, P., Carrillo, T., and Rodríguez de Castro, F.: Saharan dust and the aerosols on the Canary Islands: Past and present, Chapter 2, in: Airborne Particulates, edited by: Cheng, M. and Liu, W., Nova Science Publishers, Inc., New York, 39–80, 2009.
Menéndez, I., Pérez-Chacón, E., Mangas, J., Tauler, E., Engelbrecht, J. P., Derbyshire, E., Cana, L., and Alonso, I.: Dust deposits on La Graciosa Island (Canary Islands, Spain): texture, mineralogy and a case study of recent dust plume transport, Catena, 117, 133–144, 2014.
Middleton, N., Yiallouros, P., Kleanthous, S., Kolokotroni, O., Schwartz, J., Dockery, D. W., Demokritou, P., and Koutrakis, P.: A 10-year time-series analysis of respiratory and cardiovascular morbidity in Nicosia, Cyprus: the effect of short-term changes in air pollution and dust storms, Environ. Health, 7, 39, https://doi.org/10.1186/1476-069X-7-39, 2008.
Middleton, N. J. and Goudie, A. S.: Saharan dust: Sources and trajectories, Transactions of the Institute of British Geographers, New Series, 26, 165–181, 2001.
Mizota, C. and Matsuhisa, Y.: Isotopic evidence for the eolian origin of quartz and mica in soils developed on volcanic materials in the Canary Archipelago, Geoderma, 66, 167–332, https://doi.org/10.1016/0016-7061(95)00004-8, 1995.
Molinaroli, E.: Mineralogical Characterization of Saharan Dust with a View to its Final Destination in Mediterranean Sediments, in: The Impact of Desert Dust Across the Mediterranean Environmental Science and Technology Library, edited by: Guerzoni Stefano, R. C., Kluwer Academic Publishers, 153–162, 1996.
Molinaroli, E., Guerzoni, S., and Rampazzo, G.: Contribution of Saharan dust to the Central Mediterranean Basin, Geol. Soc. Am. Special Paper, 284, 303–312, 1993.
Moosmüller, H. and Arnott, W. P.: Particle optics in the Rayleigh regime, J. Air Waste Manage., 59, 1028–1031, https://doi.org/10.3155/1047-3289.59.9.1028, 2009.
Moosmüller, H., Chakrabarty, R. K., and Arnott, W. P.: Aerosol light absorption and its measurement: a review, J. Quant. Spectrosc. Ra. 110, 844–878, 2009.
Moosmüller, H., Engelbrecht, J. P., Skiba, M., Frey, G., Chakrabarty, R. K., and Arnott, W. P.: Single scattering albedo of fine mineral dust aerosols controlled by iron concentration, J. Geophys. Res., 117, D11210, https://doi.org/10.1029/2011JD016909, 2012.
Moreno, A., Targarona, J., Henderiks, J., Canals, M., Freudenthal, T., and Meggers, H.: Orbital forcing of dust supply to the North Canary Basin over the last 250 kyr, Quaternary Sci. Rev., 20, 1275–1376, https://doi.org/10.1016/S0277-3791(00)00184-0, 2001.
Moreno, T., Amato, F., Querol, X., Alastuey, A., Elvira, J., and Gibbons, W.: Bedrock controls on the mineralogy and chemistry of PM10 extracted from Australian desert sediments, Environ. Geol., 57, 411–420, 2009.
Muhs, D. R., Budahn, J., Skipp, G., Prospero, J. M., Patterson, D., and Bettis III, E. A.: Geochemical and mineralogical evidence for Sahara and Sahel dust additions to Quaternary soils on Lanzarote, eastern Canary Islands, Spain, Terra Nova, 22, 399–410, 2010.
Müller, T., Schladitz, A., Massling, A., Kaaden, N., Kandler, K., and Wiedensohler, A.: Spectral absorption coefficients and imaginary parts of refractive indices of Saharan dust during SAMUM-1, Tellus B, 61, 79–95, 2009.
Najafi, M. S., Khoshakhllagh, F., Zamanzadeh, S. M., Shirazi, M. H., Samadi, M., and Hajikh, S.: Characteristics of TSP loads during the Middle East springtime dust storm (MESDS) in Western Iran, Arabian Journal of Geosciences, 7, 5367–5381, 2014.
Navarro-González, R., Rainey, F. A., Molina, P., Bagaley, D. R., Hollen, B. J., Rosa, J. d. l., Small, A. M., Quinn, R. C., Grunthaner, F. J., Cáceres, L., Gomez-Silva, B., and McKay, C. P.: Mars-like soils in the Atacama Desert, Chile, and the dry limit of microbial life, Science, 302, 1018–1021, 2003.
Neff, J. C., Reynolds, R. L., Munson, S., Fernandez, D., and Belnap, J.: The role of dust storms in atmospheric particle concentrations at two sites in the western U.S., J. Geophys. Res., 118, 11201–11212, https://doi.org/10.1002/jgrd.50855, 2013.
Norboo, T., Angchuk, P. T., Yahya, M., Karnak, S. R., Pooley, F. D., Corrin, B., Kerr, I. H., Bruce, N., and Ball, K. P.: Silicosis in a Himalayan village population: role of environmental dust, Thorax, 46, 341–343, 1991.
Oldfield, F., Chiverrell, R. C., Lyons, R., Williams, E., Shen, Z., Bristow, C., Bloemendal, J., Torrent, J., and Boyle, J. F.: Discriminating dusts and dusts sources using magnetic properties and hematite:goethite ratios of surface materials and dust from North Africa, the Atlantic and Barbados, Aeolian Res., 13, 91–104, 2014.
Pérez-Marrero, J., Llinás, O., Maroto, L., Rueda, M. J., and Cianca, A.: Saharan dust storms over the Canary Islands during winter 1998 as depicted from the advanced very high-resolution radiometer, Deep-Sea Res. Pt. II, 49, 3465–3479, 2002.
Petzold, A., Rasp, K., Weinzierl, B., Esselborn, M., Hamburger, T., Dörnbrack, A., Kandler, K., Schütz, L., Knippertz, P., Fiebig, M., and Virkkula, A.: Saharan dust absorption and refractive index from aircraft-based observations during SAMUM 2006, Tellus B, 61, 118–130, 2009.
Prospero, J. M., Olmez, I., and Ames, M.: Al and Fe in PM2.5 and PM10 suspended particles in South-Central Florida: The impact of the long range transport of African mineral dust, Water Air Soil Poll., 125, 291–317, 2001.
Prospero, J. M., Ginoux, P., Torres, O., Nicholson, S. E., and Gill, T. E.: Environmental characterization of global sources of atmospheric soil dust identified with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) absorbing aerosol product, Rev. Geophys., 40, 1002, https://doi.org/10.1029/2000RG000095, 2002.
Pye, K.: Aeolian dust and dust deposits, Academic Press, London, 1987.
Reheis, M. C.: Dust deposition downwind of Owens (dry) Lake, 1991–1994: preliminary findings, J. Geophys. Res., 102, 25999–26008, 1997.
Revel-Rolland, M., De Deckker, P., Delmonte, B., Hesse, P. P., Magee, J. W., Basile-Doelsch, I., Grousset, F., and Bosch, D.: Eastern Australia: A possible source of dust in East Antarctica interglacial ice, Earth Planet. Sc. Lett., 249, 1–13, https://doi.org/10.1016/j.epsl.2006.06.028, 2006.
Reynolds, R. L., Cattle, S. R., Moskowitz, B. M., Goldstein, H. L., Yauk, K., Flagg, C. B., Berquó, T. S., Kokaly, R. F., Morman, S., and Breit, G. N.: Iron oxide minerals in dust of the Red Dawn event in eastern Australia, September 2009, Aeolian Res., 15, 1–13, 2014a.
Reynolds, R. L., Goldstein, H. L., Moskowitz, B. M., Bryant, A. C., Skiles, S. M., Kokaly, R. F., Flagg, C. B., Yauk, K., Berquó, T., Breit, G., Ketterer, M., Fernandez, D., Miller, M. E., and Painter, T. H.: Composition of dust deposited to snow cover in the Wasatch Range (Utah, USA): Controls on radiative properties of snow cover and comparison to some dust-source sediments, Aeolian Res., 15, 73–90, 2014b.
Rietveld, H. M.: A profile refinement method for nuclear and magnetic structures, J. Appl. Crystallogr., 2, 65–71, https://doi.org/10.1107/S0021889869006558, 1969.
Roquin, C., Dandjinou, T., Freyssinet, P., and Pion, J. C.: The correlation between geochemical data and SPOT satellite imagery of lateritic terrain in southern Mali, J. Geochem. Explor., 32, 149–168, 1989.
Roquin, C., Freyssinet, P., Zeegers, H., and Tardy, Y.: Element distribution patterns in laterites of southern Mali: Consequence for geochemical prospecting and mineral exploration, Appl. Geochem., 5, 303–315, 1990.
Satheesh, S. K. and Moorthy, K. K.: Radiative effects of natural aerosols: A review, Atmos. Environ., 39, 2089–2110, 2005.
Sayyah, A., Horenstein, M. N., and Mazumder, M. K.: Energy yield loss caused by dust deposition on photovoltaic panels, Sol. Energy, 107, 576–604, https://doi.org/10.1016/J.Solener.2014.05.030, 2014.
Scheuvens, D., Schütz, L., Kandler, K., Ebert, M., and Weinbruch, S.: Bulk composition of northern African dust and its source sediments – A compilation, Earth-Sci. Rev., 116, 170–194, 2013.
Schladitz, A., Müller, T., Kaaden, N., Massling, A., Kandler, K., Ebert, M., Weinbruch, S., Deutscher, C., and Wiedensohler, A.: In situ measurements of optical properties at Tinfou (Morocco) during the Saharan mineral dust experiment SAMUM 2006, Tellus B, 61, 64–78, 2009.
Shao, Y.: A model for mineral dust emission, J. Geophys. Res., 106, 20239–20254, https://doi.org/10.1029/2001JD900171, 2001.
Smedman, G.: An investigation of the diatoms from four Tertiary lake beds in western Nevada, Paleobios no. 9, University of California, Museum of Paleontology in Berkeley, 16 pp., 1969.
Smuts, J. C.: Holism and Evolution, The Gestalt Journal Press, Inc., Gouldsboro ME, USA, 361 pp., 1986.
Sokolik, I. N., Winker, D. M., Bergametti, G., Gillette, D. A., Carmichael, G., Kaufman, Y. J., Gomes, L., Schuetz, L., and Penner, J. E.: Introduction to special section: outstanding problems in quantifying the radiative impacts of mineral dust, J. Geophys. Res., 106, 18015–18027, 2001.
Sturges, W. T., Harrison, R. M., and Barrie, L. A.: Semi-quantitative X-ray diffraction analysis of size fractionated atmospheric particles, Atmos. Environ., 23, 1083–1098, 1989.
Stuut, J.-B., Zabel, M., Ratmeyer, V., Helmke, P., Schefuß, E., Lavik, G., and Schneider, R.: Provenance of present-day eolian dust collected off NW Africa, J. Geophys. Res., 110 D04202, https://doi.org/10.1029/2004JD005161, 2005.
Sun, J., Kohfeld, K. E., and Harrison, S. P.: Records of aeolian dust deposition on the Chinese Loess Plateau during the Late Quaternary, Technical Report – Max Planck Institute for Biochemistry, Jena, Germany, 318 pp., 2000.
Tanaka, T. Y. and Chiba, M.: A Numerical Study of the Contributions of Dust Source Regions to the Global Dust Budget, Global Planet. Change, 52, 88–104, 2006.
Tegen, I., Heinold, B., Todd, M., Helmert, J., Washington, R., and Dubovik, O.: Modelling soil dust aerosol in the Bodélé depression during the BoDEx campaign, Atmos. Chem. Phys., 6, 4345–4359, https://doi.org/10.5194/acp-6-4345-2006, 2006.
Todd, M. C., Washington, R., Martins, V., Dubovik, O., Lizcano, G., M'Bainayel, S., and Engelstaedter, S.: Mineral dust emission from the Bodèlè Depression, Chad during BoDEx. 2005, J. Geophys. Res., 112, D06207, https://doi.org/10.1029/2006JD007170, 2007.
US EPA: Compendium of Methods for the Determination of Inorganic Compounds in Ambient Air, Compendium Method IO-3.3, Determination of metals in ambient particulate matter using X-ray fluorescence (XRF) spectroscopy, EPA/625/R-96/010, 3.3-1–3.3-32, 1999.
van Staveren, H. J., Moes, C. J. M., van Marie, J., Prahl, S. A., and van Gemert, M. J. C.: Light scattering in Intralipid-10 % in the wavelength range of 400–1100 nm, Appl. Optics, 30, 4507–4514, 1991.
Viana, M. M., Querol, X., Alastuey, A., Cuevas, E., and Rodríguez, S.: Influence of African dust on the levels of atmospheric particulates in the Canary Islands air quality network, Atmos. Environ., 36, 5861–5875, 2002.
Von Hoyningen-Huene, W., Dinter, T., Kokhanovsky, A. A., Burrows, J. P., Wendisch, M., Bierwirth, E., Müller, D., and Diouri, M.: Measurements of desert dust optical characteristics at Porte au Sahara during SAMUM, Tellus B, 61, 206–215, 2009.
von Suchodoletz, H., Kühn, P., Hambach, U., Dietze, M., Zöller, L., and Faust, D.: Loesslike and palaeosol sediments from Lanzarote (Canary Islands/Spain) – indicators of Palaeoenvironmental change during the Late Quaternary, Palaeogeogr. Palaeocl., 278, 71–87, 2009.
von Suchodoletz, H., Glaser, B., Thrippleton, T., Broder, T., Zang, U., Eigenmann, R., Kopp, B., Reichert, M., and Zöller, L.: The influence of Saharan dust deposits on La Palma soil properties (Canary Islands, Spain), Catena, 103, 44–52, 2013.
Washington, R. and Todd, M. C.: Atmospheric controls on mineral dust emission from the Bodélé Depression, Chad: the role of the low level jet, Geophys. Res. Lett., 32, L17701, https://doi.org/10.1029/2005GL023597, 2005.
Watson, J. G.: 2002 Critical Review – Visibility: Science and regulation, J. Air Waste Manage., 52, 626–713, 2002.
Watson, J. G., Chow, J. C., and Frazier, C. A.: X-ray fluorescence analysis of ambient air samples, in: Air Sampling Instruments for Evaluation of Atmospheric Contaminants, edited by: Cohen, B. S. and Herring, S. V., Cincinnati, OH, 51–57, 1999.
Weaver, C. E. and Pollard, L. D.: The chemistry of clay minerals, Developments in Sedimentology 15, Elsevier, Amsterdam, 1973.
White, B. R., Lacchia, B. M., Greeley, R., and Leach, R. N.: Aeolian behavior of dust in a simulated Martian environment, J. Geophys. Res., 102, 25629–25640, 1997.
Wiggs, G. F. S., O'Hara, S., Wegerdt, J., van der Meer, J., Small, I., and Hubbard, R.: The dynamics and characteristics of aeolian dust in the dryland Central Asia: possible impacts on human exposure and respiratory health in the Aral Sea basin, Geographical J., 169, 142–157, 2003.
Wilkerson, G., Milliken, M., Saint-Amand, P., and Saint-Amand, D.: Roadside Geology and Mining History, Owens Valley and Mono Basin, U.S. Bureau of Land Management Buena Vista Museum of Natural History, 134 pp., 2007.
Williamson, D., Jackson, M., Banerjee, S. K., and Petit-Maire, N.: The magnetism of a glacial aeolianite sequence from Lanzarote (Canary Islands): coupling between luvic calcisol formation and Saharan dust trapping processes during wet deposition events off northwestern Sahara, Geophys. J. Int., 157, 1090–1104, 2004.
Xuan, J.: Emission inventory of eight elements, Fe, Al, K, Mg, Mn, Na, Ca and Ti, in dust source region of East Asia, Atmos. Environ., 39, 813–821, https://doi.org/10.1016/j.atmosenv.2004.10.029, 2005.
Zarei, M.: Weathering and neoformation of minerals in soils formed from volcanites at Lanzarote (Canary Islands, Spain), PhD, Berlin, 1989.
Zender, C. S., Bian, H. S., and Newman, D.: Mineral dust entrainment and deposition (dead) model: Description and 1990s dust climatology, J. Geophys. Res., 108, 4416, https://doi.org/10.1029/2002JD002775, 2003.
Short summary
This laboratory study was performed on re-suspended dust samples collected from several known dust sources of the world. We measured dust by multiple analytical techniques to understand their physical and chemical characteristics. Studies of the properties of dust are necessary to assess the magnitude of the growing dust problem, identify sources of dust, and, where feasible, apply preventative measures and remediation practices. Results can be used in global climate and health studies.
This laboratory study was performed on re-suspended dust samples collected from several known...
Altmetrics
Final-revised paper
Preprint