Articles | Volume 23, issue 21
https://doi.org/10.5194/acp-23-13869-2023
https://doi.org/10.5194/acp-23-13869-2023
Technical note
 | 
07 Nov 2023
Technical note |  | 07 Nov 2023

Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures

Andrew T. Lambe, Bin Bai, Masayuki Takeuchi, Nicole Orwat, Paul M. Zimmerman, Mitchell W. Alton, Nga L. Ng, Andrew Freedman, Megan S. Claflin, Drew R. Gentner, Douglas R. Worsnop, and Pengfei Liu

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Cited articles

Alexander, A. J.: Reaction kinetics of nitrate radicals with terpenes in solution studied by cavity ring-down spectroscopy, Chem. Phys. Lett., 393, 138–142, https://doi.org/10.1016/j.cplett.2004.06.027, 2004. a, b
Atkinson, R.: Kinetics and Mechanisms of the Gas-Phase Reactions of the NO3 Radical with Organic Compounds, J. Phys. Chem. Ref. Data, 20, 459–507, https://doi.org/10.1063/1.555887, 1991. a
Atkinson, R., Arey, J., Zielinska, B., and Aschmann, S. M.: Kinetics and nitro-products of the gas-phase OH and NO3 radical-initiated reactions of naphthalene-d8, fluoranthene-d10, and pyrene, Int. J. Chem. Kinet., 22, 999–1014, https://doi.org/10.1002/kin.550220910, 1990. a
Baciocchi, E., Del Giacco, T., Murgia, S., and Sebastiani, G.: The photochemical reaction of cerium(IV) ammonium nitrate with alkenes. Rate and mechanism for the addition of the nitrate radical to alkenes, Tetrahedron, 44, 6651–6660, https://doi.org/10.1016/S0040-4020(01)90103-6, 1988. a
Bedjanian, Y.: Temperature-dependent rate constant for the reaction of F atoms with HNO3, Int. J. Chem. Kinet., 51, 753–759, https://doi.org/10.1002/kin.21306, 2019. a
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Short summary
We developed a new method to generate nitrate radicals (NO3) for atmospheric chemistry applications that works by irradiating mixtures containing ceric ammonium nitrate with a UV light at room temperature. It has several advantages over traditional NO3 sources. We characterized its performance over a range of mixture and reactor conditions as well as other irradiation products. Proof of concept was demonstrated by generating and characterizing oxidation products of the β-pinene + NO3 reaction.
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