Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-7955-2020
https://doi.org/10.5194/acp-20-7955-2020
Research article
 | 
09 Jul 2020
Research article |  | 09 Jul 2020

Sea spray aerosol organic enrichment, water uptake and surface tension effects

Luke T. Cravigan, Marc D. Mallet, Petri Vaattovaara, Mike J. Harvey, Cliff S. Law, Robin L. Modini, Lynn M. Russell, Ed Stelcer, David D. Cohen, Greg Olsen, Karl Safi, Timothy J. Burrell, and Zoran Ristovski

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Cited articles

Adams, E. M., Casper, C. B., and Allen, H. C.: Effect of cation enrichment on dipalmitoylphosphatidylcholine (DPPC) monolayers at the air-water interface, J. Colloid Interf. Sci., 478, 353–364, 2016. a
Alroe, J., Cravigan, L. T., Mallet, M. D., Ristovski, Z. D., Miljevic, B., Osuagwu, C. G., and Johnson, G. R.: Determining the link between hygroscopicity and composition for semi-volatile aerosol species, Atmos. Meas. Tech., 11, 4361–4372, https://doi.org/10.5194/amt-11-4361-2018, 2018. a
Ault, A. P., Moffet, R. C., Baltrusaitis, J., Collins, D. B., Ruppel, M. J., Cuadra-Rodriguez, L. A., Zhao, D., Guasco, T. L., Ebben, C. J., Geiger, F. M., Bertram, T. H., Prather, K. A., and Grassian, V. H.: Size-dependent changes in sea spray aerosol composition and properties with different seawater conditions, Environ. Sci. Technol., 47, 5603–5612, https://doi.org/10.1021/es400416g, 2013a. a, b, c, d, e
Ault, A. P., Zhao, D., Ebben, C. J., Tauber, M. J., Geiger, F. M., Prather, K. A., and Grassian, V. H.: Raman microspectroscopy and vibrational sum frequency generation spectroscopy as probes of the bulk and surface compositions of size-resolved sea spray aerosol particles, Phys. Chem. Chem. Phys., 15, 6206, https://doi.org/10.1039/c3cp43899f, 2013b. a
Bates, T. S., Quinn, P. K., Frossard, A. A., Russell, L. M., Hakala, J., Petäjä, T., Kulmala, M., Covert, D. S., Cappa, C. D., Li, S. M., Hayden, K. L., Nuaaman, I., McLaren, R., Massoli, P., Canagaratna, M. R., Onasch, T. B., Sueper, D., Worsnop, D. R., and Keene, W. C.: Measurements of ocean derived aerosol off the coast of California, J. Geophys. Res., 117, D00V15, https://doi.org/10.1029/2012JD017588, 2012. a, b, c, d
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Short summary
Aerosol–cloud interactions in remote marine environments are poorly represented in atmospheric modelling, particularly over the Southern Hemisphere. This work reports in situ chamber observations of sea spray aerosol composition and water uptake during the Surface Ocean Aerosol Production (SOAP) voyage. Observations were compared with currently applied models for sea spray organic enrichment. The sea spray hygroscopicity was persistently high, even at high organic fractions.
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