Articles | Volume 20, issue 24
https://doi.org/10.5194/acp-20-15513-2020
https://doi.org/10.5194/acp-20-15513-2020
Research article
 | 
14 Dec 2020
Research article |  | 14 Dec 2020

Kinetic modeling of formation and evaporation of secondary organic aerosol from NO3 oxidation of pure and mixed monoterpenes

Thomas Berkemeier, Masayuki Takeuchi, Gamze Eris, and Nga L. Ng

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This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Cited articles

Abramson, E., Imre, D., Beranek, J., Wilson, J. M., and Zelenyuk, A.: Experimental determination of chemical diffusion within secondary organic aerosol particles, Phys. Chem. Chem. Phys., 15, 2983–2991, https://doi.org/10.1039/c2cp44013j, 2013. a
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Baltensperger, U., Kalberer, M., Dommen, J., Paulsen, D., Alfarra, M. R., Coe, H., Fisseha, R., Gascho, A., Gysel, M., Nyeki, S., Sax, M., Steinbacher, M., Prevot, A. S. H., Sjögren, S., Weingartner, E., and Zenobi, R.: Secondary organic aerosols from anthropogenic and biogenic precursors, Faraday Discuss., 130, 265–278, https://doi.org/10.1039/B417367H, 2005. a, b
Barsanti, K. C., Kroll, J. H., and Thornton, J. A.: Formation of Low-Volatility Organic Compounds in the Atmosphere: Recent Advancements and Insights, J. Phys. Chem. Lett., 8, 1503–1511, https://doi.org/10.1021/acs.jpclett.6b02969, 2017. a, b, c
Berkemeier, T., Huisman, A. J., Ammann, M., Shiraiwa, M., Koop, T., and Pöschl, U.: Kinetic regimes and limiting cases of gas uptake and heterogeneous reactions in atmospheric aerosols and clouds: a general classification scheme, Atmos. Chem. Phys., 13, 6663–6686, https://doi.org/10.5194/acp-13-6663-2013, 2013. a
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Short summary
This paper presents how environmental chamber data of secondary organic aerosol (SOA) formation can be interpreted using kinetic modeling techniques. Utilizing pure and mixed precursor experiments, we show that SOA formation and evaporation can be understood by explicitly treating gas-phase chemistry, gas–particle partitioning, and, notably, particle-phase oligomerization, but some of the non-linear, non-equilibrium effects must be accredited to diffusion limitations in the particle phase.
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