Articles | Volume 20, issue 24
https://doi.org/10.5194/acp-20-15513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-15513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Dec 2020
Research article |
| 14 Dec 2020
| 14 Dec 2020
Kinetic modeling of formation and evaporation of secondary organic aerosol from NO3 oxidation of pure and mixed monoterpenes
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Masayuki Takeuchi
School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Gamze Eris
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
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Cited
13 citations as recorded by crossref.
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al. 10.1016/j.atmosres.2023.106674
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al. 10.5194/acp-22-155-2022
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al. 10.5194/acp-21-6175-2021
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al. 10.5194/amt-14-3693-2021
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. 10.1039/D2CP03289A
- Products and Mechanisms of Secondary Organic Aerosol Formation from the NO3 Radical-Initiated Oxidation of Cyclic and Acyclic Monoterpenes M. DeVault et al. 10.1021/acsearthspacechem.2c00130
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al. 10.5194/acp-23-8993-2023
13 citations as recorded by crossref.
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al. 10.1016/j.atmosres.2023.106674
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al. 10.5194/acp-22-155-2022
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al. 10.5194/acp-21-6175-2021
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al. 10.5194/amt-14-3693-2021
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. 10.1039/D2CP03289A
- Products and Mechanisms of Secondary Organic Aerosol Formation from the NO3 Radical-Initiated Oxidation of Cyclic and Acyclic Monoterpenes M. DeVault et al. 10.1021/acsearthspacechem.2c00130
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al. 10.5194/acp-23-8993-2023
Latest update: 17 Apr 2024
Short summary
This paper presents how environmental chamber data of secondary organic aerosol (SOA) formation can be interpreted using kinetic modeling techniques. Utilizing pure and mixed precursor experiments, we show that SOA formation and evaporation can be understood by explicitly treating gas-phase chemistry, gas–particle partitioning, and, notably, particle-phase oligomerization, but some of the non-linear, non-equilibrium effects must be accredited to diffusion limitations in the particle phase.
This paper presents how environmental chamber data of secondary organic aerosol (SOA) formation...
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