Articles | Volume 20, issue 24
https://doi.org/10.5194/acp-20-15513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-15513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Dec 2020
Research article |
| 14 Dec 2020
| 14 Dec 2020
Kinetic modeling of formation and evaporation of secondary organic aerosol from NO3 oxidation of pure and mixed monoterpenes
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Masayuki Takeuchi
School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Gamze Eris
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
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Cited
24 citations as recorded by crossref.
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al.
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al.
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al.
- Carbon Nanoparticle Oxidation by NO2 and O2: Chemical Kinetics and Reaction Pathways T. Berkemeier & U. Pöschl
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al.
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al.
- Ice-nucleating properties of glassy organic and organosulfate aerosol C. Rapp et al.
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al.
- Compositional Optimization for Miticidal Activity, Ecotoxicity, and Phytotoxicity of Rosmarinus officinalis Essential Oils as Biorational Pesticides J. Yoon & J. Tak
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al.
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al.
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al.
- Multiphase Chemistry and Phase State Explain Nonlinear Effects in the Formation and Evaporation of SOA from Mixed Monoterpene Precursors H. Kang et al.
- Organic nitrates in coastal aerosols: Seasonal dynamics, influencing factors, and formation pathways M. Tian et al.
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al.
- Oxidation von Kohlenstoff‐Nanopartikeln durch NO2 und O2: Chemische Kinetik und Reaktionspfade T. Berkemeier & U. Pöschl
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al.
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al.
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al.
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al.
- Utilization and validation of the polynomial models to predict insecticidal synergy in the essential oils of Thymus vulgaris L. and Thymus zygis L. against Musca domestica L. J. Yoon & J. Tak
- Products and Mechanisms of Secondary Organic Aerosol Formation from the NO3 Radical-Initiated Oxidation of Cyclic and Acyclic Monoterpenes M. DeVault et al.
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al.
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al.
24 citations as recorded by crossref.
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al.
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al.
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al.
- Carbon Nanoparticle Oxidation by NO2 and O2: Chemical Kinetics and Reaction Pathways T. Berkemeier & U. Pöschl
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al.
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al.
- Ice-nucleating properties of glassy organic and organosulfate aerosol C. Rapp et al.
- Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons J. Wilson et al.
- Compositional Optimization for Miticidal Activity, Ecotoxicity, and Phytotoxicity of Rosmarinus officinalis Essential Oils as Biorational Pesticides J. Yoon & J. Tak
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al.
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al.
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al.
- Multiphase Chemistry and Phase State Explain Nonlinear Effects in the Formation and Evaporation of SOA from Mixed Monoterpene Precursors H. Kang et al.
- Organic nitrates in coastal aerosols: Seasonal dynamics, influencing factors, and formation pathways M. Tian et al.
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al.
- Oxidation von Kohlenstoff‐Nanopartikeln durch NO2 und O2: Chemische Kinetik und Reaktionspfade T. Berkemeier & U. Pöschl
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al.
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al.
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al.
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al.
- Utilization and validation of the polynomial models to predict insecticidal synergy in the essential oils of Thymus vulgaris L. and Thymus zygis L. against Musca domestica L. J. Yoon & J. Tak
- Products and Mechanisms of Secondary Organic Aerosol Formation from the NO3 Radical-Initiated Oxidation of Cyclic and Acyclic Monoterpenes M. DeVault et al.
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al.
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al.
Saved (final revised paper)
Latest update: 11 May 2026
Short summary
This paper presents how environmental chamber data of secondary organic aerosol (SOA) formation can be interpreted using kinetic modeling techniques. Utilizing pure and mixed precursor experiments, we show that SOA formation and evaporation can be understood by explicitly treating gas-phase chemistry, gas–particle partitioning, and, notably, particle-phase oligomerization, but some of the non-linear, non-equilibrium effects must be accredited to diffusion limitations in the particle phase.
This paper presents how environmental chamber data of secondary organic aerosol (SOA) formation...
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