Articles | Volume 19, issue 17
https://doi.org/10.5194/acp-19-11235-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-11235-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Sep 2019
Research article |
| 05 Sep 2019
| 05 Sep 2019
Exploiting multi-wavelength aerosol absorption coefficients in a multi-time resolution source apportionment study to retrieve source-dependent absorption parameters
Alice Corina Forello
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
Vera Bernardoni
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
Giulia Calzolai
Department of Physics and Astronomy, Università di Firenze and
National Institute of Nuclear Physics INFN-Florence, via G. Sansone 1, Sesto
Fiorentino, 50019, Italy
Franco Lucarelli
Department of Physics and Astronomy, Università di Firenze and
National Institute of Nuclear Physics INFN-Florence, via G. Sansone 1, Sesto
Fiorentino, 50019, Italy
Dario Massabò
Department of Physics, Università degli Studi di Genova and
National Institute of Nuclear Physics INFN-Genoa, via Dodecaneso 33, Genoa,
16146, Italy
Silvia Nava
Department of Physics and Astronomy, Università di Firenze and
National Institute of Nuclear Physics INFN-Florence, via G. Sansone 1, Sesto
Fiorentino, 50019, Italy
Rosaria Erika Pileci
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
now at: Laboratory of Atmospheric Chemistry (LAC), Paul Scherrer
Institut (PSI), Forschungsstrasse 111, Villigen, 5232, Switzerland
Paolo Prati
Department of Physics, Università degli Studi di Genova and
National Institute of Nuclear Physics INFN-Genoa, via Dodecaneso 33, Genoa,
16146, Italy
Sara Valentini
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
Gianluigi Valli
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
Department of Physics, Università degli Studi di Milano and
National Institute of Nuclear Physics INFN-Milan, via Celoria 16, Milan,
20133, Italy
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Silvia G. Danelli, Marco Brunoldi, Dario Massabò, Franco Parodi, Virginia Vernocchi, and Paolo Prati
Atmos. Meas. Tech., 14, 4461–4470, https://doi.org/10.5194/amt-14-4461-2021, https://doi.org/10.5194/amt-14-4461-2021, 2021
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Rob L. Modini, Joel C. Corbin, Benjamin T. Brem, Martin Irwin, Michele Bertò, Rosaria E. Pileci, Prodromos Fetfatzis, Kostas Eleftheriadis, Bas Henzing, Marcel M. Moerman, Fengshan Liu, Thomas Müller, and Martin Gysel-Beer
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Giovanni Baccolo, Edyta Łokas, Paweł Gaca, Dario Massabò, Roberto Ambrosini, Roberto S. Azzoni, Caroline Clason, Biagio Di Mauro, Andrea Franzetti, Massimiliano Nastasi, Michele Prata, Paolo Prati, Ezio Previtali, Barbara Delmonte, and Valter Maggi
The Cryosphere, 14, 657–672, https://doi.org/10.5194/tc-14-657-2020, https://doi.org/10.5194/tc-14-657-2020, 2020
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Atmos. Meas. Tech., 12, 3173–3182, https://doi.org/10.5194/amt-12-3173-2019, https://doi.org/10.5194/amt-12-3173-2019, 2019
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Atmos. Chem. Phys., 19, 7519–7546, https://doi.org/10.5194/acp-19-7519-2019, https://doi.org/10.5194/acp-19-7519-2019, 2019
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APHH-Beijing is a collaborative international research programme to study the sources, processes and health effects of air pollution in Beijing. This introduction to the special issue provides an overview of (i) the APHH-Beijing programme, (ii) the measurement and modelling activities performed as part of it and (iii) the air quality and meteorological conditions during joint intensive field campaigns as a core activity within APHH-Beijing.
Nivedita K. Kumar, Joel C. Corbin, Emily A. Bruns, Dario Massabó, Jay G. Slowik, Luka Drinovec, Griša Močnik, Paolo Prati, Athanasia Vlachou, Urs Baltensperger, Martin Gysel, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 17843–17861, https://doi.org/10.5194/acp-18-17843-2018, https://doi.org/10.5194/acp-18-17843-2018, 2018
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It is clear that considerable uncertainties still exist in understanding the magnitude of aerosol absorption on a global scale and its contribution to global warming. This manuscript provides a comprehensive assessment of the optical absorption by organic aerosols (brown carbon) from residential wood combustion as a function of atmospheric aging.
Dario Massabò, Silvia Giulia Danelli, Paolo Brotto, Antonio Comite, Camilla Costa, Andrea Di Cesare, Jean François Doussin, Federico Ferraro, Paola Formenti, Elena Gatta, Laura Negretti, Maddalena Oliva, Franco Parodi, Luigi Vezzulli, and Paolo Prati
Atmos. Meas. Tech., 11, 5885–5900, https://doi.org/10.5194/amt-11-5885-2018, https://doi.org/10.5194/amt-11-5885-2018, 2018
Linda M. J. Kooijmans, Kadmiel Maseyk, Ulli Seibt, Wu Sun, Timo Vesala, Ivan Mammarella, Pasi Kolari, Juho Aalto, Alessandro Franchin, Roberta Vecchi, Gianluigi Valli, and Huilin Chen
Atmos. Chem. Phys., 17, 11453–11465, https://doi.org/10.5194/acp-17-11453-2017, https://doi.org/10.5194/acp-17-11453-2017, 2017
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Carbon cycle studies rely on the accuracy of models to estimate the amount of CO2 being taken up by vegetation. The gas carbonyl sulfide (COS) can serve as a tool to estimate the vegetative CO2 uptake by scaling the ecosystem uptake of COS to that of CO2. Here we investigate the nighttime fluxes of COS. The relationships found in this study will aid in implementing nighttime COS uptake in models, which is key to obtain accurate estimates of vegetative CO2 uptake with the use of COS.
Jorge Saturno, Christopher Pöhlker, Dario Massabò, Joel Brito, Samara Carbone, Yafang Cheng, Xuguang Chi, Florian Ditas, Isabella Hrabě de Angelis, Daniel Morán-Zuloaga, Mira L. Pöhlker, Luciana V. Rizzo, David Walter, Qiaoqiao Wang, Paulo Artaxo, Paolo Prati, and Meinrat O. Andreae
Atmos. Meas. Tech., 10, 2837–2850, https://doi.org/10.5194/amt-10-2837-2017, https://doi.org/10.5194/amt-10-2837-2017, 2017
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Different Aethalometer correction schemes were compared to a multi-wavelength absorption reference measurement. One of the correction schemes was found to artificially increase the short-wavelength absorption coefficients. It was found that accounting for aerosol scattering properties in the correction is crucial to retrieve the proper absorption Ångström exponent (AAE). We found that the raw AAE of uncompensated Aethalometer attenuation significantly correlates with a measured reference AAE.
Lorenzo Caponi, Paola Formenti, Dario Massabó, Claudia Di Biagio, Mathieu Cazaunau, Edouard Pangui, Servanne Chevaillier, Gautier Landrot, Meinrat O. Andreae, Konrad Kandler, Stuart Piketh, Thuraya Saeed, Dave Seibert, Earle Williams, Yves Balkanski, Paolo Prati, and Jean-François Doussin
Atmos. Chem. Phys., 17, 7175–7191, https://doi.org/10.5194/acp-17-7175-2017, https://doi.org/10.5194/acp-17-7175-2017, 2017
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This paper presents new laboratory measurements of the shortwave mass absorption efficiency (MAE) used by climate models for mineral dust of different origin and at different sizes. We found that small particles are more efficient, by given mass, in absorbing radiation, particularly at shorter wavelength. Because dust has high concentrations in the atmosphere, light absorption by mineral dust can be competitive to other absorbing atmospheric aerosols such as black and brown carbon.
Evangelia Diapouli, Manousos I. Manousakas, Stergios Vratolis, Vasiliki Vasilatou, Stella Pateraki, Kyriaki A. Bairachtari, Xavier Querol, Fulvio Amato, Andrés Alastuey, Angeliki A. Karanasiou, Franco Lucarelli, Silvia Nava, Giulia Calzolai, Vorne L. Gianelle, Cristina Colombi, Célia Alves, Danilo Custódio, Casimiro Pio, Christos Spyrou, George B. Kallos, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 17, 3673–3685, https://doi.org/10.5194/acp-17-3673-2017, https://doi.org/10.5194/acp-17-3673-2017, 2017
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This study examined the contribution of two natural sources (long-range transport of African dust and sea salt) to the airborne particulate matter concentrations, in 5 southern European cities (Porto, Barcelona, Milan, Florence, Athens). The results demonstrated that natural sources are often expressed with high-intensity events, leading even to exceedances of the EU air quality standards. This effect was more pronounced in the case of African dust intrusions in the eastern Mediterranean area.
Silvia Becagli, Fabrizio Anello, Carlo Bommarito, Federico Cassola, Giulia Calzolai, Tatiana Di Iorio, Alcide di Sarra, José-Luis Gómez-Amo, Franco Lucarelli, Miriam Marconi, Daniela Meloni, Francesco Monteleone, Silvia Nava, Giandomenico Pace, Mirko Severi, Damiano Massimiliano Sferlazzo, Rita Traversi, and Roberto Udisti
Atmos. Chem. Phys., 17, 2067–2084, https://doi.org/10.5194/acp-17-2067-2017, https://doi.org/10.5194/acp-17-2067-2017, 2017
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The paper aims to implement a specific strategy to target the aerosol due to ship emissions. PM10 is collected south and north of the main shipping route through the Mediterranean. Other than ions and metals the analysis is complemented with measurements of rare earth elements, trajectories from a high resolution regional model and actual observations of ship traffic. The combination of these approaches allows for unambiguous identification of the ship contribution (8–11 % of PM10) in this area.
Andrés Alastuey, Xavier Querol, Wenche Aas, Franco Lucarelli, Noemí Pérez, Teresa Moreno, Fabrizia Cavalli, Hans Areskoug, Violeta Balan, Maria Catrambone, Darius Ceburnis, José C. Cerro, Sébastien Conil, Lusine Gevorgyan, Christoph Hueglin, Kornelia Imre, Jean-Luc Jaffrezo, Sarah R. Leeson, Nikolaos Mihalopoulos, Marta Mitosinkova, Colin D. O'Dowd, Jorge Pey, Jean-Philippe Putaud, Véronique Riffault, Anna Ripoll, Jean Sciare, Karine Sellegri, Gerald Spindler, and Karl Espen Yttri
Atmos. Chem. Phys., 16, 6107–6129, https://doi.org/10.5194/acp-16-6107-2016, https://doi.org/10.5194/acp-16-6107-2016, 2016
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Mineral dust content in PM10 was analysed at 20 regional background sites across Europe. Higher dust loadings were observed at most sites in summer, with the most elevated concentrations in the southern- and easternmost countries, due to external and regional sources. Saharan dust outbreaks impacted western and central European in summer and eastern Mediterranean sites in winter. The spatial distribution of some metals reveals the influence of specific anthropogenic sources on a regional scale.
Fulvio Amato, Andrés Alastuey, Angeliki Karanasiou, Franco Lucarelli, Silvia Nava, Giulia Calzolai, Mirko Severi, Silvia Becagli, Vorne L. Gianelle, Cristina Colombi, Celia Alves, Danilo Custódio, Teresa Nunes, Mario Cerqueira, Casimiro Pio, Konstantinos Eleftheriadis, Evangelia Diapouli, Cristina Reche, María Cruz Minguillón, Manousos-Ioannis Manousakas, Thomas Maggos, Stergios Vratolis, Roy M. Harrison, and Xavier Querol
Atmos. Chem. Phys., 16, 3289–3309, https://doi.org/10.5194/acp-16-3289-2016, https://doi.org/10.5194/acp-16-3289-2016, 2016
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Harmonized source apportionment of atmospheric particulate matter (PM10 and PM2.5) at 5 EU cities (Barcelona, Florence, Milan, Athens and Porto) reveals that vehicle exhaust (excluding nitrate) plus non-exhaust contributes 16–32 % to PM10 and 15–36 % to PM2.5. Secondary PM represents 37–82 % of PM2.5. Biomass burning varies from < 2 to 24 % of PM10, depending on the residential heating fuel. Other sources are local dust (7–19 % of PM10), industries (4–11 % of PM10), shipping, sea salt and Saharan dust.
G. Calzolai, S. Nava, F. Lucarelli, M. Chiari, M. Giannoni, S. Becagli, R. Traversi, M. Marconi, D. Frosini, M. Severi, R. Udisti, A. di Sarra, G. Pace, D. Meloni, C. Bommarito, F. Monteleone, F. Anello, and D. M. Sferlazzo
Atmos. Chem. Phys., 15, 13939–13955, https://doi.org/10.5194/acp-15-13939-2015, https://doi.org/10.5194/acp-15-13939-2015, 2015
P. Panteliadis, T. Hafkenscheid, B. Cary, E. Diapouli, A. Fischer, O. Favez, P. Quincey, M. Viana, R. Hitzenberger, R. Vecchi, D. Saraga, J. Sciare, J. L. Jaffrezo, A. John, J. Schwarz, M. Giannoni, J. Novak, A. Karanasiou, P. Fermo, and W. Maenhaut
Atmos. Meas. Tech., 8, 779–792, https://doi.org/10.5194/amt-8-779-2015, https://doi.org/10.5194/amt-8-779-2015, 2015
M. Marconi, D. M. Sferlazzo, S. Becagli, C. Bommarito, G. Calzolai, M. Chiari, A. di Sarra, C. Ghedini, J. L. Gómez-Amo, F. Lucarelli, D. Meloni, F. Monteleone, S. Nava, G. Pace, S. Piacentino, F. Rugi, M. Severi, R. Traversi, and R. Udisti
Atmos. Chem. Phys., 14, 2039–2054, https://doi.org/10.5194/acp-14-2039-2014, https://doi.org/10.5194/acp-14-2039-2014, 2014
S. Sandrini, L. Giulianelli, S. Decesari, S. Fuzzi, P. Cristofanelli, A. Marinoni, P. Bonasoni, M. Chiari, G. Calzolai, S. Canepari, C. Perrino, and M. C. Facchini
Atmos. Chem. Phys., 14, 1075–1092, https://doi.org/10.5194/acp-14-1075-2014, https://doi.org/10.5194/acp-14-1075-2014, 2014
M. Dall'Osto, X. Querol, A. Alastuey, M. C. Minguillon, M. Alier, F. Amato, M. Brines, M. Cusack, J. O. Grimalt, A. Karanasiou, T. Moreno, M. Pandolfi, J. Pey, C. Reche, A. Ripoll, R. Tauler, B. L. Van Drooge, M. Viana, R. M. Harrison, J. Gietl, D. Beddows, W. Bloss, C. O'Dowd, D. Ceburnis, G. Martucci, N. L. Ng, D. Worsnop, J. Wenger, E. Mc Gillicuddy, J. Sodeau, R. Healy, F. Lucarelli, S. Nava, J. L. Jimenez, F. Gomez Moreno, B. Artinano, A. S. H. Prévôt, L. Pfaffenberger, S. Frey, F. Wilsenack, D. Casabona, P. Jiménez-Guerrero, D. Gross, and N. Cots
Atmos. Chem. Phys., 13, 8991–9019, https://doi.org/10.5194/acp-13-8991-2013, https://doi.org/10.5194/acp-13-8991-2013, 2013
M. Dall'Osto, X. Querol, F. Amato, A. Karanasiou, F. Lucarelli, S. Nava, G. Calzolai, and M. Chiari
Atmos. Chem. Phys., 13, 4375–4392, https://doi.org/10.5194/acp-13-4375-2013, https://doi.org/10.5194/acp-13-4375-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Measurement report: Aircraft observations of aerosol and microphysical quantities of stratocumulus in autumn over Guangxi Province, China – daylight variation, vertical distribution, and aerosol–cloud interactions
Hygroscopic aerosols amplify longwave downward radiation in the Arctic
Measurement report: Optical and structural properties of atmospheric water-soluble organic carbon in China – insights from multi-site spectroscopic measurements
Measurement report: The variation properties of aerosol hygroscopic growth related to chemical composition during new particle formation days in a coastal city of Southeast China
In situ vertical observations of the layered structure of air pollution in a continental high-latitude urban boundary layer during winter
Size-resolved hygroscopicity and volatility properties of ambient urban aerosol particles measured by a volatility hygroscopicity tandem differential mobility analyzer system in Beijing
Terrestrial runoff is an important source of biological ice-nucleating particles in Arctic marine systems
Characterization of aerosol over the eastern Mediterranean by polarization-sensitive Raman lidar measurements during A-LIFE – aerosol type classification and type separation
Aerosol spectral optical properties in the Paris urban area and its peri-urban and forested surroundings during summer 2022 from ACROSS surface observations
Measurement report: An investigation of the spatiotemporal variability in aerosols in the mountainous terrain of the upper Colorado River basin using SAIL-Net
Contributions of the synoptic meteorology to the seasonal cloud condensation nuclei cycle over the Southern Ocean
Measurement report: Cloud condensation nuclei (CCN) activity in the South China Sea from shipborne observations during the summer and winter of 2021 – seasonal variation and anthropogenic influence
Measurement report: A comparative analysis of an intensive incursion of fluorescing African dust particles over Puerto Rico and another over Spain
Measurement report: Analysis of aerosol optical depth variation at Zhongshan Station in Antarctica
External particle mixing influences hygroscopicity in a sub-urban area
Long-term observations of black carbon and carbon monoxide in the Poker Flat Research Range, central Alaska, with a focus on forest wildfire emissions
High ice-nucleating particle concentrations associated with Arctic haze in springtime cold-air outbreaks
CCN estimations at a high-altitude remote site: role of organic aerosol variability and hygroscopicity
Aerosol hygroscopicity over the southeast Atlantic Ocean during the biomass burning season – Part 1: From the perspective of scattering enhancement
Spatial, temporal, and meteorological impact of the 26 February 2023 dust storm: increase in particulate matter concentrations across New Mexico and West Texas
Large spatiotemporal variability in aerosol properties over central Argentina during the CACTI field campaign
Quantification and characterization of primary biological aerosol particles and microbes aerosolized from Baltic seawater
Brownness of organics in anthropogenic biomass burning aerosols over South Asia
Measurement report: size-resolved particle effective density measured by the AAC-SMPS and implications for chemical composition
Source apportionment of particle number size distribution at the street canyon and urban background sites
Long-range transport of coarse mineral dust: an evaluation of the Met Office Unified Model against aircraft observations
Extreme Saharan dust events expand northward over the Atlantic and Europe, prompting record-breaking PM10 and PM2.5 episodes
Atmospheric black carbon in the metropolitan area of La Paz and El Alto, Bolivia: concentration levels and emission sources
Changing optical properties of black carbon and brown carbon aerosols during long-range transport from the Indo-Gangetic Plain to the equatorial Indian Ocean
The evolution of aerosols mixing state derived from a field campaign in Beijing: implications to the particles aging time scale in urban atmosphere
Aerosol size distribution properties associated with cold-air outbreaks in the Norwegian Arctic
Ice-nucleating particles active below −24 °C in a Finnish boreal forest and their relationship to bioaerosols
Measurement report: The influence of particle number size distribution and hygroscopicity on the microphysical properties of cloud droplets at a mountain site
Measurements of particle emissions of an A350-941 burning 100 % sustainable aviation fuels in cruise
Vertical distribution of ice nucleating particles over the boreal forest of Hyytiälä, Finland
Multi-year gradient measurements of sea spray fluxes over the Baltic Sea and the North Atlantic Ocean
Measurement report: In situ vertical profiles of below-cloud aerosol over the central Greenland Ice Sheet
Occurrence, abundance, and formation of atmospheric tarballs from a wide range of wildfires in the western US
Measurement report: Contribution of atmospheric new particle formation to ultrafine particle concentration, cloud condensation nuclei, and radiative forcing – results from 5-year observations in central Europe
Simulated contrail-processed aviation soot aerosols are poor ice-nucleating particles at cirrus temperatures
Biological and dust aerosols as sources of ice-nucleating particles in the eastern Mediterranean: source apportionment, atmospheric processing and parameterization
Quantifying the dust direct radiative effect in the southwestern United States: findings from multiyear measurements
How horizontal transport and turbulent mixing impact aerosol particle and precursor concentrations at a background site in the UAE
Markedly different impacts of primary emissions and secondary aerosol formation on aerosol mixing states revealed by simultaneous measurements of CCNC, H(/V)TDMA, and SP2
Phase matrix characterization of long-range transported Saharan dust using multiwavelength polarized polar imaging nephelometry
Vertically resolved aerosol variability at the Amazon Tall Tower Observatory under wet-season conditions
Vertical structure of a springtime smoky and humid troposphere over the southeast Atlantic from aircraft and reanalysis
Measurement Report: Long-term Assessment of Primary and Secondary Organic Aerosols in Shanghai Megacity throughout China’s Clean Air Actions since 2010
Shipborne observations of black carbon aerosols in the western Arctic Ocean during summer and autumn 2016–2020: impact of boreal fires
Attribution of aerosol particle number size distributions to main sources using an 11-year urban dataset
Sihan Liu, Honglei Wang, Delong Zhao, Wei Zhou, Yuanmou Du, Zhengguo Zhang, Peng Cheng, Tianliang Zhao, Yue Ke, Zihao Wu, and Mengyu Huang
Atmos. Chem. Phys., 25, 4151–4165, https://doi.org/10.5194/acp-25-4151-2025, https://doi.org/10.5194/acp-25-4151-2025, 2025
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To understand the effect of aerosols on the vertical distribution of stratocumulus microphysical quantities in southwest China, the daily variation characteristics and formation mechanism of the vertical profiles of stratocumulus microphysical characteristics in this region were described using the data of nine cloud-crossing aircraft observations over Guangxi from 10 October to 3 November 2020.
Denghui Ji, Mathias Palm, Matthias Buschmann, Kerstin Ebell, Marion Maturilli, Xiaoyu Sun, and Justus Notholt
Atmos. Chem. Phys., 25, 3889–3904, https://doi.org/10.5194/acp-25-3889-2025, https://doi.org/10.5194/acp-25-3889-2025, 2025
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Our study explores how certain aerosols, like sea salt, affect infrared heat radiation in the Arctic, potentially speeding up warming. We used advanced technology to measure aerosol composition and found that these particles grow with humidity, significantly increasing their heat-trapping effect in the infrared region, especially in winter. Our findings suggest these aerosols could be a key factor in Arctic warming, emphasizing the importance of understanding aerosols for climate prediction.
Haibiao Chen, Caiqing Yan, Liubin Huang, Lin Du, Yang Yue, Xinfeng Wang, Qingcai Chen, Mingjie Xie, Junwen Liu, Fengwen Wang, Shuhong Fang, Qiaoyun Yang, Hongya Niu, Mei Zheng, Yan Wu, and Likun Xue
Atmos. Chem. Phys., 25, 3647–3667, https://doi.org/10.5194/acp-25-3647-2025, https://doi.org/10.5194/acp-25-3647-2025, 2025
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A comprehensive understanding of the optical properties of brown carbon (BrC) is essential to accurately assess its climatic effects. Based on multi-site spectroscopic measurements, this study demonstrated the significant spatial heterogeneity in the optical and structural properties of water-soluble organic carbon (WSOC) in different regions of China and revealed factors affecting WSOC light absorption and the relationship between fluorophores and light absorption of WSOC.
Lingjun Li, Mengren Li, Xiaolong Fan, Yuping Chen, Ziyi Lin, Anqi Hou, Siqing Zhang, Ronghua Zheng, and Jinsheng Chen
Atmos. Chem. Phys., 25, 3669–3685, https://doi.org/10.5194/acp-25-3669-2025, https://doi.org/10.5194/acp-25-3669-2025, 2025
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Here, we show differences and variations in the aerosol scattering hygroscopic growth factor (f(RH)) between new particle formation (NPF) and non-NPF days and the effect of aerosol chemical compositions on f(RH) in Xiamen with in situ observations. The findings are helpful for the further understanding of aerosol hygroscopicity in a coastal city and the use of hygroscopic growth factors in models of air quality and climate change.
Roman Pohorsky, Andrea Baccarini, Natalie Brett, Brice Barret, Slimane Bekki, Gianluca Pappaccogli, Elsa Dieudonné, Brice Temime-Roussel, Barbara D'Anna, Meeta Cesler-Maloney, Antonio Donateo, Stefano Decesari, Kathy S. Law, William R. Simpson, Javier Fochesatto, Steve R. Arnold, and Julia Schmale
Atmos. Chem. Phys., 25, 3687–3715, https://doi.org/10.5194/acp-25-3687-2025, https://doi.org/10.5194/acp-25-3687-2025, 2025
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This study presents an analysis of vertical measurements of pollution in an Alaskan city during winter. It investigates the relationship between the atmospheric structure and the layering of aerosols and trace gases. Results indicate an overall very shallow surface mixing layer. The height of this layer is strongly influenced by a local shallow wind. The study also provides information on the pollution chemical composition at different altitudes, including pollution signatures from power plants.
Aoyuan Yu, Xiaojing Shen, Qianli Ma, Jiayuan Lu, Xinyao Hu, Yangmei Zhang, Quan Liu, Linlin Liang, Lei Liu, Shuo Liu, Hongfei Tong, Huizheng Che, Xiaoye Zhang, and Junying Sun
Atmos. Chem. Phys., 25, 3389–3412, https://doi.org/10.5194/acp-25-3389-2025, https://doi.org/10.5194/acp-25-3389-2025, 2025
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In this work, we utilized a volatility hygroscopicity tandem differential mobility analyzer (VH-TDMA) to investigate, for the first time, the hygroscopicity and volatility of submicron aerosols, as well as their hygroscopicity after heating, in urban Beijing during the autumn of 2023. We analyzed the size-resolved characteristics of hygroscopicity and volatility, the relationship between hygroscopic and volatile properties, and the hygroscopicity of heated submicron aerosols.
Corina Wieber, Lasse Z. Jensen, Leendert Vergeynst, Lorenz Meire, Thomas Juul-Pedersen, Kai Finster, and Tina Šantl-Temkiv
Atmos. Chem. Phys., 25, 3327–3346, https://doi.org/10.5194/acp-25-3327-2025, https://doi.org/10.5194/acp-25-3327-2025, 2025
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The Arctic region is subject to profound changes due to a warming climate. Ice-nucleating particles (INPs) in the seawater can get transported to the atmosphere and impact cloud formation. However, the sources of characteristics of INPs in the marine areas are poorly understood. We investigated the INPs in seawater from Greenlandic fjords and identified a seasonal variability, with highly active INPs originating from terrestrial sources such as glacial and soil runoff.
Silke Groß, Volker Freudenthaler, Moritz Haarig, Albert Ansmann, Carlos Toledano, David Mateos, Petra Seibert, Rodanthi-Elisavet Mamouri, Argyro Nisantzi, Josef Gasteiger, Maximilian Dollner, Anne Tipka, Manuel Schöberl, Marilena Teri, and Bernadett Weinzierl
Atmos. Chem. Phys., 25, 3191–3211, https://doi.org/10.5194/acp-25-3191-2025, https://doi.org/10.5194/acp-25-3191-2025, 2025
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Aerosols contribute to the largest uncertainties in climate change predictions. The eastern Mediterranean is a hotspot for aerosols with natural and anthropogenic contributions. We present lidar measurements performed during A-LIFE (Absorbing aerosol layers in a changing climate: aging, lifetime and dynamics) to characterize aerosols and aerosol mixtures. We extend current lidar classification and separation schemes and compare them to classification schemes using different methods.
Ludovico Di Antonio, Claudia Di Biagio, Paola Formenti, Aline Gratien, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Patrice Coll, Barbara D'Anna, Joel F. de Brito, David O. De Haan, Juliette R. Dignum, Shravan Deshmukh, Olivier Favez, Pierre-Marie Flaud, Cecile Gaimoz, Lelia N. Hawkins, Julien Kammer, Brigitte Language, Franck Maisonneuve, Griša Močnik, Emilie Perraudin, Jean-Eudes Petit, Prodip Acharja, Laurent Poulain, Pauline Pouyes, Eva Drew Pronovost, Véronique Riffault, Kanuri I. Roundtree, Marwa Shahin, Guillaume Siour, Eric Villenave, Pascal Zapf, Gilles Foret, Jean-François Doussin, and Matthias Beekmann
Atmos. Chem. Phys., 25, 3161–3189, https://doi.org/10.5194/acp-25-3161-2025, https://doi.org/10.5194/acp-25-3161-2025, 2025
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The spectral complex refractive index (CRI) and single scattering albedo were retrieved from submicron aerosol measurements at three sites within the greater Paris area during the ACROSS field campaign (June–July 2022). Measurements revealed urban emission impact on surrounding areas. CRI full period averages at 520 nm were 1.41 – 0.037i (urban), 1.52 – 0.038i (peri-urban), and 1.50 – 0.025i (rural). Organic aerosols dominated the aerosol mass and contributed up to 22 % of absorption at 370 nm.
Leah D. Gibson, Ezra J. T. Levin, Ethan Emerson, Nick Good, Anna Hodshire, Gavin McMeeking, Kate Patterson, Bryan Rainwater, Tom Ramin, and Ben Swanson
Atmos. Chem. Phys., 25, 2745–2762, https://doi.org/10.5194/acp-25-2745-2025, https://doi.org/10.5194/acp-25-2745-2025, 2025
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From fall 2021 to summer 2023, SAIL-Net, a network of six aerosol measurement nodes, was deployed in the East River watershed (Colorado, USA) to study aerosol variability across space and time in mountainous terrain. We found that aerosol variability is influenced by elevation differences, with the most representative site in the region changing seasonally, suggesting aerosol spatial variability also varies seasonally. This work offers a blueprint for future studies in other mountainous regions.
Tahereh Alinejadtabrizi, Yi Huang, Francisco Lang, Steven Siems, Michael Manton, Luis Ackermann, Melita Keywood, Ruhi Humphries, Paul Krummel, Alastair Williams, and Greg Ayers
Atmos. Chem. Phys., 25, 2631–2648, https://doi.org/10.5194/acp-25-2631-2025, https://doi.org/10.5194/acp-25-2631-2025, 2025
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Clouds over the Southern Ocean are crucial to Earth's energy balance, but understanding the factors that control them is complex. Our research examines how weather patterns affect tiny particles called cloud condensation nuclei (CCN), which influence cloud properties. Using data from Kennaook / Cape Grim, we found that winter air from Antarctica brings cleaner conditions with lower CCN, while summer patterns from Australia transport more particles. Precipitation also helps reduce CCN in winter.
Hengjia Ou, Mingfu Cai, Yongyun Zhang, Xue Ni, Baoling Liang, Qibin Sun, Shixin Mai, Cuizhi Sun, Shengzhen Zhou, Haichao Wang, Jiaren Sun, and Jun Zhao
Atmos. Chem. Phys., 25, 2495–2513, https://doi.org/10.5194/acp-25-2495-2025, https://doi.org/10.5194/acp-25-2495-2025, 2025
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Two shipborne observations in the South China Sea (SCS) in summer and winter 2021 were conducted. Our study found aerosol hygroscopicity is higher in the SCS in summer than winter, with significant influences from various terrestrial air masses. Aerosol size distribution had a stronger effect on activation ratio than aerosol hygroscopicity in summer and vice versa in winter. Our study provides valuable information to enhance our understanding of cloud condensation nuclei activities in the SCS.
Bighnaraj Sarangi, Darrel Baumgardner, Ana Isabel Calvo, Benjamin Bolaños-Rosero, Roberto Fraile, Alberto Rodríguez-Fernández, Delia Fernández-González, Carlos Blanco-Alegre, Cátia Gonçalves, Estela D. Vicente, and Olga L. Mayol-Bracero
Atmos. Chem. Phys., 25, 843–865, https://doi.org/10.5194/acp-25-843-2025, https://doi.org/10.5194/acp-25-843-2025, 2025
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Measurements of fluorescing aerosol particle properties have been made during two major African dust events, one over the island of Puerto Rico and the other over the city of León, Spain. The measurements were made with two wideband integrated bioaerosol spectrometers. A significant change in the background aerosol properties, at both locations, is observed when the dust is in the respective regions.
Lijing Chen, Lei Zhang, Yong She, Zhaoliang Zeng, Yu Zheng, Biao Tian, Wenqian Zhang, Zhaohui Liu, Huizheng Che, and Minghu Ding
Atmos. Chem. Phys., 25, 727–739, https://doi.org/10.5194/acp-25-727-2025, https://doi.org/10.5194/acp-25-727-2025, 2025
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Aerosol optical depth (AOD) at Zhongshan Station varies seasonally, with lower values in summer and higher values in winter. Winter and spring AOD increases due to reduced fine-mode particles, while summer and autumn increases are linked to particle growth. Diurnal AOD variation correlates positively with temperature but negatively with wind speed and humidity. Backward trajectories show that aerosols on high-AOD (low-AOD) days primarily originate from the ocean (interior Antarctica).
Shravan Deshmukh, Laurent Poulain, Birgit Wehner, Silvia Henning, Jean-Eudes Petit, Pauline Fombelle, Olivier Favez, Hartmut Herrmann, and Mira Pöhlker
Atmos. Chem. Phys., 25, 741–758, https://doi.org/10.5194/acp-25-741-2025, https://doi.org/10.5194/acp-25-741-2025, 2025
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Aerosol hygroscopicity has been investigated at a sub-urban site in Paris; analysis shows the sub-saturated regime's measured hygroscopicity and the chemically derived hygroscopic growth, shedding light on the large effect of external particle mixing and its influence on predicting hygroscopicity.
Takeshi Kinase, Fumikazu Taketani, Masayuki Takigawa, Chunmao Zhu, Yongwon Kim, Petr Mordovskoi, and Yugo Kanaya
Atmos. Chem. Phys., 25, 143–156, https://doi.org/10.5194/acp-25-143-2025, https://doi.org/10.5194/acp-25-143-2025, 2025
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Boreal forest wildfires in interior Alaska represent an important black carbon (BC) source for the Arctic and surrounding regions. We observed BC and carbon monoxide (CO) concentrations in the Poker Flat Research Range since 2016 and found a positive correlation between the observed BC / ∆CO ratio and fire radiative power (FRP) observed in Alaska and Canada. Our finding suggests the BC emission factor and/or inventory could be potentially improved by using FRP.
Erin N. Raif, Sarah L. Barr, Mark D. Tarn, James B. McQuaid, Martin I. Daily, Steven J. Abel, Paul A. Barrett, Keith N. Bower, Paul R. Field, Kenneth S. Carslaw, and Benjamin J. Murray
Atmos. Chem. Phys., 24, 14045–14072, https://doi.org/10.5194/acp-24-14045-2024, https://doi.org/10.5194/acp-24-14045-2024, 2024
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Ice-nucleating particles (INPs) allow ice to form in clouds at temperatures warmer than −35°C. We measured INP concentrations over the Norwegian and Barents seas in weather events where cold air is ejected from the Arctic. These concentrations were among the highest measured in the Arctic. It is likely that the INPs were transported to the Arctic from distant regions. These results show it is important to consider hemispheric-scale INP processes to understand INP concentrations in the Arctic.
Fernando Rejano, Andrea Casans, Marta Via, Juan Andrés Casquero-Vera, Sonia Castillo, Hassan Lyamani, Alberto Cazorla, Elisabeth Andrews, Daniel Pérez-Ramírez, Andrés Alastuey, Francisco Javier Gómez-Moreno, Lucas Alados-Arboledas, Francisco José Olmo, and Gloria Titos
Atmos. Chem. Phys., 24, 13865–13888, https://doi.org/10.5194/acp-24-13865-2024, https://doi.org/10.5194/acp-24-13865-2024, 2024
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This study provides valuable insights to improve cloud condensation nuclei (CCN) estimations at a high-altitude remote site which is influenced by nearby urban pollution. Understanding the factors that affect CCN estimations is essential to improve the CCN data coverage worldwide and assess aerosol–cloud interactions on a global scale. This is crucial for improving climate models, since aerosol–cloud interactions are the most important source of uncertainty in climate projections.
Lu Zhang, Michal Segal-Rozenhaimer, Haochi Che, Caroline Dang, Junying Sun, Ye Kuang, Paola Formenti, and Steven G. Howell
Atmos. Chem. Phys., 24, 13849–13864, https://doi.org/10.5194/acp-24-13849-2024, https://doi.org/10.5194/acp-24-13849-2024, 2024
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Using airborne measurements over the southeast Atlantic Ocean, we examined how much moisture aerosols take up during Africa’s biomass burning season. Our study revealed the important role of organic aerosols and introduced a predictive model for moisture uptake, accounting for organics, sulfate, and black carbon, summarizing results from various campaigns. These findings improve our understanding of aerosol–moisture interactions and their radiative effects in this climatically critical region.
Mary C. Robinson, Kaitlin Schueth, and Karin Ardon-Dryer
Atmos. Chem. Phys., 24, 13733–13750, https://doi.org/10.5194/acp-24-13733-2024, https://doi.org/10.5194/acp-24-13733-2024, 2024
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On 26 February 2023, New Mexico and West Texas were impacted by a severe dust storm. To analyze this storm, 28 meteorological stations and 19 PM2.5 and PM10 stations were used. Dust particles were in the air for 16 h, and dust storm conditions lasted for up to 120 min. Hourly PM2.5 and PM10 concentrations were up to 518 and 9983 µg m−3, respectively. For Lubbock, Texas, the maximum PM2.5 concentrations were the highest ever recorded.
Jerome D. Fast, Adam C. Varble, Fan Mei, Mikhail Pekour, Jason Tomlinson, Alla Zelenyuk, Art J. Sedlacek III, Maria Zawadowicz, and Louisa Emmons
Atmos. Chem. Phys., 24, 13477–13502, https://doi.org/10.5194/acp-24-13477-2024, https://doi.org/10.5194/acp-24-13477-2024, 2024
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Aerosol property measurements recently collected on the ground and by a research aircraft in central Argentina during the Cloud, Aerosol, and Complex Terrain Interactions (CACTI) campaign exhibit large spatial and temporal variability. These measurements coupled with coincident meteorological information provide a valuable data set needed to evaluate and improve model predictions of aerosols in a traditionally data-sparse region of South America.
Julika Zinke, Gabriel Pereira Freitas, Rachel Ann Foster, Paul Zieger, Ernst Douglas Nilsson, Piotr Markuszewski, and Matthew Edward Salter
Atmos. Chem. Phys., 24, 13413–13428, https://doi.org/10.5194/acp-24-13413-2024, https://doi.org/10.5194/acp-24-13413-2024, 2024
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Bioaerosols, which can influence climate and human health, were studied in the Baltic Sea. In May and August 2021, we used a sea spray simulation chamber during two ship-based campaigns to collect and measure these aerosols. We found that microbes were enriched in air compared to seawater. Bacterial diversity was analysed using DNA sequencing. Our methods provided consistent estimates of microbial emission fluxes, aligning with previous studies.
Chimurkar Navinya, Taveen Singh Kapoor, Gupta Anurag, Chandra Venkataraman, Harish C. Phuleria, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 24, 13285–13297, https://doi.org/10.5194/acp-24-13285-2024, https://doi.org/10.5194/acp-24-13285-2024, 2024
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Brown carbon (BrC) aerosols show an order-of-magnitude variation in their light absorption strength. Our understanding of BrC from real-world biomass burning remains limited, complicating the determination of its radiative impact. Our study reports absorption properties of BrC emitted from four major biomass burning sources using field measurements in India. It develops an absorption parameterization for BrC and examines the spatial variability in BrC's absorption strength across India.
Yao Song, Jing Wei, Wenlong Zhao, Jinmei Ding, Xiangyu Pei, Fei Zhang, Zhengning Xu, Ruifang Shi, Ya Wei, Lu Zhang, Lingling Jin, and Zhibin Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3298, https://doi.org/10.5194/egusphere-2024-3298, 2024
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This study investigates the size-resolved effective density (ρeff) of aerosol particles in Hangzhou using an AAC-SMPS. The ρeff values ranged from 1.47 to 1.63 g/cm3, increasing with particle diameter. Smaller particles showed significant diurnal density variations. The relationship between ρeff and particle diameter varies due to differences in the chemical composition of the particles. A new method to derive size-resolved chemical composition of particles from ρeff was proposed.
Sami D. Harni, Minna Aurela, Sanna Saarikoski, Jarkko V. Niemi, Harri Portin, Hanna Manninen, Ville Leinonen, Pasi Aalto, Phil K. Hopke, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 24, 12143–12160, https://doi.org/10.5194/acp-24-12143-2024, https://doi.org/10.5194/acp-24-12143-2024, 2024
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In this study, particle number size distribution data were used in a novel way in positive matrix factorization analysis to find aerosol source profiles in the area. Measurements were made in Helsinki at a street canyon and urban background sites between February 2015 and June 2019. Five different aerosol sources were identified. These sources underline the significance of traffic-related emissions in urban environments despite recent improvements in emission reduction technologies.
Natalie G. Ratcliffe, Claire L. Ryder, Nicolas Bellouin, Stephanie Woodward, Anthony Jones, Ben Johnson, Lisa-Maria Wieland, Maximilian Dollner, Josef Gasteiger, and Bernadett Weinzierl
Atmos. Chem. Phys., 24, 12161–12181, https://doi.org/10.5194/acp-24-12161-2024, https://doi.org/10.5194/acp-24-12161-2024, 2024
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Large mineral dust particles are more abundant in the atmosphere than expected and have different impacts on the environment than small particles, which are better represented in climate models. We use aircraft measurements to assess a climate model representation of large-dust transport. We find that the model underestimates the amount of large dust at all stages of transport and that fast removal of the large particles increases this underestimation with distance from the Sahara.
Sergio Rodríguez and Jessica López-Darias
Atmos. Chem. Phys., 24, 12031–12053, https://doi.org/10.5194/acp-24-12031-2024, https://doi.org/10.5194/acp-24-12031-2024, 2024
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Extreme Saharan dust events expanded northward to the Atlantic and Europe, prompting record-breaking PM10 and PM2.5 events. These episodes are caused by low-to-high dipole meteorology during hemispheric anomalies characterized by subtropical anticyclones shifting to higher latitudes, anomalous low pressures beyond the tropics and amplified Rossby waves. Extreme dust events occur in a paradoxical context of a multidecadal decrease in dust emissions, a topic that requires further investigation.
Valeria Mardoñez-Balderrama, Griša Močnik, Marco Pandolfi, Robin L. Modini, Fernando Velarde, Laura Renzi, Angela Marinoni, Jean-Luc Jaffrezo, Isabel Moreno R., Diego Aliaga, Federico Bianchi, Claudia Mohr, Martin Gysel-Beer, Patrick Ginot, Radovan Krejci, Alfred Wiedensohler, Gaëlle Uzu, Marcos Andrade, and Paolo Laj
Atmos. Chem. Phys., 24, 12055–12077, https://doi.org/10.5194/acp-24-12055-2024, https://doi.org/10.5194/acp-24-12055-2024, 2024
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Levels of black carbon (BC) are scarcely reported in the Southern Hemisphere, especially in high-altitude conditions. This study provides insight into the concentration level, variability, and optical properties of BC in La Paz and El Alto and at the Chacaltaya Global Atmosphere Watch Station. Two methods of source apportionment of absorption were tested and compared showing traffic as the main contributor to absorption in the urban area, in addition to biomass and open waste burning.
Krishnakant Budhavant, Mohanan Remani Manoj, Hari Ram Chandrika Rajendran Nair, Samuel Mwaniki Gaita, Henry Holmstrand, Abdus Salam, Ahmed Muslim, Sreedharan Krishnakumari Satheesh, and Örjan Gustafsson
Atmos. Chem. Phys., 24, 11911–11925, https://doi.org/10.5194/acp-24-11911-2024, https://doi.org/10.5194/acp-24-11911-2024, 2024
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The South Asian Pollution Experiment 2018 used access to three strategically located receptor observatories. Observational constraints revealed opposing trends in the mass absorption cross sections of black carbon (BC MAC) and brown carbon (BrC MAC) during long-range transport. Models estimating the climate effects of BC aerosols may have underestimated the ambient BC MAC over distant receptor areas, leading to discrepancies in aerosol absorption predicted by observation-constrained models.
Jieyao Liu, Fang Zhang, Jingye Ren, and Lu Chen
EGUsphere, https://doi.org/10.5194/egusphere-2024-2999, https://doi.org/10.5194/egusphere-2024-2999, 2024
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The particles mixing states and aging time scale are important for the evaluation of aerosols climate effects, but they are poorly parameterized in current models. We unravel the evolution of real-time mixing states and aging time scale of size-resolved particles based on field measurement in urban Beijing. This study provides observational basis for accurately parameterizing the aging time scale of aerosol particles in climate models.
Abigail S. Williams, Jeramy L. Dedrick, Lynn M. Russell, Florian Tornow, Israel Silber, Ann M. Fridlind, Benjamin Swanson, Paul J. DeMott, Paul Zieger, and Radovan Krejci
Atmos. Chem. Phys., 24, 11791–11805, https://doi.org/10.5194/acp-24-11791-2024, https://doi.org/10.5194/acp-24-11791-2024, 2024
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The measured aerosol size distribution modes reveal distinct properties characteristic of cold-air outbreaks in the Norwegian Arctic. We find higher sea spray number concentrations, smaller Hoppel minima, lower effective supersaturations, and accumulation-mode particle scavenging during cold-air outbreaks. These results advance our understanding of cold-air outbreak aerosol–cloud interactions in order to improve their accurate representation in models.
Franziska Vogel, Michael P. Adams, Larissa Lacher, Polly B. Foster, Grace C. E. Porter, Barbara Bertozzi, Kristina Höhler, Julia Schneider, Tobias Schorr, Nsikanabasi S. Umo, Jens Nadolny, Zoé Brasseur, Paavo Heikkilä, Erik S. Thomson, Nicole Büttner, Martin I. Daily, Romy Fösig, Alexander D. Harrison, Jorma Keskinen, Ulrike Proske, Jonathan Duplissy, Markku Kulmala, Tuukka Petäjä, Ottmar Möhler, and Benjamin J. Murray
Atmos. Chem. Phys., 24, 11737–11757, https://doi.org/10.5194/acp-24-11737-2024, https://doi.org/10.5194/acp-24-11737-2024, 2024
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Primary ice formation in clouds strongly influences their properties; hence, it is important to understand the sources of ice-nucleating particles (INPs) and their variability. We present 2 months of INP measurements in a Finnish boreal forest using a new semi-autonomous INP counting device based on gas expansion. These results show strong variability in INP concentrations, and we present a case that the INPs we observe are, at least some of the time, of biological origin.
Xiaojing Shen, Quan Liu, Junying Sun, Wanlin Kong, Qianli Ma, Bing Qi, Lujie Han, Yangmei Zhang, Linlin Liang, Lei Liu, Shuo Liu, Xinyao Hu, Jiayuan Lu, Aoyuan Yu, Huizheng Che, and Xiaoye Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2850, https://doi.org/10.5194/egusphere-2024-2850, 2024
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In this work, an automatic switched inlet system was developed and employed to investigate the aerosols and cloud droplets at a mountain site with frequent cloud processes. It showed different characteristics of cloud residual and interstitial particles. Stronger particle hygroscopicity reduced liquid water content and smaller cloud droplet diameters. This investigation contributes to understanding aerosol-cloud interactions by assessing the impact of aerosol particles on cloud microphysics.
Rebecca Dischl, Daniel Sauer, Christiane Voigt, Theresa Harlaß, Felicitas Sakellariou, Raphael Märkl, Ulrich Schumann, Monika Scheibe, Stefan Kaufmann, Anke Roiger, Andreas Dörnbrack, Charles Renard, Maxime Gauthier, Peter Swann, Paul Madden, Darren Luff, Mark Johnson, Denise Ahrens, Reetu Sallinen, Tobias Schripp, Georg Eckel, Uwe Bauder, and Patrick Le Clercq
Atmos. Chem. Phys., 24, 11255–11273, https://doi.org/10.5194/acp-24-11255-2024, https://doi.org/10.5194/acp-24-11255-2024, 2024
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In-flight measurements of aircraft emissions burning 100 % sustainable aviation fuel (SAF) show reduced particle number concentrations up to 41 % compared to conventional jet fuel. Particle emissions are dependent on engine power setting, flight altitude, and fuel composition. Engine models show a good correlation with measurement results. Future increased prevalence of SAF can positively influence the climate impact of aviation.
Zoé Brasseur, Julia Schneider, Janne Lampilahti, Ville Vakkari, Victoria A. Sinclair, Christina J. Williamson, Carlton Xavier, Dmitri Moisseev, Markus Hartmann, Pyry Poutanen, Markus Lampimäki, Markku Kulmala, Tuukka Petäjä, Katrianne Lehtipalo, Erik S. Thomson, Kristina Höhler, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 24, 11305–11332, https://doi.org/10.5194/acp-24-11305-2024, https://doi.org/10.5194/acp-24-11305-2024, 2024
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Ice-nucleating particles (INPs) strongly influence the formation of clouds by initiating the formation of ice crystals. However, very little is known about the vertical distribution of INPs in the atmosphere. Here, we present aircraft measurements of INP concentrations above the Finnish boreal forest. Results show that near-surface INPs are efficiently transported and mixed within the boundary layer and occasionally reach the free troposphere.
Piotr Markuszewski, E. Douglas Nilsson, Julika Zinke, E. Monica Mårtensson, Matthew Salter, Przemysław Makuch, Małgorzata Kitowska, Iwona Niedźwiecka-Wróbel, Violetta Drozdowska, Dominik Lis, Tomasz Petelski, Luca Ferrero, and Jacek Piskozub
Atmos. Chem. Phys., 24, 11227–11253, https://doi.org/10.5194/acp-24-11227-2024, https://doi.org/10.5194/acp-24-11227-2024, 2024
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Our research provides new insights into the study of sea spray aerosol (SSA) emissions in the Baltic Sea and North Atlantic. We observed that SSA flux is suppressed during increased marine biological activity in the Baltic Sea. At the same time, the influence of wave age showed higher SSA emissions in the Baltic Sea for younger waves compared to the Atlantic Ocean. These insights underscore the complex interplay between biological activity and physical dynamics in regulating SSA emissions.
Heather Guy, Andrew S. Martin, Erik Olson, Ian M. Brooks, and Ryan R. Neely III
Atmos. Chem. Phys., 24, 11103–11114, https://doi.org/10.5194/acp-24-11103-2024, https://doi.org/10.5194/acp-24-11103-2024, 2024
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Aerosol particles impact cloud properties which influence Greenland Ice Sheet melt. Understanding the aerosol population that interacts with clouds is important for constraining future melt. Measurements of aerosols at cloud height over Greenland are rare, and surface measurements are often used to investigate cloud–aerosol interactions. We use a tethered balloon to measure aerosols up to cloud base and show that surface measurements are often not equivalent to those just below the cloud.
Kouji Adachi, Jack E. Dibb, Joseph M. Katich, Joshua P. Schwarz, Hongyu Guo, Pedro Campuzano-Jost, Jose L. Jimenez, Jeff Peischl, Christopher D. Holmes, and James Crawford
Atmos. Chem. Phys., 24, 10985–11004, https://doi.org/10.5194/acp-24-10985-2024, https://doi.org/10.5194/acp-24-10985-2024, 2024
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We examined aerosol particles from wildfires and identified tarballs (TBs) from the Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign. This study reveals the compositions, abundance, sizes, and mixing states of TBs and shows that TBs formed as the smoke aged for up to 5 h. This study provides measurements of TBs from various biomass-burning events and ages, enhancing our knowledge of TB emissions and our understanding of their climate impact.
Jia Sun, Markus Hermann, Kay Weinhold, Maik Merkel, Wolfram Birmili, Yifan Yang, Thomas Tuch, Harald Flentje, Björn Briel, Ludwig Ries, Cedric Couret, Michael Elsasser, Ralf Sohmer, Klaus Wirtz, Frank Meinhardt, Maik Schütze, Olaf Bath, Bryan Hellack, Veli-Matti Kerminen, Markku Kulmala, Nan Ma, and Alfred Wiedensohler
Atmos. Chem. Phys., 24, 10667–10687, https://doi.org/10.5194/acp-24-10667-2024, https://doi.org/10.5194/acp-24-10667-2024, 2024
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We investigated the characteristics of new particle formation (NPF) for various environments from urban background to high Alpine and the impacts of NPF on cloud condensation nuclei and aerosol radiative forcing. NPF features differ between site categories, implying the crucial role of local environmental factors such as the degree of emissions and meteorological conditions. The results also underscore the importance of local environments when assessing the impact of NPF on climate in models.
Baptiste Testa, Lukas Durdina, Jacinta Edebeli, Curdin Spirig, and Zamin A. Kanji
Atmos. Chem. Phys., 24, 10409–10424, https://doi.org/10.5194/acp-24-10409-2024, https://doi.org/10.5194/acp-24-10409-2024, 2024
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Aviation soot residuals released from contrails can become compacted upon sublimation of the ice crystals, generating new voids in the aggregates where ice nucleation can occur. Here we show that contrail-processed soot is highly compact but that it remains unable to form ice at a relative humidity different from that required for the formation of background cirrus from the more ubiquitous aqueous solution droplets, suggesting that it will not perturb cirrus cloud formation via ice nucleation.
Kunfeng Gao, Franziska Vogel, Romanos Foskinis, Stergios Vratolis, Maria I. Gini, Konstantinos Granakis, Anne-Claire Billault-Roux, Paraskevi Georgakaki, Olga Zografou, Prodromos Fetfatzis, Alexis Berne, Alexandros Papayannis, Konstantinos Eleftheridadis, Ottmar Möhler, and Athanasios Nenes
Atmos. Chem. Phys., 24, 9939–9974, https://doi.org/10.5194/acp-24-9939-2024, https://doi.org/10.5194/acp-24-9939-2024, 2024
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Ice nucleating particle (INP) concentrations are required for correct predictions of clouds and precipitation in a changing climate, but they are poorly constrained in climate models. We unravel source contributions to INPs in the eastern Mediterranean and find that biological particles are important, regardless of their origin. The parameterizations developed exhibit superior performance and enable models to consider biological-particle effects on INPs.
Alexandra Kuwano, Amato T. Evan, Blake Walkowiak, and Robert Frouin
Atmos. Chem. Phys., 24, 9843–9868, https://doi.org/10.5194/acp-24-9843-2024, https://doi.org/10.5194/acp-24-9843-2024, 2024
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The dust direct radiative effect is highly uncertain. Here we used new measurements collected over 3 years and during dust storms at a field site in a desert region in the southwestern United States to estimate the regional dust direct radiative effect. We also used novel soil mineralogy retrieved from an airborne spectrometer to estimate this parameter with model output. We find that, in this region, dust has a minimal net cooling effect on this region's climate.
Jutta Kesti, Ewan J. O'Connor, Anne Hirsikko, John Backman, Maria Filioglou, Anu-Maija Sundström, Juha Tonttila, Heikki Lihavainen, Hannele Korhonen, and Eija Asmi
Atmos. Chem. Phys., 24, 9369–9386, https://doi.org/10.5194/acp-24-9369-2024, https://doi.org/10.5194/acp-24-9369-2024, 2024
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The study combines aerosol particle measurements at the surface and vertical profiling of the atmosphere with a scanning Doppler lidar to investigate how particle transportation together with boundary layer evolution can affect particle and SO2 concentrations at the surface in the Arabian Peninsula region. The instrumentation enabled us to see elevated nucleation mode particle and SO2 concentrations at the surface when air masses transported from polluted areas are mixed in the boundary layer.
Jiangchuan Tao, Biao Luo, Weiqi Xu, Gang Zhao, Hanbin Xu, Biao Xue, Miaomiao Zhai, Wanyun Xu, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Li Liu, Ye Kuang, and Yele Sun
Atmos. Chem. Phys., 24, 9131–9154, https://doi.org/10.5194/acp-24-9131-2024, https://doi.org/10.5194/acp-24-9131-2024, 2024
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Using simultaneous measurements of DMA–CCNC, H(/V)TDMA, and DMA–SP2, impacts of primary emissions and secondary aerosol formations on changes in aerosol physicochemical properties were comprehensively investigated. It was found that intercomparisons among aerosol mixing-state parameters derived from different techniques can help us gain more insight into aerosol physical properties which, in turn, will aid the investigation of emission characteristics and secondary aerosol formation pathways.
Elena Bazo, Daniel Perez-Ramirez, Antonio Valenzuela, Vanderlei Martins, Gloria Titos, Alberto Cazorla, Fernando Rejano, Diego Patrón, Arlett Diaz-Zurita, Francisco Jose Garcia-Izquierdo, David Fuertes, Lucas Alados-Arboledas, and Francisco Jose Olmo
EGUsphere, https://doi.org/10.5194/egusphere-2024-2080, https://doi.org/10.5194/egusphere-2024-2080, 2024
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This works analyses aerosol scattering phase function for transported Saharan dust to the city of Granada – located in southwestern Europe. We use the novel technique polar imaging nephelometry that helps to determine the phase functions using a CCD camara. The capability of measuring with polarized light helps to inferr new properties about the mixture of Saharan dust particles with other of anthropogenic origin.
Marco A. Franco, Rafael Valiati, Bruna A. Holanda, Bruno B. Meller, Leslie A. Kremper, Luciana V. Rizzo, Samara Carbone, Fernando G. Morais, Janaína P. Nascimento, Meinrat O. Andreae, Micael A. Cecchini, Luiz A. T. Machado, Milena Ponczek, Ulrich Pöschl, David Walter, Christopher Pöhlker, and Paulo Artaxo
Atmos. Chem. Phys., 24, 8751–8770, https://doi.org/10.5194/acp-24-8751-2024, https://doi.org/10.5194/acp-24-8751-2024, 2024
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The Amazon wet-season atmosphere was studied at the Amazon Tall Tower Observatory site, revealing vertical variations (between 60 and 325 m) in natural aerosols. Daytime mixing contrasted with nighttime stratification, with distinct rain-induced changes in aerosol populations. Notably, optical property recovery at higher levels was faster, while near-canopy aerosols showed higher scattering efficiency. These findings enhance our understanding of aerosol impacts on climate dynamics.
Kristina Pistone, Eric M. Wilcox, Paquita Zuidema, Marco Giordano, James Podolske, Samuel E. LeBlanc, Meloë Kacenelenbogen, Steven G. Howell, and Steffen Freitag
Atmos. Chem. Phys., 24, 7983–8005, https://doi.org/10.5194/acp-24-7983-2024, https://doi.org/10.5194/acp-24-7983-2024, 2024
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The springtime southeast Atlantic atmosphere contains lots of smoke from continental fires. This smoke travels with water vapor; more smoke means more humidity. We use aircraft observations and models to describe how the values change through the season and over the region. We sort the atmosphere into different types by vertical structure and amount of smoke and humidity. Since our work shows how frequently these components coincide, it helps to better quantify heating effects over this region.
Haifeng Yu, Yunhua Chang, Lin Cheng, Yusen Duan, and Jianlin Hu
EGUsphere, https://doi.org/10.5194/egusphere-2024-1488, https://doi.org/10.5194/egusphere-2024-1488, 2024
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This study presents long-term measurements and comprehensive analysis of carbonaceous aerosols in PM2.5 in Shanghai. We further estimated POC and SOC levels, examining their temporal variations on interannual, monthly, seasonal, and diurnal scales. Through rigorous statistical analysis and correlation studies with meteorological parameters and pollutant concentrations, the origins, formation mechanisms, and spatial distribution patterns of SOC were elucidated.
Yange Deng, Hiroshi Tanimoto, Kohei Ikeda, Sohiko Kameyama, Sachiko Okamoto, Jinyoung Jung, Young Jun Yoon, Eun Jin Yang, and Sung-Ho Kang
Atmos. Chem. Phys., 24, 6339–6357, https://doi.org/10.5194/acp-24-6339-2024, https://doi.org/10.5194/acp-24-6339-2024, 2024
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Black carbon (BC) aerosols play important roles in Arctic climate change, yet they are not well understood because of limited observational data. We observed BC mass concentrations (mBC) in the western Arctic Ocean during summer and early autumn 2016–2020. The mean mBC in 2019 was much higher than in other years. Biomass burning was likely the dominant BC source. Boreal fire BC transport occurring near the surface and/or in the mid-troposphere contributed to high-BC events in the Arctic Ocean.
Máté Vörösmarty, Philip K. Hopke, and Imre Salma
Atmos. Chem. Phys., 24, 5695–5712, https://doi.org/10.5194/acp-24-5695-2024, https://doi.org/10.5194/acp-24-5695-2024, 2024
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The World Health Organization identified ultrafine particles, which make up most of the particle number concentrations, as a potential risk factor for humans. The sources of particle numbers are very different from those of the particulate matter mass. We performed source apportionment of size-segregated particle number concentrations over the diameter range of 6–1000 nm in Budapest for 11 full years. Six source types were identified, characterized and quantified.
Cited articles
Amato, F., Alastuey, A., Karanasiou, A., Lucarelli, F., Nava, S., Calzolai, G., Severi, M., Becagli, S., Gianelle, V. L., Colombi, C., Alves, C., Custódio, D., Nunes, T., Cerqueira, M., Pio, C., Eleftheriadis, K., Diapouli, E., Reche, C., Minguillón, M. C., Manousakas, M.-I., Maggos, T., Vratolis, S., Harrison, R. M., and Querol, X.: AIRUSE-LIFE+: a harmonized PM speciation and source apportionment in five southern European cities, Atmos. Chem. Phys., 16, 3289–3309, https://doi.org/10.5194/acp-16-3289-2016, 2016.
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Belis, C. A., Larsen, B. R., Amato, F., El Haddad, I., Favez, O., Harrison, R. M.,
Hopke, P. K., Nava, S., Paatero, P., Prèvot, A., Quass, U., Vecchi, R., and
Viana, M.: European Guide on Air Pollution Source Identification with
Receptor Models, Luxembourg: Publications Office of the European Union,
Joint Research Center – Institute for Environment and Sustainability,
European Union, https://doi.org/10.2788/9332, 2014.
Belis, C. A., Karagulian, F., Amato, F., Almeida, M., Artaxo, P., Beddows, D. C. S.,
Bernardoni, V., Bove, M. C., Carbone, S., Cesari, D., Contini, D., Cuccia, E.,
Diapouli, E., Eleftheriadis, K., Favez, O., El Haddad, I., Harrison, R. M.,
Hellebust, S., Hovorka, J., Jang, E., Jorquera, H., Kammermeier, T., Karl, M.,
Lucarelli, F., Mooibroek, D., Nava, S., Nøjgaard, J. K., Paatero, P., Pandolfi,
M., Perrone, M. G., Petit, J. E., Pietrodangelo, A., Pokorná, P., Prati, P.,
Prevot, A. S. H., Quass, U., Querol, X., Saraga D., Sciare, J., Sfetsos, A., Valli
G., Vecchi, R., Vestenius, M., Yubero, E., and Hopke, P. K.: A new methodology to
assess the performance and uncertainty of source apportionment models II:
The results of two European intercomparison exercises, Atmos. Environ., 123,
240–250, https://doi.org/10.1016/j.atmosenv.2015.10.068, 2015.
Bernardoni, V., Vecchi, R., Valli, G., Piazzalunga, A., and Fermo, P.: PM10 source
apportionment in Milan (Italy) using time-resolved data, Sci. Total
Environ., 409, 4788–4795, https://doi.org/10.1016/j.scitotenv.2011.07.048,
2011.
Bernardoni, V., Elser, M., Valli, G., Valentini, S., Bigi, A., Fermo, P.,
Piazzalunga, A., and Vecchi, R.: Size-segregated aerosol in a hot-spot
pollution urban area: Chemical composition and three-way source
apportionment, Environ. Pollut., 231, 601–611,
https://doi.org/10.1016/j.envpol.2017.08.040, 2017a.
Bernardoni, V., Pileci, R. E., Caponi, L., and Massabò, D.: The
Multi-Wavelength Absorption Analyzer (MWAA) model as a tool for source and
component apportionment based on aerosol absorption properties: application
to samples collected in different environments, Atmosphere, 8, 218,
https://doi.org/10.3390/atmos8110218, 2017b.
Bernardoni, V., Valli, G., and Vecchi, R.: Set-up of a multi-wavelength polar
photometer for the off-line measurement of light absorption properties of
atmospheric aerosol collected with high-temporal resolution, J. Aerosol.
Sci., 107, 84–93, https://doi.org/10.1016/j.jaerosci.2017.02.009, 2017c.
Bigi, A. and Ghermandi, G.: Long-term trend and variability of atmospheric PM10 concentration in the Po Valley, Atmos. Chem. Phys., 14, 4895–4907, https://doi.org/10.5194/acp-14-4895-2014, 2014.
Bond, T. C. and Bergstrom, R. W.: Light absorption by carbonaceous particles: an
investigative review, Aerosol Sci. Tech., 40, 27–67,
https://doi.org/10.1080/02786820500421521, 2006.
Bond, T. C., Doherty, S. J., Fahey, D. W., Forster, P. M., Berntsen, T., DeAngelo,
B. J., Flanner, M. G., Ghan, S., Kärcher, B., Koch, D., Kinne, S., Kondo, Y.,
Quinn, P. K., Sarofim, M. C., Schultz, M. G., Schulz, M., Venkataraman, C., Zhang,
H., Zhang, S., Bellouin, N., Guttikunda, S. K., Hopke, P. K., Jacobson, M. Z.,
Kaiser, J. W., Klimont, Z., Lohmann, U., Schwarz, J. P., Shindell, D., Storelvmo
T., Warren, S. G., and Zender, C. S.: Bounding the role of black carbon in the
climate system: A scientific assessment, J. Geophys. Res.-Atmos., 118,
5380–5552, https://doi.org/10.1002/jgrd.50171, 2013.
Brown, S. G., Eberly, S., Paatero, P., and Norris, G. A.: Methods for estimating
uncertainty in PMF solutions: Examples with ambient air and water quality
data and guidance on reporting PMF results, Sci. Total Environ., 518–519,
626–635, https://doi.org/10.1016/j.scitotenv.2015.01.022, 2015.
Calzolai, G., Chiari, M., Lucarelli, F., Mazzei, F., Nava, S., Prati, P., Valli, G.,
and Vecchi, R.: PIXE and XRF analysis of particulate matter samples: an
inter-laboratory comparison, Nucl. Instrum. Meth. B, 266, 2401–2404,
https://doi.org/10.1016/j.nimb.2008.03.056, 2008.
Calzolai, G., Lucarelli, F., Chiari, M., Nava, S., Giannoni, M., Carraresi, L.,
Prati, P., and Vecchi, R.: Improvements in PIXE analysis of hourly particulate
matter samples, Nucl. Instrum. Meth. B, 363, 99–104,
https://doi.org/10.1016/j.nimb.2015.08.022, 2015.
Cappa, C. D., Lack, D. A., Burkholder, J. B., and Ravishankara, A. R.: Bias in
filter-based aerosol light absorption measurements due to organic aerosol
loading: Evidence from laboratory measurements, Aerosol Sci. Tech., 42,
1022–1032, https://doi.org/10.1080/02786820802389285, 2008.
Carslaw, D. C. and Ropkins, K.: Openair – an R package for air quality data
analysis, Environ. Modell. Softw., 27/28, 52–61,
https://doi.org/10.1016/j.envsoft.2011.09.008, 2012
Crespi, A., Bernardoni, V., Calzolai, G., Lucarelli, F., Nava, S., Valli, G., and
Vecchi, R.: Implementing constrained multi-time approach with bootstrap
analysis in ME-2: an application to PM2.5 data from Florence (Italy), Sci.
Total Environ., 541, 502–511,
https://doi.org/10.1016/j.scitotenv.2015.08.159, 2016.
Crilley, L. R., Lucarelli, F., Bloss, W. J., Harrison, R. M., Beddows, D. C.,
Calzolai, G., Nava, S., Valli, G., Bernardoni, V., and Vecchi, R.: Source
Apportionment of Fine and Coarse Particles at a Roadside and Urban
Background Site in London during the Summer ClearfLo Campaign, Environ.
Pollut., 220, 766–778, https://doi.org/10.1016/j.envpol.2016.06.002, 2017.
D'Alessandro, A., Lucarelli, F., Mandò, P. A., Marcazzan, G., Nava, S., Prati,
P., Valli, G., Vecchi, R., and Zucchiatti, A.: Hourly elemental composition and
sources identification of fine and coarse PM10 particulate matter in four
Italian towns, J. Aerosol Sci., 34, 243–259,
https://doi.org/10.1016/S0021-8502(02)00172-6, 2003.
Dall'Osto, M., Querol, X., Amato, F., Karanasiou, A., Lucarelli, F., Nava, S., Calzolai, G., and Chiari, M.: Hourly elemental concentrations in PM2.5 aerosols sampled simultaneously at urban background and road site during SAPUSS – diurnal variations and PMF receptor modelling, Atmos. Chem. Phys., 13, 4375–4392, https://doi.org/10.5194/acp-13-4375-2013, 2013.
Davies, N. W., Fox, C., Szpek, K., Cotterell, M. I., Taylor, J. W., Allan, J. D., Williams, P. I., Trembath, J., Haywood, J. M., and Langridge, J. M.: Evaluating biases in filter-based aerosol absorption measurements using photoacoustic spectroscopy, Atmos. Meas. Tech., 12, 3417–3434, https://doi.org/10.5194/amt-12-3417-2019, 2019.
Draxler, R. R. and Hess, G. D.: An overview of the HYSPLIT_4
modelling system for trajectories, dispersion, and deposition, Aust.
Meteorol. Mag., 47, 295–308, 1998.
Fialho, P., Hansen, A. D. A., and Honrath, R. E.: Absorption coefficients by
aerosols in remote areas: a new approach to decouple dust and black carbon
absorption coefficients using seven-wavelength Aethalometer data, J. Aerosol
Sci., 36, 267–282, https://doi.org/10.1016/j.jaerosci.2004.09.004, 2005.
Fischer, D. A. and Smith, G. D.: A portable, four wavelength, single-cell
photoacoustic spectrometer for ambient aerosol absorption, Aerosol Sci.
Tech., 52, 393–406, https://doi.org/10.1080/02786826.2017.1413231, 2018.
Fuller, K. A., Malm, W. C., and Kreidenweis, S. M.: Effects of mixing on extinction
by carbonaceous particles, J. Geophys. Res., 104, 15941–15954,
https://doi.org/10.1029/1998JD100069, 1999.
Fuzzi, S., Baltensperger, U., Carslaw, K., Decesari, S., Denier van der Gon, H., Facchini, M. C., Fowler, D., Koren, I., Langford, B., Lohmann, U., Nemitz, E., Pandis, S., Riipinen, I., Rudich, Y., Schaap, M., Slowik, J. G., Spracklen, D. V., Vignati, E., Wild, M., Williams, M., and Gilardoni, S.: Particulate matter, air quality and climate: lessons learned and future needs, Atmos. Chem. Phys., 15, 8217–8299, https://doi.org/10.5194/acp-15-8217-2015, 2015.
Gyawali, M., Arnott, W. P., Lewis, K., and Moosmüller, H.: In situ aerosol optics in Reno, NV, USA during and after the summer 2008 California wildfires and the influence of absorbing and non-absorbing organic coatings on spectral light absorption, Atmos. Chem. Phys., 9, 8007–8015, https://doi.org/10.5194/acp-9-8007-2009, 2009.
Hennigan, C. J., Sullivan, A. P., Collett Jr., J. L., and Robinson, A. L.: Levoglucosan
stability in biomass burning particles exposed to hydroxyl radicals,
Geophys. Res. Lett., 37, L09806, https://doi.org/10.1029/2010GL043088, 2010.
Henry, R. C.: History and fundamentals of multivariate air quality receptor
models, Chemometr. Intell. Lab., 37, 37–42,
https://doi.org/10.1016/S0169-7439(96)00048-2, 1997.
Hopke, P. K.: Review of receptor modeling methods for source apportionment, J.
Air Waste Manage., 66, 3, 237–259,
https://doi.org/10.1080/10962247.2016.1140693, 2016.
INEMAR – ARPA Lombardia: INEMAR, Inventario Emissioni in Atmosfera:
emissioni in Regione Lombardia nell'anno 2014 – dati finali, ARPA Lombardia
Settore Monitoraggi Ambientali,
available at: http://www.inemar.eu/xwiki/bin/view/Inemar/HomeLombardia (last access: 14 Januaery 2019), 2014.
IPCC: Climate Change 2013: The Physical Science Basis, Contribution of
Working Group I to the Fifth Assessment Report of the Intergovernmental
Panel on Climate Changes, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M.,
Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M.,
Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA,
https://doi.org/10.1017/CBO9781107415324, 2013.
Kim, E., Hopke, P. K., and Edgerton, E. S.: Source identification of Atlanta
aerosol by positive matrix factorization, J. Air Waste Manage., 53,
731–739, https://doi.org/10.1080/10473289.2003.10466209, 2003.
Kuo, C.-P., Liao, H.-T., Chou, C. C.-K., and Wu, C.-F.: Source apportionment of
particulate matter and selected volatile organic compounds with multiple
time resolution data, Sci. Total Environ., 472, 880–887,
https://doi.org/10.1016/j.scitotenv.2013.11.114, 2014.
Lack, D. A., Cappa, C. D., Covert, D. S., Baynard, T., Massoli, P., Sierau, B., Bates,
T. S., Quinn, P. K., Lovejoy, E. R., and Ravishankara, A. R.: Bias in filter-based
aerosol light absorption measurements due to organic aerosol loading:
Evidence from ambient measurements, Aerosol Sci. Tech., 42, 1033–1041,
https://doi.org/10.1080/02786820802389277, 2008.
Lee, E., Chan, C. K., and Paatero, P.: Application of positive matrix
factorization in source apportionment of particulate pollutants in Hong
Kong, Atmos. Environ., 33, 3201–3212,
https://doi.org/10.1016/S1352-2310(99)00113-2, 1999.
Liao, H.-T., Chou, C. C.-K., Chow, J. C., Watson, J. G., Hopke, P. K. and Wu, C.-F.:
Source and risk apportionment of selected VOCs and PM2.5 species using
partially constrained receptor models with multiple time resolution data,
Environ. Pollut., 205, 121–130,
https://doi.org/10.1016/j.envpol.2015.05.035, 2015.
Liu, C., Chung, C. E., Yin, Y., and Schnaiter, M.: The absorption Ångström exponent of black carbon: from numerical aspects, Atmos. Chem. Phys., 18, 6259–6273, https://doi.org/10.5194/acp-18-6259-2018, 2018.
Marcazzan, G. M., Vaccaro, S., Valli, G., and Vecchi, R.: Characterisation of PM10
and PM2.5 particulate matter in the ambient air of Milan (Italy), Atmos.
Environ., 35, 4639–4650, https://doi.org/10.1016/S1352-2310(01)00124-8,
2001.
Marcazzan, G. M., Ceriani, M., Valli, G., and Vecchi, R.: Source apportionment of
PM10 and PM2.5 in Milan (Italy) using receptor modelling, Sci. Total
Environ., 317, 137–147, https://doi.org/10.1016/S0048-9697(03)00368-1, 2003.
Mason B.: Principles of geochemistry, 3rd Edition, John Wiley &
Sons, New York, 1966.
Massabò, D., Caponi, L., Bernardoni, V., Bove, M. C., Brotto, P., Calzolai, G.,
Cassola, F., Chiari, M., Fedi, M. E., Fermo, P., Giannoni, M., Lucarelli, F., Nava,
S., Piazzalunga, A., Valli, G., Vecchi, R., and Prati, P.: Multi-wavelength
optical determination of black and brown carbon in atmospheric aerosols,
Atmos. Environ., 108, 1–12, https://doi.org/10.1016/j.atmosenv.2015.02.058,
2015.
Massabò, D., Caponi, L., Bove, M. C., and Prati, P.: Brown carbon and
thermal-optical analysis: A correction based on optical multi-wavelength
apportionment of atmospheric aerosols, Atmos. Environ., 125, 119–125,
https://doi.org/10.1016/j.atmosenv.2015.11.011, 2016.
Moffet, R. C. and Prather, K. A.: In-situ measurements of the mixing state and
optical properties of soot with implications for radiative forcing
estimates, P. Natl. Acad. Sci. USA, 106, 11872–11877,
https://doi.org/10.1073/pnas.0900040106, 2009.
Norris, G., Duvall, R., Brown, S., and Bai, S.: EPA Positive Matrix Factorization
(PMF) 5.0. Fundamentals and User Guide, U.S. Environmental Protection
Agency, Washington, DC, 2014.
Ogulei, D., Hopke, P. K., Zhou, L., Paatero, P., Park, S. S., and Ondov, J. M.:
Receptor modeling for multiple time resolved species: the Baltimore
supersite, Atmos. Environ., 39, 3751–3762,
https://doi.org/10.1016/j.atmosenv.2005.03.012, 2005.
Paatero, P.: Least squares formulation of robust non-negative factor
analysis, Chemometr. Intell. Lab., 37, 23–35,
https://doi.org/10.1016/S0169-7439(96)00044-5, 1997.
Paatero, P.: The Multilinear Engine – A Table-drive least squares program
for solving multilinear problems, including the n-way parallel factor
analysis model, J. Comput. Graph. Stat., 8, 854–888,
https://doi.org/10.1080/10618600.1999.10474853, 1999.
Paatero, P.: User's guide for the Multilinear Engine program “ME2” for
fitting multilinear and quasi-multilinear models, University of Helsinki,
Department of Physics, Finland, 2000.
Paatero, P.: User's Guide for Positive Matrix Factorization programs PMF2 and
PMF3, Part 2: reference, available at: https://www.helsinki.fi/~paatero/PMF/pmf2.zip (last access: 21 June 2018), 2010.
Paatero, P.: The Multilinear Engine (ME-2) script language (v. 1.352),
available with the program ME-2 (me2scrip.txt), 2012.
Paatero, P.: User's guide for positive matrix factorization programs PMF2 and
PMF3, part 1: Tutorial, available at: https://www.helsinki.fi/~paatero/PMF/pmf2.zip (last access: 21 June 2018), 2015.
Paatero, P.: Interactive comment on “Receptor modelling ofboth particle composition and size distributionfrom a background site in London, UK – the twostep approach” by David C. S. Beddows and Roy M. Harrison,
https://doi.org/10.5194/acp-2018-784-RC2, 2018.
Paatero, P. and Hopke, P. K.: Rotational tools for factor analytic models, J.
Chemometr., 23, 91–100, https://doi.org/10.1002/cem.1197, 2009.
Paatero, P. and Tapper, U.: Positive Matrix Factorization: a non-negative
factor model with optimal utilization of error estimates of data values,
Environmetrics, 5, 111–126, https://doi.org/10.1002/env.3170050203, 1994.
Pachon, J. E., Weber, R. J., Zhang, X., Mulholland, J. A., and Russell, A. G.:
Revising the use of potassium (K) in the source apportionment of PM2.5,
Atmos. Pollut. Res., 4, 14–21, https://doi.org/10.5094/APR.2013.002, 2013.
Peré-Trepat, E., Kim, E., Paatero, P., and Hopke, P. K.: Source apportionment
of time and size resolved ambient particulate matter measured with a
rotating DRUM impactor, Atmos. Environ., 41, 5921–5933,
https://doi.org/10.1016/j.atmosenv.2007.03.022, 2007.
Perrino, C., Catrambone, M., Dalla Torre, S., Rantica, E., Sargolini, T., and
Canepari, S.: Seasonal variations in the chemical composition of particulate
matter: a case study in the Po Valley. Part I: macro-components and mass
closure, Environ. Sci. Pollut. Res., 21, 3999–4009,
https://doi.org/10.1007/s11356-013-2067-1, 2014.
Perrone, M. G., Larsen, B. R., Ferrero, L., Sangiorgi, G., De Gennaro, G., Udisti,
R., Zangrando, R., Gambaro, A., and Bolzacchini, E.: Sources of high PM2.5
concentrations in Milan, Northern Italy: Molecular marker data and CMB
modelling, Sci. Total Environ., 414, 343–355,
https://doi.org/10.1016/j.scitotenv.2011.11.026, 2012.
Petzold, A., Ogren, J. A., Fiebig, M., Laj, P., Li, S.-M., Baltensperger, U., Holzer-Popp, T., Kinne, S., Pappalardo, G., Sugimoto, N., Wehrli, C., Wiedensohler, A., and Zhang, X.-Y.: Recommendations for reporting “black carbon” measurements, Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, 2013.
Piazzalunga, A., Fermo, P., Bernardoni, V., Vecchi, R., Valli, G., and De Gregorio,
M. A.: A simplified method for levoglucosan quantification in wintertime
atmospheric particulate matter by high performance anion-exchange
chromatography coupled with pulsed amperometric detection, Int. J. Environ.
Anal. Chem., 90, 934–947, https://doi.org/10.1080/03067310903023619, 2010.
Piazzalunga, A., Bernardoni, V., Fermo, P., Valli, G., and Vecchi, R.: Technical Note: On the effect of water-soluble compounds removal on EC quantification by TOT analysis in urban aerosol samples, Atmos. Chem. Phys., 11, 10193–10203, https://doi.org/10.5194/acp-11-10193-2011, 2011.
Piazzalunga, A., Bernardoni, V., Fermo, P., and Vecchi, R.: Optimisation of
analytical procedures for the quantification of ionic and carbonaceous
fractions in the atmospheric aerosol and application to ambient samples,
Anal. Bioanal. Chem., 405, 1123–1132,
https://doi.org/10.1007/s00216-012-6433-5, 2013.
Polissar, A., Hopke, P. K., Paatero, P., Malm, W. C., and Sisler, J. F.: Atmospheric
aerosol over Alaska: elemental composition and sources, J. Geophys. Res.,
103, 19045–19057, https://doi.org/10.1029/98JD01212, 1998.
Pope III, C. A. and Dockery, D. W.: Health effects of fine particulate air
pollution: lines that connect, J. Air Waste Manage., 56, 709–742,
https://doi.org/10.1080/10473289.2006.10464485, 2006.
R Core Team: R: A language and environment for statistical computing. R
Foundation for Statistical Computing, Vienna, Austria, available at: http://www.R-project.org (last access: 7 January 2019), 2019.
Robinson, A. L., Donahue, N. M., and Rogge, W. F.: Photochemical oxidation and
changes in molecular composition of organic aerosol in the regional context,
J. Geophys. Res., 111, D03302, https://doi.org/10.1029/2005JD006265, 2006.
Rolph, G., Stein, A., and Stunder, B.: Real-time Environmental Application and
Display sYstem: READY, Environ. Modell. Softw., 95, 210–228,
https://doi.org/10.1016/j.envsoft.2017.06.025, 2017.
Sandradewi, J., Prévôt, A. S. H., Szidat, S., Perron, N., Alfarra, M. R.,
Lanz, V. A., Weingartner, E., and Balternsperger, U.: Using aerosol light
absorption measurements for the quantitative determination of wood burning
and traffic emission contributions to particulate matter, Environ. Sci.
Technol., 42, 3316–3323, https://doi.org/10.1021/es702253m, 2008a.
Sandradewi, J., Prévôt, A. S. H., Weingartner, E., Schmidhauser, R., Gysel,
M., and Balternsperger, U.: A study of wood burning and traffic aerosols in an
Alpine valley using a multi-wavelength Aethalometer, Atmos. Environ., 2,
101–112, https://doi.org/10.1016/j.atmosenv.2007.09.034, 2008b.
Schnaiter, M., Horvath, H., Möhler, O., Naumann, K.-H., Saathoff, H., and
Schöck, O. W.: UV-VIS-NIR spectral optical properties of soot and
soot-containing aerosols, J. Aerosol Sci., 34, 1421–1444,
https://doi.org/10.1016/S0021-8502(03)00361-6, 2003.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from air
pollution to climate change, 2nd edition, John Wiley & Sons, INC,
Hoboken, New Jersey, 2006.
Simoneit, B. R. T., Schauer, J. J., Nolte, C. G., Oros, D. R., Elias, V., O., Fraser, M. P., Rogge, D. F., and Cass, G. R.: Levoglucosan, a tracer for cellulose in biomass burning
atmospheric particles, Atmos. Environ., 33, 173–182,
https://doi.org/10.1016/S1352-2310(98)00145-9, 1999.
Sofowote, U. M., Healy, R. M., Su, Y., Debosz, J., Noble, M., Munoz, A., Jeong,
C.-H., Wang, J. M., Hilker, N., Evans, G. J., and Hopke, P. K.: Understanding the
PM2.5 imbalance between a far and near-road location: Results of high
temporal frequency source apportionment and parameterization of black
carbon, Atmos. Environ., 173, 277–288,
https://doi.org/10.1016/j.atmosenv.2017.10.063, 2018.
Stein, A. F., Draxler, R. R., Rolph, G. D., Stunder, B. J. B., Cohen, M. D., and Ngan,
F.: NOAA's Hysplit atmospheric transport and dispersion modeling system,
B. Am. Meteorol. Soc., 96, 2059–2077,
https://doi.org/10.1175/BAMS-D-14-00110.1, 2015.
Thorpe, A. and Harrison, R. M.: Sources and properties of non-exhaust
particulate matter from road traffic: A review, Sci. Total Environ., 400,
270–282, https://doi.org/10.1016/j.scitotenv.2008.06.007, 2008.
Vecchi, R., Marcazzan, G., Valli, G., Ceriani, M., and Antoniazzi, C.: The role of
atmospheric dispersion in the seasonal variation of PM1 and PM2.5
concentration and composition in the urban area of Milan (Italy), Atmos.
Environ., 38, 4437–4446, https://doi.org/10.1016/j.atmosenv.2004.05.029,
2004.
Vecchi, R., Marcazzan, G., and Valli, G.: A study on nighttime-daytime PM10
concentration and elemental composition in relation to atmospheric
dispersion in the urban area of Milan (Italy), Atmos. Environ., 41,
2136–2144, https://doi.org/10.1016/j.atmosenv.2006.10.069, 2007.
Vecchi, R., Bernardoni, V., Fermo, P., Lucarelli, F., Mazzei, F., Nava, S., Prati,
P., Piazzalunga, A., and Valli, G.: 4-hours resolution data to study PM10 in a
“hot spot” area in Europe, Environ. Monit. Assess., 154, 283–300,
https://doi.org/10.1007/s10661-008-0396-1, 2009.
Vecchi, R., Bernardoni, V., Paganelli, C., and Valli, G.: A filter-based light
absorption measurement with polar photometer: effects of sampling artefacts
from organic carbon, J. Aerosol. Sci., 70, 15–25,
https://doi.org/10.1016/j.jaerosci.2013.12.012, 2014.
Vecchi, R., Bernardoni, V., Valentini, S., Piazzalunga, A., Fermo, P., and Valli,
G.: Assessment of light extinction at a European polluted urban area during
wintertime: Impact of PM1 composition and sources, Environ. Pollut., 233,
679–689, https://doi.org/10.1016/j.envpol.2017.10.059, 2018.
Vecchi, R., Piziali, F. A., Valli, G., Favaron, M., and Bernardoni, V.: Radon-based
estimates of equivalent mixing layer heights: A long-term assessment, Atmos.
Environ., 197, 150–158, https://doi.org/10.1016/j.atmosenv.2018.10.020,
2019.
Viana, M., Kuhlbusch, T. A. J., Querol, X., Alastuey, A., Harrison, R. M., Hopke,
P. K., Winiwarter, W., Vallius, M., Szidat, S., Prévôt, A. S. H., Hueglin,
C., Bloemen, H., Wåhlin, P., Vecchi, R., Miranda, A. I., Kasper-Giebl, A.,
Maenhaut, W., and Hitzenberger, R.: Source apportionment of particulate matter
in Europe: A review of methods and results, J. Aerosol Sci., 39, 827–849,
https://doi.org/10.1016/j.jaerosci.2008.05.007, 2008.
Wang, Y., Hopke, P. K., Rattigan, O. V., Xia, X., Chalupa, D. C., and Utell, M. J.:
Characterization of residential wood combustion particles using the
two-wavelenght aethalometer, Environ. Sci. Technol., 45, 7387–7393,
https://doi.org/10.1021/es2013984, 2011.
Wang, Y., Hopke, P. K., Rattigan, O. V., Chalupa, D. C., and Utell, M. J.:
Multiple-year black carbon measurements and source apportionment using
Delta-C in Rochester, New York, J. Air Waste Manage., 62, 8, 880–887,
https://doi.org/10.1080/10962247.2012.671792, 2012.
Watson, J. G.: Visibility: Science and Regulation, J. Air Waste Manage., 52,
628–713, https://doi.org/10.1080/10473289.2002.10470813, 2002.
Xie, M., Chen, X., Holder, A. L., Hays, M. D., Lewandowski, M., Offenberg, J. H.,
Kleindienst, T. E., Jaoui, M., and Hannigan, M. P.: Light absorption of organic
carbon and its sources at a southeastern U.S. location in summer, Environ.
Pollut., 244, 38–46, https://doi.org/10.1016/j.envpol.2018.09.125, 2019.
Yang, M., Howell, S. G., Zhuang, J., and Huebert, B. J.: Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE, Atmos. Chem. Phys., 9, 2035–2050, https://doi.org/10.5194/acp-9-2035-2009, 2009.
Zhou, L., Hopke, P. K., Paatero, P., Ondov, J. M., Pancras, J. P., Pekney, N. J., and
Davidson, C. I.: Advanced factor analysis for multiple time resolution aerosol
composition data, Atmos. Environ., 38, 4909–4920,
https://doi.org/10.1016/j.atmosenv.2004.05.040, 2004.
Zotter, P., Herich, H., Gysel, M., El-Haddad, I., Zhang, Y., Močnik, G., Hüglin, C., Baltensperger, U., Szidat, S., and Prévôt, A. S. H.: Evaluation of the absorption Ångström exponents for traffic and wood burning in the Aethalometer-based source apportionment using radiocarbon measurements of ambient aerosol, Atmos. Chem. Phys., 17, 4229–4249, https://doi.org/10.5194/acp-17-4229-2017, 2017.
Short summary
A new approach coupling aerosol chemical and optical properties in one source apportionment study is proposed. Besides a more robust identification of sources, it was possible to retrieve a source-specific absorption Ångström exponent and a mass absorption cross section at different wavelengths as well as optical apportionment. This piece of information can be very useful for formulating strategies for pollutant abatement to improve air quality and to face climate challenges.
A new approach coupling aerosol chemical and optical properties in one source apportionment...
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