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Volume 16, issue 18
Atmos. Chem. Phys., 16, 11601–11615, 2016
https://doi.org/10.5194/acp-16-11601-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 11601–11615, 2016
https://doi.org/10.5194/acp-16-11601-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 20 Sep 2016

Research article | 20 Sep 2016

The influence of temperature on ozone production under varying NOx conditions – a modelling study

Jane Coates et al.

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Cited articles

Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. Environ., 34, 2063–2101, 2000.
Atkinson, R., Aschmann, S. M., and Winer, A. M.: Alkyl nitrate formation from the reaction of a series of branched RO2 radicals with NO as a function of temperature and pressure, J. Atmos. Chem., 5, 91–102, 1987.
Baertsch-Ritter, N., Keller, J., Dommen, J., and Prevot, A. S. H.: Effects of various meteorological conditions and spatial emissionresolutions on the ozone concentration and ROG/NOx limitationin the Milan area (I), Atmos. Chem. Phys., 4, 423–438, https://doi.org/10.5194/acp-4-423-2004, 2004.
Bonn, B., von Schneidemesser, E., Andrich, D., Quedenau, J., Gerwig, H., Lüdecke, A., Kura, J., Pietsch, A., Ehlers, C., Klemp, D., Kofahl, C., Nothard, R., Kerschbaumer, A., Junkermann, W., Grote, R., Pohl, T., Weber, K., Lode, B., Schönberger, P., Churkina, G., Butler, T. M., and Lawrence, M. G.: BAERLIN2014 – the influence of land surface types on and the horizontal heterogeneity of air pollutant levels in Berlin, Atmos. Chem. Phys., 16, 7785–7811, https://doi.org/10.5194/acp-16-7785-2016, 2016.
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This modelling study reproduced the non-linear relationship of ozone, NOx and temperature using various chemical mechanisms previously determined from observational studies. Under urban conditions, faster reaction rates rather than increased isoprene emissions led to a slightly greater increase of ozone with temperature using different NOx conditions. This study also shows that the increase of ozone with temperature is more sensitive to atmospheric mixing than the choice of chemical mechanism.
This modelling study reproduced the non-linear relationship of ozone, NOx and temperature using...
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