Articles | Volume 13, issue 22
Research article
21 Nov 2013
Research article |  | 21 Nov 2013

A theoretical model on the formation mechanism and kinetics of highly toxic air pollutants from halogenated formaldehydes reacted with halogen atoms

Y. M. Ji, H. H. Wang, Y. P. Gao, G. Y. Li, and T. C. An

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This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Cited articles

Bednarek, G., Breil, M., Hoffmann, A., Kohlmann, J. P., Mors, V., and Zellner, R.: Rate and mechanism of the atmospheric degradation of 1,1,1,2-tetrafluoroethane (HFC-134a), Ber. Bunsen. Phys. Chem., 100, 528–539, 1996.
Behr, P., Goldbach, K., and Heydtmann, H.: The reaction of fuorine atoms with formyl fluoride and the CFO self-reaction at 293 K, Int. J. Chem. Kinet., 25, 957–967, 1993.
Behr, P., Kaupert, C., Shafranovski, E., and Heydtmann, H.: Temperature dependence of the gas-phase reactions F + CHFO, CFO + F, and CFO + CFO, Int. J. Chem. Kinet., 30, 329–333, 1998.
Beukes, J. A., D'Anna, B., Bakken, V., and Nielsen, C. J.: Experimental and theoretical study of the F, Cl and Br reactions with formaldehyde and acetaldehyde, Phys. Chem. Chem. Phys., 2, 4049–4060, 2000.
Blotevogel, J., Borch, T., Desyaterik, Y., Mayeno, A. N., and Sale, T. C.: Quantum Chemical Prediction of Redox Reactivity and Degradation Pathways for Aqueous Phase Contaminants: An Example with HMPA, Environ. Sci. Technol., 44, 5868–5874, 2010.
Final-revised paper