Articles | Volume 13, issue 22
https://doi.org/10.5194/acp-13-11277-2013
https://doi.org/10.5194/acp-13-11277-2013
Research article
 | 
21 Nov 2013
Research article |  | 21 Nov 2013

A theoretical model on the formation mechanism and kinetics of highly toxic air pollutants from halogenated formaldehydes reacted with halogen atoms

Y. M. Ji, H. H. Wang, Y. P. Gao, G. Y. Li, and T. C. An

Related authors

Cooling radiative forcing effect enhancement of atmospheric amines-mineral particle caused by heterogeneous uptake and oxidation
Weina Zhang, Jianhua Mai, Zhichao Fan, Yongpeng Ji, Yuemeng Ji, Guiying Li, Yanpeng Gao, and Taicheng An
EGUsphere, https://doi.org/10.5194/egusphere-2024-1048,https://doi.org/10.5194/egusphere-2024-1048, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary

Related subject area

Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles
Qindan Zhu, Rebecca H. Schwantes, Matthew Coggon, Colin Harkins, Jordan Schnell, Jian He, Havala O. T. Pye, Meng Li, Barry Baker, Zachary Moon, Ravan Ahmadov, Eva Y. Pfannerstill, Bryan Place, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Anthony Bucholtz, John H. Seinfeld, Carsten Warneke, Chelsea E. Stockwell, Lu Xu, Kristen Zuraski, Michael A. Robinson, J. Andrew Neuman, Patrick R. Veres, Jeff Peischl, Steven S. Brown, Allen H. Goldstein, Ronald C. Cohen, and Brian C. McDonald
Atmos. Chem. Phys., 24, 5265–5286, https://doi.org/10.5194/acp-24-5265-2024,https://doi.org/10.5194/acp-24-5265-2024, 2024
Short summary
High-resolution US methane emissions inferred from an inversion of 2019 TROPOMI satellite data: contributions from individual states, urban areas, and landfills
Hannah Nesser, Daniel J. Jacob, Joannes D. Maasakkers, Alba Lorente, Zichong Chen, Xiao Lu, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Margaux Winter, Shuang Ma, A. Anthony Bloom, John R. Worden, Robert N. Stavins, and Cynthia A. Randles
Atmos. Chem. Phys., 24, 5069–5091, https://doi.org/10.5194/acp-24-5069-2024,https://doi.org/10.5194/acp-24-5069-2024, 2024
Short summary
Summertime tropospheric ozone source apportionment study in the Madrid region (Spain)
David de la Paz, Rafael Borge, Juan Manuel de Andrés, Luis Tovar, Golam Sarwar, and Sergey L. Napelenok
Atmos. Chem. Phys., 24, 4949–4972, https://doi.org/10.5194/acp-24-4949-2024,https://doi.org/10.5194/acp-24-4949-2024, 2024
Short summary
CO anthropogenic emissions in Europe from 2011 to 2021: insights from Measurement of Pollution in the Troposphere (MOPITT) satellite data
Audrey Fortems-Cheiney, Gregoire Broquet, Elise Potier, Robin Plauchu, Antoine Berchet, Isabelle Pison, Hugo Denier van der Gon, and Stijn Dellaert
Atmos. Chem. Phys., 24, 4635–4649, https://doi.org/10.5194/acp-24-4635-2024,https://doi.org/10.5194/acp-24-4635-2024, 2024
Short summary
Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks
Amy Christiansen, Loretta J. Mickley, and Lu Hu
Atmos. Chem. Phys., 24, 4569–4589, https://doi.org/10.5194/acp-24-4569-2024,https://doi.org/10.5194/acp-24-4569-2024, 2024
Short summary

Cited articles

Bednarek, G., Breil, M., Hoffmann, A., Kohlmann, J. P., Mors, V., and Zellner, R.: Rate and mechanism of the atmospheric degradation of 1,1,1,2-tetrafluoroethane (HFC-134a), Ber. Bunsen. Phys. Chem., 100, 528–539, 1996.
Behr, P., Goldbach, K., and Heydtmann, H.: The reaction of fuorine atoms with formyl fluoride and the CFO self-reaction at 293 K, Int. J. Chem. Kinet., 25, 957–967, 1993.
Behr, P., Kaupert, C., Shafranovski, E., and Heydtmann, H.: Temperature dependence of the gas-phase reactions F + CHFO, CFO + F, and CFO + CFO, Int. J. Chem. Kinet., 30, 329–333, 1998.
Beukes, J. A., D'Anna, B., Bakken, V., and Nielsen, C. J.: Experimental and theoretical study of the F, Cl and Br reactions with formaldehyde and acetaldehyde, Phys. Chem. Chem. Phys., 2, 4049–4060, 2000.
Blotevogel, J., Borch, T., Desyaterik, Y., Mayeno, A. N., and Sale, T. C.: Quantum Chemical Prediction of Redox Reactivity and Degradation Pathways for Aqueous Phase Contaminants: An Example with HMPA, Environ. Sci. Technol., 44, 5868–5874, 2010.
Download
Altmetrics
Final-revised paper
Preprint