Articles | Volume 11, issue 1
https://doi.org/10.5194/acp-11-77-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-11-77-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
05 Jan 2011
Research article |
| 05 Jan 2011
The Chemistry of Atmosphere-Forest Exchange (CAFE) Model – Part 1: Model description and characterization
G. M. Wolfe
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Department of Chemistry, University of Washington, Seattle, WA, USA
J. A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Related subject area
Subject: Biosphere Interactions | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Temporal and spatial variations in atmospheric unintentional PCB emissions in Chinese mainland from 1960 to 2019
Biogenic isoprene emissions, dry deposition velocity, and surface ozone concentration during summer droughts, heatwaves, and normal conditions in southwestern Europe
Satellite-derived constraints on the effect of drought stress on biogenic isoprene emissions in the southeastern US
Interactive biogenic emissions and drought stress effects on atmospheric composition in NASA GISS ModelE
Plant gross primary production, plant respiration and carbonyl sulfide emissions over the globe inferred by atmospheric inverse modelling
Evaluation of interactive and prescribed agricultural ammonia emissions for simulating atmospheric composition in CAM-chem
Responses of surface ozone to future agricultural ammonia emissions and subsequent nitrogen deposition through terrestrial ecosystem changes
Modelling the influence of biotic plant stress on atmospheric aerosol particle processes throughout a growing season
Examining the competing effects of contemporary land management vs. land cover changes on global air quality
Improved gridded ammonia emission inventory in China
The impact of nitrogen and sulfur emissions from shipping on the exceedance of critical loads in the Baltic Sea region
Indirect contributions of global fires to surface ozone through ozone–vegetation feedback
Global and regional impacts of land cover changes on isoprene emissions derived from spaceborne data and the MEGAN model
A long-term estimation of biogenic volatile organic compound (BVOC) emission in China from 2001–2016: the roles of land cover change and climate variability
The regional European atmospheric transport inversion comparison, EUROCOM: first results on European-wide terrestrial carbon fluxes for the period 2006–2015
Quantifying the effects of environmental factors on wildfire burned area in the south central US using integrated machine learning techniques
Effects of fertilization and stand age on N2O and NO emissions from tea plantations: a site-scale study in a subtropical region using a modified biogeochemical model
Temperature response measurements from eucalypts give insight into the impact of Australian isoprene emissions on air quality in 2050
Data assimilation using an ensemble of models: a hierarchical approach
Fundamentals of data assimilation applied to biogeochemistry
On what scales can GOSAT flux inversions constrain anomalies in terrestrial ecosystems?
Historical (1700–2012) global multi-model estimates of the fire emissions from the Fire Modeling Intercomparison Project (FireMIP)
Contrasting effects of CO2 fertilization, land-use change and warming on seasonal amplitude of Northern Hemisphere CO2 exchange
The 2015–2016 carbon cycle as seen from OCO-2 and the global in situ network
Representing sub-grid scale variations in nitrogen deposition associated with land use in a global Earth system model: implications for present and future nitrogen deposition fluxes over North America
Global climate forcing driven by altered BVOC fluxes from 1990 to 2010 land cover change in maritime Southeast Asia
Coupling between surface ozone and leaf area index in a chemical transport model: strength of feedback and implications for ozone air quality and vegetation health
Contrasting interannual atmospheric CO2 variabilities and their terrestrial mechanisms for two types of El Niños
Vegetation greenness and land carbon-flux anomalies associated with climate variations: a focus on the year 2015
Biomass burning at Cape Grim: exploring photochemistry using multi-scale modelling
Wildfire air pollution hazard during the 21st century
Ozone and haze pollution weakens net primary productivity in China
How can mountaintop CO2 observations be used to constrain regional carbon fluxes?
Effects of ozone–vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks
Impact of Siberian observations on the optimization of surface CO2 flux
Modelling bidirectional fluxes of methanol and acetaldehyde with the FORCAsT canopy exchange model
The impact of historical land use change from 1850 to 2000 on secondary particulate matter and ozone
Global biogenic volatile organic compound emissions in the ORCHIDEE and MEGAN models and sensitivity to key parameters
Impacts of current and projected oil palm plantation expansion on air quality over Southeast Asia
Current estimates of biogenic emissions from eucalypts uncertain for southeast Australia
Air quality impacts of European wildfire emissions in a changing climate
Validation of the Swiss methane emission inventory by atmospheric observations and inverse modelling
Land cover change impacts on atmospheric chemistry: simulating projected large-scale tree mortality in the United States
High-resolution ammonia emissions inventories in China from 1980 to 2012
Delivery of anthropogenic bioavailable iron from mineral dust and combustion aerosols to the ocean
Impact of future land-cover changes on HNO3 and O3 surface dry deposition
Impact of climate and land cover changes on tropospheric ozone air quality and public health in East Asia between 1980 and 2010
Relationships between photosynthesis and formaldehyde as a probe of isoprene emission
A modified micrometeorological gradient method for estimating O3 dry depositions over a forest canopy
Biomass burning related ozone damage on vegetation over the Amazon forest: a model sensitivity study
Ye Li, Ye Huang, Yunshan Zhang, Wei Du, Shanshan Zhang, Tianhao He, Yan Li, Yan Chen, Fangfang Ding, Lin Huang, Haibin Xia, Wenjun Meng, Min Liu, and Shu Tao
Atmos. Chem. Phys., 23, 1091–1101, https://doi.org/10.5194/acp-23-1091-2023, https://doi.org/10.5194/acp-23-1091-2023, 2023
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Polychlorinated biphenyls (PCBs) are typical persistent organic pollutants (POPs) listed among the 12 initial POPs that should be prohibited or limited under the Stockholm Convention. They are widely present in the environment and pose a threat to human health and ecosystems. Emission estimation for them is essential to understand and evaluate their environment fate and associated health effect. This work developed 12 dioxin-like UP-PCBs from 66 sources from 1960 to 2019 in China.
Antoine Guion, Solène Turquety, Arineh Cholakian, Jan Polcher, Antoine Ehret, and Juliette Lathière
Atmos. Chem. Phys., 23, 1043–1071, https://doi.org/10.5194/acp-23-1043-2023, https://doi.org/10.5194/acp-23-1043-2023, 2023
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At high concentrations, tropospheric ozone (O3) deteriorates air quality. Weather conditions are key to understanding the variability in O3 concentration, especially during extremes. We suggest that identifying the presence of combined heatwaves is essential to the study of droughts in canopy–troposphere interactions and O3 concentration. Even so, they are associated, on average, with an increase in O3, partly explained by an increase in precursor emissions and a decrease in dry deposition.
Yuxuan Wang, Nan Lin, Wei Li, Alex Guenther, Joey C. Y. Lam, Amos P. K. Tai, Mark J. Potosnak, and Roger Seco
Atmos. Chem. Phys., 22, 14189–14208, https://doi.org/10.5194/acp-22-14189-2022, https://doi.org/10.5194/acp-22-14189-2022, 2022
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Drought can cause large changes in biogenic isoprene emissions. In situ field observations of isoprene emissions during droughts are confined by spatial coverage and, thus, provide limited constraints. We derived a drought stress factor based on satellite HCHO data for MEGAN2.1 in the GEOS-Chem model using water stress and temperature. This factor reduces the overestimation of isoprene emissions during severe droughts and improves the simulated O3 and organic aerosol responses to droughts.
Elizabeth Klovenski, Yuxuan Wang, Susanne E. Bauer, Kostas Tsigaridis, Greg Faluvegi, Igor Aleinov, Nancy Y. Kiang, Alex Guenther, Xiaoyan Jiang, Wei Li, and Nan Lin
Atmos. Chem. Phys., 22, 13303–13323, https://doi.org/10.5194/acp-22-13303-2022, https://doi.org/10.5194/acp-22-13303-2022, 2022
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Severe drought stresses vegetation and causes reduced emission of isoprene. We study the impact of including a new isoprene drought stress (yd) parameterization in NASA GISS ModelE called DroughtStress_ModelE, which is specifically tuned for ModelE. Inclusion of yd leads to better simulated isoprene emissions at the MOFLUX site during the severe drought of 2012, reduced overestimation of OMI satellite ΩHCHO (formaldehyde column), and improved simulated O3 (ozone) during drought.
Marine Remaud, Frédéric Chevallier, Fabienne Maignan, Sauveur Belviso, Antoine Berchet, Alexandra Parouffe, Camille Abadie, Cédric Bacour, Sinikka Lennartz, and Philippe Peylin
Atmos. Chem. Phys., 22, 2525–2552, https://doi.org/10.5194/acp-22-2525-2022, https://doi.org/10.5194/acp-22-2525-2022, 2022
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Carbonyl sulfide (COS) has been recognized as a promising indicator of the plant gross primary production (GPP). Here, we assimilate both COS and CO2 measurements into an atmospheric transport model to obtain information on GPP, plant respiration and COS budget. A possible scenario for the period 2008–2019 leads to a global COS biospheric sink of 800 GgS yr−1 and higher oceanic emissions between 400 and 600 GgS yr−1.
Julius Vira, Peter Hess, Money Ossohou, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 22, 1883–1904, https://doi.org/10.5194/acp-22-1883-2022, https://doi.org/10.5194/acp-22-1883-2022, 2022
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Ammonia is one of the main components of nitrogen deposition. Here we use a new model to assess the ammonia emissions from agriculture, the largest anthropogenic source of ammonia. The model results are consistent with earlier estimates over industrialized regions in agreement with observations. However, the model predicts much higher emissions over sub-Saharan Africa compared to earlier estimates. Available observations from surface stations and satellites support these higher emissions.
Xueying Liu, Amos P. K. Tai, and Ka Ming Fung
Atmos. Chem. Phys., 21, 17743–17758, https://doi.org/10.5194/acp-21-17743-2021, https://doi.org/10.5194/acp-21-17743-2021, 2021
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With the rising food need, more intense agricultural activities will cause substantial perturbations to the nitrogen cycle, aggravating surface air pollution and imposing stress on terrestrial ecosystems. We studied how these ecosystem changes may modify biosphere–atmosphere exchanges, and further exert secondary effects on air quality, and demonstrated a link between agricultural activities and ozone air quality via the modulation of vegetation and soil biogeochemistry by nitrogen deposition.
Ditte Taipale, Veli-Matti Kerminen, Mikael Ehn, Markku Kulmala, and Ülo Niinemets
Atmos. Chem. Phys., 21, 17389–17431, https://doi.org/10.5194/acp-21-17389-2021, https://doi.org/10.5194/acp-21-17389-2021, 2021
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Larval feeding and fungal infections of leaves can greatly change the emission of volatile compounds from plants and thereby influence aerosol processes in the air. We developed a model that considers the dynamics of larvae and fungi and the dependency of the emission on the severity of stress. We show that the infections can be highly atmospherically relevant during long periods of time and at times more important to consider than the parameters that are currently used in emission models.
Anthony Y. H. Wong and Jeffrey A. Geddes
Atmos. Chem. Phys., 21, 16479–16497, https://doi.org/10.5194/acp-21-16479-2021, https://doi.org/10.5194/acp-21-16479-2021, 2021
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Land cover change and land management are considered to have important and distinct impacts on air quality. Here we use remote sensing products and agricultural emission inventories to characterize contemporary global land cover and land management changes for chemical transport model simulations. We find that contemporary land system change has a significant impact on global air quality, with land management dominating the effects on PM and land cover change dominating the impacts on ozone.
Baojie Li, Lei Chen, Weishou Shen, Jianbing Jin, Teng Wang, Pinya Wang, Yang Yang, and Hong Liao
Atmos. Chem. Phys., 21, 15883–15900, https://doi.org/10.5194/acp-21-15883-2021, https://doi.org/10.5194/acp-21-15883-2021, 2021
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This study focused on improving fertilizer-application-related NH3 emission inventories. We comprehensively evaluated the dates and times of fertilizer application to the major crops in China, improved the spatial allocation methods for NH3 emissions from croplands with different rice types, and established a NH3 emission inventory for mainland China in 2016. The inventory showed a higher level of accuracy than other inventories based on evaluation using the WRF-Chem and observation data.
Sara Jutterström, Filip Moldan, Jana Moldanová, Matthias Karl, Volker Matthias, and Maximilian Posch
Atmos. Chem. Phys., 21, 15827–15845, https://doi.org/10.5194/acp-21-15827-2021, https://doi.org/10.5194/acp-21-15827-2021, 2021
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For the Baltic Sea countries, shipping emissions are an important source of air pollution. This study investigates the contribution of shipping emissions to the acidification and eutrophication of soils and freshwater within the airshed of the Baltic Sea in the years 2012 and 2040. The implementation of emission control areas and improving energy efficiency significantly reduces the negative impact on ecosystems expressed as a decrease in the exceedance of critical loads for sulfur and nitrogen.
Yadong Lei, Xu Yue, Hong Liao, Lin Zhang, Yang Yang, Hao Zhou, Chenguang Tian, Cheng Gong, Yimian Ma, Lan Gao, and Yang Cao
Atmos. Chem. Phys., 21, 11531–11543, https://doi.org/10.5194/acp-21-11531-2021, https://doi.org/10.5194/acp-21-11531-2021, 2021
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We present the first estimate of ozone enhancement by fire emissions through ozone–vegetation interactions using a fully coupled chemistry–vegetation model (GC-YIBs). In fire-prone areas, fire-induced ozone causes a positive feedback to surface ozone mainly because of the inhibition effects on stomatal conductance.
Beata Opacka, Jean-François Müller, Trissevgeni Stavrakou, Maite Bauwens, Katerina Sindelarova, Jana Markova, and Alex B. Guenther
Atmos. Chem. Phys., 21, 8413–8436, https://doi.org/10.5194/acp-21-8413-2021, https://doi.org/10.5194/acp-21-8413-2021, 2021
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Isoprene is mainly emitted from plants, and about 80 % of its global emissions occur in the tropics. Current isoprene inventories are usually based on modelled vegetation maps, but high pressure on land use over the last decades has led to severe losses, especially in tropical forests, that are not considered by models. We provide a study on the present-day impact of spaceborne land cover changes on isoprene emissions and the first inventory based on high-resolution Landsat tree cover dataset.
Hui Wang, Qizhong Wu, Alex B. Guenther, Xiaochun Yang, Lanning Wang, Tang Xiao, Jie Li, Jinming Feng, Qi Xu, and Huaqiong Cheng
Atmos. Chem. Phys., 21, 4825–4848, https://doi.org/10.5194/acp-21-4825-2021, https://doi.org/10.5194/acp-21-4825-2021, 2021
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We assessed the influence of the greening trend on BVOC emission in China. The comparison among different scenarios showed that vegetation changes resulting from land cover management are the main driver of BVOC emission change in China. Climate variability contributed significantly to interannual variations but not much to the long-term trend during the study period.
Guillaume Monteil, Grégoire Broquet, Marko Scholze, Matthew Lang, Ute Karstens, Christoph Gerbig, Frank-Thomas Koch, Naomi E. Smith, Rona L. Thompson, Ingrid T. Luijkx, Emily White, Antoon Meesters, Philippe Ciais, Anita L. Ganesan, Alistair Manning, Michael Mischurow, Wouter Peters, Philippe Peylin, Jerôme Tarniewicz, Matt Rigby, Christian Rödenbeck, Alex Vermeulen, and Evie M. Walton
Atmos. Chem. Phys., 20, 12063–12091, https://doi.org/10.5194/acp-20-12063-2020, https://doi.org/10.5194/acp-20-12063-2020, 2020
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The paper presents the first results from the EUROCOM project, a regional atmospheric inversion intercomparison exercise involving six European research groups. It aims to produce an estimate of the net carbon flux between the European terrestrial ecosystems and the atmosphere for the period 2006–2015, based on constraints provided by observed CO2 concentrations and using inverse modelling techniques. The use of six different models enables us to investigate the robustness of the results.
Sally S.-C. Wang and Yuxuan Wang
Atmos. Chem. Phys., 20, 11065–11087, https://doi.org/10.5194/acp-20-11065-2020, https://doi.org/10.5194/acp-20-11065-2020, 2020
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A model consisting of multiple machine learning algorithms is developed to predict wildfire burned area over the south central US and explains key environmental drivers. The developed model alleviates the issue of unevenly distributed data and predicts burned grids and burned areas with good accuracy. The model reveals climate variability such as relative humidity anomalies and antecedent drought severity contributes the most to the total burned area for winter–spring and summer fire season.
Wei Zhang, Zhisheng Yao, Xunhua Zheng, Chunyan Liu, Rui Wang, Kai Wang, Siqi Li, Shenghui Han, Qiang Zuo, and Jianchu Shi
Atmos. Chem. Phys., 20, 6903–6919, https://doi.org/10.5194/acp-20-6903-2020, https://doi.org/10.5194/acp-20-6903-2020, 2020
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The CNMM-DNDC model was modified by improving the scientific processes of soil pH reduction due to tea growth and performed well in simulating emissions of nitrous oxide and nitric oxide. Effects of manure fertilization and stand ages on emissions of both gases were well simulated. Simulated annual emission factors correlate positively with urea or manure doses. The overall inhibitory effects on the gases' emissions in the middle to late stages during a full tea plant lifetime were simulated.
Kathryn M. Emmerson, Malcolm Possell, Michael J. Aspinwall, Sebastian Pfautsch, and Mark G. Tjoelker
Atmos. Chem. Phys., 20, 6193–6206, https://doi.org/10.5194/acp-20-6193-2020, https://doi.org/10.5194/acp-20-6193-2020, 2020
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Australian cities with a high biogenic influence will see higher pollution levels in a warmer climate. We show that four Eucalyptus species grown in future-climate conditions can emit isoprene at temperatures 9 K above the peak temperatures capping isoprene in biogenic-emission models. With these measurements, we predict up to 2 ppb increases in isoprene in 2050, causing up to 21 ppb of ozone and 0.4 µg m−3 of aerosol in Sydney. The ozone increase is one-fifth of the hourly air quality limit.
Peter Rayner
Atmos. Chem. Phys., 20, 3725–3737, https://doi.org/10.5194/acp-20-3725-2020, https://doi.org/10.5194/acp-20-3725-2020, 2020
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This work extends previous calculations of carbon dioxide sources and sinks to take account of the varying quality of atmospheric models. It uses an extended version of Bayesian statistics which includes the model as one of the unknowns. I performed the work as an example of including the model in the description of the uncertainty.
Peter J. Rayner, Anna M. Michalak, and Frédéric Chevallier
Atmos. Chem. Phys., 19, 13911–13932, https://doi.org/10.5194/acp-19-13911-2019, https://doi.org/10.5194/acp-19-13911-2019, 2019
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This paper describes the methods for combining models and data to understand how nutrients and pollutants move through natural systems. The methods are analogous to the process of weather forecasting in which previous information is combined with new observations and a model to improve our knowledge of the internal state of the physical system. The methods appear highly diverse but the paper shows that they are all examples of a single underlying formalism.
Brendan Byrne, Dylan B. A. Jones, Kimberly Strong, Saroja M. Polavarapu, Anna B. Harper, David F. Baker, and Shamil Maksyutov
Atmos. Chem. Phys., 19, 13017–13035, https://doi.org/10.5194/acp-19-13017-2019, https://doi.org/10.5194/acp-19-13017-2019, 2019
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Interannual variations in net ecosystem exchange (NEE) estimated from the Greenhouse Gases Observing Satellite (GOSAT) XCO2 measurements are shown to be correlated (P < 0.05) with temperature and FLUXCOM NEE anomalies. Furthermore, the GOSAT-informed NEE anomalies are found to be better correlated with temperature and FLUXCOM anomalies than NEE estimates from most terrestrial biosphere models, suggesting that GOSAT CO2 measurements provide a useful constraint on NEE interannual variability.
Fang Li, Maria Val Martin, Meinrat O. Andreae, Almut Arneth, Stijn Hantson, Johannes W. Kaiser, Gitta Lasslop, Chao Yue, Dominique Bachelet, Matthew Forrest, Erik Kluzek, Xiaohong Liu, Stephane Mangeon, Joe R. Melton, Daniel S. Ward, Anton Darmenov, Thomas Hickler, Charles Ichoku, Brian I. Magi, Stephen Sitch, Guido R. van der Werf, Christine Wiedinmyer, and Sam S. Rabin
Atmos. Chem. Phys., 19, 12545–12567, https://doi.org/10.5194/acp-19-12545-2019, https://doi.org/10.5194/acp-19-12545-2019, 2019
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Fire emissions are critical for atmospheric composition, climate, carbon cycle, and air quality. We provide the first global multi-model fire emission reconstructions for 1700–2012, including carbon and 33 species of trace gases and aerosols, based on the nine state-of-the-art global fire models that participated in FireMIP. We also provide information on the recent status and limitations of the model-based reconstructions and identify the main uncertainty sources in their long-term changes.
Ana Bastos, Philippe Ciais, Frédéric Chevallier, Christian Rödenbeck, Ashley P. Ballantyne, Fabienne Maignan, Yi Yin, Marcos Fernández-Martínez, Pierre Friedlingstein, Josep Peñuelas, Shilong L. Piao, Stephen Sitch, William K. Smith, Xuhui Wang, Zaichun Zhu, Vanessa Haverd, Etsushi Kato, Atul K. Jain, Sebastian Lienert, Danica Lombardozzi, Julia E. M. S. Nabel, Philippe Peylin, Benjamin Poulter, and Dan Zhu
Atmos. Chem. Phys., 19, 12361–12375, https://doi.org/10.5194/acp-19-12361-2019, https://doi.org/10.5194/acp-19-12361-2019, 2019
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Here we show that land-surface models improved their ability to simulate the increase in the amplitude of seasonal CO2-cycle exchange (SCANBP) by ecosystems compared to estimates by two atmospheric inversions. We find a dominant role of vegetation growth over boreal Eurasia to the observed increase in SCANBP, strongly driven by CO2 fertilization, and an overall negative effect of temperature on SCANBP. Biases can be explained by the sensitivity of simulated microbial respiration to temperature.
Sean Crowell, David Baker, Andrew Schuh, Sourish Basu, Andrew R. Jacobson, Frederic Chevallier, Junjie Liu, Feng Deng, Liang Feng, Kathryn McKain, Abhishek Chatterjee, John B. Miller, Britton B. Stephens, Annmarie Eldering, David Crisp, David Schimel, Ray Nassar, Christopher W. O'Dell, Tomohiro Oda, Colm Sweeney, Paul I. Palmer, and Dylan B. A. Jones
Atmos. Chem. Phys., 19, 9797–9831, https://doi.org/10.5194/acp-19-9797-2019, https://doi.org/10.5194/acp-19-9797-2019, 2019
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Space-based retrievals of carbon dioxide offer the potential to provide dense data in regions that are sparsely observed by the surface network. We find that flux estimates that are informed by the Orbiting Carbon Observatory-2 (OCO-2) show different character from that inferred using surface measurements in tropical land regions, particularly in Africa, with a much larger total emission and larger amplitude seasonal cycle.
Fabien Paulot, Sergey Malyshev, Tran Nguyen, John D. Crounse, Elena Shevliakova, and Larry W. Horowitz
Atmos. Chem. Phys., 18, 17963–17978, https://doi.org/10.5194/acp-18-17963-2018, https://doi.org/10.5194/acp-18-17963-2018, 2018
Kandice L. Harper and Nadine Unger
Atmos. Chem. Phys., 18, 16931–16952, https://doi.org/10.5194/acp-18-16931-2018, https://doi.org/10.5194/acp-18-16931-2018, 2018
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Chemistry–climate modeling finds that the induced global-mean ozone forcing for 1990–2010 maritime Southeast Asian land cover change, including expansion of high-isoprene-emitting oil palm plantations, is +9.2 mW m−2. Regional land cover change drove stronger global-mean ozone enhancements in the upper troposphere than in the lower troposphere. The results indicate that this mechanism of ozone forcing may increase in importance in future years if regional oil palm expansion continues unabated.
Shan S. Zhou, Amos P. K. Tai, Shihan Sun, Mehliyar Sadiq, Colette L. Heald, and Jeffrey A. Geddes
Atmos. Chem. Phys., 18, 14133–14148, https://doi.org/10.5194/acp-18-14133-2018, https://doi.org/10.5194/acp-18-14133-2018, 2018
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Surface ozone pollution harms vegetation. As plants play key roles shaping air quality, the plant damage may further worsen air pollution. We use various computer models to examine such feedback effects, and find that ozone-induced decline in leaf density can lead to much higher ozone levels in forested regions, mostly due to the reduced ability of leaves to absorb pollutants. This study highlights the importance of considering the two-way interactions between plants and air pollution.
Jun Wang, Ning Zeng, Meirong Wang, Fei Jiang, Jingming Chen, Pierre Friedlingstein, Atul K. Jain, Ziqiang Jiang, Weimin Ju, Sebastian Lienert, Julia Nabel, Stephen Sitch, Nicolas Viovy, Hengmao Wang, and Andrew J. Wiltshire
Atmos. Chem. Phys., 18, 10333–10345, https://doi.org/10.5194/acp-18-10333-2018, https://doi.org/10.5194/acp-18-10333-2018, 2018
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Based on the Mauna Loa CO2 records and TRENDY multi-model historical simulations, we investigate the different impacts of EP and CP El Niños on interannual carbon cycle variability. Composite analysis indicates that the evolutions of CO2 growth rate anomalies have three clear differences in terms of precursors (negative and neutral), amplitudes (strong and weak), and durations of peak (Dec–Apr and Oct–Jan) during EP and CP El Niños, respectively. We further discuss their terrestrial mechanisms.
Chao Yue, Philippe Ciais, Ana Bastos, Frederic Chevallier, Yi Yin, Christian Rödenbeck, and Taejin Park
Atmos. Chem. Phys., 17, 13903–13919, https://doi.org/10.5194/acp-17-13903-2017, https://doi.org/10.5194/acp-17-13903-2017, 2017
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The year 2015 appeared as a paradox regarding how global carbon cycle has responded to climate variation: it is the greenest year since 2000 according to satellite observation, but the atmospheric CO2 growth rate is also the highest since 1959. We found that this is due to a only moderate land carbon sink, because high growing-season sink in northern lands has been partly offset by autumn and winter release and the late-year El Niño has led to an abrupt transition to land source in the tropics.
Sarah J. Lawson, Martin Cope, Sunhee Lee, Ian E. Galbally, Zoran Ristovski, and Melita D. Keywood
Atmos. Chem. Phys., 17, 11707–11726, https://doi.org/10.5194/acp-17-11707-2017, https://doi.org/10.5194/acp-17-11707-2017, 2017
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A high-resolution chemical transport model was used to reproduce observed smoke plumes. The model output was highly sensitive to fire emission factors and meteorology, particularly for secondary pollutant ozone. Aged urban air (age = 2 days) was the major source of ozone observed, with minor contributions from the fire. This work highlights the importance of assessing model sensitivity and the use of modelling to determine the contribution from different sources to atmospheric composition.
Wolfgang Knorr, Frank Dentener, Jean-François Lamarque, Leiwen Jiang, and Almut Arneth
Atmos. Chem. Phys., 17, 9223–9236, https://doi.org/10.5194/acp-17-9223-2017, https://doi.org/10.5194/acp-17-9223-2017, 2017
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Wildfires cause considerable air pollution, and climate change is usually expected to increase both wildfire activity and air pollution from those fires. This study takes a closer look at the problem by examining the role of demographic changes in addition to climate change. It finds that demographics will be the main driver of changes in wildfire activity in many parts of the developing world. Air pollution from wildfires will remain significant, with major implications for air quality policy.
Xu Yue, Nadine Unger, Kandice Harper, Xiangao Xia, Hong Liao, Tong Zhu, Jingfeng Xiao, Zhaozhong Feng, and Jing Li
Atmos. Chem. Phys., 17, 6073–6089, https://doi.org/10.5194/acp-17-6073-2017, https://doi.org/10.5194/acp-17-6073-2017, 2017
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While it is widely recognized that air pollutants adversely affect human health and climate change, their impacts on the regional carbon balance are less well understood. We apply an Earth system model to quantify the combined effects of ozone and aerosol particles on net primary production in China. Ozone vegetation damage dominates over the aerosol effects, leading to a substantial net suppression of land carbon uptake in the present and future worlds.
John C. Lin, Derek V. Mallia, Dien Wu, and Britton B. Stephens
Atmos. Chem. Phys., 17, 5561–5581, https://doi.org/10.5194/acp-17-5561-2017, https://doi.org/10.5194/acp-17-5561-2017, 2017
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Mountainous areas can potentially serve as regions where the key greenhouse gas, carbon dioxide (CO2), can be absorbed from the atmosphere by vegetation, through photosynthesis. Variations in atmospheric CO2 can be used to understand the amount of biospheric fluxes in general. However, CO2 measured in mountains can be difficult to interpret due to the impact from complex atmospheric flows. We show how mountaintop CO2 data can be interpreted by carrying out a series of atmospheric simulations.
Mehliyar Sadiq, Amos P. K. Tai, Danica Lombardozzi, and Maria Val Martin
Atmos. Chem. Phys., 17, 3055–3066, https://doi.org/10.5194/acp-17-3055-2017, https://doi.org/10.5194/acp-17-3055-2017, 2017
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Surface ozone harms vegetation, which can influence not only climate but also ozone air quality itself. We implement a scheme for ozone damage on vegetation into an Earth system model, so that for the first time simulated vegetation and ozone can coevolve in a fully coupled simulation. With ozone–vegetation coupling, simulated ozone is found to be significantly higher by up to 6 ppbv. Reduced dry deposition and enhanced isoprene emission contribute to most of these increases.
Jinwoong Kim, Hyun Mee Kim, Chun-Ho Cho, Kyung-On Boo, Andrew R. Jacobson, Motoki Sasakawa, Toshinobu Machida, Mikhail Arshinov, and Nikolay Fedoseev
Atmos. Chem. Phys., 17, 2881–2899, https://doi.org/10.5194/acp-17-2881-2017, https://doi.org/10.5194/acp-17-2881-2017, 2017
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To investigate the effect of CO2 observations in Siberia on the surface CO2 flux analyses, two experiments using observation data sets with and without Siberian measurements were performed. While the magnitude of the optimized surface CO2 flux uptake in Siberia decreased, that in the other regions of the Northern Hemisphere increased for the experiment with Siberian observations. It is expected that the Siberian observations play an important role in estimating surface CO2 flux in the future.
Kirsti Ashworth, Serena H. Chung, Karena A. McKinney, Ying Liu, J. William Munger, Scot T. Martin, and Allison L. Steiner
Atmos. Chem. Phys., 16, 15461–15484, https://doi.org/10.5194/acp-16-15461-2016, https://doi.org/10.5194/acp-16-15461-2016, 2016
Colette L. Heald and Jeffrey A. Geddes
Atmos. Chem. Phys., 16, 14997–15010, https://doi.org/10.5194/acp-16-14997-2016, https://doi.org/10.5194/acp-16-14997-2016, 2016
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Humans have altered the surface of the Earth since preindustrial times. These changes (largely expansion of croplands and pasturelands) have modified biosphere–atmosphere fluxes. In this study we use a global model to assess the impact of these changes on the formation of secondary particulate matter and troposphere ozone. We find that there are significant air quality and climate impacts associated with these changes.
Palmira Messina, Juliette Lathière, Katerina Sindelarova, Nicolas Vuichard, Claire Granier, Josefine Ghattas, Anne Cozic, and Didier A. Hauglustaine
Atmos. Chem. Phys., 16, 14169–14202, https://doi.org/10.5194/acp-16-14169-2016, https://doi.org/10.5194/acp-16-14169-2016, 2016
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We provide BVOC emissions for the present scenario, employing the updated ORCHIDEE emission module and the MEGAN model. The modelling community still faces the problem of emission model evaluation because of the absence of adequate observations. The accurate analysis performed, employing the two models, allowed the various processes modelled to be investigated, in order to fully understand the origin of the mismatch between the model estimates and to quantify the emission uncertainties.
Sam J. Silva, Colette L. Heald, Jeffrey A. Geddes, Kemen G. Austin, Prasad S. Kasibhatla, and Miriam E. Marlier
Atmos. Chem. Phys., 16, 10621–10635, https://doi.org/10.5194/acp-16-10621-2016, https://doi.org/10.5194/acp-16-10621-2016, 2016
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We investigate the impacts of current (2010) and future (2020) oil palm plantations across Southeast Asia on surface–atmosphere exchange and air quality using satellite data, land maps, and a chemical transport model. These changes lead to increases in surface ozone and particulate matter. Oil palm plantations are likely to continue to degrade regional air quality in the coming decade and hinder efforts to achieve air quality regulations in major urban areas such as Kuala Lumpur and Singapore.
Kathryn M. Emmerson, Ian E. Galbally, Alex B. Guenther, Clare Paton-Walsh, Elise-Andree Guerette, Martin E. Cope, Melita D. Keywood, Sarah J. Lawson, Suzie B. Molloy, Erin Dunne, Marcus Thatcher, Thomas Karl, and Simin D. Maleknia
Atmos. Chem. Phys., 16, 6997–7011, https://doi.org/10.5194/acp-16-6997-2016, https://doi.org/10.5194/acp-16-6997-2016, 2016
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We have tested how a model using a global inventory of plant-based emissions compares with four sets of measurements made in southeast Australia. This region is known for its eucalypt species, which dominate the summertime global inventory. The Australian part of the inventory has been produced using measurements made on eucalypt saplings. The model could not match the measurements, and the inventory needs to be improved by taking measurements of a wider range of Australian plant types and ages.
Wolfgang Knorr, Frank Dentener, Stijn Hantson, Leiwen Jiang, Zbigniew Klimont, and Almut Arneth
Atmos. Chem. Phys., 16, 5685–5703, https://doi.org/10.5194/acp-16-5685-2016, https://doi.org/10.5194/acp-16-5685-2016, 2016
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Wildfires are generally expected to increase in frequency and severity due to climate change. For Europe this could mean increased air pollution levels during the summer. Until 2050, predicted changes are moderate, but under a scenario of strong climate change, these may increase considerably during the later part of the current century. In Portugal and several parts of the Mediterranean, emissions may become relevant for meeting WHO concentration targets.
Stephan Henne, Dominik Brunner, Brian Oney, Markus Leuenberger, Werner Eugster, Ines Bamberger, Frank Meinhardt, Martin Steinbacher, and Lukas Emmenegger
Atmos. Chem. Phys., 16, 3683–3710, https://doi.org/10.5194/acp-16-3683-2016, https://doi.org/10.5194/acp-16-3683-2016, 2016
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Greenhouse gas emissions can be assessed by "top-down" methods that combine atmospheric observations, a transport model and a mathematical optimisation framework. Here, we apply such a top-down method to the methane emissions of Switzerland, utilising observations from the recently installed CarboCount-CH network. Our Swiss total emissions largely agree with those of the national "bottom-up" inventory, whereas regional differences suggest lower than reported emissions from manure handling.
Jeffrey A. Geddes, Colette L. Heald, Sam J. Silva, and Randall V. Martin
Atmos. Chem. Phys., 16, 2323–2340, https://doi.org/10.5194/acp-16-2323-2016, https://doi.org/10.5194/acp-16-2323-2016, 2016
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Land use and land cover changes driven by anthropogenic activities or natural causes (e.g., forestry management, agriculture, wildfires) can impact climate and air quality in many complex ways. Using a state-of-the-art chemistry model, we investigate how tree mortality in the US due to insect infestation and disease outbreak may impact atmospheric composition. We find that the surface concentrations of ozone and aerosol can be altered due to changing background emissions and loss processes.
Yaning Kang, Mingxu Liu, Yu Song, Xin Huang, Huan Yao, Xuhui Cai, Hongsheng Zhang, Ling Kang, Xuejun Liu, Xiaoyuan Yan, Hong He, Qiang Zhang, Min Shao, and Tong Zhu
Atmos. Chem. Phys., 16, 2043–2058, https://doi.org/10.5194/acp-16-2043-2016, https://doi.org/10.5194/acp-16-2043-2016, 2016
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The multi-year (1980–2012) comprehensive ammonia emissions inventories were compiled for China on 1 km × 1 km grid.
Various realistic parameters (ambient temperature, wind speed, soil acidity, synthetic fertilizer types, etc.) were considered in these inventories to synthetically refine the emission factors of ammonia volatilization according to local agricultural practice.
This paper shows the interannual trend and spatial distribution of ammonia emissions in details over recent decades.
A. Ito and Z. Shi
Atmos. Chem. Phys., 16, 85–99, https://doi.org/10.5194/acp-16-85-2016, https://doi.org/10.5194/acp-16-85-2016, 2016
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A new Fe dissolution scheme is developed and is applied to an atmospheric chemistry transport model to estimate anthropogenic soluble Fe deposition. Our improved model successfully captured an inverse relationship of Fe solubility and total Fe loading. Our model estimated the low end of Fe solubility compared to the previous studies. Our model results suggest that human activities contribute to about half of bioavailable Fe supply to significant portions of the oceans in the Northern Hemisphere.
T. Verbeke, J. Lathière, S. Szopa, and N. de Noblet-Ducoudré
Atmos. Chem. Phys., 15, 13555–13568, https://doi.org/10.5194/acp-15-13555-2015, https://doi.org/10.5194/acp-15-13555-2015, 2015
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Dry deposition is a key component of surface-atmosphere exchange of compounds, acting as a sink for several chemical species and strongly driven by meteorological factors, chemical properties of the trace gas considered and land surface properties. The objective of our study is to investigate the impact of vegetation distribution change, which is still not very well quantified, on the dry deposition of key atmospheric species: ozone and nitric acid vapor.
Y. Fu and A. P. K. Tai
Atmos. Chem. Phys., 15, 10093–10106, https://doi.org/10.5194/acp-15-10093-2015, https://doi.org/10.5194/acp-15-10093-2015, 2015
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Historical land cover and land use change alone between 1980 and 2010 could lead to reduced summertime surface ozone by up to 4ppbv in East Asia. Climate change alone could lead to an increase in summertime ozone by 2-10ppbv in most of East Asia. Land cover change could offset part of the climate effect and lead to a previously unknown public health benefit. The sensitivity of surface ozone to land cover change is more dependent on dry deposition than isoprene emission in most of East Asia.
Y. Zheng, N. Unger, M. P. Barkley, and X. Yue
Atmos. Chem. Phys., 15, 8559–8576, https://doi.org/10.5194/acp-15-8559-2015, https://doi.org/10.5194/acp-15-8559-2015, 2015
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We apply two global observational data sets, gross primary productivity (GPP) and tropospheric formaldehyde column variability (HCHOv), to probe isoprene emission variability on large spatiotemporal scales. GPP and HCHOv are decoupled or weakly anticorrelated in regions and seasons when isoprene emission is high. Isoprene emission models that include soil moisture dependence demonstrate greater skill in reproducing observed seasonal GPP-HCHOv correlations in the southeast US and the Amazon.
Z. Y. Wu, L. Zhang, X. M. Wang, and J. W. Munger
Atmos. Chem. Phys., 15, 7487–7496, https://doi.org/10.5194/acp-15-7487-2015, https://doi.org/10.5194/acp-15-7487-2015, 2015
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In this study, we have developed a modified micrometeorological gradient method (MGM), although based on existing micrometeorological theory, to estimate O3 dry deposition fluxes over a forest canopy using concentration gradients between a level above and a level below the canopy top. The new method provides an alternative approach in monitoring/estimating long-term deposition fluxes of similar pollutants over tall canopies and is expected to be useful for the scientific community.
F. Pacifico, G. A. Folberth, S. Sitch, J. M. Haywood, L. V. Rizzo, F. F. Malavelle, and P. Artaxo
Atmos. Chem. Phys., 15, 2791–2804, https://doi.org/10.5194/acp-15-2791-2015, https://doi.org/10.5194/acp-15-2791-2015, 2015
Cited articles
Archibald, A. T., Cooke, M. C., Utembe, S. R., Shallcross, D. E., Derwent, R. G., and Jenkin, M. E.: Impacts of mechanistic changes on HOx formation and recycling in the oxidation of isoprene, Atmos. Chem. Phys., 10, 8097–8118, https://doi.org/10.5194/acp-10-8097-2010, 2010.
Arya, S. P.: Introduction to Micrometeorology, Academic Press, San Diego, CA, 1988.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, 2003a.
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, S197–S219, 2003b.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Baeza-Romero, M. T., Glowacki, D. R., Blitz, M. A., Heard, D. E., Pilling, M. J., Rickard, A. R., and Seakins, P. W.: A combined experimental and theoretical study of the reaction between methylglyoxal and OH/OD radical: OH regeneration, Phys. Chem. Phys. Chem., 9, 4114–4128, 2007.
Baker, B., Guenther, A., Greenberg, J., Goldstein, A., and Fall, R.: Canopy fluxes of 2-methyl-3-buten-2-ol over a ponderosa pine forest by relaxed eddy accumulation: Field data and model comparison, J. Geophys. Res., 104, 26107–26114, 1999.
Baldocchi, D.: A Multi-Layer Model for Estimating Sulfur Dioxide Deposition to a Deciduous Oak Forest Canopy, Atmos. Environ., 22, 869–884, 1988.
Bouvier-Brown, N. C., Goldstein, A. H., Gilman, J. B., Kuster, W. C., and de Gouw, J. A.: In-situ ambient quantification of monoterpenes, sesquiterpenes, and related oxygenated compounds during BEARPEX 2007: implications for gas- and particle-phase chemistry, Atmos. Chem. Phys., 9, 5505–5518, https://doi.org/10.5194/acp-9-5505-2009, 2009a.
Bouvier-Brown, N. C., Goldstein, A. H., Worton, D. R., Matross, D. M., Gilman, J. B., Kuster, W. C., Welsh-Bon, D., Warneke, C., de Gouw, J. A., Cahill, T. M., and Holzinger, R.: Methyl chavicol: characterization of its biogenic emission rate, abundance, and oxidation products in the atmosphere, Atmos. Chem. Phys., 9, 2061–2074, https://doi.org/10.5194/acp-9-2061-2009, 2009b.
Bouvier-Brown, N. C., Holzinger, R., Palitzsch, K., and Goldstein, A. H.: Large emissions of sesquiterpenes and methyl chavicol quantified from branch enclosure measurements, Atmos. Environ., 43, 389–401, 2009c.
Boy, M., Sogachev, A., Lauros, J., Zhou, L., Guenther, A., and Smolander, S.: SOSA - a new model to simulate the concentrations of organic vapours and sulphuric acid inside the ABL - Part 1: Model description and initial evaluation, Atmos. Chem. Phys. Discuss., 10, 18607–18633, https://doi.org/10.5194/acpd-10-18607-2010, 2010.
Butkovskaya, N. I., Pouvesle, N., Kukui, A., and Le Bra, G.: Mechanism of the OH-initiated oxidation of glycolaldehyde over the temperature range 233–296 K, J. Phys. Chem. A, 110, 13492–13499, 2006.
Carrasco, N., Doussin, J. F., Picquet-Varrault, B., and Carlier, P.: Tropospheric degradation of 2-hydroxy-2-methylpropanal, a photo-oxidation product of 2-methyl-3-buten-2-ol: Kinetic and mechanistic study of its photolysis and its reaction with OH radicals, Atmos. Environ., 40, 2011–2019, 2006.
Carslaw, K. S., Boucher, O., Spracklen, D. V., Mann, G. W., Rae, J. G. L., Woodward, S., and Kulmala, M.: A review of natural aerosol interactions and feedbacks within the Earth system, Atmos. Chem. Phys., 10, 1701–1737, https://doi.org/10.5194/acp-10-1701-2010, 2010.
Choi, W., Faloona, I. C., McKay, M., Goldstein, A. H., and Baker, B.: Estimating the atmospheric boundary layer height over sloped, forested terrain from surface spectral analysis during BEARPEX, Atmos. Chem. Phys. Discuss., 10, 25759–25801, https://doi.org/10.5194/acpd-10-25759-2010, 2010.
Dillon, M. B., Lamanna, M. S., Schade, G. W., Goldstein, A., and Cohen, R. C.: Chemical evolution of the Sacramento urban plume: Transport and oxidation, J. Geophys. Res., 107, 4045, https://doi.org/10.1029/2001JD000969, 2002.
Dlugi, R., Berger, M., Zelger, M., Hofzumahaus, A., Siese, M., Holland, F., Wisthaler, A., Grabmer, W., Hansel, A., Koppmann, R., Kramm, G., Möllmann-Coers, M., and Knaps, A.: Turbulent exchange and segregation of HOx radicals and volatile organic compounds above a deciduous forest, Atmos. Chem. Phys., 10, 6215–6235, https://doi.org/10.5194/acp-10-6215-2010, 2010.
Dreyfus, G. B., Schade, G. W., and Goldstein, A. H.: Observational constraints on the contribution of isoprene oxidation to ozone production on the western slope of the Sierra Nevada, California, J. Geophys. Res.-Atmos., 107, 4365–4382, https://doi.org/10.1029/2001JD001490, 2002.
Farmer, D. K. and Cohen, R. C.: Observations of HNO3, $§igma$AN, $§igma$PN and NO2 fluxes: evidence for rapid HOx chemistry within a pine forest canopy, Atmos. Chem. Phys., 8, 3899–3917, https://doi.org/10.5194/acp-8-3899-2008, 2008.
Forkel, R., Klemm, O., Graus, M., Rappengluck, B., Stockwell, W. R., Grabmer, W., Held, A., Hansel, A., and Steinbrecher, R.: Trace gas exchange and gas phase chemistry in a Norway spruce forest: A study with a coupled 1-dimensional canopy atmospheric chemistry emission model, Atmos. Environ., 40, S28–S42, 2006.
Fowler, D., Pilegaard, K., Sutton, M. A., Ambus, P., Raivonen, M., Duyzer, J., Simpson, D., Fagerli, H., Fuzzi, S., Schjoerring, J. K., Granier, C., Neftel, A., Isaksen, I. S. A., Laj, P., Maione, M., Monks, P. S., Burkhardt, J., Daemmgen, U., Neirynck, J., Personne, E., Wichink-Kruit, R., Butterbach-Bahl, K., Flechard, C., Tuovinen, J. P., Coyle, M., Gerosa, G., Loubet, B., Altimir, N., Gruenhage, L., Ammann, C., Cieslik, S., Paoletti, E., Mikkelsen, T. N., Ro-Poulsen, H., Cellier, P., Cape, J. N., Horvath, L., Loreto, F., Niinemets, U., Palmer, P. I., Rinne, J., Misztal, P., Nemitz, E., Nilsson, D., Pryor, S., Gallagher, M. W., Vesala, T., Skiba, U., Brueggemann, N., Zechmeister-Boltenstern, S., Williams, J., O'Dowd, C., Facchini, M. C., de Leeuw, G., Flossman, A., Chaumerliac, N., and Erisman, J. W.: Atmospheric composition change: Ecosystems-Atmosphere interactions, Atmos. Environ., 43, 5193–5267, 2009.
Fuentes, J. D., Hayden, B. P., Garstang, M., Lerdau, M., Fitzjarrald, D., Baldocchi, D. D., Monson, R., Lamb, B., and Geron, C.: New Directions: VOCs and biosphere-atmosphere feedbacks, Atmos. Environ., 35, 189–191, 2001.
Ganzeveld, L. N., Lelieveld, J., Dentener, F. J., Krol, M. C., and Roelofs, G.-J.: Atmosphere-biosphere trace gas exchanges simulated with a single-column model, J. Geophys. Res., 107, 4297–4318, https://doi.org/10.1029/2001JD000684, 2002.
Gao, W., Wesely, M. L., and Lee, I. Y.: A numerical study of the effects of air chemistry on fluxes of NO, NO2, and O3 near the surface, J. Geophys. Res., 96, 18761–18769, 1991.
Gao, W., Wesely, M. L., and Doskey, P. V.: Numerical modeling of the turbulent diffusion and chemistry of NOx, O3, isoprene, and other reactive trace gases in and above a forest canopy, J. Geophys. Res., 98, 18339–18353, 1993.
Geron, C. D. and Arnts, R. R.: Seasonal monoterpene and sesquiterpene emissions from Pinus taeda and Pinus virginiana, Atmos. Environ., 44, 4240–4251, 2010.
Goldstein, A. H., Hultman, N. E., Fracheboud, J. M., Bauer, M. R., Panek, J. A., Xu, M., Qi, Y., Guenther, A. B., and Baugh, W.: Effects of climate variability on the carbon dioxide, water, and sensible heat fluxes above a ponderosa pine plantation in the Sierra Nevada (CA), Agr. Forest Meteorol., 101, 113–129, 2000.
Goldstein, A. H., Koven, C. D., Heald, C. L., and Fung, I. Y.: Biogenic carbon and anthropogenic pollutants combine to form a cooling haze over the southeastern United States, P. Natl. Acad. Sci. USA, 106, 8835–8840, 2009.
Gray, D. W., Lerdau, M. T., and Goldstein, A. H.: Influences of temperature history, water stress, and needle age on methylbutenol emissions, Ecology, 84, 765–776, 2003.
Guenther, A., Hewitt, C. N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M. T., McKay, W. A., Pierce, T., Scholes, B., Steinbrecher, R., Tallamraju, R., Taylor, J., and Zimmerman, P.: A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873–8892, 1995.
Guenther, A., Baugh, B., Brasseur, G., Greenberg, J., Harley, P., Klinger, L., Serça, D., and Vierling, L.: Isoprene emission estimates and uncertainties for the Central African EXPRESSO study domain, J. Geophys. Res., 104, 30625–30639, 1999.
Hall, B. D. and Claiborn, C. S.: Measurements of the dry deposition of peroxides to a Canadian boreal forest, J. Geophys. Res.-Atmos., 102, 29343–29353, 1997.
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009.
Hamba, F.: A Modified K Model for Chemically Reactive Species in the Planetary Boundary Layer, J. Geophys. Res., 98, 5173–5182, 1993.
Harley, P., Fridd-Stroud, V., Greenberg, J., Guenther, A., and Vasconcellos, P.: Emission of 2-methyl-3-buten-2-ol by pines: A potentially large natural source of reactive carbon to the atmosphere, J. Geophys. Res., 103, 25479–25486, 1998.
Harman, I. N. and Finnigan, J. J.: A simple unified theory for flow in the canopy and roughness sublayer, Bound.-Lay. Meteorol., 123, 339–363, 2007.
Hasson, A. S., Tyndall, G. S., and Orlando, J. J.: A product yield study of the reaction of HO2 radicals with ethyl peroxy (C2H5O2), acetyl peroxy (CH3C(O)O2), and acetonyl peroxy (CH3C(O)CH2O2) radicals, J. Phys. Chem. A, 108, 5979–5989, 2004.
Herman, D. J., Halverson, L. J., and Firestone, M. K.: Nitrogen Dynamics in an Annual Grassland: Oak Canopy, Climate, and Microbial Population Effects, Ecol. Appl., 13, 593–604, 2003.
Hites, R. A. and Turner, A. M.: Rate Constants for the Gas-Phase beta-Myrcene plus OH and Isoprene plus OH Reactions as a Function of Temperature, Int. J. Chem. Kinet., 41, 407–413, 2009.
Hofzumahaus, A., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C.-C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S., Shao, M., Zeng, L., Wahner, A., and Zhang, Y.: Amplified Trace Gas Removal in the Troposphere, Science, 324, 1702–1704, https://doi.org/10.1126/science.1164566, 2009.
Holzinger, R., Lee, A., Paw, K. T., and Goldstein, U. A. H.: Observations of oxidation products above a forest imply biogenic emissions of very reactive compounds, Atmos. Chem. Phys., 5, 67–75, https://doi.org/10.5194/acp-5-67-2005, 2005.
Horii, C. V., Munger, J. W., Wofsy, S. C., Zahniser, M., Nelson, D., and McManus, J. B.: Atmospheric reactive nitrogen concentration and flux budgets at a Northeastern US forest site, Agr. Forest Meteorol., 136, 159–174, 2006.
Isaksen, I. S. A., Granier, C., Myhre, G., Berntsen, T. K., Dalsoren, S. B., Gauss, M., Klimont, Z., Benestad, R., Bousquet, P., Collins, W., Cox, T., Eyring, V., Fowler, D., Fuzzi, S., Jockel, P., Laj, P., Lohmann, U., Maione, M., Monks, P., Prevot, A. S. H., Raes, F., Richter, A., Rognerud, B., Schulz, M., Shindell, D., Stevenson, D. S., Storelvmo, T., Wang, W. C., van Weele, M., Wild, M., and Wuebbles, D.: Atmospheric composition change: Climate-Chemistry interactions, Atmos. Environ., 43, 5138–5192, 2009.
Jacobson, M. Z.: Fundamentals of Atmospheric Modeling, Cambridge University Press, New York, 2005.
Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Environ., 31, 81–104, 1997.
Jensen, N. O. and Hummelshøj, P.: Derivation of canopy resistance for water vapour fluxes over a spruce forest, using a new technique for the viscous sublayer resistance, Agr. Forest Meteorol., 73, 339–352, 1995.
Jensen, N. O. and Hummelshøj, P.: Erratum to "Derivation of canopy resistance for water vapor fluxes over a spruce forest, using a new technique for the viscous sublayer resistance", Agr. Forest Meteorol., 85, p. 289, 1997.
Karl, T., Harley, P., Emmons, L., Thornton, B., Guenther, A., Basu, C., Turnipseed, A., and Jardine, K.: Efficient Atmospheric Cleansing of Oxidized Organic Trace Gases by Vegetation, Science, 330, 816–819, 2010.
Kavouras, I. G., Mihalopoulos, N., and Stephanou, E. G.: Formation and gas/particle partitioning of monoterpenes photo-oxidation products over forests, Geophys. Res. Lett., 26, 55–58, 1999.
Kleffmann, J., Gavriloaiei, T., Hofzumahaus, A., Holland, F., Koppmann, R., Rupp, L., Schlosser, E., Siese, M., and Wahner, A.: Daytime formation of nitrous acid: A major source of OH radicals in a forest, Geophys. Res. Lett., 32, L05818, https://doi.org/10.1029/2005GL022524, 2005.
Kurpius, M. R. and Goldstein, A. H.: Gas-phase chemistry dominates O3 loss to a forest, implying a source of aerosols and hydroxyl radicals to the atmosphere, Geophys. Res. Lett., 30, 1371–1374, https://doi.org/10.1029/2002GL016785, 2003.
Law, B. E. and Waring, R. H.: Remote-Sensing Of Leaf-Area Index And Radiation Intercepted By Understory Vegetation, Ecol. Appl., 4, 272–279, 1994.
Law, B. E., Kelliher, F. M., Baldocchi, D. D., Anthoni, P. M., Irvine, J., Moore, D., and Tuyl, S. V.: Spatial and temporal variation in respiration in a young ponderosa pine forest during a summer drought, Agr. Forest Meteorol., 110, 27–43, 2001.
Lee, A., Goldstein, A. H., Keywood, M. D., Gao, S., Varutbangkul, V., Bahreini, R., Ng, N. L., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes, J. Geophys. Res., 111, 1–18, https://doi.org/10.1029/2005JD006437, 2006a.
Lee, A., Goldstein, A. H., Kroll, J. H., Ng, N. L., Varutbangkul, V., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the photooxidation of 16 different terpenes, J. Geophys. Res., 111, 1–25, https://doi.org/10.1029/2006JD007050, 2006b.
Lelieveld, J., Butler, T. M., Crowley, J. N., Dillon, T. J., Fischer, H., Ganzeveld, L., Harder, H., Lawrence, M. G., Martinez, M., Taraborrelli, D., and Williams, J.: Atmospheric oxidation capacity sustained by a tropical forest, Nature, 452, 737–740, https://doi.org/10.1038/nature06870, 2008.
Magnani, F., Mencuccini, M., Borghetti, M., Berbigier, P., Berninger, F., Delzon, S., Grelle, A., Hari, P., Jarvis, P. G., Kolari, P., Kowalski, A. S., Lankreijer, H., Law, B. E., Lindroth, A., Loustau, D., Manca, G., Moncrieff, J. B., Rayment, M., Tedeschi, V., Valentini, R., and Grace, J.: The human footprint in the carbon cycle of temperate and boreal forests, Nature, 447, 849–851, 2007.
Makar, P. A., Fuentes, J. D., Wang, D., Staebler, R. M., and Wiebe, H. A.: Chemical processing of biogenic hydrocarbons within and above a temperate deciduous forest, J. Geophys. Res., 104, 3581–3603, 1999.
Meyers, T. P.: The Sensitivity of Modeled SO2 Fluxes and Profiles to Stomatal and Boundary Layer Resistances, Water Air Soil Poll., 35, 261–278, 1987.
Monteith, J. L. and Unsworth, M. H.: Principles of Environmental Physics, 2nd ed., Edward Arnold, London, UK, 1990.
Murphy, J. G., Day, D. A., Cleary, P. A., Wooldridge, P. J., Millet, D. B., Goldstein, A. H., and Cohen, R. C.: The weekend effect within and downwind of Sacramento - Part 1: Observations of o zone, nitrogen oxides, and VOC reactivity, Atmos. Chem. Phys., 7, 5327–5339, https://doi.org/10.5194/acp-7-5327-2007, 2007.
Orlando, J. J., Tyndall, G. S., and Paulson, S. E.: Mechanism of the OH-initiated oxidation of methacrolein, Geophys. Res. Lett., 26, 2191–2194, 1999.
Orlando, J. J., Tyndall, G. S., Bertman, S. B., Chen, W., and Burkholder, J. B.: Rate coefficient for the reaction of OH with CH2=C(CH3)C(O)OONO2 (MPAN), Atmos. Environ., 36, 1895–1900, 2002.
Patton, E. G., Davis, K. J., Barth, M. C., and Sullivan, P. P.: Decaying Scalars Emitted by a Forest Canopy: A Numerical Study, Bound.-Lay. Meteorol., 100, 91–129, 2001.
Paulot, F., Beaver, M. R., St. Clair, J., Spencer, K. M., Crounse, J., and Wennberg, P. O.: Exchange of hydrogen peroxide and nitric acid over a ponerosa forest measured by eddy covariance, in: Eos Trans. AGU, Fall Meet. Suppl., 90(52), Abstract A41D-0133, 2009a.
Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kroll, J. H., Seinfeld, J. H., and Wennberg, P. O.: Isoprene photooxidation: new insights into the production of acids and organic nitrates, Atmos. Chem. Phys., 9, 1479–1501, https://doi.org/10.5194/acp-9-1479-2009, 2009b.
Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kurten, A., St Clair, J. M., Seinfeld, J. H., and Wennberg, P. O.: Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene, Science, 325, 730–733, 2009c.
Pérez, I. M., LaFranchi, B. W., and Cohen, R. C.: Nitrogen oxide chemistry in an urban plume: investigation of the chemistry of peroxy and multifunctional organic nitrates with a Lagrangian model, Atmos. Chem. Phys. Discuss., 9, 27099–27165, https://doi.org/10.5194/acpd-9-27099-2009, 2009.
Pugh, T. A. M., MacKenzie, A. R., Hewitt, C. N., Langford, B., Edwards, P. M., Furneaux, K. L., Heard, D. E., Hopkins, J. R., Jones, C. E., Karunaharan, A., Lee, J., Mills, G., Misztal, P., Moller, S., Monks, P. S., and Whalley, L. K.: Simulating atmospheric composition over a South-East Asian tropical rainforest: performance of a chemistry box model, Atmos. Chem. Phys., 10, 279–298, https://doi.org/10.5194/acp-10-279-2010, 2010.
Raupach, M. R.: A practical Lagrangian method for relating scalar concentrations to source distributions in vegetation canopies, Q. J. Roy. Meteor. Soc., 115, 609–632, 1989.
Ren, X., Gao, H., Zhou, X., Crounse, J. D., Wennberg, P. O., Browne, E. C., LaFranchi, B. W., Cohen, R. C., McKay, M., Goldstein, A. H., and Mao, J.: Measurement of atmospheric nitrous acid at Bodgett Forest during BEARPEX2007, Atmos. Chem. Phys., 10, 6283–6294, https://doi.org/10.5194/acp-10-6283-2010, 2010.
Runyon, J., Waring, R. H., Goward, S. N., and Welles, J. M.: Environmental Limits On Net Primary Production And Light-Use Efficiency Across The Oregon Transect, Ecol. Appl., 4, 226–237, 1994.
Saunders, S. M., Jenkin, M. E., Derwent, R. G., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 161–180, https://doi.org/10.5194/acp-3-161-2003, 2003.
Schade, G. W., Goldstein, A. H., Gray, D. W., and Lerdau, M. T.: Canopy and leaf level 2-methyl-3-buten-2-ol fluxes from a ponderosa pine plantation, Atmos. Environ., 34, 3535–3544, 2000.
Schade, G. W. and Goldstein, A. H.: Plant physiological influences on the fluxes of oxygenated volatile organic compounds from ponderosa pine trees, J. Geophys. Res.-Atmos., 107, 4082–4091, 2002.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric Chemistry and Physics, 2nd ed., John Wiley and Sons, Inc., Hoboken, NJ, 2006.
Sievering, H., Kelly, T., McConville, G., Seibold, C., and Turnipseed, A.: Nitric acid dry deposition to conifer forests: Niwot Ridge spruce-fir-pine study, Atmos. Environ., 35, 3851–3859, 2001.
Sitch, S., Cox, P. M., Collins, W. J., and Huntingford, C.: Indirect radiative forcing of climate change through ozone effects on the land-carbon sink, Nature, 448, 791–794, 2007.
Steiner, A. L., Tonse, S., Cohen, R. C., Goldstein, A. H., and Harley, R. A.: Biogenic 2-methyl-3-buten-2-ol increases regional ozone and HOx sources, Geophys. Res. Lett., 34, L15806, https://doi.org/10.1029/2007GL030802, 2007.
Steinkamp, J. and Lawrence, M. G.: Improvement and evaluation of simulated global biogenic soil NO emissions in an AC-GCM, Atmos. Chem. Phys. Discuss., 10, 16007–16054, https://doi.org/10.5194/acpd-10-16007-2010, 2010.
Stroud, C., Makar, P., Karl, T., Guenther, A., Geron, C., Turnipseed, A. A., Nemitz, E., Baker, B., Potosnak, M., and Fuentes, J. D.: Role of canopy-scale photochemistry in modifying biogenic-atmosphere exchange of reactive terpenoid species: Results from the CELTIC field study, J. Geophys. Res., 110, D17303, https://doi.org/10.1029/2005JD005775, 2005.
Taraborrelli, D., Lawrence, M. G., Butler, T. M., Sander, R., and Lelieveld, J.: Mainz Isoprene Mechanism 2 (MIM2): an isoprene oxidation mechanism for regional and global atmospheric modelling, Atmos. Chem. Phys., 9, 2751–2777, https://doi.org/10.5194/acp-9-2751-2009, 2009.
Teske, M. E. and Thistle, H. W.: A library of forest canopy structure for use in interception modeling, Forest Ecol. Manage., 198, 341–350, 2004.
Thom, A. S.: Momentum, mass and heat exchange of plant communities, in: Vegetation and Atmosphere, edited by: Monteith, J. L., Elsevier, New York, NY, 57–109, 1975.
Thomas, R. Q., Canham, C. D., Weathers, K. C., and Goodale, C. L.: Increased tree carbon storage in response to nitrogen deposition in the US, Nat. Geosci., 3, 13–17, https://doi.org/10.1038/ngeo721, 2010. bibitem{} Thornton, J. A., Wooldridge, P. J., Cohen, R. C., Martinez, M., Harder, H., Brune, W. H., Williams, E. J., Roberts, J. M., Fehsenfeld, F. C., Hall, S. R., Shetter, R. E., Wert, B. P., and Fried, A.: Ozone production rates as a function of NOx abundances and HOx production rates in the Nashville urban plume, J. Geophys. Res., 107, 4146–4163, https://doi.org/10.1029/2001JD000932, 2002.
Walton, S., Gallagher, M. W., and Duyzer, J. H.: Use of a detailed model to study the exchange of NOx and O3 above and below a deciduous canopy, Atmos. Environ., 31, 2915–2931, 1997.
Wesely, M. L.: Parameterization of surface resistances to gaseous dry deposition in regional-scale numerical models, Atmos. Environ., 23, 1293–1304, 1989.
Wesely, M. L. and Hicks, B. B.: A review of the current status of knowledge on dry deposition, Atmos. Environ., 34, 2261–2282, 2000.
Whitehouse, L. E., Tomlin, A. S., and Pilling, M. J.: Systematic reduction of complex tropospheric chemical mechanisms, Part I: sensitivity and time-scale analyses, Atmos. Chem. Phys., 4, 2025–2056, https://doi.org/10.5194/acp-4-2025-2004, 2004.
Williams, E. J., Guenther, A., and Fehsenfeld, F. C.: An inventory of nitric oxide emissions from soils in the united states, J. Geophys. Res., 97, 7511–7519, 1992.
Wolfe, G. M., Thornton, J. A., Yatavelli, R. L. N., McKay, M., Goldstein, A. H., LaFranchi, B., Min, K.-E., and Cohen, R. C.: Eddy covariance fluxes of acyl peroxy nitrates (PAN, PPN and MPAN) above a Ponderosa pine forest, Atmos. Chem. Phys., 9, 615–634, https://doi.org/10.5194/acp-9-615-2009, 2009.
Wolfe, G. M., Thornton, J. A., Bouvier-Brown, N. C., Goldstein, A. H., Park, J.-H., McKay, M., Matross, D. M., Mao, J., Brune, W. H., LaFranchi, B. W., Browne, E. C., Min, K.-E., Wooldridge, P. J., Cohen, R. C., Crounse, J. D., Faloona, I. C., Gilman, J. B., Kuster, W. C., de Gouw, J. A., Huisman, A., and Keutsch, F. N.: The Chemistry of Atmosphere-Forest Exchange (CAFE) Model - Part 2: Application to BEARPEX-2007 observations, Atmos. Chem. Phys. Discuss., 10, 21791–21866, https://doi.org/10.5194/acpd-10-21791-2010, 2010.
Xu, M., DeBiase, T. A., Qi, Y., Goldstein, A., and Liu, Z.: Ecosystem respiration in a young ponderosa pine plantation in the Sierra Nevada Mountains, California, Tree Physiol., 21, 309–318, 2001.
Yi, C.: Momentum Transfer within Canopies, J. Appl. Meteorol. Clim. 47, 262–275, https://doi.org/10.1175/2007JAMC1667.1, 2008.
Yienger, J. J. and Levy, H.: Empirical-Model Of Global Soil-Biogenic Nox Emissions, J. Geophys. Res.-Atmos., 100, 11447–11464, 1995.
Zhang, L., Brook, J. R., and Vet, R.: A revised parameterization for gaseous dry deposition in air-quality models, Atmos. Chem. Phys., 3, 2067–2082, https://doi.org/10.5194/acp-3-2067-2003, 2003.
Zhang, L. M., Brook, J. R., and Vet, R.: On ozone dry deposition - with emphasis on non-stomatal uptake and wet canopies, Atmos. Environ., 36, 4787–4799, 2002a.
Zhang, L. M., Moran, M. D., Makar, P. A., Brook, J. R., and Gong, S. L.: Modelling gaseous dry deposition in AURAMS: a unified regional air-quality modelling system, Atmos. Environ., 36, 537–560, 2002b.
Zhang, N., Zhou, X. L., Shepson, P. B., Gao, H. L., Alaghmand, M., and Stirm, B.: Aircraft measurement of HONO vertical profiles over a forested region, Geophys. Res. Lett., 36, L15820, https://doi.org/10.1029/2009GL038999, 2009.
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