Articles | Volume 17, issue 10
Atmos. Chem. Phys., 17, 6493–6502, 2017
https://doi.org/10.5194/acp-17-6493-2017
Atmos. Chem. Phys., 17, 6493–6502, 2017
https://doi.org/10.5194/acp-17-6493-2017

Research article 01 Jun 2017

Research article | 01 Jun 2017

Efficient bulk mass accommodation and dissociation of N2O5 in neutral aqueous aerosol

Goran Gržinić et al.

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Cited articles

Abbatt, J. P. D., Lee, A. K. Y., and Thornton, J. A.: Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges, Chem. Soc. Rev., 41, 6555–6581, https://doi.org/10.1039/C2CS35052A, 2012.
Ammann, M.: Using 13N as tracer in heterogeneous atmospheric chemistry experiments, Radiochim. Acta, 89, 831–838, 2001.
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Anttila, T., Kiendler-Scharr, A., Tillmann, R., and Mentel, T. F.: On the reactive uptake of gaseous compounds by organic-coated aqueous aerosols: Theoretical analysis and application to the heterogeneous hydrolysis of N2O5, J. Phys. Chem. A, 110, 10435–10443, 2006.
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Short summary
Nitrogen oxides (NOx) largely control the ozone budget in the troposphere globally. Dinitrogen pentoxide (N2O5) is an important species as a nighttime reservoir for nitrogen oxides. Loss of N2O5 to aerosol particles is therefore important for the budget of NOx and the oxidation capacity. Here we provide direct evidence for its efficient accommodation into aqueous aerosol particles and its fast dissociation, which has not been elucidated as directly in previous studies.
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