Articles | Volume 16, issue 11
Atmos. Chem. Phys., 16, 7135–7148, 2016
https://doi.org/10.5194/acp-16-7135-2016
Atmos. Chem. Phys., 16, 7135–7148, 2016
https://doi.org/10.5194/acp-16-7135-2016

Research article 10 Jun 2016

Research article | 10 Jun 2016

Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal

Mohammad Safi Shalamzari et al.

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Cited articles

Boschan, R., Merrow, R. T., and Van Dolah, R. W.: The chemistry of nitrate esters, Chem. Rev., 55, 485–510, 1955.
Brilli, F., Hortnagl, L., Bamberger, I., Schnitzhofer, R., Ruuskanen, T. M., Hansel, A., Loreto, F., and Wohlfahrt, G.: Qualitative and quantitative characterization of volatile organic compound emissions from cut grass, Environ. Sci. Technol., 46, 3859–3865, 2012.
Chen, X. H., Hulbert, D., and Shepson, P. B.: Measurement of the organic nitrate yield from OH reaction with isoprene, J. Geophys. Res.-Atmos., 103, 25563–25568, 1998.
Darer, A. I., Cole-Filipiak, N. C., O'Connor, A. E., and Elrod, M. J.: Formation and stability of atmospherically relevant isoprene-derived organosulfates and organonitrates, Environ. Sci. Technol., 45, 1895–1902, 2011.
D'Auria, J. C., Pichersky, E., Schaub, A., Hansel, A., and Gershenzon, J.: Characterization of a BAHD acyltransferase responsible for producing the green leaf volatile (Z)-3-hexen-1-yl acetate in Arabidopsis thaliana, Plant J., 49, 194–207, 2007.
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Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are precursors for secondary organic aerosol, namely, organosulfates with MWs 230, 214, and 170. The structures were elucidated with liquid chromatography/(−)electrospray ionization mass spectrometry (MS), involving accurate mass measurements and ion trap MS. It is shown that the MW 214 isomer with the sulfate group at the C-2 position is unstable and decarboxylates to a MW 170 organosulfate.
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