Articles | Volume 16, issue 11
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
10 Jun 2016
Research article |
| 10 Jun 2016
Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal
Mohammad Safi Shalamzari
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Department of Analytical Chemistry, Ghent University, 9000 Ghent,
Belgium
Reinhilde Vermeylen
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Frank Blockhuys
Department of Chemistry, University of Antwerp, 2020 Antwerp,
Belgium
Tadeusz E. Kleindienst
National Exposure Research Laboratory, Office of Research and
Development, United States Environmental Protection Agency, Research
Triangle Park, North Carolina 27711, USA
Michael Lewandowski
National Exposure Research Laboratory, Office of Research and
Development, United States Environmental Protection Agency, Research
Triangle Park, North Carolina 27711, USA
Rafal Szmigielski
Institute of Physical Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Krzysztof J. Rudzinski
Institute of Physical Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Grzegorz Spólnik
Institute of Organic Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Witold Danikiewicz
Institute of Organic Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Willy Maenhaut
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Department of Analytical Chemistry, Ghent University, 9000 Ghent,
Belgium
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
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Latest update: 03 Jul 2025
Short summary
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are precursors for secondary organic aerosol, namely, organosulfates with MWs 230, 214, and 170. The structures were elucidated with liquid chromatography/(−)electrospray ionization mass spectrometry (MS), involving accurate mass measurements and ion trap MS. It is shown that the MW 214 isomer with the sulfate group at the C-2 position is unstable and decarboxylates to a MW 170 organosulfate.
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal...
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