Articles | Volume 16, issue 11
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
10 Jun 2016
Research article |
| 10 Jun 2016
Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal
Mohammad Safi Shalamzari
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Department of Analytical Chemistry, Ghent University, 9000 Ghent,
Belgium
Reinhilde Vermeylen
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Frank Blockhuys
Department of Chemistry, University of Antwerp, 2020 Antwerp,
Belgium
Tadeusz E. Kleindienst
National Exposure Research Laboratory, Office of Research and
Development, United States Environmental Protection Agency, Research
Triangle Park, North Carolina 27711, USA
Michael Lewandowski
National Exposure Research Laboratory, Office of Research and
Development, United States Environmental Protection Agency, Research
Triangle Park, North Carolina 27711, USA
Rafal Szmigielski
Institute of Physical Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Krzysztof J. Rudzinski
Institute of Physical Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Grzegorz Spólnik
Institute of Organic Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Witold Danikiewicz
Institute of Organic Chemistry, Polish Academy of Sciences, 01-224
Warsaw, Poland
Willy Maenhaut
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Department of Analytical Chemistry, Ghent University, 9000 Ghent,
Belgium
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Viewed
Total article views: 3,622 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 29 Oct 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,228 | 1,216 | 178 | 3,622 | 443 | 108 | 159 |
- HTML: 2,228
- PDF: 1,216
- XML: 178
- Total: 3,622
- Supplement: 443
- BibTeX: 108
- EndNote: 159
Total article views: 3,022 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Jun 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,933 | 936 | 153 | 3,022 | 253 | 89 | 133 |
- HTML: 1,933
- PDF: 936
- XML: 153
- Total: 3,022
- Supplement: 253
- BibTeX: 89
- EndNote: 133
Total article views: 600 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 29 Oct 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 295 | 280 | 25 | 600 | 190 | 19 | 26 |
- HTML: 295
- PDF: 280
- XML: 25
- Total: 600
- Supplement: 190
- BibTeX: 19
- EndNote: 26
Cited
41 citations as recorded by crossref.
- Characterization of organic nitrogen in aerosols at a forest site in the southern Appalachian Mountains X. Chen et al. 10.5194/acp-18-6829-2018
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Molecular Characteristics of Atmospheric Organosulfates During Summer and Winter Seasons in Two Cities of Southern and Northern China Y. Lin et al. 10.1029/2022JD036672
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Molecular Characterization of Organosulfur Compounds in Biodiesel and Diesel Fuel Secondary Organic Aerosol S. Blair et al. 10.1021/acs.est.6b03304
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Theoretical study on the formation of Criegee intermediates from ozonolysis of pentenal: An example of trans-2-pentenal W. Xiao et al. 10.1016/j.chemosphere.2022.135142
- Mechanism and Product Distribution of the O3-Initiated Degradation of (E)-2-Heptenal, (E)-2-Octenal, and (E)-2-Nonenal E. Gaona Colmán et al. 10.1021/acs.jpca.7b01857
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Aqueous-phase photo-oxidation of selected green leaf volatiles initiated by OH radicals: Products and atmospheric implications K. Sarang et al. 10.1016/j.scitotenv.2023.162622
- Molecular Characterization and Source Identification of Atmospheric Particulate Organosulfates Using Ultrahigh Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.9b02628
- Impacts of SO2, Relative Humidity, and Seed Acidity on Secondary Organic Aerosol Formation in the Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b02702
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications P. Wach et al. 10.1016/j.chemosphere.2018.09.026
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- Quantification of known and unknown terpenoid organosulfates in PM10 using untargeted LC–HRMS/MS: contrasting summertime rural Germany and the North China Plain M. Brüggemann et al. 10.1071/EN19089
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study I. Kourtchev et al. 10.5194/acp-16-11899-2016
- Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation A. Hettiyadura et al. 10.5194/acp-19-3191-2019
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes M. Riva et al. 10.5194/acp-16-11001-2016
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- Improved UHPLC-MS/MS Methods for Analysis of Isoprene-Derived Organosulfates G. Spolnik et al. 10.1021/acs.analchem.7b05060
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- The light absorbing and molecule characteristic of PM2.5 brown carbon observed in urban Shanghai Z. Bai et al. 10.1016/j.envpol.2022.120874
- Detection of organosulfates and nitrooxy-organosulfates in Arctic and Antarctic atmospheric aerosols, using ultra-high resolution FT-ICR mass spectrometry Y. Ye et al. 10.1016/j.scitotenv.2020.144339
- Chemical characterization of organosulfates from the hydroxyl radical-initiated oxidation and ozonolysis of cis-3-hexen-1-ol T. Barbosa et al. 10.1016/j.atmosenv.2017.04.026
- Reaction Kinetics of Green Leaf Volatiles with Sulfate, Hydroxyl, and Nitrate Radicals in Tropospheric Aqueous Phase K. Sarang et al. 10.1021/acs.est.1c03276
- Conformational diversity and environmental implications of trans-2-pentenal S. Park & C. Kwon 10.1039/D3CP04204A
- Hydration of glycolic acid sulfate and lactic acid sulfate: Atmospheric implications N. Tsona & L. Du 10.1016/j.atmosenv.2019.116921
- Special issue: Chemical characterization of secondary organic aerosol – Dedication to Professor Magda Claeys J. Surratt et al. 10.1016/j.atmosenv.2016.02.004
- Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides M. Riva et al. 10.1021/acs.est.6b02511
- Seasonal variations of fine particulate organosulfates derived from biogenic and anthropogenic hydrocarbons in the mid-Atlantic United States L. Meade et al. 10.1016/j.atmosenv.2016.09.028
38 citations as recorded by crossref.
- Characterization of organic nitrogen in aerosols at a forest site in the southern Appalachian Mountains X. Chen et al. 10.5194/acp-18-6829-2018
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Molecular Characteristics of Atmospheric Organosulfates During Summer and Winter Seasons in Two Cities of Southern and Northern China Y. Lin et al. 10.1029/2022JD036672
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Molecular Characterization of Organosulfur Compounds in Biodiesel and Diesel Fuel Secondary Organic Aerosol S. Blair et al. 10.1021/acs.est.6b03304
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Theoretical study on the formation of Criegee intermediates from ozonolysis of pentenal: An example of trans-2-pentenal W. Xiao et al. 10.1016/j.chemosphere.2022.135142
- Mechanism and Product Distribution of the O3-Initiated Degradation of (E)-2-Heptenal, (E)-2-Octenal, and (E)-2-Nonenal E. Gaona Colmán et al. 10.1021/acs.jpca.7b01857
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Aqueous-phase photo-oxidation of selected green leaf volatiles initiated by OH radicals: Products and atmospheric implications K. Sarang et al. 10.1016/j.scitotenv.2023.162622
- Molecular Characterization and Source Identification of Atmospheric Particulate Organosulfates Using Ultrahigh Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.9b02628
- Impacts of SO2, Relative Humidity, and Seed Acidity on Secondary Organic Aerosol Formation in the Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b02702
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications P. Wach et al. 10.1016/j.chemosphere.2018.09.026
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- Quantification of known and unknown terpenoid organosulfates in PM10 using untargeted LC–HRMS/MS: contrasting summertime rural Germany and the North China Plain M. Brüggemann et al. 10.1071/EN19089
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study I. Kourtchev et al. 10.5194/acp-16-11899-2016
- Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation A. Hettiyadura et al. 10.5194/acp-19-3191-2019
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes M. Riva et al. 10.5194/acp-16-11001-2016
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- Improved UHPLC-MS/MS Methods for Analysis of Isoprene-Derived Organosulfates G. Spolnik et al. 10.1021/acs.analchem.7b05060
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- The light absorbing and molecule characteristic of PM2.5 brown carbon observed in urban Shanghai Z. Bai et al. 10.1016/j.envpol.2022.120874
- Detection of organosulfates and nitrooxy-organosulfates in Arctic and Antarctic atmospheric aerosols, using ultra-high resolution FT-ICR mass spectrometry Y. Ye et al. 10.1016/j.scitotenv.2020.144339
- Chemical characterization of organosulfates from the hydroxyl radical-initiated oxidation and ozonolysis of cis-3-hexen-1-ol T. Barbosa et al. 10.1016/j.atmosenv.2017.04.026
- Reaction Kinetics of Green Leaf Volatiles with Sulfate, Hydroxyl, and Nitrate Radicals in Tropospheric Aqueous Phase K. Sarang et al. 10.1021/acs.est.1c03276
- Conformational diversity and environmental implications of trans-2-pentenal S. Park & C. Kwon 10.1039/D3CP04204A
- Hydration of glycolic acid sulfate and lactic acid sulfate: Atmospheric implications N. Tsona & L. Du 10.1016/j.atmosenv.2019.116921
3 citations as recorded by crossref.
- Special issue: Chemical characterization of secondary organic aerosol – Dedication to Professor Magda Claeys J. Surratt et al. 10.1016/j.atmosenv.2016.02.004
- Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides M. Riva et al. 10.1021/acs.est.6b02511
- Seasonal variations of fine particulate organosulfates derived from biogenic and anthropogenic hydrocarbons in the mid-Atlantic United States L. Meade et al. 10.1016/j.atmosenv.2016.09.028
Saved (preprint)
Latest update: 12 Jul 2025
Short summary
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are precursors for secondary organic aerosol, namely, organosulfates with MWs 230, 214, and 170. The structures were elucidated with liquid chromatography/(−)electrospray ionization mass spectrometry (MS), involving accurate mass measurements and ion trap MS. It is shown that the MW 214 isomer with the sulfate group at the C-2 position is unstable and decarboxylates to a MW 170 organosulfate.
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal...
Altmetrics
Final-revised paper
Preprint