Articles | Volume 16, issue 11
Atmos. Chem. Phys., 16, 7135–7148, 2016
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 7135–7148, 2016
https://doi.org/10.5194/acp-16-7135-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
10 Jun 2016
Research article
| 10 Jun 2016
Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal
Mohammad Safi Shalamzari et al.
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- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications P. Wach et al. 10.1016/j.chemosphere.2018.09.026
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- Reaction Kinetics of Green Leaf Volatiles with Sulfate, Hydroxyl, and Nitrate Radicals in Tropospheric Aqueous Phase K. Sarang et al. 10.1021/acs.est.1c03276
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Saved (preprint)
Latest update: 02 Jul 2022
Short summary
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are precursors for secondary organic aerosol, namely, organosulfates with MWs 230, 214, and 170. The structures were elucidated with liquid chromatography/(−)electrospray ionization mass spectrometry (MS), involving accurate mass measurements and ion trap MS. It is shown that the MW 214 isomer with the sulfate group at the C-2 position is unstable and decarboxylates to a MW 170 organosulfate.
Evidence is provided that the green leaf aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal...
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