Articles | Volume 13, issue 11
https://doi.org/10.5194/acp-13-5403-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-5403-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
03 Jun 2013
Research article |
| 03 Jun 2013
OH and HO2 radical chemistry during PROPHET 2008 and CABINEX 2009 – Part 1: Measurements and model comparison
S. M. Griffith
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Center for Research in Environmental Science, Indiana University, Bloomington, IN, USA
R. F. Hansen
Center for Research in Environmental Science, Indiana University, Bloomington, IN, USA
Department of Chemistry, Indiana University, Bloomington, IN, USA
S. Dusanter
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Université Lille Nord de France, 59000, Lille, France
Mines Douai, CE, F59508, Douai, France
P. S. Stevens
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Center for Research in Environmental Science, Indiana University, Bloomington, IN, USA
Department of Chemistry, Indiana University, Bloomington, IN, USA
M. Alaghmand
Department of Chemistry, Purdue University, West Lafayette, IN, USA
S. B. Bertman
Department of Chemistry, Western Michigan University, Kalamazoo, MI, USA
M. A. Carroll
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, MI, USA
M. Erickson
Department of Civil and Environmental Engineering, Washington State University, Pullman, WA, USA
M. Galloway
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
now at: Department of Chemistry and Biochemistry, University of San Diego, San Diego, CA, USA
N. Grossberg
Department of Earth and Atmospheric Sciences, University of Houston, Houston, TX, USA
J. Hottle
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
J. Hou
School of Public Health, State University of New York at Albany, Albany, NY, USA
B. T. Jobson
Department of Civil and Environmental Engineering, Washington State University, Pullman, WA, USA
A. Kammrath
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
F. N. Keutsch
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
B. L. Lefer
Department of Earth and Atmospheric Sciences, University of Houston, Houston, TX, USA
L. H. Mielke
Department of Chemistry, Purdue University, West Lafayette, IN, USA
now at: School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
A. O'Brien
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
now at: Civil and Environmental Engineering, Princeton University, Princeton, NJ, USA
P. B. Shepson
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Earth and Atmospheric Sciences, Purdue University, West Lafayette, IN, USA
M. Thurlow
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
W. Wallace
Department of Civil and Environmental Engineering, Washington State University, Pullman, WA, USA
N. Zhang
School of Public Health, State University of New York at Albany, Albany, NY, USA
X. L. Zhou
School of Public Health, State University of New York at Albany, Albany, NY, USA
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Shuvashish Kundu, Benjamin L. Deming, Michelle M. Lew, Brandon P. Bottorff, Pamela Rickly, Philip S. Stevens, Sebastien Dusanter, Sofia Sklaveniti, Thierry Leonardis, Nadine Locoge, and Ezra C. Wood
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Daisy N. Grace, Melissa B. Sebold, and Melissa M. Galloway
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John W. Halfacre, Paul B. Shepson, and Kerri A. Pratt
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Ali Akherati, Christopher D. Cappa, Michael J. Kleeman, Kenneth S. Docherty, Jose L. Jimenez, Stephen M. Griffith, Sebastien Dusanter, Philip S. Stevens, and Shantanu H. Jathar
Atmos. Chem. Phys., 19, 4561–4594, https://doi.org/10.5194/acp-19-4561-2019, https://doi.org/10.5194/acp-19-4561-2019, 2019
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Unburned and partially burned organic compounds emitted from fossil fuel and biomass combustion can react in the atmosphere in the presence of sunlight to form particles. In this work, we use an air pollution model to examine the influence of these organic compounds released by motor vehicles and fires on fine particle pollution in southern California.
Shino Toma, Steve Bertman, Christopher Groff, Fulizi Xiong, Paul B. Shepson, Paul Romer, Kaitlin Duffey, Paul Wooldridge, Ronald Cohen, Karsten Baumann, Eric Edgerton, Abigail R. Koss, Joost de Gouw, Allen Goldstein, Weiwei Hu, and Jose L. Jimenez
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Acyl peroxy nitrates (APN) were measured near the ground in Alabama using GC in summer 2013 to study biosphere–atmosphere interactions. APN were lower than measured in the SE USA over the past 2 decades. Historical data showed APN in 2013 was limited by NOx and production was dominated by biogenic precursors more than in the past. Isoprene-derived MPAN correlated with isoprene hydroxynitrates as NOx-dependent products. MPAN varied with aerosol growth, but not with N-containing particles.
Chunxiang Ye, Xianliang Zhou, Dennis Pu, Jochen Stutz, James Festa, Max Spolaor, Catalina Tsai, Christopher Cantrell, Roy L. Mauldin III, Andrew Weinheimer, Rebecca S. Hornbrook, Eric C. Apel, Alex Guenther, Lisa Kaser, Bin Yuan, Thomas Karl, Julie Haggerty, Samuel Hall, Kirk Ullmann, James Smith, and John Ortega
Atmos. Chem. Phys., 18, 9107–9120, https://doi.org/10.5194/acp-18-9107-2018, https://doi.org/10.5194/acp-18-9107-2018, 2018
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Substantial levels of HONO existed during the day throughout the troposphere over the southeastern US during NOMADSS 2013. Particulate nitrate photolysis appeared to be the major volume HONO source, while NOx was an important HONO precursor only in industrial and urban plumes. HONO was not a significant OH radical precursor in the rural troposphere away from the ground surface; however, its production from particulate nitrate photolysis was an important renoxification pathway.
Matthew J. Gunsch, Nathaniel W. May, Miao Wen, Courtney L. H. Bottenus, Daniel J. Gardner, Timothy M. VanReken, Steven B. Bertman, Philip K. Hopke, Andrew P. Ault, and Kerri A. Pratt
Atmos. Chem. Phys., 18, 3701–3715, https://doi.org/10.5194/acp-18-3701-2018, https://doi.org/10.5194/acp-18-3701-2018, 2018
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During summer 2014, atmospheric particulate matter in northern Michigan was impacted by wildfire emissions under all air mass conditions (Canadian wildfires, US urban, and Canadian forest influences). Biomass burning particles coated with secondary organic aerosol contributed the majority of the submicron aerosol mass. Given increasing wildfires, the impacts of biomass burning on air quality must be assessed, particularly for downwind areas impacted by long-range transport.
Sofia Sklaveniti, Nadine Locoge, Philip S. Stevens, Ezra Wood, Shuvashish Kundu, and Sébastien Dusanter
Atmos. Meas. Tech., 11, 741–761, https://doi.org/10.5194/amt-11-741-2018, https://doi.org/10.5194/amt-11-741-2018, 2018
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Ground-level ozone is a pollutant that affects both global climate change and regional air quality. Its complex formation chemistry makes the implementation of reduction strategies challenging and needs to be well understood to develop efficient strategies. This publication reports the development of an instrument capable of monitoring the ozone formation rate in the atmosphere. Its reliability was tested in the laboratory and in the field and important recommendations are given for improvement.
Michelle M. Lew, Sebastien Dusanter, and Philip S. Stevens
Atmos. Meas. Tech., 11, 95–109, https://doi.org/10.5194/amt-11-95-2018, https://doi.org/10.5194/amt-11-95-2018, 2018
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This paper describes measurements of the conversion efficiency of several organic peroxy radicals upon reaction with nitric oxide to the hydroperoxy radical, which can interfere with measurements of the latter. This interference could explain some of the discrepancies between measurements and model predictions of the hydroperoxy radical. Previous measurements of the hydroperoxy radical during the Mexico City Metropolitan Area campaign in 2006 are reanalyzed to account for the interference.
Pamela Rickly and Philip S. Stevens
Atmos. Meas. Tech., 11, 1–16, https://doi.org/10.5194/amt-11-1-2018, https://doi.org/10.5194/amt-11-1-2018, 2018
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The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of its concentration provide a rigorous test of our understanding of atmospheric chemistry. This paper presents measurements of a potential interference with measurements of OH using laser-induced fluorescence techniques, which may contribute to measurements of OH in forested environments. The results may help to explain discrepancies between measurements and model predictions in these environments.
William R. Simpson, Peter K. Peterson, Udo Frieß, Holger Sihler, Johannes Lampel, Ulrich Platt, Chris Moore, Kerri Pratt, Paul Shepson, John Halfacre, and Son V. Nghiem
Atmos. Chem. Phys., 17, 9291–9309, https://doi.org/10.5194/acp-17-9291-2017, https://doi.org/10.5194/acp-17-9291-2017, 2017
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We investigated Arctic atmospheric bromine chemistry during March–April 2012 to improve understanding of the role of sea ice and cracks in sea ice (leads) in this phenomenon. We find that leads vertically redistribute reactive bromine but that open/re-freezing leads are not major direct reactive halogen sources. Surface ozone depletion affects the vertical distribution and amount of reactive halogens, and aerosol particles are necessary but not sufficient to maintain reactive bromine aloft.
Jonathan H. Slade, Chloé de Perre, Linda Lee, and Paul B. Shepson
Atmos. Chem. Phys., 17, 8635–8650, https://doi.org/10.5194/acp-17-8635-2017, https://doi.org/10.5194/acp-17-8635-2017, 2017
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This study provides new insight into the oxidation of polyolefinic monoterpenes and the dependence of the formation and yields of organic nitrates (ON) and secondary organic aerosol (SOA) on hydrocarbon structure. Here we have elucidated the ON, hydroxy nitrate, and SOA yields from the NO3 oxidation of γ-terpinene, a potentially relevant nighttime ON precursor in the Midwestern US. The results advance our understanding of the chemistry that influences NOx, O3 production, and aerosol formation.
Peter K. Peterson, Denis Pöhler, Holger Sihler, Johannes Zielcke, Stephan General, Udo Frieß, Ulrich Platt, William R. Simpson, Son V. Nghiem, Paul B. Shepson, Brian H. Stirm, Suresh Dhaniyala, Thomas Wagner, Dana R. Caulton, Jose D. Fuentes, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 7567–7579, https://doi.org/10.5194/acp-17-7567-2017, https://doi.org/10.5194/acp-17-7567-2017, 2017
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High-spatial-resolution aircraft measurements in the Arctic showed the sustained transport of reactive bromine in a lofted layer via heterogeneous reactions on aerosol particles. This process provides an explanation for free tropospheric reactive bromine and the significant spatial extent of satellite-observed bromine monoxide. The knowledge gained herein improves our understanding of the fate and transport of atmospheric pollutants in the Arctic.
Chelsea R. Thompson, Paul B. Shepson, Jin Liao, L. Greg Huey, Chris Cantrell, Frank Flocke, and John Orlando
Atmos. Chem. Phys., 17, 3401–3421, https://doi.org/10.5194/acp-17-3401-2017, https://doi.org/10.5194/acp-17-3401-2017, 2017
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The generally accepted mechanism leading to ozone depletion events in the Arctic assumes efficient gas-phase recycling of bromine atoms, such that the rate of ozone depletion has often been estimated as the rate that Br atoms regenerate through gas-phase BrO + BrO and BrO + ClO reactions. Using a large suite of data from the OASIS2009 campaign, our modeling results show that the gas-phase regeneration of Br is less efficient than expected and that heterogeneous recycling on surfaces is critical.
Benjamin C. Schulze, Henry W. Wallace, James H. Flynn, Barry L. Lefer, Matt H. Erickson, B. Tom Jobson, Sebastien Dusanter, Stephen M. Griffith, Robert F. Hansen, Philip S. Stevens, Timothy VanReken, and Robert J. Griffin
Atmos. Chem. Phys., 17, 1805–1828, https://doi.org/10.5194/acp-17-1805-2017, https://doi.org/10.5194/acp-17-1805-2017, 2017
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The atmospheric chemistry associated with mixing of anthropogenic and natural species was simulated to understand how shade provided by a forest canopy impacts reactions, product distribution, and subsequent phase distribution of the products. This is important to understand, as forested areas downwind of urban areas will be impacted by this phenomenon. It was found that fast transport from below the canopy led to increases in secondary organic aerosol from nitrate radicals above the canopy.
Joel D. Rindelaub, Carlos H. Borca, Matthew A. Hostetler, Jonathan H. Slade, Mark A. Lipton, Lyudmila V. Slipchenko, and Paul B. Shepson
Atmos. Chem. Phys., 16, 15425–15432, https://doi.org/10.5194/acp-16-15425-2016, https://doi.org/10.5194/acp-16-15425-2016, 2016
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This study provides new insight into the hydrolysis reaction mechanism, which was elucidated for atmospherically relevant organic nitrates using kinetic measurements, product identification, and theoretical calculations. The results help broaden our knowledge of the organic chemistry that impacts the fate of NOx, ozone production, aerosol phase processing, and aerosol composition.
J. Kaiser, K. M. Skog, K. Baumann, S. B. Bertman, S. B. Brown, W. H. Brune, J. D. Crounse, J. A. de Gouw, E. S. Edgerton, P. A. Feiner, A. H. Goldstein, A. Koss, P. K. Misztal, T. B. Nguyen, K. F. Olson, J. M. St. Clair, A. P. Teng, S. Toma, P. O. Wennberg, R. J. Wild, L. Zhang, and F. N. Keutsch
Atmos. Chem. Phys., 16, 9349–9359, https://doi.org/10.5194/acp-16-9349-2016, https://doi.org/10.5194/acp-16-9349-2016, 2016
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OH reactivity can be used to assess the amount of reactive carbon in an air mass. “Missing” reactivity is commonly found in forested environments and is attributed to either direct emissions of unmeasured volatile organic compounds or to unmeasured/underpredicted oxidation products. Using a box model and measurements from the 2013 SOAS campaign, we find only small discrepancies in measured and calculated reactivity. Our results suggest the discrepancies stem from unmeasured direct emissions.
Luping Su, Edward G. Patton, Jordi Vilà-Guerau de Arellano, Alex B. Guenther, Lisa Kaser, Bin Yuan, Fulizi Xiong, Paul B. Shepson, Li Zhang, David O. Miller, William H. Brune, Karsten Baumann, Eric Edgerton, Andrew Weinheimer, Pawel K. Misztal, Jeong-Hoo Park, Allen H. Goldstein, Kate M. Skog, Frank N. Keutsch, and John E. Mak
Atmos. Chem. Phys., 16, 7725–7741, https://doi.org/10.5194/acp-16-7725-2016, https://doi.org/10.5194/acp-16-7725-2016, 2016
Jenny A. Fisher, Daniel J. Jacob, Katherine R. Travis, Patrick S. Kim, Eloise A. Marais, Christopher Chan Miller, Karen Yu, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Jingqiu Mao, Paul O. Wennberg, John D. Crounse, Alex P. Teng, Tran B. Nguyen, Jason M. St. Clair, Ronald C. Cohen, Paul Romer, Benjamin A. Nault, Paul J. Wooldridge, Jose L. Jimenez, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Paul B. Shepson, Fulizi Xiong, Donald R. Blake, Allen H. Goldstein, Pawel K. Misztal, Thomas F. Hanisco, Glenn M. Wolfe, Thomas B. Ryerson, Armin Wisthaler, and Tomas Mikoviny
Atmos. Chem. Phys., 16, 5969–5991, https://doi.org/10.5194/acp-16-5969-2016, https://doi.org/10.5194/acp-16-5969-2016, 2016
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We use new airborne and ground-based observations from two summer 2013 campaigns in the southeastern US, interpreted with a chemical transport model, to understand the impact of isoprene and monoterpene chemistry on the atmospheric NOx budget via production of organic nitrates (RONO2). We find that a diversity of species contribute to observed RONO2. Our work implies that the NOx sink to RONO2 production is only sensitive to NOx emissions in regions where they are already low.
Fulizi Xiong, Carlos H. Borca, Lyudmila V. Slipchenko, and Paul B. Shepson
Atmos. Chem. Phys., 16, 5595–5610, https://doi.org/10.5194/acp-16-5595-2016, https://doi.org/10.5194/acp-16-5595-2016, 2016
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Here we report on a detailed study of the photochemistry and fate of a nitrooxy enal that is produced from the reaction of NO3 with isoprene. We synthesized the 4,1-nitrooxy enal, purified it, and measured the O3 and OH reaction rate constants, and determined the atmospheric photodissociation rate constant for specified radiation conditions. The determined fast photolysis rate and high reactivity toward OH lead to a lifetime of less than 1 hour, with photolysis being a dominant daytime sink.
Hyun Cheol Kim, Pius Lee, Laura Judd, Li Pan, and Barry Lefer
Geosci. Model Dev., 9, 1111–1123, https://doi.org/10.5194/gmd-9-1111-2016, https://doi.org/10.5194/gmd-9-1111-2016, 2016
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Fair comparison between satellite- and modeled urban NO2 column densities is important in emission inventory evaluation and regulation policy making. This study focuses on the impact of satellite footprint resolution geometry. Since OMI NO2 pixels are too coarse to resolve fine-scale urban plumes, it may cause 20–30 % bias over major cities. We introduce approaches to adjust spatial and vertical structure (downscaling & averaging kernel), and demonstrate improved agreement between sat. and model.
Xiangshang Li, Yunsoo Choi, Beata Czader, Anirban Roy, Hyuncheol Kim, Barry Lefer, and Shuai Pan
Atmos. Chem. Phys., 16, 3127–3144, https://doi.org/10.5194/acp-16-3127-2016, https://doi.org/10.5194/acp-16-3127-2016, 2016
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We performed a a month-long sensitivity study of obs-nudging on meteorology and ozone chemistry. Notable increases in temperature and wind performance were observed after obs-nudging with hourly nudging files. PBL height also matched better in the sensitivity case. The model ozone improved at ground level and aloft but to a lesser degree. An examination of a high ozone episode showed that the current nudging process does not perform consistently – quite well at times while poor at other times.
R. F. Hansen, M. Blocquet, C. Schoemaecker, T. Léonardis, N. Locoge, C. Fittschen, B. Hanoune, P. S. Stevens, V. Sinha, and S. Dusanter
Atmos. Meas. Tech., 8, 4243–4264, https://doi.org/10.5194/amt-8-4243-2015, https://doi.org/10.5194/amt-8-4243-2015, 2015
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This paper describes and presents results from a intercomparison, in an environment rich in NOx (i.e., NO+NO2), of two OH reactivity instruments: one based on the comparative reactivity method, and one based on the pump-probe method. Co-located measurements were made of both ambient air and standard mixtures. Ambient OH reactivity values measured by both instruments were found to be in good agreement for ambient NOx mixing ratios as high as 100 ppbv.
F. Xiong, K. M. McAvey, K. A. Pratt, C. J. Groff, M. A. Hostetler, M. A. Lipton, T. K. Starn, J. V. Seeley, S. B. Bertman, A. P. Teng, J. D. Crounse, T. B. Nguyen, P. O. Wennberg, P. K. Misztal, A. H. Goldstein, A. B. Guenther, A. R. Koss, K. F. Olson, J. A. de Gouw, K. Baumann, E. S. Edgerton, P. A. Feiner, L. Zhang, D. O. Miller, W. H. Brune, and P. B. Shepson
Atmos. Chem. Phys., 15, 11257–11272, https://doi.org/10.5194/acp-15-11257-2015, https://doi.org/10.5194/acp-15-11257-2015, 2015
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Hydroxynitrates from isoprene oxidation were quantified both in the laboratory and through field studies. The yield of hydroxynitrates 9(+4/-3)% derived from chamber experiments was applied in a zero-dimensional model to simulate the production and loss of isoprene hydroxynitrates in an ambient environment during the 2013 Southern Oxidant and Aerosol Study (SOAS). NOx was determined to be the limiting factor for the formation of isoprene hydroxynitrates during SOAS.
K. D. Custard, C. R. Thompson, K. A. Pratt, P B. Shepson, J. Liao, L. G. Huey, J. J. Orlando, A. J. Weinheimer, E. Apel, S. R. Hall, F. Flocke, L. Mauldin, R. S. Hornbrook, D. Pöhler, S. General, J. Zielcke, W. R. Simpson, U. Platt, A. Fried, P. Weibring, B. C. Sive, K. Ullmann, C. Cantrell, D. J. Knapp, and D. D. Montzka
Atmos. Chem. Phys., 15, 10799–10809, https://doi.org/10.5194/acp-15-10799-2015, https://doi.org/10.5194/acp-15-10799-2015, 2015
V. Michoud, R. F. Hansen, N. Locoge, P. S. Stevens, and S. Dusanter
Atmos. Meas. Tech., 8, 3537–3553, https://doi.org/10.5194/amt-8-3537-2015, https://doi.org/10.5194/amt-8-3537-2015, 2015
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This study presents the results of an exhaustive characterization of a CRM instrument developed at Mines Douai to measure total OH reactivity in the troposphere. To do so, a suite of laboratory experiments was conducted to assess the different corrections that need to be applied during data processing. The results were then compared to simulations from a 0-D box model, including two different chemical mechanisms, leading to reasonable agreement.
C. R. Thompson, P. B. Shepson, J. Liao, L. G. Huey, E. C. Apel, C. A. Cantrell, F. Flocke, J. Orlando, A. Fried, S. R. Hall, R. S. Hornbrook, D. J. Knapp, R. L. Mauldin III, D. D. Montzka, B. C. Sive, K. Ullmann, P. Weibring, and A. Weinheimer
Atmos. Chem. Phys., 15, 9651–9679, https://doi.org/10.5194/acp-15-9651-2015, https://doi.org/10.5194/acp-15-9651-2015, 2015
K. R. Baker, A. G. Carlton, T. E. Kleindienst, J. H. Offenberg, M. R. Beaver, D. R. Gentner, A. H. Goldstein, P. L. Hayes, J. L. Jimenez, J. B. Gilman, J. A. de Gouw, M. C. Woody, H. O. T. Pye, J. T. Kelly, M. Lewandowski, M. Jaoui, P. S. Stevens, W. H. Brune, Y.-H. Lin, C. L. Rubitschun, and J. D. Surratt
Atmos. Chem. Phys., 15, 5243–5258, https://doi.org/10.5194/acp-15-5243-2015, https://doi.org/10.5194/acp-15-5243-2015, 2015
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This work details the evaluation of PM2.5 carbon, VOC precursors, and OH estimated by the CMAQ photochemical transport model using routine and special measurements from the 2010 CalNex field study. Here, CMAQ and most recent emissions inventory (2011 NEI) are used to generate model PM2.5 OC estimates that are examined in novel ways including primary vs. secondary formation, fossil vs. contemporary carbon, OH and HO2 evaluation, and the relationship between key VOC precursors and SOC tracers.
J. W. Taylor, J. D. Allan, D. Liu, M. Flynn, R. Weber, X. Zhang, B. L. Lefer, N. Grossberg, J. Flynn, and H. Coe
Atmos. Meas. Tech., 8, 1701–1718, https://doi.org/10.5194/amt-8-1701-2015, https://doi.org/10.5194/amt-8-1701-2015, 2015
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When using the SP2 to report black carbon core/shell coating thickness, the core density and refractive index must be estimated from literature values. We systematically vary the assumed parameters and the instrument calibration, and quantify the effects in the derived coatings. The technique is highly sensitive to the core refractive index but has only a minor sensitivity to the core density and coating refractive index. We identify the most appropriate values to use in future analysis.
P. K. Peterson, W. R. Simpson, K. A. Pratt, P. B. Shepson, U. Frieß, J. Zielcke, U. Platt, S. J. Walsh, and S. V. Nghiem
Atmos. Chem. Phys., 15, 2119–2137, https://doi.org/10.5194/acp-15-2119-2015, https://doi.org/10.5194/acp-15-2119-2015, 2015
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We developed methods to measure the vertical distribution of bromine monoxide, a gas that oxidizes pollutants, above sea ice based upon MAX-DOAS observations from Barrow, Alaska, and find that atmospheric stability exerts a strong control on BrO's vertical distribution. Specifically, more stable (temperature inversion) situations result in BrO being closer to the ground while more neutral (not inverted) atmospheres allow BrO to ascend further aloft and grow to larger column abundance.
B. Yuan, P. R. Veres, C. Warneke, J. M. Roberts, J. B. Gilman, A. Koss, P. M. Edwards, M. Graus, W. C. Kuster, S.-M. Li, R. J. Wild, S. S. Brown, W. P. Dubé, B. M. Lerner, E. J. Williams, J. E. Johnson, P. K. Quinn, T. S. Bates, B. Lefer, P. L. Hayes, J. L. Jimenez, R. J. Weber, R. Zamora, B. Ervens, D. B. Millet, B. Rappenglück, and J. A. de Gouw
Atmos. Chem. Phys., 15, 1975–1993, https://doi.org/10.5194/acp-15-1975-2015, https://doi.org/10.5194/acp-15-1975-2015, 2015
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In this work, secondary formation of formic acid at an urban site and a site in an oil and gas production region is studied. We investigated various gas phase formation pathways of formic acid, including those recently proposed, using a box model. The contributions from aerosol-related processes, fog events and air-snow exchange to formic acid are also quantified.
B. H. Czader, Y. Choi, X. Li, S. Alvarez, and B. Lefer
Atmos. Chem. Phys., 15, 1253–1263, https://doi.org/10.5194/acp-15-1253-2015, https://doi.org/10.5194/acp-15-1253-2015, 2015
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Model simulations were performed with increased HONO emissions from mobile sources that reflect recent measurements at high-traffic urban sites. These higher emissions resulted in increased morning concentrations of HONO and OH. O3 concentrations were only marginally altered. Comparison with observed data shows that HONO morning peak concentrations are better predicted by the model when the higher emissions are utilized in the simulation.
C. L. Faiola, B. T. Jobson, and T. M. VanReken
Biogeosciences, 12, 527–547, https://doi.org/10.5194/bg-12-527-2015, https://doi.org/10.5194/bg-12-527-2015, 2015
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Environmental stresses can have large impacts on the emissions of volatile organic compounds from plants, affecting both the amount and the composition of emissions. In this work we demonstrate the variety of responses among five coniferous trees species to one stress-simulated herbivory. The observed responses would lead to significant changes to the atmospheric chemistry in forested regions, highlighting the continued need for improved understanding of biosphere-atmosphere relationships.
S. General, D. Pöhler, H. Sihler, N. Bobrowski, U. Frieß, J. Zielcke, M. Horbanski, P. B. Shepson, B. H. Stirm, W. R. Simpson, K. Weber, C. Fischer, and U. Platt
Atmos. Meas. Tech., 7, 3459–3485, https://doi.org/10.5194/amt-7-3459-2014, https://doi.org/10.5194/amt-7-3459-2014, 2014
M. O. L. Cambaliza, P. B. Shepson, D. R. Caulton, B. Stirm, D. Samarov, K. R. Gurney, J. Turnbull, K. J. Davis, A. Possolo, A. Karion, C. Sweeney, B. Moser, A. Hendricks, T. Lauvaux, K. Mays, J. Whetstone, J. Huang, I. Razlivanov, N. L. Miles, and S. J. Richardson
Atmos. Chem. Phys., 14, 9029–9050, https://doi.org/10.5194/acp-14-9029-2014, https://doi.org/10.5194/acp-14-9029-2014, 2014
A. J. Scarino, M. D. Obland, J. D. Fast, S. P. Burton, R. A. Ferrare, C. A. Hostetler, L. K. Berg, B. Lefer, C. Haman, J. W. Hair, R. R. Rogers, C. Butler, A. L. Cook, and D. B. Harper
Atmos. Chem. Phys., 14, 5547–5560, https://doi.org/10.5194/acp-14-5547-2014, https://doi.org/10.5194/acp-14-5547-2014, 2014
J. W. Halfacre, T. N. Knepp, P. B. Shepson, C. R. Thompson, K. A. Pratt, B. Li, P. K. Peterson, S. J. Walsh, W. R. Simpson, P. A. Matrai, J. W. Bottenheim, S. Netcheva, D. K. Perovich, and A. Richter
Atmos. Chem. Phys., 14, 4875–4894, https://doi.org/10.5194/acp-14-4875-2014, https://doi.org/10.5194/acp-14-4875-2014, 2014
T. P. Riedel, G. M. Wolfe, K. T. Danas, J. B. Gilman, W. C. Kuster, D. M. Bon, A. Vlasenko, S.-M. Li, E. J. Williams, B. M. Lerner, P. R. Veres, J. M. Roberts, J. S. Holloway, B. Lefer, S. S. Brown, and J. A. Thornton
Atmos. Chem. Phys., 14, 3789–3800, https://doi.org/10.5194/acp-14-3789-2014, https://doi.org/10.5194/acp-14-3789-2014, 2014
C. J. Young, R. A. Washenfelder, P. M. Edwards, D. D. Parrish, J. B. Gilman, W. C. Kuster, L. H. Mielke, H. D. Osthoff, C. Tsai, O. Pikelnaya, J. Stutz, P. R. Veres, J. M. Roberts, S. Griffith, S. Dusanter, P. S. Stevens, J. Flynn, N. Grossberg, B. Lefer, J. S. Holloway, J. Peischl, T. B. Ryerson, E. L. Atlas, D. R. Blake, and S. S. Brown
Atmos. Chem. Phys., 14, 3427–3440, https://doi.org/10.5194/acp-14-3427-2014, https://doi.org/10.5194/acp-14-3427-2014, 2014
R. F. Hansen, S. M. Griffith, S. Dusanter, P. S. Rickly, P. S. Stevens, S. B. Bertman, M. A. Carroll, M. H. Erickson, J. H. Flynn, N. Grossberg, B. T. Jobson, B. L. Lefer, and H. W. Wallace
Atmos. Chem. Phys., 14, 2923–2937, https://doi.org/10.5194/acp-14-2923-2014, https://doi.org/10.5194/acp-14-2923-2014, 2014
J. D. Rindelaub, K. M. McAvey, and P. B. Shepson
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-3301-2014, https://doi.org/10.5194/acpd-14-3301-2014, 2014
Revised manuscript not accepted
M. H. Erickson, M. Gueneron, and B. T. Jobson
Atmos. Meas. Tech., 7, 225–239, https://doi.org/10.5194/amt-7-225-2014, https://doi.org/10.5194/amt-7-225-2014, 2014
J. L. Fry, D. C. Draper, K. J. Zarzana, P. Campuzano-Jost, D. A. Day, J. L. Jimenez, S. S. Brown, R. C. Cohen, L. Kaser, A. Hansel, L. Cappellin, T. Karl, A. Hodzic Roux, A. Turnipseed, C. Cantrell, B. L. Lefer, and N. Grossberg
Atmos. Chem. Phys., 13, 8585–8605, https://doi.org/10.5194/acp-13-8585-2013, https://doi.org/10.5194/acp-13-8585-2013, 2013
M. Gyawali, W. P. Arnott, R. A. Zaveri, C. Song, M. Pekour, B. Flowers, M. K. Dubey, A. Setyan, Q. Zhang, J. W. Harworth, J. G. Radney, D. B. Atkinson, S. China, C. Mazzoleni, K. Gorkowski, R. Subramanian, B. T. Jobson, and H. Moosmüller
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-7113-2013, https://doi.org/10.5194/acpd-13-7113-2013, 2013
Revised manuscript not accepted
G. G. Palancar, B. L. Lefer, S. R. Hall, W. J. Shaw, C. A. Corr, S. C. Herndon, J. R. Slusser, and S. Madronich
Atmos. Chem. Phys., 13, 1011–1022, https://doi.org/10.5194/acp-13-1011-2013, https://doi.org/10.5194/acp-13-1011-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer
Atmospheric carbonyl compounds are crucial in regional ozone heavy pollution: insights from the Chengdu Plain Urban Agglomeration, China
Understanding summertime peroxyacetyl nitrate (PAN) formation and its relation to aerosol pollution: insights from high-resolution measurements and modeling
Measurement report: Exploring the variations in ambient BTEX in urban Europe and their environmental health implications
Seasonal air concentration variability, gas–particle partitioning, precipitation scavenging, and air–water equilibrium of organophosphate esters in southern Canada
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
The variations in volatile organic compounds based on the policy change for Omicron in the traffic hub of Zhengzhou
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Measurement report: Long-term measurements of surface ozone and trends in semi-natural sub-Saharan African ecosystems
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant
Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Emissions of Intermediate- and Semi-Volatile Organic Compounds (I/SVOCs) from Different Cumulative Mileage Diesel Vehicles under Various Ambient Temperatures
The impact of organic nitrates on summer ozone formation in Shanghai, China
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation
Mechanistic insights into chloroacetic acid production from atmospheric multiphase VOC-chlorine chemistry
Differences in key volatile organic compound species in ozone formation between their initial and measured concentrations
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis
Measurement report: Elevated atmospheric ammonia may promote particle pH and HONO formation – insights from the COVID-19 pandemic
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Elevated oxidized mercury in the free troposphere: analytical advances and application at a remote continental mountaintop site
Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area
Real-world emission characteristics of VOCs from typical cargo ships and their potential contributions to secondary organic aerosol and O3 under low-sulfur fuel policies
NO3 reactivity during a summer period in a temperate forest below and above the canopy
The role of oceanic ventilation and terrestrial outflow in atmospheric non-methane hydrocarbons over the Chinese marginal seas
Concentration and source changes of nitrous acid (HONO) during the COVID-19 lockdown in Beijing
Characteristics and sources of nonmethane volatile organic compounds (NMVOCs) and O3–NOx–NMVOC relationships in Zhengzhou, China
Measurement report: TURBAN observation campaign combining street-level low-cost air quality sensors and meteorological profile measurements in Prague
Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements
Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany
Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry
Opinion: Strengthening research in the Global South – atmospheric science opportunities in South America and Africa
Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea
Contribution of cooking emissions to the urban volatile organic compounds in Las Vegas, NV
Reanalysis of NOAA H2 observations: implications for the H2 budget
A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation
Diurnal, seasonal, and interannual variations in δ(18O) of atmospheric O2 and its application to evaluate changes in oxygen, carbon, and water cycles
Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion)
Delaney B. Kilgour, Christopher M. Jernigan, Olga Garmash, Sneha Aggarwal, Shengqian Zhou, Claudia Mohr, Matt E. Salter, Joel A. Thornton, Jian Wang, Paul Zieger, and Timothy H. Bertram
Atmos. Chem. Phys., 25, 1931–1947, https://doi.org/10.5194/acp-25-1931-2025, https://doi.org/10.5194/acp-25-1931-2025, 2025
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We report simultaneous measurements of dimethyl sulfide (DMS) and hydroperoxymethyl thioformate (HPMTF) in the eastern North Atlantic. We use an observationally constrained box model to show that cloud loss is the dominant sink of HPMTF in this region over 6 weeks, resulting in large reductions in DMS-derived products that contribute to aerosol formation and growth. Our findings indicate that fast cloud processing of HPMTF must be included in global models to accurately capture the sulfur cycle.
Jiemeng Bao, Xin Zhang, Zhenhai Wu, Li Zhou, Jun Qian, Qinwen Tan, Fumo Yang, Junhui Chen, Yunfeng Li, Hefan Liu, Liqun Deng, and Hong Li
Atmos. Chem. Phys., 25, 1899–1916, https://doi.org/10.5194/acp-25-1899-2025, https://doi.org/10.5194/acp-25-1899-2025, 2025
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We studied carbonyl compounds' role in ozone pollution in the Chengdu Plain Urban Agglomeration, China. During heavy pollution in August 2019, we measured carbonyls at nine sites and analyzed their impact. Areas with higher carbonyl levels, like Chengdu, had worse ozone pollution. While their abundance matters, chemical reactions with other pollutants are the main drivers. Our findings show regional cooperation is vital to reducing ozone pollution effectively.
Baoye Hu, Naihua Chen, Rui Li, Mingqiang Huang, Jinsheng Chen, Youwei Hong, Lingling Xu, Xiaolong Fan, Mengren Li, Lei Tong, Qiuping Zheng, and Yuxiang Yang
Atmos. Chem. Phys., 25, 905–921, https://doi.org/10.5194/acp-25-905-2025, https://doi.org/10.5194/acp-25-905-2025, 2025
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Box modeling with the Master Chemical Mechanism (MCM) was used to explore summertime peroxyacetyl nitrate (PAN) formation and its link to aerosol pollution under high-ozone conditions. The MCM model is effective in the study of PAN photochemical formation and performed better during the clean period than the haze period. Machine learning analysis identified ammonia, nitrate, and fine particulate matter as the top three factors contributing to simulation bias.
Xiansheng Liu, Xun Zhang, Marvin Dufresne, Tao Wang, Lijie Wu, Rosa Lara, Roger Seco, Marta Monge, Ana Maria Yáñez-Serrano, Marie Gohy, Paul Petit, Audrey Chevalier, Marie-Pierre Vagnot, Yann Fortier, Alexia Baudic, Véronique Ghersi, Grégory Gille, Ludovic Lanzi, Valérie Gros, Leïla Simon, Heidi Héllen, Stefan Reimann, Zoé Le Bras, Michelle Jessy Müller, David Beddows, Siqi Hou, Zongbo Shi, Roy M. Harrison, William Bloss, James Dernie, Stéphane Sauvage, Philip K. Hopke, Xiaoli Duan, Taicheng An, Alastair C. Lewis, James R. Hopkins, Eleni Liakakou, Nikolaos Mihalopoulos, Xiaohu Zhang, Andrés Alastuey, Xavier Querol, and Thérèse Salameh
Atmos. Chem. Phys., 25, 625–638, https://doi.org/10.5194/acp-25-625-2025, https://doi.org/10.5194/acp-25-625-2025, 2025
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This study examines BTEX (benzene, toluene, ethylbenzene, xylenes) pollution in urban areas across seven European countries. Analyzing data from 22 monitoring sites, we found traffic and industrial activities significantly impact BTEX levels, with peaks during rush hours. The risk from BTEX exposure remains moderate, especially in high-traffic and industrial zones, highlighting the need for targeted air quality management to protect public health and improve urban air quality.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
Atmos. Chem. Phys., 25, 459–472, https://doi.org/10.5194/acp-25-459-2025, https://doi.org/10.5194/acp-25-459-2025, 2025
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Organophosphate esters are important humanmade trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation, and surface water in Canada, we explore seasonal concentration variability, gas–particle partitioning, precipitation scavenging, and the air–water equilibrium. Whereas higher summer concentrations and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas–particle partitioning is puzzling.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
Atmos. Chem. Phys., 24, 14191–14208, https://doi.org/10.5194/acp-24-14191-2024, https://doi.org/10.5194/acp-24-14191-2024, 2024
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Comprehensive observations of HONO and NOx fluxes were conducted over paddy fields in the Huaihe River Basin. Consecutive peaks in HONO and NO fluxes suggest a potentially enhanced release of HONO and NO due to soil tillage, whereas waterlogged soil may inhibit microbial nitrification processes following irrigation. Notably, biological processes and light-driven NO2 reactions at the surface may serve as sources of HONO and influence the local HONO budget during rotary tillage.
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yuyang Li, Yi Yuan, Junchen Guo, Yiqi Zhao, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
Atmos. Chem. Phys., 24, 13793–13810, https://doi.org/10.5194/acp-24-13793-2024, https://doi.org/10.5194/acp-24-13793-2024, 2024
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Online Vocus-PTR measurements show the compositions and seasonal variations in organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various species at a level of sub-parts per trillion (ppt) and organics with multiple oxygens (≥ 3) were observed. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens, while, in other seasons, the variations in them could be influenced by mixed sources.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
Atmos. Chem. Phys., 24, 13587–13601, https://doi.org/10.5194/acp-24-13587-2024, https://doi.org/10.5194/acp-24-13587-2024, 2024
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To gain insight into the impact of changes due to epidemic control policies, we undertook continuous online monitoring of volatile organic compounds (VOCs) at an urban site in Zhengzhou over a 2-month period. This study examines the characteristics of VOCs, their sources, and their temporal evolution. It also assesses the impact of the policy change on VOC pollution during the monitoring period, thus providing a basis for further research on VOC pollution and source control.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
Atmos. Chem. Phys., 24, 13603–13631, https://doi.org/10.5194/acp-24-13603-2024, https://doi.org/10.5194/acp-24-13603-2024, 2024
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Arctic ozone depletion events (ODEs) occur every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 24, 13151–13182, https://doi.org/10.5194/acp-24-13151-2024, https://doi.org/10.5194/acp-24-13151-2024, 2024
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Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still undersampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase is found at Zoétélé (Cameroon) and Skukuza (South Africa).
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 13199–13217, https://doi.org/10.5194/acp-24-13199-2024, https://doi.org/10.5194/acp-24-13199-2024, 2024
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Biogenic volatile organic compounds (BVOCs) and organic aerosol (OA) particles were measured online in a stressed spruce-dominated forest. OA was mainly attributed to the monoterpene oxidation products. The mixing ratios of BVOCs were higher than the values previously measured in other temperate forests. The results demonstrate that BVOCs are influenced not only by meteorology and biogenic emissions but also by local anthropogenic emissions and subsequent chemical transformation processes.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 13129–13150, https://doi.org/10.5194/acp-24-13129-2024, https://doi.org/10.5194/acp-24-13129-2024, 2024
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
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Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Shuwen Guo, Xuan Zheng, Xiao He, Lewei Zeng, Liqiang He, Xian Wu, Yifei Dai, Zihao Huang, Ting Chen, Shupei Xiao, Yan You, Sheng Xiang, Shaojun Zhang, Jingkun Jiang, and Ye Wu
EGUsphere, https://doi.org/10.5194/egusphere-2024-3290, https://doi.org/10.5194/egusphere-2024-3290, 2024
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We considered two potential influencing factors of heavy-duty diesel vehicle emissions that are rarely mentioned in the literature: cumulative mileage and ambient temperatures. The results suggest that the prolong use of the heavy-duty diesel vehicles and low ambient temperatures lead to reduced engine combustion efficiency, which in turn increases tailpipe emissions significantly.
Chunmeng Li, Xiaorui Chen, Haichao Wang, Tianyu Zhai, Xuefei Ma, Xinping Yang, Shiyi Chen, Min Zhou, Shengrong Lou, Xin Li, Limin Zeng, and Keding Lu
EGUsphere, https://doi.org/10.5194/egusphere-2024-3337, https://doi.org/10.5194/egusphere-2024-3337, 2024
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This study reports an observation of organic nitrate (including total peroxy nitrates and total alkyl nitrates) in Shanghai, China during the summer of 2021, by a homemade thermal dissociation cavity-enhanced absorption spectrometer (TD-CEAS, Atmos. Meas. Tech., 14, 4033–4051, 2021). The distribution of organic nitrates and their effects on local ozone production are analyzed based on the field observation in conjunction with model simulation.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
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We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
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We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
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Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2755, https://doi.org/10.5194/egusphere-2024-2755, 2024
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Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were made based on a 325 m tower in urban Beijing. Vertical changes in concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Mingxue Li, Men Xia, Chunshui Lin, Yifan Jiang, Weihang Sun, Yurun Wang, Yingnan Zhang, Maoxia He, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3137, https://doi.org/10.5194/egusphere-2024-3137, 2024
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Our field campaigns observed a strong diel pattern of chloroacetic acid as well as a strong correlation between its level and those of reactive chlorine species at a coastal site. Using quantum chemical calculations and box model simulation with updated MCM, we found that the formation pathway of chloroacetic acid involved multiphase processes. Our study deepens the understanding of atmospheric VOC-Cl chemistry and highlights the crucial role of multiphase reactions in atmospheric chemistry.
Xudong Zheng and Shaodong Xie
EGUsphere, https://doi.org/10.5194/egusphere-2024-2568, https://doi.org/10.5194/egusphere-2024-2568, 2024
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To reduce uncertainties in identifying key volatile organic compounds (VOCs) affecting ozone (O3) formation, this study focused on identifying key species based on initial VOC concentrations. Using reaction rates and observed VOCs concentrations, we calculated initial VOCs concentrations during the day and the night. Initial concentrations of alkenes and aromatics were higher than observed ones. Conversely, initial oxygenated VOC concentrations were lower than observed concentrations.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
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We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
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Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
Chengzhi Xing, Cheng Liu, Chunxiang Ye, Jingkai Xue, Hongyu Wu, Xiangguang Ji, Jinping Ou, and Qihou Hu
Atmos. Chem. Phys., 24, 10093–10112, https://doi.org/10.5194/acp-24-10093-2024, https://doi.org/10.5194/acp-24-10093-2024, 2024
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We identified the contributions of ozone (O3) and nitrous acid (HONO) to the production rates of hydroxide (OH) in vertical space on the Tibetan Plateau (TP). A new insight was offered: the contributions of HONO and O3 to the production rates of OH on the TP are even greater than in lower-altitudes areas. This study enriches the understanding of vertical distribution of atmospheric components and explains the strong atmospheric oxidation capacity (AOC) on the TP.
Xinyuan Zhang, Lingling Wang, Nan Wang, Shuangliang Ma, Shenbo Wang, Ruiqin Zhang, Dong Zhang, Mingkai Wang, and Hongyu Zhang
Atmos. Chem. Phys., 24, 9885–9898, https://doi.org/10.5194/acp-24-9885-2024, https://doi.org/10.5194/acp-24-9885-2024, 2024
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This study highlights the importance of the redox reaction of NO2 with SO2 based on actual atmospheric observations. The particle pH in future China is expected to rise steadily. Consequently, this reaction could become a significant source of HONO in China. Therefore, it is crucial to coordinate the control of SO2, NOx, and NH3 emissions to avoid a rapid increase in the particle pH.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
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In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
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Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Benjamin A. Nault, Katherine R. Travis, James H. Crawford, Donald R. Blake, Pedro Campuzano-Jost, Ronald C. Cohen, Joshua P. DiGangi, Glenn S. Diskin, Samuel R. Hall, L. Gregory Huey, Jose L. Jimenez, Kyung-Eun Min, Young Ro Lee, Isobel J. Simpson, Kirk Ullmann, and Armin Wisthaler
Atmos. Chem. Phys., 24, 9573–9595, https://doi.org/10.5194/acp-24-9573-2024, https://doi.org/10.5194/acp-24-9573-2024, 2024
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Ozone (O3) is a pollutant formed from the reactions of gases emitted from various sources. In urban areas, the density of human activities can increase the O3 formation rate (P(O3)), thus impacting air quality and health. Observations collected over Seoul, South Korea, are used to constrain P(O3). A high local P(O3) was found; however, local P(O3) was partly reduced due to compounds typically ignored. These observations also provide constraints for unmeasured compounds that will impact P(O3).
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
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Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024, https://doi.org/10.5194/acp-24-8983-2024, 2024
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In the scope of a field campaign in a suburban forest near Paris in the summer of 2022, we measured the reactivity of the nitrate radical NO3 towards biogenic volatile organic compounds (BVOCs; e.g. monoterpenes) mainly below but also above the canopy. NO3 reactivity was the highest during nights with strong temperature inversions and decreased strongly with height. Reactions with BVOCs were the main removal process of NO3 throughout the diel cycle below the canopy.
Jian Wang, Lei Xue, Qianyao Ma, Feng Xu, Gaobin Xu, Shibo Yan, Jiawei Zhang, Jianlong Li, Honghai Zhang, Guiling Zhang, and Zhaohui Chen
Atmos. Chem. Phys., 24, 8721–8736, https://doi.org/10.5194/acp-24-8721-2024, https://doi.org/10.5194/acp-24-8721-2024, 2024
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This study investigated the distribution and sources of non-methane hydrocarbons (NMHCs) in the lower atmosphere over the marginal seas of China. NMHCs, a subset of volatile organic compounds (VOCs), play a crucial role in atmospheric chemistry. Derived from systematic atmospheric sampling in coastal cities and marginal sea regions, this study offers valuable insights into the interaction between land and sea in shaping offshore atmospheric NMHCs.
Yusheng Zhang, Feixue Zheng, Zemin Feng, Chaofan Lian, Weigang Wang, Xiaolong Fan, Wei Ma, Zhuohui Lin, Chang Li, Gen Zhang, Chao Yan, Ying Zhang, Veli-Matti Kerminen, Federico Bianch, Tuukka Petäjä, Juha Kangasluoma, Markku Kulmala, and Yongchun Liu
Atmos. Chem. Phys., 24, 8569–8587, https://doi.org/10.5194/acp-24-8569-2024, https://doi.org/10.5194/acp-24-8569-2024, 2024
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The nitrous acid (HONO) budget was validated during a COVID-19 lockdown event. The main conclusions are (1) HONO concentrations showed a significant decrease from 0.97 to 0.53 ppb during lockdown; (2) vehicle emissions accounted for 53 % of nighttime sources, with the heterogeneous conversion of NO2 on ground surfaces more important than aerosol; and (3) the dominant daytime source shifted from the homogenous reaction between NO and OH (51 %) to nitrate photolysis (53 %) during lockdown.
Dong Zhang, Xiao Li, Minghao Yuan, Yifei Xu, Qixiang Xu, Fangcheng Su, Shenbo Wang, and Ruiqin Zhang
Atmos. Chem. Phys., 24, 8549–8567, https://doi.org/10.5194/acp-24-8549-2024, https://doi.org/10.5194/acp-24-8549-2024, 2024
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The increasing concentration of O3 precursors and unfavorable meteorological conditions are key factors in the formation of O3 pollution in Zhengzhou. Vehicular exhausts (28 %), solvent usage (27 %), and industrial production (22 %) are identified as the main sources of NMVOCs. Moreover, O3 formation in Zhengzhou is found to be in an anthropogenic volatile organic compound (AVOC)-limited regime. Thus, to reduce O3 formation, a minimum AVOCs / NOx reduction ratio ≥ 3 : 1 is recommended.
Petra Bauerová, Josef Keder, Adriana Šindelářová, Ondřej Vlček, William Patiño, Jaroslav Resler, Pavel Krč, Jan Geletič, Hynek Řezníček, Martin Bureš, Kryštof Eben, Michal Belda, Jelena Radović, Vladimír Fuka, Radek Jareš, and Igor Ezau
EGUsphere, https://doi.org/10.5194/egusphere-2024-1222, https://doi.org/10.5194/egusphere-2024-1222, 2024
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We implemented an observation campaign focused on street-level air quality and vertical meteorological profile measurement in Prague using low-cost sensors and remote sensing devices. Low-cost sensors have undergone long-term field testing, own data correction and drift evaluation procedures. A high level of NO2 pollution was confirmed due to the traffic load in streets, peaks of aerosol pollution appeared more under inversion conditions. The data will be further used for PALM model validation.
Arianna Peron, Martin Graus, Marcus Striednig, Christian Lamprecht, Georg Wohlfahrt, and Thomas Karl
Atmos. Chem. Phys., 24, 7063–7083, https://doi.org/10.5194/acp-24-7063-2024, https://doi.org/10.5194/acp-24-7063-2024, 2024
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The anthropogenic fraction of non-methane volatile organic compound (NMVOC) emissions associated with biogenic sources (e.g., terpenes) is investigated based on eddy covariance observations. The anthropogenic fraction of terpene emissions is strongly dependent on season. When analyzing volatile chemical product (VCP) emissions in urban environments, we caution that observations from short-term campaigns might over-/underestimate their significance depending on local and seasonal circumstances.
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024, https://doi.org/10.5194/acp-24-7101-2024, 2024
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Emissions of reactive organic gases from industrial volatile chemical product sources are measured. There are large differences among these industrial sources. We show that oxygenated species account for significant contributions to reactive organic gas emissions, especially for industrial sources utilizing water-borne chemicals.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
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Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Junwei Song, Harald Saathoff, Feng Jiang, Linyu Gao, Hengheng Zhang, and Thomas Leisner
Atmos. Chem. Phys., 24, 6699–6717, https://doi.org/10.5194/acp-24-6699-2024, https://doi.org/10.5194/acp-24-6699-2024, 2024
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This study presents concurrent online measurements of organic gas and particles (VOCs and OA) at a forested site in summer. Both VOCs and OA were largely contributed by oxygenated organic compounds. Semi-volatile oxygenated OA and organic nitrate formed from monoterpenes and sesquiterpenes contributed significantly to nighttime particle growth. The results help us to understand the causes of nighttime particle growth regularly observed in summer in central European rural forested environments.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
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This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Rebecca M. Garland, Katye E. Altieri, Laura Dawidowski, Laura Gallardo, Aderiana Mbandi, Nestor Y. Rojas, and N'datchoh E. Touré
Atmos. Chem. Phys., 24, 5757–5764, https://doi.org/10.5194/acp-24-5757-2024, https://doi.org/10.5194/acp-24-5757-2024, 2024
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This opinion piece focuses on two geographical areas in the Global South where the authors are based that are underrepresented in atmospheric science. This opinion provides context on common challenges and constraints, with suggestions on how the community can address these. The focus is on the strengths of atmospheric science research in these regions. It is these strengths, we believe, that highlight the critical role of Global South researchers in the future of atmospheric science research.
Heidi Hellén, Rostislav Kouznetsov, Kaisa Kraft, Jukka Seppälä, Mika Vestenius, Jukka-Pekka Jalkanen, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 24, 4717–4731, https://doi.org/10.5194/acp-24-4717-2024, https://doi.org/10.5194/acp-24-4717-2024, 2024
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Mixing ratios of C2-C5 NMHCs and methanethiol were measured on an island in the Baltic Sea using an in situ gas chromatograph. Shipping emissions were found to be an important source of ethene, ethyne, propene, and benzene. High summertime mixing ratios of methanethiol and dependence of mixing ratios on seawater temperature and height indicated the biogenic origin to possibly be phytoplankton or macroalgae. These emissions may have a strong impact on SO2 production and new particle formation.
Matthew M. Coggon, Chelsea E. Stockwell, Lu Xu, Jeff Peischl, Jessica B. Gilman, Aaron Lamplugh, Henry J. Bowman, Kenneth Aikin, Colin Harkins, Qindan Zhu, Rebecca H. Schwantes, Jian He, Meng Li, Karl Seltzer, Brian McDonald, and Carsten Warneke
Atmos. Chem. Phys., 24, 4289–4304, https://doi.org/10.5194/acp-24-4289-2024, https://doi.org/10.5194/acp-24-4289-2024, 2024
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Residential and commercial cooking emits pollutants that degrade air quality. Here, ambient observations show that cooking is an important contributor to anthropogenic volatile organic compounds (VOCs) emitted in Las Vegas, NV. These emissions are not fully presented in air quality models, and more work may be needed to quantify emissions from important sources, such as commercial restaurants.
Fabien Paulot, Gabrielle Pétron, Andrew M. Crotwell, and Matteo B. Bertagni
Atmos. Chem. Phys., 24, 4217–4229, https://doi.org/10.5194/acp-24-4217-2024, https://doi.org/10.5194/acp-24-4217-2024, 2024
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New data from the National Oceanic and Atmospheric Administration show that hydrogen (H2) concentrations increased from 2010 to 2019, which is consistent with the simulated increase in H2 photochemical production (mainly from methane). But this cannot be reconciled with the expected decrease (increase) in H2 anthropogenic emissions (soil deposition) in the same period. This shows gaps in our knowledge of the H2 biogeochemical cycle that must be resolved to quantify the impact of higher H2 usage.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
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This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Shigeyuki Ishidoya, Satoshi Sugawara, and Atsushi Okazaki
EGUsphere, https://doi.org/10.5194/egusphere-2024-654, https://doi.org/10.5194/egusphere-2024-654, 2024
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Diurnal, seasonal, and interannual variations of the present-day stable isotopic ratio of atmospheric O2, in other words slight variations in the Dole-Morita effect, have been detected firstly. A box model that incorporated biological and water processes associated with the Dole-Morita effect reproduced the general characteristics of the observational results. Based on the findings, we proposed some applications to evaluate oxygen, carbon, and water cycles.
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024, https://doi.org/10.5194/acp-24-3785-2024, 2024
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Using mass spectrometry data collected at the Maïdo Observatory (2160 m a.s.l., Réunion), we provide the first detailed analysis of molecular cluster chemical composition specifically in the marine free troposphere. The abundance of the identified species is related both to in situ meteorological parameters and air mass history, which also provide insight into their origin. Our work makes an important contribution to documenting the chemistry and physics of the marine free troposphere.
Cited articles
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Blanch, J. S., Llusia, J., Niinemets, U., Noe, S. M., and Penuelas, J.: Instantaneous and historical temperature effects on alpha-pinene emissions in Pinus halepensis and Quercus ilex, J. Environ. Biol., 32, 1–6, 2011.
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Carroll, M. A., Bertman, S. B., and Shepson, P. B.: Overview of the Program for Research on Oxidants: PHotochemistry, Emissions, and Transport (PROPHET) summer 1998 measurements intensive, J. Geophys. Res., 106, 24275–24288, 2001.
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Dusanter, S., Vimal, D., and Stevens, P. S.: Technical note: Measuring tropospheric OH and HO2 by laser-induced fluorescence at low pressure. A comparison of calibration techniques, Atmos. Chem. Phys., 8, 321–340, https://doi.org/10.5194/acp-8-321-2008, 2008.
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., and Molina, L. T.: Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 1: Deployment of the Indiana University laser-induced fluorescence instrument, Atmos. Chem. Phys., 9, 1665–1685, https://doi.org/10.5194/acp-9-1665-2009, 2009a.
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., Molina, L. T., Baker, A., Meinardi, S., Blake, D., Sheehy, P., Merten, A., Zhang, R., Zheng, J., Fortner, E. C., Junkermann, W., Dubey, M., Rahn, T., Eichinger, B., Lewandowski, P., Prueger, J., and Holder, H.: Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 2: Model comparison and radical budget, Atmos. Chem. Phys., 9, 6655–6675, https://doi.org/10.5194/acp-9-6655-2009, 2009b.
Emmerson, K. M., Carslaw, N., Carslaw, D. C., Lee, J. D., McFiggans, G., Bloss, W. J., Gravestock, T., Heard, D. E., Hopkins, J., Ingham, T., Pilling, M. J., Smith, S. C., Jacob, M., and Monks, P. S.: Free radical modelling studies during the UK TORCH Campaign in Summer 2003, Atmos. Chem. Phys., 7, 167–181, https://doi.org/10.5194/acp-7-167-2007, 2007.
Evans, M. J., Shallcross, D. E., Law, K. S., Wild, J. O. F., Simmonds, P. G., Spain, T. G., Berrisford, P., Methven, J., Lewis, A. C., McQuaid, J. B., Pilling, M. J., Bandy, B. J., Penkett, S. A., and Pyle, J. A.: Evaluation of a Lagrangian box model using field measurements from EASE (Eastern Atlantic Summer Experiment) 1996, Atmos. Environ., 34, 3843–3863, 2000.
Faloona, I., Tan, D., Brune, W., Hurst, J., Barket, D., Couch, T. L., Shepson, P., Apel, E., Riemer, D., Thornberry, T., Carroll, M. A., Sillman, S., Keeler, G. J., Sagady, J., Hooper, D., and Paterson, K.: Nighttime observations of anomalously high levels of hydroxyl radicals above a deciduous forest canopy, J. Geophys. Res., 106, 24315–24333, 2001.
Flynn, J., Lefer, B., Rappengluck, B., Leuchner, M., Perna, R., Dibb, J., Ziemba, L., Anderson, C., Stutz, J., Brune, W., Ren, X. R., Mao, J. Q., Luke, W., Olson, J., Chen, G., and Crawford, J.: Impact of clouds and aerosols on ozone production in Southeast Texas, Atmos. Environ., 44, 4126–4133, 2010.
Fuchs, H., Brauers, T., Dorn, H.-P., Harder, H., Häseler, R., Hofzumahaus, A., Holland, F., Kanaya, Y., Kajii, Y., Kubistin, D., Lou, S., Martinez, M., Miyamoto, K., Nishida, S., Rudolf, M., Schlosser, E., Wahner, A., Yoshino, A., and Schurath, U.: Technical Note: Formal blind intercomparison of HO2 measurements in the atmosphere simulation chamber SAPHIR during the HOxComp campaign, Atmos. Chem. Phys., 10, 12233–12250, https://doi.org/10.5194/acp-10-12233-2010, 2010.
Fuchs, H., Bohn, B., Hofzumahaus, A., Holland, F., Lu, K. D., Nehr, S., Rohrer, F., and Wahner, A.: Detection of HO2 by laser-induced fluorescence: calibration and interferences from RO2 radicals, Atmos. Meas. Tech., 4, 1209–1225, https://doi.org/10.5194/amt-4-1209-2011, 2011.
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Hofzumahaus, A., Rohrer, F., Lu, K. D., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S. R., Shao, M., Zeng, L. M., Wahner, A., and Zhang, Y. H.: Amplified Trace Gas Removal in the Troposphere, Science, 324, 1702–1704, 2009.
Holland, F., Hofzumahaus, A., Schäfer, J., Kraus, A., and Pätz, H. W.: Measurements of OH and HO2 radical concentrations and photolysis frequencies during BERLIOZ, J. Geophys. Res., 108, 8246, https://doi.org/10.1029/2001JD001393, 2003.
Hottle, J. R., Huisman, A. J., Digangi, J. P., Kammrath, A., Galloway, M. M., Coens, K. L., and Keutsch, F. N.: A Laser Induced Fluorescence-Based Instrument for In-Situ Measurements of Atmospheric Formaldehyde, Environ. Sci. Technol., 43, 790–795, 2009.
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Jenkin, M. E., Shallcross, D. E., and Harvey, J. N.: Development and application of a possible mechanism for the generation of cis-pinic acid from the ozonolysis of alpha- and beta-pinene, Atmos. Environ., 34, 2837–2850, 2000.
Jobson, B. T. and McCoskey, J. K.: Sample drying to improve HCHO measurements by PTR-MS instruments: laboratory and field measurements, Atmos. Chem. Phys., 10, 1821–1835, https://doi.org/10.5194/acp-10-1821-2010, 2010.
Kanaya, Y., Sadanaga, Y., Nakamura, K., and Akimoto, H.: Development of a ground-based LIF instrument for measuring HOx radicals: instrumentation and calibration, J. Atmos. Chem., 38, 73–110, 2001.
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Kanaya, Y. G., Cao, R. Q., Kato, S. G., Miyakawa, Y. K., Kajii, Y., Tanimoto, H., Yokouchi, Y., Mochida, M., Kawamura, K., and Akimoto, H.: Chemistry of OH and HO2 radicals observed at Rishiri Island, Japan, in September 2003: Missing daytime sink of HO2 and positive nighttime correlations with monoterpenes, J. Geophys. Res., 112, D11308, https://doi.org/10.1029/2006jd007987, 2007.
Karl, M., Dorn, H. P., Holland, F., Koppmann, R., Poppe, D., Rupp, L., Schaub, A., and Wahner, A.: Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR, J. Atmos. Chem., 55, 167–187, 2006.
Konrad, S., Schmitz, T., Buers, H. J., Houben, N., Mannschreck, K., Mihelcic, D., Musgen, P., Patz, H. W., Holland, F., Hofzumahaus, A., Schafer, H. J., Schroder, S., Volz-Thomas, A., Bachmann, K., Schlomski, S., Moortgat, G., and Grossmann, D.: Hydrocarbon measurements at Pabstthum during the BERLIOZ campaign and modeling of free radicals, J. Geophys. Res., 108, 8251, https://doi.org/10.1029/2001jd000866, 2003.
Kubistin, D., Harder, H., Martinez, M., Rudolf, M., Sander, R., Bozem, H., Eerdekens, G., Fischer, H., Gurk, C., Klüpfel, T., Königstedt, R., Parchatka, U., Schiller, C. L., Stickler, A., Taraborrelli, D., Williams, J., and Lelieveld, J.: Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: comparison of measurements with the box model MECCA, Atmos. Chem. Phys., 10, 9705–9728, https://doi.org/10.5194/acp-10-9705-2010, 2010.
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