Articles | Volume 23, issue 7
https://doi.org/10.5194/acp-23-3955-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-23-3955-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Apr 2023
Research article |
| 04 Apr 2023
| 04 Apr 2023
Chemical precursors of new particle formation in coastal New Zealand
Laboratoire de Météorologie Physique, LaMP-UMR 6016, CNRS, Université Clermont Auvergne, 63178, Aubière, France
Clémence Rose
Laboratoire de Météorologie Physique, LaMP-UMR 6016, CNRS, Université Clermont Auvergne, 63178, Aubière, France
Jonathan V. Trueblood
Laboratoire de Météorologie Physique, LaMP-UMR 6016, CNRS, Université Clermont Auvergne, 63178, Aubière, France
Sally Gray
National Institute of Water & Atmospheric Research Ltd (NIWA)
301 Evans Bay Parade, Greta Point, Wellington/Te Whanganui-a-Tara, New Zealand
Mike Harvey
National Institute of Water & Atmospheric Research Ltd (NIWA)
301 Evans Bay Parade, Greta Point, Wellington/Te Whanganui-a-Tara, New Zealand
deceased, 6 August 2022
Karine Sellegri
CORRESPONDING AUTHOR
Laboratoire de Météorologie Physique, LaMP-UMR 6016, CNRS, Université Clermont Auvergne, 63178, Aubière, France
Related authors
Piaopiao Ke, Anna Lintunen, Pasi Kolari, Annalea Lohila, Santeri Tuovinen, Janne Lampilahti, Roseline Thakur, Maija Peltola, Otso Peräkylä, Tuomo Nieminen, Ekaterina Ezhova, Mari Pihlatie, Asta Laasonen, Markku Koskinen, Helena Rautakoski, Laura Heimsch, Tom Kokkonen, Aki Vähä, Ivan Mammarella, Steffen Noe, Jaana Bäck, Veli-Matti Kerminen, and Markku Kulmala
Biogeosciences, 22, 3235–3251, https://doi.org/10.5194/bg-22-3235-2025, https://doi.org/10.5194/bg-22-3235-2025, 2025
Short summary
Short summary
Our research explores diverse ecosystems’ roles in climate cooling via the concept of CarbonSink+ potential. We measured CO2 uptake and local aerosol production in forests, farms, peatlands, urban gardens, and coastal areas across Finland and Estonia. The long-term data reveal that, while forests are vital with regard to CarbonSink+ potential, farms and urban gardens also play significant roles. These insights can help optimize management policy of natural resources to mitigate global warming.
Manon Rocco, Erin Dunne, Alexia Saint-Macary, Maija Peltola, Theresa Barthelmeß, Neill Barr, Karl Safi, Andrew Marriner, Stacy Deppeler, James Harnwell, Anja Engel, Aurélie Colomb, Alfonso Saiz-Lopez, Mike Harvey, Cliff S. Law, and Karine Sellegri
EGUsphere, https://doi.org/10.5194/egusphere-2023-516, https://doi.org/10.5194/egusphere-2023-516, 2023
Preprint archived
Short summary
Short summary
During the Sea2cloud campaign in the Southern Pacific Ocean, we measured air-sea emissions from phytopankton of two key atmospheric compounds: DMS and MeSH. These compounds are well-known to play a great role in atmospheric chemistry and climate. We see in this paper that these compounds are most emited by the nanophytoplankton population. We provide here parameters for climate models to predict future trends of the emissions of these compounds and their roles and impacts on the global warming.
Maija Peltola, Clémence Rose, Jonathan V. Trueblood, Sally Gray, Mike Harvey, and Karine Sellegri
Atmos. Chem. Phys., 22, 6231–6254, https://doi.org/10.5194/acp-22-6231-2022, https://doi.org/10.5194/acp-22-6231-2022, 2022
Short summary
Short summary
Despite the importance of marine aerosol measurements for constraining climate models, these measurements are scarce. We measured the aerosol particle number size distribution in coastal New Zealand over a total period of 10 months. This paper analyses the aerosol properties at the site, with a special focus on new particle formation and marine air masses. New particle formation was observed frequently, but in marine air masses it did not follow traditional event criteria.
Zoé Brasseur, Dimitri Castarède, Erik S. Thomson, Michael P. Adams, Saskia Drossaart van Dusseldorp, Paavo Heikkilä, Kimmo Korhonen, Janne Lampilahti, Mikhail Paramonov, Julia Schneider, Franziska Vogel, Yusheng Wu, Jonathan P. D. Abbatt, Nina S. Atanasova, Dennis H. Bamford, Barbara Bertozzi, Matthew Boyer, David Brus, Martin I. Daily, Romy Fösig, Ellen Gute, Alexander D. Harrison, Paula Hietala, Kristina Höhler, Zamin A. Kanji, Jorma Keskinen, Larissa Lacher, Markus Lampimäki, Janne Levula, Antti Manninen, Jens Nadolny, Maija Peltola, Grace C. E. Porter, Pyry Poutanen, Ulrike Proske, Tobias Schorr, Nsikanabasi Silas Umo, János Stenszky, Annele Virtanen, Dmitri Moisseev, Markku Kulmala, Benjamin J. Murray, Tuukka Petäjä, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 22, 5117–5145, https://doi.org/10.5194/acp-22-5117-2022, https://doi.org/10.5194/acp-22-5117-2022, 2022
Short summary
Short summary
The present measurement report introduces the ice nucleation campaign organized in Hyytiälä, Finland, in 2018 (HyICE-2018). We provide an overview of the campaign settings, and we describe the measurement infrastructure and operating procedures used. In addition, we use results from ice nucleation instrument inter-comparison to show that the suite of these instruments deployed during the campaign reports consistent results.
Stefanie Kremser, Mike Harvey, Peter Kuma, Sean Hartery, Alexia Saint-Macary, John McGregor, Alex Schuddeboom, Marc von Hobe, Sinikka T. Lennartz, Alex Geddes, Richard Querel, Adrian McDonald, Maija Peltola, Karine Sellegri, Israel Silber, Cliff S. Law, Connor J. Flynn, Andrew Marriner, Thomas C. J. Hill, Paul J. DeMott, Carson C. Hume, Graeme Plank, Geoffrey Graham, and Simon Parsons
Earth Syst. Sci. Data, 13, 3115–3153, https://doi.org/10.5194/essd-13-3115-2021, https://doi.org/10.5194/essd-13-3115-2021, 2021
Short summary
Short summary
Aerosol–cloud interactions over the Southern Ocean are poorly understood and remain a major source of uncertainty in climate models. This study presents ship-borne measurements, collected during a 6-week voyage into the Southern Ocean in 2018, that are an important supplement to satellite-based measurements. For example, these measurements include data on low-level clouds and aerosol composition in the marine boundary layer, which can be used in climate model evaluation efforts.
Janne Lampilahti, Katri Leino, Antti Manninen, Pyry Poutanen, Anna Franck, Maija Peltola, Paula Hietala, Lisa Beck, Lubna Dada, Lauriane Quéléver, Ronja Öhrnberg, Ying Zhou, Madeleine Ekblom, Ville Vakkari, Sergej Zilitinkevich, Veli-Matti Kerminen, Tuukka Petäjä, and Markku Kulmala
Atmos. Chem. Phys., 21, 7901–7915, https://doi.org/10.5194/acp-21-7901-2021, https://doi.org/10.5194/acp-21-7901-2021, 2021
Short summary
Short summary
Using airborne measurements we observed increased number concentrations of sub-25 nm particles in the upper residual layer. These particles may be entrained into the well-mixed boundary layer and observed at the surface. We attribute our observations to new particle formation in the topmost part of the residual layer.
Ilona Ylivinkka, Santeri Kaupinmäki, Meri Virman, Maija Peltola, Ditte Taipale, Tuukka Petäjä, Veli-Matti Kerminen, Markku Kulmala, and Ekaterina Ezhova
Atmos. Meas. Tech., 13, 5595–5619, https://doi.org/10.5194/amt-13-5595-2020, https://doi.org/10.5194/amt-13-5595-2020, 2020
Short summary
Short summary
In this study, we developed a new algorithm for cloud classification using solar radiation and cloud base height measurements. Our objective was to develop a simple and inexpensive but effective algorithm for the needs of studies related to ecosystem and atmosphere interactions. In the present study, we used the algorithm for obtaining cloud statistics at a measurement station in southern Finland, and we discuss the advantages and shortcomings of the algorithm.
Yannick Bras, Evelyn Freney, Mar Benavides, Estelle Bigeard, Gabriel Dulaquais, Céline Dimier, Laetitia Bouvier, Mickaël Ribeiro, Cécile Guieu, Sophie Bonnet, and Karine Sellegri
EGUsphere, https://doi.org/10.5194/egusphere-2025-3580, https://doi.org/10.5194/egusphere-2025-3580, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
In marine regions, sea spray aerosols may act as ice nucleating particles to promote the formation of ice crystals in the atmosphere. Here, we study the ice nucleating properties of the seawater and of generated sea spray measured during a ship campaign in contrasted waters, including hydrothermal-influenced waters. We report that the majority of particles were of biological origin, and that their variability closely followed the local biological activity.
Piaopiao Ke, Anna Lintunen, Pasi Kolari, Annalea Lohila, Santeri Tuovinen, Janne Lampilahti, Roseline Thakur, Maija Peltola, Otso Peräkylä, Tuomo Nieminen, Ekaterina Ezhova, Mari Pihlatie, Asta Laasonen, Markku Koskinen, Helena Rautakoski, Laura Heimsch, Tom Kokkonen, Aki Vähä, Ivan Mammarella, Steffen Noe, Jaana Bäck, Veli-Matti Kerminen, and Markku Kulmala
Biogeosciences, 22, 3235–3251, https://doi.org/10.5194/bg-22-3235-2025, https://doi.org/10.5194/bg-22-3235-2025, 2025
Short summary
Short summary
Our research explores diverse ecosystems’ roles in climate cooling via the concept of CarbonSink+ potential. We measured CO2 uptake and local aerosol production in forests, farms, peatlands, urban gardens, and coastal areas across Finland and Estonia. The long-term data reveal that, while forests are vital with regard to CarbonSink+ potential, farms and urban gardens also play significant roles. These insights can help optimize management policy of natural resources to mitigate global warming.
Diego Aliaga, Victoria A. Sinclair, Radovan Krejci, Marcos Andrade, Paulo Artaxo, Luis Blacutt, Runlong Cai, Samara Carbone, Yvette Gramlich, Liine Heikkinen, Dominic Heslin-Rees, Wei Huang, Veli-Matti Kerminen, Alkuin Maximilian Koenig, Markku Kulmala, Paolo Laj, Valeria Mardoñez-Balderrama, Claudia Mohr, Isabel Moreno, Pauli Paasonen, Wiebke Scholz, Karine Sellegri, Laura Ticona, Gaëlle Uzu, Fernando Velarde, Alfred Wiedensohler, Doug Worsnop, Cheng Wu, Chen Xuemeng, Qiaozhi Zha, and Federico Bianchi
Aerosol Research, 3, 15–44, https://doi.org/10.5194/ar-3-15-2025, https://doi.org/10.5194/ar-3-15-2025, 2025
Short summary
Short summary
This study examines new particle formation (NPF) in the Bolivian Andes at Chacaltaya mountain (CHC) and the urban El Alto–La Paz area (EAC). Days are clustered into four categories based on NPF intensity. Differences in particle size, precursor gases, and pollution levels are found. High NPF intensities increased Aitken mode particle concentrations at both sites, while volcanic influence selectively diminished NPF intensity at CHC but not EAC. This study highlights NPF dynamics in the Andes.
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024, https://doi.org/10.5194/acp-24-3785-2024, 2024
Short summary
Short summary
Using mass spectrometry data collected at the Maïdo Observatory (2160 m a.s.l., Réunion), we provide the first detailed analysis of molecular cluster chemical composition specifically in the marine free troposphere. The abundance of the identified species is related both to in situ meteorological parameters and air mass history, which also provide insight into their origin. Our work makes an important contribution to documenting the chemistry and physics of the marine free troposphere.
Arto Heitto, Cheng Wu, Diego Aliaga, Luis Blacutt, Xuemeng Chen, Yvette Gramlich, Liine Heikkinen, Wei Huang, Radovan Krejci, Paolo Laj, Isabel Moreno, Karine Sellegri, Fernando Velarde, Kay Weinhold, Alfred Wiedensohler, Qiaozhi Zha, Federico Bianchi, Marcos Andrade, Kari E. J. Lehtinen, Claudia Mohr, and Taina Yli-Juuti
Atmos. Chem. Phys., 24, 1315–1328, https://doi.org/10.5194/acp-24-1315-2024, https://doi.org/10.5194/acp-24-1315-2024, 2024
Short summary
Short summary
Particle growth at the Chacaltaya station in Bolivia was simulated based on measured vapor concentrations and ambient conditions. Major contributors to the simulated growth were low-volatility organic compounds (LVOCs). Also, sulfuric acid had major role when volcanic activity was occurring in the area. This study provides insight on nanoparticle growth at this high-altitude Southern Hemispheric site and hence contributes to building knowledge of early growth of atmospheric particles.
Karine Sellegri, Theresa Barthelmeß, Jonathan Trueblood, Antonia Cristi, Evelyn Freney, Clémence Rose, Neill Barr, Mike Harvey, Karl Safi, Stacy Deppeler, Karen Thompson, Wayne Dillon, Anja Engel, and Cliff Law
Atmos. Chem. Phys., 23, 12949–12964, https://doi.org/10.5194/acp-23-12949-2023, https://doi.org/10.5194/acp-23-12949-2023, 2023
Short summary
Short summary
The amount of sea spray emitted to the atmosphere depends on the ocean temperature, but this dependency is not well understood, especially when ocean biology is involved. In this study, we show that sea spray emissions are increased by up to a factor of 4 at low seawater temperatures compared to moderate temperatures, and we quantify the temperature dependence as a function of the ocean biogeochemistry.
Manon Rocco, Erin Dunne, Alexia Saint-Macary, Maija Peltola, Theresa Barthelmeß, Neill Barr, Karl Safi, Andrew Marriner, Stacy Deppeler, James Harnwell, Anja Engel, Aurélie Colomb, Alfonso Saiz-Lopez, Mike Harvey, Cliff S. Law, and Karine Sellegri
EGUsphere, https://doi.org/10.5194/egusphere-2023-516, https://doi.org/10.5194/egusphere-2023-516, 2023
Preprint archived
Short summary
Short summary
During the Sea2cloud campaign in the Southern Pacific Ocean, we measured air-sea emissions from phytopankton of two key atmospheric compounds: DMS and MeSH. These compounds are well-known to play a great role in atmospheric chemistry and climate. We see in this paper that these compounds are most emited by the nanophytoplankton population. We provide here parameters for climate models to predict future trends of the emissions of these compounds and their roles and impacts on the global warming.
Alexia D. Saint-Macary, Andrew Marriner, Theresa Barthelmeß, Stacy Deppeler, Karl Safi, Rafael Costa Santana, Mike Harvey, and Cliff S. Law
Ocean Sci., 19, 1–15, https://doi.org/10.5194/os-19-1-2023, https://doi.org/10.5194/os-19-1-2023, 2023
Short summary
Short summary
The uppermost oceanic layer was sampled to determine what can explain a potential dimethyl sulfide (DMS) enrichment in this environment. A novel sampling method was used, and the results showed that DMS was not as enriched as expected. Our results showed that the phytoplanktonic composition influenced the DMS concentration, confirming results from another study in this oceanic region. However, additional factors are required to observe a DMS enrichment in the uppermost oceanic layer.
Suzanne Crumeyrolle, Jenni S. S. Kontkanen, Clémence Rose, Alejandra Velazquez Garcia, Eric Bourrianne, Maxime Catalfamo, Véronique Riffault, Emmanuel Tison, Joel Ferreira de Brito, Nicolas Visez, Nicolas Ferlay, Frédérique Auriol, and Isabelle Chiapello
Atmos. Chem. Phys., 23, 183–201, https://doi.org/10.5194/acp-23-183-2023, https://doi.org/10.5194/acp-23-183-2023, 2023
Short summary
Short summary
Ultrafine particles (UFPs) are particles with an aerodynamic diameter of 100 nm or less and negligible mass concentration but are the dominant contributor to the total particle number concentration. The present study aims to better understand the environmental factors favoring or inhibiting atmospheric new particle formation (NPF) over Lille, a large city in the north of France, and to analyze the impact of such an event on urban air quality using a long-term dataset (3 years).
Maija Peltola, Clémence Rose, Jonathan V. Trueblood, Sally Gray, Mike Harvey, and Karine Sellegri
Atmos. Chem. Phys., 22, 6231–6254, https://doi.org/10.5194/acp-22-6231-2022, https://doi.org/10.5194/acp-22-6231-2022, 2022
Short summary
Short summary
Despite the importance of marine aerosol measurements for constraining climate models, these measurements are scarce. We measured the aerosol particle number size distribution in coastal New Zealand over a total period of 10 months. This paper analyses the aerosol properties at the site, with a special focus on new particle formation and marine air masses. New particle formation was observed frequently, but in marine air masses it did not follow traditional event criteria.
Zoé Brasseur, Dimitri Castarède, Erik S. Thomson, Michael P. Adams, Saskia Drossaart van Dusseldorp, Paavo Heikkilä, Kimmo Korhonen, Janne Lampilahti, Mikhail Paramonov, Julia Schneider, Franziska Vogel, Yusheng Wu, Jonathan P. D. Abbatt, Nina S. Atanasova, Dennis H. Bamford, Barbara Bertozzi, Matthew Boyer, David Brus, Martin I. Daily, Romy Fösig, Ellen Gute, Alexander D. Harrison, Paula Hietala, Kristina Höhler, Zamin A. Kanji, Jorma Keskinen, Larissa Lacher, Markus Lampimäki, Janne Levula, Antti Manninen, Jens Nadolny, Maija Peltola, Grace C. E. Porter, Pyry Poutanen, Ulrike Proske, Tobias Schorr, Nsikanabasi Silas Umo, János Stenszky, Annele Virtanen, Dmitri Moisseev, Markku Kulmala, Benjamin J. Murray, Tuukka Petäjä, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 22, 5117–5145, https://doi.org/10.5194/acp-22-5117-2022, https://doi.org/10.5194/acp-22-5117-2022, 2022
Short summary
Short summary
The present measurement report introduces the ice nucleation campaign organized in Hyytiälä, Finland, in 2018 (HyICE-2018). We provide an overview of the campaign settings, and we describe the measurement infrastructure and operating procedures used. In addition, we use results from ice nucleation instrument inter-comparison to show that the suite of these instruments deployed during the campaign reports consistent results.
Clémence Rose, Martine Collaud Coen, Elisabeth Andrews, Yong Lin, Isaline Bossert, Cathrine Lund Myhre, Thomas Tuch, Alfred Wiedensohler, Markus Fiebig, Pasi Aalto, Andrés Alastuey, Elisabeth Alonso-Blanco, Marcos Andrade, Begoña Artíñano, Todor Arsov, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Juan Andrés Casquero-Vera, Sébastien Conil, Konstantinos Eleftheriadis, Olivier Favez, Harald Flentje, Maria I. Gini, Francisco Javier Gómez-Moreno, Martin Gysel-Beer, Anna Gannet Hallar, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Adam Kristensson, Markku Kulmala, Heikki Lihavainen, Neng-Huei Lin, Hassan Lyamani, Angela Marinoni, Sebastiao Martins Dos Santos, Olga L. Mayol-Bracero, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Jakub Ondracek, Marco Pandolfi, Noemi Pérez, Tuukka Petäjä, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Jean-Philippe Putaud, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Junying Sun, Pierre Tulet, Ville Vakkari, Pieter Gideon van Zyl, Fernando Velarde, Paolo Villani, Stergios Vratolis, Zdenek Wagner, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Vladimir Zdimal, and Paolo Laj
Atmos. Chem. Phys., 21, 17185–17223, https://doi.org/10.5194/acp-21-17185-2021, https://doi.org/10.5194/acp-21-17185-2021, 2021
Short summary
Short summary
Aerosol particles are a complex component of the atmospheric system the effects of which are among the most uncertain in climate change projections. Using data collected at 62 stations, this study provides the most up-to-date picture of the spatial distribution of particle number concentration and size distribution worldwide, with the aim of contributing to better representation of aerosols and their interactions with clouds in models and, therefore, better evaluation of their impact on climate.
Alexandre Kukui, Michel Chartier, Jinhe Wang, Hui Chen, Sébastien Dusanter, Stéphane Sauvage, Vincent Michoud, Nadine Locoge, Valérie Gros, Thierry Bourrianne, Karine Sellegri, and Jean-Marc Pichon
Atmos. Chem. Phys., 21, 13333–13351, https://doi.org/10.5194/acp-21-13333-2021, https://doi.org/10.5194/acp-21-13333-2021, 2021
Short summary
Short summary
Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles. It is generally accepted that the major atmospheric source of H2SO4 is the reaction of OH radicals with SO2. In this study, importance of an additional H2SO4 source via oxidation of SO2 by stabilized Criegee intermediates was estimated based on measurements at a remote site on Cape Corsica. It was found that the oxidation of SO2 by SCI may be an important source of H2SO4, especially during nighttime.
Stefanie Kremser, Mike Harvey, Peter Kuma, Sean Hartery, Alexia Saint-Macary, John McGregor, Alex Schuddeboom, Marc von Hobe, Sinikka T. Lennartz, Alex Geddes, Richard Querel, Adrian McDonald, Maija Peltola, Karine Sellegri, Israel Silber, Cliff S. Law, Connor J. Flynn, Andrew Marriner, Thomas C. J. Hill, Paul J. DeMott, Carson C. Hume, Graeme Plank, Geoffrey Graham, and Simon Parsons
Earth Syst. Sci. Data, 13, 3115–3153, https://doi.org/10.5194/essd-13-3115-2021, https://doi.org/10.5194/essd-13-3115-2021, 2021
Short summary
Short summary
Aerosol–cloud interactions over the Southern Ocean are poorly understood and remain a major source of uncertainty in climate models. This study presents ship-borne measurements, collected during a 6-week voyage into the Southern Ocean in 2018, that are an important supplement to satellite-based measurements. For example, these measurements include data on low-level clouds and aerosol composition in the marine boundary layer, which can be used in climate model evaluation efforts.
Janne Lampilahti, Katri Leino, Antti Manninen, Pyry Poutanen, Anna Franck, Maija Peltola, Paula Hietala, Lisa Beck, Lubna Dada, Lauriane Quéléver, Ronja Öhrnberg, Ying Zhou, Madeleine Ekblom, Ville Vakkari, Sergej Zilitinkevich, Veli-Matti Kerminen, Tuukka Petäjä, and Markku Kulmala
Atmos. Chem. Phys., 21, 7901–7915, https://doi.org/10.5194/acp-21-7901-2021, https://doi.org/10.5194/acp-21-7901-2021, 2021
Short summary
Short summary
Using airborne measurements we observed increased number concentrations of sub-25 nm particles in the upper residual layer. These particles may be entrained into the well-mixed boundary layer and observed at the surface. We attribute our observations to new particle formation in the topmost part of the residual layer.
Clémence Rose, Matti P. Rissanen, Siddharth Iyer, Jonathan Duplissy, Chao Yan, John B. Nowak, Aurélie Colomb, Régis Dupuy, Xu-Cheng He, Janne Lampilahti, Yee Jun Tham, Daniela Wimmer, Jean-Marc Metzger, Pierre Tulet, Jérôme Brioude, Céline Planche, Markku Kulmala, and Karine Sellegri
Atmos. Chem. Phys., 21, 4541–4560, https://doi.org/10.5194/acp-21-4541-2021, https://doi.org/10.5194/acp-21-4541-2021, 2021
Short summary
Short summary
Sulfuric acid (H2SO4) is commonly accepted as a key precursor for atmospheric new particle formation. However, direct measurements of [H2SO4] remain challenging, motivating the development of proxies. Using data collected in two different volcanic plumes, we show, under these specific conditions, the good performance of a proxy from the literature and also highlight the benefit of the newly developed proxies for the prediction of the highest [H2SO4] values.
Alkuin Maximilian Koenig, Olivier Magand, Paolo Laj, Marcos Andrade, Isabel Moreno, Fernando Velarde, Grover Salvatierra, René Gutierrez, Luis Blacutt, Diego Aliaga, Thomas Reichler, Karine Sellegri, Olivier Laurent, Michel Ramonet, and Aurélien Dommergue
Atmos. Chem. Phys., 21, 3447–3472, https://doi.org/10.5194/acp-21-3447-2021, https://doi.org/10.5194/acp-21-3447-2021, 2021
Short summary
Short summary
The environmental cycling of atmospheric mercury, a harmful global contaminant, is still not sufficiently constrained, partly due to missing data in remote regions. Here, we address this issue by presenting 20 months of atmospheric mercury measurements, sampled in the Bolivian Andes. We observe a significant seasonal pattern, whose key features we explore. Moreover, we deduce ratios to constrain South American biomass burning mercury emissions and the mercury uptake by the Amazon rainforest.
Nikolaos Evangeliou, Stephen M. Platt, Sabine Eckhardt, Cathrine Lund Myhre, Paolo Laj, Lucas Alados-Arboledas, John Backman, Benjamin T. Brem, Markus Fiebig, Harald Flentje, Angela Marinoni, Marco Pandolfi, Jesus Yus-Dìez, Natalia Prats, Jean P. Putaud, Karine Sellegri, Mar Sorribas, Konstantinos Eleftheriadis, Stergios Vratolis, Alfred Wiedensohler, and Andreas Stohl
Atmos. Chem. Phys., 21, 2675–2692, https://doi.org/10.5194/acp-21-2675-2021, https://doi.org/10.5194/acp-21-2675-2021, 2021
Short summary
Short summary
Following the transmission of SARS-CoV-2 to Europe, social distancing rules were introduced to prevent further spread. We investigate the impacts of the European lockdowns on black carbon (BC) emissions by means of in situ observations and inverse modelling. BC emissions declined by 23 kt in Europe during the lockdowns as compared with previous years and by 11 % as compared to the period prior to lockdowns. Residential combustion prevailed in Eastern Europe, as confirmed by remote sensing data.
André Welti, E. Keith Bigg, Paul J. DeMott, Xianda Gong, Markus Hartmann, Mike Harvey, Silvia Henning, Paul Herenz, Thomas C. J. Hill, Blake Hornblow, Caroline Leck, Mareike Löffler, Christina S. McCluskey, Anne Marie Rauker, Julia Schmale, Christian Tatzelt, Manuela van Pinxteren, and Frank Stratmann
Atmos. Chem. Phys., 20, 15191–15206, https://doi.org/10.5194/acp-20-15191-2020, https://doi.org/10.5194/acp-20-15191-2020, 2020
Short summary
Short summary
Ship-based measurements of maritime ice nuclei concentrations encompassing all oceans are compiled. From this overview it is found that maritime ice nuclei concentrations are typically 10–100 times lower than over continents, while concentrations are surprisingly similar in different oceanic regions. The analysis of the influence of ship emissions shows no effect on the data, making ship-based measurements an efficient strategy for the large-scale exploration of ice nuclei concentrations.
Ilona Ylivinkka, Santeri Kaupinmäki, Meri Virman, Maija Peltola, Ditte Taipale, Tuukka Petäjä, Veli-Matti Kerminen, Markku Kulmala, and Ekaterina Ezhova
Atmos. Meas. Tech., 13, 5595–5619, https://doi.org/10.5194/amt-13-5595-2020, https://doi.org/10.5194/amt-13-5595-2020, 2020
Short summary
Short summary
In this study, we developed a new algorithm for cloud classification using solar radiation and cloud base height measurements. Our objective was to develop a simple and inexpensive but effective algorithm for the needs of studies related to ecosystem and atmosphere interactions. In the present study, we used the algorithm for obtaining cloud statistics at a measurement station in southern Finland, and we discuss the advantages and shortcomings of the algorithm.
Martin Heinritzi, Lubna Dada, Mario Simon, Dominik Stolzenburg, Andrea C. Wagner, Lukas Fischer, Lauri R. Ahonen, Stavros Amanatidis, Rima Baalbaki, Andrea Baccarini, Paulus S. Bauer, Bernhard Baumgartner, Federico Bianchi, Sophia Brilke, Dexian Chen, Randall Chiu, Antonio Dias, Josef Dommen, Jonathan Duplissy, Henning Finkenzeller, Carla Frege, Claudia Fuchs, Olga Garmash, Hamish Gordon, Manuel Granzin, Imad El Haddad, Xucheng He, Johanna Helm, Victoria Hofbauer, Christopher R. Hoyle, Juha Kangasluoma, Timo Keber, Changhyuk Kim, Andreas Kürten, Houssni Lamkaddam, Tiia M. Laurila, Janne Lampilahti, Chuan Ping Lee, Katrianne Lehtipalo, Markus Leiminger, Huajun Mai, Vladimir Makhmutov, Hanna Elina Manninen, Ruby Marten, Serge Mathot, Roy Lee Mauldin, Bernhard Mentler, Ugo Molteni, Tatjana Müller, Wei Nie, Tuomo Nieminen, Antti Onnela, Eva Partoll, Monica Passananti, Tuukka Petäjä, Joschka Pfeifer, Veronika Pospisilova, Lauriane L. J. Quéléver, Matti P. Rissanen, Clémence Rose, Siegfried Schobesberger, Wiebke Scholz, Kay Scholze, Mikko Sipilä, Gerhard Steiner, Yuri Stozhkov, Christian Tauber, Yee Jun Tham, Miguel Vazquez-Pufleau, Annele Virtanen, Alexander L. Vogel, Rainer Volkamer, Robert Wagner, Mingyi Wang, Lena Weitz, Daniela Wimmer, Mao Xiao, Chao Yan, Penglin Ye, Qiaozhi Zha, Xueqin Zhou, Antonio Amorim, Urs Baltensperger, Armin Hansel, Markku Kulmala, António Tomé, Paul M. Winkler, Douglas R. Worsnop, Neil M. Donahue, Jasper Kirkby, and Joachim Curtius
Atmos. Chem. Phys., 20, 11809–11821, https://doi.org/10.5194/acp-20-11809-2020, https://doi.org/10.5194/acp-20-11809-2020, 2020
Short summary
Short summary
With experiments performed at CLOUD, we show how isoprene interferes in monoterpene oxidation via RO2 termination at atmospherically relevant concentrations. This interference shifts the distribution of highly oxygenated organic molecules (HOMs) away from C20 class dimers towards C15 class dimers, which subsequently reduces both biogenic nucleation and early growth rates. Our results may help to understand the absence of new-particle formation in isoprene-rich environments.
Cited articles
Alpert, P. A., Ciuraru, R., Rossignol, S., Passananti, M., Tinel, L., Perrier, S., Dupart, Y., Steimer, S. S., Ammann, M., Donaldson, D. J., and George, C.: Fatty acid surfactant photochemistry results in new particle formation, Sci. Rep., 7, 12693, https://doi.org/10.1038/s41598-017-12601-2, 2017. a
Arnold, S. R., Spracklen, D. V., Williams, J., Yassaa, N., Sciare, J., Bonsang, B., Gros, V., Peeken, I., Lewis, A. C., Alvain, S., and Moulin, C.: Evaluation of the global oceanic isoprene source and its impacts on marine organic carbon aerosol, Atmos. Chem. Phys., 9, 1253–1262, https://doi.org/10.5194/acp-9-1253-2009, 2009. a
Baccarini, A., Karlsson, L., Dommen, J., Duplessis, P., Vüllers, J., Brooks, I. M., Saiz-Lopez, A., Salter, M., Tjernström, M., Baltensperger,
U., Zieger, P., and Schmale, J.: Frequent new particle formation over the high Arctic pack ice by
enhanced iodine emissions, Nat. Commun., 11, 1–11, 2020. a
Baccarini, A., Dommen, J., Lehtipalo, K., Henning, S., Modini, R. L., Gysel-Beer, M., Baltensperger, U., and Schmale, J.: Low-volatility vapors and new particle formation over the Southern Ocean during the Antarctic Circumnavigation Expedition, J. Geophys. Res.-Atmos., 126, e2021JD035126, https://doi.org/10.1029/2021JD035126, 2021. a, b, c, d, e, f, g
Beck, L. J., Sarnela, N., Junninen, H., Hoppe, C. J. M., Garmash, O., Bianchi, F., Riva, M., Rose, C., Peräkylä, O., Wimmer, D., Kausiala, O., Jokinen, T., Ahonen, L., Mikkilä, J., Hakala, J., He, X.-C., Kontkanen, J., Wolf, K. K. E., Cappelletti, D., Mazzola, M., Traversi, R., Petroselli, C., Viola, A. P., Vitale, V., Lange, R., Massling, A., Nøjgaard, J. K., Krejci, R., Karlsson, L., Zieger, P., Jang, S., Lee, K., Vakkari, V., Lampilahti, J.,
Thakur, R. C., Leino, K., Kangasluoma, J., Duplissy, E.-M., Siivola, E.,
Marbouti, M., Tham, Y. J., Saiz-Lopez, A., Petäjä, T., Ehn, M., Worsnop,
D. R., Skov, H., Kulmala, M., Kerminen, V.-M., and Sipilä, M.: Differing
mechanisms of new particle formation at two Arctic sites,
Geophys. Res. Lett., 48, e2020GL091334, https://doi.org/10.1029/2020GL091334, 2021. a, b
Beck, L. J., Schobesberger, S., Sipilä, M., Kerminen, V.-M., and Kulmala, M.: Estimation of sulfuric acid concentration using ambient ion composition and concentration data obtained with atmospheric pressure interface time-of-flight ion mass spectrometer, Atmos. Meas. Tech., 15, 1957–1965, https://doi.org/10.5194/amt-15-1957-2022, 2022. a, b
Berresheim, H., Elste, T., Tremmel, H. G., Allen, A. G., Hansson, H.-C., Rosman, K., Dal Maso, M., Mäkelä, J. M., Kulmala, M., and O'Dowd, C. D.: Gas-aerosol relationships of H2SO4, MSA, and OH: Observations in the coastal marine boundary layer at Mace Head, Ireland, J. Geophys. Res.-Atmos., 107, PAR 5-1–PAR 5-12, https://doi.org/10.1029/2000JD000229, 2002. a
Bianchi, F., Garmash, O., He, X., Yan, C., Iyer, S., Rosendahl, I., Xu, Z., Rissanen, M. P., Riva, M., Taipale, R., Sarnela, N., Petäjä, T., Worsnop, D. R., Kulmala, M., Ehn, M., and Junninen, H.: The role of highly oxygenated molecules (HOMs) in determining the composition of ambient ions in the boreal forest, Atmos. Chem. Phys., 17, 13819–13831, https://doi.org/10.5194/acp-17-13819-2017, 2017. a, b, c
Bianchi, F., Kurtén, T., Riva, M., Mohr, C., Rissanen, M. P., Roldin, P.,
Berndt, T., Crounse, J. D., Wennberg, P. O., Mentel, T. F., Wildt J, Junninen, H., Jokinen, T., Kulmala, M., Worsnop, D. R., Thornton, J. A., Donahue, N., Kjaergaard, H. G., and Ehn, M.: Highly
oxygenated organic molecules (HOM) from gas-phase autoxidation involving
peroxy radicals: A key contributor to atmospheric aerosol, Chem. Rev.,
119, 3472–3509, 2019. a, b
Bikkina, S., Kawamura, K., Miyazaki, Y., and Fu, P.: High abundances of oxalic, azelaic, and glyoxylic acids and methylglyoxal in the open ocean with high biological activity: Implication for secondary OA formation from isoprene, Geophys. Res. Lett., 41, 3649–3657, 2014. a
Brean, J., Dall’Osto, M., Simó, R., Shi, Z., Beddows, D., and Harrison,
R. M.: Open ocean and coastal new particle formation from sulfuric acid and
amines around the Antarctic Peninsula, Nat. Geosci., 14, 383–388, 2021. a
Breider, T., Chipperfield, M., Richards, N., Carslaw, K., Mann, G., and Spracklen, D.: Impact of BrO on dimethylsulfide in the remote marine boundary
layer, Geophys. Res. Lett., 37, L02807, https://doi.org/10.1029/2009GL040868, 2010. a
Brüggemann, M., Hayeck, N., Bonnineau, C., Pesce, S., Alpert, P. A.,
Perrier, S., Zuth, C., Hoffmann, T., Chen, J., and George, C.: Interfacial
photochemistry of biogenic surfactants: a major source of abiotic volatile
organic compounds, Faraday Discuss., 200, 59–74, 2017. a
Cainey, J. M., Keywood, M., Bigg, E. K., Grose, M. R., Gillett, R. W., and
Meyer, M.: Flux chamber study of particle formation from Durvillaea
potatorum, Environ. Chem., 4, 151–154, 2007. a
Carpenter, L. J., Chance, R. J., Sherwen, T., Adams, T. J., Ball, S. M., Evans, M. J., Hepach, H., Hollis, L. D. J., Hughes, C., Jickells, T. D., Mahajan, A., Stevens, D. P., Tinel, L., and Wadley, M. R.: Marine
iodine emissions in a changing world, P. Roy. Soc. A,
477, 20200824, https://doi.org/10.1098/rspa.2020.0824, 2021. a
Charlson, R. J., Lovelock, J. E., Andreae, M. O., and Warren, S. G.: Oceanic
phytoplankton, atmospheric sulphur, cloud albedo and climate, Nature, 326,
655–661, https://doi.org/10.1038/326655a0, 1987. a
Chen, H. and Finlayson-Pitts, B. J.: New particle formation from
methanesulfonic acid and amines/ammonia as a function of temperature,
Environ. Sci. Technol., 51, 243–252, 2017. a
Ciuraru, R., Fine, L., Van Pinxteren, M., D'Anna, B., Herrmann, H., and
George, C.: Photosensitized production of functionalized and unsaturated
organic compounds at the air-sea interface, Sci. Rep., 5, 12741, https://doi.org/10.1038/srep12741, 2015. a, b
CliFlo: NIWA's National Climate Database on the Web, https://cliflo.niwa.co.nz/, last access: 11 May 2022. a
Crawford, J., Cohen, D. D., Stelcer, E., and Atanacio, A. J.: Long term fine
aerosols at the Cape Grim global baseline station: 1998 to 2016, Atmos.
Environ., 166, 34–46, 2017. a
Cui, T., Green, H. S., Selleck, P. W., Zhang, Z., O’Brien, R. E., Gold, A., Keywood, M., Kroll, J. H., and Surratt, J. D.: Chemical characterization of isoprene-and monoterpene-derived secondary organic aerosol tracers in remote
marine aerosols over a quarter century, ACS Earth and Space Chemistry, 3,
935–946, 2019. a, b, c
Dada, L., Chellapermal, R., Buenrostro Mazon, S., Paasonen, P., Lampilahti, J., Manninen, H. E., Junninen, H., Petäjä, T., Kerminen, V.-M., and Kulmala, M.: Refined classification and characterization of atmospheric new-particle formation events using air ions, Atmos. Chem. Phys., 18, 17883–17893, https://doi.org/10.5194/acp-18-17883-2018, 2018. a
Dada, L., Ylivinkka, I., Baalbaki, R., Li, C., Guo, Y., Yan, C., Yao, L., Sarnela, N., Jokinen, T., Daellenbach, K. R., Yin, R., Deng, C., Chu, B., Nieminen, T., Wang, Y., Lin, Z., Thakur, R. C., Kontkanen, J., Stolzenburg, D., Sipilä, M., Hussein, T., Paasonen, P., Bianchi, F., Salma, I., Weidinger, T., Pikridas, M., Sciare, J., Jiang, J., Liu, Y., Petäjä, T., Kerminen, V.-M., and Kulmala, M.: Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations, Atmos. Chem. Phys., 20, 11747–11766, https://doi.org/10.5194/acp-20-11747-2020, 2020. a
Dall'Osto, M., Monahan, C., Greaney, R., Beddows, D. C. S., Harrison, R. M., Ceburnis, D., and O'Dowd, C. D.: A statistical analysis of North East Atlantic (submicron) aerosol size distributions, Atmos. Chem. Phys., 11, 12567–12578, https://doi.org/10.5194/acp-11-12567-2011, 2011. a
Edtbauer, A., Stönner, C., Pfannerstill, E. Y., Berasategui, M., Walter, D., Crowley, J. N., Lelieveld, J., and Williams, J.: A new marine biogenic emission: methane sulfonamide (MSAM), dimethyl sulfide (DMS), and dimethyl sulfone (DMSO2) measured in air over the Arabian Sea, Atmos. Chem. Phys., 20, 6081–6094, https://doi.org/10.5194/acp-20-6081-2020, 2020. a
Ehn, M., Junninen, H., Petäjä, T., Kurtén, T., Kerminen, V.-M., Schobesberger, S., Manninen, H. E., Ortega, I. K., Vehkamäki, H., Kulmala, M., and Worsnop, D. R.: Composition and temporal behavior of ambient ions in the boreal forest, Atmos. Chem. Phys., 10, 8513–8530, https://doi.org/10.5194/acp-10-8513-2010, 2010. a
Ehn, M., Kleist, E., Junninen, H., Petäjä, T., Lönn, G., Schobesberger, S., Dal Maso, M., Trimborn, A., Kulmala, M., Worsnop, D. R., Wahner, A., Wildt, J., and Mentel, Th. F.: Gas phase formation of extremely oxidized pinene reaction products in chamber and ambient air, Atmos. Chem. Phys., 12, 5113–5127, https://doi.org/10.5194/acp-12-5113-2012, 2012. a
Ehn, M., Thornton, J. A., Kleist, E., Sipilä, M., Junninen, H., Pullinen,
I., Springer, M., Rubach, F., Tillmann, R., Lee, B., Lopez-Hilfiker, F., Stefanie, A., Ismail-Hakki, A., Rissanen, M., Jokinen, T., Schobesberger, S., Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurtén, T., Nielsen, L. B., Jørgensen, S., Kjaergaard, H. K., Canagaratna, M., Dal Maso, M., Berndt, T., Petäjä, T., Wahner, A., Kerminen, V.-M., Kulmala, M., Worsnop, D. R., Wildt, J., and Mentel, T. F.: A large source
of low-volatility secondary organic aerosol, Nature, 506, 476–479, https://doi.org/10.1038/nature13032, 2014. a
Eisele, F.: Natural and anthropogenic negative ions in the troposphere, J. Geophys. Res.-Atmos., 94, 2183–2196, 1989. a
Eisele, F. and Tanner, D.: Measurement of the gas phase concentration of H2SO4 and methane sulfonic acid and estimates of H2SO4 production and loss in the atmosphere, J. Geophys. Res.-Atmos., 98, 9001–9010, 1993. a
Fleming, Z. L., Monks, P. S., and Manning, A. J.: Untangling the influence of
air-mass history in interpreting observed atmospheric composition,
Atmos. Res., 104, 1–39, 2012. a
Fossum, K. N., Ovadnevaite, J., Ceburnis, D., Preißler, J., Snider, J. R., Huang, R.-J., Zuend, A., and O’Dowd, C.: Sea-spray regulates sulfate cloud droplet activation over oceans, npj Climate and Atmospheric Science, 3, 1–6, 2020. a
Frege, C., Bianchi, F., Molteni, U., Tröstl, J., Junninen, H., Henne, S., Sipilä, M., Herrmann, E., Rossi, M. J., Kulmala, M., Hoyle, C. R., Baltensperger, U., and Dommen, J.: Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland), Atmos. Chem. Phys., 17, 2613–2629, https://doi.org/10.5194/acp-17-2613-2017, 2017. a, b, c
Furneaux, K. L., Whalley, L. K., Heard, D. E., Atkinson, H. M., Bloss, W. J., Flynn, M. J., Gallagher, M. W., Ingham, T., Kramer, L., Lee, J. D., Leigh, R., McFiggans, G. B., Mahajan, A. S., Monks, P. S., Oetjen, H., Plane, J. M. C., and Whitehead, J. D.: Measurements of iodine monoxide at a semi polluted coastal location, Atmos. Chem. Phys., 10, 3645–3663, https://doi.org/10.5194/acp-10-3645-2010, 2010. a
Gómez Martín, J. C., Saiz-Lopez, A., Cuevas, C. A., Fernandez, R. P., Gilfedder, B., Weller, R., Baker, A. R., Droste, E., and Lai, S.: Spatial and temporal variability of iodine in aerosol, J. Geophys. Res.-Atmos., 126, e2020JD034410, https://doi.org/10.1029/2020JD034410, 2021. a
Gordon, H., Kirkby, J., Baltensperger, U., Bianchi, F., Breitenlechner, M., Curtius, J., Dias, A., Dommen, J., Donahue, N. M., Dunne, E. M., Duplissy, J., Ehrhart, S., Flagan, R. C., Frege, C., Fuchs, C., Hansel, A., Hoyle, C. R., Kulmala, M., Kürten, A., Lehtipalo, K., Makhmutov, V., Molteni, U., Rissanen, M. P., Stozkhov, Y., Tröstl, J., Tsagkogeorgas, G., Wagner, R., Williamson, C., Wimmer, D., Winkler, P. M., Yan, C., and Carslaw, K. S.:
Causes and importance of new particle formation in the present-day and
preindustrial atmospheres, J. Geophys. Res.-Atmos., 122,
8739–8760, 2017. a
Guenther, A. B., Zimmerman, P. R., Harley, P. C., Monson, R. K., and Fall, R.: Isoprene and monoterpene emission rate variability: model evaluations and
sensitivity analyses, J. Geophys. Res.-Atmos., 98, 12609–12617, 1993. a
He, X.-C., Tham, Y. J., Dada, L., Wang, M., Finkenzeller, H., Stolzenburg, D., Iyer, S., Simon, M., Kürten, A., Shen, J., Rörup, B., Rissanen, M., Schobesberger, S., Baalbaki, R., Wang, D. S., Koenig, T. K., Jokinen, T., Sarnela, N., Beck, L. J., Almeida, J., Amanatidis, S., Amorim, A., Ataei, F., Baccarini, A., Bertozzi, B., Bianchi, F., Brilke, S., Caudillo, L., Chen, D., Chiu, R., Chu, B., Dias, A., Ding, A., Dommen, J., Duplissy, J., El Haddad, I., Gonzalez Carracedo, L., Granzin, M., Hansel, A., Heinritzi, M., Hofbauer, V., Junninen, H., Kangasluoma, J., Kemppainen, D., Kim, C., Kong, W., Krechmer, J. E., Kvashin, A., Laitinen, T., Lamkaddam, H., Lee, C. P., Lehtipalo, K., Leiminger, M., Li, Z., Makhmutov, V., Manninen, H. E., Marie, G., Marten, R., Mathot, S., Mauldin, R. L., Mentler, B., Möhler, O., Müller, T., Nie, W., Onnela, A., Petäjä, T., Pfeifer, J., Philippov, M., Ranjithkumar, A., Saiz-Lopez, A., Salma, I., Scholz, W., Schuchmann, S., Schulze, B., Steiner, G., Stozhkov, Y., Tauber, C., Tomé, A., Thakur, R. C., Väisänen, O., Vazquez-Pufleau, M., Wagner, A. C., Wang, Y., Weber, S. K., Winkler, P. M., Wu, Y., Xiao, M., Yan, C., Ye, Q., Ylisirniö, A., Zauner-Wieczorek, M., Zha, Q., Zhou, P., Flagan, R. C., Curtius, J., Baltensperger, U., Kulmala, M., Kerminen, V.-M., Kurtén, T., Donahue, N. M., Volkamer, R., Kirkby, J., Worsnop, D. R., and Sipilä, M.: Role of iodine
oxoacids in atmospheric aerosol nucleation, Science, 371, 589–595, 2021. a, b, c, d
Hoffmann, E. H., Tilgner, A., Schrödner, R., Bräuer, P., Wolke, R., and Herrmann, H.: An advanced modeling study on the impacts and atmospheric implications of multiphase dimethyl sulfide chemistry, P. Natl. Acad. Sci. USA, 113, 11776–11781, 2016. a
IPCC: Climate Change 2013: The Physical Science Basis, Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp., ISBN 978-1-107-05799-1, 2013. a
Jokinen, T., Sipilä, M., Kontkanen, J., Vakkari, V., Tisler, P., Duplissy, E.-M., Junninen, H., Kangasluoma, J., Manninen, H., Petäjä, T., Kulmala, M., Worsnop, D. R., Kirkby, J., Virkkula, A., and Kerminen, V.-M.: Ion-induced sulfuric acid–ammonia nucleation drives particle formation in coastal Antarctica, Science Advances, 4, eaat9744, https://doi.org/10.1126/sciadv.aat9744, 2018. a
Junninen, H., Ehn, M., Petäjä, T., Luosujärvi, L., Kotiaho, T., Kostiainen, R., Rohner, U., Gonin, M., Fuhrer, K., Kulmala, M., and Worsnop, D. R.: A high-resolution mass spectrometer to measure atmospheric ion composition, Atmos. Meas. Tech., 3, 1039–1053, https://doi.org/10.5194/amt-3-1039-2010, 2010. a, b
Kawamura, K. and Sakaguchi, F.: Molecular distributions of water soluble
dicarboxylic acids in marine aerosols over the Pacific Ocean including
tropics, J. Geophys. Res.-Atmos., 104, 3501–3509, 1999. a
Kerminen, V.-M., Ojanen, C., Pakkanen, T., Hillamo, R., Aurela, M., and
Meriläinen, J.: Low-molecular-weight dicarboxylic acids in an urban and
rural atmosphere, J. Aerosol Sci., 31, 349–362, 2000. a
Kerminen, V.-M., Chen, X., Vakkari, V., Petäjä, T., Kulmala, M., and
Bianchi, F.: Atmospheric new particle formation and growth: review of field
observations, Environ. Res. Lett., 13, 103003, https://doi.org/10.1088/1748-9326/aadf3c, 2018. a
Kloster, S., Feichter, J., Maier-Reimer, E., Six, K. D., Stier, P., and Wetzel, P.: DMS cycle in the marine ocean-atmosphere system – a global model study, Biogeosciences, 3, 29–51, https://doi.org/10.5194/bg-3-29-2006, 2006. a
Land information New Zealand: Tide predictions [data set], https://www.linz.govt.nz/sea/tides/tide-predictions, last access: 31 May 2021. a
Law, C. S., Smith, M. J., Harvey, M. J., Bell, T. G., Cravigan, L. T., Elliott, F. C., Lawson, S. J., Lizotte, M., Marriner, A., McGregor, J., Ristovski, Z., Safi, K. A., Saltzman, E. S., Vaattovaara, P., and Walker, C. F.: Overview and preliminary results of the Surface Ocean Aerosol Production (SOAP) campaign, Atmos. Chem. Phys., 17, 13645–13667, https://doi.org/10.5194/acp-17-13645-2017, 2017. a, b, c
Lawson, S. J., Selleck, P. W., Galbally, I. E., Keywood, M. D., Harvey, M. J., Lerot, C., Helmig, D., and Ristovski, Z.: Seasonal in situ observations of glyoxal and methylglyoxal over the temperate oceans of the Southern Hemisphere, Atmos. Chem. Phys., 15, 223–240, https://doi.org/10.5194/acp-15-223-2015, 2015. a
Lehtipalo, K., Yan, C., Dada, L., Bianchi, F., Xiao, M., Wagner, R., Stolzenburg, D., Ahonen, L. R., Amorim, A., Baccarini, A., Bauer, P. S., Baumgartner, B., Bergen, A., Bernhammer, A.-K., Breitenlechner, M., Brilke, S., Buchholz, A., Mazon, S. B., Chen, D., Chen, X., Dias, A., Dommen, J., Draper, D. C., Duplissy, J., Ehn, M., Finkenzeller, H., Fischer, L., Frege, C., Fuchs, C., Garmash, O., Gordon, H., Hakala, J., He, X., Heikkinen, L., Heinritzi, M., Helm, J. C., Hofbauer, V., Hoyle, C. R., Jokinen, T., Kangasluoma, J., Kerminen, V.-M., Kim, C., Kirkby, J., Kontkanen, J., Kürten, A., Lawler, M. J., Mai, H., Mathot, S., Mauldin, R. L., Molteni, U., Nichman, L., Nie, W., Nieminen, T., Ojdanic, A., Onnela, A., Passananti, M., Petäjä, T., Piel, F., Pospisilova, V., Quéléver, L. L. J., Rissanen, M. P., Rose, C., Sarnela, N., Schallhart, S., Schuchmann, S., Sengupta, K., Simon, M., Sipilä, M., Tauber, C., Tomé, A., Tröstl, J., Väisänen, O., Vogel, A. L., Volkamer, R., Wagner, A. C., Wang, M., Weitz, L., Wimmer, D., Ye, P., Ylisirniö, A., Zha, Q., Carslaw, K. S., Curtius, J., Donahue, N. M., Flagan, R. C., Hansel, A., Riipinen, I., Virtanen, A., Winkler, P. M., Baltensperger, U., Kulmala, M., and Worsnop, D. R.: Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors, Science Advances, 4, eaau5363, https://doi.org/10.1126/sciadv.aau5363, 2018. a
Li, J., Davy, P., Harvey, M., Katzman, T., Mitchell, T., and Michalski, G.: Nitrogen isotopes in nitrate aerosols collected in the remote marine boundary
layer: Implications for nitrogen isotopic fractionations among atmospheric
reactive nitrogen species, Atmos. Environ., 245, 118028, https://doi.org/10.1016/j.atmosenv.2020.118028, 2021. a
Mardyukov, A. and Schreiner, P. R.: Atmospherically relevant radicals derived
from the oxidation of dimethyl sulfide, Accounts Chem. Res., 51,
475–483, 2018. a
Mayer, K. J., Wang, X., Santander, M. V., Mitts, B. A., Sauer, J. S., Sultana, C. M., Cappa, C. D., and Prather, K. A.: Secondary marine aerosol plays a dominant role over primary sea spray aerosol in cloud formation, ACS Central Science, 6, 2259–2266, 2020. a
McFiggans, G., Coe, H., Burgess, R., Allan, J., Cubison, M., Alfarra, M. R., Saunders, R., Saiz-Lopez, A., Plane, J. M. C., Wevill, D., Carpenter, L., Rickard, A. R., and Monks, P. S.: Direct evidence for coastal iodine particles from Laminaria macroalgae – linkage to emissions of molecular iodine, Atmos. Chem. Phys., 4, 701–713, https://doi.org/10.5194/acp-4-701-2004, 2004. a
McFiggans, G., Bale, C. S. E., Ball, S. M., Beames, J. M., Bloss, W. J., Carpenter, L. J., Dorsey, J., Dunk, R., Flynn, M. J., Furneaux, K. L., Gallagher, M. W., Heard, D. E., Hollingsworth, A. M., Hornsby, K., Ingham, T., Jones, C. E., Jones, R. L., Kramer, L. J., Langridge, J. M., Leblanc, C., LeCrane, J.-P., Lee, J. D., Leigh, R. J., Longley, I., Mahajan, A. S., Monks, P. S., Oetjen, H., Orr-Ewing, A. J., Plane, J. M. C., Potin, P., Shillings, A. J. L., Thomas, F., von Glasow, R., Wada, R., Whalley, L. K., and Whitehead, J. D.: Iodine-mediated coastal particle formation: an overview of the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) Roscoff coastal study, Atmos. Chem. Phys., 10, 2975–2999, https://doi.org/10.5194/acp-10-2975-2010, 2010. a
Mirme, S. and Mirme, A.: The mathematical principles and design of the NAIS – a spectrometer for the measurement of cluster ion and nanometer aerosol size distributions, Atmos. Meas. Tech., 6, 1061–1071, https://doi.org/10.5194/amt-6-1061-2013, 2013. a
Mungall, E. L., Abbatt, J. P. D., Wentzell, J. J. B, Lee, A. K. Y., Thomas, J. L., Blais, M., Gosselin, M., Miller, L. A., Papakyriakou, T., Willis, M. D., and Liggio, J.: Microlayer source of oxygenated volatile organic compounds in the summertime marine Arctic boundary layer, P. Natl. Acad. Sci. USA, 114, 6203–6208, 2017. a
Nicovich, J., Parthasarathy, S., Pope, F., Pegus, A., McKee, M., and Wine, P.: Kinetics, mechanism, and thermochemistry of the gas phase reaction of atomic chlorine with dimethyl sulfoxide, J. Phys. Chem. A, 110, 6874–6885, 2006. a
Ning, A., Liu, L., Ji, L., and Zhang, X.: Molecular-level nucleation mechanism of iodic acid and methanesulfonic acid, Atmos. Chem. Phys., 22, 6103–6114, https://doi.org/10.5194/acp-22-6103-2022, 2022. a, b
Novak, G. A., Fite, C. H., Holmes, C. D., Veres, P. R., Neuman, J. A., Faloona, I., Thornton, J. A., Wolfe, G. M., Vermeuel, M. P., Jernigan, C. M., Peischl, J., Ryerson, T. B., Thompson, C. R., Bourgeois, I., Warneke, C., Gkatzelis, G. I., Coggon, M. M., Sekimoto, K., Bui, T. P., Dean-Day, J., Diskin, G. S., DiGangi, J. P., Nowak, J. B., Moore, R. H., Wiggins, E. B., Winstead, E. L., Robinson, C., Thornhill, K. L., Sanchez, K. J., Hall, S. R., Ullmann, K., Dollner, M., Weinzierl, B., Blake, D. R., and Bertram, T. H.: Rapid cloud removal of dimethyl sulfide oxidation products limits SO2 and cloud condensation nuclei production in the marine atmosphere, P. Natl. Acad. Sci. USA, 118, e2110472118, https://doi.org/10.1073/pnas.2110472118, 2021. a
O'Dowd, C. D., Jimenez, J. L., Bahreini, R., Flagan, R. C., Seinfeld, J. H., Hämeri, K., Pirjola, L., Kulmala, M., Jennings, S. G., and Hoffmann, T.:
Marine aerosol formation from biogenic iodine emissions, Nature, 417, 632–636, https://doi.org/10.1038/nature00775, 2002. a
Paasonen, P., Peltola, M., Kontkanen, J., Junninen, H., Kerminen, V.-M., and Kulmala, M.: Comprehensive analysis of particle growth rates from nucleation mode to cloud condensation nuclei in boreal forest, Atmos. Chem. Phys., 18, 12085–12103, https://doi.org/10.5194/acp-18-12085-2018, 2018. a
Quinn, P., Coffman, D., Johnson, J., Upchurch, L., and Bates, T.: Small
fraction of marine cloud condensation nuclei made up of sea spray aerosol,
Nat. Geosci., 10, 674–679, https://doi.org/10.1038/ngeo3003, 2017. a
Röhrl, A. and Lammel, G.: Low-molecular weight dicarboxylic acids and glyoxylic acid: seasonal and air mass characteristics, Environ. Sci. Technol., 35, 95–101, 2001. a
Rose, C., Sellegri, K., Velarde, F., Moreno, I., Ramonet, M., Weinhold, K.,
Krejci, R., Ginot, P., Andrade, M., Wiedensohler, A., and Laj, P.: Frequent
nucleation events at the high altitude station of Chacaltaya (5240 m asl), Bolivia, Atmos. Environ., 102, 18–29, 2015. a
Rossignol, S., Tinel, L., Bianco, A., Passananti, M., Brigante, M., Donaldson, D. J., and George, C.: Atmospheric photochemistry at a fatty acid–coated air-water interface, Science, 353, 699–702, 2016. a
Sanchez, K. J., Chen, C.-L., Russell, L. M., Betha, R., Liu, J., Price, D. J., Massoli, P., Ziemba, L. D., Crosbie, E. C., Moore, R. H., Müller, M., Schiller, S. A., Wisthaler, A., Lee, A. K. Y., Quinn, P. K., Bates, T. S., Porter, J., Bell, T. G., Saltzman, E. S., Vaillancourt, R. D., and Behrenfeld, M. J.: Substantial seasonal contribution of observed biogenic sulfate particles to cloud condensation nuclei, Sci. Rep., 8, 3235, https://doi.org/10.1038/s41598-018-21590-9, 2018. a
Sea2Cloud: Catalogue, Sea2Cloud [data set], https://sea2cloud.data-terra.org/en/catalogue/, last access: 3 December 2022. a
Sellegri, K.: Sea2Cloud – Baring-Head – APi-TOF – Level 2, Dataterra, [data set], https://doi.org/10.6096/4001, 2022a. a
Sellegri, K.: Sea2Cloud – Baring-Head – CPC – Level 0, Dataterra, [data
set], https://doi.org/10.25326/354, 2022b. a
Sellegri, K.: Sea2Cloud – Baring-Head – PSM – Level 2, Dataterra, [data
set], https://doi.org/10.25326/355, 2022c. a
Sellegri, K.: Sea2Cloud – Baring-Head SMPS – Level 0, Dataterra, [data
set], https://doi.org/10.25326/356, 2022d. a
Sellegri, K., Yoon, Y., Jennings, S., O’Dowd, C., Pirjola, L., Cautenet, S., Chen, H., and Hoffmann, T.: Quantification of coastal new ultra-fine particles formation from in situ and chamber measurements during the BIOFLUX
campaign, Environ. Chem., 2, 260–270, 2005. a
Sellegri, K. , Pey, J., Rose, C., Culot, A., DeWitt, H. L., Mas, S., Schwier, A. N., Temime-Roussel, B., Charriere, B., Saiz-Lopez, A., Mahajan, A. S., Parin, D., Kukui, A., Sempere, R., D'Anna, B., and Marchand, N..: Evidence of atmospheric nanoparticle formation from emissions of marine microorganisms, Geophys. Res. Lett., 43, 6596–6603, 2016. a, b
Sempéré, R. and Kawamura, K.: Low molecular weight dicarboxylic acids and related polar compounds in the remote marine rain samples collected from
western Pacific, Atmos. Environ., 30, 1609–1619, 1996. a
Shaw, S. L., Gantt, B., and Meskhidze, N.: Production and emissions of marine isoprene and monoterpenes: a review, Adv. Meteorol., 2010, 408696, https://doi.org/10.1155/2010/408696, 2010. a
Sievering, H., Cainey, J., Harvey, M., McGregor, J., Nichol, S., and Quinn, P.: Aerosol non-sea-salt sulfate in the remote marine boundary layer under clear-sky and normal cloudiness conditions: ocean-derived biogenic alkalinity enhances sea-salt sulfate production by ozone oxidation, J. Geophys. Res.-Atmos., 109, D19317, https://doi.org/10.1029/2003JD004315, 2004. a
Sipilä, M., Sarnela, N., Jokinen, T., Henschel, H., Junninen, H., Kontkanen, J., Richters, S., Kangasluoma, J., Franchin, A., Peräkylä, O., Rissanen, M. P., Ehn, M., Vehkamäki, H., Kurten, T., Berndt, T., Petäjä, T., Worsnop, D., Ceburnis, D., Kerminen, V.-M., Kulmala, M., and O'Dowd, C.: Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3, Nature, 537, 532–534, https://doi.org/10.1038/nature19314, 2016. a, b
Stark, H., Brown, S., Goldan, P., Aldener, M., Kuster, W., Jakoubek, R.,
Fehsenfeld, F., Meagher, J., Bates, T., and Ravishankara, A.: Influence of
nitrate radical on the oxidation of dimethyl sulfide in a polluted marine
environment, J. Geophys. Res.-Atmos., 112, D10S10, https://doi.org/10.1029/2006JD007669, 2007. a
Stephens, B. B., Brailsford, G. W., Gomez, A. J., Riedel, K., Mikaloff Fletcher, S. E., Nichol, S., and Manning, M.: Analysis of a 39-year continuous atmospheric CO2 record from Baring Head, New Zealand, Biogeosciences, 10, 2683–2697, https://doi.org/10.5194/bg-10-2683-2013, 2013. a
Sulo, J., Sarnela, N., Kontkanen, J., Ahonen, L., Paasonen, P., Laurila, T., Jokinen, T., Kangasluoma, J., Junninen, H., Sipilä, M., Petäjä, T., Kulmala, M., and Lehtipalo, K.: Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest, Atmos. Chem. Phys., 21, 695–715, https://doi.org/10.5194/acp-21-695-2021, 2021. a
Takashima, H., Kanaya, Y., Kato, S., Friedrich, M. M., Van Roozendael, M., Taketani, F., Miyakawa, T., Komazaki, Y., Cuevas, C. A., Saiz-Lopez, A., and Sekiya, T.: Full latitudinal marine atmospheric measurements of iodine monoxide, Atmos. Chem. Phys., 22, 4005–4018, https://doi.org/10.5194/acp-22-4005-2022, 2022. a
Vanhanen, J., Mikkilä, J., Lehtipalo, K., Sipilä, M., Manninen, H., Siivola,
E., Petäjä, T., and Kulmala, M.: Particle size magnifier for nano-CN
detection, Aerosol Sci. Tech., 45, 533–542, 2011. a
Veres, P. R., Neuman, J. A., Bertram, T. H., Assaf, E., Wolfe, G. M., Williamson, C. J., Weinzierl, B., Tilmes, S., Thompson, C. R., Thames, A. B., Schroder, J. C., Saiz-Lopez, A., Rollins, A. W., Roberts, J. M., Price, D., Peischl, J., Nault, B. A., Møller, K. H., Miller, D. O., Meinardi, S., Li, Q., Lamarque, J.-F., Kupc, A., Kjaergaard, H. G., Kinnison, D., Jimenez, J. L., Jernigan, C. M., Hornbrook, R. S., Hills, A., Dollner, M., Day, D. A., Cuevas, C. A., Campuzano-Jost, P., Burkholder, J., Bui, T. P., Brune, W. H., Brown, S. S., Brock, C. A., Bourgeois, I., Blake, D. R., Apel, E. C., and Ryerson, T. B.: Global airborne sampling reveals a previously unobserved dimethyl sulfide oxidation mechanism in the marine atmosphere, P. Natl. Acad. Sci. USA, 117, 4505–4510, https://doi.org/10.1073/pnas.1919344117, 2020. a, b
Wan, Y., Huang, X., Jiang, B., Kuang, B., Lin, M., Xia, D., Liao, Y., Chen, J., Yu, J. Z., and Yu, H.: Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere, Atmos. Chem. Phys., 20, 9821–9835, https://doi.org/10.5194/acp-20-9821-2020, 2020. a
Wang, H., Kawamura, K., and Yamazaki, K.: Water-soluble dicarboxylic acids, ketoacids and dicarbonyls in the atmospheric aerosols over the Southern Ocean and western Pacific Ocean, J. Atmos. Chem., 53, 43–61, 2006. a
Wang, X., Jacob, D. J., Eastham, S. D., Sulprizio, M. P., Zhu, L., Chen, Q., Alexander, B., Sherwen, T., Evans, M. J., Lee, B. H., Haskins, J. D., Lopez-Hilfiker, F. D., Thornton, J. A., Huey, G. L., and Liao, H.: The role of chlorine in global tropospheric chemistry, Atmos. Chem. Phys., 19, 3981–4003, https://doi.org/10.5194/acp-19-3981-2019, 2019. a
Wang, X., Jacob, D. J., Downs, W., Zhai, S., Zhu, L., Shah, V., Holmes, C. D., Sherwen, T., Alexander, B., Evans, M. J., Eastham, S. D., Neuman, J. A., Veres, P. R., Koenig, T. K., Volkamer, R., Huey, L. G., Bannan, T. J., Percival, C. J., Lee, B. H., and Thornton, J. A.: Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants, Atmos. Chem. Phys., 21, 13973–13996, https://doi.org/10.5194/acp-21-13973-2021, 2021. a, b
Wollesen de Jonge, R., Elm, J., Rosati, B., Christiansen, S., Hyttinen, N., Lüdemann, D., Bilde, M., and Roldin, P.: Secondary aerosol formation from dimethyl sulfide – improved mechanistic understanding based on smog chamber experiments and modelling, Atmos. Chem. Phys., 21, 9955–9976, https://doi.org/10.5194/acp-21-9955-2021, 2021. a
Yan, C., Nie, W., Äijälä, M., Rissanen, M. P., Canagaratna, M. R., Massoli, P., Junninen, H., Jokinen, T., Sarnela, N., Häme, S. A. K., Schobesberger, S., Canonaco, F., Yao, L., Prévôt, A. S. H., Petäjä, T., Kulmala, M., Sipilä, M., Worsnop, D. R., and Ehn, M.: Source characterization of highly oxidized multifunctional compounds in a boreal forest environment using positive matrix factorization, Atmos. Chem. Phys., 16, 12715–12731, https://doi.org/10.5194/acp-16-12715-2016, 2016. a, b
Yan, C., Dada, L., Rose, C., Jokinen, T., Nie, W., Schobesberger, S., Junninen, H., Lehtipalo, K., Sarnela, N., Makkonen, U., Garmash, O., Wang, Y., Zha, Q., Paasonen, P., Bianchi, F., Sipilä, M., Ehn, M., Petäjä, T., Kerminen, V.-M., Worsnop, D. R., and Kulmala, M.: The role of H2SO4-NH3 anion clusters in ion-induced aerosol nucleation mechanisms in the boreal forest, Atmos. Chem. Phys., 18, 13231–13243, https://doi.org/10.5194/acp-18-13231-2018, 2018.
a, b
Yan, J., Jung, J., Zhang, M., Bianchi, F., Tham, Y. J., Xu, S., Lin, Q., Zhao, S., Li, L., and Chen, L.: Uptake selectivity of methanesulfonic acid (MSA) on fine particles over polynya regions of the Ross Sea, Antarctica, Atmos. Chem. Phys., 20, 3259–3271, https://doi.org/10.5194/acp-20-3259-2020, 2020. a
Yao, L., Garmash, O., Bianchi, F., Zheng, J., Yan, C., Kontkanen, J., Junninen, H., Mazon, S. B., Ehn, M., Paasonen, P., Sipilä, M., Wang, M., Wang, X., Xiao, S., Chen, H., Lu, Y., Zhang, B., Wang, D., Fu, Q., Geng, F., Li, L., Wang, H., Qiao, L., Yang, X., Chen, J., Kerminen, V.-M., Petäjä, T., Worsnop, D. R., Kulmala, M., and Wang, L.: Atmospheric new particle formation from sulfuric acid and amines in a Chinese megacity, Science, 361, 278–281, 2018. a
Zheng, G., Kuang, C., Uin, J., Watson, T., and Wang, J.: Large contribution of organics to condensational growth and formation of cloud condensation nuclei (CCN) in the remote marine boundary layer, Atmos. Chem. Phys., 20, 12515–12525, https://doi.org/10.5194/acp-20-12515-2020, 2020. a
Short summary
We measured the chemical composition of ambient ions at a coastal New Zealand site and connected these data with aerosol size distribution data to study the chemical precursors of new particle formation at the site. Our results showed that iodine oxides and sulfur species were important for particle formation in marine air, while in land-influenced air sulfuric acid and organics were connected to new particle formation events.
We measured the chemical composition of ambient ions at a coastal New Zealand site and connected...
Special issue
Altmetrics
Final-revised paper
Preprint