Articles | Volume 22, issue 23
https://doi.org/10.5194/acp-22-15413-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-15413-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Dec 2022
Research article |
| 06 Dec 2022
| 06 Dec 2022
Chemical characterization of organic compounds involved in iodine-initiated new particle formation from coastal macroalgal emission
Yibei Wan
School of Environmental Studies, China University of Geosciences,
Wuhan 430074, China
Xiangpeng Huang
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and
Pollution Control, Collaborative Innovation Center of Atmospheric
Environment and Equipment Technology, School of Environmental Science and
Engineering, Nanjing University of Information Science and Technology,
Nanjing 210044, China
Chong Xing
School of Environmental Studies, China University of Geosciences,
Wuhan 430074, China
Qiongqiong Wang
School of Environmental Studies, China University of Geosciences,
Wuhan 430074, China
Xinlei Ge
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and
Pollution Control, Collaborative Innovation Center of Atmospheric
Environment and Equipment Technology, School of Environmental Science and
Engineering, Nanjing University of Information Science and Technology,
Nanjing 210044, China
School of Environmental Studies, China University of Geosciences,
Wuhan 430074, China
Related authors
No articles found.
Xinyu Wang, Nan Chen, Bo Zhu, and Huan Yu
Atmos. Chem. Phys., 25, 9601–9615, https://doi.org/10.5194/acp-25-9601-2025, https://doi.org/10.5194/acp-25-9601-2025, 2025
Short summary
Short summary
Gas–particle partitioning governs the fate of organic molecules and the formation of organic aerosols in the atmosphere. Based on field measurement data, we built machine learning models to predict gas–particle partitioning. We also unveiled previously unrecognized interactions that led to the deviations of partitioning from the equilibrium state under real atmospheric conditions. Our study provided valuable insights for future research in atmospheric chemistry.
Yu Huang, Xingru Li, Dan Dan Huang, Ruoyuan Lei, Binhuang Zhou, Yunjiang Zhang, and Xinlei Ge
Atmos. Chem. Phys., 25, 7619–7645, https://doi.org/10.5194/acp-25-7619-2025, https://doi.org/10.5194/acp-25-7619-2025, 2025
Short summary
Short summary
This work comprises a comprehensive investigation into the chemical and optical properties of brown carbon (BrC) in PM2.5 samples collected in Nanjing, China. In particular, we used a machine learning approach to identify a list of key BrC species, which can be a good reference for future studies. Our findings extend understanding of BrC properties and are valuable to the assessment of BrC's impact on air quality and radiative forcing.
Qingxiao Meng, Yunjiang Zhang, Sheng Zhong, Jie Fang, Lili Tang, Yongcai Rao, Minfeng Zhou, Jian Qiu, Xiaofeng Xu, Jean-Eudes Petit, Olivier Favez, and Xinlei Ge
Atmos. Chem. Phys., 25, 7485–7498, https://doi.org/10.5194/acp-25-7485-2025, https://doi.org/10.5194/acp-25-7485-2025, 2025
Short summary
Short summary
We developed a machine-learning-based method to reconstruct missing elemental carbon (EC) data in four Chinese cities from 2013 to 2023. Using machine learning, we filled data gaps and introduced a new approach to analyze EC trends. Our findings reveal a significant decline in EC due to stricter pollution controls, though this slowed after 2020. This study provides a versatile framework for addressing data gaps and supports strategies to reduce urban air pollution and its climate impacts.
Hanrui Lang, Yunjiang Zhang, Sheng Zhong, Yongcai Rao, Minfeng Zhou, Jian Qiu, Jingyi Li, Diwen Liu, Florian Couvidat, Olivier Favez, Didier Hauglustaine, and Xinlei Ge
EGUsphere, https://doi.org/10.5194/egusphere-2025-231, https://doi.org/10.5194/egusphere-2025-231, 2025
Short summary
Short summary
This study investigates how dust pollution influences particulate nitrate formation. We found that dust pollution could reduce the effectiveness of ammonia emission controls by altering aerosol chemistry. Using field observations and modeling, we showed that dust particles affect nitrate distribution between gas and particle phases. Our findings highlight the need for pollution control strategies that consider both human emissions and dust sources for better urban air quality management.
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
Atmos. Chem. Phys., 24, 10655–10666, https://doi.org/10.5194/acp-24-10655-2024, https://doi.org/10.5194/acp-24-10655-2024, 2024
Short summary
Short summary
This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
Atmos. Chem. Phys., 24, 9733–9748, https://doi.org/10.5194/acp-24-9733-2024, https://doi.org/10.5194/acp-24-9733-2024, 2024
Short summary
Short summary
Short-term strict emission control can improve air quality, but its effectiveness needs assessment. During the 2021 summer COVID-19 lockdown in Yangzhou, we found that PM2.5 levels did not decrease despite reduced primary emissions. Aged black-carbon particles increased substantially due to higher O3 levels and transported pollutants. High humidity and low wind also played key roles. The results highlight the importance of a regionally balanced control strategy for future air quality management.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
Short summary
Short summary
In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Chaman Gul, Shichang Kang, Yuanjian Yang, Xinlei Ge, and Dong Guo
EGUsphere, https://doi.org/10.5194/egusphere-2024-1144, https://doi.org/10.5194/egusphere-2024-1144, 2024
Preprint archived
Short summary
Short summary
Long-term variations in upper atmospheric temperature and water vapor in the selected domains of time and space are presented. The temperature during the past two decades showed a cooling trend and water vapor showed an increasing trend and had an inverse relation with temperature in selected domains of space and time. Seasonal temperature variations are distinct, with a summer minimum and a winter maximum. Our results can be an early warning indication for future climate change.
Jianzhong Xu, Xinghua Zhang, Wenhui Zhao, Lixiang Zhai, Miao Zhong, Jinsen Shi, Junying Sun, Yanmei Liu, Conghui Xie, Yulong Tan, Kemei Li, Xinlei Ge, Qi Zhang, and Shichang Kang
Earth Syst. Sci. Data, 16, 1875–1900, https://doi.org/10.5194/essd-16-1875-2024, https://doi.org/10.5194/essd-16-1875-2024, 2024
Short summary
Short summary
A comprehensive aerosol observation project was carried out in the Tibetan Plateau (TP) and its surroundings in recent years to investigate the properties and sources of atmospheric aerosols as well as their regional differences by performing multiple intensive field observations. The release of this dataset can provide basic and systematic data for related research in the atmospheric, cryospheric, and environmental sciences in this unique region.
Xinlei Ge, Yele Sun, Justin Trousdell, Mindong Chen, and Qi Zhang
Atmos. Meas. Tech., 17, 423–439, https://doi.org/10.5194/amt-17-423-2024, https://doi.org/10.5194/amt-17-423-2024, 2024
Short summary
Short summary
This study aims to enhance the application of the Aerodyne high-resolution aerosol mass spectrometer (HR-AMS) in characterizing organic nitrogen (ON) species within aerosol particles and droplets. A thorough analysis was conducted on 75 ON standards that represent a diverse spectrum of ambient ON types. The results underscore the capacity of the HR-AMS in examining the concentration and chemistry of atmospheric ON compounds, thereby offering insights into their sources and environmental impacts.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yusen Duan, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 475–486, https://doi.org/10.5194/acp-24-475-2024, https://doi.org/10.5194/acp-24-475-2024, 2024
Short summary
Short summary
We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 d during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Shuhui Zhu, Min Zhou, Liping Qiao, Dan Dan Huang, Qiongqiong Wang, Shan Wang, Yaqin Gao, Shengao Jing, Qian Wang, Hongli Wang, Changhong Chen, Cheng Huang, and Jian Zhen Yu
Atmos. Chem. Phys., 23, 7551–7568, https://doi.org/10.5194/acp-23-7551-2023, https://doi.org/10.5194/acp-23-7551-2023, 2023
Short summary
Short summary
Organic aerosol (OA) is increasingly important in urban PM2.5 pollution as inorganic ions are becoming lower. We investigated the chemical characteristics of OA during nine episodes in Shanghai. The availability of bi-hourly measured molecular markers revealed that the control of local urban sources such as vehicular and cooking emissions lessened the severity of local episodes. Regional control of precursors and biomass burning would reduce PM2.5 episodes influenced by regional transport.
Rui Li, Kun Zhang, Qing Li, Liumei Yang, Shunyao Wang, Zhiqiang Liu, Xiaojuan Zhang, Hui Chen, Yanan Yi, Jialiang Feng, Qiongqiong Wang, Ling Huang, Wu Wang, Yangjun Wang, Jian Zhen Yu, and Li Li
Atmos. Chem. Phys., 23, 3065–3081, https://doi.org/10.5194/acp-23-3065-2023, https://doi.org/10.5194/acp-23-3065-2023, 2023
Short summary
Short summary
Molecular markers in organic aerosol (OA) provide specific source information on PM2.5, and the contribution of cooking emissions to OA is significant, especially in urban environments. This study investigates the variation in concentrations and oxidative degradation of fatty acids and corresponding oxidation products in ambient air, which can be a guide for the refinement of aerosol source apportionment and provide scientific support for the development of emission source control policies.
Xinghua Zhang, Wenhui Zhao, Lixiang Zhai, Miao Zhong, Jinsen Shi, Junying Sun, Yanmei Liu, Conghui Xie, Yulong Tan, Kemei Li, Xinlei Ge, Qi Zhang, Shichang Kang, and Jianzhong Xu
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2022-211, https://doi.org/10.5194/essd-2022-211, 2022
Manuscript not accepted for further review
Short summary
Short summary
A comprehensive aerosol observation project was carried out in the Tibetan Plateau (TP) in recent years to investigate the properties and sources of atmospheric aerosols as well as their regional differences by performing multiple short-term intensive field observations. The real-time online high-time-resolution (hourly) data of aerosol properties in the different TP region are integrated in a new dataset and can provide supporting for related studies in in the TP.
Shijie Cui, Dan Dan Huang, Yangzhou Wu, Junfeng Wang, Fuzhen Shen, Jiukun Xian, Yunjiang Zhang, Hongli Wang, Cheng Huang, Hong Liao, and Xinlei Ge
Atmos. Chem. Phys., 22, 8073–8096, https://doi.org/10.5194/acp-22-8073-2022, https://doi.org/10.5194/acp-22-8073-2022, 2022
Short summary
Short summary
Refractory black carbon (rBC) aerosols are important to air quality and climate change. rBC can mix with many other species, which can significantly change its properties and impacts. We used a specific set of techniques to exclusively characterize rBC-containing (rBCc) particles in Shanghai. We elucidated their composition, sources and size distributions and factors that affect their properties. Our findings are very valuable for advancing the understanding of BC and controlling BC pollution.
Xudong Li, Ye Tao, Longwei Zhu, Shuaishuai Ma, Shipeng Luo, Zhuzi Zhao, Ning Sun, Xinlei Ge, and Zhaolian Ye
Atmos. Chem. Phys., 22, 7793–7814, https://doi.org/10.5194/acp-22-7793-2022, https://doi.org/10.5194/acp-22-7793-2022, 2022
Short summary
Short summary
This work has, for the first time, investigated the optical and chemical properties and oxidative potential of aqueous-phase photooxidation products of eugenol (a biomass-burning-emitted compound) and elucidated the interplay among these properties. Large mass yields exceeding 100 % were found, and the aqueous processing is a source of BrC (likely relevant with humic-like substances). We also show that aqueous processing can produce species that are more toxic than that of its precursor.
Haoran Zhang, Nan Li, Keqin Tang, Hong Liao, Chong Shi, Cheng Huang, Hongli Wang, Song Guo, Min Hu, Xinlei Ge, Mindong Chen, Zhenxin Liu, Huan Yu, and Jianlin Hu
Atmos. Chem. Phys., 22, 5495–5514, https://doi.org/10.5194/acp-22-5495-2022, https://doi.org/10.5194/acp-22-5495-2022, 2022
Short summary
Short summary
We developed a new algorithm with low economic/technique costs to identify primary and secondary components of PM2.5. Our model was shown to be reliable by comparison with different observation datasets. We systematically explored the patterns and changes in the secondary PM2.5 pollution in China at large spatial and time scales. We believe that this method is a promising tool for efficiently estimating primary and secondary PM2.5, and has huge potential for future PM mitigation.
Mutian Ma, Laura-Hélèna Rivellini, YuXi Cui, Megan D. Willis, Rio Wilkie, Jonathan P. D. Abbatt, Manjula R. Canagaratna, Junfeng Wang, Xinlei Ge, and Alex K. Y. Lee
Atmos. Meas. Tech., 14, 2799–2812, https://doi.org/10.5194/amt-14-2799-2021, https://doi.org/10.5194/amt-14-2799-2021, 2021
Short summary
Short summary
Chemical characterization of organic coatings is important to advance our understanding of the physio-chemical properties and atmospheric processing of black carbon (BC) particles. This work develops two approaches to improve the elemental analysis of oxygenated organic coatings using a soot-particle aerosol mass spectrometer. Analyzing ambient data with the new approaches indicated that secondary organics that coated on BC were likely less oxygenated compared to those externally mixed with BC.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
Short summary
Short summary
We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
Dong Chen, Yu Zhao, Jie Zhang, Huan Yu, and Xingna Yu
Atmos. Chem. Phys., 20, 10193–10210, https://doi.org/10.5194/acp-20-10193-2020, https://doi.org/10.5194/acp-20-10193-2020, 2020
Short summary
Short summary
We studied the characteristics and sources of aerosol scattering for Nanjing. The method of aerosol scattering estimation was optimized based on field measurements, and the impacts of aerosol size and composition were quantified. To explore the reasons for the reduced visibility, source apportionment of aerosol scattering was conducted by pollution level. This work stressed the linkage between aerosols and visibility and improved the understanding of emissions and their role in air quality.
Cited articles
Allan, J. D., Williams, P. I., Najera, J., Whitehead, J. D., Flynn, M. J., Taylor, J. W., Liu, D., Darbyshire, E., Carpenter, L. J., Chance, R., Andrews, S. J., Hackenberg, S. C., and McFiggans, G.: Iodine observed in new particle formation events in the Arctic atmosphere during ACCACIA, Atmos. Chem. Phys., 15, 5599–5609, https://doi.org/10.5194/acp-15-5599-2015, 2015.
Ashu-Ayem, E. R., Nitschke, U., Monahan, C., Chen, J., Darby, S. B., Smith,
P. D., O'Dowd, C. D., Stengel, D. B., and Venables, D. S.: Coastal Iodine
Emissions. 1. Release of I2 by Laminaria digitata in Chamber Experiments,
Environ. Sci. Technol., 46, 10413–10421, https://doi.org/10.1021/es204534v,
2012.
Baccarini, A., Karlsson, L., Dommen, J., Duplessis, P., Vüllers, J.,
Brooks, I. M., Saiz-Lopez, A., Salter, M., Tjernström, M.,
Baltensperger, U., Zieger, P., and Schmale, J.: Frequent new particle
formation over the high Arctic pack ice by enhanced iodine emissions, Nat.
Commun., 11, 4924, https://doi.org/10.1038/s41467-020-18551-0, 2020.
Beck, L. J., Sarnela, N., Junninen, H., Hoppe, C. J. M., Garmash, O.,
Bianchi, F., Riva, M., Rose, C., Peräkylä, O., Wimmer, D., Kausiala,
O., Jokinen, T., Ahonen, L., Mikkilä, J., Hakala, J., He, X.-C.,
Kontkanen, J., Wolf, K. K. E., Cappelletti, D., Mazzola, M., Traversi, R.,
Petroselli, C., Viola, A. P., Vitale, V., Lange, R., Massling, A.,
Nøjgaard, J. K., Krejci, R., Karlsson, L., Zieger, P., Jang, S., Lee, K.,
Vakkari, V., Lampilahti, J., Thakur, R. C., Leino, K., Kangasluoma, J.,
Duplissy, E.-M., Siivola, E., Marbouti, M., Tham, Y. J., Saiz-Lopez, A.,
Petäjä, T., Ehn, M., Worsnop, D. R., Skov, H., Kulmala, M.,
Kerminen, V.-M., and Sipilä, M.: Differing Mechanisms of New Particle
Formation at Two Arctic Sites, Geophys. Res. Lett., 48,
e2020GL091334, https://doi.org/10.1029/2020GL091334, 2021.
Burkholder, J. B., Curtius, J., Ravishankara, A. R., and Lovejoy, E. R.: Laboratory studies of the homogeneous nucleation of iodine oxides, Atmos. Chem. Phys., 4, 19–34, https://doi.org/10.5194/acp-4-19-2004, 2004.
Donahue, N. M., Ortega, I. K., Chuang, W., Riipinen, I., Riccobono, F.,
Schobesberger, S., Dommen, J., Baltensperger, U., Kulmala, M., Worsnop, D.
R., and Vehkamaki, H.: How do organic vapors contribute to new-particle
formation?, Faraday Discuss., 165, 91–104, https://doi.org/10.1039/C3FD00046J, 2013.
Ehn, M., Thornton, J. A., Kleist, E., Sipila, M., Junninen, H., Pullinen,
I., Springer, M., Rubach, F., Tillmann, R., Lee, B., Lopez-Hilfiker, F.,
Andres, S., Acir, I.-H., Rissanen, M., Jokinen, T., Schobesberger, S.,
Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurten, T., Nielsen, L. B.,
Jorgensen, S., Kjaergaard, H. G., Canagaratna, M., Maso, M. D., Berndt, T.,
Petaja, T., Wahner, A., Kerminen, V.-M., Kulmala, M., Worsnop, D. R., Wildt,
J., and Mentel, T. F.: A large source of low-volatility secondary organic
aerosol, Nature, 506, 476–479, https://doi.org/10.1038/nature13032, 2014.
Faxon, C., Hammes, J., Le Breton, M., Pathak, R. K., and Hallquist, M.: Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry, Atmos. Chem. Phys., 18, 5467–5481, https://doi.org/10.5194/acp-18-5467-2018, 2018.
Gómez Martín, J. C., Gálvez, O., Baeza-Romero, M. T., Ingham,
T., Plane, J. M. C., and Blitz, M. A.: On the mechanism of iodine oxide
particle formation, Phys. Chem. Chem. Phys., 15, 15612–15622, https://doi.org/10.1039/c3cp51217g, 2013.
Gómez Martín, J. C., Lewis, T. R., Blitz, M. A., Plane, J. M. C.,
Kumar, M., Francisco, J. S., and Saiz-Lopez, A.: A gas-to-particle
conversion mechanism helps to explain atmospheric particle formation through
clustering of iodine oxides, Nat. Commun., 11, 4521, https://doi.org/10.1038/s41467-020-18252-8, 2020.
Gómez Martín, J. C., Lewis, T. R., James, A. D., Saiz-Lopez, A.,
and Plane, J. M. C.: Insights into the Chemistry of Iodine New Particle
Formation: The Role of Iodine Oxides and the Source of Iodic Acid, J.
Am. Chem. Soc., 144, 9240–9253, https://doi.org/10.1021/jacs.1c12957,
2022.
Heard, D. E., Read, K. A., Methven, J., Al-Haider, S., Bloss, W. J., Johnson, G. P., Pilling, M. J., Seakins, P. W., Smith, S. C., Sommariva, R., Stanton, J. C., Still, T. J., Ingham, T., Brooks, B., De Leeuw, G., Jackson, A. V., McQuaid, J. B., Morgan, R., Smith, M. H., Carpenter, L. J., Carslaw, N., Hamilton, J., Hopkins, J. R., Lee, J. D., Lewis, A. C., Purvis, R. M., Wevill, D. J., Brough, N., Green, T., Mills, G., Penkett, S. A., Plane, J. M. C., Saiz-Lopez, A., Worton, D., Monks, P. S., Fleming, Z., Rickard, A. R., Alfarra, M. R., Allan, J. D., Bower, K., Coe, H., Cubison, M., Flynn, M., McFiggans, G., Gallagher, M., Norton, E. G., O'Dowd, C. D., Shillito, J., Topping, D., Vaughan, G., Williams, P., Bitter, M., Ball, S. M., Jones, R. L., Povey, I. M., O'Doherty, S., Simmonds, P. G., Allen, A., Kinnersley, R. P., Beddows, D. C. S., Dall'Osto, M., Harrison, R. M., Donovan, R. J., Heal, M. R., Jennings, S. G., Noone, C., and Spain, G.: The North Atlantic Marine Boundary Layer Experiment(NAMBLEX). Overview of the campaign held at Mace Head, Ireland, in summer 2002, Atmos. Chem. Phys., 6, 2241–2272, https://doi.org/10.5194/acp-6-2241-2006, 2006.
Huang, R.-J., Hoffmann, T., Ovadnevaite, J., Laaksonen, A., Kokkola, H., Xu,
W., Xu, W., Ceburnis, D., Zhang, R., Seinfeld, J. H., and O'Dowd, C.:
Heterogeneous iodine-organic chemistry fast-tracks marine new particle
formation, P. Natl. Acad. Sci. USA, 119,
e2201729119, https://doi.org/10.1073/pnas.2201729119, 2022.
Inomata, S., Sato, K., Hirokawa, J., Sakamoto, Y., Tanimoto, H., Okumura,
M., Tohno, S., and Imamura, T.: Analysis of secondary organic aerosols from
ozonolysis of isoprene by proton transfer reaction mass spectrometry,
Atmos. Environ., 97, 397–405,
https://doi.org/10.1016/j.atmosenv.2014.03.045, 2014.
Jimenez, J. L., Bahreini, R., Cocker III, D. R., Zhuang, H., Varutbangkul,
V., Flagan, R. C., Seinfeld, J. H., O'Dowd, C. D., and Hoffmann, T.: New
particle formation from photooxidation of diiodomethane (CH2I2), J.
Geophys. Res.-Atmos., 108, 4318,
https://doi.org/10.1029/2002JD002452, 2003.
Kundu, S., Fisseha, R., Putman, A. L., Rahn, T. A., and Mazzoleni, L. R.: High molecular weight SOA formation during limonene ozonolysis: insights from ultrahigh-resolution FT-ICR mass spectrometry characterization, Atmos. Chem. Phys., 12, 5523–5536, https://doi.org/10.5194/acp-12-5523-2012, 2012.
Kundu, S., Fisseha, R., Putman, A. L., Rahn, T. A., and Mazzoleni, L. R.:
Molecular formula composition of β-caryophyllene ozonolysis SOA
formed in humid and dry conditions, Atmos. Environ., 154, 70–81,
https://doi.org/10.1016/j.atmosenv.2016.12.031, 2017.
Li, R., Palm, B. B., Ortega, A. M., Hlywiak, J., Hu, W., Peng, Z., Day, D.
A., Knote, C., Brune, W. H., de Gouw, J. A., and Jimenez, J. L.: Modeling
the Radical Chemistry in an Oxidation Flow Reactor: Radical Formation and
Recycling, Sensitivities, and the OH Exposure Estimation Equation,
J. Phys. Chem. A, 119, 4418–4432, https://doi.org/10.1021/jp509534k, 2015.
Lopez-Hilfiker, F. D., Mohr, C., Ehn, M., Rubach, F., Kleist, E., Wildt, J., Mentel, Th. F., Lutz, A., Hallquist, M., Worsnop, D., and Thornton, J. A.: A novel method for online analysis of gas and particle composition: description and evaluation of a Filter Inlet for Gases and AEROsols (FIGAERO), Atmos. Meas. Tech., 7, 983–1001, https://doi.org/10.5194/amt-7-983-2014, 2014.
McFiggans, G., Coe, H., Burgess, R., Allan, J., Cubison, M., Alfarra, M. R., Saunders, R., Saiz-Lopez, A., Plane, J. M. C., Wevill, D., Carpenter, L., Rickard, A. R., and Monks, P. S.: Direct evidence for coastal iodine particles from Laminaria macroalgae – linkage to emissions of molecular iodine, Atmos. Chem. Phys., 4, 701–713, https://doi.org/10.5194/acp-4-701-2004, 2004.
McFiggans, G., Bale, C. S. E., Ball, S. M., Beames, J. M., Bloss, W. J., Carpenter, L. J., Dorsey, J., Dunk, R., Flynn, M. J., Furneaux, K. L., Gallagher, M. W., Heard, D. E., Hollingsworth, A. M., Hornsby, K., Ingham, T., Jones, C. E., Jones, R. L., Kramer, L. J., Langridge, J. M., Leblanc, C., LeCrane, J.-P., Lee, J. D., Leigh, R. J., Longley, I., Mahajan, A. S., Monks, P. S., Oetjen, H., Orr-Ewing, A. J., Plane, J. M. C., Potin, P., Shillings, A. J. L., Thomas, F., von Glasow, R., Wada, R., Whalley, L. K., and Whitehead, J. D.: Iodine-mediated coastal particle formation: an overview of the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) Roscoff coastal study, Atmos. Chem. Phys., 10, 2975–2999, https://doi.org/10.5194/acp-10-2975-2010, 2010.
Monahan, C., Ashu-Ayem, E. R., Nitschke, U., Darby, S. B., Smith, P. D.,
Stengel, D. B., Venables, D. S., and O'Dowd, C. D.: Coastal Iodine
Emissions: Part 2. Chamber Experiments of Particle Formation from Laminaria
digitata-Derived and Laboratory-Generated I2, Environ. Sci.
Technol., 46, 10422–10428, https://doi.org/10.1021/es3011805, 2012.
Nguyen, T. B., Bateman, A. P., Bones, D. L., Nizkorodov, S. A., Laskin, J.,
and Laskin, A.: High-resolution mass spectrometry analysis of secondary
organic aerosol generated by ozonolysis of isoprene, Atmos.
Environ., 44, 1032–1042,
https://doi.org/10.1016/j.atmosenv.2009.12.019, 2010.
O'Dowd, C. D., Jimenez, J. L., Bahreini, R., Flagan, R. C., Seinfeld, J. H.,
Hämeri, K., Pirjola, L., Kulmala, M., Jennings, S. G., and Hoffmann, T.:
Marine aerosol formation from biogenic iodine emissions, Nature, 417, 632, https://doi.org/10.1038/nature00775, 2002.
O'Dowd, C. D., Facchini, M. C., Cavalli, F., Cebrunis, D., Mircea, M.,
Decesari, S., Fuzzi, S., Yoon, Y. J., and Putard, J.-P.: Biogenically driven
organic contribution to marine aerosol, Nature, 431, 676–680, 2004.
Plane, J. M. C., Joseph, D. M., Allan, B. J., Ashworth, S. H., and
Francisco, J. S.: An Experimental and Theoretical Study of the Reactions OIO + NO and OIO + OH, J. Phys. Chem. A, 110, 93–100, https://doi.org/10.1021/jp055364y, 2006.
Putman, A. L., Offenberg, J. H., Fisseha, R., Kundu, S., Rahn, T. A., and
Mazzoleni, L. R.: Ultrahigh-resolution FT-ICR mass spectrometry
characterization of α-pinene ozonolysis SOA, Atmos.
Environ., 46, 164–172,
https://doi.org/10.1016/j.atmosenv.2011.10.003, 2012.
Riva, M., Budisulistiorini, S. H., Zhang, Z. F., Gold, A., Thornton, J. A.,
Turpin, B. J., and Surratt, J. D.: Multiphase reactivity of gaseous
hydroperoxide oligomers produced from isoprene ozonolysis in the presence of
acidified aerosols, Atmos. Environ., 152, 314–322, https://doi.org/10.1016/j.atmosenv.2016.12.040, 2017.
Saiz-Lopez, A., Plane, J. M. C., Baker, A. R., Carpenter, L. J., von Glasow,
R., Gómez Martín, J. C., McFiggans, G., and Saunders, R. W.:
Atmospheric Chemistry of Iodine, Chem. Rev., 112, 1773–1804, https://doi.org/10.1021/cr200029u, 2012.
Saiz-Lopez, A., Fernandez, R. P., Ordóñez, C., Kinnison, D. E., Gómez Martín, J. C., Lamarque, J.-F., and Tilmes, S.: Iodine chemistry in the troposphere and its effect on ozone, Atmos. Chem. Phys., 14, 13119–13143, https://doi.org/10.5194/acp-14-13119-2014, 2014.
Saunders, R. W. and Plane, J. M. C.: Formation Pathways and Composition of
Iodine Oxide Ultra-Fine Particles, Environ. Chem., 2, 299–303,
https://doi.org/10.1071/EN05079, 2005.
Saunders, R. W., Kumar, R., Gómez Martín, J. C., Mahajan, A. S., Murray, B. J. and Plane, J. M. C.: Studies of the Formation and Growth of Aerosol from Molecular Iodine Precursor, Z. Phys. Chem., 224, 1095–1117, https://doi.org/10.1524/zpch.2010.6143, 2010.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from
air pollution to climate change, 3nd, John Wiley and Sons. Inc., New
York, ISBN 978-1-119-22117-3, 2016.
Sellegri, K., Yoon, Y. J., Jennings, S. G., O'Dowd, C. D., Pirjola, L.,
Cautenet, S., Chen, H., and Hoffmann, T.: Quantification of Coastal New
Ultra-Fine Particles Formation from In situ and Chamber Measurements during
the BIOFLUX Campaign, Environ. Chem., 2, 260–270,
https://doi.org/10.1071/EN05074, 2005.
Sellegri, K., Pey, J., Rose, C., Culot, A., DeWitt, H. L., Mas, S., Schwier,
A. N., Temime-Roussel, B., Charriere, B., Saiz-Lopez, A., Mahajan, A. S.,
Parin, D., Kukui, A., Sempere, R., D'Anna, B., and Marchand, N.: Evidence of
atmospheric nanoparticle formation from emissions of marine microorganisms,
Geophys. Res. Lett., 43, 6596–6603,
https://doi.org/10.1002/2016GL069389, 2016.
Sipilä, M., Sarnela, N., Jokinen, T., Henschel, H., Junninen, H.,
Kontkanen, J., Richters, S., Kangasluoma, J., Franchin, A.,
Peräkylä, O., Rissanen, M. P., Ehn, M., Vehkamäki, H., Kurten,
T., Berndt, T., Petäjä, T., Worsnop, D., Ceburnis, D., Kerminen,
V.-M., Kulmala, M., and O'Dowd, C.: Molecular-scale evidence of aerosol
particle formation via sequential addition of HIO3, Nature, 537, 532–534, https://doi.org/10.1038/nature19314,
2016.
Teruel, M. A., Dillon, T. J., Horowitz, A., and Crowley, J. N.: Reaction of
O(3P) with the alkyl iodides: CF3I, CH3I, CH2I2, C2H5I, 1-C3H7I and 2-C3H7I,
Phys. Chem. Chem. Phys., 6, 2172–2178, https://doi.org/10.1039/B316402K, 2004.
Vaattovaara, P., Huttunen, P. E., Yoon, Y. J., Joutsensaari, J., Lehtinen, K. E. J., O'Dowd, C. D., and Laaksonen, A.: The composition of nucleation and Aitken modes particles during coastal nucleation events: evidence for marine secondary organic contribution, Atmos. Chem. Phys., 6, 4601–4616, https://doi.org/10.5194/acp-6-4601-2006, 2006.
Wang, M., Zeng, L., Lu, S., Shao, M., Liu, X., Yu, X., Chen, W., Yuan, B.,
Zhang, Q., Hu, M., and Zhang, Z.: Development and validation of a
cryogen-free automatic gas chromatograph system (GC-MS/FID) for online
measurements of volatile organic compounds, Analytical Methods, 6,
9424–9434, https://doi.org/10.1039/C4AY01855A, 2014.
Wang, M., Chen, D., Xiao, M., Ye, Q., Stolzenburg, D., Hofbauer, V., Ye, P.,
Vogel, A. L., Mauldin, R. L., 3rd, Amorim, A., Baccarini, A., Baumgartner,
B., Brilke, S., Dada, L., Dias, A., Duplissy, J., Finkenzeller, H., Garmash,
O., He, X. C., Hoyle, C. R., Kim, C., Kvashnin, A., Lehtipalo, K., Fischer,
L., Molteni, U., Petäjä, T., Pospisilova, V., Quéléver, L.
L. J., Rissanen, M., Simon, M., Tauber, C., Tomé, A., Wagner, A. C.,
Weitz, L., Volkamer, R., Winkler, P. M., Kirkby, J., Worsnop, D. R.,
Kulmala, M., Baltensperger, U., Dommen, J., El-Haddad, I., and Donahue, N.
M.: Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic
Compounds, Environ. Sci. Technol., 54, 7911–7921, https://doi.org/10.1021/acs.est.0c02100, 2020.
Wang, X., Hayeck, N., Brüggemann, M., Yao, L., Chen, H., Zhang, C.,
Emmelin, C., Chen, J., George, C., and Wang, L.: Chemical Characteristics of
Organic Aerosols in Shanghai: A Study by Ultrahigh-Performance Liquid
Chromatography Coupled With Orbitrap Mass Spectrometry, J.
Geophys. Res.-Atmos., 122, 11703–711722,
https://doi.org/10.1002/2017JD026930, 2017.
Whitehead, J. D., McFiggans, G. B., Gallagher, M. W., and Flynn, M. J.:
Direct linkage between tidally driven coastal ozone deposition fluxes,
particle emission fluxes, and subsequent CCN formation, Geophys. Res.
Lett., 36, L04806, https://doi.org/10.1029/2008GL035969, 2009.
Yan, C., Nie, W., Vogel, A. L., Dada, L., Lehtipalo, K., Stolzenburg, D.,
Wagner, R., Rissanen, M. P., Xiao, M., Ahonen, L., Fischer, L., Rose, C.,
Bianchi, F., Gordon, H., Simon, M., Heinritzi, M., Garmash, O., Roldin, P.,
Dias, A., Ye, P., Hofbauer, V., Amorim, A., Bauer, P. S., Bergen, A.,
Bernhammer, A. K., Breitenlechner, M., Brilke, S., Buchholz, A., Mazon, S.
B., Canagaratna, M. R., Chen, X., Ding, A., Dommen, J., Draper, D. C.,
Duplissy, J., Frege, C., Heyn, C., Guida, R., Hakala, J., Heikkinen, L.,
Hoyle, C. R., Jokinen, T., Kangasluoma, J., Kirkby, J., Kontkanen, J.,
Kürten, A., Lawler, M. J., Mai, H., Mathot, S., Mauldin, R. L., 3rd,
Molteni, U., Nichman, L., Nieminen, T., Nowak, J., Ojdanic, A., Onnela, A.,
Pajunoja, A., Petäjä, T., Piel, F., Quéléver, L. L. J.,
Sarnela, N., Schallhart, S., Sengupta, K., Sipilä, M., Tomé, A.,
Tröstl, J., Väisänen, O., Wagner, A. C., Ylisirniö, A., Zha,
Q., Baltensperger, U., Carslaw, K. S., Curtius, J., Flagan, R. C., Hansel,
A., Riipinen, I., Smith, J. N., Virtanen, A., Winkler, P. M., Donahue, N.
M., Kerminen, V. M., Kulmala, M., Ehn, M., and Worsnop, D. R.:
Size-dependent influence of NOx on the growth rates of organic aerosol
particles, Science Advances, 6, eaay4945, https://doi.org/10.1126/sciadv.aay4945, 2020.
Yu, H.: Size spectrum, time series and atom number distribution of macroalgal emission vapors and oxidation products, Zenodo [data set], https://doi.org/10.5281/zenodo.6965859, 2022.
Yu, H., Ren, L., Huang, X., Xie, M., He, J., and Xiao, H.: Iodine speciation and size distribution in ambient aerosols at a coastal new particle formation hotspot in China, Atmos. Chem. Phys., 19, 4025–4039, https://doi.org/10.5194/acp-19-4025-2019, 2019.
Short summary
The organic compounds involved in continental new particle formation have been investigated in depth in the last 2 decades. In contrast, no prior work has studied the exact chemical composition of organic compounds and their role in coastal new particle formation. We present a complementary study to the ongoing laboratory and field research on iodine nucleation in the coastal atmosphere. This study provided a more complete story of coastal I-NPF from low-tide macroalgal emission.
The organic compounds involved in continental new particle formation have been investigated in...
Altmetrics
Final-revised paper
Preprint