Articles | Volume 21, issue 15
https://doi.org/10.5194/acp-21-11581-2021
https://doi.org/10.5194/acp-21-11581-2021
Research article
 | 
04 Aug 2021
Research article |  | 04 Aug 2021

Photodegradation of atmospheric chromophores: changes in oxidation state and photochemical reactivity

Zhen Mu, Qingcai Chen, Lixin Zhang, Dongjie Guan, and Hao Li

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Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-1032,https://doi.org/10.5194/acp-2019-1032, 2020
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Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Aiona, P. K., Luek, J. L., Timko, S. A., Powers, L. C., Gonsior, M., and Nizkorodov, S. A.: Effect of Photolysis on Absorption and Fluorescence Spectra of Light-Absorbing Secondary Organic Aerosols, ACS Earth Space Chem., 2, 235–245, https://doi.org/10.1021/acsearthspacechem.7b00153, 2018. 
Altieri, K. E., Carlton, A. G., Lim, H. J., Turpin, B. J., and Seitzinger, S. P.: Evidence for oligomer formation in clouds: Reactions of isoprene oxidation products, Environ. Sci. Technol., 40, 4956–4960, https://doi.org/10.1021/es052170n, 2006. 
Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud methylglyoxal reactions: Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ., 42, 1476–1490, https://doi.org/10.1016/j.atmosenv.2007.11.015, 2008. 
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
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Sunlight affects the life and chemical composition of atmospheric aerosols and thus alters air quality. This study demonstrated that the photo-aging process not only changed the chemical compositions of chromophoric aerosols but also changed the roles of the chromophoric organic matter in the photo-aging process of aerosol. This study adds to our understanding of how sunlight affects chromophoric aerosol aging.
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