Articles | Volume 18, issue 3
https://doi.org/10.5194/acp-18-2225-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-2225-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Feb 2018
Research article |
| 15 Feb 2018
| 15 Feb 2018
Modeling the partitioning of organic chemical species in cloud phases with CLEPS (1.1)
Clémence Rose
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Nadine Chaumerliac
CORRESPONDING AUTHOR
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Laurent Deguillaume
CORRESPONDING AUTHOR
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Hélène Perroux
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Camille Mouchel-Vallon
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
now at: National Center for Atmospheric Research, Boulder, Colorado,
USA
Maud Leriche
Université de Toulouse, UPS, CNRS, Laboratoire d'Aérologie,
31400 Toulouse, France
Luc Patryl
CEA, DAM, DIF, 91297 Arpajon, France
Patrick Armand
CEA, DAM, DIF, 91297 Arpajon, France
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Chao Yan, Lubna Dada, Clémence Rose, Tuija Jokinen, Wei Nie, Siegfried Schobesberger, Heikki Junninen, Katrianne Lehtipalo, Nina Sarnela, Ulla Makkonen, Olga Garmash, Yonghong Wang, Qiaozhi Zha, Pauli Paasonen, Federico Bianchi, Mikko Sipilä, Mikael Ehn, Tuukka Petäjä, Veli-Matti Kerminen, Douglas R. Worsnop, and Markku Kulmala
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B. Vié, J.-P. Pinty, S. Berthet, and M. Leriche
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C. Barbet, L. Deguillaume, N. Chaumerliac, M. Leriche, A. Berger, E. Freney, A. Colomb, K. Sellegri, L. Patryl, and P. Armand
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-13395-2015, https://doi.org/10.5194/acpd-15-13395-2015, 2015
Preprint withdrawn
M. Joly, P. Amato, L. Deguillaume, M. Monier, C. Hoose, and A.-M. Delort
Atmos. Chem. Phys., 14, 8185–8195, https://doi.org/10.5194/acp-14-8185-2014, https://doi.org/10.5194/acp-14-8185-2014, 2014
L. Deguillaume, T. Charbouillot, M. Joly, M. Vaïtilingom, M. Parazols, A. Marinoni, P. Amato, A.-M. Delort, V. Vinatier, A. Flossmann, N. Chaumerliac, J. M. Pichon, S. Houdier, P. Laj, K. Sellegri, A. Colomb, M. Brigante, and G. Mailhot
Atmos. Chem. Phys., 14, 1485–1506, https://doi.org/10.5194/acp-14-1485-2014, https://doi.org/10.5194/acp-14-1485-2014, 2014
M. Leriche, J.-P. Pinty, C. Mari, and D. Gazen
Geosci. Model Dev., 6, 1275–1298, https://doi.org/10.5194/gmd-6-1275-2013, https://doi.org/10.5194/gmd-6-1275-2013, 2013
Related subject area
Subject: Clouds and Precipitation | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Regional scale effects of the aerosol cloud interaction simulated with an online coupled comprehensive chemistry model
Representation of tropical deep convection in atmospheric models – Part 1: Meteorology and comparison with satellite observations
Structure-activity relationships to estimate the effective Henry's law constants of organics of atmospheric interest
Uncertainties in atmospheric chemistry modelling due to convection parameterisations and subsequent scavenging
A meteorological overview of the ARCTAS 2008 mission
Leslie Nuñez López, Pierre Amato, and Barbara Ervens
EGUsphere, https://doi.org/10.5194/egusphere-2023-2270, https://doi.org/10.5194/egusphere-2023-2270, 2023
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Living bacteria comprise a small particle fraction in the atmosphere. Our model study shows that atmospheric bacteria in clouds may efficiently biodegrade formic and acetic acids that affect acidity of rain. We conclude that current atmospheric models underestimate losses of these acids as they only consider chemical processes. We suggest that biodegradation can affect atmospheric concentration not only of formic and acetic acids but also of other volatile, moderately soluble organics.
Aishwarya Raman, Thomas Hill, Paul J. DeMott, Balwinder Singh, Kai Zhang, Po-Lun Ma, Mingxuan Wu, Hailong Wang, Simon P. Alexander, and Susannah M. Burrows
Atmos. Chem. Phys., 23, 5735–5762, https://doi.org/10.5194/acp-23-5735-2023, https://doi.org/10.5194/acp-23-5735-2023, 2023
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Ice-nucleating particles (INPs) play an important role in cloud processes and associated precipitation. Yet, INPs are not accurately represented in climate models. This study attempts to uncover these gaps by comparing model-simulated INP concentrations against field campaign measurements in the SO for an entire year, 2017–2018. Differences in INP concentrations and variability between the model and observations have major implications for modeling cloud properties in high latitudes.
Liji M. David, Mary Barth, Lena Höglund-Isaksson, Pallav Purohit, Guus J. M. Velders, Sam Glaser, and A. R. Ravishankara
Atmos. Chem. Phys., 21, 14833–14849, https://doi.org/10.5194/acp-21-14833-2021, https://doi.org/10.5194/acp-21-14833-2021, 2021
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We calculated the expected concentrations of trifluoroacetic acid (TFA) from the atmospheric breakdown of HFO-1234yf (CF3CF=CH2), a substitute for global warming hydrofluorocarbons, emitted now and in the future by India, China, and the Middle East. We used two chemical transport models. We conclude that the projected emissions through 2040 would not be detrimental, given the current knowledge of the effects of TFA on humans and ecosystems.
Keun-Ok Lee, Brice Barret, Eric L. Flochmoën, Pierre Tulet, Silvia Bucci, Marc von Hobe, Corinna Kloss, Bernard Legras, Maud Leriche, Bastien Sauvage, Fabrizio Ravegnani, and Alexey Ulanovsky
Atmos. Chem. Phys., 21, 3255–3274, https://doi.org/10.5194/acp-21-3255-2021, https://doi.org/10.5194/acp-21-3255-2021, 2021
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This paper focuses on the emission sources and pathways of pollution from the boundary layer to the Asian monsoon anticyclone (AMA) during the StratoClim aircraft campaign period. Simulations with the Meso-NH cloud-chemistry model at a horizontal resolution of 15 km are performed over the Asian region to characterize the impact of monsoon deep convection on the composition of AMA and on the formation of the Asian tropopause aerosol layer during the StratoClim campaign.
Amina Khaled, Minghui Zhang, Pierre Amato, Anne-Marie Delort, and Barbara Ervens
Atmos. Chem. Phys., 21, 3123–3141, https://doi.org/10.5194/acp-21-3123-2021, https://doi.org/10.5194/acp-21-3123-2021, 2021
Viral Shah, Daniel J. Jacob, Jonathan M. Moch, Xuan Wang, and Shixian Zhai
Atmos. Chem. Phys., 20, 12223–12245, https://doi.org/10.5194/acp-20-12223-2020, https://doi.org/10.5194/acp-20-12223-2020, 2020
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Cloud water pH affects atmospheric chemistry, and acid rain damages ecosystems. We use model simulations along with observations to present a global view of cloud water and precipitation pH. Sulfuric acid, nitric acid, and ammonia control the pH in the northern midlatitudes, but carboxylic acids and dust cations are important in the tropics and subtropics. The acid inputs to many nitrogen-saturated ecosystems are high enough to cause acidification, with ammonium as the main acidifying species.
D. Barahona
Atmos. Chem. Phys., 15, 13819–13831, https://doi.org/10.5194/acp-15-13819-2015, https://doi.org/10.5194/acp-15-13819-2015, 2015
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This paper describes the process of the transfer of water molecules between liquid and the ice during the early stages of ice formation. Using concepts of nonreversible thermodynamics, it is shown that the activation energy can be defined in terms of the bulk self-diffusivity of water and the probability of interface transfer. The application of this model to classical nucleation theory shows good agreement of measured nucleation rates with experimental results for temperatures as low as 190K.
R. Mashayekhi and J. J. Sloan
Atmos. Chem. Phys., 14, 5111–5125, https://doi.org/10.5194/acp-14-5111-2014, https://doi.org/10.5194/acp-14-5111-2014, 2014
C. A. Klich and H. E. Fuelberg
Atmos. Chem. Phys., 14, 609–627, https://doi.org/10.5194/acp-14-609-2014, https://doi.org/10.5194/acp-14-609-2014, 2014
J.-F. Doussin and A. Monod
Atmos. Chem. Phys., 13, 11625–11641, https://doi.org/10.5194/acp-13-11625-2013, https://doi.org/10.5194/acp-13-11625-2013, 2013
C. Mouchel-Vallon, P. Bräuer, M. Camredon, R. Valorso, S. Madronich, H. Herrmann, and B. Aumont
Atmos. Chem. Phys., 13, 1023–1037, https://doi.org/10.5194/acp-13-1023-2013, https://doi.org/10.5194/acp-13-1023-2013, 2013
H. S. Peterson and W. H. Beasley
Atmos. Chem. Phys., 11, 10259–10268, https://doi.org/10.5194/acp-11-10259-2011, https://doi.org/10.5194/acp-11-10259-2011, 2011
W. Feng, M. P. Chipperfield, S. Dhomse, B. M. Monge-Sanz, X. Yang, K. Zhang, and M. Ramonet
Atmos. Chem. Phys., 11, 5783–5803, https://doi.org/10.5194/acp-11-5783-2011, https://doi.org/10.5194/acp-11-5783-2011, 2011
M. Bangert, C. Kottmeier, B. Vogel, and H. Vogel
Atmos. Chem. Phys., 11, 4411–4423, https://doi.org/10.5194/acp-11-4411-2011, https://doi.org/10.5194/acp-11-4411-2011, 2011
M. R. Russo, V. Marécal, C. R. Hoyle, J. Arteta, C. Chemel, M. P. Chipperfield, O. Dessens, W. Feng, J. S. Hosking, P. J. Telford, O. Wild, X. Yang, and J. A. Pyle
Atmos. Chem. Phys., 11, 2765–2786, https://doi.org/10.5194/acp-11-2765-2011, https://doi.org/10.5194/acp-11-2765-2011, 2011
T. Raventos-Duran, M. Camredon, R. Valorso, C. Mouchel-Vallon, and B. Aumont
Atmos. Chem. Phys., 10, 7643–7654, https://doi.org/10.5194/acp-10-7643-2010, https://doi.org/10.5194/acp-10-7643-2010, 2010
H. Tost, M. G. Lawrence, C. Brühl, P. Jöckel, The GABRIEL Team, and The SCOUT-O3-DARWIN/ACTIVE Team
Atmos. Chem. Phys., 10, 1931–1951, https://doi.org/10.5194/acp-10-1931-2010, https://doi.org/10.5194/acp-10-1931-2010, 2010
H. E. Fuelberg, D. L. Harrigan, and W. Sessions
Atmos. Chem. Phys., 10, 817–842, https://doi.org/10.5194/acp-10-817-2010, https://doi.org/10.5194/acp-10-817-2010, 2010
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Short summary
A detailed aqueous phase mechanism CLEPS 1.1 is coupled with warm microphysics including activation of aerosol particles into cloud droplets. Simulated aqueous concentrations of carboxylic acids are close to the long-term measurements conducted at Puy de Dôme (France). Sensitivity tests show that formic and acetic acids mainly originate from the gas phase with highly variable aqueous-phase reactivity depending on cloud pH, while C3–C4 carboxylic acids mainly originate from the particulate phase.
A detailed aqueous phase mechanism CLEPS 1.1 is coupled with warm microphysics including...
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