Articles | Volume 16, issue 23
https://doi.org/10.5194/acp-16-15425-2016
https://doi.org/10.5194/acp-16-15425-2016
Research article
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13 Dec 2016
Research article | Highlight paper |  | 13 Dec 2016

The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact

Joel D. Rindelaub, Carlos H. Borca, Matthew A. Hostetler, Jonathan H. Slade, Mark A. Lipton, Lyudmila V. Slipchenko, and Paul B. Shepson

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Cited articles

Baker, J. W. and Easty, D. M.: Hydrolysis of organic nitrates, Nature, 166, p. 156, https://doi.org/10.1038/166156a0, 1950.
Barone, V. and Cossie, M.: Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model, J. Phys. Chem. A, 102, 1995–2001, 1998.
Bateman, A. P., Nizkorodov, S. A., Laskin, J., and Laskin, A.: Photolytic processing of secondary organic aerosols dissolved in cloud droplets, Phys. Chem. Chem. Phys., 13, 12199–12212, 2011.
Bean, J. K. and Hildebrandt Ruiz, L.: Gas-particle partitioning and hydrolysis of organic nitrates formed from the oxidation of a-pinene in environmental chamber experiments, Atmos. Chem. Phys., 16, 2175–2184, https://doi.org/10.5194/acp-16-2175-2016, 2016.
Bleier, D. B. and Elrod, M. J.: Kinetics and Thermodynamics of Atmospherically Relevant Aqueous Phase Reactions of α-Pinene Oxide, J. Phys. Chem. A, 117, 4223–4232, 2013.
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Short summary
This study provides new insight into the hydrolysis reaction mechanism, which was elucidated for atmospherically relevant organic nitrates using kinetic measurements, product identification, and theoretical calculations. The results help broaden our knowledge of the organic chemistry that impacts the fate of NOx, ozone production, aerosol phase processing, and aerosol composition.
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