Articles | Volume 14, issue 23
https://doi.org/10.5194/acp-14-13189-2014
https://doi.org/10.5194/acp-14-13189-2014
Research article
 | 
11 Dec 2014
Research article |  | 11 Dec 2014

Novel methods for predicting gas–particle partitioning during the formation of secondary organic aerosol

F. Wania, Y. D. Lei, C. Wang, J. P. D. Abbatt, and K.-U. Goss

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Cited articles

Abraham, M. H.: Scales of solute hydrogen-bonding: Their construction and application to physicochemical and biochemical processes, Chem. Soc. Rev. 22, 73–83, 1993.
Abraham, M. H., Whiting, G. S., Doherty, R. M., and Shuely, W. J.: Hydrogen bonding xvii. The characterisation of 24 gas-liquid chromatographic stationary phases studied by Poole and co-workers, including molten salts, and evaluation of solute-stationary phase interactions, J. Chromatography, 587, 229–236, 1991.
Arp, H. P. H. and Goss, K. U.: Ambient gas/particle partitioning. 3. Estimating partition coefficients of apolar, polar, and ionizable organic compounds by their molecular structure, Environ. Sci. Technol., 43, 1923–1929, 2009.
Arp, H. P. H., Schwarzenbach, R. P., and Goss, K. U.: Ambient gas/particle partitioning. 1. Sorption mechanisms of apolar, polar, and ionizable organic compounds, Environ. Sci. Technol., 42, 5541–5547, 2008a.
Arp, H. P. H., Schwarzenbach, R. P., and Goss, K. U.: Ambient gas/particle partitioning. 2: The influence of particle source and temperature on sorption to dry terrestrial aerosols, Environ. Sci. Technol., 42, 5951–5957, 2008b.
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Short summary
A description of the formation of secondary organic aerosol requires the prediction of the partitioning equilibrium of organic compounds with multiple functional groups between gas and organic particle phase. While this is typically done by predicting both the saturation vapour pressure and the activity coefficient in the organic particle phase, we demonstrate here that it is feasible to predict the partitioning equilibrium directly. This direct approach has greater precision.
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