Articles | Volume 14, issue 21
https://doi.org/10.5194/acp-14-11571-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-14-11571-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
05 Nov 2014
Research article |
| 05 Nov 2014
Evolution of aerosol chemistry in Xi'an, inland China, during the dust storm period of 2013 – Part 1: Sources, chemical forms and formation mechanisms of nitrate and sulfate
G. H. Wang
School of Human Settlements and Civil Engineering, Xi'an Jiaotong University, Xi'an 710079, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
C. L. Cheng
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
Y. Huang
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
South China Institute of Environmental Science, Guangzhou 510655, China
Y. Q. Ren
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
F. Wu
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
J. J. Meng
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
J. J. Li
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
Y. T. Cheng
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
J. J. Cao
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
S. X. Liu
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
T. Zhang
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
R. Zhang
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
Y. B. Chen
State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China
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Biogenic secondary organic aerosol (BSOA), as an important atmospheric component, is prevalent within the boundary layer and can influence air quality and human health. Our observations demonstrate that anthropogenic NOx and the enhanced aerosol water driven by sulfate inhibit BSOA formation in lifting air masses, leading to a moderate reduction in the SOA burden in the upper boundary layer.
Zheng Li, Gehui Wang, Binyu Xiao, Rongjie Li, Can Wu, Shaojun Lv, Feng Wu, Qingyan Fu, and Yusen Duan
EGUsphere, https://doi.org/10.5194/egusphere-2025-654, https://doi.org/10.5194/egusphere-2025-654, 2025
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Gas-to-aerosol partitioning of organics were investigated in Shanghai during 2023 dust storm period. We found the partitioning coefficients (Fp) of WSOCs in DS were comparable to those during a haze episode (HE), and aerosol liquid water content primarily drove Fp variation in HE, while pH was the dominant factor in DS. Moreover, an enhanced light absorption of Asian dust by brown carbon, mainly in coarse mode, formation was revealed.
Si Zhang, Yining Gao, Xinbei Xu, Luyao Chen, Can Wu, Zheng Li, Rongjie Li, Binyu Xiao, Xiaodi Liu, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 14177–14190, https://doi.org/10.5194/acp-24-14177-2024, https://doi.org/10.5194/acp-24-14177-2024, 2024
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Secondary organic aerosols (SOAs) from acetone photooxidation in the presence of various seeds were studied to illustrate SOA formation kinetics under ammonia-rich conditions. The oxidation mechanism of acetone was investigated using an observation-based model incorporating a Master Chemical Mechanism model. A higher SOA yield of acetone was observed compared to methylglyoxal due to an enhanced uptake of the small photooxidation products of acetone.
Xinbei Xu, Yining Gao, Si Zhang, Luyao Chen, Rongjie Li, Zheng Li, Rui Li, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3046, https://doi.org/10.5194/egusphere-2024-3046, 2024
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This work systematically explained the nonlinear effect of NOx level on isoprene-SOA mass yield through a series of chamber experiments. We found that the turning point under various oxidants was smaller than previous reported in the presence of OH precursors, which could be attributed to the RO2 pathway competition in nucleation and condensation of low volatile products. The highest SOA yield was at a branching ratio β of 0.5, which can be used as a reference for field campaign and modeling.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 9263–9275, https://doi.org/10.5194/acp-24-9263-2024, https://doi.org/10.5194/acp-24-9263-2024, 2024
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Brown carbon (BrC) is prevalent in the troposphere and can efficiently absorb solar and terrestrial radiation. Our observations show that the enhanced light absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
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Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
Shijie Liu, Xinbei Xu, Si Zhang, Rongjie Li, Zheng Li, Can Wu, Rui Li, Guiqin Zhang, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1599, https://doi.org/10.5194/egusphere-2024-1599, 2024
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We conducted α-pinene photooxidation experiments in an atmospheric chamber at different NOx concentrations. The increased distribution coefficient of the oxidation products between the aerosol and gas phases with NOx was responsible for the increased SOA yields with NOx under low-NOx conditions. We also found the fraction of SOA made up of nitrogen-containing organic compounds (NOCs) increased with NOx.
Rui Li, Yining Gao, Lijia Zhang, Yubing Shen, Tianzhao Xu, Wenwen Sun, and Gehui Wang
Atmos. Chem. Phys., 24, 7623–7636, https://doi.org/10.5194/acp-24-7623-2024, https://doi.org/10.5194/acp-24-7623-2024, 2024
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A three-stage model was developed to obtain the global maps of reactive nitrogen components during 2000–2100. The results implied that cross-validation R2 values of four species showed satisfactory performance (R2 > 0.55). Most reactive nitrogen components, except NH3, in China showed increases during 2000–2013. In the future scenarios, SSP3-7.0 (traditional-energy scenario) and SSP1-2.6 (carbon neutrality scenario) showed the highest and lowest reactive nitrogen component concentrations.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Yanqin Ren, Gehui Wang, Jie Wei, Jun Tao, Zhisheng Zhang, and Hong Li
Atmos. Chem. Phys., 23, 6835–6848, https://doi.org/10.5194/acp-23-6835-2023, https://doi.org/10.5194/acp-23-6835-2023, 2023
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Nine quantified nitrated aromatic compounds (NACs) in PM2.5 were examined at the peak of Mt. Wuyi. They manifested a significant rise in overall abundance in the winter and autumn. The transport of contaminants had a significant impact on NACs. Under low-NOx conditions, the formation of NACs was comparatively sensitive to NO2, suggesting that NACs would become significant in the aerosol characteristics when nitrate concentrations decreased as a result of emission reduction measures.
Rui Li, Yining Gao, Yubao Chen, Meng Peng, Weidong Zhao, Gehui Wang, and Jiming Hao
Atmos. Chem. Phys., 23, 4709–4726, https://doi.org/10.5194/acp-23-4709-2023, https://doi.org/10.5194/acp-23-4709-2023, 2023
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A random forest model was used to isolate the effects of emission and meteorology to trace elements in PM2.5 in Tangshan. The results suggested that control measures facilitated decreases of Ga, Co, Pb, Zn, and As, due to the strict implementation of coal-to-gas strategies and optimisation of industrial structure and layout. However, the deweathered levels of Ca, Cr, and Fe only displayed minor decreases, indicating that ferrous metal smelting and vehicle emission controls should be enhanced.
Ling Huang, Hanqing Liu, Greg Yarwood, Gary Wilson, Jun Tao, Zhiwei Han, Dongsheng Ji, Yangjun Wang, and Li Li
EGUsphere, https://doi.org/10.5194/egusphere-2022-1502, https://doi.org/10.5194/egusphere-2022-1502, 2023
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Secondary organic aerosols are an important component of PM2.5, with contributions from anthropogenic, biogenic volatile organic compounds, semi- and intermediate volatility organic compounds. Policy makers need to know which SOA precursors are important. We investigated the role of different SOA precursors and SOA algorithms by applying two commonly used models, CAMx and CMAQ. Suggestions for SOA modelling and control are provided.
Can Wu, Cong Cao, Jianjun Li, Shaojun Lv, Jin Li, Xiaodi Liu, Si Zhang, Shijie Liu, Fan Zhang, Jingjing Meng, and Gehui Wang
Atmos. Chem. Phys., 22, 15621–15635, https://doi.org/10.5194/acp-22-15621-2022, https://doi.org/10.5194/acp-22-15621-2022, 2022
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Over the past decade, the relative abundance of NH4NO3 in aerosol has been enhanced in most urban areas of China, which profoundly affects the PM2.5 pollution episodes. Our work finds that fine-particle nitrate and ammonium exhibited distinct, different physicochemical behaviors in the aerosol aging process.
Li Liu, Ye Kuang, Miaomiao Zhai, Biao Xue, Yao He, Jun Tao, Biao Luo, Wanyun Xu, Jiangchuan Tao, Changqin Yin, Fei Li, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, and Min Shao
Atmos. Chem. Phys., 22, 7713–7726, https://doi.org/10.5194/acp-22-7713-2022, https://doi.org/10.5194/acp-22-7713-2022, 2022
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Using simultaneous measurements of a humidified nephelometer system and an aerosol chemical speciation monitor in winter in Guangzhou, the strongest scattering ability of more oxidized oxygenated organic aerosol (MOOA) among aerosol components considering their dry-state scattering ability and water uptake ability was revealed, leading to large impacts of MOOA on visibility degradation. This has important implications for visibility improvement in China and aerosol radiative effect simulation.
Shijie Liu, Dandan Huang, Yiqian Wang, Si Zhang, Xiaodi Liu, Can Wu, Wei Du, and Gehui Wang
Atmos. Chem. Phys., 21, 17759–17773, https://doi.org/10.5194/acp-21-17759-2021, https://doi.org/10.5194/acp-21-17759-2021, 2021
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A series of chamber experiments was performed to probe the individual and common effects of NH3 and NOx on toluene secondary organic aerosol (SOA) formation through OH photooxidation. The synergetic effects of NH3 and NOx on the toluene SOA concentration and optical absorption were observed. The higher-volatility products formed in the presence of NOx could precipitate into the particle phase when NH3 was added. The formation pathways of N-containing OAs through NOx or NH3 are also discussed.
Jinlong Ma, Juanyong Shen, Peng Wang, Shengqiang Zhu, Yu Wang, Pengfei Wang, Gehui Wang, Jianmin Chen, and Hongliang Zhang
Atmos. Chem. Phys., 21, 7343–7355, https://doi.org/10.5194/acp-21-7343-2021, https://doi.org/10.5194/acp-21-7343-2021, 2021
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Due to the reduced anthropogenic emissions during the COVID-19 lockdown, mainly from the transportation and industrial sectors, PM2.5 decreased significantly in the whole Yangtze River Delta (YRD) and its major cities. However, the contributions and relative importance of different source sectors and regions changed differently, indicating that control strategies should be adjusted accordingly for further pollution control.
Xiaona Shang, Ling Li, Xinlian Zhang, Huihui Kang, Guodong Sui, Gehui Wang, Xingnan Ye, Hang Xiao, and Jianmin Chen
Atmos. Meas. Tech., 14, 1037–1045, https://doi.org/10.5194/amt-14-1037-2021, https://doi.org/10.5194/amt-14-1037-2021, 2021
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Oxidative stress can be used to evaluate not only adverse health effects but also adverse ecological effects. However, little research uses eco-toxicological assay to assess the risks posed by particle matter to non-human biomes. One important reason might be that the concentration of toxic components of atmospheric particles is far below the high detection limit of eco-toxic measurement. To solve the rapid detection problem, we extended a VACES for ecotoxicity aerosol measurement.
Shengzhen Zhou, Luolin Wu, Junchen Guo, Weihua Chen, Xuemei Wang, Jun Zhao, Yafang Cheng, Zuzhao Huang, Jinpu Zhang, Yele Sun, Pingqing Fu, Shiguo Jia, Jun Tao, Yanning Chen, and Junxia Kuang
Atmos. Chem. Phys., 20, 6435–6453, https://doi.org/10.5194/acp-20-6435-2020, https://doi.org/10.5194/acp-20-6435-2020, 2020
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In this work, measurements of size-segregated aerosols were conducted at three altitudes (ground level, 118 m, and 488 m) on the 610 m high Canton Tower in southern China. Vertical variations of PM and size-segregated chemical compositions were investigated. The results indicated that meteorological parameters and atmospheric aqueous and heterogeneous reactions together led to aerosol formation and haze episodes in the Pearl River Delta region during the measurement periods.
Yuning Xie, Gehui Wang, Xinpei Wang, Jianmin Chen, Yubao Chen, Guiqian Tang, Lili Wang, Shuangshuang Ge, Guoyan Xue, Yuesi Wang, and Jian Gao
Atmos. Chem. Phys., 20, 5019–5033, https://doi.org/10.5194/acp-20-5019-2020, https://doi.org/10.5194/acp-20-5019-2020, 2020
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As a result of strict emission control, nitrate-dominated PM2.5 in pollution episodes was observed in urban Beijing during the winter of 2017–2018. With the help of sufficient ammonia, particle pH could increase to near neutral (5.4) as particulate nitrate fraction increases. Further tests imply that airborne particle hygroscopicity would be enhanced at moderate RH in nitrate-dominated particles, and pH elevation will be accelerated when ammonia and particulate nitrate both increase.
Jianjun Li, Qi Zhang, Gehui Wang, Jin Li, Can Wu, Lang Liu, Jiayuan Wang, Wenqing Jiang, Lijuan Li, Kin Fai Ho, and Junji Cao
Atmos. Chem. Phys., 20, 4889–4904, https://doi.org/10.5194/acp-20-4889-2020, https://doi.org/10.5194/acp-20-4889-2020, 2020
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We examined light absorption properties and molecular composition of water-soluble (WS) and water-insoluble (WI) BrC in PM2.5 collected from northwest China. We found that photochemical formation contributes significantly to light absorption of WI-BrC in summer, whereas aqueous-phase reactions play an important role in secondary WS-BrC formation in winter. BrC was estimated to account for 1.36 % and 3.74 %, respectively, of total down-welling solar radiation in the UV range in summer and winter.
Can Wu, Gehui Wang, Jin Li, Jianjun Li, Cong Cao, Shuangshuang Ge, Yuning Xie, Jianmin Chen, Xingru Li, Guoyan Xue, Xinpei Wang, Zhuyu Zhao, and Fang Cao
Atmos. Chem. Phys., 20, 2017–2030, https://doi.org/10.5194/acp-20-2017-2020, https://doi.org/10.5194/acp-20-2017-2020, 2020
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Brown carbon (BrC), as an important component of aerosol, has attracted wide attention in recent years, yet very limited information on size differences is available. This paper reveals that BrC presented a bimodal pattern and was mainly derived from biomass burning in an interior city of China. Our results are very helpful for readers to comprehensively understand the features of brown carbon in China.
Jianjun Li, Gehui Wang, Qi Zhang, Jin Li, Can Wu, Wenqing Jiang, Tong Zhu, and Limin Zeng
Atmos. Chem. Phys., 19, 10481–10496, https://doi.org/10.5194/acp-19-10481-2019, https://doi.org/10.5194/acp-19-10481-2019, 2019
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In this study, we investigated molecular compositions of organic aerosols (OAs) in summertime PM2.5 at a rural site in the North China Plain. We found that regional emission from field biomass burning (BB) significantly affects the concentration and molecular distribution of aliphatic lipids, sugars, and terpene-derived SOA, but has limited influence on PAHs, hopenes, and phthalates. The contribution of BB to OA increased by more than 50 % during the period influenced by regional open-field BB.
Jun Tao, Zhisheng Zhang, Yunfei Wu, Leiming Zhang, Zhijun Wu, Peng Cheng, Mei Li, Laiguo Chen, Renjian Zhang, and Junji Cao
Atmos. Chem. Phys., 19, 8471–8490, https://doi.org/10.5194/acp-19-8471-2019, https://doi.org/10.5194/acp-19-8471-2019, 2019
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Mass-scattering efficiencies (MSE) of dominant chemical species in atmospheric aerosols are important parameters for building the relationships between chemical species and the particle-scattering coefficient. Particle MSE mainly depends on the mass fractions of (NH4)2SO4, NH4NO3, and organic matter and their MSEs in the droplet mode. MSEs of (NH4)2SO4, NH4NO3 and organic matter were determined by their size distributions in the droplet mode.
Jingjing Meng, Gehui Wang, Zhanfang Hou, Xiaodi Liu, Benjie Wei, Can Wu, Cong Cao, Jiayuan Wang, Jianjun Li, Junji Cao, Erxun Zhang, Jie Dong, Jiazhen Liu, Shuangshuang Ge, and Yuning Xie
Atmos. Chem. Phys., 18, 15069–15086, https://doi.org/10.5194/acp-18-15069-2018, https://doi.org/10.5194/acp-18-15069-2018, 2018
Gehui Wang, Fang Zhang, Jianfei Peng, Lian Duan, Yuemeng Ji, Wilmarie Marrero-Ortiz, Jiayuan Wang, Jianjun Li, Can Wu, Cong Cao, Yuan Wang, Jun Zheng, Jeremiah Secrest, Yixin Li, Yuying Wang, Hong Li, Na Li, and Renyi Zhang
Atmos. Chem. Phys., 18, 10123–10132, https://doi.org/10.5194/acp-18-10123-2018, https://doi.org/10.5194/acp-18-10123-2018, 2018
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Several studies using thermodynamic models estimated pH and sulfate formation rate during pollution periods in China are highly conflicting. Here we show distinct sulfate formation for organic seed particles from that of (NH4)2SO4 seeds, when the particles are exposed to SO2, NO2, and NH3 at high RH. Our results reveal that the pH value of ambient organics-dominated aerosols is sufficiently high to promote efficient SO2 oxidation by NO2 with NH3 neutralization under polluted conditions in China.
Zirui Liu, Wenkang Gao, Yangchun Yu, Bo Hu, Jinyuan Xin, Yang Sun, Lili Wang, Gehui Wang, Xinhui Bi, Guohua Zhang, Honghui Xu, Zhiyuan Cong, Jun He, Jingsha Xu, and Yuesi Wang
Atmos. Chem. Phys., 18, 8849–8871, https://doi.org/10.5194/acp-18-8849-2018, https://doi.org/10.5194/acp-18-8849-2018, 2018
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We have established a national-level network (CARE-China) that conducted continuous monitoring of PM2.5 and its chemical compositions in China. Our analysis reveals the spatial and seasonal variabilities of the urban and background aerosol species and their contributions to the PM2.5 budget. The integration of data provided an extensive spatial coverage of fine-particle concentrations and could be used to validate model results and implement effective air pollution control strategies.
Jun Tao, Leiming Zhang, Junji Cao, and Renjian Zhang
Atmos. Chem. Phys., 17, 9485–9518, https://doi.org/10.5194/acp-17-9485-2017, https://doi.org/10.5194/acp-17-9485-2017, 2017
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In this study, studies on PM2.5 chemical composition, source apportionment and its impact on aerosol optical properties across China are thoroughly reviewed, and historical emission control policies in China and their effectiveness in reducing PM2.5 are discussed.
Yunfei Wu, Xiaojia Wang, Jun Tao, Rujin Huang, Ping Tian, Junji Cao, Leiming Zhang, Kin-Fai Ho, Zhiwei Han, and Renjian Zhang
Atmos. Chem. Phys., 17, 7965–7975, https://doi.org/10.5194/acp-17-7965-2017, https://doi.org/10.5194/acp-17-7965-2017, 2017
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As black carbon (BC) aerosols play an important role in the climate and environment, the size distribution of refractory BC (rBC) was investigated. On this basis, the source of rBC was further analyzed. The local traffic exhausts contributed greatly to the rBC in urban areas. However, its contribution decreased significantly in the polluted period compared to the clean period, implying the increasing contribution of other sources, e.g., coal combustion or biomass burning, in the polluted period.
Jiayuan Wang, Gehui Wang, Jian Gao, Han Wang, Yanqin Ren, Jianjun Li, Bianhong Zhou, Can Wu, Lu Zhang, Shulan Wang, and Fahe Chai
Atmos. Chem. Phys., 17, 981–992, https://doi.org/10.5194/acp-17-981-2017, https://doi.org/10.5194/acp-17-981-2017, 2017
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We compared the differences in concentrations of oxalic acid and related SOA and the stable carbon isotopic compositions of oxalic acid Beijing before, during and after the APEC 2014 conference, to investigate the impact of pollutant emission controls on the origins and formation mechanisms of PM2.5. Our results indicate that the significant reduction in PM2.5 during APEC is firstly due to the emission control and secondly attributed to the relatively colder and drier conditions.
Tian Feng, Guohui Li, Junji Cao, Naifang Bei, Zhenxing Shen, Weijian Zhou, Suixin Liu, Ting Zhang, Yichen Wang, Ru-jin Huang, Xuexi Tie, and Luisa T. Molina
Atmos. Chem. Phys., 16, 10045–10061, https://doi.org/10.5194/acp-16-10045-2016, https://doi.org/10.5194/acp-16-10045-2016, 2016
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The springtime organic aerosol (OA) concentrations in the Guanzhong Basin, China are simulated using the WRF-Chem model with two secondary OA (SOA) modules. Model results are verified with near-surface observations. The non-traditional SOA module significantly improves SOA simulation. Oxidation and partitioning of primary OAs is the most important pathway in SOA formation. Residential emissions are the dominant anthropogenic OA source.
Xin Long, Xuexi Tie, Junji Cao, Rujin Huang, Tian Feng, Nan Li, Suyu Zhao, Jie Tian, Guohui Li, and Qiang Zhang
Atmos. Chem. Phys., 16, 9675–9691, https://doi.org/10.5194/acp-16-9675-2016, https://doi.org/10.5194/acp-16-9675-2016, 2016
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We studied the impact of crop field burning (CFB) on air pollution in North China Plain (NCP) using MODIS observations and the numerical model WRF-CHEM. The CFB plume emitted in southern NCP and went through a long-range transport to northern NCP. The long-range transport and the effect of mountains obviously enhanced the PM2.5 pollution in northern NCP. The prohibition of CFB should be strict not just in or around Beijing, but also on the ulterior crop growth areas of southern NCP.
Chunpeng Leng, Junyan Duan, Chen Xu, Hefeng Zhang, Yifan Wang, Yanyu Wang, Xiang Li, Lingdong Kong, Jun Tao, Renjian Zhang, Tiantao Cheng, Shuping Zha, and Xingna Yu
Atmos. Chem. Phys., 16, 9221–9234, https://doi.org/10.5194/acp-16-9221-2016, https://doi.org/10.5194/acp-16-9221-2016, 2016
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Meteorological conditions, local anthropogenic emissions and aerosol properties played major roles in this historic winter haze weather formation. Aerosols the size of 600–1400 nm are mostly responsible for the impairment of atmospheric visibility. This study was performed by combining many on-line measurement techniques which were calibrated regularly to ensure reliability, and can act as a reference for forecasting and eliminating the occurrences of regional atmospheric pollutions in China.
Naifang Bei, Guohui Li, Ru-Jin Huang, Junji Cao, Ning Meng, Tian Feng, Suixin Liu, Ting Zhang, Qiang Zhang, and Luisa T. Molina
Atmos. Chem. Phys., 16, 7373–7387, https://doi.org/10.5194/acp-16-7373-2016, https://doi.org/10.5194/acp-16-7373-2016, 2016
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Rapid industrialization and urbanization have caused severe air pollution in the Guanzhong basin, northwestern China with heavy haze events occurring frequently in recent winters. Due to frequent occurrence of unfavorable synoptic situations during wintertime, mitigation of emissions is the optimum approach to mitigate the air pollution in the Guanzhong basin.
Tian Feng, Naifang Bei, Ru-Jin Huang, Junji Cao, Qiang Zhang, Weijian Zhou, Xuexi Tie, Suixin Liu, Ting Zhang, Xiaoli Su, Wenfang Lei, Luisa T. Molina, and Guohui Li
Atmos. Chem. Phys., 16, 4323–4342, https://doi.org/10.5194/acp-16-4323-2016, https://doi.org/10.5194/acp-16-4323-2016, 2016
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The occurrence of high O3 levels with high PM2.5 concentrations constitutes a dilemma for the design of O3 control strategies in Xi’an and surrounding areas. If the O3 mitigation approach decreases aerosols in the atmosphere directly or indirectly, the enhanced photolysis caused by aerosol reduction would compensate for the O3 loss. If only the PM2.5 control strategy is implemented, the O3 pollution will decrease.
N. Li, T.-M. Fu, J. J. Cao, J. Y. Zheng, Q. Y. He, X. Long, Z. Z. Zhao, N. Y. Cao, J. S. Fu, and Y. F. Lam
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-33583-2015, https://doi.org/10.5194/acpd-15-33583-2015, 2015
Revised manuscript not accepted
M. Wang, B. Xu, J. Cao, X. Tie, H. Wang, R. Zhang, Y. Qian, P. J. Rasch, S. Zhao, G. Wu, H. Zhao, D. R. Joswiak, J. Li, and Y. Xie
Atmos. Chem. Phys., 15, 1191–1204, https://doi.org/10.5194/acp-15-1191-2015, https://doi.org/10.5194/acp-15-1191-2015, 2015
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Carbonaceous aerosols recorded in a Tibetan glacier present a distinct seasonal dependence and an increasing trend after 1980, which has important implications for the accelerated glacier melting. We use a global aerosol--climate model to quantify the aerosol source--receptor relationships, showing that emissions in South Asia had the largest contribution. The emission inventories and historical fuel consumption in South Asia are consistent with our ice-core analysis and model results.
J. Tao, J. Gao, L. Zhang, R. Zhang, H. Che, Z. Zhang, Z. Lin, J. Jing, J. Cao, and S.-C. Hsu
Atmos. Chem. Phys., 14, 8679–8699, https://doi.org/10.5194/acp-14-8679-2014, https://doi.org/10.5194/acp-14-8679-2014, 2014
Z. J. Lin, Z. S. Zhang, L. Zhang, J. Tao, R. J. Zhang, J. J. Cao, S. J. Fan, and Y. H. Zhang
Atmos. Chem. Phys., 14, 7631–7644, https://doi.org/10.5194/acp-14-7631-2014, https://doi.org/10.5194/acp-14-7631-2014, 2014
R.-J. Huang, W.-B. Li, Y.-R. Wang, Q. Y. Wang, W. T. Jia, K.-F. Ho, J. J. Cao, G. H. Wang, X. Chen, I. EI Haddad, Z. X. Zhuang, X. R. Wang, A. S. H. Prévôt, C. D. O'Dowd, and T. Hoffmann
Atmos. Meas. Tech., 7, 2027–2035, https://doi.org/10.5194/amt-7-2027-2014, https://doi.org/10.5194/amt-7-2027-2014, 2014
J. J. Li, G. H. Wang, J. J. Cao, X. M. Wang, and R. J. Zhang
Atmos. Chem. Phys., 13, 11535–11549, https://doi.org/10.5194/acp-13-11535-2013, https://doi.org/10.5194/acp-13-11535-2013, 2013
Y. Kanaya, H. Akimoto, Z.-F. Wang, P. Pochanart, K. Kawamura, Y. Liu, J. Li, Y. Komazaki, H. Irie, X.-L. Pan, F. Taketani, K. Yamaji, H. Tanimoto, S. Inomata, S. Kato, J. Suthawaree, K. Okuzawa, G. Wang, S. G. Aggarwal, P. Q. Fu, T. Wang, J. Gao, Y. Wang, and G. Zhuang
Atmos. Chem. Phys., 13, 8265–8283, https://doi.org/10.5194/acp-13-8265-2013, https://doi.org/10.5194/acp-13-8265-2013, 2013
R. Zhang, J. Jing, J. Tao, S.-C. Hsu, G. Wang, J. Cao, C. S. L. Lee, L. Zhu, Z. Chen, Y. Zhao, and Z. Shen
Atmos. Chem. Phys., 13, 7053–7074, https://doi.org/10.5194/acp-13-7053-2013, https://doi.org/10.5194/acp-13-7053-2013, 2013
L. Xing, T.-M. Fu, J. J. Cao, S. C. Lee, G. H. Wang, K. F. Ho, M.-C. Cheng, C.-F. You, and T. J. Wang
Atmos. Chem. Phys., 13, 4307–4318, https://doi.org/10.5194/acp-13-4307-2013, https://doi.org/10.5194/acp-13-4307-2013, 2013
Z. J. Lin, J. Tao, F. H. Chai, S. J. Fan, J. H. Yue, L. H. Zhu, K. F. Ho, and R. J. Zhang
Atmos. Chem. Phys., 13, 1115–1128, https://doi.org/10.5194/acp-13-1115-2013, https://doi.org/10.5194/acp-13-1115-2013, 2013
G. H. Wang, B. H. Zhou, C. L. Cheng, J. J. Cao, J. J. Li, J. J. Meng, J. Tao, R. J. Zhang, and P. Q. Fu
Atmos. Chem. Phys., 13, 819–835, https://doi.org/10.5194/acp-13-819-2013, https://doi.org/10.5194/acp-13-819-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement report: Molecular composition, sources, and evolution of atmospheric organic aerosols in a basin city in China
Characterizing lead-rich particles in Beijing's atmosphere following coal-to-gas conversion: insights from single-particle aerosol mass spectrometry
Climatology of aerosol pH and its controlling factors at the Melpitz continental background site in Central Europe
Technical note: Towards a stronger observational support for haze pollution control by interpreting carbonaceous aerosol results derived from different measurement approaches
Particle flux–gradient relationships in the high Arctic: emission and deposition patterns across three surface types
Advances in characterization of black carbon particles and their associated coatings using the soot-particle aerosol mass spectrometer in Singapore, a complex city environment
Iron isotopes suggest significant aerosol dissolution over the Pacific Ocean
Enrichment of organic nitrogen in fog residuals observed in the Italian Po Valley
Asian dust transport of proteinaceous matter from the Gobi Desert to northern China
Machine-learning-assisted chemical characterization and optical properties of atmospheric brown carbon in Nanjing, China
Technical note: Reconstructing missing surface aerosol elemental carbon data in long-term series with ensemble learning
Enhanced emission of intermediate-volatility/semi-volatile organic matter in gas and particle phases from ship exhausts with low-sulfur fuels
Measurement report: Crustal materials play an increasing role in elevating particle pH – insights from 12-year records in a typical inland city of China
Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations
Measurement report: In-depth characterization of ship emissions during operations in a Mediterranean port
Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations
Measurement report: Per- and polyfluoroalkyl substances (PFAS) in particulate matter (PM10) from activated sludge aeration
African dust transported to Barbados in the wintertime lacks indicators of chemical aging
A 60-year atmospheric nitrate isotope record from a southeastern Greenland ice core with minimal postdepositional alteration
Measurement report: Characterization of aerosol hygroscopicity over Southeast Asia during the NASA CAMP2Ex campaign
Long–term Trends in PM2.5 Chemical Composition and Its Impact on Aerosol Properties: Field Observations from 2007 to 2020 in Pearl River Delta, South China
Atmospheric Organosulfate Formation Regulated by Continental Outflows and Marine Emissions over East Asian Marginal Seas
Individual particle compositions and aerosol mixing states at different altitudes over the ocean in East Asia
Molecular characterization of organic aerosols in urban and forested areas of Paris using high-resolution mass spectrometry
Measurement report: Wintertime aerosol characterization at an urban traffic site in Helsinki, Finland
Source apportionment and ecotoxicity of PM2.5 pollution events in a major Southern Hemisphere megacity: influence of a biofuel-impacted fleet and biomass burning
The impacts of pollution sources and temperature on the light absorption of HULIS were revealed by UHPLC-HRMS/MS at the molecular structure level
Effects of Anthropogenic Pollutants on Biogenic Secondary Organic Aerosol Formation in the Atmosphere of Mt. Hua, China
Marine organic aerosol at Mace Head: effects from phytoplankton and source region variability
Elemental composition, iron mineralogy and solubility of anthropogenic and natural mineral dust aerosols in Namibia: a case study analysis from the AEROCLO-sA campaign
Fossil-Dominated SOA Formation in Coastal China: Size-Divergent Pathways of Aqueous Fenton Reactions versus Gas-phase VOC Autoxidation
Measurement report: Sources and meteorology influencing highly time-resolved PM2.5 trace elements at three urban sites in the extremely polluted Indo-Gangetic Plain in India
Measurement report: Year-long chemical composition, optical properties, and sources of atmospheric aerosols in the northeastern Tibetan Plateau
Formation of highly absorptive secondary brown carbon through nighttime multiphase chemistry of biomass burning emissions
Hydroxymethanesulfonate (HMS) Formation under Urban and Marine Atmosphere: role of aerosol ionic strength
The sources and diurnal variations of submicron aerosols in a coastal-rural environment near Houston, US
Measurement report: Vertically resolved atmospheric properties observed over the Southern Great Plains with the ArcticShark uncrewed aerial system
Measurement report: Simultaneous measurement on atmospheric gas- and aerosol-phase water-soluble organics in Shanghai: Remarkable increase in light absorbing of Asian dust aerosols during long-range transport
Unraveling Arctic submicron organic aerosol sources: a year-long study by H-NMR and AMS in Ny-Ålesund, Svalbard
Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China
Unveiling single-particle composition, size, shape, and mixing state of freshly emitted Icelandic dust via electron microscopy analysis
The Critical Role of Volatile Organic Compounds Emission in Nitrate Formation in Lhasa, Tibetan Plateau: Insights from Oxygen Isotope Anomaly Measurements
The critical role of aqueous-phase processes in aromatic-derived nitrogen-containing organic aerosol formation in cities with different energy consumption patterns
Characterization of atmospheric water-soluble brown carbon in the Athabasca oil sands region, Canada
Sensitivity of aerosol and cloud properties to coupling strength of marine boundary layer clouds over the northwest Atlantic
Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer
Observations of high-time-resolution and size-resolved aerosol chemical composition and microphysics in the central Arctic: implications for climate-relevant particle properties
A critical review of the use of iron isotopes in atmospheric aerosol research
Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations
Atmospheric chemistry in East Asia determines the iron solubility of aerosol particles supplied to the North Pacific Ocean
Junke Zhang, Xinyi Fu, Chunying Chen, Yunfei Su, Siyu Liu, Luyao Chen, Yubao Chen, Gehui Wang, and Andre S. H. Prevot
Atmos. Chem. Phys., 25, 8983–9004, https://doi.org/10.5194/acp-25-8983-2025, https://doi.org/10.5194/acp-25-8983-2025, 2025
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We measured (at the molecular level) the 125 organic aerosol (OA) compounds present in Chengdu in winter. OA was dominated by fatty acids, phthalate esters, and anhydrosugars, and it was deeply influenced by anthropogenic sources. As pollution worsened, secondary inorganic species and secondary organic carbon (OC) dominated the increase in PM2.5, fatty acids and anhydrosugars dominated the increase in OA, and the contributions of secondary formation and biomass burning to OC increased markedly.
Xiufeng Lian, Yongjiang Xu, Fengxian Liu, Long Peng, Xiaodong Hu, Guigang Tang, Xu Dao, Hui Guo, Liwei Wang, Bo Huang, Chunlei Cheng, Lei Li, Guohua Zhang, Xinhui Bi, Xiaofei Wang, Zhen Zhou, and Mei Li
Atmos. Chem. Phys., 25, 8891–8905, https://doi.org/10.5194/acp-25-8891-2025, https://doi.org/10.5194/acp-25-8891-2025, 2025
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In this study, we analyzed the mixing state and atmospheric chemical processes of Pb-rich single particles in Beijing. We focused on analyzing the differences in Pb-rich particles between the heating period and non-heating period, as well as the formation mechanism of lead nitrate after coal-to-gas conversion. Our results highlighted the improvement of Pb levels in the particulate as a result of coal-to-gas conversion.
Vikram Pratap, Christopher J. Hennigan, Bastian Stieger, Andreas Tilgner, Laurent Poulain, Dominik van Pinxteren, Gerald Spindler, and Hartmut Herrmann
Atmos. Chem. Phys., 25, 8871–8889, https://doi.org/10.5194/acp-25-8871-2025, https://doi.org/10.5194/acp-25-8871-2025, 2025
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In this work, we characterize trends in aerosol pH and its controlling factors during the period 2010–2019 at the Melpitz research station in eastern Germany. We find strong trends in aerosol pH and major inorganic species in response to changing emissions. We conduct a detailed thermodynamic analysis of the aerosol system and discuss implications for controlling particulate matter in the region.
Yuan Cheng, Ying-jie Zhong, Zhi-qing Zhang, Xu-bing Cao, and Jiu-meng Liu
Atmos. Chem. Phys., 25, 8493–8505, https://doi.org/10.5194/acp-25-8493-2025, https://doi.org/10.5194/acp-25-8493-2025, 2025
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As an emerging hotspot of atmospheric sciences, northeastern China is distinct due to the frigid winter and the strong emissions from agricultural fires. Based on field campaigns conducted in Harbin, we successively identified the analytical method that could lead to proper results of organic and elemental carbon. Our results are believed to be a support for future efforts in the exploration of PM2.5 sources in northeastern China, which are essential for further improving the regional air quality.
Theresa Mathes, Heather Guy, John Prytherch, Julia Kojoj, Ian Brooks, Sonja Murto, Paul Zieger, Birgit Wehner, Michael Tjernström, and Andreas Held
Atmos. Chem. Phys., 25, 8455–8474, https://doi.org/10.5194/acp-25-8455-2025, https://doi.org/10.5194/acp-25-8455-2025, 2025
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The Arctic is warming faster than the global average and an investigation of aerosol–cloud–sea ice interactions is crucial for studying its climate system. During the ARTofMELT Expedition 2023, particle and sensible heat fluxes were measured over different surfaces. Wide lead surfaces acted as particle sources, with the strongest sensible heat fluxes, while closed ice surfaces acted as particle sinks. In this study, methods to measure these interactions are improved, enhancing our understanding of Arctic climate processes.
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
Atmos. Chem. Phys., 25, 8185–8211, https://doi.org/10.5194/acp-25-8185-2025, https://doi.org/10.5194/acp-25-8185-2025, 2025
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This work advances our understanding of the emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Capucine Camin, François Lacan, Catherine Pradoux, Marie Labatut, Anne Johansen, and James W. Murray
Atmos. Chem. Phys., 25, 8213–8228, https://doi.org/10.5194/acp-25-8213-2025, https://doi.org/10.5194/acp-25-8213-2025, 2025
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This paper presents the chemical and iron isotopic composition of aerosols (> 1 µm) over the equatorial and tropical Pacific Ocean in previously undocumented areas. Analysis of our data suggests that a significant proportion of aerosol iron (∼ 13 %) is not only dissolved but also removed during atmospheric transport. Such removal had not previously been evidenced to our knowledge. This highlights the unique and strong constraints brought by iron isotopes on atmospheric process studies.
Fredrik Mattsson, Almuth Neuberger, Liine Heikkinen, Yvette Gramlich, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Paul Zieger, Ilona Riipinen, and Claudia Mohr
Atmos. Chem. Phys., 25, 7973–7989, https://doi.org/10.5194/acp-25-7973-2025, https://doi.org/10.5194/acp-25-7973-2025, 2025
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This study investigated aerosol–cloud interactions, focusing on organic nitrogen (ON) formation in the aqueous phase. Measurements were conducted in wintertime in the Po Valley, Italy, using aerosol mass spectrometry. The fog was enriched in more hygroscopic inorganic compounds and ON, containing, e.g., imidazoles. The formation of imidazole by aerosol–fog interactions could be confirmed for the first time in atmospheric observations. Findings highlight the role of fog in nitrogen aerosol formation.
Ren-Guo Zhu, Hua-Yun Xiao, Meiju Yin, Hao Xiao, Zhongkui Zhou, Yuanyuan Pan, Guo Wei, and Cheng Liu
Atmos. Chem. Phys., 25, 7699–7718, https://doi.org/10.5194/acp-25-7699-2025, https://doi.org/10.5194/acp-25-7699-2025, 2025
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The concentrations and δ15N isotopic values of CAAs (combined amino acids) in surface soil and plants from the Gobi Desert, as well as in PM2.5 samples from four cities in Northern China, were measured. CAAs transported by Gobi dust were rich in alanine, glycine and glutamic acid. Glycine and leucine in Gobi Desert sources exhibited δ15N depletion by more than 6 ‰ compared to their values in urban PM2.5. Substantial protein-N deposition can be transported by the Gobi Desert to northern China over brief periods.
Yu Huang, Xingru Li, Dan Dan Huang, Ruoyuan Lei, Binhuang Zhou, Yunjiang Zhang, and Xinlei Ge
Atmos. Chem. Phys., 25, 7619–7645, https://doi.org/10.5194/acp-25-7619-2025, https://doi.org/10.5194/acp-25-7619-2025, 2025
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This work comprises a comprehensive investigation into the chemical and optical properties of brown carbon (BrC) in PM2.5 samples collected in Nanjing, China. In particular, we used a machine learning approach to identify a list of key BrC species, which can be a good reference for future studies. Our findings extend understanding of BrC properties and are valuable to the assessment of BrC's impact on air quality and radiative forcing.
Qingxiao Meng, Yunjiang Zhang, Sheng Zhong, Jie Fang, Lili Tang, Yongcai Rao, Minfeng Zhou, Jian Qiu, Xiaofeng Xu, Jean-Eudes Petit, Olivier Favez, and Xinlei Ge
Atmos. Chem. Phys., 25, 7485–7498, https://doi.org/10.5194/acp-25-7485-2025, https://doi.org/10.5194/acp-25-7485-2025, 2025
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We developed a machine-learning-based method to reconstruct missing elemental carbon (EC) data in four Chinese cities from 2013 to 2023. Using machine learning, we filled data gaps and introduced a new approach to analyze EC trends. Our findings reveal a significant decline in EC due to stricter pollution controls, though this slowed after 2020. This study provides a versatile framework for addressing data gaps and supports strategies to reduce urban air pollution and its climate impacts.
Binyu Xiao, Fan Zhang, Zeyu Liu, Yan Zhang, Rui Li, Can Wu, Xinyi Wan, Yi Wang, Yubao Chen, Yong Han, Min Cui, Libo Zhang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 25, 7053–7069, https://doi.org/10.5194/acp-25-7053-2025, https://doi.org/10.5194/acp-25-7053-2025, 2025
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Intermediate-volatility/semi-volatile organic compounds in gas and particle phases from ship exhausts are enhanced due to the switch of fuels from low sulfur to ultra-low sulfur. The findings indicate that optimization is necessary for the forthcoming global implementation of an ultra-low-sulfur oil policy. Besides, we find that organic diagnostic markers of hopanes in conjunction with the ratio of octadecanoic to tetradecanoic could be considered potential tracers for heavy fuel oil exhausts.
Hongyu Zhang, Shenbo Wang, Zhangsen Dong, Xiao Li, and Ruiqin Zhang
Atmos. Chem. Phys., 25, 6943–6955, https://doi.org/10.5194/acp-25-6943-2025, https://doi.org/10.5194/acp-25-6943-2025, 2025
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Analyzing 12-year Zhengzhou data revealed post-2019 crustal material rebound caused by soil dust resuspension, elevating particle pH. Similar coarse particle increases are observed across cities of the North China Plain. Long-term particle acidity evolution in this region requires an integrated assessment of interactions among acidic precursors, ammonia, and crustal components.
Yanqin Ren, Zhenhai Wu, Fang Bi, Hong Li, Haijie Zhang, Junling Li, Rui Gao, Fangyun Long, Zhengyang Liu, Yuanyuan Ji, and Gehui Wang
Atmos. Chem. Phys., 25, 6975–6990, https://doi.org/10.5194/acp-25-6975-2025, https://doi.org/10.5194/acp-25-6975-2025, 2025
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The daily concentrations of Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs), and nitrated phenols (NPs) in PM2.5 were all increased during the heating season. Biomass burning was identified to be the primary source of these aromatic compounds, particularly for PAHs. Phenol and nitrobenzene are two main primary precursors for 4NP, with phenol showing lower reaction barriers. P-Cresol was identified as the primary precursor for the formation of 4-methyl-5-nitrocatechol.
Lise Le Berre, Brice Temime-Roussel, Grazia Maria Lanzafame, Barbara D'Anna, Nicolas Marchand, Stéphane Sauvage, Marvin Dufresne, Liselotte Tinel, Thierry Leonardis, Joel Ferreira de Brito, Alexandre Armengaud, Grégory Gille, Ludovic Lanzi, Romain Bourjot, and Henri Wortham
Atmos. Chem. Phys., 25, 6575–6605, https://doi.org/10.5194/acp-25-6575-2025, https://doi.org/10.5194/acp-25-6575-2025, 2025
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A summer campaign in a Mediterranean port examined pollution caused by ships. Two stations in the port measured pollution levels and captured over 350 ship plumes to study their chemical composition. Results showed that pollution levels, such as ultra-fine particles, were higher in the port than in the city and offer strong support to improve emission inventories. These findings may also serve as reference to assess the benefits of a sulfur Emission Control Area in the Mediterranean in 2025.
Jiayin Li, Tianyu Zhai, Xiaorui Chen, Haichao Wang, Shuyang Xie, Shiyi Chen, Chunmeng Li, Yuanjun Gong, Huabin Dong, and Keding Lu
Atmos. Chem. Phys., 25, 6395–6406, https://doi.org/10.5194/acp-25-6395-2025, https://doi.org/10.5194/acp-25-6395-2025, 2025
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We directly measured the dinitrogen pentoxide (N2O5) uptake coefficient using an aerosol flow tube, which critically impacts the NOx fate and particulate nitrate formation in a typical highland city, Kunming, in China. We found that the performance of current γ (N2O5) parameterizations showed deviations with the varying aerosol liquid water content (ALWC). Such differences would lead to biased estimation of particulate nitrate production potential. We give suggestions for future research directions.
Jishnu Pandamkulangara Kizhakkethil, Zongbo Shi, Anna Bogush, and Ivan Kourtchev
Atmos. Chem. Phys., 25, 5947–5958, https://doi.org/10.5194/acp-25-5947-2025, https://doi.org/10.5194/acp-25-5947-2025, 2025
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Pollution with per- and polyfluoroalkyl substances (PFAS) has received attention due to their environmental persistence and bioaccumulation, but their sources remain poorly understood. PM10 (particulate matter) collected above a scaled-down activated sludge tank treating domestic sewage in the UK was analysed for a range of short-, medium-, and long-chain PFAS. Eight PFAS were detected in the PM10. Our results suggest that wastewater treatment processes, i.e. activated sludge aeration, could aerosolise PFAS into airborne PM.
Haley M. Royer, Michael T. Sheridan, Hope E. Elliott, Edmund Blades, Nurun Nahar Lata, Zezhen Cheng, Swarup China, Zihua Zhu, Andrew P. Ault, and Cassandra J. Gaston
Atmos. Chem. Phys., 25, 5743–5759, https://doi.org/10.5194/acp-25-5743-2025, https://doi.org/10.5194/acp-25-5743-2025, 2025
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Saharan dust transported across the Atlantic to the Caribbean, South America, and North America is hypothesized to undergo chemical processing by acids that enhances cloud droplet formation and nutrient availability. In this study, chemical analysis performed on African dust deposited over Barbados shows that acid tracers are found mostly on sea salt and smoke particles, rather than dust, indicating that dust particles undergo minimal chemical processing.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
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Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Genevieve Rose Lorenzo, Luke D. Ziemba, Avelino F. Arellano, Mary C. Barth, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Richard Ferrare, Miguel Ricardo A. Hilario, Michael A. Shook, Simone Tilmes, Jian Wang, Qian Xiao, Jun Zhang, and Armin Sorooshian
Atmos. Chem. Phys., 25, 5469–5495, https://doi.org/10.5194/acp-25-5469-2025, https://doi.org/10.5194/acp-25-5469-2025, 2025
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Novel aerosol hygroscopicity analyses of CAMP2Ex (Cloud, Aerosol, and Monsoon Processes Philippines Experiment) field campaign data show low aerosol hygroscopicity values in Southeast Asia. Organic carbon from smoke decreases hygroscopicity to levels more like those in continental than in polluted marine regions. Hygroscopicity changes at cloud level demonstrate how surface particles impact clouds in the region, affecting model representation of aerosol and cloud interactions in similar polluted marine regions with high organic carbon emissions.
Yunfeng He, Xiang Ding, Quanfu He, Yuqing Zhang, Duohong Chen, Tao Zhang, Kong Yang, Junqi Wang, Qian Cheng, Hao Jiang, Zirui Wang, Ping Liu, Xinming Wang, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2025-2204, https://doi.org/10.5194/egusphere-2025-2204, 2025
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The long-term field measurements in the Pearl River Delta revealed a significant decline in PM2.5 main components. As air quality improved, secondary species became more dominant. In addition, the proportion of nitrate had doubled. The changes in chemical composition led to the reductions in aerosol acidity, liquid water content and light extinction coefficient. Our results help to improve understanding of the secondary species formation under decreasing anthropogenic emissions.
Shubin Li, Yujue Wang, Yiwen Zhang, Yizhe Yi, Yuchen Wang, Yuqi Guo, Chao Yu, Yue Jiang, Jinhui Shi, Chao Zhang, Jialei Zhu, Wei Hu, Jianzhen Yu, Xiaohong Yao, Huiwang Gao, and Min Hu
EGUsphere, https://doi.org/10.5194/egusphere-2025-2154, https://doi.org/10.5194/egusphere-2025-2154, 2025
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Organosulfates (OSs) are an unrecognized and potentially important component in marine organic aerosols. In this study, we quantified and characterized the OSs over East Asian marginal seas. The chemical nature and spatiotemporal distribution of OSs were modified by the joint influence of marine emissions and transported terrestrial pollutants. The results highlight the vital roles of OSs in shaping organic aerosol formation and sulfur cycle during summer in marine boundary layer.
Kouji Adachi, Atsushi Yoshida, Tatsuhiro Mori, Nobuhiro Moteki, Sho Ohata, Kazuyuki Kita, Yoshimi Kawai, and Makoto Koike
EGUsphere, https://doi.org/10.5194/egusphere-2025-2230, https://doi.org/10.5194/egusphere-2025-2230, 2025
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This study measured the compositions and mixing states of individual aerosol particles collected at different altitudes over the western North Pacific by simultaneous sampling from an aircraft and a research vessel. The results showed that they were strongly influenced by Siberian Forest biomass burning and mixed with sea spray, and identified various aerosol compositions at different altitudes, sizes, and aerosol sources, highlighting a wide range of individual particle compositions.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 25, 4885–4905, https://doi.org/10.5194/acp-25-4885-2025, https://doi.org/10.5194/acp-25-4885-2025, 2025
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In order to study aerosols in environments influenced by anthropogenic and biogenic emissions, we performed analyses of samples collected during the ACROSS (Atmospheric Chemistry Of the Suburban Forest) campaign in summer 2022 in the greater Paris area. After analysis of the chemical composition by means of total carbon determination and high-resolution mass spectrometry, this work highlights the influence of anthropogenic inputs on the chemical composition of both urban and forested areas.
Kimmo Teinilä, Sanna Saarikoski, Henna Lintusaari, Teemu Lepistö, Petteri Marjanen, Minna Aurela, Heidi Hellén, Toni Tykkä, Markus Lampimäki, Janne Lampilahti, Luis Barreira, Timo Mäkelä, Leena Kangas, Juha Hatakka, Sami Harni, Joel Kuula, Jarkko V. Niemi, Harri Portin, Jaakko Yli-Ojanperä, Ville Niemelä, Milja Jäppi, Katrianne Lehtipalo, Joonas Vanhanen, Liisa Pirjola, Hanna E. Manninen, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 25, 4907–4928, https://doi.org/10.5194/acp-25-4907-2025, https://doi.org/10.5194/acp-25-4907-2025, 2025
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Physical and chemical properties of particulate matter and concentrations of trace gases were measured in a street canyon in Helsinki, Finland, and an urban background site in January–February 2022 to investigate the effect of wintertime conditions on pollutants. State-of-the-art instruments and a mobile laboratory were used, and the measurement data were analysed further with modelling tools like positive matrix factorization and the Pollution Detection Algorithm.
Guilherme Martins Pereira, Leonardo Yoshiaki Kamigauti, Rubens Fabio Pereira, Djacinto Monteiro dos Santos, Thayná da Silva Santos, José Vinicius Martins, Célia Alves, Cátia Gonçalves, Ismael Casotti Rienda, Nora Kováts, Thiago Nogueira, Luciana Rizzo, Paulo Artaxo, Regina Maura de Miranda, Marcia Akemi Yamasoe, Edmilson Dias de Freitas, Pérola de Castro Vasconcellos, and Maria de Fatima Andrade
Atmos. Chem. Phys., 25, 4587–4616, https://doi.org/10.5194/acp-25-4587-2025, https://doi.org/10.5194/acp-25-4587-2025, 2025
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The chemical composition of fine particulate matter was studied in the megacity of São Paulo (Brazil) during a polluted period. Vehicular-related sources remain relevant; however, a high contribution of biomass burning was observed and correlated with sample ecotoxicity. Emerging biomass burning sources, such as forest fires and sugarcane-bagasse-based power plants, highlight the need for additional control measures alongside stricter rules concerning vehicular emissions.
Tao Qiu, Yanting Qiu, Yongyi Yuan, Rui Su, Xiangxinyue Meng, Jialiang Ma, Xiaofan Wang, Yu Gu, Zhijun Wu, Yang Ning, Xiuyi Hua, Dapeng Liang, and Deming Dong
EGUsphere, https://doi.org/10.5194/egusphere-2025-1808, https://doi.org/10.5194/egusphere-2025-1808, 2025
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Our research reveals that some species from biomass burning and coal combustion dominate the light absorption of organic aerosols during winter. Cold weather helps these species accumulate in aerosols by slowing their degradation and altering atmospheric chemical processes. This means colder regions might experience stronger and more persistent climate impacts. Our findings highlight the importance of local temperatures and pollution sources when tackling climate challenges.
Can Wu, Yubao Chen, Yuwei Sun, Huijun Zhang, Si Zhang, Cong Cao, Jianjun Li, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1668, https://doi.org/10.5194/egusphere-2025-1668, 2025
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Biogenic secondary organic aerosol (BSOA), as an important atmospheric component, is prevalent within the boundary layer and can influence air quality and human health. Our observations demonstrate that anthropogenic NOx and the enhanced aerosol water driven by sulfate inhibit BSOA formation in lifting air masses, leading to a moderate reduction in the SOA burden in the upper boundary layer.
Emmanuel Chevassus, Kirsten N. Fossum, Darius Ceburnis, Lu Lei, Chunshui Lin, Wei Xu, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 25, 4107–4129, https://doi.org/10.5194/acp-25-4107-2025, https://doi.org/10.5194/acp-25-4107-2025, 2025
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This study presents the first source apportionment of organic aerosol at Mace Head via high-resolution mass spectrometry. Introducing transfer entropy as a novel method reveals that aged organic aerosol originates from both open-ocean ozonolysis and local peat-burning oxidation. Methanesulfonic acid and organic sea spray both mirror phytoplankton activity, with the former closely tied to coccolithophore blooms and the latter linked to diatoms, chlorophytes, and cyanobacteria.
Paola Formenti, Chiara Giorio, Karine Desboeufs, Alexander Zherebker, Marco Gaetani, Clarissa Baldo, Gautier Landrot, Simona Montebello, Servanne Chevaillier, Sylvain Triquet, Guillaume Siour, Claudia Di Biagio, Francesco Battaglia, Jean-François Doussin, Anais Feron, Andreas Namwoonde, and Stuart John Piketh
EGUsphere, https://doi.org/10.5194/egusphere-2025-446, https://doi.org/10.5194/egusphere-2025-446, 2025
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The elemental composition and solubility of several metals, including iron, at a coastal site in Namibia in August–September 2017, indicate that natural and anthropogenic dust had different solubility depending on mineralogy but mostly to the processing by fluoride ions from marine emissions, pointing out to the complexity of atmospheric/oceanic interactions in this region of the world influenced by the Benguela current and significant aerosol load.
Jia-Yuan Wang, Meng-Xue Tang, Shan Lu, Ke-Jin Tang, Xing Peng, Ling-Yan He, and Xiao-Feng Huang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1034, https://doi.org/10.5194/egusphere-2025-1034, 2025
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Our study explores how secondary organic aerosols (SOA), a major component of air pollution, form in different particle sizes in a coastal city in China. We found that SOA in fine particles is mainly produced through aqueous chemical reactions, especially those involving iron. In contrast, coarse particles form SOA through reactions with ozone and gases from both fossil fuels and natural sources. These findings highlight the need for size-specific air pollution models.
Ashutosh K. Shukla, Sachchida N. Tripathi, Shamitaksha Talukdar, Vishnu Murari, Sreenivas Gaddamidi, Manousos-Ioannis Manousakas, Vipul Lalchandani, Kuldeep Dixit, Vinayak M. Ruge, Peeyush Khare, Mayank Kumar, Vikram Singh, Neeraj Rastogi, Suresh Tiwari, Atul K. Srivastava, Dilip Ganguly, Kaspar Rudolf Daellenbach, and André S. H. Prévôt
Atmos. Chem. Phys., 25, 3765–3784, https://doi.org/10.5194/acp-25-3765-2025, https://doi.org/10.5194/acp-25-3765-2025, 2025
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Our study delves into the elemental composition of aerosols at three sites across the Indo-Gangetic Plain (IGP), revealing distinct patterns during pollution episodes. We found significant increases in chlorine (Cl)-rich and solid fuel combustion (SFC) sources, indicating dynamic emission sources, agricultural burning impacts, and meteorological influences. Surges in Cl-rich particles during cold periods highlight their role in particle growth under high-relative-humidity conditions.
Kemei Li, Yanqing An, Jianzhong Xu, Miao Zhong, Wenhui Zhao, and Xiang Qin
EGUsphere, https://doi.org/10.5194/egusphere-2025-41, https://doi.org/10.5194/egusphere-2025-41, 2025
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This study presents a year-long PM2.5 study at Waliguan Baseline Observatory in the northeast of the Tibet Plateau to investigate the optical properties of water-soluble brown carbon and its source. Our findings highlight that organic matter, sulfate, and nitrate are the dominant contributors to PM2.5 mass concentrations. Notable seasonal variations in the light absorption capacity of water-soluble brown carbon, accompanied by a high degree of photochemical oxidation are also observed.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuwen Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 25, 3737–3752, https://doi.org/10.5194/acp-25-3737-2025, https://doi.org/10.5194/acp-25-3737-2025, 2025
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This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from diluted biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with background aerosol water and water-rich fogs and clouds.
Rongshuang Xu, Yu-Chi Lin, Siyu Bian, Feng Xie, and Yan-Lin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-683, https://doi.org/10.5194/egusphere-2025-683, 2025
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This work reported the hydroxymethanesulfonate (HMS) level in a continental city and, for the first time, in marine atmosphere. The enhancement by aerosol ionic strength (IS) on HMS formation was quantified which first rise with increasing IS, peaking at 4 mol kg–1 before declining. Given the IS range of marine (2–6) and urban aerosol (6–20 mol kg–1) and the clearly negative correlation between humidity and IS, the moderate IS level under humid condition may notably boost ambient HMS formation.
Jing Li, Jiaoshi Zhang, Xianda Gong, Steven Spielman, Chongai Kuang, Ashish Singh, Maria A. Zawadowicz, Lu Xu, and Jian Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-726, https://doi.org/10.5194/egusphere-2025-726, 2025
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Using measurements at a rural coastal site, we quantified aerosols in representative air masses and identified major source of organics in Houston area. Our results show cooking aerosol is likely overestimated by earlier studies. Additionally, diurnal variation of highly oxidized organics is mostly driven by air mass changes instead of photochemistry. This study highlights the impacts of emissions, atmospheric chemistry, and meteorology on aerosol properties in the coastal-rural environment.
Fan Mei, Qi Zhang, Damao Zhang, Jerome D. Fast, Gourihar Kulkarni, Mikhail S. Pekour, Christopher R. Niedek, Susanne Glienke, Israel Silber, Beat Schmid, Jason M. Tomlinson, Hardeep S. Mehta, Xena Mansoura, Zezhen Cheng, Gregory W. Vandergrift, Nurun Nahar Lata, Swarup China, and Zihua Zhu
Atmos. Chem. Phys., 25, 3425–3444, https://doi.org/10.5194/acp-25-3425-2025, https://doi.org/10.5194/acp-25-3425-2025, 2025
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This study highlights the unique capability of the ArcticShark, an uncrewed aerial system, in measuring vertically resolved atmospheric properties. Data from 32 research flights in 2023 reveal seasonal patterns and correlations with conventional measurements. The consistency and complementarity of in situ and remote sensing methods are highlighted. The study demonstrates the ArcticShark’s versatility in bridging data gaps and improving the understanding of vertical atmospheric structures.
Zheng Li, Gehui Wang, Binyu Xiao, Rongjie Li, Can Wu, Shaojun Lv, Feng Wu, Qingyan Fu, and Yusen Duan
EGUsphere, https://doi.org/10.5194/egusphere-2025-654, https://doi.org/10.5194/egusphere-2025-654, 2025
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Gas-to-aerosol partitioning of organics were investigated in Shanghai during 2023 dust storm period. We found the partitioning coefficients (Fp) of WSOCs in DS were comparable to those during a haze episode (HE), and aerosol liquid water content primarily drove Fp variation in HE, while pH was the dominant factor in DS. Moreover, an enhanced light absorption of Asian dust by brown carbon, mainly in coarse mode, formation was revealed.
Marco Paglione, Yufang Hao, Stefano Decesari, Mara Russo, Karam Mansour, Mauro Mazzola, Diego Fellin, Andrea Mazzanti, Emilio Tagliavini, Manousos Ioannis Manousakas, Evangelia Diapouli, Elena Barbaro, Matteo Feltracco, Kaspar Rudolf Daellenbach, and Matteo Rinaldi
EGUsphere, https://doi.org/10.5194/egusphere-2025-760, https://doi.org/10.5194/egusphere-2025-760, 2025
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A year-long set of PM1 samples from Ny-Ålesund, Svalbard, was analyzed by H-NMR and HR-TOF-AMS for the chemical characterization of the organic fraction. Positive Matrix Factorization allowed to identify five organic aerosol sources with specific seasonality. Winter-spring aerosol is dominated by Eurasian pollution, while summer is characterized by biogenic aerosols from marine sources; occasional summertime high OA loadings are associated with wildfire aerosols.
Ting Yang, Yu Xu, Yu-Chen Wang, Yi-Jia Ma, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2967–2978, https://doi.org/10.5194/acp-25-2967-2025, https://doi.org/10.5194/acp-25-2967-2025, 2025
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Previous measurement–model comparisons of atmospheric isoprene levels showed a significant unidentified source of isoprene in some northern Chinese cities during winter. Here, the first combination of large-scale observations and field combustion experiments provides novel insights into biomass burning emissions as a significant source of isoprene-derived organosulfates during winter in northern cities of China.
Agnesh Panta, Konrad Kandler, Kerstin Schepanski, Andres Alastuey, Pavla Dagsson Waldhauserova, Sylvain Dupont, Melanie Eknayan, Cristina González-Flórez, Adolfo González-Romero, Martina Klose, Mara Montag, Xavier Querol, Jesús Yus-Díez, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2025-494, https://doi.org/10.5194/egusphere-2025-494, 2025
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Iceland is among the most active dust source areas in the world. Dust properties are influenced by particle size, mineralogy, shape, and mixing state. This work characterizes freshly emitted individual aerosol particles of Icelandic dust using electron microscopy. Our study provides insights into critical particle-specific information will contribute to better constraining climate models that consider mineralogical variations in their representation of the dust cycle.
Xueqin Zheng, Junwen Liu, Nima Chuduo, Bian Ba, Pengfei Yu, Phu Drolgar, Fang Cao, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-164, https://doi.org/10.5194/egusphere-2025-164, 2025
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In this study, we present the first report on the annual variation of stable oxygen isotope anomalies (∆17O = δ17O - 0.52 × δ18O) in NO3- collected from the urban area of Lhasa , on the Tibetan Plateau, China. Using a Bayesian isotope mixture model, we found that the relative contribution of the NO3+VOC pathway to NO3- formation in spring in Lhasa was several times higher than in urban cities, highlighting the significant influence of VOC transported from outside the Tibetan Plateau.
Yi-Jia Ma, Yu Xu, Ting Yang, Lin Gui, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2763–2780, https://doi.org/10.5194/acp-25-2763-2025, https://doi.org/10.5194/acp-25-2763-2025, 2025
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The abundance, potential precursors, and main formation mechanisms of nitrogen-containing organic compounds (NOCs) in PM2.5 during winter were compared among cities with different energy consumption patterns. The aerosol NOC pollution during winter in China is closely associated with the intensity of precursor emissions and the aqueous-phase processes. Our results highlight the importance of emission reduction strategies in controlling aerosol NOCs pollution during winter in China.
Dane Blanchard, Mark Gordon, Duc Huy Dang, Paul Andrew Makar, and Julian Aherne
Atmos. Chem. Phys., 25, 2423–2442, https://doi.org/10.5194/acp-25-2423-2025, https://doi.org/10.5194/acp-25-2423-2025, 2025
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This study offers the first known evaluation of water-soluble brown carbon aerosols in the Athabasca oil sands region (AOSR), Canada. Fluorescence spectroscopy analysis of aerosol samples from five regional sites (collected during the summer of 2021) identified oil sands operations as a measurable brown carbon source. Industrial aerosol emissions were unlikely to impact regional radiative forcing. These findings show that fluorescence spectroscopy can be used to monitor brown carbon in the AOSR.
Kira Zeider, Kayla McCauley, Sanja Dmitrovic, Leong Wai Siu, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Simon Kirschler, John B. Nowak, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, Paquita Zuidema, and Armin Sorooshian
Atmos. Chem. Phys., 25, 2407–2422, https://doi.org/10.5194/acp-25-2407-2025, https://doi.org/10.5194/acp-25-2407-2025, 2025
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In situ aircraft data collected over the northwest Atlantic Ocean are utilized to compare aerosol conditions and turbulence between near-surface and below-cloud-base altitudes for different regimes of coupling strength between those two levels, along with how cloud microphysical properties vary across those regimes. Stronger coupling yields more homogenous aerosol structure vertically along with higher cloud drop concentrations and sea salt influence in clouds.
Amie Dobracki, Ernie R. Lewis, Arthur J. Sedlacek III, Tyler Tatro, Maria A. Zawadowicz, and Paquita Zuidema
Atmos. Chem. Phys., 25, 2333–2363, https://doi.org/10.5194/acp-25-2333-2025, https://doi.org/10.5194/acp-25-2333-2025, 2025
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Biomass-burning aerosol is commonly present in the marine boundary layer over the southeast Atlantic Ocean between June and October. Our research indicates that burning conditions, aerosol transport pathways, and prolonged oxidation processes (heterogeneous and aqueous phases) determine the chemical, microphysical, and optical properties of the boundary layer aerosol. Notably, we find that the aerosol optical properties can be estimated from the chemical properties alone.
Benjamin Heutte, Nora Bergner, Hélène Angot, Jakob B. Pernov, Lubna Dada, Jessica A. Mirrielees, Ivo Beck, Andrea Baccarini, Matthew Boyer, Jessie M. Creamean, Kaspar R. Daellenbach, Imad El Haddad, Markus M. Frey, Silvia Henning, Tiia Laurila, Vaios Moschos, Tuukka Petäjä, Kerri A. Pratt, Lauriane L. J. Quéléver, Matthew D. Shupe, Paul Zieger, Tuija Jokinen, and Julia Schmale
Atmos. Chem. Phys., 25, 2207–2241, https://doi.org/10.5194/acp-25-2207-2025, https://doi.org/10.5194/acp-25-2207-2025, 2025
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Limited aerosol measurements in the central Arctic hinder our understanding of aerosol–climate interactions in the region. Our year-long observations of aerosol physicochemical properties during the MOSAiC expedition reveal strong seasonal variations in aerosol chemical composition, where the short-term variability is heavily affected by storms in the Arctic. Local wind-generated particles are shown to be an important source of cloud seeds, especially in autumn.
Yifan Zhang, Rui Li, Zachary B. Bunnell, Yizhu Chen, Guanhong Zhu, Jinlong Ma, Guohua Zhang, Tim M. Conway, and Mingjin Tang
EGUsphere, https://doi.org/10.5194/egusphere-2025-474, https://doi.org/10.5194/egusphere-2025-474, 2025
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The sources of aerosol Fe, especially soluble aerosol Fe, remain to be constrained. The stable isotope ratio of Fe (δ56Fe) has emerged as a potential tracer for discriminating and quantifying sources of aerosol Fe. In this review, we examine the state of the field for using δ56Fe as an aerosol source tracer, and constraints on endmember signatures.
Feng Jiang, Harald Saathoff, Uzoamaka Ezenobi, Junwei Song, Hengheng Zhang, Linyu Gao, and Thomas Leisner
Atmos. Chem. Phys., 25, 1917–1930, https://doi.org/10.5194/acp-25-1917-2025, https://doi.org/10.5194/acp-25-1917-2025, 2025
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The chemical composition of brown carbon in the particle and gas phase was determined by mass spectrometry. BrC in the gas phase was mainly controlled by secondary formation and particle-to-gas partitioning. BrC in the particle phase was mainly from secondary formation. This work helps to get a better understanding of diurnal variations and the sources of brown carbon aerosol at a rural location in central Europe.
Kohei Sakata, Shotaro Takano, Atsushi Matsuki, Yasuo Takeichi, Hiroshi Tanimoto, Aya Sakaguchi, Minako Kurisu, and Yoshio Takahashi
EGUsphere, https://doi.org/10.5194/egusphere-2025-161, https://doi.org/10.5194/egusphere-2025-161, 2025
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Deposition of aerosol iron (Fe) into the ocean stimulates primary production and influences the global carbon cycle, although the factors governing the aerosol Fe solubility remain uncertain. Our observations in Japan revealed that both mineral dust and anthropogenic aerosols are significant sources of dissolved Fe, and that atmospheric chemical weathering enhances their solubility. This finding is expected to play a crucial role in estimating the supply of dissolved iron to the ocean.
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