Articles | Volume 13, issue 13
https://doi.org/10.5194/acp-13-6473-2013
https://doi.org/10.5194/acp-13-6473-2013
Research article
 | 
08 Jul 2013
Research article |  | 08 Jul 2013

Radical mechanisms of methyl vinyl ketone oligomerization through aqueous phase OH-oxidation: on the paradoxical role of dissolved molecular oxygen

P. Renard, F. Siekmann, A. Gandolfo, J. Socorro, G. Salque, S. Ravier, E. Quivet, J.-L. Clément, M. Traikia, A.-M. Delort, D. Voisin, V. Vuitton, R. Thissen, and A. Monod

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Cited articles

Alarifi, A. and Aouak, T.: Homopolymerization of benzylmethacrylate and methylvinylketone using Ni(acac)2-methylaluminoxane catalyst system, Arabian Journal of Chemistry 2, 87–93, 2009.
Baduel, C., Voisin, D., and Jaffrezo, J.-L.: Seasonal variations of concentrations and optical properties of water soluble HULIS collected in urban environments, Atmos. Chem. Phys., 10, 4085–4095, https://doi.org/10.5194/acp-10-4085-2010, 2010.
Bateman, A. P., Walser, M. L., Desyaterik, Y., Laskin, J., Laskin, A., and Nizkorodov, S. A.: The Effect of Solvent on the Analysis of Secondary Organic Aerosol Using Electrospray Ionization Mass Spectrometry, Environ. Sci. Technol., 42, 7341–7346, https://doi.org/10.1021/es801226w, 2008.
Benson, B. B. and Krause, D.: The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere, American Society of Limnology and Oceanography Inc., Department of Physics, Amherst College, Amherst, Massachusetts, USA, 1984.
Carlton, A. G., Wiedinmyer, C., and Kroll, J. H.: A review of Secondary Organic Aerosol (SOA) formation from isoprene, Atmos. Chem. Phys., 9, 4987–5005, https://doi.org/10.5194/acp-9-4987-2009, 2009.
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