Articles | Volume 13, issue 13
https://doi.org/10.5194/acp-13-6473-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-6473-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Radical mechanisms of methyl vinyl ketone oligomerization through aqueous phase OH-oxidation: on the paradoxical role of dissolved molecular oxygen
P. Renard
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
F. Siekmann
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
A. Gandolfo
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
J. Socorro
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
G. Salque
Université Joseph Fourier, Grenoble 1/CNRS-INSU, Laboratoire de Glaciologie et Géophysique de l'Environnement, 54 rue Molière, 38402 Saint-Martin-d'Hères, France
S. Ravier
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
E. Quivet
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
J.-L. Clément
Aix Marseille Université, CNRS, ICR UMR7273, 13397, Marseille, France
M. Traikia
Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, 63000 Clermont-Ferrand, France
A.-M. Delort
Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, 63000 Clermont-Ferrand, France
CNRS, UMR6296, ICCF, BP 80026, 63171 Aubière, France
D. Voisin
Université Joseph Fourier, Grenoble 1/CNRS-INSU, Laboratoire de Glaciologie et Géophysique de l'Environnement, 54 rue Molière, 38402 Saint-Martin-d'Hères, France
V. Vuitton
Institut de Planétologie et d'Astrophysique de Grenoble (IPAG) UMR5274, UJF-Grenoble1/CNRS-INSU, Grenoble, 38041, France
R. Thissen
Institut de Planétologie et d'Astrophysique de Grenoble (IPAG) UMR5274, UJF-Grenoble1/CNRS-INSU, Grenoble, 38041, France
A. Monod
Aix-Marseille Université, CNRS, LCE FRE3416, 13331, Marseille, France
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Cited
35 citations as recorded by crossref.
- Aqueous phase oligomerization of α,β-unsaturated carbonyls and acids investigated using ion mobility spectrometry coupled to mass spectrometry (IMS-MS) P. Renard et al.
- Multiphase Photochemistry of Pyruvic Acid under Atmospheric Conditions A. Reed Harris et al.
- Tropospheric Aqueous-Phase Chemistry: Kinetics, Mechanisms, and Its Coupling to a Changing Gas Phase H. Herrmann et al.
- Kinetics, Mechanism, and Secondary Organic Aerosol Yield of Aqueous Phase Photo-oxidation of α-Pinene Oxidation Products D. Aljawhary et al.
- Direct photolysis of carbonyl compounds dissolved in cloud and fog~droplets S. Epstein et al.
- Structure–activity relationship for the estimation of OH-oxidation rate constants of carbonyl compounds in the aqueous phase J. Doussin & A. Monod
- cis-Pinonic Acid Oxidation by Hydroxyl Radicals in the Aqueous Phase under Acidic and Basic Conditions: Kinetics and Mechanism B. Witkowski & T. Gierczak
- Mechanisms of isomerization and hydration reactions of typical β-diketone at the air-droplet interface Y. Ji et al.
- Aqueous Photochemistry of Glyoxylic Acid A. Eugene et al.
- Classification of clouds sampled at the puy de Dôme (France) based on 10 yr of monitoring of their physicochemical properties L. Deguillaume et al.
- Environmental Processing of Lipids Driven by Aqueous Photochemistry of α-Keto Acids R. Rapf et al.
- Photochemical Kinetics of Pyruvic Acid in Aqueous Solution A. Reed Harris et al.
- Aqueous oxidation of green leaf volatiles by hydroxyl radical as a source of SOA: Kinetics and SOA yields N. Richards-Henderson et al.
- Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols V. McNeill
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al.
- Model Analysis of Secondary Organic Aerosol Formation by Glyoxal in Laboratory Studies: The Case for Photoenhanced Chemistry A. Sumner et al.
- Laboratory studies of the aqueous-phase oxidation of polyols: submicron particles vs. bulk aqueous solution K. Daumit et al.
- Photochemical Synthesis of Oligomeric Amphiphiles from Alkyl Oxoacids in Aqueous Environments R. Rapf et al.
- Formation of Organosulfur Compounds through Transition Metal Ion-Catalyzed Aqueous Phase Reactions L. Huang et al.
- The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges B. Nozière et al.
- Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 2: Development of the chemical mechanism and atmospheric implications B. Ervens et al.
- Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 1: Aging processes of oligomers P. Renard et al.
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al.
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al.
- Experimental and theoretical studies on the photodegradation of 2-ethylhexyl 4-methoxycinnamate in the presence of reactive oxygen and chlorine species A. Gackowska et al.
- Oligomer formation in the troposphere: from experimental knowledge to 3-D modeling V. Lemaire et al.
- Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products B. Witkowski et al.
- Sunlight as an energetic driver in the synthesis of molecules necessary for life R. Rapf & V. Vaida
- Liquid phase transformation mechanism of β-caryophyllonic acid initiated by hydroxyl radicals and ozone in atmosphere C. Sun et al.
- Insight into the formation of organosulfur compounds from the reaction of methyl vinyl ketone with sulfite radical in atmospheric aqueous phase G. Lv et al.
- Aqueous Phase Oligomerization of Methyl Vinyl Ketone by Atmospheric Radical Reactions P. Renard et al.
- Kinetics and products of the aqueous-phase oxidation of β-caryophyllonic acid by hydroxyl radicals B. Witkowski et al.
- Kinetics and Mechanisms of Aqueous-Phase Reactions of Triplet-State Imidazole-2-carboxaldehyde and 3,4-Dimethoxybenzaldehyde with α,β-Unsaturated Carbonyl Compounds K. Aregahegn et al.
- Formation of Organosulfur Compounds from Aqueous Phase Reactions of S(IV) with Methacrolein and Methyl Vinyl Ketone in the Presence of Transition Metal Ions L. Huang et al.
- A New Potential Atmospheric Accretion Mechanism: Acid-Catalyzed Hetero-Michael Addition Reactions R. Fenselau et al.
35 citations as recorded by crossref.
- Aqueous phase oligomerization of α,β-unsaturated carbonyls and acids investigated using ion mobility spectrometry coupled to mass spectrometry (IMS-MS) P. Renard et al.
- Multiphase Photochemistry of Pyruvic Acid under Atmospheric Conditions A. Reed Harris et al.
- Tropospheric Aqueous-Phase Chemistry: Kinetics, Mechanisms, and Its Coupling to a Changing Gas Phase H. Herrmann et al.
- Kinetics, Mechanism, and Secondary Organic Aerosol Yield of Aqueous Phase Photo-oxidation of α-Pinene Oxidation Products D. Aljawhary et al.
- Direct photolysis of carbonyl compounds dissolved in cloud and fog~droplets S. Epstein et al.
- Structure–activity relationship for the estimation of OH-oxidation rate constants of carbonyl compounds in the aqueous phase J. Doussin & A. Monod
- cis-Pinonic Acid Oxidation by Hydroxyl Radicals in the Aqueous Phase under Acidic and Basic Conditions: Kinetics and Mechanism B. Witkowski & T. Gierczak
- Mechanisms of isomerization and hydration reactions of typical β-diketone at the air-droplet interface Y. Ji et al.
- Aqueous Photochemistry of Glyoxylic Acid A. Eugene et al.
- Classification of clouds sampled at the puy de Dôme (France) based on 10 yr of monitoring of their physicochemical properties L. Deguillaume et al.
- Environmental Processing of Lipids Driven by Aqueous Photochemistry of α-Keto Acids R. Rapf et al.
- Photochemical Kinetics of Pyruvic Acid in Aqueous Solution A. Reed Harris et al.
- Aqueous oxidation of green leaf volatiles by hydroxyl radical as a source of SOA: Kinetics and SOA yields N. Richards-Henderson et al.
- Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols V. McNeill
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al.
- Model Analysis of Secondary Organic Aerosol Formation by Glyoxal in Laboratory Studies: The Case for Photoenhanced Chemistry A. Sumner et al.
- Laboratory studies of the aqueous-phase oxidation of polyols: submicron particles vs. bulk aqueous solution K. Daumit et al.
- Photochemical Synthesis of Oligomeric Amphiphiles from Alkyl Oxoacids in Aqueous Environments R. Rapf et al.
- Formation of Organosulfur Compounds through Transition Metal Ion-Catalyzed Aqueous Phase Reactions L. Huang et al.
- The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges B. Nozière et al.
- Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 2: Development of the chemical mechanism and atmospheric implications B. Ervens et al.
- Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 1: Aging processes of oligomers P. Renard et al.
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al.
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al.
- Experimental and theoretical studies on the photodegradation of 2-ethylhexyl 4-methoxycinnamate in the presence of reactive oxygen and chlorine species A. Gackowska et al.
- Oligomer formation in the troposphere: from experimental knowledge to 3-D modeling V. Lemaire et al.
- Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products B. Witkowski et al.
- Sunlight as an energetic driver in the synthesis of molecules necessary for life R. Rapf & V. Vaida
- Liquid phase transformation mechanism of β-caryophyllonic acid initiated by hydroxyl radicals and ozone in atmosphere C. Sun et al.
- Insight into the formation of organosulfur compounds from the reaction of methyl vinyl ketone with sulfite radical in atmospheric aqueous phase G. Lv et al.
- Aqueous Phase Oligomerization of Methyl Vinyl Ketone by Atmospheric Radical Reactions P. Renard et al.
- Kinetics and products of the aqueous-phase oxidation of β-caryophyllonic acid by hydroxyl radicals B. Witkowski et al.
- Kinetics and Mechanisms of Aqueous-Phase Reactions of Triplet-State Imidazole-2-carboxaldehyde and 3,4-Dimethoxybenzaldehyde with α,β-Unsaturated Carbonyl Compounds K. Aregahegn et al.
- Formation of Organosulfur Compounds from Aqueous Phase Reactions of S(IV) with Methacrolein and Methyl Vinyl Ketone in the Presence of Transition Metal Ions L. Huang et al.
- A New Potential Atmospheric Accretion Mechanism: Acid-Catalyzed Hetero-Michael Addition Reactions R. Fenselau et al.
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